Invisible, Ballpoint, Or Typewriter Ink Compositions Or Process Of Preparing; Or Composition For Correction Ribbons Or Correction Fluids Or Process Of Preparing Patents (Class 523/161)
  • Patent number: 7423076
    Abstract: The present invention relates to a microencapsulated pigment in which pigment particles having cationic groups on their surfaces are coated with a polymer having repeating structural units derived from an anionic polymerizable surfactant having at least an anionic group, a hydrophobic group and a polymerizable group, and a microencapsulated pigment in which pigment particles having anionic groups on their surfaces are coated with a polymer having repeating structural units derived from a cationic polymerizable surfactant having a cationic group, a hydrophobic group and a polymerizable group. Further, the invention relates to a process for producing the microencapsulated pigment, an aqueous dispersion containing the microencapsulated pigment, and an ink jet recording ink containing the aqueous dispersion.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: September 9, 2008
    Assignee: Seiko Epson Corporation
    Inventor: Toshiyuki Miyabayashi
  • Patent number: 7423075
    Abstract: A polymer having a specific repeating structural unit having in the side chain at least one selected from a sulfonic acid, a sulfonic acid ester and a sulfonic acid salt and a specific repeating structural unit having in the side chain at least one selected from a carboxylic acid, a carboxylic acid ester and a carboxylic acid salt.
    Type: Grant
    Filed: May 2, 2005
    Date of Patent: September 9, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masayuki Ikegami, Koichi Sato, Ikuo Nakazawa, Ryuji Higashi, Sakae Suda, Keiichiro Tsubaki, Keiko Yamagishi
  • Patent number: 7420006
    Abstract: An ink set comprises a black ink which contains a black pigment, resin particles having carboxyl group, a first pH-adjusting agent, a water-soluble organic solvent, and water, and a color ink which contains a coloring pigment, resin particles, a second pH-adjusting agent, a water-soluble organic solvent, and water. The pH of the black ink is not less than 7.8, and the pH of the color ink is not more than 4.5. Any bleeding of the black ink is not caused even when an image is formed on a cloth or the like with the ink set. Even when the cloth is washed, then the ink is not lost from the image formation objective, and the initial image density is maintained.
    Type: Grant
    Filed: August 22, 2003
    Date of Patent: September 2, 2008
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventor: Takashi Kawaguchi
  • Patent number: 7417080
    Abstract: Provided is an oil-based ink composition comprising at least a colorant, titanium oxide, a solvent including propylene glycol monomethyl ether and ethanol, a polyvinylbutyral resin and a ketone resin.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: August 26, 2008
    Assignee: Mitsubishi Pencil Co., Ltd.
    Inventors: Masanao Yano, Yoshihito Fujiwara, Tadashi Koriki, Yuji Omori, Naoto Yokokawa
  • Patent number: 7417079
    Abstract: The use of a styrene-maleic anhydride copolymer in self-dispersed black pigment inks provides a means of achieving black-to-color bleed control against color.
    Type: Grant
    Filed: July 28, 2003
    Date of Patent: August 26, 2008
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Patricia A Wang, Alexey S Kabalnov
  • Patent number: 7414083
    Abstract: An ink for ink-jet recording contains tripropylene glycol normal butyl ether or dipropylene glycol normal propyl ether, an acrylic polymer, a water-insoluble coloring agent, and water. The ink simultaneously satisfies the straight travel stability of ink droplets during the discharge with an ink-jet recording apparatus, the recovery performance upon introduction into a recording head of the ink-jet recording apparatus, the fixation performance of printed matters, and the drying performance after the printing.
    Type: Grant
    Filed: September 23, 2003
    Date of Patent: August 19, 2008
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Mayuko Okada, Masaya Fujioka, Shunichi Higashiyama
  • Patent number: 7414082
    Abstract: The present invention relates to a recording liquid comprising at least: a pigment (a); and a polymer (b) having one or more types of bond selected from the group consisting of amide bond, urethane bond and urea bond in the molecule, having a weight-average molecular weight of 5000 to 300000 and having an acid value of free acid of not less than 55 mgKOH/g and less than 150 mgKOH/g, the surface tension of said recording liquid being 25 to 54 dyne/cm.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: August 19, 2008
    Assignees: Mitsubishi Chemical Corporation, Mikuni Color Ltd.
    Inventors: Takashi Hirasa, Kazunori Maruyama, Naomi Fujimori
  • Patent number: 7414081
    Abstract: Radiation-curable compositions, and methods of making the same, for providing a wide variety of substrates with a durable, colored coating or colorant are disclosed. The color is at least in part provided by chromophore molecules that are covalently bonded to other components within the radiation-curable composition. A telecommunication element having a durable color identifying polymeric coating thereon is also disclosed. The telecommunication element comprises an elongated communication transmission medium, such as an optical fiber or an optical fiber ribbon, and a radiation-cured polymeric coating having an identifying color applied on at least a portion of the transmission medium.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: August 19, 2008
    Assignee: Draka Comteq B.V.
    Inventors: Robert W. Greer, Todd Warren Gantt, Michael B. Purvis, Bob J. Overton
  • Patent number: 7411008
    Abstract: The present invention provides a chemical ink comprises a solvent, a binder polymer, a colorant and optionally a crosslinker. The ink of the invention has one or more of the following characteristics: a viscosity lower than about 50 centipoises; a surface tension of from about 20 mN/m to about 60 mN/m; a particle size of less than about 5 ?m; prolonged stability; an appropriate color level (visible by eye); uniform drop formation; jet stability; good adhesion to contact lenses; good transfer from a mold to a lens made in the mold; and stability of ink in inkjet nozzles. The ink of the invention is useful for inkjet printing of a high-quality color image on a contact lens or a mold so as to produce a colored contact lens.
    Type: Grant
    Filed: November 4, 2002
    Date of Patent: August 12, 2008
    Assignee: Novartis AG
    Inventors: Robert Carey Tucker, Sandra Corti
  • Patent number: 7405245
    Abstract: To provide an aqueous ink composition which, without impairing ejection stability, is excellent in light-fastness and water-fastness, does not cause cohesion differential, gloss differential, bronzing phenomenon, color-bleeding, and the like, and has improved fixing ability and coloring property. An aqueous ink composition comprising at least water, a pigment dispersed by polymer, a sulfonyl group-containing (co)polymer, and an ultra-penetrating agent.
    Type: Grant
    Filed: November 2, 2001
    Date of Patent: July 29, 2008
    Assignee: Seiko Epson Corporation
    Inventors: Kazuaki Watanabe, Shinichi Kato, Bunji Ishimoto
  • Patent number: 7402616
    Abstract: A fusible conductive ink for use in manufacturing microfluidic analytical systems includes micronised powder containing platinum and carbon, poly(bisphenol A-co-epichlorohydrin)-glycidyl end capped polymer, and a solvent. In addition, the ratio of micronised powder to poly(bisphenol A-co-epichlorohydrin)-glycidyl end capped polymer is in the range of 3:1 to 1:3. The fusible conductive inks can be employed in the manufacturing of microfluidic systems to form electrodes, electrically conductive traces and/or electrically conductive contact pads.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: July 22, 2008
    Assignee: Lifescan, Inc.
    Inventors: James Iain Rodgers, Margaret Maclennan, James Moffat, Alan McNeilage
  • Patent number: 7402615
    Abstract: A water washable waterless offset printing ink comprised of a binding agent having (i) a solid resin in an ester solvent, and (ii) an alkyd resin and/or an oil of one or more aliphatic carboxylic acid esters; a colorant; and a neutralizing agent.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: July 22, 2008
    Assignee: Sun Chemical Corporation
    Inventors: Christian Johnke, Bernard Fritz
  • Patent number: 7402613
    Abstract: A water-based ink for ink-jet printing, comprising colored particles containing: (a) a core particle having a colorant; and (b) a shell having a resin and encapsulating the core particle, wherein the resin comprises a monomer unit having a hydroxyl group in an amount of 0.1 to 50 weight % based on the total weight of the shell.
    Type: Grant
    Filed: September 6, 2002
    Date of Patent: July 22, 2008
    Assignee: Konica Corporation
    Inventors: Hidetaka Ninomiya, Hiroaki Ando
  • Patent number: 7402614
    Abstract: Re-dispersible pigmented printing ink compositions, preferably for the continuous ink jet printing process are obtained by the addition of a flocculating agent to the pigment dispersion in the printing liquid. The compositions do not form hard sediments and are easy to re-disperse on stopping and resuming the printing operations. Suitable flocculating agents bind the pigment particles in the sediment into three-dimensional “airy” structures, which are easy to break up. The ink compositions of the invention are furthermore characterized by a good printability in the dispersed state.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: July 22, 2008
    Assignee: SICPA Holding S.A.
    Inventors: Xavier Marguerettaz, Thomas Tiller, Edgar Muller, Frederic Gremaud, Sylvain Jaquier
  • Patent number: 7402617
    Abstract: The present invention is drawn toward latex particulates in ink-jet inks having a surface dielectric constant from 2.0 to 3.0.
    Type: Grant
    Filed: February 6, 2003
    Date of Patent: July 22, 2008
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Sivapackia Ganapathiappan, Kent Vincent
  • Patent number: 7399796
    Abstract: A jettable non-curable support material composition useful for three-dimensional ink jet printing comprising at least one fatty alcohol and at least one abietic rosin ester alcohol, wherein the support material has a melting point between about 50° C. to about 65° C. and a freezing point between about 45° C. to about 55° C.
    Type: Grant
    Filed: June 17, 2004
    Date of Patent: July 15, 2008
    Assignee: 3D Systems, Inc.
    Inventors: Pingyong Xu, Stephen A. Ruatta, Kris Alan Schmidt, Vu A. Doan
  • Patent number: 7399797
    Abstract: A cationic polymerizable composition comprising a cationic polymerizable mixture, a cationic polymerization initiator and an amino alcohol, wherein the amino alcohol contains two hydroxyl groups and one carbon chain containing a carbon atom having one or no hydrogen atom bonded to the carbon atom, an actinic ray curable ink-jet ink using the same, and a method of stabilizing the cationic polymerizable composition.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: July 15, 2008
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Nobumasa Sasa
  • Patent number: 7396396
    Abstract: A water-in-oil emulsion ink comprises a water phase and an oil phase, wherein the water phase comprises a carbon black pigment having a pH of less than 8 dispersed therein by a water-soluble resin, and wherein the water phase also comprises a pH-adjusting agent to achieve a pH value for the water phase of 8 or greater. The ink maintains stable rheology on ageing, and provides a stable and consistent ink detection signal even after periods of non-use.
    Type: Grant
    Filed: November 10, 2004
    Date of Patent: July 8, 2008
    Assignees: GR Advanced Materials Ltd., Tohoku Ricoh Co., Ltd.
    Inventor: John Christopher Adams
  • Patent number: 7396864
    Abstract: A HAPs-free ink jet ink includes a pigment; a binder comprising vinyl chloride-vinyl acetate copolymer; and a HAPs-free solvent component comprising 1-methoxy-2-propanol acetate, a dispersing solvent selected from cyclohexanone, n-propyl acetate, n-butyl acetate, diisobutyl ketone, isobutyl acetate, amyl acetate, and combinations of these, and a diluent solvent selected from dipropylene glycol methyl ether, dipropylene glycol methyl ether acetate, tripropylene glycol methyl ether, ethylene glycol diacetate, propylene glycol n-butyl ether, propylene glycol n-propyl ether, and combinations of these. The ink has excellent stability and printing properties. Printing with the ink avoids release of HAPs while allowing long print runs with low maintenance.
    Type: Grant
    Filed: July 26, 2004
    Date of Patent: July 8, 2008
    Assignee: Jetrion, L.L.C.
    Inventor: Deena L Salenbien
  • Patent number: 7396863
    Abstract: An ink set comprising a black ink and a color ink, wherein the black ink comprises an aqueous dispersion of water-insoluble vinyl polymer particles containing an oil-soluble black dye or carbon black, the vinyl polymer particles have an ionicity opposite to that of the color ink, and the vinyl polymer comprises a water-insoluble vinyl polymer prepared by copolymerizing (a) a salt forming group-containing monomer, (b) a monomer represented by the formula (I): CH2?C(R1)COO(R2O)pR3 ??(I) wherein R1 is hydrogen atom or a lower alkyl group, R2 is a divalent hydrocarbon group which may have a hetero-atom, R3 is a monovalent hydrocarbon group which may have a hetero-atom, and p is a number of 1 to 60, (c) a macromer, and (d) a monomer copolymerizable with these monomers. The ink set can be used as an ink set for inkjet recording, which is excellent in not only fixing abilities and water resistance, but also bleeding resistance and jettability, and can form very clear printouts.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: July 8, 2008
    Assignee: Kao Corporation
    Inventors: Yukihiro Nakano, Shigeki Nagashima, Hiroki Kubo, Michitaka Sawada
  • Patent number: 7393881
    Abstract: A telecommunication element having a durable color identifying polymeric coating thereon is disclosed. The telecommunication element comprises an elongated communication transmission medium, such as an optical fiber or an optical fiber ribbon, and a radiation cured polymeric coating having an identifying color applied on at least a portion of the transmission medium. The identifying color in the polymeric coating is provided by chromophore molecules that are covalently bonded thereto. Coating compositions and a method are also disclosed.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: July 1, 2008
    Assignee: ALCATEL
    Inventor: Robert W. Greer, IV
  • Patent number: 7393884
    Abstract: A pigmented ink composition comprising a pigment, a resin having an acidic group and an organic solvent having a boiling point of at least 150° C. which is present in an amount of from 50 to 90% by weight based on the whole weight of the ink composition. When this ink composition is subjected to an printed layer-sliding test in which the ink composition is applied on a cationically treated printing medium with a #4 bar coater (available from TOYO SEIKI KOGYO CO., LTD.) and dried and then the printed surface is slid with a cloth on which a weight of 50 g is placed, the printed record is not grazed. This ink composition contains the pigment with a small dispersion particle size and has good water resistance, can be printed on a plain paper sheet without cockling, and suffers from no grazing of printed records when the ink composition is printed on a cationically treated paper sheet.
    Type: Grant
    Filed: June 20, 2003
    Date of Patent: July 1, 2008
    Assignee: Hitachi Maxwell, Ltd.
    Inventors: Takahiro Furutani, Nagayuki Takao
  • Patent number: 7388040
    Abstract: A fixer fluid having reduced kogation. The fixer fluid includes at least one phosphate ester surfactant and at least one cationic polymer, wherein the fixer fluid is formulated so that the at least one phosphate ester surfactant does not precipitate with the at least one cationic polymer. The at least one phosphate ester surfactant may be an anionic phosphate ester surfactant or an amphoteric phosphate ester surfactant. If the at least one phosphate ester surfactant is an anionic phosphate ester surfactant, it may have greater than or equal to approximately 2 moles of ethylene oxide per mole of the phosphate ester surfactant. The present invention also relates to an inkjet ink having reduced kogation and a method of producing a fixer fluid having reduced kogation.
    Type: Grant
    Filed: April 8, 2004
    Date of Patent: June 17, 2008
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Richard A. Sader, Mark L. Choy, Yi-Hua Tsao, Paul J. Bruinsma
  • Patent number: 7384992
    Abstract: This invention relates to novel rosin-alkyl ester of unsaturated fatty acid vinylic polymer and emulsion compositions and the processes for preparing them. In particular, the invention relates to novel rosin-alkyl ester of unsaturated fatty acid vinylic polymer and emulsion compositions which the polymer exhibit properties that make them useful as support resins for industrial coatings, ink and overprint formulations and as additives for formulating various coating compositions; and the emulsion which exhibits properties that make them useful as water-borne vehicles for coatings on various substrates.
    Type: Grant
    Filed: September 24, 2004
    Date of Patent: June 10, 2008
    Assignee: MeadWestvaco Corporation
    Inventor: Louis Joseph Tortorelli
  • Patent number: 7384990
    Abstract: The present invention is drawn to compositions and methods of generating active ester functionalized latex particulates in a liquid suspension, as well as compositions and methods of preparing ink-jet inks. Steps of the methods can include synthesizing polymerizable monomers with active ester groups and polymerizing these monomers with other monomers to form functionalized latex particulates having active ester group. These latex particulates can be used in a wide variety of applications, including in ink-jet ink printing applications.
    Type: Grant
    Filed: June 17, 2004
    Date of Patent: June 10, 2008
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Zhang-Lin Zhou
  • Patent number: 7384991
    Abstract: The present invention provides an aqueous ink containing a dispersion in which a colorant is encapsulated with a polymer to make it dispersible in water, wherein the polymer has aromatic rings in an amount of from 20% by weight to 70% by weight based on the weight of the polymer, and further, the ink contains a compound represented by the following formula: wherein R represents a bivalent organic group, PO represents a propyleneoxy group, EO represents an ethyleneoxy group, x, y, a and b are each the number of repeating units, x represents a number of 1 to 200, y represents a number of 1 to 50, a represents a number of 1 to 30, and b represents a number of 0 to 20.
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: June 10, 2008
    Assignee: Seiko Epson Corporation
    Inventors: Hidehiko Komatsu, Masahiro Yatake, Kazuhiko Hara, Masaaki Itano, Jun Ito, Motoki Masuda
  • Patent number: 7381760
    Abstract: The invention relates to a pigment dispersion comprising: a condensate of or a salt between a polyallylamine and a polyester having a free carboxylic acid or the salt; a pigment derivative represented by the following general formula (1); a pigment; and an organic solvent, (P?X)?[N(R1, R2, R3, R4)]+??general formula (1) wherein p represents an organic dyestuff residue; X represents a sulfonic acid group or a carboxylic acid group; R1 represents an alkyl group having 5 to 20 carbon atoms; and R2, R3 and R4 each independently represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms.
    Type: Grant
    Filed: June 29, 2004
    Date of Patent: June 3, 2008
    Assignee: Toyo Ink Mfg.Co., Ltd.
    Inventors: Seiji Aida, Shinya Fujimatsu, Kaori Nakano, Shinichi Sato, Daisuke Tanabe
  • Patent number: 7381755
    Abstract: An aqueous ink jet ink composition including a pigment, a polymer latex containing at least one halogenated vinyl monomer, at least one surfactant, and a humectant. An ink and receiver combination for a non-absorbing substrate is also disclosed.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: June 3, 2008
    Assignee: Eastman Kodak Company
    Inventors: Xiaoru Wang, Huijuan D. Chen, Ricky G. Frazier, Jin-Shan Wang
  • Patent number: 7381757
    Abstract: A decolorable ink usable in various printing processes and an image forming method utilizing such decolorable ink. The decolorable ink comprises a block polymer having a stimulus responsiveness, a colorant which decolors in response to a change in a property of the block polymer when a stimulus is applied to the block polymer, and a solvent. Also the image forming method conducts recording by applying ink onto a recording medium, utilizing the decolorable ink as the ink.
    Type: Grant
    Filed: June 9, 2003
    Date of Patent: June 3, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koichi Sato, Ikuo Nakazawa, Sakae Suda, Masayuki Ikegami
  • Patent number: 7381758
    Abstract: The invention relates to passivated optically variable pigment, a method of preparing said passivated optically variable pigment, an ink composition comprising said passivated optically variable pigment, the use of said ink composition, and a document carrying a marking made with said ink composition.
    Type: Grant
    Filed: August 15, 2002
    Date of Patent: June 3, 2008
    Assignee: SICPA Holding S.A.
    Inventors: Aline Vuarnoz, Olivier Amrein, Patrick Veya
  • Patent number: 7381754
    Abstract: An ink composition comprising at least one dye represented by one of the following chemical structural formulae and an anthraquinone-based pigment as coloring materials, an alcohol or an ether as a solvent, and a resin. In a preferred embodiment, a triarylmethane-based dye is used in combination or polyvinylbutyral is contained as the resin. wherein A is a tertiary or quaternary ammonium ion group.
    Type: Grant
    Filed: July 19, 2002
    Date of Patent: June 3, 2008
    Assignee: Mitsubishi Pencil Co., Ltd.
    Inventors: Shuuji Ichikawa, Takayuki Ikai
  • Patent number: 7381753
    Abstract: An inkjet ink composition having a binder including an aqueous dispersion of polymer particles, the polymer including, as polymerized units, (a) from 0 to 1 wt. % monoethylenically unsaturated acid monomer, based on polymer weight; and (b) monomer of the formula CH2?C(R1)—CON(R2)(R3) wherein R1?H, CH3 or C2H5 and R2 and R3 are independently selected from C1-C6 saturated alkyl and cycloalkyl groups; and wherein the total of (a) and (b) is at least 0.1 wt % monomer based on the polymer weight. The binder may be a copolymer of ethyl acrylate and acrylamide. An inkjet ink composition including the inkjet ink binder, a colorant, and a liquid medium is also provided.
    Type: Grant
    Filed: April 14, 2005
    Date of Patent: June 3, 2008
    Assignee: Lexmark International, Inc.
    Inventors: Bradley Leonard Beach, Alberto Carrillo, Michael Paul Hallden-Abberton, Ann P. Holloway, Joseph Edward Johnson, George Max Lein, Richard Foster Merritt, Anna Marie Pearson
  • Patent number: 7381759
    Abstract: A dispersible composition that comprises a polymer compound, a functional substance such as a colorant, and a solvent or a dispersion medium, where the polymer compound is comprised of a monomer unit represented by the general formula (1) wherein A is a straight-chain or branched alkylene group of 1 to 15 carbon atoms with or without substitution; m is an integer of 0 to 30, and when m is 2 or more, A is the same or different each other; B is a single bond or an alkylene with or without substitution; D is a substituted or unsubstituted aromatic ring structure; n is an integer of 1 to 10, and when n is 2 or more, D is the same or different with each other. The composition is usable as an ink composition or toner composition.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: June 3, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Sakae Suda, Koichi Sato, Ikuo Nakazawa, Masayuki Ikegami
  • Patent number: 7378458
    Abstract: The invention provides a method for preparing an ink having constituents of a water-soluble dye having a water-soluble solubilizing group of at least one of a sulfonic group and a carboxyl group, water, a water-soluble substance that is condensation-polymerized in the absence of the water, a water-soluble medium and an additive including at least one of an organic acid salt and an inorganic acid salt. This method includes a first mixing step of mixing at least the dye and the water-soluble substance out of the constituents of the ink excluding the additive; a second mixing step of mixing a mixture obtained in the first mixing step and the additive; and a pH adjusting step, performed before the second mixing step, of preparing a solution including the mixture or a solution including the additive while adjusting the solution to a given pH range by using a pH adjuster.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: May 27, 2008
    Assignees: Matsushita Electric Industrial Co., Ltd., Ricoh Company, Ltd.
    Inventors: Hidekazu Arase, Mamoru Soga, Masaichiro Tatekawa, Shigeru Kusakata, Tsutomu Matsuda, Masashi Itoh
  • Patent number: 7378459
    Abstract: Disclosed herein is a pigment-dispersed ink-jet ink comprising a pigment and a resinous dispersing agent, wherein the resinous dispersing agent is a vinyl copolymer having an acid value of 50 mg KOH/g or higher and a solubility of at most 3% by mass in an alkaline solution containing KOH in an amount 1.5 times as much as the acid value, and the viscosity characteristic of the ink as measured by means of a viscoelastometer satisfies the following relationship: 1.1?(Viscosity of an ink as measured under conditions of 20° C. and a shear rate of 0.5 sec?1)/(Viscosity of an ink as measured under conditions of 20° C. and a shear rate of 100 sec?1)?2.0.
    Type: Grant
    Filed: October 5, 2004
    Date of Patent: May 27, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventor: Kenji Nishiguchi
  • Patent number: 7375147
    Abstract: Ink jet recording method and apparatus is provided in which a color image is recorded by discharging, onto a recording medium, a black ink and at least one of a cyan ink, a magenta ink and a yellow ink from a black-ink recording head that ejects the black ink onto the recording medium, and a color-ink recording head that ejects the at least one of a cyan ink, a magenta ink and a yellow ink onto the recording medium, wherein the black ink contains carbon black, water, a water-soluble organic solvent, and a water-soluble polymer having an anionic functional group, and has a drying time of 5 seconds or more on the recording medium, and at least one type of the color ink contains a color material, water, a water-soluble organic solvent, and a coagulating agent, and has a drying time of 5 seconds or less on the recording medium.
    Type: Grant
    Filed: June 10, 2004
    Date of Patent: May 20, 2008
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Atsushi Suzuki, Nobuyuki Ichizawa, Yoshiro Yamashita
  • Publication number: 20080112911
    Abstract: A process for manufacturing a highly water-soluble vinyl alcohol-N-vinyl amine copolymer with a degree of hydrolysis higher than 93%, including a hydrolysis reaction of a vinyl alcohol-N-vinyl formamide copolymer with an alkaline metal hydroxide in methanol wherein the process is carried out with more than 1.5 mol of the alkaline metal hydroxide per mol of N-vinyl formamide units and without addition of water. A higher water soluble vinyl alcohol-N-vinyl amine copolymer obtained by this process and the use thereof.
    Type: Application
    Filed: January 26, 2006
    Publication date: May 15, 2008
    Applicant: ERKOL, S.A.
    Inventors: Juan Carlos Rodriguez Esteban, Alfredo Seco Carracedo, Maria del Carmen Palau Vall, Joseba Iñaki Iragorri Sainz
  • Patent number: 7371456
    Abstract: The present invention provides nanoparticle based recording mediums, inks and ink compositions, methods of making nanoparticle based recording mediums and inks, nanoparticles and methods for making nanoparticles, methods for stabilizing colorants against electromagnetic radiation (including radiation in the visible wavelength range), methods for enhancing the substrate independent durability performance of inks, and methods for color density control. The nanoparticle based inks deliver better color, color density control, improved printability, enhanced durability, and increased lightfastness, and are capable of being printed on woven and non-woven fabrics and paper products without special treatment or other limitations.
    Type: Grant
    Filed: October 2, 2001
    Date of Patent: May 13, 2008
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ronald S. Nohr, John Gavin MacDonald
  • Patent number: 7371785
    Abstract: An erasable ink composition comprising water, a water-soluble organic solvent, and the following colorant, colorless resin particles and shear-thinning, viscosity-adjustment agent, characterized in that the colorless resin particles have a mean particle diameter smaller than that of the colorant and are contained in an amount larger than that of the colorant: (a) 3 to wt % (based on the whole ink) of colorless resin particles which are made of at least one resin selected from among acrylic resins, urethane resins, silicone resins and melamine resins and have a mean particle diameter of 0.10 to 10 ?m, (b) 1 to 40 wt % (based on the whole ink) of a colorant having a mean particle diameter of 2 ?m or above, and (c) 0.01 to 4 wt % (based on the whole ink) of a shear thinning, viscosity-adjustment agent.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: May 13, 2008
    Assignee: Sakura Color Products Corporation
    Inventors: Yasuyuki Yoshimura, Norimasa Kurihara, Atsushi Sudo, Norihiro Hirano, Isao Enjon
  • Patent number: 7368487
    Abstract: Ink jet printable compositions comprise an aqueous vehicle, particles of a self-crosslinking polymer, and optional colorant. In one embodiment, an ink jet printable ink may comprise an aqueous vehicle, a colorant, and a silyl-terminated sulfopoly(ester-urethane) polymer. In another embodiment, an ink jet printable ink comprises an aqueous vehicle, colorant, and at least 20 weight percent dispersed shear deformable polymer particles wherein the polymer is self-crosslinking. In another aspect, the invention concerns methods of printing a composition, and printed articles produced thereby.
    Type: Grant
    Filed: November 15, 2001
    Date of Patent: May 6, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Dong Wu, Larry R. Krepski, Kevin M. Lewandowski, Caroline M. Ylitalo, Peter T. Elliott
  • Patent number: 7365107
    Abstract: The invention relates to a marking liquid which contains a polymer dispersion with particles which are colored with marking agent, optionally further dyes and marking agents, one or more salts of a polyvalent, in particular bi- or trivalent cation, water and optionally moisture retaining agents and further usual additives, wherein the polymer forming the polymer particles is selected from the group of polyesters, polyester amides, polymers and copolymers based on acrylate or methacrylate with a proportion of free carboxylic acid groups of less than 10% by weight, melamine-formaldehyde-sulfonamide resins and mixtures thereof.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: April 29, 2008
    Assignee: Schwan-STABILO Schwanhausser GmbH & Co. KG
    Inventors: Hans-Dieter Denninger, Thomas Spengler, Ivan Horvat, Klaus-Dieter Schröder
  • Patent number: 7365108
    Abstract: An ink includes a jettable vehicle, a plurality of pigment solids dispersed in the jettable vehicle, and a styrene-maleimide copolymer dispersed in the jettable vehicle. Additionally, a method of rapidly printing an ink-jet image including ink-jetting an ink-jet ink onto a media substrate at a firing frequency from 12 kHz to 25 kHz, wherein the ink-jet ink includes a jettable vehicle, a plurality of non-acid-functionalized pigment solids dispersed in the jettable vehicle, and a styerene-maleimide copolymer dispersed in the jettable vehicle.
    Type: Grant
    Filed: July 14, 2004
    Date of Patent: April 29, 2008
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Marlene McGorrin, Zia Rehman, Paul Tyrell, Mary E Austin
  • Patent number: 7361692
    Abstract: A dispersant comprising a polyester chain obtainable by polymerising a hydroxy carboxylic acid or lactone thereof such as E-caprolactone with a cyclic alkylene carbonate such as 5,5-dimethyltrimethylene carbonate. The dispersant may be in the form of a phosphate ester where the polyester chain is reacted with a phosphating agent such as polyphosphoric acid or the polyester chain may be attached to a polyamine or polyimine such as polyethyleneimine.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: April 22, 2008
    Assignee: The Lubrizol Corporation
    Inventor: Dean Thetford
  • Patent number: 7361698
    Abstract: A water-based pigment ink contains a pigment, a hydrophilic dispersant, an aqueous medium, an alkali agent for solubilizing the hydrophilic dispersant in the aqueous medium, and a hydrophilic compound having at least one structural unit of “hydrophobic molecular chain-hydrophilic molecular chain-hydrophobic molecular chain” in a structure thereof. The water-based pigment ink is suited especially as an ink for ink-jet printers.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: April 22, 2008
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Michiei Nakamura, Naoyuki Sakai, Hiroyuki Shimanaka, Dai Watanabe, Kenji Ogawa, Yoshiyuki Zama, Hisao Okamoto, Atsushi Nogami, Kazuo Kanou, Tohru Hosoda
  • Patent number: 7361699
    Abstract: A water-based ink containing an aqueous dispersion of polymer particles of a water-insoluble polymer having an alkyl group of at least 20 carbon atoms in its side chain, and a hydrophobic dye. The water-based ink of the present invention can be suitably used as, for instance, an ink for inkjet recording, and the like.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: April 22, 2008
    Assignee: Kao Corporation
    Inventor: Shigemi Wakabayashi
  • Patent number: 7358301
    Abstract: A composition and method of associating stabilizer functionalities with latex particulates is provided. The composition can comprise a latex particulate configured for inclusion in an ink-jet ink to provide improved humidfastness of an image printed by the ink-jet ink, wherein the latex particulate has a molecular weight from 10,000 Mw to 10,000,000 Mw, and has a particle size from 10 nm to 2 ?m; and an image stabilizer configured for improving durability of the image, wherein the image stabilizer is bound to or otherwise associated with the latex particulate. The method can comprise the steps of coupling a polymerizable monomer with a stabilizing agent reactive with the polymerizable monomer, thereby forming a stabilizer precursor-containing monomer; polymerizing the stabilizer-containing monomer to form a latex particulate; and decoupling the stabilizing agent from the latex particulate.
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: April 15, 2008
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Kent Vincent, Sivapackia Ganapathiappan
  • Patent number: 7354476
    Abstract: An inkjet ink composition having a binder including an aqueous dispersion of polymer particles, the polymer comprising as polymerized units from 3 to 20 wt. % monoethylenically unsaturated acid monomer, based on polymer weight, and having a glass transition temperature (Tg) in the range of from ?40° C. to 120° C., and the polymer particles having a volume average particle diameter as measured by dynamic light scattering of at least 35 nanometers greater than the weight average particle diameter as measured by capillary hydrodynamic fractionation is provided. An inkjet ink composition including the inkjet ink binder is also provided.
    Type: Grant
    Filed: April 14, 2005
    Date of Patent: April 8, 2008
    Assignee: Lexmark International, Inc.
    Inventors: Bradley Leonard Beach, Alberto Carrillo, Stephen A. Crescimanno, Michael Paul Hallden-Abberton, Ann P. Holloway, Anna Marie Pearson
  • Patent number: 7354962
    Abstract: Encapsulated pigment for use in ink-jet ink formulations, improved ink-jet ink formulations using the encapsulated pigment, and methods for producing same. The pigment particles are pretreated with a polymer that is soluble in organic solvents, but substantially insoluble in water. The pigment particles are added to a solution of polymer/organic solvent, mixed to form a paste then collected after driving off the solvent. The encapsulated pigment can be used to prepare an ink-jet ink formulation by grinding it in a water carrier with a conventional polymer dispersant.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: April 8, 2008
    Assignee: Lexmark International, Inc.
    Inventors: Charles Edward Akers, Jr., Jing X. Sun
  • Patent number: 7354960
    Abstract: A water-based ink containing colored microparticles containing a dye and a polymer dispersed in water, wherein a total amount of a monomer remaining in the colored microparticles is less than or equal to 5000 ppm based on the total weight of the water-based ink.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: April 8, 2008
    Assignee: Konica Minolta Holdings Inc.
    Inventors: Hidetaka Ninomiya, Masaki Nakamura, Akihiko Takeda
  • Patent number: 7354961
    Abstract: The invention provides a process for producing a water dispersion for ink jet recording,which comprises the following steps 1 and 2: (Step 1) a step of obtaining a pigment treated with (a) a water-insoluble vinyl polymer particles by making a pigment and (a) a water-insoluble vinyl polymer particles present in an aqueous solvent and then removing the solvent; and (Step 2) a step of obtaining a water dispersion of a pigment-containing water-insoluble vinyl polymer particles by dispersing a mixture comprising the water-insoluble vinyl polymer particle (a)—treated pigment obtained in step 1, an organic solvent, (b) a water-insoluble vinyl polymer and water and then removing the organic solvent.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: April 8, 2008
    Assignee: Kao Corporation
    Inventors: Koji Azuma, Takehiro Tsutsumi, Ryuma Mizushima, Hirotaka Takeno, Toshiya Iwasaki