Invisible, Ballpoint, Or Typewriter Ink Compositions Or Process Of Preparing; Or Composition For Correction Ribbons Or Correction Fluids Or Process Of Preparing Patents (Class 523/161)
  • Patent number: 7686877
    Abstract: The invention relates to pigmented tinting concentrates comprising a) stabilized pigments; b) humectant compounds obtainable by effecting a Diels Alder reaction at a temperature of 150-260° C. between a polyunsaturated compound and a co-reactant having the formula R1XOC—CH?CH—COXR2 or CH2?CH—COXR3 or CH2?CH(CH3)—COXR3 wherein X is oxygen or —NH— and wherein at least one of R1 and R2 is a polyether moiety and any other of R1 and R2 is a polyether moiety or hydrogen and R3 is a polyether moiety.
    Type: Grant
    Filed: May 8, 2006
    Date of Patent: March 30, 2010
    Assignee: Ciba Corporation
    Inventors: Lothar Alexander Engelbrecht, Roedolph Van Bohemen, Frank Oliver Heinrich Pirrung
  • Patent number: 7683107
    Abstract: The present invention provides a method for the deposition of an ink jet printable composition, to a substrate comprising: depositing an ink composition on a substrate by ink jet printing; wherein said composition comprises: (a) functional material; (b) organic polymer comprising polyvinylpyrrolidone; dispersed in (c) dispersion vehicle selected from organic solvent, water, or mixtures thereof; and wherein the viscosity of said composition is between 5 mPa·s to 50 mPa·s at a temperature of 25 to 35° C.
    Type: Grant
    Filed: February 9, 2004
    Date of Patent: March 23, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Haixin Yang
  • Patent number: 7683108
    Abstract: Provided are ink jet ink excellent in dispersion stability and ejection stability and capable of forming images with fastness, abrasion resistance, color developability, and high density with little feathering; a microencapsulated pigment (MCP) providing the ink and a process of making the same; and an aqueous dispersion of the MCP. The MCP comprises pigment particles having a hydrophilic group on their surface (hydrophilized pigment particles) and coated with a polymer by emulsion polymerization. The process comprises emulsion polymerization in the presence of the hydrophilized pigment particles. The ink essentially contains the MCP and water.
    Type: Grant
    Filed: March 10, 2006
    Date of Patent: March 23, 2010
    Assignee: Seiko Epson Corporation
    Inventors: Hiroto Nakamura, Toshiyuki Miyabayashi, Masahiro Yatake, Hidehiko Komatsu
  • Publication number: 20100068642
    Abstract: The invention relates to a pigment preparation containing (a) 50-99 percent by weight of at least one pigment, (b) 1 to 50 percent by weight of an additive based on polyalkylene glycols, and (c) 0 to 10 percent by weight of an auxiliary agent from among the group comprising fillers, fire retardants, preservatives, light-stability agents, pigmentary and non-pigmentary dispersing agents, surfactants, antioxidants, foam inhibitors, resins, and antistatic agents, the percentages being in relation to the total weight of the pigment preparation. The additive that is based on polyalkylene glycols corresponds to formula Z?-[-(AO—)n1—B-T-X—Y]m—Z (1), wherein AO represents a C2-C10 alkyleneoxy unit, B represents a C2-C10 alkylene radical, and T represents —NR—, X represents one of the groups (formula), and Y represents a chemical bond or —NR3—.
    Type: Application
    Filed: September 28, 2007
    Publication date: March 18, 2010
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Carsten Plueg, Jesus Pitarch Lopez
  • Patent number: 7678845
    Abstract: A pigment dispersion includes a pigment and a block copolymer having ionic aromatic monomers. The pigment dispersions can be used for manufacturing inkjet inks and for the coating of colored layers. A process for preparing the pigment dispersion is also disclosed.
    Type: Grant
    Filed: January 26, 2006
    Date of Patent: March 16, 2010
    Assignee: Agfa Graphics NV
    Inventors: Frank Louwet, Geert Deroover, Bert Groenendaal, Markus Hartenstein, Joachim Storsberg
  • Patent number: 7678844
    Abstract: Compositions, systems, and methods of printing an ink-jet image are provided. The composition can include a liquid vehicle including water, a liquid vehicle having from 5 wt % to 35 wt % of total organic solvent content; from 1 wt % to 6 wt % of acid-functionalized pigment solids; and from 0.001 wt % to 6 wt % of styrene-maleic anhydride copolymer, said styrene-maleic anhydride copolymer having a weight average molecular weight from about 400 Mw to 15,000 Mw.
    Type: Grant
    Filed: March 22, 2004
    Date of Patent: March 16, 2010
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Zia Rehman, Paul Tyrell, Marlene McGorrin, Mary E Austin, Alexey S Kabalnov, Patricia A Wang
  • Patent number: 7674843
    Abstract: A pigment dispersion includes a pigment with at least one carboxylic acid group and a block copolymer including aromatic monomers having at least one carboxylic acid group or a salt thereof and aromatic monomers having at least one sulfonic acid group or a salt thereof. The pigment dispersions can be used for manufacturing inkjet inks and for the coating of colored layers.
    Type: Grant
    Filed: January 26, 2006
    Date of Patent: March 9, 2010
    Assignee: Agfa Graphics NV
    Inventors: Frank Louwet, Geert Deroover, Bert Groenendaal, Markus Hartenstein, Joachim Storsberg
  • Patent number: 7674841
    Abstract: An additive for a printing ink comprising a wax of either an ethylene homopolymer or ethylene.C3-20 ?-olefin copolymer each has an intrinsic viscosity, weight-average molecular weight/number-average molecular weight ratio, z-average molecular weight/weight-average molecular weight ratio, density, penetration hardness, and acid value in specific ranges; a solvent dispersion obtained by dispersing the wax; and a printing ink containing the wax.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: March 9, 2010
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masaki Yoda, Hideo Toyoda
  • Publication number: 20100050901
    Abstract: Various complex structures (nano/micro particles) are incorporated into a taggant providing different optical, magnetic and spectroscopic identification codes. The size and shape of the taggant can be tailored for many different types of products ranging from pharmaceuticals, auto and airplane parts all the way to apparel goods. By integrating a number of different nano/micro structures with various optical, electrical and magnetic properties, significant barriers are introduced to the counterfeiters attempting to replicate the taggant. The latter is easily incorporated to different types of products and is detected with various types of handheld readers/detectors depending on the complexity of the security level. The taggant may detect environmental materials or conditions.
    Type: Application
    Filed: August 20, 2009
    Publication date: March 4, 2010
    Inventors: Alexandru S. Biris, Enkeleda Dervishi
  • Patent number: 7671108
    Abstract: A printing ink including 100 parts by weight of an aluminum foil, 3 to 200 parts by weight of a binder polymer, and 600 to 2500 parts by weight of a solvent, wherein the aluminum foil contains aluminum foils with thicknesses of 0.03 ?m or less and foil surface areas of 1.5 ?m2 to 1500 ?m2 in an amount of 80% or more based on an accumulated foil surface area, and having a viscosity of 1000 to 3000 cps (measured at 20° C. with a BM-type rotational viscometer) to keep a clearance on a thin outline with a width of 0.15 mm, and a printed matter printed on a surface of a transparent substrate with the ink and viewed as a front face opposite the printed face thereof.
    Type: Grant
    Filed: August 8, 2006
    Date of Patent: March 2, 2010
    Assignee: Teikoku Printing Inks Mfg. Co., Ltd.
    Inventor: Naoto Takada
  • Patent number: 7666925
    Abstract: There is provided an ink composition for waterless lithographic printing of a seamless can for retort food which is excellent in retort resistance and does not have an adverse effect on environment, and a printing method using the same ink composition. This ink composition comprises (A) an alkyd resin containing 40 to 60% by mass of at least one kind of fatty acids and (B) an organic solvent which contains an aliphatic hydrocarbon solvent as main component and does not contain an aromatic hydrocarbon solvent substantially, wherein the number average number of carbon atoms of fatty acids in the alkyd resin (A) is from 10 to 14 and a solid content of the alkyd resin is from 30 to 70% by mass.
    Type: Grant
    Filed: April 11, 2006
    Date of Patent: February 23, 2010
    Assignee: Matsui Chemical Co., Ltd.
    Inventors: Takao Matsuyoshi, Shinichiro Baba, Kayo Yokoyama
  • Patent number: 7666924
    Abstract: A polymeric dispersant containing a vinyl polymer having a constitutional unit represented by the following formula 1: wherein R1 is a hydrogen atom or a methyl group, R2 and R4 may be the same or different and are each independently an alkylene group having from 2 to 18 carbon atoms or an arylene group having from 6 to 18 carbon atoms, R3 is an alkylene group having from 4 to 18 carbon atoms or an arylene group having from 6 to 18 carbon atoms, M1 and M2 may be the same or different and are each independently a hydrogen atom or a cation, k and m may be the same or different and are each independently a number from 0 to 20, and L is a number from 1 to 20, with the proviso that L is 2 or more when k is zero. The polymeric dispersant is used for the production of a water dispersion for ink-jet printing. The water dispersion for ink-jet printing is used for the production of a water-based ink for ink-jet printing.
    Type: Grant
    Filed: June 10, 2005
    Date of Patent: February 23, 2010
    Assignee: KAO Corporation
    Inventors: Nobuyuki Takizawa, Shigeki Nagashima, Takehiro Tsutsumi
  • Patent number: 7655174
    Abstract: A fully curable jettable composition having a viscosity less than 30 cps at a temperature within the range of 15-180° C., more preferably at a temperature of 15-100° C., e.g. 60-80° C. the composition comprising: (A) at least one low viscosity reactive resin selected from the group consisting of compounds containing an oxetane ring, cycloaliphatic epoxy resins, tetrahydrofurans, hexahydropyrans and mono-functional (meth)acrylates, said resin having a molecular weight of not greater than 300 Daltons, e.g. 250 Daltons or less, and a viscosity at a temperature in the said range of less than 30 cps, e.g.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: February 2, 2010
    Assignee: Huntsman Advanced Materials Americas LLC
    Inventors: Ranjana C Patel, Yong Zhao, Richard John Peace
  • Patent number: 7655708
    Abstract: An ink jet ink composition comprising an aqueous media and a pigment dispersion comprising a specific carbon black pigment and a polymeric dispersant wherein said polymeric dispersant is a copolymer comprising at least a hydrophobic methacrylate or acrylate monomer containing an aliphatic chain having greater than or equal to 12 carbons; and a hydrophilic methacrylic or acrylic acid monomer; wherein said copolymer comprises at least 10% by weight of the methacrylate or acrylate monomer and at least 5% by weight of the methacrylic or acrylic acid monomer; and wherein the copolymer comprises, in total, 20 to 95 weight % of hydrophobic monomer.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: February 2, 2010
    Assignee: Eastman Kodak Company
    Inventors: Gary L. House, Anne T. Wyand
  • Patent number: 7655707
    Abstract: Compositions and methods of printing an ink-jet image are provided. The composition can be an ink-jet ink comprising an aqueous liquid vehicle, polymer-encapsulated pigment solids dispersed in the liquid, a first copolymeric binder, and a second copolymeric binder. The polymer-encapsulated pigment solids can have a pigment core and a copolymeric shell, wherein the copolymeric shell includes multiple polymerized monomers. The first copolymeric binder can include at least one of the multiple polymerized monomers but which is different than the copolymeric shell. The second copolymeric binder can include at least one of the multiple polymerized monomers, but is also different than the copolymeric shell and the first copolymeric binder.
    Type: Grant
    Filed: December 2, 2005
    Date of Patent: February 2, 2010
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Zeying Ma
  • Patent number: 7649026
    Abstract: Radiation curable compositions, such as UV curable ink compositions, contain a polymeric dispersant, a curable material, and a nanoscale pigment particle composition including an organic monoazo laked pigment including at least one functional moiety, and a sterically bulky stabilizer compound including at least one functional group, wherein the functional moiety of the pigment associates non-covalently with the functional group of the stabilizer; and the presence of the associated stabilizer limits the extent of particle growth and aggregation, to afford nanoscale-sized pigment particles.
    Type: Grant
    Filed: November 1, 2007
    Date of Patent: January 19, 2010
    Assignee: Xerox Corporation
    Inventors: C. Geoffrey Allen, Rina Carlini, Sandra J. Gardner
  • Patent number: 7649030
    Abstract: The present invention is drawn toward ink-jet inks, coating compositions, methods of printing durable images, and fluoro-diol-modified polyurethanes. The ink-jet ink can comprise a liquid vehicle, a colorant, and a fluoro-diol-modified polyurethane binder having a weight average molecular weight from about 3,000 Mw to about 180,000 Mw, wherein each side chain of the binder has no more than 15 fluoro substitutions.
    Type: Grant
    Filed: January 25, 2007
    Date of Patent: January 19, 2010
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Kai-Kong Iu
  • Patent number: 7638561
    Abstract: An aqueous inkjet ink composition suitable for printing on a hydrophobic surface such as a vinyl surface including an aqueous vehicle, a self-dispersed pigment, a silicone-containing surfactant and an aqueous emulsion polymer having a glass transition temperature (Tg) of from ?40° C. to 150° C. Also provided is a method for printing an image on a hydrophobic substrate.
    Type: Grant
    Filed: June 8, 2005
    Date of Patent: December 29, 2009
    Assignee: Rohm and Haas Company
    Inventors: Zhenwen Fu, Hailan Guo, Michael Hallden-Abberton, Himal H. Ray
  • Patent number: 7638562
    Abstract: Ink receptive particles for receiving ink, including: particles P including hydrophilic polymer particles having a ratio of hydrophilic monomer(s) to the total monomer components thereof of from about 10 mol % to about 90 mol %; and hydrophobic polymer particles, attached to at least a part of a surface of the particles P and having a ratio of hydrophilic monomer(s) to the total monomer components thereof of from about 0 mol % to about 10 mol %.
    Type: Grant
    Filed: May 24, 2007
    Date of Patent: December 29, 2009
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Takatsugu Doi, Masaya Ikuno, Ken Hashimoto
  • Patent number: 7635727
    Abstract: Disclosed are composite transparencies and methods for their production. The colored composite transparencies include a surface at least partially coated with a transparent tinted coating deposited from a coating composition comprising polymer-enclosed color-imparting particles.
    Type: Grant
    Filed: April 6, 2006
    Date of Patent: December 22, 2009
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Dennis L. Faler, Cheryl E. Belli, Stephen G. McQuown, John A. Winter, Deborah E. Hayes, James P. Colton, Shan Cheng, Noel R. Vanier
  • Patent number: 7629427
    Abstract: The invention provides a block polymer compound enabling satisfactory dispersion of a colorant in a solvent, and an ink composition containing such block polymer compound. The block polymer compound of the invention is a block polymer compound having at least three block segments, comprising block segments A, B and C arranged in succession, wherein the block segment C is most solvent attractive while the block segment A is most solvent repulsive, and at least either one of the block segments includes an ionic group or an acidic group.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: December 8, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koichi Sato, Ikuo Nakazawa, Sakae Suda, Masayuki Ikegami, Keiichiro Tsubaki
  • Patent number: 7625956
    Abstract: Disclosed is a phase change ink comprising a colorant, an initiator, and an ink vehicle, said ink vehicle comprising (a) at least one radically curable monomer compound, and (b) a compound of the formula wherein R1 is an alkylene, arylalkylene, or alkylarylene group, R2 and R2? each, independently of the other, are alkylene, arylene, arylalkylene, or alkylarylene groups, R3 and R3? each, independently of the other, are either (a) photoinitiating groups, or (b) groups which are alkyl, aryl, arylalkyl, or alkylaryl groups, provided that at least one of R3 and R3? is a photoinitiating group, and X and X? each, independently of the other, is an oxygen atom or a group of the formula —NR4—, wherein R4 is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group.
    Type: Grant
    Filed: November 30, 2005
    Date of Patent: December 1, 2009
    Assignee: Xerox Corporation
    Inventors: Peter G. Odell, Eniko Toma, Jennifer L. Belelie
  • Patent number: 7625958
    Abstract: Provided are a water dispersion for ink-jet printing, wherein it is a water dispersion of water-insoluble graft polymer particles containing a colorant; the above graft polymer contains a principal chain having a constitutional unit derived from a vinyl base monomer and a side chain which is derived from a macromer containing an aromatic ring and having a polymerizable functional group at one end; both of the Log P values of the above principal chain and the above side chain are positive; and a difference between both falls in a specific range, and a water-based ink containing the same. The above water-based ink is excellent in a discharge stability, a storage stability, a heat stability and a water resistance.
    Type: Grant
    Filed: July 28, 2005
    Date of Patent: December 1, 2009
    Assignee: KAO Corporation
    Inventors: Nobushige Tanaka, Koji Azuma, Takehiro Tsutsumi
  • Patent number: 7625959
    Abstract: A curable jettable liquid for manufacturing a flexographic printing plate comprising at least one photo-initiator, at least one monofunctional monomer, at least 5 wt % of a polyfunctional monomer or oligomer and at least 5 wt % of a plasticizer both based on the total weight of the curable jettable liquid capable of realizing a layer after curing having an elongation at break of at least 5%, a storage modulus E? smaller than 200 MPa at 30 Hz and a volumetric shrinkage smaller than 10%.
    Type: Grant
    Filed: August 25, 2005
    Date of Patent: December 1, 2009
    Assignee: Agfa Graphics, N.V.
    Inventors: Eddie Daems, Luc Leenders
  • Patent number: 7615583
    Abstract: A radiation-curable ink including, (a) a colorant dispersion containing a pigment and a diluent, the pigment being present in an amount of 20 to 95 weight % based on the total weight of the colorant dispersion; (b) polymerizable compound; and (c) a polymerization initiator, wherein the radiation-curable ink has a viscosity of 6 to 500 mPa·s measured at 25° C. and comprises water in an amount of not more than 2.5 weight % based on the total weight of the radiation-curable ink measured with Karl Fisher method.
    Type: Grant
    Filed: March 9, 2006
    Date of Patent: November 10, 2009
    Assignee: Konica Corporation
    Inventor: Atsushi Nakajima
  • Patent number: 7615110
    Abstract: An intaglio printing ink, curing by free radical acrylate chemistry, which does not fluoresce in at least the visible region under ultraviolet light is prepared by using an acylphosphine oxide as the photoinitiator.
    Type: Grant
    Filed: March 30, 2005
    Date of Patent: November 10, 2009
    Assignee: Sun Chemical Corporation
    Inventors: Michael W. Leonard, John A. Dyer, James R. Tucker, Shaun L. Herlihy
  • Patent number: 7612124
    Abstract: Disclosed are ink compositions comprising a liquid vehicle and a colorant, wherein the colorant comprises polymer-enclosed color-imparting particles, wherein the particles are enclosed by a friable polymer. Also disclosed are methods for making an ink composition and methods for improving the transparency of an ink composition comprising a pigment colorant.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: November 3, 2009
    Assignee: PPG Industries Ohio, Inc.
    Inventors: W. David Polk, Dennis L. Faler, Noel R. Vanier, Eldon L. Decker
  • Patent number: 7612125
    Abstract: A pigmented ink for printing on untreated vinyl foils or substrates coated with vinyl by means of piezoelectric printing systems which include at least one heating device, wherein the ink is composed of a liquid carrier substance, water insoluble coloring agents, polymeric binding agents, drying decelerators, as well as additional additives, wherein the liquid carrier substance is composed of water and drying decelerators which are mixable in water. The liquid carrier substance has a content of at least 80% by weight water and the content of drying decelerators is composed of at least butyldiglycol and 1-metaxipropanol-2, and the ink has a pH-value of greater than 8.5.
    Type: Grant
    Filed: March 11, 2008
    Date of Patent: November 3, 2009
    Assignee: J.S. Staedtler GmbH & Co.
    Inventors: Anke Müller, Stefan Engel
  • Patent number: 7608117
    Abstract: The present invention relates to a method of producing a granular formulation of colorants soluble in plastics, which method comprises suspending in water a filter cake obtained from preparation of the colorant, adding thereto from 0.1 to 5.0% by weight, calculated with respect to the weight of colorant, of a polyvinylpyrrolidone and, where appropriate, further adjuvants, and then drying the aqueous suspension to form granules, to the granular formulations obtainable according to that method, and to the use thereof in the production of colored plastics or colored polymeric particles.
    Type: Grant
    Filed: May 8, 2007
    Date of Patent: October 27, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Paolo Balliello, Walter Dümler
  • Patent number: 7605192
    Abstract: The present invention relates to an aqueous ink, particularly an aqueous ink suitable for ink jet recording. The ink is an aqueous ink comprising a modified pigment having organic groups chemically attached to the surface of a particle of the pigment and an aqueous medium which is a dispersant of the pigment, wherein the above-described organic group includes a reaction product of a functional group chemically attached to the surface of the pigment directly or via another atomic group with a copolymer of an ionic monomer and a hydrophobic monomer.
    Type: Grant
    Filed: December 9, 2005
    Date of Patent: October 20, 2009
    Assignees: Canon Kabushiki Kaisha, Cabot Corporation
    Inventors: Mikio Sanada, Yoshihisa Takizawa, Katsuhiko Takahashi, Masashi Ogasawara, Yoichi Takada, Tomonari Watanabe, Yui Tokuda
  • Patent number: 7604694
    Abstract: A marking liquid which contains a polymer dispersion with particles which are colored with marking agent, optionally further dyes and marking agents, one or more salts of a polyvalent, in particular bi- or trivalent cation, water and optionally moisture retaining agents and further usual additives, wherein the polymer forming the polymer particles is selected from the group of polyesters, polyester amides, polymers and copolymers based on acrylate or methacrylate with a proportion of free carboxylic acid groups of less than 10% by weight, melamine-formaldehyde-sulfonamide resins and mixtures thereof.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: October 20, 2009
    Assignee: Schwan-STABILO Schwanhausser GmbH & Co. KG
    Inventors: Hanns Dieter Denninger, Thomas Spengler, Ivan Horvat, Klaus Dieter Schröder
  • Publication number: 20090257816
    Abstract: Disclosed herein is a water-based erasable ink for use in a writing instrument. The ink comprises platy-like pigment particles, film formers and an aqueous vehicle. Also disclosed are writing instruments using such inks as well as comprising a reservoir containing a water based erasable ink having a non-shear-thinning composition and a porous fiber nib in fluid communication with this reservoir. Related methods of forming an erasable marking are also disclosed.
    Type: Application
    Filed: April 15, 2008
    Publication date: October 15, 2009
    Inventors: Pawel CZUBAROW, Joshua Hart POLLACK, Jeremy Matthew SCHWARTZ
  • Patent number: 7598332
    Abstract: There is provided a polymer compound including a repetitive unit structure represented by the following general formula (2): General formula (2): (where X? represents a polyalkenyl group; A represents a linear or branched alkylene group having a carbon atom number of 1 to 15, which may be substituted; m represents an integer of 0 to 30; B represents a single bond or an alkylene group which may be substituted; D represents an aromatic ring structure which may be substituted; n represents an integer of 0 to 10; and R represents a hydrogen atom, an alkyl group which may be substituted, or an aromatic ring structure which may be substituted). The polymer compound is suitable for improving dispersibility of a coloring material or solid material in an ink composition or toner composition.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: October 6, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masayuki Ikegami, Koichi Sato, Ikuo Nakazawa, Sakae Suda, Keiichiro Tsubaki, Ryuji Higashi, Keiko Yamagishi
  • Patent number: 7598301
    Abstract: There is provided a water-based ink that can exhibit high gloss on gloss paper and has excellent fixation while maintaining ink reliability such as recovery from clogging, continuous printing stability, and ink storage stability. The water-based ink comprises at least yellow pigment-containing polymer particles A and pigment-free polymer particles B. The polymer particles A are formed of a water insoluble vinyl polymer produced by polymerizing a specific monomer composition A, and the polymer particles B are formed of a water insoluble vinyl polymer produced by polymerizing a specific monomer composition B and has a minimum film forming temperature of 20° C. or above. The polymer particles B have an average particle diameter of 30 to 60 nm.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: October 6, 2009
    Assignee: Seiko Epson Corporation
    Inventors: Masahiro Hanmura, Miharu Kanaya
  • Patent number: 7594722
    Abstract: The image forming apparatus includes: a treatment liquid application device which applies treatment liquid onto a recording medium, the treatment liquid containing cationic polymer and a coloring material aggregating agent; an ink liquid ejection device which ejects droplets of ink liquid toward the recording medium, the ink liquid having anionic properties and containing a solvent and a coloring material which aggregates due to reaction with the coloring material aggregating agent; and a solvent absorbing device which absorbs the solvent on the recording medium in a state where an aggregate of the coloring material and the solvent are separated after a first reaction in which a film is formed at a liquid interface between the treatment and ink liquids on the recording medium by mixing treatment and ink liquids and a second reaction in which the aggregate of the coloring material in the ink liquid is formed after film formation.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: September 29, 2009
    Assignee: Fujifilm Corporation
    Inventors: Tetsuzo Kadomatsu, Masaaki Konno
  • Patent number: 7592378
    Abstract: The present invention pertains to an aqueous inkjet ink made from certain aqueous titanium dioxide slurries, and an associated inkjet ink set for inkjet printing. The invention also pertains to a method of inkjet printing with the ink and ink set. The use of the specific titanium dioxide slurries described herein result in inkjet inks having improved stability and better anti-settling performance with less pigment agglomeration and flocculation over time.
    Type: Grant
    Filed: January 28, 2008
    Date of Patent: September 22, 2009
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Tyau-Jeen Lin, Patrick F. McIntyre, Hamdy A. Elwakil
  • Patent number: 7582687
    Abstract: Disclosed are colorant compounds of the formula wherein R, R1, R2, R3, and R4 each, independently of the others, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and wherein R, R1, R2, R3, and R4 each can be joined to a phenyl moiety to form a ring, each R?a, R?b, and R?c, independently of the others, is a halogen atom, an alkyl group, an alkoxy group, a nitrile group, a nitro group, an amide group, or a sulfonamide group, z1, z2, and z3 each, independently of the others, is an integer of 0, 1, 2, 3, or 4, n is an integer representing the number of carbon atoms in each repeat alkylene oxide unit, x is an integer representing the number of repeat alkylene oxide units, D is an anion, and g is the charge on the anion, wherein said colorant has no more than one —OH, —SH, or primary or secondary amino group per molecule.
    Type: Grant
    Filed: July 31, 2006
    Date of Patent: September 1, 2009
    Assignee: Xerox Corporation
    Inventors: Jeffery H. Banning, Donald R. Titterington, Clifford R. King
  • Patent number: 7579390
    Abstract: There is proposed an inkjet ink composition comprising a pigment component to which a resin having a basic terminal is adsorbed, a photo-acid generating agent containing an onium salt, and at least one kind of solvent which can be polymerized under the presence of an acid. The content of multivalent salt included in the onium salt is not more than 20% by weight based on a total weight of onium salt, and the content of the pigment component is confined within the range of 3 to 41% by weight based on the ink composition.
    Type: Grant
    Filed: March 8, 2005
    Date of Patent: August 25, 2009
    Assignee: Toshiba Tec Kabushiki Kaisha
    Inventors: Toru Ushirogouchi, Kazuhiko Ohtsu, Mitsuru Ishibashi, Ryozo Akiyama, Masahi Hiroki
  • Patent number: 7576146
    Abstract: Polymeric colored dispersant having the structure A-(B—X)n, where A is an organic chromophore; B is a covalently bonded linking moiety; X is a branched or linear C50-C200 polymeric covalently linked hydrocarbon, and n is an integer from 1 to 4, and low viscosity colorant dispersions containing same having a relative interfacial tension drop of less than about 1.5.
    Type: Grant
    Filed: December 5, 2003
    Date of Patent: August 18, 2009
    Assignee: Sun Chemical Corporation
    Inventors: Gregory T. Huber, Tatiana N. Romanova, Russel J. Schwartz, Terence R. Chamberlain
  • Patent number: 7572845
    Abstract: Disclosed are colorant compounds of the formula wherein R, R1, R2, R3, and R4 each, independently of the others, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and wherein R, R1, R2, R3, and R4 each can be joined to a phenyl moiety to form a ring, each R?a, R?b, and R?c, independently of the others, is a halogen atom, an alkyl group, an alkoxy group, a nitrile group, a nitro group, an amide group, or a sulfonamide group, z1, z2, and z3 each, independently of the others, is an integer of 0, 1, 2, 3, or 4, n is an integer representing the number of carbon atoms in each repeat alkylene oxide unit, x is an integer representing the number of repeat alkylene oxide units, D is an anion, and g is the charge on the anion, wherein said colorant has no more than one —OH, —SH, or primary or secondary amino group per molecule.
    Type: Grant
    Filed: July 31, 2006
    Date of Patent: August 11, 2009
    Assignee: Xerox Corporation
    Inventors: Jeffery H. Banning, Donald R. Titterington, Clifford R. King
  • Patent number: 7572844
    Abstract: The present invention relates to a stimuli-responsive composition that comprises a polymer, a solvent and a substance having a predetermined function. One embodiment of the present invention is a composition comprising a block polymer, a solvent and a substance having a predetermined function. The present invention also relates to an ink composition containing the composition, an image-forming method and an image-forming apparatus using the composition, and a recording medium applying the composition. Further, the present invention relates to an ABC type block polymer compound wherein the polymer is an ABC type triblock polymer, and wherein at least one of the blocks in the triblock polymer changes in nature from solvophilic to solvophobic or from solvophobic to solvophilic in response to stimuli, and more preferably, the A component, then the B component, and finally the C component respond to the stimuli.
    Type: Grant
    Filed: March 1, 2006
    Date of Patent: August 11, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koichi Sato, Ikuo Nakazawa, Sakae Suda, Masayuki Ikegami, Sadahito Aoshima, Shinji Sugihara
  • Patent number: 7569623
    Abstract: The present invention provides an ink composition comprising fine particles having a polymerizable functional group.
    Type: Grant
    Filed: July 15, 2005
    Date of Patent: August 4, 2009
    Assignee: Seiko Epson Corporation
    Inventors: Takashi Oyanagi, Keitaro Nakano
  • Publication number: 20090191420
    Abstract: Composition, which comprises a latent activator and a colour former, a process for the preparation of these compositions, substrates coated with these compositions and a process for their preparation, a process for preparing marked substrates using these compositions and marked substrates obtainable by the latter process.
    Type: Application
    Filed: January 17, 2007
    Publication date: July 30, 2009
    Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC.
    Inventors: Karen O'Donoghue, Jonathan Campbell, Ian Street
  • Patent number: 7566751
    Abstract: Polyvinyl acetals with low solution viscosities and maximum Newtonian flow behavior contain sulphonate-functional vinyl ether or sulphonate-functional allyl ether units in addition to conventional vinyl ester, vinyl alcohol, and vinyl acetal units.
    Type: Grant
    Filed: June 23, 2005
    Date of Patent: July 28, 2009
    Assignee: Kuraray Europe GmbH
    Inventor: Andreas Lumpp
  • Patent number: 7563835
    Abstract: A method of preparing a universal base composition disclosed which consists of milling a pigment in a resin that is soluble in both water and organic solvent and wherein the resin contains both hydrophobic and hydrophilic monomers such that the total weight of the hydrophobic and hydrophilic monomers is at least about 20% of the total weight of the resin and the weight ratio of hydrophobic monomers to hydrophilic monomers is from about ? to about 5.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: July 21, 2009
    Assignee: Sun Chemical Corporation
    Inventors: Juanita Parris, Ning Wu, Jeannette Simoni-Truncellito, Robert Catena, Jitu Modi, William P. Keaveney, Robert Auerbach
  • Patent number: 7563853
    Abstract: A polymer compound of a block polymer containing at least three block segments each having a repeating unit structure comprising a polyalkenyl ether structure comprises a repeating unit structure having a silyl ether side chain represented by the formula (1) in at least one block segment of the block polymer and a repeating unit structure containing one kind or two or more kinds of either a side chain having an ionic functional group represented by the formula (2) or an ester-type functional group obtained by esterifying the ionic functional group in at least one other block segment.
    Type: Grant
    Filed: May 2, 2005
    Date of Patent: July 21, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keiichiro Tsubaki, Masayuki Ikegami, Koichi Sato, Ikuo Nakazawa, Ryuji Higashi, Sakae Suda, Keiko Yamagishi
  • Patent number: 7563834
    Abstract: Sublimable pad-printing ink and a method of marking an object with the ink, wherein the ink includes a hardening transparent pad-printing ink base and at least one sublimable colored pigment. The hardening transparent pad-printing ink base resists a sublimation temperature of the at least one sublimable colored pigment. The method includes pad-printing the object with a marking that includes a monochrome or polychrome marking composition having at least one monocolor pigmented component including fine particles of at least one sublimable monocolor colored pigment and heating at least one of the object and the pad-printed marking composition.
    Type: Grant
    Filed: October 7, 2005
    Date of Patent: July 21, 2009
    Assignee: Gaming Partners International
    Inventor: Michel Tollhupp
  • Patent number: 7553886
    Abstract: The present invention is drawn to cross-linked latex particulates. The latex particulates include a plurality of polymerized monomers and cross-linking agent. The cross-linking agents are of particular structures and include at least one Cl or Br. From about 0.05 wt % to about 15 wt % of the latex particulate is cross-linked with the cross-linking agent. Such latex particulates can be used in latex suspensions and inks.
    Type: Grant
    Filed: April 23, 2007
    Date of Patent: June 30, 2009
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Sivapackia Ganapathiappan
  • Patent number: 7553883
    Abstract: The invention provides an aqueous pigment ink composition that ensures excellent recording characteristics on any type of recording mediums. An aqueous pigment ink composition of the invention includes a pigment, a water-dispersible polymer, water, and a water-soluble organic solvent, where the pigment is dispersed as primary particles having an average primary particle diameter of not greater than 50 nm and as secondary particles having a ratio of an average secondary particle diameter to the average primary particle diameter in a range of 1 to 10, and the water-dispersible polymer has a minimum glass transition temperature of lower than 100° C. Using this polymer ensures good dispersion stability and favorable glossiness on a glossy medium.
    Type: Grant
    Filed: May 16, 2005
    Date of Patent: June 30, 2009
    Assignee: Seiko Epson Corporation
    Inventor: Masahiro Yatake
  • Patent number: 7550518
    Abstract: A three-dimensional printing materials system and method can produce both appearance models and small numbers of functional parts in an office environment. The method can include building cross-sectional portions of a three-dimensional article, and assembling the individual cross-sectional areas in a layer-wise fashion to form a final article. The individual cross-sectional areas can be built by using an ink-jet printhead to deliver an aqueous solvent or binder to an adhesive particulate mixture, causing the particles of the mixture to adhere together, and to previous cross-sectional areas. The binder can include at least one of nonaqueous organic monomeric compound, anionically ionizable polymer, cationic polymer, polymer, waterborne colloid, or inorganic solute.
    Type: Grant
    Filed: February 28, 2005
    Date of Patent: June 23, 2009
    Assignee: Z Corporation
    Inventors: James F. Bredt, Sarah L. Clark, Evert F. Uy, Matthew J. DiCologero, Timothy Anderson, Michael Tarkanian, Derek X. Williams