Slurried, Dispersed, Or Suspended Ingredient Admixed With Previously Formed Latex, Aqueous Dispersion Or Aqueous Suspension Of A Solid Polymer Patents (Class 523/334)
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Patent number: 5049594Abstract: There is disclosed a process for preparing an organic polymer composition which includes an inorganic filler, which comprises: (i) treating an inorganic filler by adding to a particulate white inorganic material a natural or synthetic latex composition which comprises a suspension of polymer particles in water wherein the latex solids are selected from the group consisting of acrylic copolymers and vinyl acetate copolymers, and dewatering and drying the resultant mixture, the amount of the natural or synthetic latex composition added being such as to provide from 1% to 10% by weight of latex solids based on the weight of dry inorganic material; and (ii) combining the treated inorganic filler with an organic polymer. Also disclosed is an organic polymeric composition comprising an organic polymer and an inorganic filler.Type: GrantFiled: January 17, 1990Date of Patent: September 17, 1991Assignee: ECC International LimitedInventor: David G. Jeffs
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Patent number: 5028482Abstract: A process for preparing an inorganic filler comprises admixing a particulate inorganic material with a natural or synthetic latex composition and an aqueous suspension of fine carbon black, and dewatering and drying the resultant mixture, the amount of the natural or synthetic latex composition added being such as to provide a coating on the inorganic mineral of from 1% to 10% by weight of latex solids based on the weight of dry inorganic material.Type: GrantFiled: September 6, 1989Date of Patent: July 2, 1991Assignee: ECC International LimitedInventor: David G. Jeffs
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Patent number: 5025044Abstract: Blends of asphalt emulsions or melts and aqueous elastomeric latices are prepared using a screw type extruder adapted to provide sufficient back pressure within the screw flights of the extruder to express the water from the blend through a vent provided in the extruder.Type: GrantFiled: September 25, 1990Date of Patent: June 18, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventors: Lance A. Christell, Fred Y. Kafka
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Patent number: 5025063Abstract: Heat cured, thermoset protective surface coating films applied to a substrate are produced preferably by a dual cure of a polymeric ionomeric binder comprising zinc modified carboxyl functional epoxy-ester polymers. The epoxy-ester polymer contains both carboxy and hydroxyl functionality and coreacts with a zinc salt selected from a zinc carbonate or an organic zinc salt having a pKa above about 3.0. Upon heat curing, the carboxyl and hydroxyl groups crosslink while the zinc forms a zinc cluster to produce a thermoset film.Type: GrantFiled: August 23, 1989Date of Patent: June 18, 1991Assignee: The Glidden CompanyInventors: Gary P. Craun, Barbara L. Kunz
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Patent number: 5017630Abstract: High amounts of silicon dioxide are readily incorporated into an emulsion polymerized elastomer by mixing an aqueous dispersion of silicon dioxide with a latex of the emulsion polymer and subsequently spray drying the mixture. Free flowing, fine-size (e.g., less than 500 micrometers) particles are produced with generally complete incorporation of silicon dioxide. The presence of the silicon dioxide permits rubbers with low gel and/or low Mooney viscosity to be spray dried whereas previously this could not be accomplished. Compared to conventional means of adding a silica to a bale rubber, the above powdered masterbatch gives shorter mixing times with lower power consumption with improved physical properties, such as tensile strength.Type: GrantFiled: August 17, 1989Date of Patent: May 21, 1991Assignee: Zeon Chemicals USA, Inc.Inventors: Charles C. Raines, Philip H. Starmer
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Patent number: 5008306Abstract: Fiber reinforced thermoplastics sheet is produced by a wet method from (a) an aqueous dispersion of reinforcing fibers an dispersing agent; and (b) an aqueous dispersion of thermoplastics polymer powder and an ionic polymer additive of opposite charge to the fiber dispersion. The dispersions are mixed, a high molecular weight ionic polymer flocculating agent is added, of charge opposite to that of the mixture, and the resulting suspension is drained and dried to form the sheet.Type: GrantFiled: July 22, 1988Date of Patent: April 16, 1991Assignee: Exxon Chemical Patents Inc.Inventor: Michel Goguelin
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Patent number: 4997864Abstract: A process for the preparation of composite particle dispersons is disclosed. The composite particles have a core particle 1 surrounded by a second material 2. Normally a core shell particle will be formed and the second material which forms the shell will be a polymer material.The composite particles are formed by mixing a dispersion of polymer particles with pre-formed core material particles. The polymer particles are stabilized relative to one another, and the core material particles are destabilized in the dispersion so that they are able to make contact with the surfaces of the polymer particles. The process takes place at a temperature above the operative glass transition temperature of the polymer, and in the process the polymer spreads over the surface of the core particle so that the core particle is encapsulated.Type: GrantFiled: January 24, 1989Date of Patent: March 5, 1991Assignee: Imperial Chemical Industries PLCInventor: Julian A. Waters
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Patent number: 4990590Abstract: An anionic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde followed by the reaction of such products with acrylic acid, and the uses of the emulsifier in anionic bituminous emulsions and paving slurry seal mixtures are disclosed.Type: GrantFiled: November 27, 1989Date of Patent: February 5, 1991Assignee: Westvaco CorporationInventor: Peter Schilling
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Patent number: 4990592Abstract: An anionic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde followed by the reaction of such products with acrylic acid, and the uses of the emulsifier in anionic bituminous emulsions and paving slurry seal mixtures are disclosed.Type: GrantFiled: November 27, 1989Date of Patent: February 5, 1991Assignee: Westvaco CorporationInventor: Peter Schilling
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Patent number: 4990591Abstract: An anionic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde followed by the reaction of such products with acrylic acid, and the uses of the emulsifier in anionic bituminous emulsions and paving slurry seal mixtures are disclosed.Type: GrantFiled: April 7, 1989Date of Patent: February 5, 1991Assignee: Westvaco CorporationInventor: Peter Schilling
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Patent number: 4968350Abstract: The process for preparing a redispersible powder of a water-insoluble polymer by a producing a gel of a water-soluble macromolecular substance and water. Then a second solution is prepared by mixing a single organic solvent which is partially miscible with water and a water-insoluble polymer. These two solutions are emulsified and then water is added to diffuse the solvent to form microparticles in suspension. The particles are collected by a conventional method.Type: GrantFiled: December 9, 1988Date of Patent: November 6, 1990Inventors: Christian Bindschaedler, Robert Gurny, Eric Doelker
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Patent number: 4963600Abstract: A method for minimizing the inherent yellowness of any kind of clear coating is disclosed. This method involves the addition of very small amounts of blue pigments or dyes to the clear coating so that chroma neutralization occurs. The chroma neutralization results in a clear coat which is crystal clear in appearance.Type: GrantFiled: December 19, 1988Date of Patent: October 16, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Joseph F. Coughlin
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Patent number: 4960805Abstract: In production of a casein-type artificial key material for keyboard musical instruments, fine grains of an elastomer such as polyurethane elastomer are added to a mixture to be kneaded together so that, in the structure of the product, islanded elastomer is uniformly dispersed in the matrix of casein. Inbred brittleness of casein is much improved by inclusion of the elastomer and strong bond between casein and the elastomer well removes the danger of interface separation.Type: GrantFiled: December 28, 1988Date of Patent: October 2, 1990Assignee: Yamaha CorporationInventor: Yutaka Oshima
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Patent number: 4954553Abstract: Waterborne, neutralized, carboxyl-bearing phenoxy resin with which is blended a relatively soft, neutral, non-carboxyl-bearing modifier resin. A coalescing solvent is preferably included in the aqueous blend.Type: GrantFiled: September 30, 1988Date of Patent: September 4, 1990Assignee: Union Carbide Chemicals and Plastics Company Inc.Inventors: Robert N. Johnson, Ismael Colon
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Patent number: 4918118Abstract: A process for improving properties of a synthetic resin powder by subjecting a latex of a graft-copolymer whose back bone is a rubber to coagulation, and adding a lubricant to the graft-copolymer in an amount of 0.01 to 10 parts by weight based on 100 parts by weight of said graft-copolymer, and then removing water. The bulk specific gravity of a synthetic resin powder produced is large, the flowability and blocking resistance are remarkably improved in comparison with known methods and blocking during storage is prevented. Lines for transporting the powder do not become packed with the resin powder. It is possible to automatically weigh the resin powder, and the powder does not exhibit a tendency to increase in volume during mass transport.Type: GrantFiled: April 11, 1988Date of Patent: April 17, 1990Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Atsushi Kawakatsu, Ryuichi Takagi
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Patent number: 4912151Abstract: A method for manufacturing pourable pulverulent rubber-filler mixtures starting from rubber solutions is disclosed. In this method, the filler is dispersed in an organic solvent and then mixed with a rubber solution to obtain a stable rubber-containing filler dispersion. The dispersion is then introduced into hot water containing a dispersed filler and subjected to high shear forces, causing the organic solvent to simultaneously be largely distilled off. After the rubber-containing filler dispersion has been completely added, an aqueous filler dispersion is added, water is removed from the precipitated rubber-filler mixture, and the product mixture is dried under constant agitation.Type: GrantFiled: January 30, 1989Date of Patent: March 27, 1990Assignee: Huels AktiengesellschaftInventor: Ralf Tappe
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Patent number: 4910236Abstract: An ink is produced without flushing by forming both an emulsion of a selected organic liquid and water and an aqueous suspension of a pigment. The emulsion and the pigment are then mixed together, whereby the pigment is phase-transferred from the aqueous phase to the non-aqueous phase, and whereby a mixture is formed. The mixture is concentrated (e.g. via filtration) and added to an ink mixing tank where the remaining water is removed by evaporation and wherein the remaining ingredients are added so that the ink is produced.Type: GrantFiled: January 19, 1988Date of Patent: March 20, 1990Assignee: BASF CorporationInventors: Thomas E. Foye, Edward K. Sasamoto, Reinhard J. Sappok
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Patent number: 4883829Abstract: Process for producing pourable powdered rubber with filler content independent of particle size. By adjusting to a pH in the range of 3.7 to 6.5 after the mixing of rubber latices or aqueous emulsions of rubber solutions with filler suspensions containing precipitant, and by using 0.1 to 2.0 phr of a selected metal salt, powdered rubbers can be produced with filler content independent of particle size.Type: GrantFiled: April 22, 1988Date of Patent: November 28, 1989Assignee: Huls AktiengesellschaftInventors: Hans-Juergen Smigerski, Uwe Ernst
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Patent number: 4835196Abstract: A process for the production of a free flowing filled elastomer powder by combining an elastomer latex with a filler suspension is disclosed wherein the combining of elastomer latex and filler suspension takes place in the presence of about 0.1-15 parts by weight--calculated per 100 parts by weight of elastomer solid in the elastomer latex--of a high-molecular-weight amine with quaternary nitrogen functions and with an average molecular weight of about 10.sup.4 to 10.sup.8.Type: GrantFiled: March 2, 1987Date of Patent: May 30, 1989Assignee: Huels AktiengesellschaftInventors: Michael Mueller, Walter Kleinert
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Patent number: 4800103Abstract: A process for preparing an inorganic filler comprising treating a particulate inorganic material with a natural or synthetic latex composition and dewatering and drying the resultant mixture. The surface-treated inorganic filler can be used with advantage in a polymeric resin composition.Type: GrantFiled: August 29, 1986Date of Patent: January 24, 1989Assignee: ECC International LimitedInventor: David G. Jeffs
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Patent number: 4798854Abstract: Process for the production of a composite material based on a polymer matrix comprising homogeneously dispersed therein an organic and/or inorganic filler, said process consisting in mixing together the aqueous dispersions of the single components, in which the dispersed particles of the dispersion have a surface charge of the same sign and a "zeta potential" between 10 and 100mV (in absolute value) and wherein the ratio (in absolute value) between the "zeta potentials" of the particles of each dispersion is between 0.2 and 5.Type: GrantFiled: February 26, 1987Date of Patent: January 17, 1989Assignee: Ausimont S.p.A.Inventors: Mario Visca, Giancarlo Boero, Daria Lenti
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Patent number: 4788231Abstract: A process for preparing a pourable powdered rubber containing filler, comprising preparing a blend by mixing a portion of said filler to be incorporated in said rubber product with 0.1 to 6.5 phr of a water-soluble salt of a Group IIa, IIb, IIIa or VIII metal of the Periodic Table and a rubber latex or aqueous emulsion of a rubber solution, adjusting the pH of the blend to a pH ranging from 3.2 to 8.6 by addition of an acid, adding the remaining amount of filler to the pH adjusted blend, separating the rubber containing filler from the aqueous phase of the blend, and drying the powdered rubber product obtained.Type: GrantFiled: April 5, 1988Date of Patent: November 29, 1988Assignee: Huls AktiengesellschaftInventors: Hans-Jurgen Smigerski, Uwe Ernst
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Patent number: 4774270Abstract: An aqueous based electrically conductive paint having substantially enhanced settling properties employing a nickel flake pigment and a surfactant having substantial unsaturation characteristics. Paint finds particular application in providing EMI and RFI shielding for electrical components when applied to cabinetry housing such components.Type: GrantFiled: June 19, 1987Date of Patent: September 27, 1988Assignee: The B. F. Goodrich CompanyInventors: F. R. Sullivan, David M. Aleska
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Patent number: 4745140Abstract: Aqueous-based adhesive compositions having good adhesion to a non-polar polymeric surface and to cellulosic materials comprise a dispersion of an adhesive comprising an N-vinyl lactam polymeric resin, a tackifier for such adhesive, and an effective amount of an ethylene/vinyl acetate copolymer emulsion stabilizer for the resin and tackifier. Preferred N-vinyl lactam polymeric resins are vinyl pyrrolidone/vinyl acetate copolymers and a preferred class of tackifier are the rosin ester tackifiers.Type: GrantFiled: March 13, 1987Date of Patent: May 17, 1988Assignee: Chesebrough-Pond's Inc.Inventor: Jagadish C. Goswami
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Patent number: 4742093Abstract: A non-permanent ornamental paint mixture being water soluble after drying. The mixture consists essentially of: from about 75.0 to about 85.0 parts by weight water; from about 10.0 to about 12.0 parts by weight filler; from about 0.5 to about 1.5 parts by weight aqueous pigment dispersion; from about 2.0 to about 2.5 parts by weight release agent; from about 3.0 to about 4.5 parts by weight acid containing, cross-linked acrylic emulsion copolymer; up to 1.0 parts by weight alkali; up to 0.1 parts by weight defoamer; and up to 0.1 parts by weight antimicrobial agent.Type: GrantFiled: December 2, 1986Date of Patent: May 3, 1988Assignee: Pep Rally Paint, Inc.Inventors: Wanda H. Sadler, John Milligan, Jerry W. Parks
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Patent number: 4694032Abstract: A process for preparing a thermoplastic resin composition capable of giving delustered articles which comprises blending (A) 10 to 30 parts by weight of a graft-copolymer and (B) 90 to 70 parts by weight of a copolymer, the total amount of the components (A) and (B) being 100 parts by weight;said graft-copolymer (A) being prepared by adding a nonionic or cationic polymer coagulant to (1) 70 to 95 parts by weight of diene rubber having a diene content of more than 50% by weight to give a coagulated diene rubber, and then graft-polymerizing (2) 30 to 5 parts by weight of at least one monomer selected from the group consisting a vinyl aromatic monomer, a vinyl cyanide and a methacrylic acid ester onto the coagulated diene rubber, the total amount of the components (1) and (2) being 100 parts by weight; said polymer (B) being prepared by polymerizing at least one monomer selected from the group consisting of an aromatic vinyl monomer, a vinyl cyanide, an acrylic acid ester and a methacrylic acid ester.Type: GrantFiled: November 7, 1985Date of Patent: September 15, 1987Assignee: Kanegaguchi Kagaku Kogyo Kabushiki KaishaInventors: Osamu Kakimoto, Fumiya Nagoshi
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Patent number: 4663370Abstract: Polyolefin reinforced asphalt paving and sealing composition containing straight chain unsaturated fatty acid having up to 30 weight percent rosin as a plasticizer, plus an adhesion control component comprising high density polyolefin fines; and a corresponding method for controlling high temperature tracking and washing characteristics without aggravating mixing or plugging problems, by replacing, at least in part, regular inorganic aggregate such as sand with high density polyolefin fines.Type: GrantFiled: October 7, 1985Date of Patent: May 5, 1987Assignee: Hercules IncorporatedInventors: John B. Marvel, Sr., James P. Modrak
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Patent number: 4661548Abstract: An aqueous copolymer emulsion useful as a ceramic tile adhesive contains filler material, a zinc compound and an aqueous emulsion of a copolymer containing residues of an unsaturated aliphatic hydrocarbon monomer, an unsaturated monomer copolymerizable therewith and a small amount of residues containing carboxyl groups.Type: GrantFiled: November 20, 1985Date of Patent: April 28, 1987Assignee: Scott Bader Company LimitedInventor: Robert G. Parker
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Patent number: 4659749Abstract: A casting mixture comprises a ceramic slip and a styrene/acrylic copolymer latex emulsion which provides unique properties and does not require firing.Type: GrantFiled: August 19, 1985Date of Patent: April 21, 1987Inventor: Marshall E. Sornik
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Patent number: 4626559Abstract: A non-permanent ornamental paint mixture that is water soluble after drying. The mixture comprises a first solution of a mixture consisting essentially of water, defoamer, dispersing agent, filler and antimicrobial agent. A second solution is mixed with the first solution and comprises a mixture consisting essentially of water, an acid containing, cross-linked acrylic emulsion copolymer, defoamer, a release agent and alkali. An aqueous pigment dispersion is used in the paint mixture to provide the color.Type: GrantFiled: April 22, 1985Date of Patent: December 2, 1986Assignee: Pep Rally Paint, Inc.Inventors: Wanda H. Sadler, John Milligan, Jerry W. Parks
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Patent number: 4613649Abstract: A light-weight high-strength plastic concrete is obtained by mixing a nonionic surface active agent having a hydrophilic-lipophilic balance of 3 to 6, a vinyl monomer, and a cement slurry with stirring to form a W/O type emulsion, thereafter polymerizing the vinyl monomer and hardening the cement in the W/O type emulsion simultaneously.The plastic concrete obtained by the aforesaid process has a smooth surface and the appearance thereof is almost same as that of an ordinary cement concrete. The plastic concrete is also excellent in workability such as cutting, scraping riveting, etc.Type: GrantFiled: July 15, 1985Date of Patent: September 23, 1986Assignee: Okura Kogyo Kabushiki KaishaInventors: Takashi Saeki, Hideaki Matsuda
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Patent number: 4609690Abstract: Disclosed is an improved aqueous latex adhesive composition of the type having an aqueous latex in admixture with a water dispersible multi-isocyanate cross-linking agent and a thickener. The improvement for a room temperature curable adhesive composition having improved water resistance comprises the curable ingredients consisting essentially of an aqueous hydroxyl functional latex which contains hydroxyl groups as its only isocyanate reactive functionality and the multi-isocyanate cross-linking agent. The cross-linking agent is a water dispersible or water dispersed multi-isocyanate and preferably is a multi-isocyanate which has undergone partial reaction of some of its isocyanate groups with a hydrophobic monohydroxy alcohol. Desirably, fillers incorporated into the adhesive composition are formed into a filler grind prior to incorporation into the adhesive composition. The adhesive composition is especially useful as a structural adhesive in structural lamination manufacture.Type: GrantFiled: December 28, 1984Date of Patent: September 2, 1986Assignee: Ashland Oil, Inc.Inventors: Norma J. Gruber, Clois E. Powell
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Patent number: 4602059Abstract: A coating color possessing desirable rheological and other properties is prepared from a binder composition comprising two polymeric components wherein one of said polymeric components is a lightly cross-linked copolymer derived from an ester of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, an unsaturated carboxamide and, optionally, one or more other comonomers. Paper coating with the coating colors containing the binder composition exhibit high binding strengths and excellent printability.Type: GrantFiled: December 22, 1983Date of Patent: July 22, 1986Assignee: The Dow Chemical CompanyInventors: Bernardus J. M. S. van Rooden, Jose L. T. Martinez
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Patent number: 4602052Abstract: A rubber composition containing carbon black as a reinforcing filler and a quaternary ammonium salt as a coupling agent and a method of making it are disclosed.Type: GrantFiled: September 17, 1984Date of Patent: July 22, 1986Assignee: Amoco CorporationInventors: Kenneth E. Weber, Dirk Oberlin
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Patent number: 4598105Abstract: A rubber composition containing carbon black and a second particulate filler of kaolin, metakaolin, talc, pyrophyllite coal, coke, graphite or metal carbonate filler and a method of making it are disclosed.Type: GrantFiled: September 17, 1984Date of Patent: July 1, 1986Assignee: Amoco CorporationInventors: Kenneth E. Weber, Dirk Oberlin
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Patent number: 4584341Abstract: This invention is a method of producing a latex of crosslinked polydiorganosiloxane. The latex yields an elastomer upon removal of the water. The latex is prepared by homogenizing a mixture of hydroxyl endblocked polydiorganosiloxane, less than 75 millimoles of surface active anionic catalyst per kilogram of polydiorganosiloxane where said surface active anionic catalyst is dodecylbenzene sulfonic acid or hydrogen lauryl sulfate, and water to yield an oil-in-water emulsion. This emulsion is then admixed with from 0.5 to 15 parts by weight of an alkoxy silicon compound selected from a silane of the formula R.sub.a 'Si(OR.sup.3).sub.4-a where R' is a monovalent hydrocarbon radical of up to 12 carbon atoms, R.sup.3 is an alkyl radical of 1 to 6 carbon atoms, and a is 0 or 1, a partial hydrolyzate of the silane, or mixtures of silane and partial hydrolyzate. The resulting emulsion is maintained at a temperature of about 15.degree. to 30.degree. C.Type: GrantFiled: June 25, 1984Date of Patent: April 22, 1986Assignee: Dow Corning CorporationInventors: David J. Huebner, John C. Saam
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Patent number: 4582539Abstract: In a rubbery composition in which a silica containing material is utilized as a reinforcing agent, the hysteresis of the rubbery composition is improved by incorporating the silica containing material into the rubbery composition in the form of zinc modified silica. The zinc modified silica provides an improved reinforcing agent which improves the hysteresis of the rubbery composition when the rubbery composition containing the zinc modified silica is cured.Type: GrantFiled: August 30, 1982Date of Patent: April 15, 1986Assignee: Phillips Petroleum CompanyInventor: Carl J. Stacy
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Patent number: 4578411Abstract: The conventional processing of rubbers into shaped articles of manufacture normally include a compounding step. In this compounding step the rubber is mixed with fillers, curatives, and various other additives so as to obtain a homogeneous mixture. The relatively high viscosity of these raw materials makes it necessary to utilize heavy machinery, such as Banbury mixtures, which consume large amounts of energy in the mixing procedure.The present invention provides an improved process for the production of tack-free, pourable, filler containing powdered rubber. This powdered rubber can be compounded eliminating in whole or in part the need for heavy equipment which consumes high amounts of energy.Type: GrantFiled: September 10, 1984Date of Patent: March 25, 1986Assignee: The Goodyear Tire & Rubber CompanyInventors: William Budd, Paul H. Sandstrom
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Patent number: 4568718Abstract: This invention is a method of producing an aqueous latex of crosslinked polydiorganosiloxane. The latex yields an elastomer upon removal of the water. The latex is prepared by homogenizing a mixture of hydroxyl endblocked polydiorganosiloxane; a silane of the formula R.sub.a 'Si(OR.sup.3).sub.4-a where R' is a monovalent hydrocarbon radical of up to 12 carbon atoms, R.sup.3 is an alkyl radical of 1 to 6 carbon atoms, a partial hydrolyzate, or mixture of silane and hydrolyzate, and a is 0 or 1; a surface active anionic catalyst of the formulae R.sup.2 C.sub.6 H.sub.4 SO.sub.3 H wherein R.sup.2 is a monovalent hydrocarbon radical of at least 6 carbon atoms, R.sup.2 OSO.sub.2 OH, or ##STR1## wherein R.sup.4 is H or R.sup.2 ; and water. The resulting emulsion is maintained at a temperature of 15.degree. to 30.degree. C. for at least 5 hours at a pH of less than 5 until a crosslinked polymer is formed, then this emulsion is admixed with base to a pH of greater than 7.Type: GrantFiled: June 25, 1984Date of Patent: February 4, 1986Assignee: Dow Corning CorporationInventors: David J. Huebner, John C. Saam
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Patent number: 4567231Abstract: This invention is a method of producing a latex of crosslinked polydiorganosiloxane reinforced with colloidal silica. The method allows the production of a latex having a relatively high amount of silica present in relation to the polymer because the water used to form the emulsion can be that present in the acidic colloidal silica sol used in the method. The high solids latex can be useful as a caulking material. The method homogenizes a hydroxyl endblocked polydiorganosiloxane, a silane of the formula R'.sub.a Si(OR.sup.3).sub.4-a where R' is a monovalent hydrocarbon radical of up to 12 carbon atoms, R.sup.3 is an alkyl radical of 1 to 6 carbon atoms, a partial hydrolyzate, or mixture of silane and hydrolyzate, and a is 0 or 1; a surface active anionic catalyst of the formulae R.sup.2 C.sub.6 H.sub.4 SO.sub.3 H wherein R.sup.2 is a monovalent hydrocarbon radical of at least 6 carbon atoms, R.sup.2 OSO.sub.2 OH, or ##STR1## wherein R.sup.4 is H or R.sup.Type: GrantFiled: June 25, 1984Date of Patent: January 28, 1986Assignee: Dow Corning CorporationInventors: David J. Huebner, John C. Saam
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Patent number: 4556686Abstract: Improved stable crosslinked dispersion which is further stabilized with butylated melamine formaldehyde resin. The dispersion to which the improvement of the invention applies is formed by addition polymerization of selected monomers in the presence of an organic liquid which is a solvent for the monomers, but a non-solvent for the polymer and a polymeric dispersion stabilizer having solvated and non-solvated segments.Type: GrantFiled: June 20, 1985Date of Patent: December 3, 1985Assignee: Ford Motor CompanyInventor: Stanley K. Horvath
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Patent number: 4539346Abstract: Rubber chemicals, such as accelerators, are often sold in rodform binders. In order for such rods of a rubber chemical to maintain their structural integrity a polymeric binder is utilized. An improved binder for chemical agents is disclosed herein. This binder is a blend of a graft copolymer and a random copolymer.Type: GrantFiled: March 22, 1984Date of Patent: September 3, 1985Assignee: The Goodyear Tire & Rubber CompanyInventors: Michael R. Ambler, Richard R. Lattime, Edward Wanca
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Patent number: 4503170Abstract: The instant invention is directed to shear thickening fluids to prevent unwanted flow in wells penetrating subterranean formations. The shear thickening fluids comprise (1) a water swellable granular clay present in sufficient quantity so that, upon interaction with an aqueous phase, a stiff paste rapidly forms having a strength of at least 2000 lbs/100 ft.sup.2, (2) a nonaqueous phase comprising a hydrocarbon material and a surfactant, and (3) an aqueous phase comprising water and a watersoluble polymer. The granular clay and water-polymer solution are kept separated by the intervening hydrocarbon-surfactant composition, which is the continuous phase. The intervening oil phase prevents the interaction between the water-polymer phase and the granular clay and results in a stable, nonreacting, pumpable composite until such time as the granular clay is fragmented by application of a sufficiently high shear force.Type: GrantFiled: July 21, 1982Date of Patent: March 5, 1985Assignee: Exxon Production Research Co.Inventors: Evelyn N. Drake, Mary E. Morrison, Charles R. Dawson
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Patent number: 4482657Abstract: A process is provided for producing a silica-synthetic polymer mixture by mixing silica, water and an alkyl trimethylammonium halide, adding this mixture to a latex of the synthetic polymer, coagulating the mixture and recovering the silica-polymer mixture. Such mixtures may be used for the production of rubbery vulcanizates such as shoe soles, light colored shaped articles and the like.Type: GrantFiled: July 12, 1983Date of Patent: November 13, 1984Assignee: Polysar LimitedInventors: Erhardt Fischer, Douglas C. Edwards
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Patent number: 4440879Abstract: A process for preparing filler-containing polytetrafluoroethylene fine powder which comprises mixing together an aqueous dispersion of particles of polytetrafluoroethylene and an aqueous dispersion of particles of a filler adsorbed with polyvalent cation at the surfaces so as to be charged positively in the presence of an anionic surfactant and a water-immiscible organic liquid to coagulate the polytetrafluoroethylene particles and the filler particles in combination and recovering the coagulated particles from the resultant dispersion mixture, said filler particles being per se chargeable negatively in water.Type: GrantFiled: February 18, 1981Date of Patent: April 3, 1984Assignee: Daikin Kogyo Co., Ltd.Inventors: Shoji Kawachi, Katsutoshi Yamamoto, Shinichiro Kai
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Patent number: 4439575Abstract: Aqueous varnishes containing mineral fillers and/or pigments are prepared by allowing a hot wax emulsion in water at between 80.degree. C. and 100.degree. C. to flow with vigorous stirring into the aqueous varnish containing mineral fillers and/or pigments and to cover at least some of the filler and/or pigment particles with a wax coating. These varnishes show virtually no sedimentation of the solid constituents.Type: GrantFiled: September 27, 1982Date of Patent: March 27, 1984Assignee: BASF Farben + Fasern AGInventor: Gunther Schwarz
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Patent number: 4435537Abstract: The subject invention relates to storage stable dispersions comprising certain aromatic polyesters dispersed in certain polyhydroxyl compounds and their process of preparation. The dispersions are useful for the preparation of polymers containing urethane and/or isocyanurate linkages.Type: GrantFiled: March 22, 1982Date of Patent: March 6, 1984Assignee: BASF AktiengesellschaftInventors: Peter Horn, Anton Hesse, Walter Heckmann, Ulrich Lebert, Alfred Guthmann, Matthias Marx
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Patent number: 4431755Abstract: A rubber composition containing a phyllosilicate mineral filler is disclosed.Type: GrantFiled: July 16, 1982Date of Patent: February 14, 1984Assignee: Standard Oil Company (Indiana)Inventors: Kenneth E. Weber, Harold Mukamal
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Patent number: 4426470Abstract: Reinforced polymer composites having a uniform mix of fiber, polymer and binder and having good physical properties are prepared by forming dilute aqueous slurries of a solid heat fusible organic polymer, a reinforcing material and a bound charge latex binder.Type: GrantFiled: September 16, 1982Date of Patent: January 17, 1984Assignee: The Dow Chemical CompanyInventors: Ritchie A. Wessling, Larry D. Yats, Darryl K. Tolbert
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Patent number: 4425450Abstract: Coating compositions comprising hydroxy functional film formers, crosslinking agent therefor and a novel flow control additive. Flow control additive comprises stable crosslinked dispersion formed by addition polymerization of selected monomers in the presence of (i) organic liquid which is a solvent for the monomers, but a non-solvent for the polymer and (ii) polymeric dispersion stabilizer having solvated and non-solvated segments, wherein the dispersion is stabilized further by inclusion therein of a butylated melamine formaldehyde resin.Type: GrantFiled: August 14, 1981Date of Patent: January 10, 1984Assignee: Ford Motor CompanyInventor: Stanley K. Horvath