Polymer Derived From Silicon Reactant Patents (Class 523/425)
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Patent number: 10993279Abstract: This disclosure relates to techniques for adaptive C-DRX Management. A wireless device and a cellular base station may establish a cellular link. According to some embodiments, the base station may monitor upcoming traffic with the wireless device. Based at least in part on the upcoming traffic for the wireless device, the base station may provide a command indicating to the wireless device to enter C-DRX. The command may further indicate to the wireless device a number of C-DRX cycles through which to remain in a low power state.Type: GrantFiled: October 25, 2019Date of Patent: April 27, 2021Assignee: Apple Inc.Inventors: Tarik Tabet, Ajoy K. Singh, Sarma V. Vangala, Vinay R. Majjigi, Samy Khay-Ibbat
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Patent number: 10738065Abstract: Provided is a method for preparing an epoxy compound having an alkoxysilyl group effectively by using a mild catalyst as well as an aromatic alcohol ring-opening agent. The preparation method for an epoxy compound having an alkoxysilyl group includes: performing a ring opening step by reacting an epoxy compound having an epoxide group, which is a starting material, with an aromatic alcohol ring-opening agent in the presence of a phosphine-based catalyst and an optional solvent so as to obtain an intermediate having a partially ring-opened epoxide group; and performing an alkoxysilylation step by reacting the intermediate having a partially ring-opened epoxide with isocyanate alkoxysilane.Type: GrantFiled: May 7, 2019Date of Patent: August 11, 2020Assignee: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGYInventors: Yun Ju Kim, Hyun Aee Chun, Su Jin Park, Sook Yeon Park
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Patent number: 9050624Abstract: A film-forming composition for imprinting that enables a structure to be obtained after coating the composition on a substrate and pressing a mold thereto with low compression pressure, a method of manufacturing a structure using the film-forming composition for imprinting, and a structure obtained thereby. The film-forming composition for imprinting according to the present invention contains a resin and an organic solvent, in which the organic solvent includes a particular solvent having a boiling point of 100 to 200° C. at ambient pressure. When the structure is manufactured, the film-forming composition for imprinting according to the present invention is coated on a substrate to form a resin layer, and after a mold is pressed against the resin layer, the mold is released from the resin layer.Type: GrantFiled: June 24, 2011Date of Patent: June 9, 2015Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventor: Yoshiyuki Takeuchi
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Publication number: 20150051316Abstract: The present invention relates to an alkoxysilylated epoxy compound, a composite exhibiting good heat resistance properties, low CTE and high glass transition temperature and not requiring a coupling agent, a composition including the same, a cured product formed of the composition, a use of the cured product, and a method of preparing the epoxy compound having alkoxysilyl group. An epoxy compound having an epoxy group and an alkoxysilyl group, a composition including the epoxy compound, a curing agent, a filler and/or a reaction catalyst, a cured product of the composition, and a use of the composition including an electronic part are provided. In a composite and/or cured product, the epoxy composition exhibits improved heat resistance properties, decreased CTE, and increased glass transition temperature or Tg-less. The cured product exhibits good flame retardant properties by the introduction of the alkoxysilyl group.Type: ApplicationFiled: April 2, 2013Publication date: February 19, 2015Inventors: Hyun-Aee Chun, Su-Jin Park, Sang-Yong Tak, Yun-Ju Kim, Sook-Yeon Park, Sung-Hwan Park
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Publication number: 20140216300Abstract: A water-based ink for use in a computer-to-plate inkjet printing and a preparation method therefor. A polymer of 5 to 40 wt %, an additive of 0.01 to 10 wt %, a dye or pigment of 0.01 to 10 wt %, an organic solvent of 1 to 30 wt %, an anti-foaming agent of 0 to 5 wt %, and deionized water are stirred and mixed at room temperature. When the polymer is dissolved, the mixed solution is filtered. The filtrate is the water-based ink. The water-based ink is sprayed via a computer-to-plate machine onto a surface of a metal substrate (which may be an aluminum plate, a zinc plate, or a copper plate) to form a graphic region. A printing plate allowing for computer-to-plate printing is acquired after solidification. The printing plate acquired is allowed to achieve a halftone dot reproduction rate between 2 and 99% and a recognition rate of 175 lpi.Type: ApplicationFiled: September 7, 2012Publication date: August 7, 2014Applicant: Institute of Chemistry, Chinese Academy of ScienceInventors: Wei Wu, Haihua Zhou, Yanlin Song
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Patent number: 8784991Abstract: A composition and a method for coating metallic surfaces with a silane/silanol/siloxane/polysiloxane-containing composition, whereby the composition contains a) at least one compound selected from the silanes, silanols, siloxanes and polysiloxanes, b) at least two compounds selected from titanium-, hafnium-, zirconium-, aluminum- or boron-containing compounds, optionally c) at least one type of cation selected from cations of metals of the 1st to 3rd and 5th to 8th sub-groups including the lanthanides and the 2nd main group of the periodic table of the elements or at least one corresponding compound, d) at least one organic compound selected from monomers, oligomers, polymers, copolymers and block copolymers or e) at least one substance affecting the pH value, water and optionally at least one organic solvent.Type: GrantFiled: April 6, 2011Date of Patent: July 22, 2014Assignee: Chemetall GmbHInventors: Thomas Kolberg, Manfred Walter, Peter Schubach
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Publication number: 20140179830Abstract: The invention relates to a two-component composition, including a component A, which includes at least one silane-functional polymer and at least one hardener or accelerator for epoxy resins, and a component B, which includes at least one aqueous emulsion of at least one epoxy resin. Two-component compositions according to the invention are suitable as adhesives, sealants or coatings.Type: ApplicationFiled: August 24, 2012Publication date: June 26, 2014Applicant: SIKA TECHNOLOGY AGInventors: Urs Burckhardt, Fabien Choffat, Daniele Rutz, Steffen Kelch, Ulrich Wolf
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Patent number: 8722148Abstract: This invention relates to a coating composition comprising (A) 100 weight parts of at least one epoxy resin; (B) 40 to 900 weight parts of at least one alkoxy-containing aminofunctional silicone resin; (C) up to 50 weight parts of at least one organic hardener; (D) up to 100 weight parts of at least one epoxyfunctional silicone resin; and (E) up to 10 weight parts of at least one cure accelerator, provided the alkoxy-containing aminofunctional silicone resin (B) has a total alkoxy content ranging from 26 to 80 mol percent per mole of silicon (Si) in the alkoxy-containing aminofunctional silicone resin. Methods for preparing the above-described composition and for treating substrates are also disclosed.Type: GrantFiled: December 16, 2010Date of Patent: May 13, 2014Assignee: Dow Corning CorporationInventors: John Bernard Horstman, Randall Schmidt, Steven Swier
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Publication number: 20140058012Abstract: Aqueous emulsions of epoxy- and organo-substituted, branched organopolysiloxanes are prepared by emulsifying the latter in water with the aid of a dispersing agent. The emulsions are storage stable and are useful in multi-component coating, adhesive, and binder systems.Type: ApplicationFiled: August 23, 2012Publication date: February 27, 2014Applicant: WACKER CHEMICAL CORPORATIONInventors: Timothy McCormack, Daniel Calimente
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Patent number: 8536250Abstract: A simultaneous interpenetrating polymer network—geopolymer epoxy composition includes a first component comprised of a waterborne epoxy curing agent, an aluminosilicate source, and an amorphous silica, and a second component comprised of an epoxy resin and an alkaline silicate solution. The two components are mixed to produce a SIN-GE composition that cures at ambient temperatures. The SIN-GE composition may be a low-viscosity, sprayable composition, or may be a higher-viscosity composition. The compositions may be used as coatings, adhesives, mortars, casting materials, and the like.Type: GrantFiled: October 14, 2010Date of Patent: September 17, 2013Assignee: Tnemec Company Inc.Inventors: Remi Briand, Laura J. Betzen, Jeremy M. Ethington, Erin McKenzie, Peter A. Smith
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Publication number: 20130236649Abstract: Epoxy-polysiloxane based coating and flooring compositions exhibiting improved flexibility, and excellent weatherability and corrosion resistance after curing are described. The epoxy-polysiloxane polymer coating composition may be prepared by combining a polysiloxane, an epoxide resin material and a cure system including a blend of compounds selected from a dialkoxy functional aminosilane, a trialkoxy functional aminosilane, and an amino functional polysiloxane resin, where the blend has an average alkoxy functionality value ranging from 2.0 to 2.Type: ApplicationFiled: March 9, 2012Publication date: September 12, 2013Applicant: PPG Industries Ohio, Inc.Inventor: Norman R. Mowrer
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Publication number: 20130224496Abstract: The present invention is directed to the surprising discovery that a hard, low energy epoxysilicone/organic epoxy coating can be generated that can be easily sanded, easily repaired and are chemically stable to the marine environment. The invention reveals the use of epoxy functional siloxanes that chemically bond with an organic epoxy polymer and a polyfunctional amine or amide to form block copolymer networks with the silicone distributed through the entire matrix. The coating thus generated can be applied directly over most hull substrates, anticorrosion coatings or as a repair over itself.Type: ApplicationFiled: October 29, 2011Publication date: August 29, 2013Applicant: Hardcoat Surfaces LLCInventors: Duane R. Palmateer, John A. Kilgour
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Publication number: 20130121948Abstract: There is provided herein a composition comprising the non-covalent bonded reaction product of a hydrophilic polymer containing an acid functional group and a hydrophobic polymer which contains an amine group bound directly to the hydrophobic polymer backbone; and, optionally a diluent, as well as a process of making such a composition.Type: ApplicationFiled: November 16, 2011Publication date: May 16, 2013Applicant: Momentive Performance Materials Inc.Inventors: Anne Dussaud, Ning Lu
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Publication number: 20120156382Abstract: The invention relates to a two-component composition consisting of a component A containing a polymer with a molecular weight of 250 to 5000 g/mol which has at least 2 epoxy groups per molecule, a component B containing a compound of the formula (I) R1-phenyl-(—O—R2)a where R1=H, C1 to C6-alkyl, a=1, 2, or 3, R2=—O—CH2—CHOH—CH2—NH—CH2-phenyl-CH2—NH2, wherein the epoxy/NH ratio of the components A to B is between 0.75:1 to 1.25:1.Type: ApplicationFiled: December 14, 2011Publication date: June 21, 2012Applicant: Henkel AG & Co, KGaAInventors: Holger Eichelmann, Michael Hoeltgen
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Publication number: 20120021125Abstract: An acrylic-fiber finish for use in carbon-fiber production contributes to high tenacity of resultant carbon fiber. The acrylic-fiber finish for carbon-fiber production includes an epoxy-polyether-modified silicone and a surfactant. The weight ratios of the epoxy-polyether-modified silicone and the surfactant in the total of the non-volatile components of the finish respectively range from 1 to 95 wt % and from 5 to 50 wt %. The carbon fiber production method includes a fiber production process for producing an acrylic fiber for carbon-fiber production by applying the finish to an acrylic fiber which is a basic material for the acrylic fiber for carbon-fiber production; an oxidative stabilization process for converting the acrylic fiber produced in the fiber production process into oxidized fiber in an oxidative atmosphere at 200 to 300 deg.C.; and a carbonization process for carbonizing the oxidized fiber in an inert atmosphere at 300 to 2,000 deg.C.Type: ApplicationFiled: May 21, 2010Publication date: January 26, 2012Applicant: MATSUMOTO YUSHI-SEIYAKU CO., LTD.Inventors: Takeyoshi Nakayama, Yoshio Hashimoto, Mikio Nakagawa
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Publication number: 20120018072Abstract: This invention relates to a method for storing a naphthol aralkyl type cyanate ester resin solution, which is difficult to precipitate due to long term storage in a solution state, and particularly relates to a method for storing a naphthol aralkyl type cyanate ester resin solution (AB), which comprises: preparing (i) a naphthol aralkyl type cyanate ester resin solution (AB) comprising a naphthol aralkyl type cyanate ester resin (A), a maleimide compound (B) and a solvent, (ii) a naphthol aralkyl type cyanate ester resin solution (AB) comprising a prepolymer of a naphthol aralkyl type cyanate ester resin (A), a maleimide compound (B) and a solvent, or (iii) a naphthol aralkyl type cyanate ester resin solution (AB) comprising a prepolymer of a naphthol aralkyl type cyanate ester resin (A) and a maleimide compound (B), and a solvent, and; storing the resin solution (AB).Type: ApplicationFiled: March 24, 2010Publication date: January 26, 2012Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Masayoshi Ueno, Yoshihiro Kato, Takeshi Nobukuni
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Publication number: 20110317239Abstract: [Problems] A coating composition preferably used for forming a hard coating by being applied and cured on a light-transmitting member such as a highly refractive plastic lens or a highly refractive photochromic plastic lens having a function for developing a color, the coating composition markedly improving weather resistance (preventing discoloration) while sustaining high refractive index, scratch resistance and excellent adhesion to the optical material. [Means for Solution] The coating composition comprises (A) a fine granular metal oxide containing titanium oxide and (B) a fine granular metal oxide containing titanium oxide having dissimilar properties as selected by a specific light irradiation test and, further, contains (C) an epoxy group-containing organosilicon compound such as ?-glycidoxypropyltrimethoxysilane, (D) water, (E) an organic solvent such as methyl alcohol, and (F) a curing catalyst such as aluminum acetyl acetonato or magnesium perchlorate at specific ratios.Type: ApplicationFiled: May 13, 2010Publication date: December 29, 2011Inventors: Katsuhiro Mori, Shunichiro Nakatsukasa
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Publication number: 20110190415Abstract: The invention relates to an aqueous silicone dispersion, containing one or more polyorganosiloxanes (POSs) intended to be crosslinked or having been crosslinked by elimination of water or alcohol, according to a polycondensation mechanism. The present invention also relates to methods for preparing aqueous silicone emulsions and dispersions.Type: ApplicationFiled: March 28, 2011Publication date: August 4, 2011Applicant: RHODIA CHIMIEInventors: Nadia MARTIN, Martial DERUELLE, Patricia BEURDELEY
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Publication number: 20110189488Abstract: A compositon and a method for coating metallic surfaces with a silane/silanol/siloxane/polysiloxane-containing composition, whereby the composition contains a) at least one compound selected from the silanes, silanols, siloxanes and polysiloxanes, b) at least two compounds selected from titanium-, hafnium-, zirconium-, aluminum- or boron-containing compounds, optionally c) at least one type of cation selected from cations of metals of the 1st to 3rd and 5th to 8th sub-groups including the lanthanides and the 2nd main group of the periodic table of the elements or at least one corresponding compound, d) at least one organic compound selected from monomers, oligomers, polymers, copolymers and block copolymers or e) at least one substance affecting the pH value, water and optionally at least one organic solvent.Type: ApplicationFiled: April 6, 2011Publication date: August 4, 2011Inventors: Thomas Kolberg, Manfred Walter, Peter Schubach
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Publication number: 20110143064Abstract: This composition comprises, in water: (A) at least one adhesion promoter bearing at least one amine functional group and/or at least one epoxy functional group; (B) at least one monomer and/or at least one prepolymer intended to form a polymer system capable of reacting covalently with the amine and/or epoxy functional group(s) of the constituent (A); (C) at least one curing agent or crosslinker used in an amount equivalent to ±30 mol % of the stoichiometry of the constituent (B); the constituent (B) being present in the composition in an amount of 0.5 to 5% by weight, in particular in an amount of 1.5% by weight, expressed as solids in water; and the constituent (A) being present in an amount of 0.2 to 3 parts by weight per 100 parts by weight of the constituent (B).Type: ApplicationFiled: July 8, 2009Publication date: June 16, 2011Applicant: SAINT-GOBAIN EMBALLAGEInventors: Claude Da Silva, Stephane Lohou, Jean-Baptiste Denis
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Publication number: 20110112221Abstract: A process for producing an epoxy silane oligomer including a reaction glycidoxy silane and/or cycloaliphatic epoxy silane having 2 or 3 allcoxy groups and, optionally, a copolymerizable silane other than glycidoxy and cycloaliphatic epoxy silane, with less than 1.5 equivalents of water in the presence of a catalyst, wherein said water is continuously fed during the reaction.Type: ApplicationFiled: January 14, 2011Publication date: May 12, 2011Applicant: Momentive Performance Materials Inc.Inventors: Alain Lejeune, Yves Gentil
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Patent number: 7723452Abstract: The invention relates to a method of treatment of a retroreflective sheet with a treatment composition that comprises a fluorinated compound having one or more silyl groups and an auxiliary compound selected from the group consisting of (i) one or more non-fluorinated compounds of an element M selected from Si, Ti, Zr, B, Al, Ge, V, Pb and Sn and (ii) an organic compound having a Si—H group. The invention also relates to compositions comprising (i) a fluorinated compound comprising one or more silyl groups and (ii) an auxiliary compound selected from the group consisting of organic compounds having a Si—H group.Type: GrantFiled: June 28, 2007Date of Patent: May 25, 2010Assignee: 3M Innovative Properties CompanyInventors: Gert A. M. Hooftman, Dorothee B. Loosen
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Publication number: 20090297855Abstract: A non-stick coating composition comprising a waterborne phenoxy resin, a crosslinker, a silicone compound, and a Fluoropolymer. An article, such as aluminum, may be coated with the composition. The composition may be multi-layers, but only the layers other than the first layer includes the silicone compound. The invention includes the method for applying the coating or coatings.Type: ApplicationFiled: April 30, 2009Publication date: December 3, 2009Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.Inventors: Thomas James BATE, Arthur WACHOWSKI
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Patent number: 7351783Abstract: A paint composition has a resin constituent which includes (i) a non-aromatic epoxy resin, (ii) a polysiloxane and (iii) an epoxysilane. The paint composition has an anti-corrosive effect.Type: GrantFiled: July 4, 2000Date of Patent: April 1, 2008Assignee: Nor-Maali OyInventors: Mika Perälä, Seppo Tikkanen
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Patent number: 7285579Abstract: Solventless siloxane epoxy-based coating compositions for use on metals, plastics, wood, and glass are disclosed. The compositions are cationically curable in air by U.V. or by electron beam radiation. The siloxane epoxy coating compositions exhibit excellent film properties after curing, such as good adhesion, flexibility, and appearance. The coating compositions may be clear or may contain fillers, dyes, and pigments. A method for manufacturing a coated metal, plastic, wood, or glass substrate using the compositions is also disclosed, as well as the coated material manufactured by the method.Type: GrantFiled: March 15, 2005Date of Patent: October 23, 2007Assignee: Polyset Company, Inc.Inventor: Ramkrishna Ghoshal
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Patent number: 7026422Abstract: A hydrolytic condensation coating composition includes a silane, an epoxy resin, a hydrolytic condensation catalyst, and a solvent. The weight ratio of the epoxy resin to the silane is 1:0.4˜6. The silane is reactable with the epoxy resin, and is hydrolyzable in the presence of the hydrolytic condensation catalyst to form a three-dimensional stereo-network structure. A hard coat film obtained by coating a plastic substrate with the coating composition, followed by thermo-curing, exhibits high transparency and hardness, and has excellent anti-scratch and chemical-resistant properties. The hard coat film is suitable for use as a surface protective film for displays, polarizers, touch panels, ITO conductive films, other optical elements, and the like.Type: GrantFiled: March 13, 2003Date of Patent: April 11, 2006Assignee: Far Eastern Textile Ltd.Inventors: Yun-Han Chang, Tsai-An Yu, Wen-Chih Lin
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Patent number: 6962948Abstract: Solventless siloxane epoxy-based coating compositions for use on metals, plastics, wood, and glass are disclosed. The compositions are cationically curable in air by heat or by electron beam radiation. The siloxane epoxy coating compositions exhibit excellent film properties after curing, such as good adhesion, flexibility, weatherability, and corrosion resistance even in the absence of a chromium-containing filler. The coating compositions may be clear or may contain fillers and/or pigments. A method for manufacturing a coated metal, plastic, wood, or glass substrate using the compositions is also disclosed, as well as the coated material manufactured by the method.Type: GrantFiled: August 7, 2003Date of Patent: November 8, 2005Assignee: Polyset Company, Inc.Inventor: Ramkrishna Ghoshal
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Patent number: 6706405Abstract: Erosion resistant coating compositions comprising a poly(Bisphenol A-co-epichlorohydrin) glycidyl end-capped component, an active hydrogen compound, a linear siloxane and a silsesquioxane. Protective coatings formed from such a composition impart particle-erosion resistance to parts having such a coating disposed on some portion of their surface.Type: GrantFiled: February 11, 2002Date of Patent: March 16, 2004Assignee: Analytical Services & Materials, Inc.Inventors: Bridget Marion Sanders, Karl Erik Wiedemann
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Publication number: 20030149135Abstract: A curable underfill encapsulant composition which is especially useful in the no-flow underfill encapsulation process. The composition contains an epoxy resin, a fluxing agent, a linear polyanhydride and a catalyst. In an alternative embodiment, the composition also contains a linear anhydride. Various additives, such as surfactants and coupling agents may also be added to the composition.Type: ApplicationFiled: January 31, 2002Publication date: August 7, 2003Inventors: Paul Morganelli, Anthony Debarros, Brian Wheelock, Jayesh Shah
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Publication number: 20010049405Abstract: A stain/topcoat system for non-porous thermoset and/or thermoplastic articles comprises a pigmented stain, and a topcoat comprising one or more non-siloxane film-forming polymers, an emulsion of one or more curable organopolysiloxanes, a weatherability agent having a functional group that is reactive with carboxylate functional sites and water. The topcoat displays exceptional adhesion and weatherability to pigmented stained surfaces.Type: ApplicationFiled: December 29, 2000Publication date: December 6, 2001Applicant: Therma-Tru CorporationInventor: Cem A. Porter
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Publication number: 20010031362Abstract: A water based, low VOC coating includes an aqueous dispersion of an amine terminated epoxy resin and an organosilane curing agent of the formula: R1—(CH2)x—Si—(R3)n—(R2)3−n; wherein R1 is an epoxide, an isocyanate, or an acrylic; R2 is an alkoxy group, acetoxy group, or an oximino group; R3 is a C1—C6 alkyl group; X is an integer from 2-10; and n is 0 to 2.Type: ApplicationFiled: May 22, 2001Publication date: October 18, 2001Applicant: PRC-DeSoto International, Inc.Inventors: Sam Abrami, Jak Aklian, Adrian Balladares, Anni Kazorian
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Patent number: 5998509Abstract: A resin composition comprising (a) an epoxy compound, (b) a curing agent comprising a polysiloxane resin having a phenolic hydroxyl group on its side chain, and (c) an inorganic filler. The mixing ratio of the inorganic filler should preferably be 10 to 95% by weight based on the entire resin composition.Type: GrantFiled: November 28, 1997Date of Patent: December 7, 1999Assignee: Kabushiki Kaisha ToshibaInventors: Rumiko Hayase, Shinetsu Fujieda, Yasuyuki Hotta, Shinji Murai
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Patent number: 5965637Abstract: The use of a thermosetting epoxy resin blend as a casting compound for electronic or electrotechnical components. The blend contains a silicone-modified epoxy resin in which organic components containing epoxy groups are chemically bonded to silicone components, and a mineral filler, optionally silanized, that regulates the thermal expansion behavior, in an amount of 40 wt % to 75 wt %, based on the thermosetting epoxy resin blend. The thermosetting epoxy resin blends are used to particular advantage for casting diodes.Type: GrantFiled: June 10, 1998Date of Patent: October 12, 1999Assignee: Robert Bosch GmbHInventors: Werner Pfander, Irene Jennrich, Richard Spitz, Uwe Koehler, Siegfried Schuler
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Patent number: 5919851Abstract: A paint composition comprising, as a leveling agent, 0.01 to 3.0 parts by weight of a polyfluorinated carbon chain-containing compound and 0.01 to 3.0 parts by weight of a silicone oil per 100 parts by weight of a film forming component and being capable of forming a film being excellent in water- and oil-repelling property and stain resistance, and painted articles being excellent in water- and oil-repelling property and stain resistance can be provided.Type: GrantFiled: April 8, 1997Date of Patent: July 6, 1999Assignee: Daikin Industries, Ltd.Inventors: Seitaro Yamaguchi, Koichiro Ogita, Nobuyuki Tomihashi
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Patent number: 5883276Abstract: An improved aqueous electrocoating composition that contains an anticrater agent which is a reaction product of polyoxyalkylene diamine and glycidoxy alkyl alkoxy silane which is hydrolyzed and has a number average molecular weight of about 700-5,000; electrodeposited finishes are formed that have a significant reduction in craters and are smooth and even finishes.Type: GrantFiled: October 22, 1997Date of Patent: March 16, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Allisa Gam, Ding Yu Chung
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Patent number: 5760109Abstract: Proposed is a novel organopolysiloxane composition in the form of a water-base emulsion suitable for use as a surface-coating agent on rubber articles such as automobile parts to impart excellent smoothness of the surface, abrasion resistance, adhesion to the rubber surface and so on. The composition comprises: (a) an organopolysiloxane having a viscosity of at least 10000 centipoise at 25.degree. C. and having a molecular structure consisting of the difunctional siloxane units and the trifunctional siloxane units terminated at each molecular chain end with a hydroxy group, in the form of an aqueous emulsion; (b) a hydrolysis-condensation product of an epoxy group-containing dialkoxy silane in the form of an aqueous emulsion; (c) a water-soluble organic amino compound having at least two amino groups in a molecule and containing no silicon atom; and (d) silicone rubber particles in the form of an aqueous dispersion, each in a specified weight proportion.Type: GrantFiled: August 8, 1996Date of Patent: June 2, 1998Assignee: Shin-Etsu Chemical, Co., Ltd.Inventors: Yoshinori Inokuchi, Satoshi Kuwata
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Patent number: 5750596Abstract: An improved aqueous electrocoating composition that contains an anticrater agent which is a reaction product of polyoxyalkylene diamine and isocyanto alkyl alkoxy silane which is hydrolyzed and has a number average molecular weight of about 2,000-5,000; electrodeposited finishes are formed that have a significant reduction in craters and are smooth and even finishes.Type: GrantFiled: December 23, 1996Date of Patent: May 12, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Allisa Gam
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Patent number: 5739181Abstract: Transparent substrates are rendered resistant to fogging by the application of a hardcoat composition comprising finely divided silica, a multi-functional olefin containing two or more olefinic moieties and one or more divalent oxyalkylene radicals having the formula:--((CX2).sub.n O).sub.x ((CX2)O).sub.y --where the sum of the x stoichiometric subscripts for each divalent oxyalkylene radical and the sum of the y stoichiometric subscripts for each divalent oxyalkylene radical when said sums are added together is ten or greater and the stoichiometric subscripts n and m are different and have values independently ranging from one to ten, where each X is independently selected from the group consisting of hydrogen, one to forty carbon atom monovalent hydrocarbon radicals and six to forty carbon atom monovalent aromatic hydrocarbon and an olefinically functionalized trialkoxysilane followed by curing.Type: GrantFiled: June 7, 1996Date of Patent: April 14, 1998Assignee: General Electric CompanyInventors: Igor V. Khudyakov, George F. Medford
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Patent number: 5723519Abstract: An improved aqueous electrocoating composition that contains an anticrater agent which is a reaction product of polyoxyalkylene diamine and glycidoxy alkyl alkoxy silane which is hydrolyzed and has a number average molecular weight of about 700-5,000; electrodeposited finishes are formed that have a significant reduction in craters and are smooth and even finishes.Type: GrantFiled: February 25, 1997Date of Patent: March 3, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Allisa Gam, Ding Yu Chung
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Patent number: 5703178Abstract: A heat ablative coating composition is prepared by combining an epoxy silane resin, an epoxy resin, a silicone intermediate, a silicon-modified polyether, an aminosilane, at least one organometallic catalyst, at least one organic solvent, water, at least one filler, optional nonsilicon-containing amine catalyst, and optional pigments and thixotropic agents. The heat ablative coating composition is applied to a substrate to form a film having a build thickness in the range of from about 0.1 to 0.5 inches that is capable of curing at ambient outdoor temperature in about seven days, depending on ambient conditions. The heat ablative film so formed is designed to undergo a slow thermal decomposition when exposed to high temperature conditions without igniting or causing excessive smoke, and is designed to have good thermal conductivity to protect the underlying substrate from thermal decomposition.Type: GrantFiled: November 30, 1995Date of Patent: December 30, 1997Assignee: Ameron International CorporationInventor: Roland L. Gasmena
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Patent number: 5561174Abstract: Disclosed is a liquid epoxy resin composition comprising (A) a liquid epoxy resin, (B) a dimethylpolysiloxane having epoxy groups at its both ends, and (C) a dispersing agent comprising the reaction product of (C-1) a dimethylpolysiloxane having amino groups or carboxyl groups reactive with epoxy resins at its side chains or both ends and having phenyl groups or polyether groups for improving its compatibility with epoxy resins at its side chains, and (C-2) an epoxy resin having the same structure as the component (A). The composition has a reduced internal stress, while maintaining the heat resistance intrinsic to epoxy resins, and has excellent resistance, crack resistance and heat shock resistance.Type: GrantFiled: September 29, 1995Date of Patent: October 1, 1996Assignee: Murata Manufacturing Co., Ltd.Inventors: Yoshinori Saito, Masaaki Hirayama, Shunjiro Imagawa, deceased
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Patent number: 5548018Abstract: An aqueous primer composition comprising a copolymer wherein a cationic monomer, a specific alkoxysilane monomer, a silane macromonomer and an ethylenically unsaturated monomer are contained in aqueous medium. For this reason, regardless of the alkalinity of the substrate, the aqueous primer composition can form a highly water-resistant, alkali-resistant, tough film. Furthermore, compared with the prior art, a higher concentration and a lower viscosity, so that the resulting primer composition shows excellent penetration into the substrate at high concentration and provides for sufficient substrate-reinforcing and water-proofing effects. Moreover, when forming a film thereby and forming a finish layer thereon, this composition shows a high affinity for the top coating or adhesive to insure a firm integration of the finish layer with the substrate surface.Type: GrantFiled: May 19, 1995Date of Patent: August 20, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventor: Masao Maekawa
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Patent number: 5547711Abstract: Self-crosslinking preparation made from water, alkoxysiline compounds containing perfluoroalkyl groups, compounds soluble in water or emulsifiable or dispersible in water containing perfluoroalkyl groups and optionally further constituents, which preparations are storage stable and suited for the protection of glass, stony material, textiles, leather and paper.Type: GrantFiled: May 19, 1995Date of Patent: August 20, 1996Assignee: Bayer AktiengesellschaftInventors: Stephan Kirchmeyer, Klaus Pohmer, Tillmann Hassel
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Patent number: 5466729Abstract: This invention provides a dispersion composition comprising (a) water and (b) a silylated epoxy resin prepared by reacting (i) a silane having at least two silicon atoms each bearing at least one hydrolyzable group and attached to a secondary amine by a hydrocarbon and (ii) a resin containing at least two epoxy groups and methods of using the dispersion.Type: GrantFiled: October 21, 1994Date of Patent: November 14, 1995Assignee: OSi Specialties, Inc.Inventors: Antoine J. E. Guillet, Remy C. H. Gauthier
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Patent number: 5441995Abstract: The present invention provides a paint film with fewer craters and indentations, while maintaining performance as an electrodeposition paint. The electrodeposition paint composition contains an aqueous dispersing system containing an electrodepositable resin and a block polymer containing polysiloxane units and polyalkylene oxide units.Type: GrantFiled: June 6, 1994Date of Patent: August 15, 1995Assignee: Nippon Paint Co., Ltd.Inventors: Atsushi Ohgaki, Hiroharu Ohsugi, Hisaki Tanabe, Kenshiro Tobinaga, Yoshio Kojima
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Patent number: 5380781Abstract: Cationically electrodepositable (gelled) fine particles using, as the base, an epoxy resin-amine adduct having hydrolysable alkoxysilane groups, and a cationic electrodeposition paint composition comprising said fine particles. Said fine particles give a paint film having excellent corrosion resistance and are useful as a rheology-controlling agent for cationic electrodeposition paint. Said electrodeposition paint composition has an excellent edge-covering property, and a paint film formed therewith on an article to be coated can give improved corrosion resistance to the edges of said article and has good surface smoothness.Type: GrantFiled: July 23, 1993Date of Patent: January 10, 1995Assignee: Kansai Paint Co., Ltd.Inventors: Kiyoshi Kato, Kenichi Yoneyama, Haruo Nagaoka, Kenji Yamamoto, Kazuyuki Morimoto, Masafumi Kume
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Patent number: 5362772Abstract: A cationic finely divided polymeric microgel dispersed in an aqueous medium for use in cationic electrocoating compositions of a epoxy terminated polyepoxy hydroxy ether resin being end capped with a ketimine, a primary amine, secondary amine or mixtures thereof and amino siloxane to provide silanol groups and amino groups; the amino groups of the polymeric microgel being neutralized with an acid to form cationic groups for water dispersibility and the silanol groups being condensed with hydroxy groups of the resins and other silanol groups of the resin thereby forming a crosslinked microgel.Type: GrantFiled: July 9, 1993Date of Patent: November 8, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventors: Peter W. Uhlianuk, Raymond S. Van Ham
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Patent number: 5362775Abstract: An epoxy resin composition comprising (i) an epoxy resin, (ii) a phenolic curing agent, (iii) an organophosphorous curing agent, (iv) alumina, and (v) a separating means for separating the organophosphorous curing agent and the alumina, which may be a coating over the surfaces of the organophosphorous curing agent.Type: GrantFiled: March 24, 1992Date of Patent: November 8, 1994Assignees: Nippondenso Co., Ltd., Shin-Etsu Chemical Co., Ltd.Inventors: Akira Shintai, Hiroshi Shibata, Toshio Shiobara, Koji Futatsumori, Seizi Katayama, Yasutaka Yoshida
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Patent number: 5356960Abstract: An improved aqueous electrocoating composition that contains an anticrater agent which is a reaction product of poly epoxy hydroxy ether resin, polyoxyalkylene diamine and an amino, glycidyl or isocyanate functional alkyl alkoxy silane having a number average molecular weight of about 1,000-6,000; electrodeposited finishes are formed that have a significant reduction in craters and are smooth and even finishes.Type: GrantFiled: August 11, 1993Date of Patent: October 18, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventors: Ding Y. Chung, Allisa Gam
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Patent number: 5317046Abstract: Polyamide--Epoxy--Silicone modified compositions in a water base that are air curable to give tough flexible coatings that may be pigment loaded and maintain the chemical resistance and bonding capabilities of the usual epoxy coatings with hardness and gloss equal to or greater than baked epoxy coatings is disclosed.Type: GrantFiled: October 13, 1992Date of Patent: May 31, 1994Inventor: Philip A. Fonkalsrud