Organic Sulfur Compound Dnrm Patents (Class 523/453)
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Patent number: 4749042Abstract: A composition is provided which, when applied to a metal surface, forms a corrosion-inhibiting film thereon. The composition comprises an epoxy resin, and a petroleum sulfonate, usually in a hydrocarbon diluent. The composition can further comprise a polyamine, an alcohol or both. The composition is applied by contacting the metal surface with the composition as one solution or as a hydrocarbon solution of the epoxy resin and a solution comprising the petroleum sulfonate. The composition is particularly useful in the treatment of downhole metal surfaces in oil and gas wells to inhibit the corrosion of the metal.Type: GrantFiled: October 10, 1986Date of Patent: June 7, 1988Assignee: Phillips Petroleum CompanyInventor: Yulin Wu
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Flame-resistant, thermoplastic polyurethane elastomers, process for their preparation, and their use
Patent number: 4748195Abstract: The invention relates to flame-resistant, thermoplastic polyurethane elastomers containing a flame-retardant additive package comprising:(a) a compound selected from the group consisting of antimony trioxide, zinc borate and mixtures thereof,(b) a chlorinated polyethylene, and(c) a brominated aromatic compound, preferably selected from the group consisting of polytetrabromobis(phenol)-A-glycidyl ether), polytribromostyrene, and polytetrabromobis(phenol)-A-carbonate).The flame-retardant additive package may be incorporated into the starting components used to prepare the thermoplastic polyurethane prior to the reaction which forms the polyurethane, to the reaction mixture during the reaction, or to the finished thermoplastic polyurethane elastomers.The flame resistant, thermoplastic polyurethane elastomers are suitable for the preparation of, for example, molded articles, films, sheets, and cable jackets.Type: GrantFiled: December 8, 1986Date of Patent: May 31, 1988Assignee: BASF AktiengesellschaftInventors: Christa Hackl, Dietrich Wagner, Hans M. Rombrecht -
Patent number: 4719267Abstract: A heat curable one package polyurethane resin composition adaptable to use for automotive seam sealing, particularly under high solids acrylic enamel paints, said composition comprising an isocyanate terminated polyurethane prepolymer having pendant epoxy groups along the polymer chain and the isocyanate groups of which are blocked by reaction with an oxime, and a curing agent having at least two active hydrogen atoms per molecule, such as a polyol, a polyamine, or a blocked polyamine.Type: GrantFiled: August 6, 1986Date of Patent: January 12, 1988Assignee: Essex Specialty Products, Inc.Inventors: Sidky Rizk, Harry W. S. Hsieh
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Patent number: 4675350Abstract: Disclosed is a composition comprising about 5 to about 95 phr of a polyepoxide or other resinous component, about 20 to about 90% of an aprotic solvent, about 5 to about 95 phr of a polyimide having sufficient amic acid functionality to be soluble in the solvent, and sufficient water to hydrolyze the polyimide. A laminate is made from the composition by heating it until the amic acid functionality is substantially eliminated, then impregnating a fibrous substrate with the composition, heating the impregnated substrate to evaporate the solvent and B-stage the composition and form a prepreg, forming a stack of the prepregs, and heating and pressing the stack of prepregs to cure the composition. A wire enamel can also be made from the composition.Type: GrantFiled: October 23, 1985Date of Patent: June 23, 1987Assignee: Westinghouse Electric Corp.Inventors: Joseph R. Marchetti, Zal N. Sanjana
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Patent number: 4624975Abstract: The hydrolyzable halide content of glycidyl ethers prepared by dehydrohalogenating a halohydrin ether intermediate product in the presence of an organic solvent, washing the resultant product with water and distilling the solvent from the organic phase from the water wash step is stabilized when the distillation step is conducted in the presence of a sulfonic acid, sulfonic acid ester, organic sulfate or any combination thereof such as p-toluene sulfonate.Type: GrantFiled: September 20, 1985Date of Patent: November 25, 1986Assignee: The Dow Chemical CompanyInventor: Ha Q. Pham
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Patent number: 4619961Abstract: Organic materials are made flame retardant by addition of a polyhalogenated polyphenylene sulfide such as decabromodiphenyl sulfide or 1,4-thiobis(2,4,6-tribromophenyl)-2,3,5,6-tetrabromobenzene alone or in combination with a Group VA metal oxide, e.g. Sb.sub.2 O.sub.3. A process for making the compounds is also disclosed.Type: GrantFiled: December 26, 1984Date of Patent: October 28, 1986Assignee: Ethyl CorporationInventors: Burton J. Sutker, Saadat Hussain, Amgad S. Mossaad
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Patent number: 4614674Abstract: Addition of waxes or wax-like substances, in conjunction with metal salts or metal complexes of organic compounds, to powder coating compositions based on epoxy resins and carboxyl-terminated polyesters affords a matting effect without substantially impairing the other properties of said coating composition.Type: GrantFiled: May 3, 1985Date of Patent: September 30, 1986Assignee: Ciba-Geigy CorporationInventor: Horst Lauterbach
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Patent number: 4598108Abstract: The invention provides a water-reducible coating composition comprising an epoxy resin, an amino group-containing curing agent for the epoxy resin and a watersoluble organic compound which occurs in at least 2 tautomeric forms, in one of which a labile hydrogen atom is linked to a carbon atom and which compound contains at least one carbonyloxy group or sulfonyl group.Type: GrantFiled: June 27, 1985Date of Patent: July 1, 1986Assignee: Akzo NVInventor: Cornelis A. M. Hoefs
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Patent number: 4560716Abstract: Epoxy resin compositions including an epoxy resin, a hardener and an additive for forming a rust preventing film are provided. The additive is at least one selected from dithiophosphoric acids, dithiophosphoric acid derivatives, metal salts of dithiocarbamic acids and oxidized waxes. The composition may also include a secondary additive such as an organosilicon compound, an organoaluminum compound or an organotitanium compound for dithiophosphoric acid and/or dithiophosphoric acid derivative; an alkylarylsilsesquioxane silicone compound for a metal salt of dithiocarbamic acid; an alkylarylsilsesquioxane silicone compound, an organoaluminum compound, an organotitanium compound or an organotin compound for an oxidized wax. These epoxy resin compositions, when used as encapsulating materials, prevent moisture and impurities from penetrating into the surface of an encapsulated product because of the rust preventing film existing between the composition and the encapsulated product.Type: GrantFiled: August 24, 1984Date of Patent: December 24, 1985Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Shigeyuki Sato, Mitsumasa Matsushita
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Patent number: 4551488Abstract: A resinous protective coating useful in adhering plastics to metallic substrates. The protective coating is particularly useful as a solder mask and in the manufacture of printed circuit boards with circuit patterns having a resolution of at least 0.25 mm lines and spaces thereon. The protective coating comprises resins dissolved in solvents, wherein the coating, upon being subjected to heat, goes from a liquid or soft "gel-like" state into a solid phase without bleeding. The protective coating is resistant to copper, nickel and gold electroplating baths, adheres to insulating substrates, adhesive coated base materials as well as metallic substrates and is capable of withstanding the thermal shock of dip soldering.Type: GrantFiled: June 29, 1984Date of Patent: November 5, 1985Assignee: Kollmorgen Technologies CorporationInventors: Edward J. Leech, Frank D. Russo
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Patent number: 4535107Abstract: This invention is a method of treating polyester material for use in reinforcing rubber, the method being characterized by treating the polyester material with a treating liquid containing an epoxy compound and a melamine compound and subsequently heat treating the material at 100.degree.-250.degree. C.Type: GrantFiled: September 16, 1983Date of Patent: August 13, 1985Assignee: Unitika LimitedInventor: Shigemitsu Murase
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Patent number: 4476263Abstract: Certain alkali metal salts of organic diacids having one or more hydroxyl functional groups, as for example sodium and potassium citrate, provide improved adhesion of organic coatings electrodeposited on metal substrate. The new sanitary coatings are particularly useful for untreated aluminum and aluminum alloy cans used in the packaging of various food products including acidic foods like tomatoes, corn, and green beans which require in-can-sterilization.Type: GrantFiled: November 23, 1983Date of Patent: October 9, 1984Assignee: SCM CorporationInventor: Phillip M. Owens
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Patent number: 4447564Abstract: The compositions are anhydride-hardened epoxy resins which are filled with calcium-magnesium or calcium carbonate particles having a coating of a multibasic organic or inorganic acid bonded to the surfaces of the particles. Castings or moldings made therefrom, particularly electrical parts for SF.sub.6 technology, exhibit improved mechanical properties such as bending strength and impact strength.Type: GrantFiled: September 28, 1982Date of Patent: May 8, 1984Assignee: Siemens AktiengesellschaftInventor: Rudolf Grimmer
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Patent number: 4444924Abstract: The invention relates to a filled, resin composition and a method for the manufacture therefor. The composition is a matrix of an epoxy resin, a carbonate-containing filler, particularly calcium-magnesium carbonate or calcium carbonate, an anhydride hardener and an adhesive at 0.1 to 3.0 percent by weight, relative to the weight of the filler. The adhesive is a multibasic organic acid, an organic hydroxy acid such as malic acid or an amino acid. In the process, the adhesive can first be added to the hardener or to the filler containing resin before hardener is added.Type: GrantFiled: September 28, 1982Date of Patent: April 24, 1984Assignee: Siemens AktiengesellschaftInventor: Rudolf Grimmer
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Patent number: 4429068Abstract: A rubber material which is a cured rubber having a hardness of from 30.degree. as measured with an A-type rubber hardness tester to 15.degree. as measured with an F-type rubber hardness tester and an impact resilience of not less than 50%. The material has excellent vibration-proof, sound-proof, shock-absorbing or cushioning properties and is useful as a material for vibration-proof, sound-proof, shock-absorbing and cushioning members.Type: GrantFiled: November 19, 1981Date of Patent: January 31, 1984Assignee: Hohyu Rubber Co., Ltd.Inventor: Akitaro Nakahira
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Patent number: 4386173Abstract: This invention relates to a sprayable hot melt corrosion preventative composition and process for making the composition. The composition is characterized by comprising: (1) between about 10 and about 25 parts by weight of an epoxy resin elastomer adduct mixture, (2) between about 10 and about 25 parts by weight microcrystalline wax; and (3) between about 50 and about 80 parts by weight of a dispersion of petroleum sulfonate complex in nonvolatile diluent oil. The total weight of (1), (2) and (3) is 100 parts. The composition may additionally comprise up to about 20 parts by weight of optional materials such as pigments, fillers, and/or additional nonvolatile oil. The process for making the composition includes providing the adduct material which is maintained at an elevated temperature, blending the wax therein, heating the dispersion and adding thereto the adduct-wax mixture.Type: GrantFiled: April 23, 1982Date of Patent: May 31, 1983Assignee: Ford Motor CompanyInventor: Yun F. Chang
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Patent number: 4374220Abstract: Flame retardants having good stability at the processing temperatures of high melting polymers are described. The flame retardants are halogen-containing bis-imides, for example, those of the formula ##STR1## R being defined in the specification.Type: GrantFiled: May 14, 1981Date of Patent: February 15, 1983Assignee: Raychem CorporationInventor: Joseph Sonnenberg
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Patent number: 4338133Abstract: A jet printing ink composition comprises 2 to 60 wt.% of a binder precursor of an alkoxysilane having the formula R.sub.4-n Si(OH).sub.n (n=0 to 2; and R represents a C.sub.1 -C.sub.4 alkoxy group, methoxyethoxy, ethoxyethoxy or phenoxy group) or an oligomer thereof; and 25 to 95 wt.% of a solvent for said alkoxysilane or oligomer thereof; 0.001 to 5 wt.% of a solvent soluble acid; and 0.1 to 8 wt.% of a solvent soluble dyestuff, if necessary, further comprises up to 2 wt.% of a solvent soluble inert silicone oil for inhibiting blotting and up to 3 wt.% of an electroconductive agent.Type: GrantFiled: April 28, 1981Date of Patent: July 6, 1982Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Tsunehiko Toyoda, Tokio Matsumoto, Toshiaki Arakawa
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Patent number: 4331582Abstract: A catalyst for forming ambient temperature stable diamino-diphenyl sulfone-epoxy composition comprises the half-salt of a strong aromatic sulfonic acid such as toluene sulfonic acid and an imidazole, preferably an alkylated imidazole such as 2-ethyl-4-methylimidazole. The composition fully cures at moderate temperature to form a humidity resistant resin having a high heat distortion temperature and can be impregnated onto reinforcing fibers such as graphite to form composites.Type: GrantFiled: January 14, 1980Date of Patent: May 25, 1982Assignee: HitcoInventor: Eduard P. Babayan