Transition Metal Atom Patents (Class 523/515)
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Patent number: 8546490Abstract: A film comprising a polylactic acid and polypropylene blend having a haze of from about 10% to about 95% and a gloss 45° of from about 50 to about 125. A method of producing an oriented film comprising blending polypropylene and polylactic acid to form a polymeric blend, forming the polymeric blend into a film, and orienting the film. A method of producing an injection molded article comprising blending polypropylene and polylactic acid to form a polymeric blend, injecting the polymeric blend into a mold, and forming the article.Type: GrantFiled: March 12, 2013Date of Patent: October 1, 2013Assignee: Fina Technology, Inc.Inventors: Fengkui Li, Tim Coffy, Michel Daumerie
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Patent number: 8444905Abstract: A film comprising a polylactic acid and polypropylene blend having a haze of from about 10% to about 95% and a gloss 45° of from about 50 to about 125. A method of producing an oriented film comprising blending polypropylene and polylactic acid to form a polymeric blend, forming the polymeric blend into a film, and orienting the film. A method of producing an injection molded article comprising blending polypropylene and polylactic acid to form a polymeric blend, injecting the polymeric blend into a mold, and forming the article.Type: GrantFiled: July 30, 2012Date of Patent: May 21, 2013Assignee: Fina Technology, Inc.Inventors: Fengkui Li, Tim J. Coffy, Michel Daumerie
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Patent number: 8372917Abstract: A film comprising a polylactic acid and polypropylene blend having a haze of from about 10% to about 95% and a gloss 45° of from about 50 to about 125. A method of producing an oriented film comprising blending polypropylene and polylactic acid to form a polymeric blend, forming the polymeric blend into a film, and orienting the film. A method of producing an injection molded article comprising blending polypropylene and polylactic acid to form a polymeric blend, injecting the polymeric blend into a mold, and forming the article.Type: GrantFiled: July 30, 2012Date of Patent: February 12, 2013Assignee: Fina Technology IncInventors: Fengkui Li, Tim J. Coffy, Michel Daumerie
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Patent number: 8268913Abstract: A film comprising a polylactic acid and polypropylene blend having a haze of from about 10% to about 95% and a gloss 45° of from about 50 to about 125. A method of producing an oriented film comprising blending polypropylene and polylactic acid to form a polymeric blend, forming the polymeric blend into a film, and orienting the film. A method of producing an injection molded article comprising blending polypropylene and polylactic acid to form a polymeric blend, injecting the polymeric blend into a mold, and forming the article.Type: GrantFiled: June 30, 2008Date of Patent: September 18, 2012Assignee: Fina Technology, Inc.Inventors: Fengkui Li, Tim J. Coffy, Michel Daumerie
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Patent number: 7815727Abstract: A thermoplastic resin composition which comprises (A) 40 to 98 mass % thermoplastic resin and (B) 60 to 2 mass % titanium oxide particles whose surface has been coated with a hydrous oxide and/or oxide of at least one metal selected from the group consisting of aluminum, silicon, zirconium, tin, cerium, titanium, and zinc, wherein the titanium oxide particles contain 80 to 97 mass %, excluding 97 mass %, titanium oxide ingredient and have total content of alkali metal cations and alkaline earth metal cations extractable with pure water of 120 mass ppm or lower. The resin composition is excellent in reflectance and thermal stability in residence during molding into large products.Type: GrantFiled: November 5, 2003Date of Patent: October 19, 2010Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hiroshi Kawato, Yoshihiko Horio
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Publication number: 20080305363Abstract: Disclosed herein are pigments comprising mostly rutile TiO2, wherein the mostly rutile TiO2 consists essentially of low abrasion TiO2 particles produced by introducing a metal halide into the chloride process. Further disclosed are ink, can coatings, fibers, papers, and plastics comprising the pigment. Also disclosed herein are pigments comprising the low abrasion TiO2 pigments comprising TiO2 particles which have been further heat treated at a temperature of at least about 800° C. in an oxidizing atmosphere for a time period of at least about 1 hour.Type: ApplicationFiled: August 15, 2008Publication date: December 11, 2008Inventors: Michael Andrew Hofmann, Charles David Musick, Narayanan Sankara Subramanian, Kostantinos Kourtakis, Austin Henry Reid, JR.
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Patent number: 7256223Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.Type: GrantFiled: January 10, 2005Date of Patent: August 14, 2007Assignee: Michigan State University, Board of TrusteesInventors: Amar K. Mohanty, Lawrence T. Drzal, Brian P. Rook, Manjusri Misra
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Patent number: 6869985Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.Type: GrantFiled: November 26, 2002Date of Patent: March 22, 2005Assignee: AWI Licensing CompanyInventors: Amar Kumar Mohanty, Lawrence T. Drzal, Brian P. Rook, Manjusri Misra
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Patent number: 6673273Abstract: Electrolyte compositions for use in cells and batteries that include a crosslinked solid ionically conductive polymer having urethane groups, urea groups, thiocarbamate groups, or combinations thereof, particles, and a salt. Certain electrolyte compositions include a liquid thereby forming a gel electrolyte composition.Type: GrantFiled: October 24, 2001Date of Patent: January 6, 2004Assignee: 3M Innovative Properties CompanyInventors: Dinh Ba Le, Jerome Edward Scanlan, Ravindra L. Arudi
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Patent number: 6545068Abstract: A composition is provided which comprises a first component, a second component, and a compressible substance in which the first component comprises a peroxide, a liquid which comprises water, and a solid particulate; and the second component comprises a polymer, a crosslinking agent, and a solid particulate. The composition can further comprises a sugar. Also disclosed is a process that can be used for preventing a grouting composition from becoming limp. The process comprises combining a grouting composition with a compressible substance in which the composition comprises a first component and a second component as disclosed above.Type: GrantFiled: February 9, 2000Date of Patent: April 8, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Walter John Simmons, Domenic Joseph Barsotti, Phillip Edwin Gramlich
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Patent number: 6541545Abstract: An composition is provided which comprises a first component and a second component in which the first component comprises a peroxide, a liquid which comprises water, a sugar, and a solid particulate; and the second component comprises a polymer, a crosslinking agent, and a solid particulate. Also disclosed are processes for reducing fluid loss in a grouting composition and for anchoring a reinforcing member in a hole using the composition disclosed above.Type: GrantFiled: March 19, 1999Date of Patent: April 1, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Walter John Simmons, Domenic Joseph Barsotti
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Patent number: 6194492Abstract: Disclosed is an anisotropic conductive film which exhibits a conductivity in the thickness direction thereof by pressurizing the film in the thickness direction, the film including: an adhesive; and conductive particles dispersed in the adhesive; wherein the adhesive is a thermosetting or photosetting adhesive containing as a main component at least one kind selected from a group consisting of (a) a polymer obtained by acetalation of a polyvinyl alcohol, (b) a compound containing an allyl group, (c) a monomer containing an acryloxy group or methacryloxy group, and (d) a polymer obtained by polymerization of one or more selected from a group consisting of an acrylic monomer and a methacrylic monomer.Type: GrantFiled: June 5, 1998Date of Patent: February 27, 2001Assignee: Bridgestone CorporationInventors: Ryo Sakurai, Takahiro Matsuse, Hidefumi Kotsubo, Tetsuo Kitano, Yasuhiro Morimura
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Patent number: 6130273Abstract: The present invention discloses solventless composition suitable for application as a hot melt to a substrate, said composition comprising a mixture or alloy of resins, selected such that the averaged glass transition temperature (Tg) of the combined unreacted resins is greater than -30.degree. and less than +60.degree. C. The melt viscosity of the unreacted resins are selected so that the combined resin mix has a melt viscosity of from about 0.05 to 25 Poise when measured at 180.degree. C. and at a shear rate of 10,000 Hz.Type: GrantFiled: March 29, 1994Date of Patent: October 10, 2000Assignees: Taubmans Proprietary Limited, John Lysaght (Australia) LimitedInventors: Roger Owen Edwards, Gregory Ian Foster, Kevin Hilton Green, Garry Michael McKay
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Patent number: 6103810Abstract: This invention is directed to the preparation of alloy articles consisting essentially of glass and high temperature organic thermoplastic or thermosetting polymers having working temperatures which are compatible with that of the glass and/or the precursor glass for the glass-ceramic. The glass and polymer are combined at the working temperature to form an intimate mixture; i.e., the glass and polymer are in a sufficiently fluid state to be blended together to yield a body exhibiting an essentially uniform, fine-grained microstructure wherein, desirably, there is at least partial miscibility and/or a reaction between the glass and the polymer to promote adhesion and bonding therebetween. A body is shaped from the mixture and cooled to room temperature.Type: GrantFiled: June 27, 1997Date of Patent: August 15, 2000Assignee: Corning IncorporatedInventors: Paul D. Frayer, Roy J. Monahan, Michelle D. Pierson
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Patent number: 6063303Abstract: The present invention relates to a magnetic powder that contains resin-coated magnetic particles. The resin-coated magnetic particles include magnetic particles A and B that are formed in non-spherical shapes, with the magnetic particles A and B coated with a resin C. The resin-coated magnetic particles make it possible to increase the filling quantity of the magnetic particles A and B when the magnetic powder is employed to constitute a magnetic molded article, to ultimately improve the electromagnetic characteristics of the magnetic molded article.Type: GrantFiled: February 22, 1999Date of Patent: May 16, 2000Assignee: TDK CorporationInventor: Hitoshi Ohtaki
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Patent number: 5972421Abstract: A method for producing a pelletized pavement marking mixture includes selecting an appropriate thermoplastic binder that is a solid at ambient temperatures and heating the appropriate thermoplastic binder in a reaction vessel to a temperature sufficient to form a liquid thermoplastic binder; forming a heated pavement marking mixture by adding a plasticizer and a filler to the liquid thermoplastic binder in the reaction vessel; forming a substantially homogeneous pavement marking mixture by blending the heated pavement marking mixture for period sufficient to substantially evenly distribute the plasticizer and the filler within the liquid thermoplastic resin while maintaining the heated pavement mixture at an elevated temperature; extruding the substantially homogeneous pavement marking mixture from the reaction vessel to form an extruded substantially homogeneous pavement marking mixture; and pelletizing the extruded substantially homogeneous pavement marking mixture.Type: GrantFiled: November 12, 1998Date of Patent: October 26, 1999Assignee: Stimsonite CorporationInventor: Walter Brian Finley
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Patent number: 5932344Abstract: A cement retarder which comprises a saturated or unsaturated polyester obtained by a reaction of a polycarboxylic acid component comprising a polycarboxylic acid having 2 to 6 carbon atoms in the main chain or its derivative, and a polyol component containing a polyhydric alcohol having 2 to 4 carbon atoms or its condensate, wherein:(a) the saturated polyester has a weight average molecular weight of about 300 to about 50,000; or(b) the unsaturated polyester has a weight average molecular weight of about 500 to about 25,000; or(c) the polyhydric alcohol used to obtain the saturated or unsaturated polyester is a condensate of a C.sub.2-4 alkylene glycol; or(d) the saturated polyester is a polyester obtained by the use of a condensate of a C.sub.2-4 alkylene glycol and has a weight average molecular weight of about 300 to about 50,000; or(e) the unsaturated polyester is a polyester obtained by the use of a condensate of a C.sub.Type: GrantFiled: October 7, 1996Date of Patent: August 3, 1999Assignee: Daicel-Huels Ltd.Inventors: Yoshiyuki Ikemoto, Toru Ikuta
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Patent number: 5849817Abstract: The present invention relates to a metal pigment, comprising a particle, preferably a flake, of iron or an alloy thereof, having on its surface a colored coating, formed by exposing the said particle to an elevated temperature in an oxygen-containing atmosphere. The product finds use in surface coatings and in the mass coloration of plastics, especially where a colored "glitter" effect is required.Type: GrantFiled: November 7, 1997Date of Patent: December 15, 1998Assignee: Silberline LimitedInventors: William Innes Green, Jonathan Joseph Whistler Knox
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Patent number: 5843221Abstract: A sprayable, high solids, low-volatiles composition is provided which may be used as a coating on a variety of substrates. The sprayable filler composition comprises a first filler/glazing component formed from a mixture of a resin, a filler, a mixture of thixotropic clays, a phosphosilicate, and a first organic solvent. The coating also has a second organic solvent component as well as a second catalyst component. The coating as applied to a substrate has a thickness of up to 6 mils without sagging, running or cracking.Type: GrantFiled: August 4, 1997Date of Patent: December 1, 1998Assignee: Illinois Tool Works, Inc.Inventor: David Michael Parish
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Patent number: 5700856Abstract: A peroxide-generating composition for use in curing an unsaturated polyester resin and to the cured unsaturated polyester resin composition so prepared, particularly unsaturated polyester resin compositions containing inert filler materials used prepare a cast or molded product. The peroxide-generating composition comprises an allyl alcohol alkanoate, such as allyl alcohol propoxylate, which in the presence of a metal salt promoter, such as cobalt carboxylate, either with the allyl alcohol alkanoate or separately as a prepromoter in the unsaturated polyester resin composition provides for the generation from the allyl alcohol alkanoate of a peroxide to effect the in situ cure of the unsaturated polyester resin composition.Type: GrantFiled: April 10, 1996Date of Patent: December 23, 1997Assignee: Hehr International Inc.Inventor: Stuart B. Smith
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Patent number: 5691402Abstract: A vinyl ester resin/filler composite is disclosed which has a glass transition temperature of at least 315.degree. C. when cured. One version of the composite includes tabular alumina as a filler. Another version of the composite includes a powdered base nickel alloy as a filler. The composite is especially advantageous when used to build tools for use in plastic molding machines and processes.Type: GrantFiled: September 13, 1996Date of Patent: November 25, 1997Assignee: Composite Technology Group, LLCInventor: Richard M. Anders
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Patent number: 5591789Abstract: A paste composition having a high thermal conductivity and a relatively low viscosity is used to provide a thermal conductive connection between an electronic component and a cooling device to increase the heat transfer rate between the component and the device cooling the electronic component. The paste composition comprises a non-aqueous dielectric carrier, thermally conductive filler particles and a specially defined dispersant comprising the self-condensation reaction product of a hydroxy fatty acid, the reaction product having an acid number of about 30-100. A 12-hydroxy stearic acid self condensed reaction product is the preferred dispersant.Type: GrantFiled: June 7, 1995Date of Patent: January 7, 1997Assignee: International Business Machines CorporationInventors: Sushumna Iruvanti, Keith S. Olsen, Krishna G. Sachdev
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Patent number: 5425997Abstract: Curable and cured compositions having improved substrate adhesion, a method of providing a coating composition with improved substrate adhesion, a method of adhering a coating composition to a substrate, a method of providing a substrate with an adherent cured coating or film, and substrates with coatings or films formed from a cured composition are provided, wherein the coating composition comprises a fatty acid modified alkyd resin, a metal salt of an .alpha., .beta.-ethylenically unsaturated carboxylic acid and, optionally, an initiator and/or metal salt drying agent.Type: GrantFiled: February 25, 1994Date of Patent: June 20, 1995Assignee: Sartomer Company, Inc.Inventors: C. Richard Costin, Gary W. Ceska, Michael A. Bailey
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Patent number: 5399611Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.Type: GrantFiled: September 27, 1993Date of Patent: March 21, 1995Assignee: The Sherwin-Williams CompanyInventor: John Mathai
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Patent number: 5395866Abstract: A resin composition including a modified acrylic unsaturated polyester resin composition comprising a maleic dicyclopentadienyl glycol polyester which is dissolved in a mixture of styrene monomer and methylmethacrylate monomer. The maleic dicyclopentadienyl glycol polyester is the reaction product of a glycol or mixture of glycols, an ethylenically unsaturated polycarboxylic acid moiety and dicyclopentadiene. The glycol utilized as a reactant preferably has a structure defined by: H--(OCHR--CH.sub.2).sub.n --OH wherein R is H or CH.sub.3 and n is 1-10. The concentration of unsaturated polyester is preferably about 40 weight percent to about 75 weight percent in the resin composition. The concentration of styrene monomer ranges from about 5 weight percent to about 40 weight percent, while the concentration of methylmethacrylate monomer ranges from about 5 weight percent to about 45 weight percent.Type: GrantFiled: June 18, 1993Date of Patent: March 7, 1995Assignee: Interplastic CorporationInventors: Louis R. Ross, Matthew C. Kastl
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Patent number: 5374669Abstract: A sprayable, high solids, low-volatiles filler composition is provided which may be used as a coating on a variety of substrates. The sprayable filler composition comprises a first filler/glazing component formed from a mixture of a resin, a filler, a mixture of thixotropic clays, activated fumed silica, hollow glass microspheres, and a ketone solvent. The sprayable filler composition has a second catalyst component. The glazing/filler component is blended with the catalyst component, preferably either internally or externally of the spray nozzle, and the resultant sprayable filler composition is sprayed onto a substrate. The resulting cured coating provides a sandable surface which is corrosion resistant.Type: GrantFiled: May 26, 1993Date of Patent: December 20, 1994Assignee: Fibre Glass-Evercoat Company, Inc.Inventors: David M. Parish, Kenneth E. Lewis
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Patent number: 5373036Abstract: A sprayable, high solids, low-volatiles filler composition is provided which may be used as a coating on a variety of substrates. The sprayable filler composition comprises a first filler/glazing component formed from a mixture of a resin, a filler, a mixture of thixotropic clays, activated fumed silica, hollow glass microspheres, and a ketone solvent. The sprayable filler composition has a second catalyst component. The glazing/filler component is blended with the catalyst component, preferably either internally or externally of the spray nozzle, and the resultant sprayable filler composition is sprayed onto a substrate. The resulting cured coating provides a sandable surface which is corrosion resistant.Type: GrantFiled: January 18, 1994Date of Patent: December 13, 1994Assignee: Fibre Glass-Evercoat Company, Inc.Inventors: David M. Parish, Kenneth E. Lewis
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Patent number: 5367012Abstract: This invention is directed to an alloy, and a method of producing an alloy, of increased resistance to moisture, comprising a melt mixture of at least one phosphate glass, at least one organic thermoplastic or thermosetting polymer, and an amount of a water soluble stabilizer component which provides a source of metal cations having a valency of 2.sup.+ or higher The amount of the stabilizer component added is that amount effective to improve the alloy's resistance to moisture. Preferably, the alloy is comprised of: (a) 5-80% of the matrix material; (b) 15-90% of the phosphate glass; and, (c) 0.1 to 40% of the stabilizer component. Additionally, the metal cations which are found in the stabilizer component and which form part of the insoluble surface layer are preferably selected from the group consisting of Ba.sup.2+, Mg.sup.2+, Ca.sup.2+, Al.sup.3+, Zn.sup.2+, Sr.sup.+2 and Fe.sup.3+.Type: GrantFiled: August 9, 1993Date of Patent: November 22, 1994Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Dana C. Bookbinder, James E. Dickinson, Jr., Brent M. Wedding
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Patent number: 5236973Abstract: An electrical insulator including a thermosetting matrix and a filler composed primarily of powdered material embedded in the thermosetting matrix. The insulator has a high service life in spite of severe mechanical stressing at temperatures of up to 105.degree. C. This is achieved as a result of the thermosetting matrix having a glass transition temperature exceeding 140.degree. C. and the inclusion of a powdered filler, which has a reduced rigidity compared with the thermosetting matrix, embedded in the thermosetting matrix.Type: GrantFiled: April 2, 1992Date of Patent: August 17, 1993Assignee: Asea Brown Boveri Ltd.Inventors: Anton Demarmels, Leopold Ritzer
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Patent number: 5236975Abstract: Disclosed is a concrete non-cure material for preventing the surface of cement mortar, which maintains contact with said material, from setting or hardening. This invention also discloses a concrete product or concrete structure with surface decorations produced by affixing the concrete non-cure material to the surface of the decorative material or to the inner surface of a form for a concrete molding and production methods therefor.Type: GrantFiled: October 24, 1991Date of Patent: August 17, 1993Assignee: Kabushiki Kaisha ZokeiInventor: Sukeyoshi Sekine
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Patent number: 5126075Abstract: Material for a housing of electronic components, a compound of synthetic resin, which contains ferrite powder and carbon fiber, is bestowed with original properties of the synthetic resin, such as lightness and freedom of molding, high permeability brought by ferrite powder, and high conductivity and mechanical properties by a designated carbon fiber. The material is made into a light housing with various shapes by injection molding or vacuum molding. The housing concentrates on its surface magnetic flux from external low-frequency field and shields the electronic components from electromagnetic wave noise and low-frequency magnetic field, preventing electromagnetic troubles of the electronic components.Type: GrantFiled: October 27, 1989Date of Patent: June 30, 1992Assignee: Kitogawa Industries Co., Ltd.Inventor: Asaharu Nakagawa
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Patent number: 5082878Abstract: New shrinkage control agents, for unsaturated polyester resin systems, which are copolymers of vinyl versatate and vinyl acetate, i.e., poly(vinyl versatate-co-vinyl acetate). The shrink control agents are useful both with neat and filled unsaturated polyester resin systems. The shrink control agents are especially useful under conditions where the unsaturated polyester resin system is cured at or below ambient temperatures.Type: GrantFiled: December 27, 1990Date of Patent: January 21, 1992Assignee: W.R. Grace & Co.-ConnInventors: Donald A. Bansleben, Joseph M. Daly, Emil Zavadsky
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Patent number: 5063258Abstract: Coating compositions which do not contain metal powders and which contain, as coloring component, 0.001 to 30% by weight of at least one organic pigment and/or of a polymer-soluble dye and/or of a pearlescent pigment and 0.001 to 30% by weight of molybdenum disulfide, based on the coating produced therewith, are suitable, for example, for coloring surfaces, especially metal surfaces.Type: GrantFiled: September 5, 1989Date of Patent: November 5, 1991Assignee: Ciba-Geigy CorporationInventor: Fridolin Babler
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Patent number: 5045575Abstract: A method of improving the flowability and reducing voids in liquid synthetic thermosetting resins precursor compositions used to pot structures such as a honeycomb core or electronic parts and assemblies. Up to about 0.50 weight percent of a suitable titanate coupling agent is mixed with the liquid resin precursor, preferably in a vacuum or an inert atmosphere, any necessary hardener is added later to the premixed resin with the agent, then the resin is poured into a mold holding the structure to be potted. The titanate coupling agents have the general formula: ##STR1## where: R is an alkoxy, alkyl, alkenyl, alkynyl or aralkyl group having from 1 to about 30 carbon atoms or a substituted derivative thereof;M is zirconium or titanium; andR is independently an aryl, aralkyl, alkaryl, alkyl or alkeno group having from 1 to about 30 carbon atoms.Type: GrantFiled: December 18, 1989Date of Patent: September 3, 1991Assignee: General Dynamics Corporation, Convair divisionInventor: Solomon M. Gabayson
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Patent number: 5035836Abstract: A solid lubricated resistive ink includes solid lubricants which provide self-lubrication of the resistive ink under high vacuum and low moisture conditions. The resistive inks include a polymer-based binder and an electrically conductive solid lubricant which remains electrically conductive and lubricative under low moisture and high vacuum. Effective lubricants include MoSe.sub.2, NbSe.sub.2 graphite intercalated with bromine and graphite intercalated with a metal chloride. The resistive ink may additionally include carbon.Type: GrantFiled: June 19, 1989Date of Patent: July 30, 1991Assignee: Hughes Aircraft CompanyInventors: Michael N. Gardos, Larry C. Lipp, William S. Griffin
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Patent number: 4829106Abstract: Molding materials having a long shelf life consist of an unsaturated polyester resin, monomers, conventional additives and an inhibitor combination comprising a phenol or quinone, a phosphine or an ester of phosphorous acid, and a metal cation in the form of a salt or a complex which is soluble in the polyester resin.Type: GrantFiled: September 16, 1987Date of Patent: May 9, 1989Assignee: BASF AktiengesellschaftInventors: Jan Holoch, Alfred Guthmann, Hans-Juergen Christoph, Heinz B. Kemper
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Patent number: 4757036Abstract: Homogeneous, nonporous ceramic fibers containing at least one magnetically-unaligned, microcrystaline transition metal oxide spinel phase. The ceramic fibers may be used in polymeric, ceramic and metallic composites. Said ceramic spinel is produced by dispersing soluble inorganic and transition metal compounds in an aqueous mixture, concentrating to produce a viscous concentrate, shaping into the desired article, gelling the shaped article, and heating to produce the transition metal spinel article. Beads, bubbles, flakes, microspheres, films and granules may be made as well as fibers.Type: GrantFiled: September 14, 1987Date of Patent: July 12, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: David R. Kaar, Harold G. Sowman
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Patent number: 4690960Abstract: A vibration damping material having an improved mechanical strength and excellent vibration damping characteristic is disclosed.The material is made by usage of composition of 40 to 90 weight percent of iron oxide particles 0.1 to 100 .mu.m in size and 60 to 10 weight percent of resin.Type: GrantFiled: January 14, 1985Date of Patent: September 1, 1987Assignee: Nippon Electric Co., Ltd.Inventors: Fumio Yamauchi, Tsutomu Tohara, Shigeo Nakano, Shigeo Emoto
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Patent number: 4579890Abstract: Described herein are curable molding compositions comprising a mixture of:(a) an unsaturated polyester;(b) acrylic or methacrylic acid or a functionalized derivative thereof having a molecular weight of less than 300;(c) an ethylenically unsaturated monomer which is soluble in and copolymerizable with (a) and (b) and which is different from (b); and(d) one or more fibers with a melting point or a glass transition temperature above about 130.degree. C.Type: GrantFiled: October 27, 1983Date of Patent: April 1, 1986Assignee: Union Carbide CorporationInventor: Linda A. Domeier
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Patent number: 4555534Abstract: There is disclosed thickened, low shrinkage polyester molding compositions having improved pigmentation. The improved pigmentation in thickenable polyester molding compositions containing a carboxylated vinyl ester polymer low profile additive is achieved either by incorporating a surfactant in the composition, by using as the low profile additive a vinyl acetate/maleic acid copolymer, or by a combination of the two methods.Type: GrantFiled: September 23, 1982Date of Patent: November 26, 1985Assignee: Union Carbide CorporationInventor: Kenneth E. Atkins
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Patent number: 4522879Abstract: A two-package air-drying coating system resistant to strong organic solvents, free from toxic heavy metals and excellent, for example, as a primer for adhering urethanes or epoxy enamels to previously painted steel, is based upon a rheologically desirable mixture of (1) plate-like filler, e.g., talc, (2) carbon black, and (3) barium lanolate with a binder composed of a polyol and a polyisocyanate crosslinking agent.Type: GrantFiled: January 26, 1984Date of Patent: June 11, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventor: Achim R. Krueger
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Patent number: 4501829Abstract: A coating composition comprising (A) a polyester resin modified with a lactone having 6 to 8 ring carbon atoms (I) or a mixture of said lactone-modified polyester resin (I) and a non-modified polyester resin (II), the lactone content being from 5 to 40% by weight of the total polyester resin (in solid) (I) or (I+II), the number average molecular weight being 800.about.200 mg KOH/g and wherein the resinous acid value is 2.about.20 mg KOH/g, (B) a crosslinking agent, (C) a pigment and (D) optionally other resins. The composition is useful as an intercoat paint for automobile bodies.Type: GrantFiled: September 6, 1983Date of Patent: February 26, 1985Assignee: Nippon Paint Co., Ltd.Inventors: Shoji Oda, Kunihiko Ehara, Hirotoshi Umemoto, Shinji Nakano
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Patent number: 4491642Abstract: There is disclosed thickened, low shrinkage polyester molding compositions having improved pigmentation. The improved pigmentation in thickenable polyester molding compositions is achieved by using as the low profile additive a vinyl acetate/maleic acid copolymer, and optionally incorporating a surfactant in the composition.Type: GrantFiled: April 25, 1984Date of Patent: January 1, 1985Assignee: Union Carbide CorporationInventor: Kenneth E. Atkins
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Patent number: 4479891Abstract: This manufacturing process consists in forming a passivation layer on manganese pigments and thereafter mixing the latter with a resin to form a paint. This paint is electrically conductive since the passivation layer is based on chromate, Mn/Fe phosphate or Zn phosphate. These pigments preferably have a degree of purity equal to or greater than 99.9%.Type: GrantFiled: June 8, 1983Date of Patent: October 30, 1984Assignee: Battelle Development CorporationInventors: Michel Kornmann, Yehuda Talmor
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Patent number: 4469714Abstract: This invention provides a composition comprising about 15 to about 75% by weight of a thermosetting or ultraviolet-curable resin, about 24.5 to about 84.5% by weight of finely divided heat-resistant inorganic substance and about 0.5 to about 20% by weight of a finely divided palladium catalyst. This composition is the solvent-free type and useful for forming an electroconductive metal coating on an electrically nonconductive base material by chemical plating.Type: GrantFiled: September 2, 1983Date of Patent: September 4, 1984Assignee: Okuno Chemical Industry Co., Ltd.Inventors: Masatoshi Wada, Nobuyuki Konaga, Kenichi Nishiwaki, Yasuhiro Kobori
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Patent number: 4463117Abstract: A heat-stable, polymer-forming composition of a polymerizable material, a transition metal compound, a polymer chain terminator, and, optionally, a preventive antioxidant is disclosed as well as particular uses of such composition.Type: GrantFiled: April 19, 1982Date of Patent: July 31, 1984Assignee: Technicon Instruments CorporationInventor: Michael J. Malin
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Patent number: 4362626Abstract: An adsorbent, which is prepared by subjecting to curing a mixture consisting of (a) one part by weight of at least one member selected from the group consisting of titanium oxide hydrate, zirconium oxide hydrate and tin oxide hydrate and of (b) about 1/10 to 3 parts by weight of an epoxy, unsaturated polyester or polyurethane resin.The adsorbent can be used as an adsorbent for a great variety of anions and cations and especially as the adsorbent for phosphate ion.The adsorbent displays also improved chemical resistance, resistant to acids and alkalis, and can be subjected to repeated desorption and regeneration procedures without causing any deterioration of its adsorptive capacity, thus permitting the repeated usage over a long period of time.Type: GrantFiled: August 12, 1980Date of Patent: December 7, 1982Assignee: Takeda Chemical Industries, Ltd.Inventors: Tatsuro Takeuchi, Masaki Sokukawa, Ryuzo Kimoto
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Patent number: 4352897Abstract: A resin molded stator comprising a stator core and coils as major constituents at least parts of which are molded into one piece by a molding material, said molding material comprising (a) a low-shrink unsaturated polyester resin, (b) a filler having a particle size of 44 .mu. or less, and (c) a fibrous material having a length of 3 mm or less, in proportions of 15 to 40% by weight of the component (a) and 60 to 85% by weight of a total of the components (b) and (c), and a weight ratio of the component (b) to the component (c) being 3/1 to 30/1, is excellent in crack resistance, moisture resistance and insulating properties.Type: GrantFiled: December 14, 1979Date of Patent: October 5, 1982Assignee: Hitachi, Ltd.Inventors: Masatsugu Ogata, Hirokazu Takasaki, Masanori Nemoto, Toshikazu Narahara, Kenichi Hironaka, Tetuo Ishikawa
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Patent number: 4346050Abstract: Improved polymer bonded concrete is disclosed wherein the amount of polymer binder used may be reduced to amounts as low as 3 to 10% by weight of the concrete. The concrete has however high strength and other improved properties such as high modulus of elasticity, low thermal expansion and contraction, better fire resistance, low shrinkage on curing and the like and also very importantly, the cost is reduced. Preparation of the concrete is disclosed using an in situ polymerization process together with intense vibration of the monomer component-solids mix.Type: GrantFiled: December 17, 1980Date of Patent: August 24, 1982Assignee: Plastibeton Canada Inc.Inventors: Peter F. Trent, Raymond Charlebois