Two Or More Phosphorus Rings Patents (Class 524/119)
  • Patent number: 11248087
    Abstract: A type of cationic dyeable polyester fiber and preparing method thereof are disclosed. The preparing method is to manufacture a fiber from a cationic modified polyester through a fully drawn yarn (FDY) process, wherein the cationic modified polyester is composed of terephthalic acid segments, ethylene glycol segments, sodium salt of diethylene ester of 5-sulfoisophthalic acid segments and tert-butyl branched diol segments and a molecular formula of tert-butyl branched diol is as following: The cationic modified polyester is further dispersed with a high temperature calcined solid heteropolyacid. A final fiber has a dye uptake of 87.8-92.2% and a K/S value of 23.27-25.67 when dyed at 120° C., as well as an intrinsic viscosity drop of 13-17% when stored at 25° C. and R.H. 65% for 60 months.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: February 15, 2022
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Lili Wang, Xiaoyu Wang, Fangming Tang
  • Patent number: 11111369
    Abstract: The present invention is directed to a polypropylene composition (C) comprising a heterophasic propylene copolymer and an inorganic filler, the use of said polypropylene composition (C) for the production of a foamed article and a foamed article obtained from said polypropylene composition (C).
    Type: Grant
    Filed: November 28, 2017
    Date of Patent: September 7, 2021
    Assignee: BOREALIS AG
    Inventors: Susanne Kahlen, Daniela Mileva, Georg Grestenberger, Michael Tranninger, Michael Jerabek, Dieter Nicolussi, Anna Hartl
  • Patent number: 10689512
    Abstract: A resin composition is provided. The resin composition comprises the following: (a) a resin system, which comprises a thermosetting resin constituent and a vinyl-containing elastomer and has a dissipation factor (Df) of not higher than 0.008 at 10 GHz after curing; and (b) a phosphorous-containing flame retardant, which is a compound of formula (I), a compound of formula (II), or a combination thereof: wherein R1, R2, R21, R22, R23, R24, and n are as defined in the specification.
    Type: Grant
    Filed: April 25, 2017
    Date of Patent: June 23, 2020
    Assignee: TAIWAN UNION TECHNOLOGY CORPORATION
    Inventors: Shur-Fen Liu, Meng-Huei Chen
  • Patent number: 10442758
    Abstract: There is provided as a biocide zinc or copper (II) salt having the general formula CH2?C(R1)COO-M-OCOC6H3R2R4, wherein M is Zn or Cu, R1 is selected from the group comprising hydrogen and methyl, R2 is selected from the group comprising hydrogen and OH, R4 is selected from the group comprising hydrogen, alkyl and SO2OH group.
    Type: Grant
    Filed: April 1, 2016
    Date of Patent: October 15, 2019
    Assignee: LABORATORIYA BIO ZET, LLC
    Inventors: Igor I. Zotkin, Nadezhda V. Kuznetsova, Larisa V. Kabanova
  • Patent number: 10385191
    Abstract: The present disclosure provides a filled composition made from and/or containing (A) a first polymer composition made from and/or containing (i) a heterophasic polypropylene copolymer and (ii) a polypropylene blend, and (B) a biofiller composition made from and/or containing a cellulose-based biofiller. The filled composition can additionally be made with and/or contain an elastomeric ethylene copolymer composition. Optionally, the filled composition can further be made with and/or contains a grafted polyolefin composition. The filled composition is useful in making automotive components.
    Type: Grant
    Filed: April 26, 2017
    Date of Patent: August 20, 2019
    Assignee: Equistar Chemicals, LP
    Inventors: Changlai Yang, Dongman Choi
  • Patent number: 9777142
    Abstract: The present invention relates to a polyolefin composition comprising two heterophasic propylene copolymers which differ in the intrinsic viscosity of their xylene soluble fractions.
    Type: Grant
    Filed: August 18, 2014
    Date of Patent: October 3, 2017
    Assignee: BOREALIS AG
    Inventors: Martina Sandholzer, Susanne Kahlen, Georg Grestenberger
  • Patent number: 9181423
    Abstract: Polypropylene composition comprising (a) a high melt strength polypropylene having a melt flow rate MFR2 (230° C.) of equal or below 15 g/10 min and a branching index g? of below 1.0, (b) a first heterophasic propylene copolymer comprising a polypropylene having a melt flow rate MFR2 (230° C.) in the range of 50 to 500 g/10 min and an elastomeric propylene copolymer having a propylene content in the range of 50 to 80 wt.-% and an intrinsic viscosity (IV) of equal or more than 2.5 dl/g, (c) a second heterophasic propylene copolymer comprising a random propylene copolymer having a melt flow rate MFR2 (230° C.) in the range of 1 to 40 g/10 min, a branching index g? of 1.0, and a comonomer content of more than 0.5 wt.-%, and an elastomeric propylene copolymer having a propylene content in the range of 50 to 80 wt.-%, and an intrinsic viscosity (IV) of equal or below 2.4 dl/g, (d) a polyethylene plastomer having an ethylene content of at least 50 wt.-%, and (e) a mineral filler (F).
    Type: Grant
    Filed: August 25, 2011
    Date of Patent: November 10, 2015
    Assignee: Borealis AG
    Inventors: Cornelia Kock, Christelle Grein, Tonja Schedenig
  • Publication number: 20150105505
    Abstract: Varnishes useful in manufacturing prepregs and laminates including at least one polymer selected from the group consisting of polyphenylene ether, polyphenylene oxide and combinations thereof; at least on reactive monomer; and at least one initiator.
    Type: Application
    Filed: October 15, 2014
    Publication date: April 16, 2015
    Inventors: Guroen He, Tarun Amla
  • Publication number: 20150051327
    Abstract: The main objection of the present invention is to provide a halogen-free flame retardant for resins which has a high heat resistance and is capable of exhibiting excellent flame retardance while maintaining a good transparency. The present invention provides a flame retardant for resins which includes a condensed phosphonic acid ester having a specific chemical structure, a flame-retarded resin composition containing the same, and a molded article made from the composition.
    Type: Application
    Filed: July 26, 2012
    Publication date: February 19, 2015
    Applicant: MARUBISHI OIL CHEMICAL CO., LTD.
    Inventors: Junichi Kobayashi, Akira Ishikawa, Kai Miwa, Shigeto Iguchi
  • Publication number: 20150031805
    Abstract: Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants.
    Type: Application
    Filed: July 22, 2014
    Publication date: January 29, 2015
    Applicant: CHEMTURA CORPORATION
    Inventors: Zachary D. Stockdale, Mark V. Hanson, Larry D. Timberlake, Subramaniam Narayan, William R. Fielding
  • Publication number: 20140316032
    Abstract: The present invention relates to the use of aromatic P—N-compounds in flame retardant polymer compositions. These compositions are especially useful for the manufacture of flame retardant compositions based onthermoplastic polymers, especially polyolefin homo- and copolymers, polycondensates, such as polyamines or polyesters and duroplastic polymers, such as polyepoxides.
    Type: Application
    Filed: November 8, 2012
    Publication date: October 23, 2014
    Applicant: BASF SE
    Inventors: Rainer Xalter, Michael Roth, Manfred Doering, Ciesielski Michael, Sebastian Wagner
  • Publication number: 20140088227
    Abstract: It is described a colouring composition for thermoplastic polymers comprising the product of reaction of an organic dye with one or more polymer additives selected from an aromatic phosphate metal salt, a hindered phenol antioxidant and a salt of a fatty acid. It is disclosed also a process for preparing and using such composition.
    Type: Application
    Filed: May 7, 2012
    Publication date: March 27, 2014
    Applicant: Trading and Marketing Consultants Palmarole AG
    Inventors: Giampaolo Guerani, Gerard Palmarole
  • Patent number: 8536256
    Abstract: This invention relates to 9,10-Dihydro-9-Oxa-10-Phosphaphenantrene-10-oxide derived additive flame-retardants, which are useful in epoxy resin compositions. The epoxy resin compositions may be used in making prepregs or laminates for printed wiring boards and composite materials.
    Type: Grant
    Filed: May 19, 2010
    Date of Patent: September 17, 2013
    Assignee: Albemarle Corporation
    Inventors: Kimberly M. White, Yu Li Angell, Scott E. Angell, Arthur G. Mack
  • Publication number: 20130203908
    Abstract: Polypropylene composition comprising (a) a high melt strength polypropylene having a melt flow rate MFR2 (230° C.) of equal or below 15 g/lOmin and a branching index g? of below 1.0, (b) a first heterophasic propylene copolymer comprising a polypropylene having a melt flow rate MFR2 (230° C.) in the range of 50 to 500 g/lOmin and an elastomeric propylene copolymer having a propylene content in the range of 50 to 80 wt.-% and an intrinsic viscosity (IV) of equal or more than 2.5 dl/g, (c) a second heterophasic propylene copolymer comprising a random propylene copolymer having a melt flow rate MFR2 (230° C.) in the range of 1 to 40 g/lOmin, a branching index g? of 1.0, and a comonomer content of more than 0.5 wt.-%, and an elastomeric propylene copolymer having a propylene content in the range of 50 to 80 wt.-%, and an intrinsic viscosity (IV) of equal or below 2.4 dl/g, (d) a polyethylene plastomer having an ethylene content of at least 50 wt.-%, and (e) a mineral filler (F).
    Type: Application
    Filed: August 25, 2011
    Publication date: August 8, 2013
    Applicant: BOREALIS AG
    Inventors: Cornelia Kock, Christelle Grein, Tonja Schedenig
  • Publication number: 20130123401
    Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.
    Type: Application
    Filed: January 9, 2013
    Publication date: May 16, 2013
    Applicant: Dow Global Technologies LLC
    Inventor: Dow Global Technologies LLC
  • Publication number: 20130072586
    Abstract: Disclosed are compositions comprising antioxidants and stabilizers, such as, acid scavengers or organic phosphorus stabilizers, and optionally further comprising co-stabilizers. The disclosed compositions are useful as stabilizers for polyolefins and other polymeric materials. The disclosed compositions and methods generally provide longer shelf lifes and better oxidative resistance to materials than currently available antioxidants.
    Type: Application
    Filed: August 23, 2012
    Publication date: March 21, 2013
    Applicant: Polnox Corporation
    Inventors: Vijayendra Kumar, Rajesh Kumar, Ashish Dhawan, Sui-Zhou Yang, Ashok L. Cholli
  • Patent number: 8357324
    Abstract: The present invention relates to a process for the production of polyethylene hollow articles, which process comprises charging the polyethylene with one or more NO-acyl hindered amine additives containing one or more groups of formula (I), filling this mixture into a mold, heating this mold in an oven to above 280° C., such that the additized polyethylene melts, rotating the mold around at least 2 axes, the additized polyethylene spreading to the walls, cooling the mold while still rotating, opening it, and taking the resultant hollow article out, where the group of formula (I) is where Ra is a monoacyl or diacyl radical; R1-R4 are each C1-C6alkyl; and R5 and R6 are each, independently of one another, hydrogen, C1-C6alkyl or C6-C10aryl; or R5 and R6 are together oxygen.
    Type: Grant
    Filed: April 19, 2010
    Date of Patent: January 22, 2013
    Assignee: BASF SE
    Inventors: Jiong Yu, John Sigler, Eric Wallis
  • Publication number: 20130012630
    Abstract: The present invention provides a granulated resin additive composition which comprises an aromatic metal phosphate salt and a phenolic antioxidant and, when blended in a resin, allows the resulting resin composition to have excellent mechanical strengths and transparency. The granulated resin additive composition is characterized by comprising a phosphate salt compound represented by the Formula (I): (wherein, R1, R2, R3 and R4 each independently represent a hydrogen atom or a C1 to C8 alkyl group which is optionally branched; X represents a direct bond or a C1 to C4 alkylidene group; M represents an alkali metal, an alkaline earth metal or aluminum; n represents an integer of 1 to 3; and m represents 0 or 1), a phenolic antioxidant and a fatty acid calcium salt, in which granulated resin additive composition the content of the fatty acid calcium salt is 1 to 6 parts by mass with respect to 100 parts by mass of the granulated resin additive composition.
    Type: Application
    Filed: March 29, 2011
    Publication date: January 10, 2013
    Applicant: ADEKA CORPORATION
    Inventors: Tomonori Shimizu, Naoko Tanji, Atsushi Sakai
  • Publication number: 20120214906
    Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.
    Type: Application
    Filed: May 3, 2012
    Publication date: August 23, 2012
    Applicant: Dow Global Technologies LLC
    Inventor: Joseph Gan
  • Patent number: 8236881
    Abstract: The present invention relates to flame retardant polymer compositions which comprise mixtures of phosphinic acid salts and dihydro-oxa-phospho-phenantrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polycondensates like polyesters, polyamides and polycarbonates.
    Type: Grant
    Filed: December 20, 2011
    Date of Patent: August 7, 2012
    Assignee: BASF SE
    Inventor: Michael Roth
  • Patent number: 8222329
    Abstract: Disclosed herein is a symmetric cyclic phosphonate compound represented by the following Formula 1, a method of preparing the same and a flame retardant styrenic resin composition including the same: wherein R1 and R2 are each independently hydrogen, C1-C6 alkyl or C6-C20 aryl. The styrene resin composition employing the symmetric cyclic phosphonate compound exhibits good flame retardancy and impact strength, does not release halide gas during preparation or combustion of the resin composition, and thus is environmentally friendly.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: July 17, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Beom Jun Joo, Sang Hyen Hong, Min Soo Lee, Byun Kun Lee
  • Publication number: 20120095140
    Abstract: The present invention relates to flame retardant polymer compositions which comprise mixtures of phosphinic acid salts and dihydro-oxa-phospho-phenantrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polycondensates like polyesters, polyamides and polycarbonates.
    Type: Application
    Filed: December 20, 2011
    Publication date: April 19, 2012
    Inventor: MICHAEL ROTH
  • Patent number: 8101678
    Abstract: The present invention relates to flame retardant polymer compositions which comprise mixtures of phosphinic acid salts and dihydro-oxa-phospho-phenantrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polycondensates like polyesters, polyamides and polycarbonates.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: January 24, 2012
    Assignee: BASF SE
    Inventor: Michael Roth
  • Patent number: 8093316
    Abstract: Disclosed are polymer blends comprising a mixture of (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a metallic catalyst; (B) at least one phosphite ester compound; and (C) at least one hindered amine light stabilizer. The polymer blends exhibit improved color, especially when used as a component of a polyester/polycarbonate blend.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: January 10, 2012
    Assignee: Eastman Chemical Company
    Inventors: Jason Clay Pearson, Douglas Stephens McWilliams, Gether Irick, Jr., Max Allen Weaver
  • Patent number: 8058332
    Abstract: Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X? is independently oxygen or sulfur, each m is independently zero or 1 when X? is oxygen and zero, 1 or 2 when X? is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: November 15, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Ravi B. Shankar, David R. Wilson, William J. Kruper, Bruce A. King, Michelle L. Hudack, Chun Wang, Ted A. Morgan, Inken Beulich, Daniel J. Murray, William Gerald Stobby, Mark W. Beach, Ing Feng Hu
  • Publication number: 20110160365
    Abstract: A flame retardant polycarbonate resin composition of the present invention comprises: (A) about 30 to about 100% by weight of a polycarbonate resin; (B) about 0 to about 70% by weight of a rubber modified aromatic vinyl based copolymer resin; and (C) about 0.1 to about 40 parts by weight of a phosphorous compound or a combination of phosphorus compounds represented by the following Chemical Formula (I), per 100 parts by weight of a base resin comprising (A) and (B). The flame retardant polycarbonate resin composition of the present invention can have excellent flame retardancy and heat resistance. wherein R1, R2, R3, and R4 are each independently hydroxyl, phenol, phenyl, or C1-C4 alkyl; and n is an integer of 1 to 10.
    Type: Application
    Filed: December 28, 2010
    Publication date: June 30, 2011
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Seon Ae Lee, Im Hyuck Bae, Beom Jun Joo
  • Patent number: 7915374
    Abstract: Processes for producing polyethylene terephthalate copolyesters are disclosed, that include the steps of: esterifying a mixture of at least terephthalic acid, from 20 mole percent to 45 mole percent 1,4-cyclohexanedimethanol, and ethylene glycol, optionally in the presence of one or more alkaline earth metals or alkali metals, to form an oligomer; polycondensing the oligomer in the melt phase in the presence of aluminum and one or more alkaline earth metals or alkali metals, to obtain a copolyester having an intrinsic viscosity of at least 0.5 dL/g; and thereafter adding to the copolyester a phosphorus-containing compound.
    Type: Grant
    Filed: April 27, 2009
    Date of Patent: March 29, 2011
    Assignee: Eastman Chemical Company
    Inventors: Jason Christopher Jenkins, Gary Wayne Connell, Howard Smith Carman, Jr., Douglas Weldon Carico, Jr., Jimmy Ray Trotter, Alan Wayne White, Mary Therese Jernigan, Rodney Scott Armentrout
  • Publication number: 20110054078
    Abstract: Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H—P?O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R?(Y)m?]m(X—O—R?)n ??Formula (I) wherein R? is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R? is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m?, m and n are, independently, numbers equal to or greater than 1; and (C) a thermosetting or thermoplastic composition. These compounds are useful for making flame retardant epoxy and polyurethane resins and ignition resistant thermoplastic resins, each of which is useful for a variety of end uses requiring flame retardancy or ignition resistance.
    Type: Application
    Filed: November 4, 2010
    Publication date: March 3, 2011
    Applicant: Dow Global Technologies Inc.
    Inventor: Joseph Gan
  • Patent number: 7893135
    Abstract: The present invention relates to compositions comprising A) aromatic polycarbonate, B) polyalkylene terephthalate and C) a concentrate comprising polyalkylene terephthalate and at least one compound selected from the group consisting of ortho-phosphoric acid, phosphorous acid, carboxylic acid esters of ortho-phosphoric acid and carboxylic acid esters of phosphorous acid, Compositions of the present invention are distinguished by high melt stability. The present invention also relates to a process for the preparation of impact-modified polyalkylene terephthalate/polycarbonate compositions, wherein a concentrate of polyalkylene terephthalate with a phosphorus-containing additive is used.
    Type: Grant
    Filed: March 20, 2009
    Date of Patent: February 22, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Pierre Moulinie, Ralf Hufen, Stephan Konrad, Dieter Wittmann
  • Publication number: 20110034573
    Abstract: Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X? is independently oxygen or sulfur, each m is independently zero or 1 when X? is oxygen and zero, 1 or 2 when X? is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.
    Type: Application
    Filed: October 18, 2010
    Publication date: February 10, 2011
    Inventors: Ravi B. Shankar, David R. Wilson, William J. Kruper, Bruce A. King, Michelle L. Hudack, Chun Wang, Ted A. Morgan, Inken Beulich, Daniel J. Murray, William Gerald Stobby, Mark W. Beach, Ing Feng Hu
  • Publication number: 20110009539
    Abstract: The invention relates to a flameproof PMMA moulding material, mouldings produced therefrom and the use thereof. Small amounts of an organo-phosphorus compound are sufficient to increase the glow wire flammability index by 300° C.
    Type: Application
    Filed: February 26, 2009
    Publication date: January 13, 2011
    Applicant: EVONIK ROEHM GMBH
    Inventors: Thorsten Goldacker, Klaus Koralewski, Michael Wicker
  • Publication number: 20100298475
    Abstract: The present invention relates to flame resistance additives for organic polymers, and in particular polyphosphonate-type flame resistance additives in a polycarbonate or a polyester carbonate and/or in blends of polycarbonate or a polyester carbonate with an acrylonitrile, butadiene, and styrene terpolymer. The aromatic polyphosphonate compounds of the present invention are represented by the structure, wherein a and b are each from 0 to 6, with a+b being from 2 to 6, each R is independently hydrogen, unsubstituted or inertly substituted alkyl having up to 6 carbon atoms, —NO2, —NR12, —C?N, —OR1, —C(O)OR1, or —C(O)NR12 (wherein R1 is hydrocarbyl or hydrogen), each R2 is independently hydrogen, alkyl or inertly substituted alkyl, each R3 is a covalent bond or a divalent linking group, and each R4 is independently an alkyl, aryl, inertly substituted alkyl or inertly substituted aryl group.
    Type: Application
    Filed: January 8, 2009
    Publication date: November 25, 2010
    Inventors: David R. Wilson, Ravi B. Shankar, Ashwin R. Bharadwaj, Bruce A. King
  • Patent number: 7786197
    Abstract: A flame retardant resin composition consisting essentially of: (A) 100 parts by weight of the total of resin components (components A) which include at least 60 wt % of an aromatic polyester resin; (B) an organic phosphorus compound (component B-1) represented by the following general formula (1) and having an acid value of 0.7 mgKOH/g or less or an organic phosphorus compound (component B-2) represented by the following general formula (2); (C) 0 to 50 parts by weight of a flame retardancy improving resin (component C); and (D) 0 to 200 parts by weight of a filler (component D), and a molded article thereof. Wherein, when the organic phosphorus compound is the component B-1, the amount of the component B-1 is 1 to 100 parts by weight and when the organic phosphorus compound is the component B-2, the component B-2 is used in combination with a biscumyl compound (component B-3), the amount of the component B-2 is 5 to 30 parts by weight, and the amount of the component B-3 is 0.01 to 5 parts by weight.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: August 31, 2010
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Katsuhiro Yamanaka, Yutaka Taketani
  • Publication number: 20100137482
    Abstract: Disclosed herein is a symmetric cyclic phosphonate compound represented by the following Formula 1, a method of preparing the same and a flame retardant styrenic resin composition including the same: wherein R1 and R2 are each independently hydrogen, C1-C6 alkyl or C6-C20 aryl. The styrenic resin composition employing the symmetric cyclic phosphonate compound exhibits good flame retardancy and impact strength, does not release halide gas during preparation or combustion of the resin composition, and thus is environmentally friendly.
    Type: Application
    Filed: February 5, 2010
    Publication date: June 3, 2010
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Beom Jun JOO, Sang Hyen HONG, Min Soo LEE, Byun Kun LEE
  • Patent number: 7691924
    Abstract: The present invention relates to a flame retardant polycarbonate thermoplastic resin composition that comprises a polycarbonate resin, a rubber modified vinyl-grafted copolymer, a phosphorous mixture of a cyclic phosphazene oligomer compound and a phosphate ester morpholide compound or a phosphoric acid ester as a flame retardant, and, optionally, a fluorinated polyolefin resin, which has good flame retardancy, heat resistance, mechanical strength, impact strength, heat stability, processability, and appearance.
    Type: Grant
    Filed: August 21, 2006
    Date of Patent: April 6, 2010
    Assignee: Cheil Industries
    Inventors: Jong-Cheol Lim, Sang Hyun Hong, Kyung-Hoon Seo, Sam-Joo Yang
  • Publication number: 20090247676
    Abstract: The invention is a watery dispersion containing a) a flame-stabilizing substance of general formula (I) where R1 is hydrogen, C1-4-alkyl, —CH2Cl, —CH2Br, —CH2O—C1-4-alkyl or phenyl, R2 is hydrogen, C1-4-alkyl, —CH2Cl, —CH2Br or —CH2O—C1-4-alkyl, or R1 and R2 together with the ring carbon atoms form cyclohexylidene, cyclohexenylidene or 3,4-dibromocyclohexylidene, R3 and R5 independent of each other are hydrogen or C1-4-alkyl, R4 is hydrogen or methyl, and X is oxygen or sulfur, and b) a dispersive agent or combination of dispersive agents.
    Type: Application
    Filed: March 27, 2007
    Publication date: October 1, 2009
    Applicant: CLARIANT INTERNATIONAL LTD.
    Inventors: Olaf Mueller, Albert Muenkel, Bjoern Fechner
  • Publication number: 20090163627
    Abstract: Disclosed herein is a symmetric cyclic phosphonate compound represented by the following Formula 1, a method of preparing the same and a flame retardant styrenic resin composition including the same: wherein R1 and R2 are each independently hydrogen, C1-C6 alkyl or C6-C20 aryl. The styrenic resin composition employing the symmetric cyclic phosphonate compound exhibits good flame retardancy and impact strength, does not release halide gas during preparation or combustion of the resin composition, and thus is environmentally friendly.
    Type: Application
    Filed: December 16, 2008
    Publication date: June 25, 2009
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Beom Jun JOO, Sang Hyen HONG, Min Soo LEE, Byun Kun LEE
  • Publication number: 20080269383
    Abstract: Organic polymer compositions can be made flame-retardant by addition of selected organic phosphate and other components, such as known flame-retardants or conventional additives for further improvements, e.g. in name retardancy or light stability.
    Type: Application
    Filed: May 18, 2005
    Publication date: October 30, 2008
    Applicant: CIBA SPECIALTY CEMICALS HOLDING INC.
    Inventors: Jean-Roch Pauquet, Grant Leslie, Natacha Berthelon, Daniel Muller
  • Patent number: 7411013
    Abstract: A flame-retardant resin composition comprises a base resin (A), an organic phosphorus compound (B) having a unit represented by the following formula (1a), and a flame-retardant auxiliary (C). Wherein Ar represents an aromatic hydrocarbon ring or a nitrogen-containing aromatic heterocycle; X1 represents an oxygen atom or a sulfur atom; Y1 and Y2 are the same or different and each represents a hydrocarbon group, an alkoxy group, an aryloxy group, or an aralkyloxy group; Z1 represents an alkylene group, or a nitrogen-containing bivalent group corresponding to an alkylamine; Y1 and Y2 may bind to each other, and Y1 and Y2 together with the adjacent phosphorus atom may form a ring; “a” denotes 0 or 1; and “b” denotes an integer of 1 to 6.
    Type: Grant
    Filed: December 24, 2003
    Date of Patent: August 12, 2008
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hatsuhiko Harashina, Shinya Yamada
  • Publication number: 20080153950
    Abstract: Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X? is independently oxygen or sulfur, each m is independently zero or 1 when X? is oxygen and zero, 1 or 2 when X? is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.
    Type: Application
    Filed: December 20, 2007
    Publication date: June 26, 2008
    Inventors: Ravi B. Shankar, William J. Kruper, David R. Wilson, Bruce A. King, Michelle L. Hudack, Daniel J. Murray, Chun Wang, William Gerald Stobby, Ted A. Morgan, Mark W. Beach, Inken Beulich, Ing Feng Hu
  • Publication number: 20080127431
    Abstract: An aqueous dispersion which comprises a) a flame retardant of the general formula (I) wherein R1 represents hydrogen, C1-4-alkyl, —CH2Cl, —CH2Br, —CH2O—C1-4-alkyl or phenyl, R2 represents hydrogen, C1-4-alkyl, —CH2Cl, —CH2Br or —CH2O—C1-4-alkyl, or R1 and R2 together with the ring carbon atoms bound to them, represent cyclohexylidene, cyclohexenylidene or 3,4-dibromocyclohexylidene, R3 and R5 independently represent hydrogen or C1-4-alkyl, R4 represents hydrogen or methyl, and X represents oxygen or sulfur, and b) an acrylate copolymer which substantially consists of 50 to 80 mol % of monoalkenyl aromatics and 20 to 50 mol % of acrylates. The inventive aqueous dispersions have an average molar mass Mv between 1000 and 50 000 g/mol.
    Type: Application
    Filed: November 11, 2005
    Publication date: June 5, 2008
    Inventors: Andreas Harz, Olaf Mueller
  • Patent number: 7365114
    Abstract: The flameproof styrenic resin composition according to the present invention comprises (A) about 70 to 99.5 parts by weight of a rubber-modified polystyrene resin and (B) about 0.
    Type: Grant
    Filed: September 15, 2003
    Date of Patent: April 29, 2008
    Assignee: Cheil Industries Inc.
    Inventors: Sang Hyun Hong, Yae Ho Yang, Young Sik Ryu
  • Publication number: 20080085957
    Abstract: It is an object of the present invention to provide a polyester based artificial hair which has excellent setting properties, feeling and transparency and further has excellent flame-retardancy and controlled gloss of fiber surface while maintaining fiber properties possessed by a conventional polyester fiber such as heat resistance, strength and elongation and the like.
    Type: Application
    Filed: April 8, 2005
    Publication date: April 10, 2008
    Applicant: KANEKA CORPORATION
    Inventor: Toshiyuki Masuda
  • Patent number: 7323119
    Abstract: The present invention relates to the color stabilization of hydroquinone hydroxyethyl ethers by phosphite compounds containing the bis-cyclic structure of spiro phosphites, both rings being attached to the same tertiary carbon atom in the phosphite molecule.
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: January 29, 2008
    Assignee: Arch Chemicals, Inc.
    Inventors: Jayne Mallwitz, Robert C. Hire, Kiran B. Chandalia
  • Publication number: 20070293608
    Abstract: A polycarbonate composition is disclosed having improved fatigue resistance characteristics. The composition is useful for manufacture of electronic and mechanical articles, such as cell phone housing, among others. The composition comprises an effective amount of a polycarbonate, an impact modifier, and a pentraerythritol diphosphite derivative represented by formula (P-1): wherein m is an integer and 1?m?5; n is an integer and 1?n?5; and each of R1 and R2 is independently selected from the group consisting of arylalkyl, alkylarylalkyl, aryl, alkylaryl, and any combination thereof.
    Type: Application
    Filed: June 19, 2006
    Publication date: December 20, 2007
    Applicant: General Electric Company
    Inventors: Jing Chen, Theodorus Lambertus Hoeks, Mahari Tjahjadi
  • Patent number: 7279515
    Abstract: Resorcinol carbonate-based phosphate esters are prepared by reacting resorcinol carbonates with phosphorous oxychloride or a chlorophosphate. The resorcinol carbonates can be synthesized by the reaction of resorcinol with phosgene or diphenyl carbonate. The resorcinol carbonate-based phosphate esters can be used as flame retardants and perhaps flowing agents.
    Type: Grant
    Filed: September 21, 2005
    Date of Patent: October 9, 2007
    Inventors: Raj B. Durairaj, Gary A. Jesionowski
  • Patent number: 7087667
    Abstract: A flame retardant resin composition consisting essentially of: (A) 100 parts by weight of the total of resin components (components A) which include at least 60 wt % of an aromatic polyester resin; (B) an organic phosphorus compound (component B-1) represented by the following general formula (1) and having an acid value of 0.7 mgKOH/g or less or an organic phosphorus compound (component B-2) represented by the following general formula (2); (C) 0 to 50 parts by weight of a flame retardancy improving resin (component C); and (D) 0 to 200 parts by weight of a filler (component D), and a molded article thereof. Wherein, when the organic phosphorus compound is the component B-1, the amount of the component B-1 is 1 to 100 parts by weight and when the organic phosphorus compound is the component B-2, the component B-2 is used in combination with a biscumyl compound (component B-3), the amount of the component B-2 is 5 to 3.0 parts by weight, and the amount of the component B-3 is 0.01 to 5 parts by weight.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: August 8, 2006
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Katsuhiro Yamanaka, Yutaka Taketani
  • Patent number: 7067569
    Abstract: The invention relates to a synergistic mixture comprising a) at least one compound selected from the group consisting of the phosphites of the formula (I) to (V), of the phosphonites of the formulae (VI) to (IX) and (XV), of the di/oligophosphonites of the formulae (X) and (XI) and of the phosphinites of the formulae (XII) to (XIV), and b) at least one compound selected from the group consisting of the phosphanes of the formula (XVI), the di/oligophosphanes of the formulae (XVII) and (XVIII), and of the cyclophosphanes of the formula (XIX), and also to a process for stabilizing polymers with respect to thermooxidative degradation by addition and incorporation of a synergistic mixture of this type.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: June 27, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Peter Staniek
  • Patent number: 7067076
    Abstract: The invention is directed to a phosphonate composition having flame retardant properties. The phosphonate composition of the invention has the general formula: wherein R1 and R2 are independently C1–C4 alkyl, R3 is H or C1–C4 alkyl, and R4 is linear or branched C9–C22 alkyl, C9–C22 cycloalkyl, C9–C22 aryl or C9–C22 aralkyl and n=0 or 1. The invention is also directed to a method of producing the phosphonate composition having flame retardant properties.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: June 27, 2006
    Assignee: Rhodia Inc.
    Inventors: Shiming Wo, Dwight Shamblee
  • Patent number: 6991759
    Abstract: The present invention provides a process for preparation of semi-conducting polymer film containing beta crystalline phase of polyvinylidene fluoride which have a large number of application in piezoelectric devices viz. electromechanical sensors, tactile sensors for robotics, touch sensitive switches etc, which can be made at low temperatures and at low electric fields and having low resistivity/semi-conducting range.
    Type: Grant
    Filed: December 10, 2003
    Date of Patent: January 31, 2006
    Inventor: Radhakrishnan Subramaniam