Abstract: The present invention comprises novel single-functional and mixtures of multi-functional oligomeric performance additive compounds having one or more components of Structure A R1 ? ? ##STR1## (The definitions of R, Z1, Z2, Z3, A1, A2, A3 and y are given in the Summary Section), their uses and polymeric compounds and compositions containing them which have enhanced oxidative stabilities, enhanced ultraviolet (UV) and light stabilites and/or enhanced flame retardance. An example is the bis sulfonic acid bispotassium salt reaction product from an oligomeric caprolactone diol (TONE.RTM. 260), 2-sulfobenzoic acid anhydride and potassium carbonate, and use of this product, at levels up to about 3.0%, in a general purpose bisphenol A polycarbonate resin, to enhance the fire resistance or flame retardance of the polycarbonate resin.
Type:
Grant
Filed:
March 22, 1991
Date of Patent:
November 10, 1992
Assignee:
ELF Atochem North America, Inc.
Inventors:
Ronald E. MacLeay, Jose Sanchez, Daryl L. Stein
Abstract: This invention provides cationic emulsions of bituminous binders of the bitumen/polymer type, formed by a dispersion of an organic phase of the binder in an aqueous phase containing a cationic nitrogenous emulsifier and a mineral or organic acid, the acid being in appropriate quantity so that the pH of the aqueous phase is comprised between 3 and 9. The aqueous phase also contains an agent consisting of at least one water-soluble sequestering salt of phosphonic acid, particularly a salt of alkaline metal or of amine of hydroxyalkyl-1,1-diphosphonic acid, and optionally a water-soluble thickening agent. To obtain the emulsions, which are usable for road applications, the emulsifying agent, the sequestering agent and optionally the thickening agent may be used in the form of a premixture containing the agents and called cationic emulsifying system.
Abstract: The present invention disclosed herein is connected with a polypropylene resin composition giving off no corrosive and poisonous gases, having excellent moldability, providing molded articles with excellent mechanical strength and high flame retardance. The composition of the present invention is composed of predetermined amounts of a polypropylene resin, a polyethylene resin, polyammonium phosphate or polyammonium phosphate modified by melamine resin and a 1,3,5-triazine derivative. This composition may additionally contain a predetermined amount of one or more of specific thiophosphites and may further contain a predetermined amount of an olefinic synthetic rubber or elastomer and a crosslinking agent.
Abstract: A process for enhancing the fabrication of thermoplastic polymers entailing the addition of from 0.01 to 1 part, per hundred parts of thermoplastic polymer, of a processing aid, said processing aid comprising a processing additive, such as a silicon or a polyol, and a processing adjuvant, such as a phosphate.
Type:
Grant
Filed:
May 24, 1989
Date of Patent:
May 15, 1990
Assignee:
Union Carbide Chemicals and Plastics Company Inc.
Inventors:
Pak S. Leung, Errol D. Goddard, Fred H. Ancker
Abstract: Thermoplastic compositions comprising polyphenylene ethers and polyesters, impact-modified by glycidyl (meth)acrylate grafted EPDM and compatibilized by an aromatic polycarbonate exhibit high impact strength alone and when combined with other impact modifiers. Their shear sensitive viscosity properties makes them uniquely suitable for extrusion and blow molding applications.
Type:
Grant
Filed:
September 9, 1987
Date of Patent:
April 10, 1990
Inventors:
John B. Yates, III, Charles F. Pratt, Angelika H. McHale
Abstract: Organic materials normally subject to gradual degradation in the presence of oxygen are stabilized by inclusion of an aromatic fluorophosphite having at least one benzene group bonded through oxygen to phosphorus and at least one fluorine atom bonded directly to the same phosphorus. Stabilization is improved by also including a conventional phenolic antioxidant. Many of the aromatic fluorophosphites are new compounds.
Abstract: A process for enhancing the fabrication of thermoplastic polymers entailing the addition of from 0.01 to 1 part, per hundred parts of thermoplastic polymer, of a processing aid, said processing aid comprising a processing additive, such as a silicone or a polyol, and a processing adjuvant, such as a phosphate.
Type:
Grant
Filed:
March 8, 1988
Date of Patent:
August 15, 1989
Assignee:
Union Carbide Corporation
Inventors:
Pak S. Leung, Errol D. Goddard, Fred H. Ancker
Abstract: Stabilizers for organic polymers, consisting of one or more phosphorus-containing compounds of the family of alkyl- and/or phenyl-phosphites, alkyl- and/or phenyl-phosphonites, alkyl- and/or phenyl-diphosphonites, are directly added to the reaction mixture during the (co)polymerization of .alpha.-olefins or of mixtures thereof with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized, and show a thermo-oxidative resistance higher than that of the same polymeric compositions to which the same antioxidants have been added by a traditional route.
Abstract: Included are halogenated phosphate-phosphites and their acid halides and acids. The halogenated phosphate-phosphites can be prepared by a process comprising serially contacting(A) a phosphorus trihalide with a triol;(B) a halogenating agent; and(C) an oxirane or an alcohol,under conditions sufficient to prepare the halogenated phosphate-phosphite. Steps (A) and (B) can prepare their acid halides. Use of water in step (C) can prepare their acids. For example, 3-((bis(2-chloroethoxy)phosphino)oxy)(2-bromomethyl-2-methylpropyl, 2-bromoethyl, 2-chloroethyl)-phosphorate can be prepared from 2-methyl-2-(hydroxymethyl)-1,3-propanediol; phosphorus trichloride; bromine; and ethylene oxide.Also included is use of the compounds as a hydraulic fluid or flame retardant. For example, polyurethanes can be rendered less flammable with the halogenated phosphate-phosphite flame retardant.
Abstract: The present invention provides a method of producing a softening agent in which a silicone resin containing particular functional groups, a particular emulsifier and a particular antistatic agent are dispersed stably in an aqueous medium in a particular ratio, and which can give durable slippery touch, softness and processability at the same time to fibers after treatment. The invention also provides an industrially advantageous method of producing acrylic fibers which have animal hair-like touch and processability by one-step treatment, by fixing said softening agent to the acrylic fibers.
Abstract: This invention claims flame retardant polycarbonate resin compositions comprising an aromatic carbonate polymer and, as a novel flame retardant additive therefor, a phosphorus-containing polycarbonate composition produced by carrying out a polycarbonate condensation in which at least part of the diol compound is a bishydroxyalkylphosphine oxide. Also described are the novel flame retardants per se.
Abstract: The present invention comprises an acrylic adhesive composition having improved stability comprising polymerizable acrylic monomers in combination with polymerization initiators therefor; the improvement further comprises incorporating in the homogenous mixture of acrylic monomers and an initiator, including other substances to augment its performance as an adhesive,an effective amount of an inhibitor, being hydroquinone, and an effective amount of accelerator, being alpha amino phosphonic acid, or an alkali metal salt thereof.
Abstract: Aqueous compositions which contain a hydrolysed polymaleic anhydride, a complexing agent and a mixture of nonionic and anionic surfactants are suitable for use as assistants in the opening up of cellulose-containing fibre materials.
Abstract: Polymeric hindered secondary phosphonates which have the repeating structural unit of the formula ##STR1## where R.sub.1 and R.sub.2 are independently alkyl, cycloalkyl, aralkyl or alkaryl, A is alkylene, E is alkylene or phenylene, p is 0 or 1 and n is 2 to 50 are useful as stabilizers for organic polymers to counteract the degradative effects of heat, light and air.
Abstract: An anti-corrosive coating composition includes an anti-corrosive pigment component comprising (a) a salt comprising a polyvalent metal cation and an organic polyphosphonic acid containing at least 2 phosphonic acid groups and (b) a corrosion passivator capable of modifying the metal oxide film on the metal to be protected to render it more protective. The ratio of the polyphosphonate salt (a) to the passivator (b) in the coating composition is 1:1 to 50:1 by weight.
Abstract: An anti-corrosive coating composition includes as an anti-corrosive pigment dispersed in a film-forming binder a salt of a polyvalent metal cation and an organic polyphosphonic acid containing at least 2 phosphonic acid groups. The ratio of polyvalent metal cations to phosphonate groups in the salt is at least 0.8/n:1, where n is the valency of the polyvalent metal ion.
Type:
Grant
Filed:
May 31, 1983
Date of Patent:
February 26, 1985
Assignee:
International Paint Public Limited Company
Inventors:
Frank Reeder, Michael J. Nunn, Michael J. Mitchell, Kenneth F. Baxter
Abstract: A polyolefin resin composition for metallized films, having superior high-impact properties and heat-sealability and also superior printability and adhesive properties of metallized surface and further a good taken-up figure of rolled film is provided, which composition is obtained by blending a crystalline propylene-.alpha.-olefin copolymer containing 70% by weight or more of propylene component and having a crystalline m.p. of 150.degree. C. or lower, with a high density polyethylene having a density of 0.940 g/cm.sup.3 or higher, in blending ratios of 96 to 80% by weight of the copolymer and 4 to 20% by weight of the polyethylene, the ratio of the melt flow rate of the polyethylene to that of the copolymer being .gtoreq.0.7.