Aryl Group Patents (Class 524/135)
  • Patent number: 5115005
    Abstract: Compounds of the formula Ia or Ib ##STR1## in which R.sub.1 and R.sub.2, independently of one another, are hydrogen, alkyl, cycloalkyl, alkenyl, aryl or aralkyl or, together with the carbon atoms in the .alpha.-position to the carbonyl groups, form a cyclopentane, cyclopentene, cyclohexane, cyclohexene, cyclohexadiene or bicyclo[2.2.1]hept-5-ene ring which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, or form a monocyclic or polycyclic, aromatic ring system which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, R.sub.3 and R.sub.4, independently of one another, are hydrogen, alkyl, alkenyl, aryl or aralkyl, and R.sub.5 and R.sub.6, independently of one another, are alkyl, aryl or aralkyl groups, are highly suitable as flame retardants for polymers.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: May 19, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans-Peter Horner
  • Patent number: 5102931
    Abstract: The subject of the invention is flameproofed, non-dripping polyamide moulding compounds which contain specific amounts of the following:A) Phosphinic acid esters of polyphenols based on phenolaldehyde/ketone condensates,B) Anti-dripping agents (such as polyfluoroethylene polymers or aramides),C) Zinc borate,D) Thermoplastics with a predominantly aromatic main chain and a high thermal deflection temperature (Vicat B.gtoreq.180.degree. C.),and, if applicable, reinforcing agents and other additives for flameproofing and processing.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: April 7, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott, Aziz El-Sayed, Peter-Rolf Muller, Martin Wandel
  • Patent number: 5079299
    Abstract: This invention provides a mold release composition copmrising (1) a compound or a polymer having at least one of perfluoroalkyl groups having 4 to 20 carbon atoms and perfluoroalkenyl groups having 4 to 20 carbon atoms, and (2) a ladder polymer of organosilsesquioxane.
    Type: Grant
    Filed: July 16, 1989
    Date of Patent: January 7, 1992
    Assignee: Daikin Industries, Ltd.
    Inventors: Iwao Hisamoto, Masayoshi Shinjyo, Seiji Takubo, Yasuko Katakura
  • Patent number: 5063265
    Abstract: Described herein are novel heat-stabilized poly(aryl ether ketone) compositions. Stability is imparted by blending a poly(aryl ether ketone) with an aromatic phosphorus compound and an organic acid having a dissociation constant within a well-defined range.
    Type: Grant
    Filed: January 3, 1990
    Date of Patent: November 5, 1991
    Assignee: Amoco Corporation
    Inventor: James E. Harris
  • Patent number: 5061743
    Abstract: Certain hydroxy alkanoate polymers, such as 3-hydroxybutyrate polymers, when obtained by solvent extraction from fermentation masses, can have long cycle times during thermal processing due to a low rate of crystallization. A combination of (a) an organophosphonic or organophosphoric acid or ester with (b) an oxide, hydroxide, or carboxylate of a metal of Groups I to V is an effective nucleating agent.
    Type: Grant
    Filed: May 30, 1990
    Date of Patent: October 29, 1991
    Assignee: Imperial Chemical Industries plc
    Inventors: John M. Herring, Andrew Webb
  • Patent number: 5030675
    Abstract: Flame-resistant molding compounds of polycarbonate, polyalkylene terephthalate, graft polymer, fluorinated polyolefine and phosphorus compound can be worked up into moulded products which have a particularly advantageous combination of joint line strength, dimensional stability under heat and toughness.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: July 9, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Wittmann, Hans-Jurgen Kress, Horst Peters, Josef Buekers, Christian Lindner
  • Patent number: 5017633
    Abstract: A filled polyolefin, particularly polypropylene, containing a sterically hindered phenol antioxidant and a compound of formula I and/or II ##STR1## in which R is unsubstituted phenyl or phenyl substituted by 1 or 2 C.sub.1-12 alkyl groupsn is 0 or 1 andA is a monofunctional or difunctional residue of a phenyl, diphenyl, diphenyl ether, diphenylmethane or dibenzofuran,as processing stabilizer has good long-term stability even in the absence of conventional sulphur-containing co-stabilizers.
    Type: Grant
    Filed: July 6, 1989
    Date of Patent: May 21, 1991
    Assignee: Sandoz Ltd.
    Inventor: Guenther Tscheulin
  • Patent number: 4939237
    Abstract: A process for producing a polyamide with a relative viscosity of at least 100 is disclosed. The process comprises adding a catalyst selected from the group consisting of ortho-phosphoric acid, meta-phosphoric acid, alkali-metal hypophosphite and phenylphosphinic acid to the polyamide, which has a relative viscosity of from 30 to 70, mixing the catalyst and polyamide at a temperature above the melting temperature of the polyamide under reduced pressure and for a time sufficient to increase the relative viscosity of the polyamide to at least 100, and extruding the resulting polyamide into shaped form and quenching said polyamide. The catalyst is present in amounts of at least 0.01 wt. % and increases in relative viscosity may develop in times as short as about one minute.
    Type: Grant
    Filed: November 2, 1988
    Date of Patent: July 3, 1990
    Assignee: Du Pont Canada Inc.
    Inventor: Erica M. Besso
  • Patent number: 4889879
    Abstract: Coherent thermoplastic aggregates with very high content of pulverized mineral materials, composed of the said materials, of polyolefin polymers and/or copolymers, and possibly also of various familiar adjuvants, characterized by the fact that, in order for them to have both a volumetric mass close to or at most equal to the theoretical volumetric mass of the pulverized mineral substances entering into their composition and an excellent compatibility with redispersion polymers, the polymers and/or copolymers entering into the composition of the said aggregates in presence of a fluidizing agent are chosen within the group of thermoplastics with melting and/or softening point at least equal to 60.degree. C. and index of fluidity at least 50 (measured according to the standard ASTM D 1238) of the polyolefin type, other than those containing a polar monomer.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: December 26, 1989
    Assignee: Pluess Staufer AG
    Inventors: Henry Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
  • Patent number: 4886627
    Abstract: Conductive structures in polymers are obtained by a method in which poly(organylheteroacetylenes) of formula I ##STR1## or a mixture of poly(organylheteroacetylenes) of formula I and other polymers are exposed to radiation of high energy density, preferably laser radiation. At relatively low temperatures of 100.degree. C. to 600.degree. C., the polymer structure is effected so that electrically conductive structures result. The products are employed in electrical engineering, electronics and microelectronics, preferably as printed conductors. The invention makes it possible to inscribe long-term stable, conductive structures in an insulating polymer matrix in a one-step method, it being possible to use modern computer techniques (computer graphics)and to produce computer-aided conductor structures directly. The polymers can be used without supports or applied on rigid or flexible materials.
    Type: Grant
    Filed: March 15, 1988
    Date of Patent: December 12, 1989
    Assignee: VEB Metallurgieelektronik Leipzig
    Inventors: Harald Gruber, Andreas M. Richter, Egon Fanghanel, Hans-Klaus Roth, Heinz Friedrich, Siegfried Maras
  • Patent number: 4879346
    Abstract: Blends of a silicone-polycarbonate block copolymer with a compatibilized alloy of polyphenylene ether and polyester resins comprise a class of thermoplastic materials with physical properties ranging from those of a self-extinquishing, tough thermoplastic elastomer to a rigid engineering material. The compatibilizers include aromatic polycarbonates and rubber-modified impact modifiers.
    Type: Grant
    Filed: June 10, 1988
    Date of Patent: November 7, 1989
    Assignee: General Electric Company
    Inventors: Richard C. Bopp, John B. Yates, III
  • Patent number: 4866115
    Abstract: A solid mixture contains as essential components(A) from 40 to 99% by weight, based on the total weight of (A) and (B), of a nonnucleating thermoplastic polyamide and(B) from 1 to 60% by weight, based on the total weight of (A) and (B), of a thermoplastic polyamide which contains a nucleating agent, and in addition(C) from 0 to 60% by weight, based on the total weight of (A)+(B)+(C), of fibrous or particulate fillers.
    Type: Grant
    Filed: August 5, 1988
    Date of Patent: September 12, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Betz, Eckhard M. Koch, Christoph Plachetta, Gerd Blinne, Karl Hahn
  • Patent number: 4826900
    Abstract: An ignition resistant carbonate polymer composition comprising a mixture of one or more carbonate polymers, and a high elastic memory polytetrafluoroethylene having a heat shrinkage equal to or greater than 15% with or without one or more organo phosphorous compounds.
    Type: Grant
    Filed: March 31, 1988
    Date of Patent: May 2, 1989
    Assignee: The Dow Chemical Company
    Inventors: Samuel A. Ogoe, Thoi H. Ho
  • Patent number: 4824885
    Abstract: Stabilizers for organic polymers, consisting of one or more phosphorus-containing compounds of the family of alkyl- and/or phenyl-phosphites, alkyl- and/or phenyl-phosphonites, alkyl- and/or phenyl-diphosphonites, are directly added to the reaction mixture during the (co)polymerization of .alpha.-olefins or of mixtures thereof with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized, and show a thermo-oxidative resistance higher than that of the same polymeric compositions to which the same antioxidants have been added by a traditional route.
    Type: Grant
    Filed: July 6, 1987
    Date of Patent: April 25, 1989
    Assignee: Enichem Sintesi S.p.A.
    Inventors: Ambrogio Magni, Erik Bersanetti
  • Patent number: 4788238
    Abstract: The present invention provides thermoplastic flame-retardant moulding compositions containing halogen-containing copolycarbonates, styrene/maleic anhydride copolymers, phosphorus compounds of the formula (I) ##STR1## and tetrafluoroethylene polymers and, if desired, further known additives.
    Type: Grant
    Filed: September 21, 1987
    Date of Patent: November 29, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gert Todtemann, Klaus Reinking, Otto Koch, Kress Hans-Jurgen, Lindner Christian, Friedemann Muller, Horst Peters, Josef Buekers
  • Patent number: 4722955
    Abstract: Carbonate polymer compositions exhibit good thermal stability and good non-yellowing characteristics. Compositions comprise a carbonate polymer (e.g., a homopolycarbonate of bisphenol A), a heat stabilizing phosphorous compound (e.g., an organo-phosphite or an organo-phosphonite), an epoxy compound containing internal acyclic ether linkages (e.g., a diglycidyl ether of a polypropylene glycol), and optionally a hindered phenol. Such compositions retain desirable properties upon exposure to hot and humid conditions.
    Type: Grant
    Filed: April 15, 1985
    Date of Patent: February 2, 1988
    Assignee: The Dow Chemical Company
    Inventor: Kevin F. Dick
  • Patent number: 4690954
    Abstract: A method for improving a production characteristic of flame-retardant polyurethanes. The characteristic may be selected from the group consisting of(1) processability;(2) scorch;(3) odor; and(4) flame-retardant efficiency.The method comprises incorporation into a polyurethane an amount effective to reduce combustibility of a haloether phosphorate flame-retardant under conditions sufficient to improve said characteristic. Also, the flame-retardant polyurethane composition such as prepared by said method. Preferably, the polyurethane is a foam, especially a flexible foam and most especially flexible slabstock foam.
    Type: Grant
    Filed: April 28, 1986
    Date of Patent: September 1, 1987
    Assignee: The Dow Chemical Company
    Inventors: David J. Wampfler, Donna J. Fielding, Chester E. Pawloski
  • Patent number: 4639475
    Abstract: The invention relates to an adhesive stick of an adhesive resin dissolved and/or dispersed in an aqueous solvent system and containing a gel-forming component and, if desired, other standard additives. The new adhesive stick is characterized in that its adhesive layers applied by rubbing onto a receiving surface show permanently tacky pressure-sensitive adhesive properties and in that the stick contains the reaction product of sorbitol and/or xylitol and benzaldehyde as the gel-forming component and, as adhesive resin, a reaction mixture from the reaction of methyl vinyl ether/maleic acid anhydride copolymers with partially neutralized acid phosphate esters of nonionic wetting agents of the lower alkylene oxide adduct type.
    Type: Grant
    Filed: April 17, 1984
    Date of Patent: January 27, 1987
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Dierichs, Gerhard Gierenz, Gabriella Kraus
  • Patent number: 4536531
    Abstract: A polyester resin composition having excellent molding mobility and crystallizing property, comprises (A) at least one thermoplastic polyester resin selected from polyethylene terephthalate resins and polybutylene terephthalate resins; (B) a polycaprolactone having a number average molecular weight of from 200 to 2,000 in an amount of 0.1 to 30 parts by weight per 100 parts by weight of the polyester resin, in which polycaprolactone molecules, at least 50% of the terminal radicals thereof, are modified to be non-reactive, (C) 0.01 to 10 parts by weight of a crystal nucleating agent per 100 parts of the polyester resin, and optionally, (D) at least one additive selected from fillers and specific phosphorous compounds which may be in combination with a specific epoxy compound, the polyester resin composition being useful for producing a molded product having an excellent dimensional stability and mechanical strength.
    Type: Grant
    Filed: May 19, 1983
    Date of Patent: August 20, 1985
    Assignee: Teijin Limited
    Inventors: Yoshinari Ogawa, Noriyuki Akagi
  • Patent number: 4474914
    Abstract: Ortho-alkylated phenyl phosphonites of the formula ##STR1## wherein R.sup.1 is alkyl, phenyl or phenyl substituted by alkyl, R.sup.2 is tertiary alkyl or phenylalkyl, and R.sup.3 is hydrogen, alkyl or phenylalkyl are useful as stabilizers for organic polymers and lubricating oils, particularly as processing stabilizers for polyolefins.
    Type: Grant
    Filed: May 31, 1983
    Date of Patent: October 2, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: John D. Spivack
  • Patent number: 4439569
    Abstract: This invention is directed to a polymeric thermo-sensitive material which comprises a polyamide composition containing compounds of sulphur-contained compounds or phosphorous acid ester, and which is smaller in polarization in the application of direct-current electric field, higher in temperature detection function, does not cause flexibility deterioration due to heating operation and is less in hygroscopicity. A composition containing thiophosphorous acid ester and bis(hydroxyphenyl) sulfide derivative from a group of the phosphorous acid ester is particularly superior in quality.
    Type: Grant
    Filed: September 22, 1982
    Date of Patent: March 27, 1984
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Shu Hotta, Yoshio Kishimoto, Wataru Shimotsuma
  • Patent number: 4407995
    Abstract: Polycarbonates are heat stabilized by the incorporation of a carbonate compound having a boiling point greater than about 250.degree. C. and an organophosphorous compound such as a phosphonite or a phosphite. The amount of the additive compound used in each instance is from 100 to 10,000 parts per million.
    Type: Grant
    Filed: July 28, 1982
    Date of Patent: October 4, 1983
    Assignee: The Dow Chemical Company
    Inventor: Kevin F. Dick
  • Patent number: 4397973
    Abstract: A composition comprising (a) an aromatic polycarbonate and (b) a minor amount of a oxyalkylene siloxane block copolymer, and, optionally, an organic phosphite or phosphonite and/or epoxy compound provide lower viscosity in the melt without producing brittle molded parts.
    Type: Grant
    Filed: August 7, 1981
    Date of Patent: August 9, 1983
    Assignee: General Electric Company
    Inventors: Steven W. Scott, Howard A. Vaughn, Jr.