P Directly Bonded To Oxygen Only Patents (Class 524/140)
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Patent number: 7388040Abstract: A fixer fluid having reduced kogation. The fixer fluid includes at least one phosphate ester surfactant and at least one cationic polymer, wherein the fixer fluid is formulated so that the at least one phosphate ester surfactant does not precipitate with the at least one cationic polymer. The at least one phosphate ester surfactant may be an anionic phosphate ester surfactant or an amphoteric phosphate ester surfactant. If the at least one phosphate ester surfactant is an anionic phosphate ester surfactant, it may have greater than or equal to approximately 2 moles of ethylene oxide per mole of the phosphate ester surfactant. The present invention also relates to an inkjet ink having reduced kogation and a method of producing a fixer fluid having reduced kogation.Type: GrantFiled: April 8, 2004Date of Patent: June 17, 2008Assignee: Hewlett-Packard Development Company, L.P.Inventors: Richard A. Sader, Mark L. Choy, Yi-Hua Tsao, Paul J. Bruinsma
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Patent number: 7384994Abstract: Olefinic interpolymer compositions comprising the olefinic interpolymer, residuals from a transition metal catalyst and boron containing activator package, and a charge dissipation modifier and methods for making them. The compositions have dissipation factors that are at least 50% less than the corresponding olefinic interpolymer compositions which have not been treated with charge dissipation modifiers. The compositions are useful in wire and cable applications.Type: GrantFiled: May 22, 2007Date of Patent: June 10, 2008Assignee: Dow Global Technologies Inc.Inventors: Carlos Gilberto Ortiz, Peter Anthony Fox, Raymond L. Laakso, Jr., Gary R. Marchand, Steven R. Oriani, Walter Werner Schmiegel, Michael K. Laughner, Deepak R. Parikh
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Patent number: 7381763Abstract: A flame retardant aromatic polycarbonate resin composition comprising: (A) an aromatic polycarbonate resin (component A); (B) an acrylonitrile-styrene copolymer (component B); (C) inorganic fillers (components C); (D) an organic phosphorus compound-based flame retardant (component D); and (E) a fluorine-containing anti-dripping agent (component E), the amounts of the above components are specific and particularly the components C consist of (C1) mica and (C2) talc and/or wollastonite in a specific ratio, and a molded article formed from the resin composition. According to the present invention, there are provided a resin composition which has excellent mechanical properties, flame retardancy and dimensional stability, is light in weight and rarely wears away a mold and a molded article of the resin composition.Type: GrantFiled: November 21, 2005Date of Patent: June 3, 2008Assignee: Teijin Chemicals, Ltd.Inventor: Seiji Kikuchi
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Publication number: 20080118875Abstract: A hardmask composition includes a solvent and an organosilicon copolymer. The organosilicon copolymer may be represented by Formula A: (SiO1.5—Y—SiO1.5)x(R3SiO1.5)y ??(A) wherein x and y may satisfy the following relations: x is about 0.05 to about 0.9, y is about 0.05 to about 0.9, and x+y=1, R3 may be a C1-C12 alkyl group, and Y may be a linking group including a substituted or unsubstituted, linear or branched C1-C20 alkyl group, a C1-C20 group containing a chain that includes an aromatic ring, a heterocyclic ring, a urea group or an isocyanurate group, or a C2-C20 group containing one or more multiple bonds.Type: ApplicationFiled: November 21, 2007Publication date: May 22, 2008Inventors: Mi Young Kim, Sang Kyun Kim, Sang Hak Lim, Sang Ran Koh, Hui Chan Yun, Do Hyeon Kim, Dong Seon Uh, Jong Seob Kim
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Publication number: 20080113200Abstract: A composition comprising a compound of formula (I) or (II): wherein r and q are independently integers of 1 to 3; Rf is linear or branched chain perfluoroalkyl group having 1 to 6 carbon atoms; j is an integer 0 or 1, or a mixture thereof, x is 1 or 2, Z is —O— or —S—, X is hydrogen or M, and M is an ammonium ion, an alkali metal ion, or an alkanolammonium ion is disclosed.Type: ApplicationFiled: November 13, 2006Publication date: May 15, 2008Inventors: Sheng Peng, Stephen James Getty, Xianjun Meng
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Patent number: 7358287Abstract: The invention relates to a flame retardant polycarbonate composition which is comprised of a polycarbonate, a phosphoric acid ester, a functionalized acrylic polymer, and an alkyl methacrylate-diene-vinyl aromatic terpolymer, wherein the polycarbonate is present in the composition in an amount of at least about 85 weight percent, wherein the phosphoric acid ester is present at a level which is within the range of about 1 weight percent to about 12 weight percent, wherein the functionalized acrylic polymer is present at a level which is within the range of about 0.5 weight percent to about 4.5 weight percent, and wherein the alkyl methacrylate-diene-vinyl aromatic terpolymer is present at a level which is within the range of about 0.5 weight percent to about 4.5 weight percent, with the proviso that the sum of the amount of the functionalized acrylic polymer and the alkyl methacrylate-diene-vinyl aromatic terpolymer present in the composition does not total more than 5 weight percent.Type: GrantFiled: May 31, 2005Date of Patent: April 15, 2008Assignee: Ovation Polymer Technology and Engineered Materials, Inc.Inventors: Jin Zhu, Nishant Negandhi
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Patent number: 7345104Abstract: Blends of polycarbonate and copolyester that are capable of being extrusion blow-molded are described. The blends preferably comprise (I) about 1 to 99% by weight of a linear or branched polycarbonate and (II) about 1 to 99% by weight of a mixture of (i) about 40 to 100% by weight of a first copolyester and (ii) about 0 to 60% by weight of a second copolyester. The first copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues, (B) diol residues comprising about 45 to 75 mole percent of 1,4-cyclohexanedimethanol (CHDM) residues and about 25 to 55 mole percent of ethylene glycol residues, and (C) about 0.05 to 1.0 mole percent of the residue of a trifunctional monomer. The optional second copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues and (B) diol residues comprising about 52 to 90 mole percent of CHDM residues and about 10 to 48 mole percent of ethylene glycol residues.Type: GrantFiled: November 5, 2004Date of Patent: March 18, 2008Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Harold Eugene Dobbs, Spencer Allen Gilliam
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Patent number: 7342059Abstract: Blends of polycarbonate and copolyester that are capable of being extrusion blow-molded are described. The blends preferably comprise (I) about 1 to 99% by weight of a linear or branched polycarbonate and (II) about 1 to 99% by weight of a mixture of (i) about 40 to 100% by weight of a first copolyester and (ii) about 0 to 60% by weight of a second copolyester. The first copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues, (B) diol residues comprising about 45 to 75 mole percent of 1,4-cyclohexanedimethanol (CHDM) residues and about 25 to 55 mole percent of ethylene glycol residues, and (C) about 0.05 to 1.0 mole percent of the residue of a trifunctional monomer. The optional second copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues and (B) diol residues comprising about 52 to 90 mole percent of CHDM residues and about 10 to 48 mole percent of ethylene glycol residues.Type: GrantFiled: December 16, 2003Date of Patent: March 11, 2008Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Harold Eugene Dobbs, Spencer Allen Gilliam, Wesley Raymond Hale
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Patent number: 7319126Abstract: Branched synthetic polyisoprenes are described having a macrostructure and a microstructure very similar to those of natural rubber. According to one aspect, these polyisoprenes have an apparent stress F/S0 greater than or equal to 0.4 MPa at a relative elongation ? of 150%, applied to a dumbbell-shaped test specimen consisting of the crosslinkable polyisoprene. According to another aspect, these polyisoprenes fulfill the relationship: Cotan ??0.3761. ?inh+0.15,:??(i) where cotan ? is the cotangent of the loss angle of a sample of said polyisoprene, measured at 130° C. by means of an instrument known by the trade name “RPA2000”, said sample being subjected to shear stress to 10% deformation and at a stress frequency of 0.035 Hz, and where ?inh is the inherent viscosity of said polyisoprene, measured in toluene at 25° C. and at a concentration of said polyisoprene in toluene of 0.1 g/dl.Type: GrantFiled: April 18, 2005Date of Patent: January 15, 2008Assignee: Michelin Recherche et Technique S.A.Inventors: Philppe Laubry, Fanny Barbotin, Philippe Johnson, Jean-Luc Auger
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Publication number: 20080004379Abstract: A method of making polycarbonate includes the steps of forming polycarbonate by a melt transesterification method using an activated diaryl carbonate, and compounding the polycarbonate with a phosphorus-containing compound that has an abstractable proton or hydrolyzable group. The phosphorus-containing compound is compounded with the polycarbonate in an amount sufficient to result in an improvement in the color properties of the polycarbonate as compared to pellets formed from the same polycarbonate without addition of the phosphorus-containing compound.Type: ApplicationFiled: March 20, 2007Publication date: January 3, 2008Applicant: GENERAL ELECTRIC COMPANYInventors: Sjef Berndsen, Hans Peter Brack, Bernd Jansen, Dennis Karlik, Edward Kung, Daniel Lowery, Patrick Joseph McCloskey
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Patent number: 7307120Abstract: The present invention provides a thermoplastic resin composition containing 100 parts by mass of a mixture of a thermoplastic resin (A) and carbon nanotubes (B), the mixture being composed of the component (A) in an amount of 20 to 99.95 mass % and the component (B) in an amount of 0.05 to 20 mass %; a flame retardant (C) in an amount of 0.05 to 30 parts by mass; and a polyfluoroolefin resin in an amount of 0 to 2 parts by mass. The flame retardant is preferably a phosphorus compound, and the thermoplastic resin preferably contains, as a component, an aromatic polycarbonate-polyorganosiloxane copolymer.Type: GrantFiled: January 28, 2003Date of Patent: December 11, 2007Assignee: Idemitsu Kosan Co., Ltd.Inventor: Akio Nodera
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Patent number: 7297736Abstract: Disclosed are polymer blends comprising polycarbonate(s) and polyester(s) wherein the polycarbonate is a polycarbonate derived from bisphenol A and the polyester comprises residues of or is derived from one or more aromatic dicarboxylic acids, neopentyl glycol, and 1,4-cyclohexanedimethanol.Type: GrantFiled: October 28, 2004Date of Patent: November 20, 2007Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Sam Richard Turner
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Patent number: 7279516Abstract: The present invention is in the field of polymer sheets for use in multiple layer glass panels, and more specifically, the present invention is in the field of polymer sheets comprising agents that improve fire resistance in the polymer sheets.Type: GrantFiled: November 2, 2004Date of Patent: October 9, 2007Assignee: Solutia IncorporatedInventor: John Joseph D'Errico
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Patent number: 7273014Abstract: The invention relates to plastic pallets that pass the Underwriters Laboratory UL 2335 protocol for pallets wherein said pallets comprises at least one resin selected from the group consisting of: (a) polyphenylene ether resin and blends containing polyphenylene ether resin, (b) polycarbonate resin and blends containing polycarbonate resin, (c) vinyl aromatic graft copolymer resin; (d) polyetherimide resin and blends containing polyetherimide resin, and (e) thermosetting resins. In a preferred embodiment, the plastic pallet has an open deck design. The invention also relates to a method to make pallets that pass the UL 2335 protocol.Type: GrantFiled: February 4, 2004Date of Patent: September 25, 2007Assignee: General Electric CompanyInventors: Adeyinka Adedeji, Geoffrey Henry Riding, Bruce Marshall Torrey
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Patent number: 7256228Abstract: A stabilized thermoplastic resin composition is disclosed which comprises structural units derived at least one substituted or unsubstituted polycarbonate, at least one substituted or unsubstituted polyester and a combination of at least two quenchers, wherein said quencher is selected from a group consisting of phosphorus compound, carboxylic acid, derivates of carboxylic acids, epoxy functional polymers and boron compound. Also disclosed is a stabilized thermoplastic resin composition comprising: structural units derived at least one substituted or unsubstituted polycarbonate, at least one substituted or unsubstituted polyester, an epoxy functional polymers and a combination of at least one quenchers, wherein said quencher is selected from a group consisting of phosphorus compounds, carboxylic acid compounds, polyols, and boron compounds. In addition the composition disclosed possess good optical properties, thermal properties and stability.Type: GrantFiled: March 31, 2004Date of Patent: August 14, 2007Assignee: General Electric CompanyInventors: Parminder Agarwal, Peter H. Th. Vollenberg, Gabrie Hoogland, Vishvajit Chandrakant Juikar, Ganesh Kannan, Abbas-Alli Ghudubhai Shaikh, Sachin Ashok Shelukar
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Patent number: 7238427Abstract: The present invention is in the field of polymer sheets for use in multiple layer glass panels, and more specifically, the present invention is in the field of polymer sheets comprising agents that improve fire resistance in the polymer sheets.Type: GrantFiled: November 2, 2004Date of Patent: July 3, 2007Assignee: Solutia IncorporatedInventor: Yinong Ma
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Patent number: 7235624Abstract: Olefinic interpolymer compositions comprising the olefinic interpolymer, residuals from a transition metal catalyst and boron containing activator package, and a charge dissipation modifier and methods for making them. The compositions have dissipation factors that are at least 50% less than the corresponding olefinic interpolymer compositions which have not been treated with charge dissipation modifiers. The compositions are useful in wire and cable applications.Type: GrantFiled: August 23, 2006Date of Patent: June 26, 2007Assignee: Dow Global Technologies Inc.Inventors: Carlos Gilberto Ortiz, Peter Anthony Fox, Raymond L. Laakso, Jr., Gary R. Marchand, Steven R. Oriani, Walter Werner Schmiegel, Michael K. Laughner, Deepak R. Parikh
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Patent number: 7232854Abstract: Polycarbonate compositions containing a specific combination of additives achieve desirable flame retardance characteristics when used in thin wall polycarbonate articles. These compositions contain a polycarbonate/siloxane component, containing a polycarbonate siloxane copolymer, or a mixture of a polycarbonate siloxane copolymer and polycarbonate resin; a mineral filler; and a flame retardant. The composition contains at least 50% by weight of polycarbonate when the polycarbonate of the polycarbonate siloxane copolymer and any polycarbonate resin (linear or branched) are considered together; and the polycarbonate siloxane copolymer and the mineral filler are present in amounts effective to achieve a flex modulus of 29,000 kg/cm3 or greater, for example 30,000 kg/cm3 or greater, good flex-fold strength and good impact strength, for example a room temperature Notched Izod Impact Strength of 25 kgf-cm/cm or greater.Type: GrantFiled: February 3, 2004Date of Patent: June 19, 2007Assignee: General Electric CompanyInventors: Shiping Ma, Thomas Ebeling, Shrish Rane
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Patent number: 7223812Abstract: A thermoplastic molding composition containing talc is disclosed. The composition wherein talc has a median particle size of less than 1000 nm further contains a polycarbonate and/or polyester-carbonate, and a graft polymer having as graft base a rubber having a glass transition temperature of below about 10° C. is suitable for preparing molded articles having improved mechanical properties, such as weld line strength, elongation at break and toughness at low temperatures.Type: GrantFiled: June 5, 2002Date of Patent: May 29, 2007Assignee: Bayer AktiengesellschaftInventors: Andreas Seidel, Marc Vathauer, Thomas Eckel, Holger Warth, Dieter Wittmann
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Patent number: 7220790Abstract: A thermoplastic molding composition having good flame resistance, melt flowability, resistance to chemicals and creep is disclosed. The composition contains A) at least one member having weight average molecular weight (Mw) of 25,000 to 35,000 g/mol, selected from the group consisting of aromatic polycarbonate and polyestercarbonate B) ABS graft polymer produced by the mass polymerization process and characterized in (i) having a butadiene content of 8 to 15% in relation to the weight of the graft polymer, (ii) having an acrylic acid derivative content of 15 to 30% in relation to the total weight of the acrylic derivative and styrene monomer, and (iii) containing styrene monomer-acrylic acid derivative copolymer having a weight average molecular weight of 5·104 to 14·104 g/mol. The composition may further contain one or more of halogen-free phosphorus compounds, fluorinated polyolefin, a polymer containing acrylate monomer and an inorganic material in particulate form.Type: GrantFiled: July 25, 2003Date of Patent: May 22, 2007Assignee: Bayer AktiengesellschaftInventors: Andreas Seidel, Thomas Eckel, Dieter Wittmann, Dirk Kurzidim
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Patent number: 7205346Abstract: A flame-retardant resin composition comprises a thermoplastic resin; a flame retardant comprising a phosphorus-containing compound (A), a aromatic resin (B), and at least one flame-retardant auxiliary (C) selected from a nitrogen-containing compound and a metal salt of an inorganic acid; and at least one stabilizer auxiliary (D) selected from a compound having a functional group reactive to an active hydrogen atom and a water-repellent compound. The phosphorus-containing compound may be a phosphoric ester. The aromatic resin may be a polyphenylene sulfide-series resin or a polyphenylene oxide-series resin. The nitrogen-containing compound is a salt of an amino group-containing triazine compound with an oxygen acid, a salt of an amino group-containing triazine compound with a hydroxyl group-containing triazine compound, a polyphosphoric acid amide, a cyclic urea compound, or others.Type: GrantFiled: November 28, 2002Date of Patent: April 17, 2007Assignee: Polyplastics Co., Ltd.Inventor: Hatsuhiko Harashina
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Patent number: 7196126Abstract: A thermoplastic flame retardant resin composition according to the present invention comprises: (A) about 40˜95 parts by weight of a styrenic resin; (B) about 5˜60 parts by weight of a polyphenylene ether, (C) about 0.1˜40 parts by weight of a rubber modified polystyrene resin containing about 40˜65% by weight of a rubber and about 0.1˜8% by weight of acrylonitrile based on 100 parts by weight of the sum of (A) and (B); and (D) about 5 to 30 parts by weight of an aromatic phosphoric acid ester compound based on 100 parts by weight of the sum of (A) and (B).Type: GrantFiled: April 14, 2003Date of Patent: March 27, 2007Assignee: Cheil Industries Inc.Inventors: Sung Hee Ahn, Jae Ho Yang, Young Gil Jang, Su Hak Bae
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Patent number: 7179519Abstract: Polyimide/metal laminates having a polyimide film and a metal layer laminated thereon, wherein the polyimide film contains titanium element and flexible print wiring boards with the use of the same are disclosed. The polyimide/metal laminates are excellent in adhesion under the ordinary conditions and, moreover, can sustain the adhesive strength at a high ratio after exposure to high temperature or high temperature and high humidity. Owing to these characteristics, these polyimide/metal laminates are appropriately usable in flexible print wiring boards, multi-layered print wiring boards, rigid flex wiring boards, tapes for TAP, semiconductor packages such as CFOs and multi chip modules (MCMs), magnetic recording films, coating films for aerospace materials and filmy resistance elements.Type: GrantFiled: May 16, 2003Date of Patent: February 20, 2007Assignee: Kaneka CorporationInventors: Masaru Nishinaka, Kiyokazu Akahori
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Patent number: 7166653Abstract: The novel transparent polyolefin, polyester or polyamide article disclosed is stabilized against the effects of light, oxygen, heat and agressive chemicals by addition of 0.005–0.30% by weight the polymeric substrate of a hydroxyphenyl triazine UV absorber, and is characterized by its thickness between 1 and 500 ?m. Preferred polyolefin articles thus stabilized are agricultural films containing as further stabilizer a sterically hindered amine. The novel compositions act as selective UV filter especially useful in agriculture.Type: GrantFiled: May 6, 2003Date of Patent: January 23, 2007Assignee: Ciba Specialty Chemicals Corp.Inventors: David George Leppard, François Gugumus, Michela Bonora
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Patent number: 7151126Abstract: The present invention relates to a flame retardant thermoplastic resin composition that contains a polyphenylene ether resin and a phenol resin derivative, both of them having good char formability, regardless of the base resin. A flame retardant thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a thermoplastic resin as a base resin, (B) about 0.1˜100 parts by weight of polyphenylene ether, (C) about 0.1˜100 parts by weight of a phenol resin derivative, and (D) about 0.1˜50 parts by weight of a phosphorous compound or a mixture of phosphorous compounds. The thermoplastic resin composition may contain up to 5.0 parts by weight of an anti-dripping agent based on 100 parts by weight of the base resin.Type: GrantFiled: December 26, 2001Date of Patent: December 19, 2006Assignee: Cheil Industries Inc.Inventors: Jae Ho Yang, Sang Hyun Hong, Gyu Chul Lee, Bok Nam Jang, Sung Hee Ahn
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Patent number: 7148275Abstract: The present invention relates to a flame retardant thermoplastic resin composition that contains a phenol resin derivative having good char formability, regardless of the base resin. A flame retardant thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a thermoplastic resin as a base resin, (B) about 0.1˜100 parts by weight of a phenol resin derivative, and (C) about 0.1˜50 parts by weight of a phosphorous compound or a mixture of phosphorous compounds.Type: GrantFiled: December 26, 2001Date of Patent: December 12, 2006Assignee: Cheil Industries Inc.Inventors: Jae Ho Yang, Sang Hyun Hong, Gyu Chul Lee, Young Gil Jang, Su Hak Bae
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Patent number: 7144934Abstract: Olefinic interpolymer compositions comprising the olefinic interpolymer, residuals from a transition metal catalyst and boron containing activator package, and a charge dissipation modifier and methods for making them. The compositions have dissipation factors that are at least 50% less than the corresponding olefinic interpolymer compositions which have not been treated with charge dissipation modifiers. The compositions are useful in wire and cable applications.Type: GrantFiled: October 22, 2003Date of Patent: December 5, 2006Assignee: Dow Global Technologies Inc.Inventors: Carlos Gilberto Ortiz, Peter Anthony Fox, Raymond L. Laakso, Gary Robert Marchand, Steven R. Oriani, Walter Werner Schmiegel, Michael K. Laughner, Deepak R. Parikh
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Patent number: 7144527Abstract: The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1–C6-alkyl, linear or branched, and/or aryl; R3 is C1–C10-alkylene, linear or branched, C6–C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.Type: GrantFiled: September 11, 2003Date of Patent: December 5, 2006Assignee: Clariant GmbHInventors: Volker Thewes, Andrea Zurstrassen
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Patent number: 7138447Abstract: The present invention provides a thermoplastic polymer composition mainly comprising a block copolymer prepared by extending, with a specific polyurethane component, the polymer chain of a block copolymer, which may be hydrogenated, having a polymer block of an aromatic vinyl compound and a polymer block of a conjugated diene. The thermoplastic polymer composition according to the present invention is excellent in handling properties and melt-moldability, because it shows non-tackiness. By using the thermoplastic polymer composition according to the present invention, a molded article having high qualities can be produced with good productivity.Type: GrantFiled: July 9, 2002Date of Patent: November 21, 2006Assignee: Kuraray Co., Ltd.Inventor: Hidekazu Saito
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Patent number: 7135509Abstract: A flame-retardant polybutylene terephthalate resin composition wherein (A) 20-70% by weight of a polybutylene terephthalate resin or a mixture of a polybutylene terephthalate resin and a polyethylene terephthalate resin, (B) 1–20% by weight of a vinyl based resin, (C) 1–20% by weight of a phosphoric acid ester, (D) 1–30% by weight of a salt of a triazine based compound and cyanuric acid or isocyanuric acid, and (E) 0.1–5% by weight of an alkaline earth metal compound are compounded, and formed articles thereof have high degrees of flame retardancy and tracking resistance, and are unlikely to allow occurrence of metal pollution or deterioration in hydrolysis resistance due to a phosphoric acid ester, and therefore are suitable for machine component parts, electrical/electronic component parts, and automotive component parts.Type: GrantFiled: September 25, 2002Date of Patent: November 14, 2006Assignee: Toray Industries, Inc.Inventors: Hiromitsu Ishii, Takashi Nagao, Jiro Kumaki
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Patent number: 7119136Abstract: A curable composition includes a functionalized poly(arylene ether) resin, an acryloyl monomer, and a phosphorus flame retardant. The composition exhibits an improved balance of properties such as toughness, flame retardance, heat-resistance, and moisture resistance. It is useful, for example, as an encapsulant for semiconductor products.Type: GrantFiled: September 23, 2004Date of Patent: October 10, 2006Assignee: General Electric CompanyInventors: John Robert Campbell, Bryan Duffey, John Austin Rude, Prameela Susarla, Michael Alan Vallance, Gary William Yeager, Kenneth Paul Zarnoch
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Patent number: 7115677Abstract: A flame-retardant resin composition comprises 10 to 300 parts by weight of a flame retardant (B) and 1 to 200 parts by weight of an inorganic filler (C) (a glass fiber and/or a glass flake), relative to 100 parts by weight of a base resin (A). The flame retardant (B) comprises a polyphenylene oxide-series resin and/or a polyphenylene sulfide-series resin (B1), a phosphoric ester (B2), and a nitrogen-containing cyclic compound (B3) (for example, a polyphosphate of an amino group-containing triazine compound). The inorganic filler (C) has been treated with a surface-treatment agent or sizing agent containing a novolak epoxy resin. Such a resin composition is useful for obtaining a shaped article which has been inhibited from dripping and to which flame retardancy is highly imparted.Type: GrantFiled: November 28, 2002Date of Patent: October 3, 2006Assignee: Polyplastics Co., Ltd.Inventors: Hatsuhiko Harashina, Shinya Yamada
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Patent number: 7094819Abstract: A flame retardant polytrimethylene terephthalate resin composition, comprising: 30 to 99 parts by weight of (A) a polytrimethylene terephthalate resin, and 1 to 70 parts by weight of at least one flame retardant selected from the group consisting of (B-1) phosphorus-containing flame retardant and (B-2) nitrogen-containing flame retardant, is disclosed. The composition has superior mechanical characteristics, chemical resistance, electrical characteristics, weatherability, heat aging resistance and hydrolysis resistance, and has superior moldability, good appearance with less warpage deformation when molded, and furthermore has superior flame retardance and does not generate highly corrosive hydrogen halide gas upon combustion.Type: GrantFiled: August 7, 2002Date of Patent: August 22, 2006Assignee: Asahi Kasei Chemicals CorporationInventors: Junko Kakegawa, Tomofumi Maekawa, Hideki Nakamura
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Patent number: 7084196Abstract: Polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of (i.) at least one compound selected from the group consisting of nitroxyl stabilizers, hydroxylamine stabilizers, nitrone stabilizers, substituted hydroxylamine stabilizers, amine oxide stabilizers, benzofuranone stabilizers phosphite and phosphonite stabilizers, quinone methide stabilizers and monoacrylate esters of 2,2?-alkylidenebisphenol stabilizers and (ii.) at least one compound selected from the group consisting of brominated flame retardants, phosphorus containing flame retardants and inorganic flame retardants such as ammonium polyphosphate or decabromodiphenyl oxide; wherein the amount of organic or inorganic flame retardant of component (ii.) required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when component (i.) is not present.Type: GrantFiled: March 12, 2002Date of Patent: August 1, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Malisa V. Troutman, Ramanathan Ravichandran, Rangarajan Srinivsan, Roswell Easton King, Douglas Wayn Horsey
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Patent number: 7067569Abstract: The invention relates to a synergistic mixture comprising a) at least one compound selected from the group consisting of the phosphites of the formula (I) to (V), of the phosphonites of the formulae (VI) to (IX) and (XV), of the di/oligophosphonites of the formulae (X) and (XI) and of the phosphinites of the formulae (XII) to (XIV), and b) at least one compound selected from the group consisting of the phosphanes of the formula (XVI), the di/oligophosphanes of the formulae (XVII) and (XVIII), and of the cyclophosphanes of the formula (XIX), and also to a process for stabilizing polymers with respect to thermooxidative degradation by addition and incorporation of a synergistic mixture of this type.Type: GrantFiled: July 13, 2001Date of Patent: June 27, 2006Assignee: Clariant Finance (BVI) LimitedInventor: Peter Staniek
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Patent number: 7034069Abstract: The present invention relates to highly compatible, high molecular weight hydroxyphenylbenzotriazole UV-absorbers and for their use in protecting plants in green houses and the protection of foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like from the deleterious effects of ultraviolet radiation. It has been found that certain highly compatible, high molecular weight hydroxyphenylbenzotriazole UV-absorbers are especially effective towards this end when incorporated in the containers or films in which such materials are stored.Type: GrantFiled: June 24, 2002Date of Patent: April 25, 2006Assignee: Ciba Specialty Chemicals Corp.Inventors: Dario Lazzari, Gianluca Ferri, Massimiliano Sala, Michela Bonora, Manuele Vitali
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Patent number: 7030180Abstract: A polycarbonate composition containing inorganic material with an anisotropic particle geometry and with an iron content of less than about 100 ppm is disclosed. The composition is suitable for producing molded articles exhibiting improved mechanical properties both at ambient and low temperatures.Type: GrantFiled: January 22, 2002Date of Patent: April 18, 2006Assignee: Bayer AktiengesellschaftInventors: Andreas Seidel, Thomas Eckel, Holger Warth, Dieter Wittmann
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Patent number: 7019057Abstract: A flame retardant, thermoplastic molding composition is disclosed. The composition contains A) at least one of aromatic polycarbonate and polyester carbonate, B) polyalkyl (alkyl)acrylate, C) a graft polymer the molecular structure of which is substantially free of units derived from styrene, butadiene and acrylonitrile, D) at least one organic phosphoric acid ester, E) an optional anti-drip agent, and F) optionally at least one polymer additive. The composition is characterized in its good property profile especially weld line strength, resistance to chemicals, elongation at break, thermal stability and melt flowability.Type: GrantFiled: February 2, 2004Date of Patent: March 28, 2006Assignee: Bayer AktiengesellschaftInventors: Andreas Seidel, Thomas Eckel
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Patent number: 7005465Abstract: The present invention offers a resin composition for user as a covering material for wires and cables that excels in fire retardancy with non-halogen, chemical resistance and melting properties, and also excels in workability, heat resistance, impact resistance and flexibility. A resin composition for wires and cables covering material is obtained by blending polyphenylene ether resin with syndiotactic polystyrene polymer, atactic polystyrene resin and non-halogen fire retardant or blending polyphenylene ether resin with syndiotactic polystyrene polymer, atactic polystyrene resin, non-halogen fire retardant and thermoplastic elastomer in fixed ratios.Type: GrantFiled: August 1, 2003Date of Patent: February 28, 2006Assignee: General ElectricInventor: Sho Sato
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Patent number: 6964989Abstract: This invention relates generally to water resistant peelable protective and decorative clear or pigmented coating compositions and, more specifically, to solvent and aqueous based, polymeric coating compositions which form a protective and/or decorative coating on a variety of substrates, including automotive paints, metals, plastics, concrete, natural and synthetic elastomers, and ceramics. The coatings are be formulated for temporary or long term protection depending upon the application.Type: GrantFiled: March 27, 2003Date of Patent: November 15, 2005Assignee: Ashland Inc.Inventors: Jiafu Fang, Zhiqiang Zhang, Frances E. Lockwood, Richard J. Baumgart, Michael A. Dituro
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Patent number: 6956073Abstract: A flame-retardant resin composition comprising (A)(1) a resin component containing an aromatic polycarbonate resin and a styrene-containing resin or (2) a resin component containing a polyphenylene ether resin and a polystyrene, and (B) a flame retardant that is a phosphoric ester of the following formula (I), wherein each of R1, R2, R3 and R4 is independently an aryl group having 6 to 12 carbon atoms, each of R5 and R6 is independently methyl or a hydrogen atom, each of R7 and R8 is methyl, m1 and m2 are 0 or integers of 1 or 2, each of a, b, c and d is independently 0 or 1, and n is 0 or an integer of 1 or 5.Type: GrantFiled: November 21, 2002Date of Patent: October 18, 2005Assignee: Teijin Chemicals, Ltd.Inventors: Makoto Takagi, Tetsuya Aibara
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Patent number: 6939905Abstract: A molding composition characterized by its improved processability and flame resistance, suitable especially for extrusion is disclosed. The composition that contains polycarbonate, an impact modifier and a halogen-free phosphous-containing flameproofing agent features flame resistance of V-0 in the UL 94 V fire behavior test at wall thickness ?1.5 mm and a melt viscosity, measured at 260° C.Type: GrantFiled: February 21, 2001Date of Patent: September 6, 2005Assignee: Bayer AktiengesellschaftInventors: Andreas Seidel, Thomas Eckel, Bernd Keller, Dieter Wittmann
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Patent number: 6930138Abstract: A flame retarding and smoke suppressing additive powder that can be mixed with resins includes a carbonific material, a heat activated blowing agent, a heat activated halogen material, a phosphate material, and an inorganic material. The additive powder, when added to a curable or hardenable resin, forms a mixture where the additive powder is about 20-30%, by weight, of the mixture. The resin can be styrenic, olefinic, acrylic, cellulosic, polyester, or polyamide such as are commonly used in the manufacture of fiberglass reinforced structures and moldable plastics.Type: GrantFiled: August 5, 2004Date of Patent: August 16, 2005Assignee: Avtec Industries, Inc.Inventors: Kevin Schell, John B. Rowen, Anthony S. Camarota
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Patent number: 6921784Abstract: A polycarbonate resin molding material containing (A) 100 parts by weight of a polycarbonate resin and 0.001 to 1.0 part by weight of a mold release agent (B) which is composed of a fatty acid ester and a phosphorus-containing heat stabilizer and contains 0.0001 to 50 parts by weight, per 100 parts by weight of the fatty acid ester (b1), of the phosphorus-containing heat stabilizer (b2). The present invention provides a polycarbonate resin molding material excellent in mold releasability and heat resistance during molding, and a molded article therefrom. According to the present invention, particularly, there is provided a polycarbonate resin molding material excellent in mold releasability and thermal stability during molding and suitable for producing a optical disk by incorporating a small amount of a mold release agent and a heat stabilizer.Type: GrantFiled: July 24, 2002Date of Patent: July 26, 2005Assignee: Teijin Chemicals, Ltd.Inventors: Yutaka Dohi, Masaki Shiomi
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Patent number: 6906124Abstract: A translucent thermoplastic molding composition containing polycarbonate, phosphorous compound and a fluorinated polyolefin is disclosed. Characterized in its excellent flame proofing, optical properties and resistance to chemicals the composition is suitable for making articles that in the course of use come in contact with solvents lubricants and cleaning compositions.Type: GrantFiled: May 21, 2001Date of Patent: June 14, 2005Assignee: Bayer AktiengesellschaftInventors: Torsten Derr, Thomas Eckel, Michael Zobel, Dieter Wittmann, Andreas Seidel
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Patent number: 6878763Abstract: The free radical initiated addition polymerization of ethylenically unsaturated, particularly acrylic monomers in which the dispersed phase is stabilised by a surfactant including at least one anionic surfactant compound of the formula (I): R1—(OA)n—X where R1 is C16 to C22 hydrocarbyl including at least two double bonds; OA is oxyalkylene group; n is from 2 to 60; and X includes at least one acidic H atom, and is particularly a phosphate ester group, or a salt thereof, is described. The use of the surfactants of the formula (I) enable efficient emulsification and thus polymerization at temperatures above those at which non-ionic unsaturated surfactants are effective. The polymer latex products give polymer films having good water resistance properties.Type: GrantFiled: April 17, 2002Date of Patent: April 12, 2005Assignee: Imperial Chemical Industries PLCInventors: Trevor Graham Blease, Johny Denis Grade
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Patent number: 6849675Abstract: A golf ball comprising a core and a cover layer, wherein at least one of the core or cover layer comprises a plasticized polyurethane composition comprising at least one polyurethane and at least one plasticizer.Type: GrantFiled: January 23, 2002Date of Patent: February 1, 2005Assignee: Acushnet CompanyInventor: Michael J. Sullivan
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Patent number: 6846866Abstract: The invention provides polyurethane containing a) a first additive comprising at least one mono-hindered hydroxyphenyl group and having a molecular weight of at least about 300 Daltons; b) a second additive selected from the group consisting of i) condensation polymers of p-cresol and divinyl benzene and ii) compounds comprising at least one unsymmetrically di-hindered hydroxyphenyl group and having a molecular weight of at least about 300 Daltons; and c) an inorganic chlorine-resist additive. The polyurethane of the invention exhibits improved resistance to degradation by chlorine and by atmospheric fumes.Type: GrantFiled: June 3, 2002Date of Patent: January 25, 2005Assignee: Invista North America S.a.r.L.Inventors: Nathan E. Houser, Gordon W. Selling
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Patent number: 6838503Abstract: A resin composition useful for wire and cable covering material is formed by compounding a phosphate ester retardant, boron phosphate, and zinc borate hydrate with a polyphenylene ether group resin or a combination of a polyphenylene ether group resin and an aromatic vinyl group resin, in a specific ratio.Type: GrantFiled: June 28, 2002Date of Patent: January 4, 2005Assignee: General Electric CompaInventors: Ming Yin, Takuro Kitamura, Atsuo Oshiro, Kenichi Ishiwa, Kazunari Kosaka, Hiroshi Kubo
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Patent number: 6822026Abstract: The present invention relates to a flame-retardant polypropylene resin composition comprising (A) polypropylene resin 20-60% by weight, (B) polyphenylene ether-based resin 1-50% by weight, (C) hydrogenated block copolymer of a vinylaromatic compound and conjugated diene, which mainly is based on vinylaromatic compound, 0.1-15% by weight, (D) aromatic phosphoric ester in phenol strucure 1-20% by weight, (E) polyammonium phosphate 1-20% by weight, and (F) pentaerythritol-based flame retardant auxiliary agent 0.1-13% by weight. The weight ratio of the aromatic phosphoric ester in phenol structure to the polyammonium phosphate is preferably 0.2-5.0. The composition has advanced flame-retardant and heat-resistant property, and processing property.Type: GrantFiled: July 2, 2003Date of Patent: November 23, 2004Assignee: Sansung General Chemicals Co.Inventors: In Sik Jung, Jong Soo Hong, Man Seang Her, Won Beum Jung