P Directly Bonded To Oxygen Only Patents (Class 524/140)
  • Patent number: 5369160
    Abstract: Disclosed is a thermoplastic polyamide with reduced flammability obtained by melt mixing a polyamide with a phosphate ester of the general formula: ##STR1## wherein n is a number of from 1 to 10;m is a number of from 0 to 3;x is a number of from 0 to 3;R is linear or branched C.sub.1 -to C.sub.18 -alkyl radical.
    Type: Grant
    Filed: September 24, 1992
    Date of Patent: November 29, 1994
    Assignee: BASF Corporation
    Inventors: Atish Adyha, Robert L. Lilly
  • Patent number: 5367011
    Abstract: Blends of low molecular weight PBT resin and high molecular weight polyester resin, such as high molecular weight PBT resin, are imparted with excellent melt viscosity stability by the addition of certain phosphorus-containing compounds.
    Type: Grant
    Filed: December 8, 1993
    Date of Patent: November 22, 1994
    Assignee: General Electric Company
    Inventor: Eileen B. Walsh
  • Patent number: 5322870
    Abstract: An additive package can be used in a single-coat, in situ self-phosphatizing paint to provide a phosphate layer that inhibits corrosion of a surface on which the paint is applied. The additive package includes an amine and a phosphatizing reagent that can be an alkyl-, phenyl- or aryl- ester phosphoric acid or an alkyl-, phenyl- or aryl-phosphonic acid. The reagent and the amine are present in a ratio effective to produce reagent-amine complexes. A paint can include the additive package in addition to a polymer coat forming resin and a cross-linking agent.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: June 21, 1994
    Assignee: Board of Regents, Northern Illinois University
    Inventor: Chhiu-Tsu Lin
  • Patent number: 5322883
    Abstract: Disclosed is a thermoplastic polyester with reduced flammability obtained by:(a) condensating an aromatic dicarboxylic acid and an alkylene glycol in a mole ratio of from 1:1.1-1.5 at a temperature of from 180.degree. to 240.degree. C. in the presence of a catalyst;(b) adding a polyalkylene glycol phosphate ester;(c) polycondensating at a temperature of from 265.degree. to 280.degree. C. under a pressure decreasing from 760 torr to less than 2 torr until an intrinsic viscosity of about 0.5 to about 0.7 is reached.
    Type: Grant
    Filed: September 24, 1992
    Date of Patent: June 21, 1994
    Assignee: BASF Corporation
    Inventors: Atish Adyha, Thomas F. Corbin, Robert L. Lilly
  • Patent number: 5302646
    Abstract: A thermoplastic blend composition is provided containing an aromatic polycarbonate, a phosphate flame retardant and a hydroxy functional graft copolymer. The compositions exhibit flame retardancy and low gloss and are useful as molding resins.
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: April 12, 1994
    Assignee: General Electric Company
    Inventors: Shripathy Vilasagar, Herbert S. Rawlings
  • Patent number: 5276256
    Abstract: A molding composition containing, based on the total weight of the composition:A) at least 40% by weight of at least one halogen-free polycarbonate;B) 5-40% by weight of at least one halogen-free graft copolymer composed of;1) 40-80% by weight of an elastomer with a glass transition temperature below 0.degree. C., which elastomer is composed of, at least 50% by weight of a diene or of an at least C.sub.4 -alkyl acrylate, 1-40% by weight of a halogen-free phosphorus compound of the formula ##STR1## 2) 20-60% by weight of a shell composed of, 40-98% by weight of styrene, .alpha.-alkylstyrene, nuclear-substituted styrene and/or C.sub.1 -C.sub.8 -alkyl (meth)acrylate, and 2-60% by weight of (meth)acrylonitrile and/or maleic anhydride;C) 5-40% by weight of a halogen-free thermoplastic copolymer composed of, 50-95% by weight of styrene, .alpha.-alkylstyrene, nuclear-substituted styrene and/or C.sub.1 -C.sub.
    Type: Grant
    Filed: September 25, 1992
    Date of Patent: January 4, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Niessner, Rainer Neumann, Karl Ruppmich, Friedrich Seitz, Doris Zeltner
  • Patent number: 5272193
    Abstract: Thermoplastic polycarbonate moulding compounds containing 40 to 90 parts by weight of a thermoplastic aromatic polycarbonate; 0 to 80 parts by weight of a copolymer or polycondensate consisting of 0 to 50 parts by weight of a thermoplastic copolymer of 50 to 95% by weight of styrene, .alpha.-methylstyrene, styrene alkylated in the nucleus, halogenated styrene or mixtures thereof and 5 to 50% by weight of acrylonitrile, methacrylonitrile, alkyl acrylate, alkyl methacrylate, maleic acid anhydride, N-substituted maleiimide, vinyl acetate or mixtures thereof and/or 0 to 80 parts by weight of a thermoplastic polyalkylene terephthalate; 1 to 25 parts by weight of graft polymer prepared from 5 to 90 parts by weight of a mixture of: 50 to 95% by weight of styrene, .alpha.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: December 21, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott
  • Patent number: 5270381
    Abstract: A thermoplastic elastomer composition comprising, as the main blend components, 100 parts by weight of a crystalline chlorinated polyethylene with a chlorination degree of from 20 to 45% and a heat of crystal fusion of from 5 to 35 cal/g as measured by a DSC method and from 10 to 75 parts by weight of a plasticizer.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: December 14, 1993
    Assignee: Mitsubishi Kasei Vinyl Company
    Inventors: Masahiro Yamanaka, Kazuya Hori, Hiroyuki Mori, Naoki Ichikawa, Mizuo Washimi
  • Patent number: 5266618
    Abstract: A flame-retardant resin composition comprising the following components (A), (B), (C) and (D): (A) 100 parts by weight of a thermoplastic resin comprising 1 a polycarbonate resin, or 2 a polycarbonate resin and a non-polycarbonate resin, (B) from 0.1 to 40 parts by weight of a phosphorus compound, (C) from 0.001 to 40 parts by weight of a boron compound, and (D) from 0.01 to 5 parts by weight of a polyorganosiloxane and/or from 0.001 to 5 parts by weight of a fluorine resin.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: November 30, 1993
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Jun Watanabe, Noriaki Kudo
  • Patent number: 5234979
    Abstract: The present invention relates to thermoplastic moulding compositions consisting of halogen-free polycarbonates, halogen-free polystyrene and/or halogen-free copolymers of styrene with acrylonitrile, halogen-free phosphorus compounds of the formula I ##STR1## and tetrafluoroethylene polymers, and, if appropriate, other known additives.
    Type: Grant
    Filed: January 25, 1988
    Date of Patent: August 10, 1993
    Inventors: Gert Todtemann, Klaus Reinking
  • Patent number: 5225463
    Abstract: Self-extinguishing polymeric compositions containing: a) from 90 to 40 parts by weight of a thermoplastic polymer, or a polymer having elastomeric properties and b) 10 to 60 parts by weight of one or more 2,4,6-triamino-1,3,5-triazine compounds salified with an oxygenated acid of phosphorus, wherein at least one of the triamino substituents of the triazine compound are substituted with at least one of the following radicals ##STR1## wherein m=an integer between 2 and 8;p=an integer between 2 and 6;R.sub.8 =H; C.sub.1 -C.sub.8 alkyl; C.sub.2 -C.sub.6 alkenyl; C.sub.q H.sub.2q OR.sub.9 wherein q is an integer between 1 and 4 and R.sub.9 is hydrogen or C.sub.1 -C.sub.4 alkyl; C.sub.6 -C.sub.12 cycloalkyl or alkylcycloalkyl;R' is H; C.sub.1 -C.sub.8 alkyl; C.sub.2 -C.sub.6 alkenyl; C.sub.6 -C.sub.12 cycloalkyl or alkylcycloalkyl; C.sub.1 -C.sub.4 hydroxyalkyl, or ##STR2## is replaced by a heterocyclic radical bound to the alkyl chain through the nitrogen atom.
    Type: Grant
    Filed: April 11, 1991
    Date of Patent: July 6, 1993
    Assignee: Ministero dell'Universita e della Ricerca Scientifica e Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Gilberto Nucida, Mario Pirozzi, Enrico Masarati
  • Patent number: 5219907
    Abstract: A flame retardant molding composition contains a halogen-free polycarbonate at least one halogen-free graft copolymer assembled from copolymerized units of an elastomer and certain ethylenically unsaturated monomers which include 1-50% by weight of an organic phosphorus compound of the formula (I) ##STR1## a halogen-free thermoplastic copolymer comprising styrene, .alpha.-alkylstyrene, nuclear-substituted styrene and/or C.sub.1 -C.sub.8 -alkyl (meth)acrylate, and (meth)acrylonitrile and/or maleic anhydride, as well as 1-46% by weight of a halogen-free phosphorus compound of the formula (I): Optionally a monophosphate additive and up to 5% by weight of a polytetrafluoroethylene with a median particle size of from 0.05 to 20 .mu.m may be added.
    Type: Grant
    Filed: September 25, 1992
    Date of Patent: June 15, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Niessner, Rainer Neumann, Karl Ruppmich, Friedrich Seitz, Doris Zeltner
  • Patent number: 5204393
    Abstract: An improved flame retardant polyolefin is disclosed which comprises a combination of ammonium polyphosphate; tris(2-hydroxyethyl) isocyanurate; and melamine cyanurate; and a selected silica in an amount from 0.5 percent to an amount equal to one-half the amount by weight of THEIC, wherein the selected silica meets defined surface area, particle size and absorption criteria.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: April 20, 1993
    Assignee: Hoechst Celanese Corporation
    Inventors: Raymond W. Nalepa, Daniel J. Scharf
  • Patent number: 5204391
    Abstract: Provided are novel blocked polyisocyanurates to be suitably used as an adhesiveness providing agent, coating material, sealant and crosslinking agent for polymers containing active hydrogens. Also provided are polyvinyl chloride plastisol compositions comprising a polyvinyl chloride resin, the above blocked polyisocyanurate as an adhesiveness providing agent, plasticizer and a specific agent for accelerating dissociation of the blocked polyisocyanurate. These compositions have excellent properties such as high adhesiveness even cured at low temperatures and resistance to yellowing, and are suitably used particularly as sealants for car body.
    Type: Grant
    Filed: July 23, 1992
    Date of Patent: April 20, 1993
    Assignee: Sunstar Engineering, Inc.
    Inventors: Yoshihiro Nakata, Hirohide Tomoyasu
  • Patent number: 5204392
    Abstract: An improved flame reardant polyolefin is disclosed which comprises a combination of ammoniumm polyphosphate; tris(2-hydroxyethyl) isocyanurate; and a selected silica in an amount from 0.5 percent to an amount equal to one-half the amount by weight of THEIC, wherein the silica meets defined surface arera, particle size and absorption criteria.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: April 20, 1993
    Assignee: Hoechst Celanese Corporation
    Inventors: Raymond W. Nalepa, Daniel J. Scharf
  • Patent number: 5185393
    Abstract: A water-in-oil emulsion of a cationic polymer suitable for inversion, comprising a continuous phase comprising a hydrophobic liquid, a discontinuous phase comprising a water-soluble cationic polymer, and a surface active agent system for inventing the emulsion in water, the system comprising a mixture of at least one alkyl phosphate represented by formula (I) or (II) and at least one other surface active agent compatible with the at least one alkyl phosphate: ##STR1## wherein R.sub.1 represents a saturated or unsaturated hydrocarbon group having from 8 to 18 carbon atoms; X and Y, which may be the same or different, each represents a hydrogen atom, an alkali metal, an ammonium group, or an alkanolamino group; and n1 represents 0 or an integer of from 1 to 4; ##STR2## wherein R.sub.2 and R.sub.
    Type: Grant
    Filed: December 28, 1990
    Date of Patent: February 9, 1993
    Assignee: Nitto Chemical Industry Co., Ltd.
    Inventors: Shoichi Kanda, Takeshi Narita, Masahiro Ushigome, Masaharu Nagahama
  • Patent number: 5147912
    Abstract: A two step method of preparing fire retardant thermoplastic polymer granules from fire retarding agents and thermoplastic polymers in a stationary granulating cylinder containing mixing elements mounted to a central rotating shaft which fluidizes and throws contained materials toward the center of the cylinder, forcing axial and radial flows simultaneously on the materials thereby forming granules. In the first step, a fire retarding agent is mixed with a fluid thermoplastic polymer at a temperature exceeding the solidification point of the polymer until a homogeneous mixture is formed. In the second stage, the mixture is solidified by cooling while the granulating cylinder continues to operate until the fire retardant agent is bound together in homogeneous granular form by a matrix of solid thermoplastic polymer. Suitable fire retarding agents include alumina, phosphates, borates, melamine, melamine cyanurate, metal cyanurates, and halogenated phenols.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: FR Polymers, Inc.
    Inventor: William P. Moore
  • Patent number: 5137953
    Abstract: The invention relates to thermoplastic molding compounds containing thermoplastic aromatic polycarbonates, thermoplastic copolymers, optionally graft polymers and/or tetrafluoroethylene polymers and/or silicone resins, characterized in that they contain phosphorus compounds corresponding to formula (I) ##STR1## in which R is a --CH.sub.2 --, ##STR2## group and the aromatic radicals may even be alkyl-substituted.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: August 11, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott, Jochen Schoeps, Horst Peters, Werner Ballas
  • Patent number: 5137952
    Abstract: Free radical-curable compositions comprising a plastisol component and a copolymer containing free anhydride functionality and, optionally, other reactive diluents are provided. In particular, curable compositions employing a plastisol, preferably a polyvinyl chloride-containing plastisol, and a low molecular weight crosslinking copolymer component having free anhydride functionality and which is a partial esterification product of a terminally ethylenically unsaturated compound and a polymerizable maleic anhydride are provided. The compositions of the invention yield improved adhesives, sealants, coatings, and insulators for a wide variety of substrates and may be employed in a variety of coatings and castings. Processes for preparing cured plastisol compositions from the disclosed free radical-curable compositions are also provided.
    Type: Grant
    Filed: September 26, 1991
    Date of Patent: August 11, 1992
    Assignee: Sartomer Company, Inc.
    Inventors: Henry C. Miller, Michael A. Bailey, David L. Weaver
  • Patent number: 5134182
    Abstract: A composition based upon a blend of lower alkyl or lower alkoxyalkyl polyacrylate ester elastomers with one or more materials selected from liquid butadiene acrylonitrile copolymers and halogenated fire-retardant plasticizers. Blends with the liquid butadiene acrylonitrile copolymers include from about 5 to about 50% by weight of the copolymer and from about 50 to about 95% by weight of the polyacrylate ester elastomer. Blends with the halogenated fire-retardant plasticizer include from about 5 to about 100 parts by weight of the halogenated fire-retardant plasticizer per 100 parts of the polyacrylate ester elastomer. Hydrocarbon-resistant sealant compositions further contain effective amounts of one or more plasticizers in amounts effective to plasticize the blend together with one or more reinforcing materials.
    Type: Grant
    Filed: August 1, 1990
    Date of Patent: July 28, 1992
    Assignee: Thomas & Betts Corporation
    Inventor: Kwang-Ho Chu
  • Patent number: 5130358
    Abstract: A cationic polymer composition suitable for use as a flocculating agent and as a retention aid in paper making consists of a mixture ofa) a hydrophilic cationic polymer,b) an anionic surfactant,optionally c) a water-immeriscible oil in which the polymer a) is insoluble,and, if c) is present,optionally d) a lipophilic non-ionic surfactant,optionally e) waterand optionally f) an oil-miscible polar solvent.The compositions may be prepared by water-in-oil emulsion polymerisation and are readily diluted with water.
    Type: Grant
    Filed: March 22, 1989
    Date of Patent: July 14, 1992
    Assignee: Sandoz Ltd.
    Inventor: Bernard Danner
  • Patent number: 5130452
    Abstract: Compounds of general formula I ##STR1## wherein X.sub.1 is chloro or bromo,X.sub.2 is chloro, bromo or hydrogen, andY is O or S, andR.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.4 alkyl, andR.sub.3 and R.sub.4 is a group of formula II ##STR2## which carries identical or different substituents and wherein R.sub.1, R.sub.2, X.sub.1 and X.sub.2 are as defined above, or R.sub.3 and R.sub.4, when taken together, form a group of formula III ##STR3## wherein R.sub.1 and R.sub.2 are as defined above, are very suitable flame retardants for polymers.
    Type: Grant
    Filed: May 6, 1991
    Date of Patent: July 14, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Flury, Wolfgang Scharf
  • Patent number: 5126388
    Abstract: The present invention relates to a process for producing a plastic lens having a high refractive index and profile regularity comprising forming a mixture of one or more of sulfur-containing aromatic polyisocyanate compounds, one or more of active hydrogen compounds selected from the group consisting of polyol compounds and polythiol compounds, and at least one internal mold releasing agent, and subjecting the resulting mixture to casting polymerization, and a plastic lens obtained according to the process.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: June 30, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Teruyuki Nagata, Koju Okazaki, Nobuyuki Kajimoto, Tohru Miura, Yoshinobu Kanemura, Katsuyoshi Sasagawa
  • Patent number: 5079299
    Abstract: This invention provides a mold release composition copmrising (1) a compound or a polymer having at least one of perfluoroalkyl groups having 4 to 20 carbon atoms and perfluoroalkenyl groups having 4 to 20 carbon atoms, and (2) a ladder polymer of organosilsesquioxane.
    Type: Grant
    Filed: July 16, 1989
    Date of Patent: January 7, 1992
    Assignee: Daikin Industries, Ltd.
    Inventors: Iwao Hisamoto, Masayoshi Shinjyo, Seiji Takubo, Yasuko Katakura
  • Patent number: 5061745
    Abstract: The invention relates to polycarbonate molding compounds consisting of halogen-free polycarbonates, graft polymers, phosphorus compounds, tetrafluoroethylene polymers and, optionally, copolymers and/or, optionally, other additives known per se and a process for their production.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: October 29, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Wittmann, Horst Peters, Jochen Schoeps, Hans-Jurgen Kress, Josef Buekers, Karl-Heinz Ott
  • Patent number: 5055495
    Abstract: An improvement in the method for the foaming of polyvinylchloride resins by the use of a blowing agent and an activator therefor which uses as the activator a mixture of at least one organotin mercapto acid ester and a diorganotin oxide complex with an ester of an oxygen-containing acid.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: October 8, 1991
    Assignee: Witco Corporation
    Inventors: Michael R. Croce, Stuart D. Brilliant
  • Patent number: 5034281
    Abstract: The present invention provides resin compositions comprising a blend of two different saponified products of ethylene-vinyl acetate copolymers. The composition is much improved compared to a single EVOH in flexibility without adversely affecting the transparency and gas barrier property. Laminate films comprising at least one layer of said composition are excellent in resistance to dropping shock, ability to prevent air-back, skin-pack adaptability and shrink-packaging capability.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: July 23, 1991
    Assignee: Kuraray Co., Ltd.
    Inventors: Akihiko Kawasaki, Tohei Moritani
  • Patent number: 5030675
    Abstract: Flame-resistant molding compounds of polycarbonate, polyalkylene terephthalate, graft polymer, fluorinated polyolefine and phosphorus compound can be worked up into moulded products which have a particularly advantageous combination of joint line strength, dimensional stability under heat and toughness.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: July 9, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Wittmann, Hans-Jurgen Kress, Horst Peters, Josef Buekers, Christian Lindner
  • Patent number: 5025058
    Abstract: A flame-resistant non-drying putty composition is prepared by adding 2 to 20 parts by weight of an unvulcanized solid rubber, 10 to 50 parts by weight of a plasticizer, 300 to 800 parts by weight of a metal hydrate, 20 to 200 parts by weight of a foliated talc, and 0.5 to 5 parts by weight of an organic fiber to 100 parts by weight of one type of liquid resin having a viscosity of 5,000 to 200,000 centipoise at room temperature or a mixture of two or more types thereof and kneading the resultant mixture.
    Type: Grant
    Filed: May 23, 1990
    Date of Patent: June 18, 1991
    Assignee: The Furukawa Electric Co., Ltd.
    Inventor: Atsuyoshi Senoo
  • Patent number: 5021489
    Abstract: This invention relates to corrosion-inhibiting compositions and particula to compositions capable of forming films on metal substrates to protect said metal from corrosion. The film-forming compositions which are capable of displacing moisture from the metal surface comprises effective amounts of an acrylic resin, a silicone resin and a copolymer derived from a silicone and alkyd monomers. These resins together with effective amounts of an organic phosphate and a sulfonate are used in combination with lower molecular weight alcohols and at least one solvent.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: June 4, 1991
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Walter E. Knight, Kenneth G. Clark, David L. Gauntt
  • Patent number: 5021490
    Abstract: An internally plasticized polyvinyl halide composition is prepared by polymerizing a vinyl halide in the presence of a reactive polyester plasticizer having terminal groups copolymerizable therewith. The reactive polyester acts as an internal plasticizer for the polyvinyl halide composition and is not readily extactable therefrom.
    Type: Grant
    Filed: August 3, 1989
    Date of Patent: June 4, 1991
    Assignee: The B. F. Goodrich Company
    Inventors: Josef C. Vyvoda, James T. Harvilchuck
  • Patent number: 4977193
    Abstract: An improvement in the method for the foaming of polyvinylchloride resins by the use of a blowing agent and an activator therefor which uses as the activator a mixture of at least one organotin mercapto acid ester and a diorganotin oxide complex with an ester of an oxygen-containing acid.
    Type: Grant
    Filed: May 4, 1990
    Date of Patent: December 11, 1990
    Assignee: Witco Corporation
    Inventors: Michael R. Croce, Stuart D. Brilliant
  • Patent number: 4957965
    Abstract: Thermoplastic molding materials contain, as essential components,(A) 5-95% by weight of a polyamide;(B) 5-95% by weight of a modified polyphenylene ether, prepared from(b.sub.1) 4.95-99.9% by weight of a polyphenylene ether,(b.sub.2) 0-90% by weight of a vinylaromatic polymer,(b.sub.3) 0.05-10% by weight of one or more compounds from the group consisting of(b.sub.31) an .alpha.,.beta.-unsaturated dicarbonyl compound,(b.sub.32) a monomer containing amide groups and a polymerizable double bond and(b.sub.33) a monomer containing lactam groups and a polymerizable double bond,(b.sub.4) 0-80% by weight of further graft-active monomers and(b.sub.5) 0.01-0.09% by weight of a free radical initiator,(C) 0-90% by weight of an unmodified polyphenylene ether,(D) 0-45% by weight of a vinylaromatic polymer and(E) 0-40% by weight of a rubber impact modifier.
    Type: Grant
    Filed: August 5, 1988
    Date of Patent: September 18, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Christof Taubitz, Klaus Muehlbach, Hermann Brandt, Klaus Boehlke
  • Patent number: 4942189
    Abstract: The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 1,000 cps; forming an interpolymer complex of neutralized sulfonated polymer (water insoluble) and copolymer of styrene/vinylpyridine in the solvent system to form a solution, a concentration of the water insoluble interpolymer complex polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; the admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and interpolymer complex transferring from the organic liquid to the water phase, thereby causing the water phase to gel (i.e., thicken).
    Type: Grant
    Filed: July 31, 1989
    Date of Patent: July 17, 1990
    Assignee: Exxon Research and Engineering Company
    Inventors: Dennis G. Peiffer, Robert D. Lundberg, Ilan Duvdevani
  • Patent number: 4929648
    Abstract: A binder composition which comprises an aqueous alkaline solution of a phenolic resole resin and an additive wherein the additive is phenoxyethanol or a derivative of phenoxyethanol.
    Type: Grant
    Filed: March 24, 1989
    Date of Patent: May 29, 1990
    Assignee: Acme Resin Corporation
    Inventors: David R. Armbruster, Kwok-Tuen Tse
  • Patent number: 4927870
    Abstract: Ignition resistant non-haloaromatic containing thermoplastic polymer compositions are disclosed which are mixtures of (1) a non-carbonate polymer such as a polyester terephthalate, a polyacetal, a polymethylmethacrylate and the like, (2) a carbonate polymer, or (3) a blend of (1) and (2) with a high elastic memory polytetrafluoroethylene, an organic phosphate, and a metal salt of an inorganic acid.
    Type: Grant
    Filed: August 25, 1988
    Date of Patent: May 22, 1990
    Assignee: The Dow Chemical Company
    Inventors: Samuel A. Ogoe, Thoi H. Ho
  • Patent number: 4925890
    Abstract: A process for enhancing the fabrication of thermoplastic polymers entailing the addition of from 0.01 to 1 part, per hundred parts of thermoplastic polymer, of a processing aid, said processing aid comprising a processing additive, such as a silicon or a polyol, and a processing adjuvant, such as a phosphate.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: May 15, 1990
    Assignee: Union Carbide Chemicals and Plastics Company Inc.
    Inventors: Pak S. Leung, Errol D. Goddard, Fred H. Ancker
  • Patent number: 4916176
    Abstract: An aqueous coating composition comprising a film-forming material, a metallic pigment, phosphate inhibitor being either an orthophosphoric acid or an organic acid ester of phosphoric acid containing a group of formula (I): ##STR1## a cationic salt of one or more of the following metals: sodium, potassium, magnesium, calcium, strontium, barium, vanadium, cobalt, nickel, copper, zinc or silver; and a water containing diluent.
    Type: Grant
    Filed: May 6, 1988
    Date of Patent: April 10, 1990
    Assignee: Imperical Chemical Industries PLC
    Inventors: Zafirios Vachlas, Stephen J. Thorne
  • Patent number: 4889879
    Abstract: Coherent thermoplastic aggregates with very high content of pulverized mineral materials, composed of the said materials, of polyolefin polymers and/or copolymers, and possibly also of various familiar adjuvants, characterized by the fact that, in order for them to have both a volumetric mass close to or at most equal to the theoretical volumetric mass of the pulverized mineral substances entering into their composition and an excellent compatibility with redispersion polymers, the polymers and/or copolymers entering into the composition of the said aggregates in presence of a fluidizing agent are chosen within the group of thermoplastics with melting and/or softening point at least equal to 60.degree. C. and index of fluidity at least 50 (measured according to the standard ASTM D 1238) of the polyolefin type, other than those containing a polar monomer.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: December 26, 1989
    Assignee: Pluess Staufer AG
    Inventors: Henry Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
  • Patent number: 4883835
    Abstract: This invention relates to mixtures of polycarbonates with graft polymers and copolymers which have been rendered flame resistant and which are characterized by containing modified polyalkylene ethers as antistatic agents.
    Type: Grant
    Filed: March 31, 1988
    Date of Patent: November 28, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Josef Buysch, Norbert Schon, Hans-Jurgen Kress, Herbert Eichenauer, Josef Buekers
  • Patent number: 4871590
    Abstract: A thixotropic hot-melt adhesive contains reactive silane groups and is still viscous and plastically moldable after cooling. It contains a mixture ofat least one thermoplastic material, andat least one thixotropic agent,wherein silane groups are contained either in the thermoplastic material itself or in at least one added silane-based binder.
    Type: Grant
    Filed: November 6, 1987
    Date of Patent: October 3, 1989
    Assignee: Sika AG, vorm. Kaspar Winkler & Co.
    Inventors: Peter W. Merz, Lutz-Dieter Zabel
  • Patent number: 4863983
    Abstract: An extrudable composition comprising hydrocarbon polymer, organophosphite or organophosphate compound and fluorocarbon polymer. The organophosphite or organophosphate and the fluorocarbon polymer are present in the composition in such relative proportions and concentrations as to reduce the occurrence of melt defects during the extrusion of said thermoplastic hydrocarbon polymer.
    Type: Grant
    Filed: April 15, 1988
    Date of Patent: September 5, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Bryce V. Johnson, Joyce M. Kunde
  • Patent number: 4812499
    Abstract: Compositions of thermoplastic polymers comprising, in mixture, a thermoplastic polymer and a mixture of self-extinguishability-conferring additives, formed by:ammonium phosphate or ammonium polyphosphate: ##STR1## (wherein p is preferably equal to or greater than 50); phosphorus-containing compound definable by means of the general formula: ##STR2## (wherein R.sub.1, R.sub.2 and R.sub.3 have the meaning as indicated in the disclosure).
    Type: Grant
    Filed: March 20, 1986
    Date of Patent: March 14, 1989
    Assignee: Enichem Sintesi S.p.A.
    Inventors: Gioacchino Cipriani, Gianluigi Landoni
  • Patent number: 4803231
    Abstract: Coherent thermoplastic aggregates with very high content of pulverulent mineral materials, said aggregates comprised of the said mineral materials, further of polyolefin polymers and/or copolymers, and possibly additionally of miscellaneous known additives; characterized in that, with the aim of achieving a density near to or at most equal to the theoretical density of the pulverulent mineral materials entering into their composition, while still having excellent compatibility with the polymers of redispersion, i.e., the polymers into which the subject aggregates are to be mixed, the interparticle voids between the grains of the mineral materials, which grains are basically in contact with each other, are at most filled--in the presence of a fluidifacient agent--by at least one polyolefin polymer and/or copolymer having a fusion temperature and/or softening temperature at least equal to 60.degree. C., and having a fluidity index (ASTM 1238) of at least 50.
    Type: Grant
    Filed: October 29, 1985
    Date of Patent: February 7, 1989
    Assignee: Pluess Staufer A. G.
    Inventors: Henri Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
  • Patent number: 4788238
    Abstract: The present invention provides thermoplastic flame-retardant moulding compositions containing halogen-containing copolycarbonates, styrene/maleic anhydride copolymers, phosphorus compounds of the formula (I) ##STR1## and tetrafluoroethylene polymers and, if desired, further known additives.
    Type: Grant
    Filed: September 21, 1987
    Date of Patent: November 29, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gert Todtemann, Klaus Reinking, Otto Koch, Kress Hans-Jurgen, Lindner Christian, Friedemann Muller, Horst Peters, Josef Buekers
  • Patent number: 4788232
    Abstract: Resinous pigment concentrates comprising at least one pigment and a dispersing additive of a naphthenic extender oil and/or a phosphate ester blended with a major portion of a resinous polymer containing a significant proportion of at least one polymerized conjugated diene monomer, when used for coloring resinous polymers as described, are effective in reducing such defects in finished articles as gels and surface blemishes.
    Type: Grant
    Filed: October 23, 1987
    Date of Patent: November 29, 1988
    Assignee: Phillips Petroleum Company
    Inventor: Donald G. Needham
  • Patent number: 4769179
    Abstract: This invention provides a flame-retardant resin composition comprising (A) about 100 parts by weight of at least one resin selected from the group consisting of ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, isobutylene-isoprene copolymer and ethylene-propylene-diene terpolymer, (B) about 50 to about 300 parts by weight of a hydrate of metallic oxide, and (C) about 0.05 to about 5 parts by weight of a phosphorus-containing titanate coupling agent, the composition having been already crosslinked by use of about 0.1 to about 20 parts by weight of a crosslinking agent or by irradiation of ionizable radiation.The composition of the invention has an outstanding flame retardancy and can be made into a molded product capable of exhibiting fully useful mechanical and electrical characteristics.
    Type: Grant
    Filed: February 19, 1987
    Date of Patent: September 6, 1988
    Assignee: Mitsubishi Cable Industries, Limited
    Inventors: Hiroshi Kato, Kazuhiko Kanemitsuya, Kiyoshi Furukawa
  • Patent number: 4766165
    Abstract: The present invention relates to flame-retarding moulding compositions which are based on thermoplastic polycarbonates, copolymers of styrenes and maleic anhydride, phosphorus compounds of the formula (I) ##STR1## tetrafluoroethylene polymers, small amounts of graft polymers and optionally halogen compounds and which in addition can contain stabilizers, pigments, flow agents, release agents and/or antistatics, and to a process for their preparation.
    Type: Grant
    Filed: June 5, 1986
    Date of Patent: August 23, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Jurgen Kress, Friedemann Muller, Christian Lindner, Horst Peters, Josef Buekers, Gert Todtemann
  • Patent number: 4751260
    Abstract: The present invention relates to flame-retarding, thermoplastic polycarbonate moulding materials of high impact strength consisting of halogen-containing polycarbonates, copolymers formed from styrenes and (meth)acrylonitrile, phosphorus compounds of the formula (I) ##STR1## tetrafluoroethylene polymers and small amounts of graft polymers and, if appropriate, effective amounts of stabilizers, pigments, lubricants, mould release agents and/or antistatic agents, and to a process for the preparation thereof.
    Type: Grant
    Filed: April 30, 1986
    Date of Patent: June 14, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Jurgen Kress, Friedemann Muller, Christian Lindner, Horst Peters, Josef Buekers
  • Patent number: RE32765
    Abstract: A polyester which when made into an article such as films, containers, bottles and the like has a very high clarity, a low haze value, and a neutral hue. In the preparation of the resin, an antimony catalyst is utilized along with small amounts of a bluing agent such as a cobalt compound and a phosphate compound with the phosphate compound generally being slightly in excess of an equivalent amount of the cobalt compound. The polyester is made from dicarboxylic acids and preferably aromatic acids such as terephthalic acid reacted with polyhydric alcohols.
    Type: Grant
    Filed: February 13, 1987
    Date of Patent: October 11, 1988
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Douglas D. Callander, Fred L. Massey