Aryl Group Patents (Class 524/141)
  • Patent number: 5952408
    Abstract: The present invention relates to flameproof thermoplastic resin compositions comprising (A) a base resin comprising (1) 75 to 96% by weight of a thermoplastic, halogen-free polycarbonate, (2) 4 to 25% by weight of a styrene-containing graft copolymer, and (3) 0 to 10% by weight of a styrene-containing copolymer, (B) 5 to 20 parts by weight, per 100 parts by weight of the base resin (A), of a phosphate composition, and (C) 0.05 to 10 parts by weight, per 100 parts by weight of the base resin (A), of a zeolite. The addition of the zeolite component provides thermoplastic resin compositions with a good combination of physical properties, including improved long-term heat stability.
    Type: Grant
    Filed: February 9, 1998
    Date of Patent: September 14, 1999
    Assignee: Cheil Industries, Inc.
    Inventors: Kyu-cheol Lee, Sam-joo Yang, Bok-nam Jang
  • Patent number: 5900446
    Abstract: Disclosed is an aromatic polycarbonate-styrene polymer resin composition comprising (A) an aromatic polycarbonate, (B) a specific rubber-modified styrene polymer and (C) a compatibility agent which is a copolymer containing an aromatic vinyl monomer and which has a non-uniform distribution with respect to the proportions of component monomers constituting the copolymer, so that the copolymer comprises copolymer molecules having different solubility parameter (SP) values, wherein the difference in SP value between the copolymer molecule having a maximum SP value and the copolymer molecule having a minimum SP value is from 0.3 to 1.0 ?(cal/cm.sup.3).sup.1/2 !, and wherein the copolymer has an average SP value of from 10.6 to 11.0 ?(cal/cm.sup.3 ).sup.1/2 !.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: May 4, 1999
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Hajime Nishihara, Akihiro Watanabe
  • Patent number: 5871570
    Abstract: There is dsiclosed a flame retardant resin composition comprising the following components (A), (B), (C), (D), (E) and (F), wherein 1-10 parts by weight of (C), 2-10 parts by weight of (D), 0.05-2 parts by weight of (E) and 0.01-10 parts by weight of (F) are contained per 100 parts by weight of a resin whose weight ratio of (A)/(B) is 75/25-90/10.(A) a polycarbonate resin whose viscosity-average molecular weight is 16,000-29,000,(B) a polyalkylene terephthalate resin,(C) a copolymer containing a rubbery polymer and at least one selected from the group consisting of aromatic vinyl monomers, vinyl cyanide monomers, acrylic acid, acrylic esters, methacrylic acid, methacrylic esters and maleimide-type monomers as components,(D) an organic phosphorus-type flame retardant,(E) a fluorocarbon-type resin, and(F) an epoxy compound not containing halogens.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: February 16, 1999
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tadashi Koyama, Kenji Mogami, Masahiro Asada
  • Patent number: 5852082
    Abstract: A polyolefin-based flame retardant resin composition which emits no hazardous gases on combustion or incineration after use, requires no additional costs for treating ash, and has excellent flame resistance and mechanical strength is provided.To 100 parts by weight of a polyolefin-based resin, 2 to 60 parts by weight of melamine cyanurate surface-treated by fine silica, and 1 to 30 parts by weight of a phosphoric acid ester are compounded.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: December 22, 1998
    Assignee: Aicello Chemical Co., Ltd.
    Inventors: Kouji Uchida, Miki Takahashi
  • Patent number: 5846656
    Abstract: A stabilizing system for stabilizing polymeric materials against ultraviolet light and thermooxidative deterioration is provided in which the stabilizing system is in pellet form. The pellet is formed from a substantially dry homogeneous mixture of at least one stabilizer and an agent which will prevent melting of the stabilizer. The stabilizer compound makes up about 50% to about 98% by weight of the mixture. The stabilizers are antioxidants (such as phosphites and hindered phenols) or hindered amine UV light stabilizers, or combinations thereof. The melt preventing agent may be a compound derived from a fatty acid or a fatty alcohol, or a fatty acid or a fatty alcohol, or a combination of fatty acids or fatty alcohols which makes up about 3%-10% of the homogeneous mixture. The fatty acids, fatty alcohols, and the compounds derived therefrom preferably have a low melting point in the range of 50.degree.-100.degree. C. and preferably between 50.degree. C. and about 80.degree. C.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: December 8, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Neil Dunski
  • Patent number: 5837757
    Abstract: Disclosed are non-bromine, flame-retardant polycarbonate resin compositions having increased reflectance and improved light shieldability, light fastness and moldability while still having good mechanical properties such as flame retardancy and impact resistance, and light reflectors as produced by molding the compositions. One type of the composition comprises (A) a polycarbonate resin and (B) a titanium oxide powder in a ratio by weight of from 70/30 to 90/10, and contains (C) a stilbene-bisbenzoxazole derivative in an amount of from 1 to 1000 ppm by weight and optionally (D) a non-halogen phosphate compound in an amount of from 0.05 to 1.00% by weight in term of phosphorus element, relative to the total weight of the component (A) and the component (B). The other type of the composition comprises (A) from 99.9 to 70% by weight of a polycarbonate resin and (B) from 0.1 to 30% by weight of a titanium oxide powder, and contains (D) a non-halogen phosphate compound in an amount of from 0.05 to 1.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: November 17, 1998
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Akio Nodera, Hiroshi Itagaki
  • Patent number: 5811470
    Abstract: Compositions and methods are described wherein a styrenic polymer is rendered flame retardant by incorporation therein before, during or after its formation, a combination of (a) at least one organic phosphorus additive that (i) is halogen-free, and (ii) is composed solely of carbon, hydrogen, and phosphorus, and optionally and preferably one or more of the elements nitrogen, oxygen, and sulfur; and (b) elemental sulfur; in proportions such that (i) the sulfur content from b) is less than 2 percent by weight of the weight of the styrenic polymer plus the weight of a) and b), and (ii) the styrenic polymer plus ingredients a) and b) can provide test specimens which exhibit an LOI of at least 24 if tested in accordance with ASTM Standard Test Method D 2863-87.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: September 22, 1998
    Assignee: Albemarle Corporation
    Inventors: John C. Prindle, Jr., Christopher J. Nalepa, Govindarajulu Kumar
  • Patent number: 5792806
    Abstract: An aqueous coating composition which includes, as essential components thereof, (A) an acrylic resin emulsion, (B) a urethane resin emulsion, (C) a crosslinking agent and (D) an acidic phosphate or phosphite ester.
    Type: Grant
    Filed: September 12, 1996
    Date of Patent: August 11, 1998
    Assignee: Kansai Paint Company, Limited
    Inventors: Yoshinori Yamamoto, Tuguo Nezu, Yoshinori Kato
  • Patent number: 5750602
    Abstract: The invention relates to flameproofed polycarbonate/ABS blends which are resistant to stress cracking, wherein the polycarbonates are wholly or partly modified by halobutyl rubber blocks.
    Type: Grant
    Filed: October 9, 1996
    Date of Patent: May 12, 1998
    Assignee: Bayer AG
    Inventors: Burkhard Kohler, Jurgen Kirsch, Richard Weider, Dieter Wittmann, Horst Beicher
  • Patent number: 5741838
    Abstract: This invention relates to halogen-free flame retardant thermoplastic moulding compounds prepared from polycarbonate and graft polymer, which may contain thermoplastic copolymer and/or polyalkylene terephthalate, wherein the flame retardant used is polyphenylene oxide combined with phosphorus compounds.
    Type: Grant
    Filed: August 9, 1995
    Date of Patent: April 21, 1998
    Assignee: Bayer AG
    Inventors: Karl Fuhr, Thomas Eckel, Dieter Wittmann, Heinrich Alberts
  • Patent number: 5739188
    Abstract: A thermoplastic composition comprising: (i) a thermoplastic resin; (ii) an antiplasticizing amount of a solid plasticizer; (iii) optionally an acid scavenger; and (iv) optionally a heat stabilizer selected from the group consisting of mixed metal stabilizers, organotin stabilizers, lead stabilizers, metal free stabilizers, or any combination of the foregoing which improves the processability of the thermoplastic resin without affecting the physical properties of the thermoplastic resin.
    Type: Grant
    Filed: September 6, 1995
    Date of Patent: April 14, 1998
    Inventor: Nirav Desai
  • Patent number: 5723526
    Abstract: A resin composition consisting essentially of (a) an aromatic polycarbonate resin, (b) a thermoplastic graft copolymer obtained by grafting a diene rubber component with a vinyl cyanide compound and an aromatic vinyl compound, (c) a phosphoric acid ester, (d) a polytetrafluoroethylene, (e) a talc, and (f) a composite rubber having a network structure in which a polyorganosiloxane rubber component and a polyalkyl (meth)acrylate rubber component interpenetrate each other, each in a specified amount. This resin composition has excellent fluidity and allows easy mold- processing. The molded article made therefrom is excellent in flame retardancy, stiffness, heat-resistance, impact strength and appearance.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: March 3, 1998
    Assignee: Teijin Chemicals Ltd
    Inventor: Masashi Nagasawa
  • Patent number: 5719209
    Abstract: A process is provided for making a flame retardant thermoplastic composition. The process involves making a preblend composition by blending a lubricant with a tetrafluoroethylene polymer. The preblend is a shelf stable tetrafluoroethylene polymer composition which can be admixed with a thermoplastic and a flame retardant to make the flame retardant thermoplastic composition which are useful to make molded components for computer housings, keyboard housings, printer housings and power tool housings.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: February 17, 1998
    Assignee: General Electric Company
    Inventors: Ronald R. Miller, Yoke Kum Fong, Roger D. Amos
  • Patent number: 5714533
    Abstract: Disclosed are a rubber composition having an improved charging property which comprises 100 parts by weight of rubber component containing diene rubber of 90 parts by weight or more, and a filler of 30 to 120 parts by weight and a nonionic surfactant or phosphoric ester of 0.2 to 8 parts by weight, and a pneumatic tire characterized by that the above rubber composition having an improved charging property is used for the tread parts of the pneumatic tire.The typical examples of the nonionic surfactant and phosphoric ester are an adduct of ethylene oxide of 2 to 30 moles to linear, cyclic or branched, and saturated or unsaturated, and monohydric or polyhydric aliphatic alcohol having carbon atoms of 6 to 25, or an adduct of ethylene oxide of 2 to 30 moles to alkylphenol, and the compounds represented by the following formula (V): ##STR1## wherein R.sup.
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: February 3, 1998
    Assignee: Bridgestone Corporation
    Inventors: Kazuya Hatakeyama, Masahiro Hojo, Daisuke Nohara, Franco Cataldo
  • Patent number: 5710199
    Abstract: The present invention is directed to compositions for use as additives in the automotive industry, which compositions contain waste powder prime and a plasticizer selected from the group consisting of 2-ethylhexyl diphenyl phosphate, diisoheptyl phthalate, a linear phthalate based upon C.sub.7 -C.sub.9 alcohols, a mixture of esters containing a minimum of 55 percent of diesters and a maximum of 20 percent dibenzoate, a mixture of esters containing a minimum of 60 percent of diesters and a maximum of 30 percent dibenzoate and dipropylene glycol dibenzoate and automotive sealants which contain waste powder prime, a plasticizer selected from the group consisting of 2-ethylhexyl diphenyl phosphate, diisoheptyl phthalate, a linear phthalate based upon C.sub.7 -C.sub.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: January 20, 1998
    Inventors: James F. Hubert, Richard A. Rinka
  • Patent number: 5698621
    Abstract: There is disclosed a printable self-clinging flexible film containing a polymerized PVC-based resin, a primary plasticizer and a stabilizer. The film exhibits high tackiness and surface tension, and printing ink may be applied directly to the surface of the film. Compositions for forming the film, and related methods are also disclosed.
    Type: Grant
    Filed: April 7, 1995
    Date of Patent: December 16, 1997
    Assignees: Achilles USA, Inc., Achilles Corporation
    Inventors: Bach T. Nguyen, Tomiki Matsumoto, Toshihiro Katagiri
  • Patent number: 5688848
    Abstract: A polyimide composition and polyimide composite are provided. The composition has a polyimide resin, a reactive plasticizer and a phosphate. The composition is crosslinked and exhibits desired levels of processability and improved thermooxidative stability. The composites have a polyimide resin, a phosphate and reinforcing fibers, and exhibit reduced wear and friction. The compositions and composites are useful for making aircraft engine hardware such as bushings.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: November 18, 1997
    Assignee: General Electric Company
    Inventors: James A. Cella, Gary K. Shank, Judith A. Serth
  • Patent number: 5674924
    Abstract: The present invention relates to flameproof thermoplastic resin compositions comprising (A) a base resin consisting of (1) 80 to 96% by weight of a thermoplastic, halogen-free polycarbonate, and (2) 4 to 20% by weight of a core-shell type ABS resin with a graft index of 40 or above, which is obtained by grafting 25 to 45% by weight of a styrene and 10 to 15% by weight of an acrylonitrile onto 45 to 60% by weight of a butadiene rubber, (B) 5 to 20 parts by weight, per 100 parts by weight of the base resin(A), of a phosphate composition, and (C) 0.1 to 2.0 parts by weight, per 100 parts by weight of the base resin(A), of a perfluoroalkane polymer. The phosphate composition is represented as the general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 independently of one another are C.sub.6 -C.sub.20 aryl or alkyl-substituted C.sub.6 -C.sub.20 aryl, n is 0 to 5, and the average n of the phosphate composition is, n is 0 to 5, about 0.3 to 0.8.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: October 7, 1997
    Assignee: Cheil Industries Inc.
    Inventors: Kyu-Cheol Lee, Sam-Joo Yang, Bok-Nam Jang
  • Patent number: 5670563
    Abstract: The invention relates to compositions comprisinga) a chlorine-containing polymerb) at least one organotin compound andc) at least one phosphorus compound of formula(R.sub.7 S).sub.3 P.dbd.X.sub.nwherein the meaning of the individual substituents is as defined in the disclosure.
    Type: Grant
    Filed: July 17, 1995
    Date of Patent: September 23, 1997
    Assignee: Ciba-Specialty Chemicals Corporation
    Inventors: Horst Zinke, Johannes Kaufhold
  • Patent number: 5665802
    Abstract: The present invention provides an improved grade of polyimide containing an organic phosphorus compound, a film composed thereof and a method of making the aforementioned film. According to the present invention, it is possible to obtain a polyimide film improved in mechanical strength.
    Type: Grant
    Filed: September 9, 1996
    Date of Patent: September 9, 1997
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Haruhiko Maki, Hirosaku Nagano, Yoshiaki Inaba
  • Patent number: 5663280
    Abstract: Disclosed is a carbonate polymer composition comprising (a) a carbonate polymer having a weight average molecular weight of from about 20,000 to about 40,000 and (b) from greater than about 0.1 to less than about 1.0 weight percent (based on carbonate polymer composition weight) low volatility aromatic phosphate ester compound, and optionally (c) from about 0.001 to about 0.1 weight percent (based on carbonate polymer compositions weight) of an alkali metal salt having a pH of at least about 7. Preferably the low volatility aromatic phosphate ester is selected from the group of aromatic phosphate ester oligomer compounds or haloaryl phosphate compounds. It has been found to be preferable to use a low volatility aromatic phosphate ester which experiences a weight loss of no more than 5 weight percent at 250.degree. C. when heated to a temperature of 500.degree. C. in a thermogravimetric analysis (TGA) at a heating rate of 20.degree. C. per minute, more preferably no more than 40 percent at 300.degree. C.
    Type: Grant
    Filed: April 23, 1996
    Date of Patent: September 2, 1997
    Assignee: The Dow Chemical Company
    Inventors: Samuel A. Ogoe, Nancy J. Schrock, Jimmie D. Spoon
  • Patent number: 5658974
    Abstract: The invention relates to halogen-free, flameproofed, thermoplastic moulding compounds made from polycarbonate and graft polymers which may optionally contain a copolymer and/or polyalkylene terephthalate, wherein a silicon resin in combination with a blend of monophosphate and oligomeric polyphosphates is used as a flameproofing agent.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: August 19, 1997
    Assignee: Bayer AG
    Inventors: Karl Fuhr, Thomas Eckel, Dieter Wittmann, Heinrich Alberts
  • Patent number: 5646198
    Abstract: A coating composition comprising (A) a polymer obtained by polymerizing (a1) one or more unsaturated acid anhydrides or unsaturated carboxylic acids and (a2) one or more other unsaturated monomers copolmerizable therewith, and (B) at least one compound selected from one or both of (b1) a compound group comprising amino-acids, compounds having one or more carboxyl groups in the molecule, compounds having both hydrophobic group and hydrophilic group in the molecule, chelate compounds, hydroxyl- or acetyl-substituted carboxylic acid esters, ion-exchangeable layer clay minerals and powers of inorganic materials which have been made lipophilic with an organic material, and (b2) a group of compound which is crystallizable and selected from polyether compounds, polyester compounds, polyether-polyester compounds, olefinic glycol compounds, acrylic esters, methacrylic esters and polycarbonate compounds, is useful for preparing an antifouling coating composition by mixing with a copper compound.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: July 8, 1997
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Hiroyuki Tanaka, Seiji Tai, Koichi Kamijima, Yumiko Wada, Tsutomu Mamiya, Makoto Murakami, Teruo Yoshida
  • Patent number: 5643981
    Abstract: The flameproof thermoplastic resin compositions of this invention comprise from 2 to 20 parts by weight of aromatic diphosphates, from 2 to 7 parts by weight of phosphorous compounds and from 0.1 to 2.0 parts by weight of polyfluoroalkyl resins per 100 parts by weight of the resin mixture consisting of from 60 to 98% by weight of polycarbonate resins, from 2 to 40% by weight of styrene-containing graft copolymer resins, and from 0 to 20% by weight of styrene-containing copolymer resins. The structural formula of said aromatic diphosphates is as follows (I): ##STR1## in which, R.sup.1 and R.sup.2 are same or different lower alkyls, R.sup.3 and R.sup.4 are same or different hydrogen atom or alkyl groups, Y is a single bond or --CH.sub.2 --, --C(CH.sub.3).sub.2 --, --S--, --SO.sub.2 --, --O--, --CO--, or --N.dbd.N--, k is 0 or 1, and m is an integer of 0 to 4.
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: July 1, 1997
    Assignee: Cheil Industries, Inc.
    Inventors: Sam-Joo Yang, Bok-Nam Jang
  • Patent number: 5627228
    Abstract: A flame-retardant (C) of a nuclearly alkylated aromatic phosphoric acid ester of the following formula (I) and a fluororesin (D) such as polytetrafluoroethylene are added to 100 parts by weight of a mixture of thermoplastic resins comprising an aromatic polycarbonate (A) and a styrenic resin (B) comprising at least a rubber-modified styrenic resin: ##STR1## wherein (i) at least one of R.sup.1 to R.sup.4 is either a 2,3-, a 3,4-, or 3,5-dialkylphenyl group, each alkyl group having 1 to 3 carbon atoms, A is a phenylene group, n denotes an integer of 0 to 5, and R.sup.1 to R.sup.4 contain both the dialkylphenyl group and a monoalkylphenyl group; or (ii) at least one of R.sup.1 to R.sup.4 is a phenyl group substituted with 1 to 5 alkyl groups each having 1 to 4 carbon atoms, A is 1,3-phenylene group and n denotes an integer of 1 to 5. The flame-retardant (C) may be a mixture of the compound (i) and the compound (ii).
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: May 6, 1997
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Michio Kobayashi
  • Patent number: 5618867
    Abstract: The present application relates to a flame retarded polycarbonate resin composition containing for flame retardancy a hydroxy-terminated aromatic oligomeric phosphate composition of the formula: ##STR1## where R is a hydrocarbyl group derived from an aliphatic or aromatic diol, Ar is an alkyl-substituted or unsubstituted phenyl group, n is from about 0 to about 10, and the phosphate composition contains a predominant amount of phosphate where n ranges from 0 to 1.
    Type: Grant
    Filed: August 3, 1995
    Date of Patent: April 8, 1997
    Assignee: Akzo Nobel NV
    Inventors: Danielle A. Bright, Paul Y. Moy
  • Patent number: 5614573
    Abstract: Flame retardant compounds including at least one of a group of specified phosphoryl compounds which have a phenylene group in the molecule are applied to fiber materials composed of polyester-based synthetic fibers. Sufficiently long-lasting flame retardancy may be imparted to polyester-based synthetic fiber materials without the use of halogen compounds.
    Type: Grant
    Filed: March 27, 1995
    Date of Patent: March 25, 1997
    Assignees: Nicca Chemical Co., Ltd., Kanebo Limited
    Inventors: Junji Sano, Kunio Ichihashi, Hajime Saito, Hirotomo Banko
  • Patent number: 5594054
    Abstract: There are provided flame retardant, flexibilized thermoplastic compositions which comprise, in admixture, a normally flammable polyphenylene ether resin, an aromatic phosphate plasticizer in an amount at least sufficient to provide a flame retardant, flexibilized composition after molding, and a thermoplastic elastomer comprising a block copolymer of a vinyl aromatic compound and a diene monomer. Preferred features comprise such compositions which also include a halogenated hydrocarbon, alumina trihydrate and/or elemental red phosphorus.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 14, 1997
    Assignee: General Electric Company
    Inventor: Gim F. Lee, Jr.
  • Patent number: 5583170
    Abstract: The invention relates to a novel curable mixture comprising a silicone rubber a), at least one aryl phosphoric acid ester b) and optionally at least one further additive c), the improvement wherein the aryl phosphoric acid ester b) is silicone incompatible, whereby upon curing of the mixture the cured product is self-lubricating.
    Type: Grant
    Filed: October 6, 1995
    Date of Patent: December 10, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventor: Dieter Wrobel
  • Patent number: 5554683
    Abstract: A vinyl chloride resin elastomer composition comprising, as main components, 100 parts by weight of a vinyl chloride resin, from 10 to 200 parts by weight of an acrylic rubber containing a tetrahydrofuran-insoluble cross-linking component, from 1 to 50 parts by weight of an acrylic resin and from 30 to 300 parts by weight of a plasticizer.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: September 10, 1996
    Assignee: Mitsubishi Chemical MKV Company
    Inventor: Masabumi Oshima
  • Patent number: 5552465
    Abstract: Polycarbonate molding compositions resistant to light aging and exhibiting an improved notched impact strength are disclosed. The compositions which are based on an aromatic polycarbonate, aromatic polyester carbonate or a polyester, contain a redox-catalyzed graft polymer of resin-forming monomers on a rubber, a phosphorus compound and a fluorinated polyolefin.
    Type: Grant
    Filed: December 1, 1995
    Date of Patent: September 3, 1996
    Assignee: Bayer Atkiengesellschaft
    Inventors: Dieter Witmann, Jochen Schoeps, Bernd Urbanneck, Karl Huff, Karl-Heinz Ott, Horst Peters
  • Patent number: 5543448
    Abstract: Blends of polycarbonate and polyester are admixed in compositions with poly(phenylene ether), and/or with a poly(phenylene ether) concentrate containing poly(phenylene ether), polystyrene, a vinyl aromatic copolymer, polyamide, polycarbonate, polyester, poly(alkyl acrylate), and/or poly(alkyl methacrylate).
    Type: Grant
    Filed: January 26, 1995
    Date of Patent: August 6, 1996
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5539030
    Abstract: Polycarbonate is admixed in compositions with poly(phenylene ether), and/or with a poly(phenylene ether) concentrate containing poly(phenylene ether), polystyrene, a vinyl aromatic copolymer, polyamide, polycarbonate, polyester, poly(alkyl acrylate), and/or poly(alkyl methacrylate). The blended compositions may also optionally contain additional vinyl aromatic copolymer as a separate component, impact modifiers, thermoplastic molding materials including polystyrene, polyolefin, polyamide, poly(vinyl chloride), polyurethane, polyacetal, and conventional additives such as dyes and pigments.
    Type: Grant
    Filed: November 28, 1994
    Date of Patent: July 23, 1996
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5498656
    Abstract: Proposed is a polyvinyl alcohol molding resin composition exhibiting excellent workability in the molding procedure by extrusion and injection and capable of giving molded articles, e.g., films and sheets, having excellent properties in respect of good appearance and excellent resistance against coloration by heating. The molding resin composition comprises a polyvinyl alcohol and a limited amount of an additive ingredient which is an alkali or alkaline earth metal salt of organic sulfonic acid, e.g., sodium and calcium dodecylbenzene sulfonates, a polyoxyethylene ester of phosphoric acid or a combination thereof.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: March 12, 1996
    Assignees: Shin-Etsu Polymer Co., Ltd., Akishima Chemical Industries Co., Ltd.
    Inventors: Yusuke Morita, Masami Fukushima, Fumio Gotou, Shigeo Aoki
  • Patent number: 5496881
    Abstract: The invention is an aqueous composition for forming fireproof coatings and caulking. The composition is halogen, asbestos and antimony-free. The composition contains 5-20% by weight of a binder resin; 10-60% by weight of a particulate flameproofing agent; 0.2 to 27.5% by weight of non-asbestos inorganic fibers with an average length of 300 micron; 0.1 to 10% by weight of a plasticizer; and water.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: March 5, 1996
    Assignee: Chemische Fabrik Gruenau GmbH
    Inventors: Dieter Annemaier, Robert Graf
  • Patent number: 5475056
    Abstract: The invention relates to plastisols which prevent a yellowing of top coats applied thereon, to a process for their preparation and to their use. The plastisols based on PVC or methacryl contain, in addition to basic adhesion promoters, aldehydes, ketones, their derivatives, oligomers or mixtures of same.
    Type: Grant
    Filed: April 13, 1995
    Date of Patent: December 12, 1995
    Assignee: Teroson GmbH
    Inventors: Bernhard Koesters, Xaver Muenz, Manfred Asang
  • Patent number: 5466733
    Abstract: The invention relates to a material which comprises at least 20% of polyphenylene ether and which comprises as a flame-retardant 0.05-10% by weight of a boron compound, for example, boric acid, B.sub.2 O.sub.3, borate, salts or borate esters related to the polyphenylene ether, as well as, optionally, a plasticiser and further conventionally used additives.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: November 14, 1995
    Assignee: General Electric Company
    Inventors: Theodorus L. Hoeks, Christianus A. A. Claesen, Johannes H. G. M. Lohmeijer, James E. Pickett
  • Patent number: 5464895
    Abstract: A dispersing agent for use in a thermosetting composition, a thermosetting composition containing said dispersing agent, and application thereof to thermosetting composition having no yield point. The dispersing agent acting on mineral fillers and used in filled acrylic or polyester resin-based thermosetting compositions belongs to the family of organophosphates corresponding to the general formula: ##STR1## where: A is a branched or unbranched polyaryl group,x and y are whole numbers between 0 and 100 such that x+y is a whole number greater than 40 but not greater than 100, ##STR2## B and E are independently a branched or unbranched polyaryl group, or an alkyl, aryl, arylalkyl, alkylaryl, alkanoyl, or amine radical, and in B and E, and R.sub.1 and R.sub.2 may be identical or different, x1, y1, x2 and y2 are whole numbers, and the sums x1+y1 and x2+y2 are not greater than 100.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: November 7, 1995
    Assignee: Coatex, S.A.
    Inventors: Pierre Blanchard, Jean-Bernard Egraz, Georges Ravet
  • Patent number: 5455292
    Abstract: The present invention provides a resin composition comprising:(A) at least one thermoplastic resin not having halogen selected from the group consisting of a polyphenylene ether resin, a polycarbonate resin, a polystyrene resin, a polyolefin resin, a polyamide resin and a thermoplastic elastomer; and(B) a phosphoric acid ester compound represented by general formula I: ##STR1## wherein Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4 independently represent an alkyl group having 1 to 6 carbon atoms; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently represent a methyl group or a hydrogen atom; n represents an integer of 1 or more; n1 and n2 independently represent an integer of 0 to 2; and m1, m2, m3 and m4 independently represent an integer of 1 to 3.According to the present invention, a resin composition excellent in flame retardance can be obtained.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: October 3, 1995
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Junko Kakegawa, Shigeki Takayama
  • Patent number: 5455092
    Abstract: A labelstock which comprises a release-coated liner, a facestock including a layer consisting essentially of one or more nucleating agents of polyolefins and (a) one or more olefin homopolymers or (b) one or more copolymers of olefins or (c) a mixture of (a) and (b), and a pressure-sensitive adhesive for releasably joining the facestock to the release-coated liner.
    Type: Grant
    Filed: May 11, 1993
    Date of Patent: October 3, 1995
    Assignee: The Dow Chemical Company
    Inventor: Harvey C. Tung
  • Patent number: 5447984
    Abstract: Curable polymer mortar or concrete compositions with improved workability and processability use polymerizable liquid resin composed of unsaturated urethane of a specified form and vinyl monomers as binder and also contain an inorganic powder filler, aggregates and a viscosity reducer of a specified kind and a low shrinking agent of a specified kind each at a specified rate. Cured compositions with improved accuracy in measurements, strength and water absorption can be obtained from such compositions. Self-leveling property can also be provided.
    Type: Grant
    Filed: November 28, 1994
    Date of Patent: September 5, 1995
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Yoshihiko Ohama, Katsunori Demura, Hirokazu Matsueda, Tatsuhiko Ozaki, Atsushi Kodama
  • Patent number: 5442004
    Abstract: Gels of hard-elastomer-hard block copolymers with at least 300 parts of extending liquid per 100 parts of the copolymer contain at least 50 parts (per 100 parts of copolymer) of a stabilizing additive which resists migration of PVC plasticizers into the gel when in contact with a plasticized PVC article. Styrene-(ethylene-butylene)-styrene triblock copolymers with organic phosphate stabilizers are preferred, these stabilizers tending to raise the gel softening temperature.
    Type: Grant
    Filed: November 10, 1993
    Date of Patent: August 15, 1995
    Assignee: Raychem Limited
    Inventors: Alistair A. P. Sutherland, John M. Hudson
  • Patent number: 5418279
    Abstract: Stereoregular polystyrenes can be combined with a plasticizer to make a non-PVC plastisol with physical properties comparable to PVC-based plastisols.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: May 23, 1995
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Jie Ren, William P. Roberts, Arthur D. Ketley
  • Patent number: 5416134
    Abstract: The present invention is directed to an aqueous emulsion acrylic pressure sensitive adhesive composition that excels in high performance applications. The inventive adhesive composition comprises in water:(I) a polymer system wherein the system is:(A) (a) a copolymer of between about 95 wt-% and 99.9 wt-% of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and between about 0.1 wt-% and 5 wt-% N-alkyl substituted or unsubstituted amide of (meth)acrylic acid, and(b) a homopolymer or copolymer of between about 0 wt-% and 99.8 wt-% of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and about 0.2 wt-% and 100 wt-% of an ethylenically unsaturated carboxylic acid; or(B) (a) a copolymer of between about 90 wt-% and 99.8 wt-% of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and about 0.2 wt-% and 10 wt-% of an ethylenically unsaturated carboxylic acid; and(b) a homopolymer or copolymer of between about 0 wt-% and 99.1 wt-% of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and between about 0.
    Type: Grant
    Filed: December 21, 1993
    Date of Patent: May 16, 1995
    Assignee: Ashland Oil, Inc.
    Inventor: Michael J. Skoglund
  • Patent number: 5412014
    Abstract: A free-flowing silicone polymer powder, said powder having an average particle size of 1 to 1000 microns and being prepared by mixing a polydiorganosiloxane with a silica filler, and a phosphorus-based fire retardant compound are uniformly dispersed in an organic resin using conventional equipment, such as a single screw extruder. The resulting resin composition shows a significant improvement in fire retardancy but does not exhibit the severe deterioration of impact resistance incurred when the resin is modified with only phosphorus-based fire retardant.
    Type: Grant
    Filed: October 26, 1993
    Date of Patent: May 2, 1995
    Assignee: Dow Corning Corporation
    Inventor: David J. Romenesko
  • Patent number: 5387633
    Abstract: Copolymers of styrene and sodium styrene sulfonate can be combined with a plasticizer to make a non-PVC plastisol sealant for containers.
    Type: Grant
    Filed: March 8, 1994
    Date of Patent: February 7, 1995
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Richard W. Bush, Eugene E. Carney, Shao-Hai Wu, Felek Jachimowicz, Timothy G. Grasel, Tsutomu Takeuchi
  • Patent number: 5380779
    Abstract: A pressure sensitive adhesive composition is described which is water-dispersible under acidic conditions. The composition comprises a terpolymer of a hydrophobic monomeric acrylic or methacrylic ester of a non-tertiary alcohol (monomer A); a polar monomer copolymerizable with said A monomer and having carboxylic, sulfonic acid or hydroxyl functionality or combinations thereof (monomer B); and a water soluble or water-dispersible macromolecular monomer of the formula X--Y--Z which is copolymerizable with A and B wherein X is a copolymerizable moiety containing a double bond, Y is a divalent linking group and Z is a water-dispersible polymeric moiety (monomer C). The combined acid groups employed in the B monomer are neutralized from 5 to 100% based on the total amount of acid groups in B. The composition further comprises tackifier and/or plasticizers at a level such that the ratio of terpolymer to additives falls within a range of from 0.2:1 to 5:1.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: January 10, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Francois C. D'Haese
  • Patent number: 5369157
    Abstract: Thermoplastic compositions containing, per 100 parts by weight of a thermoplastic material containing at least one alkenyl aromatic hydrocarbon polymer or copolymer and, if required, at least one other thermoplastic of elastomeric resin:(a) from 5 to 30 parts by weight of melamine and melamine isocyanurate,(b) from 2 to 10 parts by weight of at least one polyol containing at least 4 hydroxyl functions per molecule, and(c) from 0 to 14 parts by weight of at least one organic ester of phosphoric acid.A process for their preparation consists of mixing the various constituents at a temperature higher than the softening point of the alkenyl aromatic hydrocarbon polymer or copolymer, between 150.degree. and 200.degree. C., for a duration between 1 and 5 minutes in an internal mixer or extruder.Articles obtained by transformation of the above compositions are formed having low combustion rates.
    Type: Grant
    Filed: December 27, 1993
    Date of Patent: November 29, 1994
    Assignee: Atochem
    Inventor: Rene Wirth
  • Patent number: 5364898
    Abstract: Improved thermoplastic compositions characterized by high tensile elongation values are described. They comprise polyphenylene ether resin, a hydrogenated elastomeric block copolymer having an A-B-A' structure, with specific molecular weight values for the copolymer blocks and a phenylsiloxane fluid of particular composition. Electrical conductor articles which include polymerized thermoplastic compositions as mentioned above represent another embodiment of this invention.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: November 15, 1994
    Assignee: General Electric Company
    Inventors: Gim F. Lee, Jr., Kevin M. Snow
  • Patent number: 5354792
    Abstract: The invention relates to a flowability improving agent comprising a combination, calculated on a dry product, of: A) 60-99% by weight of a sulphonated melamine-formaldehyde resin, a sulphonated melamine-urea-formaldehyde resin or a sulphonated naphthalene-formaldehyde resin; C) 0.5-40% by weight of a boron containing polyhydroxycarboxylic acid or a water-soluble salt of such an acid and optionally D) 0.5-30% by weight of a compound with formulaAr O--(R.sub.1).sub.n --R.sub.2where Ar is unsubstituted or substituted benzene moiety or naphthalene moiety, R.sub.1 is an oxyethylene group; --CH.sub.2 CH.sub.2 O--or an oxypropylene group; ##STR1## an oxyethylene chain or an oxypropylene chain with up to fifteen oxyethylene groups or oxypropylene groups or a combination of oxyethylene groups and oxypropylene groups to a chain where the sum of these groups is at most fifteen; the mean value n for n is 1-15 and R.sub.2 is hydrogen or a phosphonate group with the formula ##STR2## where M.sub.1 and M.sub.
    Type: Grant
    Filed: August 6, 1992
    Date of Patent: October 11, 1994
    Assignee: Perstorp AB
    Inventors: Lars-Inge Olsson, Kent Hamacek