Aryl Group Patents (Class 524/158)
-
Patent number: 6423367Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: July 27, 2001Date of Patent: July 23, 2002Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
-
Patent number: 6380283Abstract: A method of treating natural rubber latex to reduce the antigenic protein content includes enzyme treatment of the natural rubber latex and utilizing a chemical stabilizer of the type similar to branched dodecyl benzene sulphonic acid alone or in combination with other stabilizers such as a sulfated fatty acid in combination with hydroxypropyl methylcellulose is disclosed. Also disclosed is a treatment of natural rubber latex with antioxidants either alone or together which ether serve to allow natural rubber latex products to be chlorinated without suffering debilitating aging effects. The first antioxidant is of the type 4,4-(6-T-butyl-M-cresol) or 4,4+-Butylidenebis (3-methyl-6-tert-butylphenol) while the second antioxidant is of the type of a polymeric hindered phenol or butylated reaction product of P-cresol and dicyclopentadiene.Type: GrantFiled: November 23, 1999Date of Patent: April 30, 2002Assignee: Tillotson Healthcare CorporationInventors: Frank W. Perrella, Joseph K. Pieroni, Thomas N. Tillotson
-
Patent number: 6316533Abstract: A composition containing (A) one or more aromatic sulfonates, (B) one or more aldehyde resins and (C) a buffer and is prepared and used for treating, in particular neutralizing, leather tanned with mineral compounds or mineral-free compounds.Type: GrantFiled: August 26, 1999Date of Patent: November 13, 2001Assignee: BASF AktiengesellschaftInventors: Gerhard Wolf, Georg Igl, Thomas Grösser, Adolf Stübinger, Jürgen Werner, Erhard Guenther
-
Patent number: 6310124Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.Type: GrantFiled: November 25, 1998Date of Patent: October 30, 2001Assignee: Cytec Technology, Corp.Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
-
Patent number: 6306209Abstract: A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by polymerizing (i) at least one prepolymer having a radically polymerizable group, and (ii) at least one second monomer. The prepolymer is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of at least one radically polymerizable first monomer. The second monomer forms a polymeric backbone segment of the pigment dispersant, and the prepolymer forms polymeric segments that are pendent to the backbone. The backbone segment of the pigment dispersant is hydrophilic, while at least a portion of each pendent polymeric segment is hydrophobic.Type: GrantFiled: December 16, 1999Date of Patent: October 23, 2001Assignee: PPG Industries Ohio, inc.Inventors: Brian E. Woodworth, Gregory J. McCollum, James B. O'Dwyer, Simion Coca
-
Publication number: 20010031806Abstract: An optical brightener mixture comprisingType: ApplicationFiled: February 8, 2001Publication date: October 18, 2001Inventors: Thomas Lutkenhorst, Thomas Martini, Joseph Thomas Craddock
-
Patent number: 6297296Abstract: The invention relates to the use of cationic latex particles that can complex with anionic dyes to provide water fastness and further to provide a medium in which inherently unstable anionic dyes can be brought in close proximity with other anionic components, by complexation to cationic latices, in order to stabilize the anionic dyes especially with regard to light and oxidative degradation. In particular this invention will provide for methods of generating waterfast and improved lightfast ink jet images.Type: GrantFiled: May 19, 1999Date of Patent: October 2, 2001Assignee: Kodak Polychrome Graphics LLCInventor: Allan Wexler
-
Patent number: 6294270Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: December 23, 1998Date of Patent: September 25, 2001Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
-
Patent number: 6271290Abstract: The present invention provides a method for making a polycarbonate composition. The polycarbonate is prepared by melt synthesis using a sulfur-containing acid compound to at least partially quench the melt catalyst. The polycarbonate composition comprises said polycarbonate, phosphorous acid, further sulfur-containing acid compound and an ester derived from a mono-fatty acid and a polyhydric alcohol.Type: GrantFiled: December 6, 1999Date of Patent: August 7, 2001Assignee: General Electric CompanyInventors: Kazushige Inoue, Hiromi Ishida, Theodorus Lambertus Hoeks, Lennard Alexander Markestein
-
Patent number: 6248818Abstract: Disclosed are polythiophene-based conductive polymer liquid compositions of high conductivity and transparency. The compositions comprise 16-32 weight % of an aqueous polythiophene-based conductive polymer solution, 52-80 weight % of an alcohol solvent, 1-12 weight % of an amide solvent, 0.01-0.4 weight % of a sulfonic acid group-containing monomer dopant, and optionally 2-8 weight % of an alkoxysilane. The compositions can be applied to transparent substrates to form coatings which have a surface resistance of 1 k&OHgr;/□ or less and a transmittance of 92% or higher. With the excellent conductivity and transparency, the compositions are useful as electromagnetic wave-shielding materials, finding numerous applications in cathode ray tube screens (TV sets and computer monitors) as well as CPP films, polyethyleneterephthalate films, polycarbonate panels, and acryl panels.Type: GrantFiled: November 3, 1999Date of Patent: June 19, 2001Assignee: Samsung General Chemicals Co. Ltd.Inventors: Hyun Don Kim, Hae Ryong Chung, Min Kyo Cheong, Tu Won Chang
-
Patent number: 6225386Abstract: An antistatic agent having phosphonium sulfonate of a specified kind and inorganic sulfonate of a specified kind mixed at a specified ratio can provide synthetic polymer materials with a superior antistatic characteristic without adversely affecting the natural hue and transparency of the material. Aliphatic carboxylic acid ester of polyhydric alcohol may also be mixed together in the agent.Type: GrantFiled: November 3, 1999Date of Patent: May 1, 2001Assignee: Takemoto Yushi Kabushiki KaishaInventor: Masahiro Suzuki
-
Patent number: 6177511Abstract: Novel organopolysiloxane compositions comprising (A) organopolysiloxanes which contain at least one SiC-bonded organic radical containing basic nitrogen, where the basic nitrogen is optionally present in part as a salt of a water-soluble organic acid, water-soluble inorganic acid, or water-insoluble organic acid, (B) anionic, cationic, nonionic or amphoteric surfactants, which are in soluble or soluble in (A) (C) substituted or unsubstituted diacrylates and/or oligoacrylates, and optionally, (C′) substituted or unsubstituted acrylates, and (D) water are described.Type: GrantFiled: January 25, 1999Date of Patent: January 23, 2001Assignee: Wacker-Chemie GmbHInventors: Jochen Dauth, Bernward Deubzer, Robert Schröck, Petra Gratzl
-
Patent number: 6172147Abstract: Mortar cement additives provide workability while retaining strength by employing a multi-stage polymer comprising a hydrophobically-modified, ionically-soluble polymer stage, the polymer being soluble at a pH of 6 and above; and an air-entraining agent. The additives also employ, as optional ingredients, set retarding agents and superplasticizers. Examplary methods of the invention involve addition of the multi-stage polymer and an air entraining agent to the mortar cement, preferably during intergrinding of Portland cement in the mill. Cement compositions comprising the polymer and an air-entraining agent are also disclosed.Type: GrantFiled: May 5, 1998Date of Patent: January 9, 2001Assignee: W. R. Grace & Co.-Conn.Inventors: Angel Abelleira, John Hallock
-
Patent number: 6160027Abstract: It is desirable to reduce the amount of volatile organic blowing agent in expandable polystyrene. This may be accomplished by partially polymerizing a mass of styrene and incorporating therein water together with an emulsifier. The partially polymerized mass is then polymerized to a high conversion using conventional suspension techniques. The polymer beads containing water which acts as a blowing agent are recovered.Type: GrantFiled: December 30, 1998Date of Patent: December 12, 2000Assignee: Nova Chemicals (International) S.A.Inventors: Jeroen Joost Crevecoeur, Eric Wilhelmus Johannes Frederik Neijman, Laurentius Nicolaas Ida Hubertus Nelissen, Johannes Maria Zijderveld
-
Patent number: 6153304Abstract: Articles of manufacture are provided with a low surface energy, permanently non-stick, non-fouling and ice-phobic surface by a system of coating comprising applying a primary coating having a surface energy of 22-28 dynes/cm.sup.2 comprising a novel polymeric material having non-stick and hardness properties and then applying a top coating having lower surface energy of from about 18-21 dynes/cm.sup.2 comprising a siliconic polymer and interdigitating means to make the top coating permanent, the means preferably comprising a bi- or polyfunctional organic compound adapted to wet the surface of the primary coating and chemically or physically bond thereto and to couple to the siliconic polymeric substance in the top coating. The coated substrates are resistant to marking by graffiti, to adherence by marine fouling organisms, and frozen ice on the surface is easily removed.Type: GrantFiled: August 13, 1999Date of Patent: November 28, 2000Assignee: Decora IncorporatedInventors: John Ralph Smith, Nissim N. Garti
-
Patent number: 6150443Abstract: Provided are a flame-retardant polycarbonate resin composition capable of being formed into moldings having good impact resistance, high strength and good thermal stability that are intrinsic to polycarbonate resins and having good antistatic properties and good flame retardancy, and also injection moldings of the composition. The composition comprises 100 parts by weight of a resin or resin mixture of (A) from 50 to 100% by weight of a polycarbonate resin and (B) from 0 to 50% by weight of a styrenic resin, from 1 to 50 parts by weight of (C) a flame retardant, and from 0.1 to 5 parts by weight of (D) an anionic antistatic agent, and has a sodium sulfate content of at most 0.05% by weight. Optionally, the composition may contain (F) a fluoro-olefinic resin, (G) a rubber-like elastomer, and (H) an inorganic filler.Type: GrantFiled: August 9, 1999Date of Patent: November 21, 2000Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Akio Nodera, Naoki Mitsuta
-
Patent number: 6020407Abstract: An improved thickening composition for aqueous systems including latex paints and coatings is described. The substantially anhydrous composition comprises in specified ratios a solid thickener polymer, and one or more surfactants. The solid thickener polymer includes associative thickeners. Associative thickener polymers include polyurethanes, polyesters, polyacrylamides, modified hydroxyethyl celluloses, alkali soluble emulsions and other chemicals. Specific surfactants utilized include dialkyl sulfosuccinates, alkyl sulfates, alpha olefin sulfonates and sulfates of ethoxylated alcohols.Type: GrantFiled: November 7, 1995Date of Patent: February 1, 2000Assignee: Rheox, Inc.Inventors: Barbara A. Campbell, Joseph G. Doolan, Charles A. Cody, Wilbur Mardis
-
Patent number: 5994458Abstract: A process for the preparation of a latex comprising the polymerization of monomer in the presence of a chain transfer component, an initiator, a diphenyloxide disulfonate, and an optional nonionic surfactant.Type: GrantFiled: September 2, 1998Date of Patent: November 30, 1999Assignee: Xerox CorporationInventors: Chieh-Min Cheng, Grazyna E. Kmiecik-Lawrynowicz
-
Patent number: 5993532Abstract: A stabilized solution of hydrogen silsesquioxane resin is disclosed. The solution comprises 100 parts by weight solvent, 0.1 to 100 parts by weight hydrogen silsesquioxane resin, and 0.002 to 4 parts by weight acid. These solutions are useful for forming coatings on substrates.Type: GrantFiled: November 26, 1997Date of Patent: November 30, 1999Assignees: Dow Corning Corporation, Dow Corning Toray Silicone Co., Ltd.Inventors: Dennis William Broderick, James Anthony Helwick, Takashi Nakamura
-
Patent number: 5948838Abstract: The present invention relates to a polycarbonate resin composition comprising 100 parts by weight of a polycarbonate resin; 0.01 to 5 parts by weight of a compound containing oxymethylene unit, a compound containing oxymethylene unit having substituent or a cyclic ether compound having substituent.Type: GrantFiled: February 25, 1997Date of Patent: September 7, 1999Assignee: Mitsubishi Engineering-Plastics Corp.Inventors: Shinya Miya, Satoshi Kanayama
-
Patent number: 5919854Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.Type: GrantFiled: October 3, 1996Date of Patent: July 6, 1999Assignee: Cytec Technology Corp.Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
-
Patent number: 5888405Abstract: The invention relates to a method to inhibit bacteria from adhering to a submergible surface. The method contacts the submergible surface with an effective amount of at least one amino methyl phosphonic acid or salt thereof to inhibit bacterial adhesion to the submergible surface. The invention also relates to a method for controlling biofouling of an aqueous system. This method adds an effective amount of at least one amino methyl phosphonic acid or salt thereof to inhibit bacteria from adhering to a submerged surface within the aqueous system. This method effectively controls biofouling without substantially killing the fouling organisms. The amino methyl phosphonic acid used in the methods of the invention has the formula R.sup.1 R.sup.2 NCH.sub.2 P(O)(OH).sub.2. In this formula, R.sup.1 and R.sup.2 are independently a C.sub.6 -C.sub.20 alkyl group or a CH.sub.2 P(O)(OH).sub.2 group. However, R.sup.1 and R.sup.2 are not both a CH.sub.2 P(O)(OH).sub.2 group. Alternatively, R.sup.1 and R.sup.Type: GrantFiled: July 29, 1997Date of Patent: March 30, 1999Assignee: Buckman Laboratories International Inc.Inventors: Thomas E. McNeel, Marilyn S. Whittemore, Stephen D. Bryant, Graciela H. Vunk
-
Patent number: 5852087Abstract: Easily dyeable meta-linkage-containing aromatic polyamide fibers consisting of a composition which comprises a meta-linkage-containing aromatic polyamide incorporating a quaternary onium salt of an alkylbenzenesulfonic acid. They are easily dyeable with cationic dyes, and thus may be used in the fields of bedding, clothing and interior decoration.Type: GrantFiled: December 20, 1996Date of Patent: December 22, 1998Assignee: Teijin LimitedInventors: Akihiro Ohba, Koki Sasaki
-
Patent number: 5798410Abstract: Artificial latexes that are film forming at room temperature can be prepared from a copolymer of ethylene and a C.sub.3 -C.sub.20 .alpha.-olefin. The copolymer is characterized by having a polydispersity index not greater than 2.5; random distribution of comonomer units along the polymer backbone; and a homogeneity index of at least 75. The copolymer preferably contains no polar substituents, which are generally necessary to make useful latexes from polyethylene.Type: GrantFiled: August 23, 1996Date of Patent: August 25, 1998Assignee: The Dow Chemical CompanyInventors: Brian W. Walther, James R. Bethea
-
Patent number: 5760112Abstract: A water-borne autodepositing coating composition that has a pH of 1.6 to 5 and contains as essential components a water-dispersible or water-soluble organic coating-forming resin, a liquid dispersion of carbon black, acid, and oxidizing agent, and that may contain metal ions as an optional component, has an excellent storage stability and produces a strongly adherent and highly corrosion-resistant coating when the liquid dispersion of carbon black is an aqueous dispersion in which carbon black is dispersed using as a dispersant a naphthalenesulfonate-formaldehyde condensate.Type: GrantFiled: August 23, 1996Date of Patent: June 2, 1998Assignee: Henkel CorporationInventors: Mutsumi Hirota, Takumi Honda, Norifumi Hatano, Shoichi Sangenya, Shunjiro Saiki
-
Patent number: 5739177Abstract: A dental composition containing an acid such as maleic acid, phosphoric acid or citric acid; an organosulfonate and/or an organosulfinate such as an acid group-containing (meth)acrylate monomer having in the molecules thereof a carboxyl group or a phosphoric acid group, a sodium benzenesulfonate or a sodium p-toluenesulfinate; a water-soluble organic solvent such as ethanol or propanol; and the water: but without substantially containing any polymerizable monomer except the above acid group-containing (meth)acrylate monomer, or further containing a hydroxy- or a dihydroxyalkyl (meth)acrylate monomer. For adhesion of a dental filling material to teeth, the composition of the invention is used as a pre-treatment agent on teeth prior to applying an adhesive. This makes it possible to treat enamel and dentin simultaneously and to accomplish strong adhesive strength to both of them.Type: GrantFiled: June 6, 1996Date of Patent: April 14, 1998Assignee: Tokuyama CorporationInventors: Hideki Ohno, Mikio Kimura, Satoru Fuchigami, Makoto Oguri
-
Patent number: 5717057Abstract: A method for manufacturing polycarbonate in which an aromatic dihydroxy compound and a carbonic acid diester can be effectively subjected to melt polycondensation using a small amount of a catalyst, making it possible to manufacture polycarbonate having outstanding color matching, outstanding thermal stability, color-matching stability, etc., during molding, and outstanding water resistance is characterized in that when an aromatic dihydroxy compound and a carbonic acid diester are subjected to melt polycondensation in the presence of a catalyst, the catalyst is dissolved or dispersed as a catalyst solution, this catalyst solution is added to the melt polycondensation reaction system, and the aromatic dihydroxy compound and carbonic acid diester are subjected to melt polycondensation.Type: GrantFiled: December 28, 1995Date of Patent: February 10, 1998Assignee: General Electric CompanyInventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
-
Patent number: 5686512Abstract: The present invention discloses a process for manufacturing surfactants for hydrocarbon by modifying the paper making black liquor resin using modifying agents. The process is to react or combine an alkaline aqueous solution, chemical substances such as olefin, aromatic hydrocarbon, and fatty acids, amino acids, phospholipids as well as one or more of the surfactants for petroleum recovery with 20%-80% of the paper making black liquor resin, the reaction lasting for 1-3 hours at the temperature of 80.degree.-100.degree. C. and ordinary pressure, the pH value of the reaction mixture being kept at 10-12. The surfactant prepared by this method can be effectively used in the recovery of thick oil, asphalt emulsification for road pavement and the oil driving in tertiary recovery oil drainage in petroleum recovery. It has remarkable viscosity reducing effect on petroleum, its emulsification ability being strong, its viscosity reducing rate for 3.0.times.10.sup.5 -5.0.times.10.sup.Type: GrantFiled: July 31, 1995Date of Patent: November 11, 1997Inventor: Dongsheng Liu
-
Patent number: 5668202Abstract: A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfonates group sulfonic acid anhydride group or a sulfate group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.Type: GrantFiled: June 19, 1996Date of Patent: September 16, 1997Assignee: Teijin LimitedInventors: Masumi Hirata, Wataru Funakoshi, Katsushi Sasaki
-
Patent number: 5656680Abstract: The invention provides a processing aid and method for lubricating and improving the processability and releasability of rubber and plastic without adversely affecting and, in certain instances, improving the physical properties of the rubber or plastic such as adhesion, tack, modulus and tensile strength. The processing aid comprises a pre-formed homogeneous mixture of at least one silicone fluid lubricant and at least one peptizing agent. A preferred processing aid also includes a silicone fluid wetting agent, which affords decreased vulcanization times and increased production rates.Type: GrantFiled: April 2, 1993Date of Patent: August 12, 1997Assignee: Technical Processing, Inc.Inventors: Enrique Aguirre, Paul R. Yankner
-
Patent number: 5610212Abstract: A means for stabilizing a deproteinized natural rubber latex is disclosed, comprising adding a stabilizer selected from the group consisting of (a) an anionic surfactant, (b) an amphoteric surfactant, (c) a nonionic surfactant, (d) a nonionic or amphoteric oligomer or polymer, and (e) an anionic oligomer or polymer. By adding the stabilizer, the mechanical stability of a deproteinized natural rubber latex can be markedly improved.Type: GrantFiled: May 13, 1994Date of Patent: March 11, 1997Assignees: Kao Corporation, Sumitomo Rubber Industries, Ltd.Inventors: Yasuyuki Tanaka, Yuichi Hioki, Masaharu Hayashi, Naoya Ichikawa, Toshiaki Sakaki
-
Patent number: 5606008Abstract: The purpose of the present invention is to provide a method for manufacturing polycarbonate in which polycarbonate having outstanding color matching, outstanding thermal properties, particularly retention stability during molding, and outstanding water resistance can be effectively and easily manufactured.In the method for manufacturing polycarbonate of the present invention, an aromatic dihydroxy compound and a carbonic acid ester are subjected to melt condensation polymerization in the presence of a catalyst composed of(a) an aliphatic amine with 24-60 carbon atoms, and (b) an alkali metal compound and/or alkaline earth metal compound.The (a) aliphatic amine having 24-60 carbon atoms should preferably be an aliphatic tertiary amine and be used in the amount of 1.times.6.sup.-6 -1.times.10.sup.-1 moles for each mole of the aromatic dihydroxy compound, and the (b) alkali metal compound and/or alkaline earth metal compound should be used in an extremely minute specified amount.Type: GrantFiled: July 21, 1995Date of Patent: February 25, 1997Assignee: General Electric CompanyInventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
-
Patent number: 5574091Abstract: Artificial latexes that are film-forming at room temperature can be prepared from a copolymer of ethylene and a C.sub.3 -C.sub.20 alpha olefin. The copolymer preferably contains no polar substituents, which are generally necessary to make useful latexes from polyethylene.Type: GrantFiled: June 5, 1995Date of Patent: November 12, 1996Assignee: The Dow Chemical ComapnyInventors: Brian W. Walther, Jim R. Bethea
-
Patent number: 5574101Abstract: An acrylic resin composition comprising at least one polyamide elastomer consisting of hard segments and soft segments in a specified ratio, an acrylic resin and optionally at least one electrolyte, which has excellent permanent antistatic properties, is good in transparency, has a very faint color, is inexpensive, and is only slightly deteriorated in transparency even when immersed in water.Type: GrantFiled: May 26, 1995Date of Patent: November 12, 1996Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kiyoshi Kawakami, Yuzuru Ishibashi, Toshio Suzuki
-
Patent number: 5548009Abstract: A process for improving the storage life of a one-component silicone paste containing an alkali metal phosphate and which cures with elimination of acetic acid on exposure to atmospheric moisture, which comprises adding to such paste an acidic additive bearing the functional group --SO.sub.3 H or hydrogen chloride in a concentration sufficient to convene the alkali metal phosphate into the alkali metal salt of the acidic additive.Type: GrantFiled: April 26, 1994Date of Patent: August 20, 1996Assignee: Bayer AktiengesellschaftInventors: Wilhelm Weber, Karl-Heinz Sockel, Hans-Heinrich Moretto
-
Patent number: 5521239Abstract: The invention concerns a rubber eraser made of a binder and plasticizer, as well as fillers, pigments and/or other additives, if applicable, which contains polyalkyl methacrylate (PAMA), especially polymethyl methacrylate (PMMA), polyethyl methacrylate (PEMA), polypropyl methacrylate (PPMA), polybutyl methacrylate (PBMA) and/or copolymerizates of these as the binder. Furthermore, the invention concerns processes for manufacturing such rubber erasers, where either first, a plastisol of fine-grain polyalkyl methacrylate and plasticizer is formed, and fillers, internal lubricants, pigments and/or other additives are then mixed into this plastisol, or according to which first, the PAMA powder, the filler as well as any other dry components such as internal lubricants, pigments, etc. are intimately mixed while dry, and the liquid plasticizer is then added to this mixture and mixed or kneaded in.Type: GrantFiled: December 13, 1994Date of Patent: May 28, 1996Assignee: J. S. Staedtler GmbH & Co.Inventor: Werner Handl
-
Patent number: 5500469Abstract: An artificial latex comprising a stable aqueous colloidal dispersion of a preformed multiblock copolymer prepared using a sulfate of an ethoxylated phenol as a dispersing and stabilizing agent is described. This composition is particularly suitable for preparing articles such as gloves or condoms that are free of vulcanizing agents and proteins.Type: GrantFiled: September 22, 1994Date of Patent: March 19, 1996Assignee: The Dow Chemical CompanyInventors: Kenneth E. Johnsen, Ronald R. Pelletier
-
Patent number: 5498656Abstract: Proposed is a polyvinyl alcohol molding resin composition exhibiting excellent workability in the molding procedure by extrusion and injection and capable of giving molded articles, e.g., films and sheets, having excellent properties in respect of good appearance and excellent resistance against coloration by heating. The molding resin composition comprises a polyvinyl alcohol and a limited amount of an additive ingredient which is an alkali or alkaline earth metal salt of organic sulfonic acid, e.g., sodium and calcium dodecylbenzene sulfonates, a polyoxyethylene ester of phosphoric acid or a combination thereof.Type: GrantFiled: March 31, 1995Date of Patent: March 12, 1996Assignees: Shin-Etsu Polymer Co., Ltd., Akishima Chemical Industries Co., Ltd.Inventors: Yusuke Morita, Masami Fukushima, Fumio Gotou, Shigeo Aoki
-
Patent number: 5496921Abstract: Polycarbonates are prepared by inducing the melt polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of alkali metal compounds and/or alkaline earth metal compound droxy and adding to the polycarbonate which is the reaction product thereof: a sulfonic acid compound having the formula ##STR1## in an amount of 0.05-10 ppm, based on the polycarbonate, an epoxy compound in an amount of 1-2000 ppm, based on the polycarbonate and a phosphorus compound in an amount of 10-1000 ppm, based on the polycarbonate.Type: GrantFiled: October 24, 1994Date of Patent: March 5, 1996Assignee: GE Plastics JapanInventors: Takeshi Sakashita, Tomoaki Shimoda
-
Patent number: 5494952Abstract: A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfanate group and a sulfonic acid anhydride group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.Type: GrantFiled: May 10, 1995Date of Patent: February 27, 1996Assignee: Teijin LimitedInventors: Masumi Hirata, Wataru Funakoshi, Katsushi Sasaki
-
Patent number: 5491187Abstract: Methods for reducing or eliminating static electric charges on resins by adding to the resins an effective amount of at least one substituted ammonium salt of an alkylbenzene sulfonic acid, the salt having the formula: ##STR1## wherein R is a straight or branched chain alkyl group having from 10 to 14 carbon atoms, R.sub.1 is hydroxyethyl or an alkyl group having from one to six carbon atoms, R.sub.2 and R.sub.3 are the same or different and are hydroxyethyl, an alkyl group having from one to six carbon atoms, or hydrogen, and R.sub.4 is hydrogen or an alkyl group having from one to six carbon atoms, together with resins so produced and compositions additionally containing fatty acids for such use.Type: GrantFiled: June 6, 1995Date of Patent: February 13, 1996Assignee: Witco CorporationInventors: James J. Ward, William P. Chatham
-
Patent number: 5486555Abstract: A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having either a sulfonate group, a sulfonic acid anhydride group or a sulfate group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.Type: GrantFiled: May 10, 1995Date of Patent: January 23, 1996Assignee: Teijin LimitedInventors: Masumi Hirata, Wataru Funakoshi, Katsushi Sasaki
-
Patent number: 5476892Abstract: Polyols are conditioned and stabilized by mixing them at 0 to 150.degree. C. with from about 0.0001 to about 1% by weight, based on the quantity of polyol, of a silylated acid corresponding to the formula:X--[Si(CH.sub.3).sub.3 ].sub.nin whichX represents a neutral acid residue obtained by removal of the acidic hydrogen atoms from an n-basic acid having a maximum pKa value of 3, provided that the n-basic acid is not a hydrohalic acid andn represents an integer of from 1 to 3.The resultant polyol is characterized by good color and activity properties. The stabilized polyols are particularly useful in the production of polyurethanes, particularly polyurethane foams.Type: GrantFiled: December 9, 1993Date of Patent: December 19, 1995Assignee: Bayer AktiengesellschaftInventors: Hans J. Scholl, Hartmut Nefzger, Helmut Reiff, Bernd Quiring
-
Patent number: 5470899Abstract: A process for reducing the pH of anionic polyurethane dispersions which are stabilized by carboxylate or sulfonate groups, which comprises adding a compound which has from one to four ester groups but no acid group or acid halide or anhydride group to the dispersions.Type: GrantFiled: December 28, 1993Date of Patent: November 28, 1995Assignee: BASF AktiengesellschaftInventors: Erich Gulbins, Karl Haeberle, Ulrike Licht, Alexander Wallon
-
Patent number: 5468793Abstract: Methods for reducing or eliminating static electric charges on resins by adding to the resins an effective amount of at least one substituted ammonium salt of an alkylbenzene sulfonic acid, the salt having the formula: ##STR1## wherein R is a straight or branched chain alkyl group having from 10 to 14 carbon atoms, R.sub.1 is hydroxyethyl or an alkyl group having from one to six carbon atoms, R.sub.2 and R.sub.3 are the same or different and are hydroxyethyl, an alkyl group having from one to six carbon atoms, or hydrogen, and R.sub.4 is hydrogen or an alkyl group having from one to six carbon atoms, together with resins so produced and compositions additionally containing fatty acids for such use.Type: GrantFiled: July 25, 1994Date of Patent: November 21, 1995Assignee: Wico CorporationInventors: James J. Ward, William P. Chatham
-
Patent number: 5464895Abstract: A dispersing agent for use in a thermosetting composition, a thermosetting composition containing said dispersing agent, and application thereof to thermosetting composition having no yield point. The dispersing agent acting on mineral fillers and used in filled acrylic or polyester resin-based thermosetting compositions belongs to the family of organophosphates corresponding to the general formula: ##STR1## where: A is a branched or unbranched polyaryl group,x and y are whole numbers between 0 and 100 such that x+y is a whole number greater than 40 but not greater than 100, ##STR2## B and E are independently a branched or unbranched polyaryl group, or an alkyl, aryl, arylalkyl, alkylaryl, alkanoyl, or amine radical, and in B and E, and R.sub.1 and R.sub.2 may be identical or different, x1, y1, x2 and y2 are whole numbers, and the sums x1+y1 and x2+y2 are not greater than 100.Type: GrantFiled: September 29, 1994Date of Patent: November 7, 1995Assignee: Coatex, S.A.Inventors: Pierre Blanchard, Jean-Bernard Egraz, Georges Ravet
-
Patent number: 5456862Abstract: This invention relates to compositions of thermally stable electrically conductive substituted and unsubstituted polyanilines and to conductive articles formed from such compositions.Type: GrantFiled: July 11, 1994Date of Patent: October 10, 1995Assignee: AlliedSignal Inc.Inventors: A. Jen Kwan-Yue, Ronald L. Elsenbaumer
-
Patent number: 5424343Abstract: A cyanoacrylate monomer adhesive formulation which has improved thermal properties resulting from the inclusion in the formulation of an effective amount for enhancing the thermal resistance of the cured polymer of a naphthosultone compound having at least one strong electron withdrawing group thereon, suitably a nitro group.Type: GrantFiled: October 8, 1992Date of Patent: June 13, 1995Assignee: Loctite CorporationInventor: Shabbir Attarwala
-
Patent number: 5418269Abstract: Optical grade polycarbonate resin compositions and methods for their preparation are disclosed. The disclosed compositions are comprised of polycarbonate resins and esters of aliphatic carboxylic acids and alcohols and exhibit good mold release and thermal stability while experiencing little discoloration during molding.Type: GrantFiled: March 19, 1993Date of Patent: May 23, 1995Assignee: GE Plastics JapanInventors: Kenichi Ishiwa, Hideyuki Itoi
-
Patent number: 5403878Abstract: Polycarbonate resin compositions suitable for optical uses and methods for their preparation are disclosed. The disclosed compositions are comprised of polycarbonate resins and .alpha.-olefin oligomers and exhibit good mold release and thermal stability while experiencing little discoloration or molecular weight reduction during molding.Type: GrantFiled: March 17, 1993Date of Patent: April 4, 1995Inventors: Kenichi Ishiwa, Hideyuki Itoi