Aryl Group Patents (Class 524/158)
  • Patent number: 6423367
    Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: July 23, 2002
    Assignee: 3M Innovative Properties Company
    Inventor: Robert Steven Clough
  • Patent number: 6380283
    Abstract: A method of treating natural rubber latex to reduce the antigenic protein content includes enzyme treatment of the natural rubber latex and utilizing a chemical stabilizer of the type similar to branched dodecyl benzene sulphonic acid alone or in combination with other stabilizers such as a sulfated fatty acid in combination with hydroxypropyl methylcellulose is disclosed. Also disclosed is a treatment of natural rubber latex with antioxidants either alone or together which ether serve to allow natural rubber latex products to be chlorinated without suffering debilitating aging effects. The first antioxidant is of the type 4,4-(6-T-butyl-M-cresol) or 4,4+-Butylidenebis (3-methyl-6-tert-butylphenol) while the second antioxidant is of the type of a polymeric hindered phenol or butylated reaction product of P-cresol and dicyclopentadiene.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: April 30, 2002
    Assignee: Tillotson Healthcare Corporation
    Inventors: Frank W. Perrella, Joseph K. Pieroni, Thomas N. Tillotson
  • Patent number: 6316533
    Abstract: A composition containing (A) one or more aromatic sulfonates, (B) one or more aldehyde resins and (C) a buffer and is prepared and used for treating, in particular neutralizing, leather tanned with mineral compounds or mineral-free compounds.
    Type: Grant
    Filed: August 26, 1999
    Date of Patent: November 13, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Wolf, Georg Igl, Thomas Grösser, Adolf Stübinger, Jürgen Werner, Erhard Guenther
  • Patent number: 6310124
    Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: October 30, 2001
    Assignee: Cytec Technology, Corp.
    Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
  • Patent number: 6306209
    Abstract: A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by polymerizing (i) at least one prepolymer having a radically polymerizable group, and (ii) at least one second monomer. The prepolymer is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of at least one radically polymerizable first monomer. The second monomer forms a polymeric backbone segment of the pigment dispersant, and the prepolymer forms polymeric segments that are pendent to the backbone. The backbone segment of the pigment dispersant is hydrophilic, while at least a portion of each pendent polymeric segment is hydrophobic.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: October 23, 2001
    Assignee: PPG Industries Ohio, inc.
    Inventors: Brian E. Woodworth, Gregory J. McCollum, James B. O'Dwyer, Simion Coca
  • Publication number: 20010031806
    Abstract: An optical brightener mixture comprising
    Type: Application
    Filed: February 8, 2001
    Publication date: October 18, 2001
    Inventors: Thomas Lutkenhorst, Thomas Martini, Joseph Thomas Craddock
  • Patent number: 6297296
    Abstract: The invention relates to the use of cationic latex particles that can complex with anionic dyes to provide water fastness and further to provide a medium in which inherently unstable anionic dyes can be brought in close proximity with other anionic components, by complexation to cationic latices, in order to stabilize the anionic dyes especially with regard to light and oxidative degradation. In particular this invention will provide for methods of generating waterfast and improved lightfast ink jet images.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: October 2, 2001
    Assignee: Kodak Polychrome Graphics LLC
    Inventor: Allan Wexler
  • Patent number: 6294270
    Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: September 25, 2001
    Assignee: 3M Innovative Properties Company
    Inventor: Robert Steven Clough
  • Patent number: 6271290
    Abstract: The present invention provides a method for making a polycarbonate composition. The polycarbonate is prepared by melt synthesis using a sulfur-containing acid compound to at least partially quench the melt catalyst. The polycarbonate composition comprises said polycarbonate, phosphorous acid, further sulfur-containing acid compound and an ester derived from a mono-fatty acid and a polyhydric alcohol.
    Type: Grant
    Filed: December 6, 1999
    Date of Patent: August 7, 2001
    Assignee: General Electric Company
    Inventors: Kazushige Inoue, Hiromi Ishida, Theodorus Lambertus Hoeks, Lennard Alexander Markestein
  • Patent number: 6248818
    Abstract: Disclosed are polythiophene-based conductive polymer liquid compositions of high conductivity and transparency. The compositions comprise 16-32 weight % of an aqueous polythiophene-based conductive polymer solution, 52-80 weight % of an alcohol solvent, 1-12 weight % of an amide solvent, 0.01-0.4 weight % of a sulfonic acid group-containing monomer dopant, and optionally 2-8 weight % of an alkoxysilane. The compositions can be applied to transparent substrates to form coatings which have a surface resistance of 1 k&OHgr;/□ or less and a transmittance of 92% or higher. With the excellent conductivity and transparency, the compositions are useful as electromagnetic wave-shielding materials, finding numerous applications in cathode ray tube screens (TV sets and computer monitors) as well as CPP films, polyethyleneterephthalate films, polycarbonate panels, and acryl panels.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: June 19, 2001
    Assignee: Samsung General Chemicals Co. Ltd.
    Inventors: Hyun Don Kim, Hae Ryong Chung, Min Kyo Cheong, Tu Won Chang
  • Patent number: 6225386
    Abstract: An antistatic agent having phosphonium sulfonate of a specified kind and inorganic sulfonate of a specified kind mixed at a specified ratio can provide synthetic polymer materials with a superior antistatic characteristic without adversely affecting the natural hue and transparency of the material. Aliphatic carboxylic acid ester of polyhydric alcohol may also be mixed together in the agent.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: May 1, 2001
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventor: Masahiro Suzuki
  • Patent number: 6177511
    Abstract: Novel organopolysiloxane compositions comprising (A) organopolysiloxanes which contain at least one SiC-bonded organic radical containing basic nitrogen, where the basic nitrogen is optionally present in part as a salt of a water-soluble organic acid, water-soluble inorganic acid, or water-insoluble organic acid, (B) anionic, cationic, nonionic or amphoteric surfactants, which are in soluble or soluble in (A) (C) substituted or unsubstituted diacrylates and/or oligoacrylates, and optionally, (C′) substituted or unsubstituted acrylates, and (D) water are described.
    Type: Grant
    Filed: January 25, 1999
    Date of Patent: January 23, 2001
    Assignee: Wacker-Chemie GmbH
    Inventors: Jochen Dauth, Bernward Deubzer, Robert Schröck, Petra Gratzl
  • Patent number: 6172147
    Abstract: Mortar cement additives provide workability while retaining strength by employing a multi-stage polymer comprising a hydrophobically-modified, ionically-soluble polymer stage, the polymer being soluble at a pH of 6 and above; and an air-entraining agent. The additives also employ, as optional ingredients, set retarding agents and superplasticizers. Examplary methods of the invention involve addition of the multi-stage polymer and an air entraining agent to the mortar cement, preferably during intergrinding of Portland cement in the mill. Cement compositions comprising the polymer and an air-entraining agent are also disclosed.
    Type: Grant
    Filed: May 5, 1998
    Date of Patent: January 9, 2001
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Angel Abelleira, John Hallock
  • Patent number: 6160027
    Abstract: It is desirable to reduce the amount of volatile organic blowing agent in expandable polystyrene. This may be accomplished by partially polymerizing a mass of styrene and incorporating therein water together with an emulsifier. The partially polymerized mass is then polymerized to a high conversion using conventional suspension techniques. The polymer beads containing water which acts as a blowing agent are recovered.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: December 12, 2000
    Assignee: Nova Chemicals (International) S.A.
    Inventors: Jeroen Joost Crevecoeur, Eric Wilhelmus Johannes Frederik Neijman, Laurentius Nicolaas Ida Hubertus Nelissen, Johannes Maria Zijderveld
  • Patent number: 6153304
    Abstract: Articles of manufacture are provided with a low surface energy, permanently non-stick, non-fouling and ice-phobic surface by a system of coating comprising applying a primary coating having a surface energy of 22-28 dynes/cm.sup.2 comprising a novel polymeric material having non-stick and hardness properties and then applying a top coating having lower surface energy of from about 18-21 dynes/cm.sup.2 comprising a siliconic polymer and interdigitating means to make the top coating permanent, the means preferably comprising a bi- or polyfunctional organic compound adapted to wet the surface of the primary coating and chemically or physically bond thereto and to couple to the siliconic polymeric substance in the top coating. The coated substrates are resistant to marking by graffiti, to adherence by marine fouling organisms, and frozen ice on the surface is easily removed.
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: November 28, 2000
    Assignee: Decora Incorporated
    Inventors: John Ralph Smith, Nissim N. Garti
  • Patent number: 6150443
    Abstract: Provided are a flame-retardant polycarbonate resin composition capable of being formed into moldings having good impact resistance, high strength and good thermal stability that are intrinsic to polycarbonate resins and having good antistatic properties and good flame retardancy, and also injection moldings of the composition. The composition comprises 100 parts by weight of a resin or resin mixture of (A) from 50 to 100% by weight of a polycarbonate resin and (B) from 0 to 50% by weight of a styrenic resin, from 1 to 50 parts by weight of (C) a flame retardant, and from 0.1 to 5 parts by weight of (D) an anionic antistatic agent, and has a sodium sulfate content of at most 0.05% by weight. Optionally, the composition may contain (F) a fluoro-olefinic resin, (G) a rubber-like elastomer, and (H) an inorganic filler.
    Type: Grant
    Filed: August 9, 1999
    Date of Patent: November 21, 2000
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Akio Nodera, Naoki Mitsuta
  • Patent number: 6020407
    Abstract: An improved thickening composition for aqueous systems including latex paints and coatings is described. The substantially anhydrous composition comprises in specified ratios a solid thickener polymer, and one or more surfactants. The solid thickener polymer includes associative thickeners. Associative thickener polymers include polyurethanes, polyesters, polyacrylamides, modified hydroxyethyl celluloses, alkali soluble emulsions and other chemicals. Specific surfactants utilized include dialkyl sulfosuccinates, alkyl sulfates, alpha olefin sulfonates and sulfates of ethoxylated alcohols.
    Type: Grant
    Filed: November 7, 1995
    Date of Patent: February 1, 2000
    Assignee: Rheox, Inc.
    Inventors: Barbara A. Campbell, Joseph G. Doolan, Charles A. Cody, Wilbur Mardis
  • Patent number: 5994458
    Abstract: A process for the preparation of a latex comprising the polymerization of monomer in the presence of a chain transfer component, an initiator, a diphenyloxide disulfonate, and an optional nonionic surfactant.
    Type: Grant
    Filed: September 2, 1998
    Date of Patent: November 30, 1999
    Assignee: Xerox Corporation
    Inventors: Chieh-Min Cheng, Grazyna E. Kmiecik-Lawrynowicz
  • Patent number: 5993532
    Abstract: A stabilized solution of hydrogen silsesquioxane resin is disclosed. The solution comprises 100 parts by weight solvent, 0.1 to 100 parts by weight hydrogen silsesquioxane resin, and 0.002 to 4 parts by weight acid. These solutions are useful for forming coatings on substrates.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: November 30, 1999
    Assignees: Dow Corning Corporation, Dow Corning Toray Silicone Co., Ltd.
    Inventors: Dennis William Broderick, James Anthony Helwick, Takashi Nakamura
  • Patent number: 5948838
    Abstract: The present invention relates to a polycarbonate resin composition comprising 100 parts by weight of a polycarbonate resin; 0.01 to 5 parts by weight of a compound containing oxymethylene unit, a compound containing oxymethylene unit having substituent or a cyclic ether compound having substituent.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: September 7, 1999
    Assignee: Mitsubishi Engineering-Plastics Corp.
    Inventors: Shinya Miya, Satoshi Kanayama
  • Patent number: 5919854
    Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: July 6, 1999
    Assignee: Cytec Technology Corp.
    Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
  • Patent number: 5888405
    Abstract: The invention relates to a method to inhibit bacteria from adhering to a submergible surface. The method contacts the submergible surface with an effective amount of at least one amino methyl phosphonic acid or salt thereof to inhibit bacterial adhesion to the submergible surface. The invention also relates to a method for controlling biofouling of an aqueous system. This method adds an effective amount of at least one amino methyl phosphonic acid or salt thereof to inhibit bacteria from adhering to a submerged surface within the aqueous system. This method effectively controls biofouling without substantially killing the fouling organisms. The amino methyl phosphonic acid used in the methods of the invention has the formula R.sup.1 R.sup.2 NCH.sub.2 P(O)(OH).sub.2. In this formula, R.sup.1 and R.sup.2 are independently a C.sub.6 -C.sub.20 alkyl group or a CH.sub.2 P(O)(OH).sub.2 group. However, R.sup.1 and R.sup.2 are not both a CH.sub.2 P(O)(OH).sub.2 group. Alternatively, R.sup.1 and R.sup.
    Type: Grant
    Filed: July 29, 1997
    Date of Patent: March 30, 1999
    Assignee: Buckman Laboratories International Inc.
    Inventors: Thomas E. McNeel, Marilyn S. Whittemore, Stephen D. Bryant, Graciela H. Vunk
  • Patent number: 5852087
    Abstract: Easily dyeable meta-linkage-containing aromatic polyamide fibers consisting of a composition which comprises a meta-linkage-containing aromatic polyamide incorporating a quaternary onium salt of an alkylbenzenesulfonic acid. They are easily dyeable with cationic dyes, and thus may be used in the fields of bedding, clothing and interior decoration.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: December 22, 1998
    Assignee: Teijin Limited
    Inventors: Akihiro Ohba, Koki Sasaki
  • Patent number: 5798410
    Abstract: Artificial latexes that are film forming at room temperature can be prepared from a copolymer of ethylene and a C.sub.3 -C.sub.20 .alpha.-olefin. The copolymer is characterized by having a polydispersity index not greater than 2.5; random distribution of comonomer units along the polymer backbone; and a homogeneity index of at least 75. The copolymer preferably contains no polar substituents, which are generally necessary to make useful latexes from polyethylene.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: August 25, 1998
    Assignee: The Dow Chemical Company
    Inventors: Brian W. Walther, James R. Bethea
  • Patent number: 5760112
    Abstract: A water-borne autodepositing coating composition that has a pH of 1.6 to 5 and contains as essential components a water-dispersible or water-soluble organic coating-forming resin, a liquid dispersion of carbon black, acid, and oxidizing agent, and that may contain metal ions as an optional component, has an excellent storage stability and produces a strongly adherent and highly corrosion-resistant coating when the liquid dispersion of carbon black is an aqueous dispersion in which carbon black is dispersed using as a dispersant a naphthalenesulfonate-formaldehyde condensate.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: June 2, 1998
    Assignee: Henkel Corporation
    Inventors: Mutsumi Hirota, Takumi Honda, Norifumi Hatano, Shoichi Sangenya, Shunjiro Saiki
  • Patent number: 5739177
    Abstract: A dental composition containing an acid such as maleic acid, phosphoric acid or citric acid; an organosulfonate and/or an organosulfinate such as an acid group-containing (meth)acrylate monomer having in the molecules thereof a carboxyl group or a phosphoric acid group, a sodium benzenesulfonate or a sodium p-toluenesulfinate; a water-soluble organic solvent such as ethanol or propanol; and the water: but without substantially containing any polymerizable monomer except the above acid group-containing (meth)acrylate monomer, or further containing a hydroxy- or a dihydroxyalkyl (meth)acrylate monomer. For adhesion of a dental filling material to teeth, the composition of the invention is used as a pre-treatment agent on teeth prior to applying an adhesive. This makes it possible to treat enamel and dentin simultaneously and to accomplish strong adhesive strength to both of them.
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: April 14, 1998
    Assignee: Tokuyama Corporation
    Inventors: Hideki Ohno, Mikio Kimura, Satoru Fuchigami, Makoto Oguri
  • Patent number: 5717057
    Abstract: A method for manufacturing polycarbonate in which an aromatic dihydroxy compound and a carbonic acid diester can be effectively subjected to melt polycondensation using a small amount of a catalyst, making it possible to manufacture polycarbonate having outstanding color matching, outstanding thermal stability, color-matching stability, etc., during molding, and outstanding water resistance is characterized in that when an aromatic dihydroxy compound and a carbonic acid diester are subjected to melt polycondensation in the presence of a catalyst, the catalyst is dissolved or dispersed as a catalyst solution, this catalyst solution is added to the melt polycondensation reaction system, and the aromatic dihydroxy compound and carbonic acid diester are subjected to melt polycondensation.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: February 10, 1998
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5686512
    Abstract: The present invention discloses a process for manufacturing surfactants for hydrocarbon by modifying the paper making black liquor resin using modifying agents. The process is to react or combine an alkaline aqueous solution, chemical substances such as olefin, aromatic hydrocarbon, and fatty acids, amino acids, phospholipids as well as one or more of the surfactants for petroleum recovery with 20%-80% of the paper making black liquor resin, the reaction lasting for 1-3 hours at the temperature of 80.degree.-100.degree. C. and ordinary pressure, the pH value of the reaction mixture being kept at 10-12. The surfactant prepared by this method can be effectively used in the recovery of thick oil, asphalt emulsification for road pavement and the oil driving in tertiary recovery oil drainage in petroleum recovery. It has remarkable viscosity reducing effect on petroleum, its emulsification ability being strong, its viscosity reducing rate for 3.0.times.10.sup.5 -5.0.times.10.sup.
    Type: Grant
    Filed: July 31, 1995
    Date of Patent: November 11, 1997
    Inventor: Dongsheng Liu
  • Patent number: 5668202
    Abstract: A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfonates group sulfonic acid anhydride group or a sulfate group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: September 16, 1997
    Assignee: Teijin Limited
    Inventors: Masumi Hirata, Wataru Funakoshi, Katsushi Sasaki
  • Patent number: 5656680
    Abstract: The invention provides a processing aid and method for lubricating and improving the processability and releasability of rubber and plastic without adversely affecting and, in certain instances, improving the physical properties of the rubber or plastic such as adhesion, tack, modulus and tensile strength. The processing aid comprises a pre-formed homogeneous mixture of at least one silicone fluid lubricant and at least one peptizing agent. A preferred processing aid also includes a silicone fluid wetting agent, which affords decreased vulcanization times and increased production rates.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: August 12, 1997
    Assignee: Technical Processing, Inc.
    Inventors: Enrique Aguirre, Paul R. Yankner
  • Patent number: 5610212
    Abstract: A means for stabilizing a deproteinized natural rubber latex is disclosed, comprising adding a stabilizer selected from the group consisting of (a) an anionic surfactant, (b) an amphoteric surfactant, (c) a nonionic surfactant, (d) a nonionic or amphoteric oligomer or polymer, and (e) an anionic oligomer or polymer. By adding the stabilizer, the mechanical stability of a deproteinized natural rubber latex can be markedly improved.
    Type: Grant
    Filed: May 13, 1994
    Date of Patent: March 11, 1997
    Assignees: Kao Corporation, Sumitomo Rubber Industries, Ltd.
    Inventors: Yasuyuki Tanaka, Yuichi Hioki, Masaharu Hayashi, Naoya Ichikawa, Toshiaki Sakaki
  • Patent number: 5606008
    Abstract: The purpose of the present invention is to provide a method for manufacturing polycarbonate in which polycarbonate having outstanding color matching, outstanding thermal properties, particularly retention stability during molding, and outstanding water resistance can be effectively and easily manufactured.In the method for manufacturing polycarbonate of the present invention, an aromatic dihydroxy compound and a carbonic acid ester are subjected to melt condensation polymerization in the presence of a catalyst composed of(a) an aliphatic amine with 24-60 carbon atoms, and (b) an alkali metal compound and/or alkaline earth metal compound.The (a) aliphatic amine having 24-60 carbon atoms should preferably be an aliphatic tertiary amine and be used in the amount of 1.times.6.sup.-6 -1.times.10.sup.-1 moles for each mole of the aromatic dihydroxy compound, and the (b) alkali metal compound and/or alkaline earth metal compound should be used in an extremely minute specified amount.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: February 25, 1997
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5574091
    Abstract: Artificial latexes that are film-forming at room temperature can be prepared from a copolymer of ethylene and a C.sub.3 -C.sub.20 alpha olefin. The copolymer preferably contains no polar substituents, which are generally necessary to make useful latexes from polyethylene.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: November 12, 1996
    Assignee: The Dow Chemical Comapny
    Inventors: Brian W. Walther, Jim R. Bethea
  • Patent number: 5574101
    Abstract: An acrylic resin composition comprising at least one polyamide elastomer consisting of hard segments and soft segments in a specified ratio, an acrylic resin and optionally at least one electrolyte, which has excellent permanent antistatic properties, is good in transparency, has a very faint color, is inexpensive, and is only slightly deteriorated in transparency even when immersed in water.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: November 12, 1996
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Kiyoshi Kawakami, Yuzuru Ishibashi, Toshio Suzuki
  • Patent number: 5548009
    Abstract: A process for improving the storage life of a one-component silicone paste containing an alkali metal phosphate and which cures with elimination of acetic acid on exposure to atmospheric moisture, which comprises adding to such paste an acidic additive bearing the functional group --SO.sub.3 H or hydrogen chloride in a concentration sufficient to convene the alkali metal phosphate into the alkali metal salt of the acidic additive.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: August 20, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wilhelm Weber, Karl-Heinz Sockel, Hans-Heinrich Moretto
  • Patent number: 5521239
    Abstract: The invention concerns a rubber eraser made of a binder and plasticizer, as well as fillers, pigments and/or other additives, if applicable, which contains polyalkyl methacrylate (PAMA), especially polymethyl methacrylate (PMMA), polyethyl methacrylate (PEMA), polypropyl methacrylate (PPMA), polybutyl methacrylate (PBMA) and/or copolymerizates of these as the binder. Furthermore, the invention concerns processes for manufacturing such rubber erasers, where either first, a plastisol of fine-grain polyalkyl methacrylate and plasticizer is formed, and fillers, internal lubricants, pigments and/or other additives are then mixed into this plastisol, or according to which first, the PAMA powder, the filler as well as any other dry components such as internal lubricants, pigments, etc. are intimately mixed while dry, and the liquid plasticizer is then added to this mixture and mixed or kneaded in.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: May 28, 1996
    Assignee: J. S. Staedtler GmbH & Co.
    Inventor: Werner Handl
  • Patent number: 5500469
    Abstract: An artificial latex comprising a stable aqueous colloidal dispersion of a preformed multiblock copolymer prepared using a sulfate of an ethoxylated phenol as a dispersing and stabilizing agent is described. This composition is particularly suitable for preparing articles such as gloves or condoms that are free of vulcanizing agents and proteins.
    Type: Grant
    Filed: September 22, 1994
    Date of Patent: March 19, 1996
    Assignee: The Dow Chemical Company
    Inventors: Kenneth E. Johnsen, Ronald R. Pelletier
  • Patent number: 5498656
    Abstract: Proposed is a polyvinyl alcohol molding resin composition exhibiting excellent workability in the molding procedure by extrusion and injection and capable of giving molded articles, e.g., films and sheets, having excellent properties in respect of good appearance and excellent resistance against coloration by heating. The molding resin composition comprises a polyvinyl alcohol and a limited amount of an additive ingredient which is an alkali or alkaline earth metal salt of organic sulfonic acid, e.g., sodium and calcium dodecylbenzene sulfonates, a polyoxyethylene ester of phosphoric acid or a combination thereof.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: March 12, 1996
    Assignees: Shin-Etsu Polymer Co., Ltd., Akishima Chemical Industries Co., Ltd.
    Inventors: Yusuke Morita, Masami Fukushima, Fumio Gotou, Shigeo Aoki
  • Patent number: 5496921
    Abstract: Polycarbonates are prepared by inducing the melt polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of alkali metal compounds and/or alkaline earth metal compound droxy and adding to the polycarbonate which is the reaction product thereof: a sulfonic acid compound having the formula ##STR1## in an amount of 0.05-10 ppm, based on the polycarbonate, an epoxy compound in an amount of 1-2000 ppm, based on the polycarbonate and a phosphorus compound in an amount of 10-1000 ppm, based on the polycarbonate.
    Type: Grant
    Filed: October 24, 1994
    Date of Patent: March 5, 1996
    Assignee: GE Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5494952
    Abstract: A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfanate group and a sulfonic acid anhydride group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: February 27, 1996
    Assignee: Teijin Limited
    Inventors: Masumi Hirata, Wataru Funakoshi, Katsushi Sasaki
  • Patent number: 5491187
    Abstract: Methods for reducing or eliminating static electric charges on resins by adding to the resins an effective amount of at least one substituted ammonium salt of an alkylbenzene sulfonic acid, the salt having the formula: ##STR1## wherein R is a straight or branched chain alkyl group having from 10 to 14 carbon atoms, R.sub.1 is hydroxyethyl or an alkyl group having from one to six carbon atoms, R.sub.2 and R.sub.3 are the same or different and are hydroxyethyl, an alkyl group having from one to six carbon atoms, or hydrogen, and R.sub.4 is hydrogen or an alkyl group having from one to six carbon atoms, together with resins so produced and compositions additionally containing fatty acids for such use.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: February 13, 1996
    Assignee: Witco Corporation
    Inventors: James J. Ward, William P. Chatham
  • Patent number: 5486555
    Abstract: A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having either a sulfonate group, a sulfonic acid anhydride group or a sulfate group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: January 23, 1996
    Assignee: Teijin Limited
    Inventors: Masumi Hirata, Wataru Funakoshi, Katsushi Sasaki
  • Patent number: 5476892
    Abstract: Polyols are conditioned and stabilized by mixing them at 0 to 150.degree. C. with from about 0.0001 to about 1% by weight, based on the quantity of polyol, of a silylated acid corresponding to the formula:X--[Si(CH.sub.3).sub.3 ].sub.nin whichX represents a neutral acid residue obtained by removal of the acidic hydrogen atoms from an n-basic acid having a maximum pKa value of 3, provided that the n-basic acid is not a hydrohalic acid andn represents an integer of from 1 to 3.The resultant polyol is characterized by good color and activity properties. The stabilized polyols are particularly useful in the production of polyurethanes, particularly polyurethane foams.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: December 19, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans J. Scholl, Hartmut Nefzger, Helmut Reiff, Bernd Quiring
  • Patent number: 5470899
    Abstract: A process for reducing the pH of anionic polyurethane dispersions which are stabilized by carboxylate or sulfonate groups, which comprises adding a compound which has from one to four ester groups but no acid group or acid halide or anhydride group to the dispersions.
    Type: Grant
    Filed: December 28, 1993
    Date of Patent: November 28, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Erich Gulbins, Karl Haeberle, Ulrike Licht, Alexander Wallon
  • Patent number: 5468793
    Abstract: Methods for reducing or eliminating static electric charges on resins by adding to the resins an effective amount of at least one substituted ammonium salt of an alkylbenzene sulfonic acid, the salt having the formula: ##STR1## wherein R is a straight or branched chain alkyl group having from 10 to 14 carbon atoms, R.sub.1 is hydroxyethyl or an alkyl group having from one to six carbon atoms, R.sub.2 and R.sub.3 are the same or different and are hydroxyethyl, an alkyl group having from one to six carbon atoms, or hydrogen, and R.sub.4 is hydrogen or an alkyl group having from one to six carbon atoms, together with resins so produced and compositions additionally containing fatty acids for such use.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: November 21, 1995
    Assignee: Wico Corporation
    Inventors: James J. Ward, William P. Chatham
  • Patent number: 5464895
    Abstract: A dispersing agent for use in a thermosetting composition, a thermosetting composition containing said dispersing agent, and application thereof to thermosetting composition having no yield point. The dispersing agent acting on mineral fillers and used in filled acrylic or polyester resin-based thermosetting compositions belongs to the family of organophosphates corresponding to the general formula: ##STR1## where: A is a branched or unbranched polyaryl group,x and y are whole numbers between 0 and 100 such that x+y is a whole number greater than 40 but not greater than 100, ##STR2## B and E are independently a branched or unbranched polyaryl group, or an alkyl, aryl, arylalkyl, alkylaryl, alkanoyl, or amine radical, and in B and E, and R.sub.1 and R.sub.2 may be identical or different, x1, y1, x2 and y2 are whole numbers, and the sums x1+y1 and x2+y2 are not greater than 100.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: November 7, 1995
    Assignee: Coatex, S.A.
    Inventors: Pierre Blanchard, Jean-Bernard Egraz, Georges Ravet
  • Patent number: 5456862
    Abstract: This invention relates to compositions of thermally stable electrically conductive substituted and unsubstituted polyanilines and to conductive articles formed from such compositions.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: October 10, 1995
    Assignee: AlliedSignal Inc.
    Inventors: A. Jen Kwan-Yue, Ronald L. Elsenbaumer
  • Patent number: 5424343
    Abstract: A cyanoacrylate monomer adhesive formulation which has improved thermal properties resulting from the inclusion in the formulation of an effective amount for enhancing the thermal resistance of the cured polymer of a naphthosultone compound having at least one strong electron withdrawing group thereon, suitably a nitro group.
    Type: Grant
    Filed: October 8, 1992
    Date of Patent: June 13, 1995
    Assignee: Loctite Corporation
    Inventor: Shabbir Attarwala
  • Patent number: 5418269
    Abstract: Optical grade polycarbonate resin compositions and methods for their preparation are disclosed. The disclosed compositions are comprised of polycarbonate resins and esters of aliphatic carboxylic acids and alcohols and exhibit good mold release and thermal stability while experiencing little discoloration during molding.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: May 23, 1995
    Assignee: GE Plastics Japan
    Inventors: Kenichi Ishiwa, Hideyuki Itoi
  • Patent number: 5403878
    Abstract: Polycarbonate resin compositions suitable for optical uses and methods for their preparation are disclosed. The disclosed compositions are comprised of polycarbonate resins and .alpha.-olefin oligomers and exhibit good mold release and thermal stability while experiencing little discoloration or molecular weight reduction during molding.
    Type: Grant
    Filed: March 17, 1993
    Date of Patent: April 4, 1995
    Inventors: Kenichi Ishiwa, Hideyuki Itoi