Two Or More N-n Bonds Patents (Class 524/192)
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Patent number: 11884846Abstract: Described is an adhesive composition in the form of an aqueous polymer dispersion comprising tackifiers, a compound crosslinking via keto or aldehyde groups and a pressure-sensitive adhesive polymer which is formed by emulsion polymerization from soft (meth)acrylic ester monomers, acid monomers, monomers having keto or aldehyde groups, styrene and optionally further monomers, wherein the polymerization may be carried out in the presence of chain transfer agents. The pressure-sensitive adhesive polymer has certain gel contents. The pressure-sensitive adhesive composition may be used to produce adhesive labels, adhesive tapes or adhesive films.Type: GrantFiled: April 10, 2019Date of Patent: January 30, 2024Inventors: Matthias Gerst, Dirk Wulff
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Patent number: 11292892Abstract: Disclosed is a flame retardant composition containing (A) an amine phosphate and (B) a zinc glycerolate. It is preferred that component (A) contain an amine pyrophosphate and that the mass ratio of component (A) to component (B) be 99.99:0.01 to 60:40. The flame retardant composition preferably further contains (C) zinc oxide, wherein the content of component (C) is 0.01 to 10 parts by mass per 100 parts by mass of the sum of components (A) and (B). The flame retardant composition preferably further contains (D) hydrotalcite, wherein the content of component (D) is 0.01 to 5 parts by mass per 100 parts by mass of the sum of components (A) and (B).Type: GrantFiled: May 15, 2018Date of Patent: April 5, 2022Assignee: ADEKA CORPORATIONInventors: Yang Ni, Yutaka Yonezawa, Naoko Tanji
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Patent number: 9828509Abstract: The present invention is a composition comprising a) an aqueous dispersion of TiO2 particles encapsulated with an encapsulating acrylic or styrene-acrylic polymer comprising from structural units of diacetone acrylamide; and b) adipic acid dihydrazide. The composition is useful in coatings applications and shows a surprising improvement in gloss over compositions that do not include diacetone acrylamide functionalized encapsulating polymer and adipic acid dihydrazide.Type: GrantFiled: June 29, 2016Date of Patent: November 28, 2017Assignee: Rohm and Haas CompanyInventors: James C. Bohling, David G. Kelly, Pu Luo, Yogesh Tiwary
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Patent number: 9670336Abstract: We provide a method for producing a rubber composition that includes a rubber component (A) including natural rubber, at least one filler (B) selected from an inorganic filler and carbon black, and a hydrazide compound (C), the method comprising compounding in an optional preliminary compounding stage and a plurality of compounding stages, and adding the hydrazide compound (C) and kneading in the preliminary compounding stage and/or a first compounding stage, the hydrazide compound (C) being represented by general formula (I): R—CONHNH2, where R represents an alkyl group having from 1 to 30 carbon atoms, a cycloalkyl group having from 3 to 30 carbon atoms, or an aryl group. We also provide a rubber composition produced with this method.Type: GrantFiled: March 24, 2014Date of Patent: June 6, 2017Assignee: BRIDGESTONE CORPORATIONInventors: Aya Saiki, Haruki Minojima
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Patent number: 9267075Abstract: The invention is directed to stable crosslinked water-soluble swellable polymers and methods for making same. More particularly, the invention relates to a composition comprising expandable polymeric particles having anionic sites and labile crosslinkers and stable crosslinkers, said particle mixed with a fluid and a cationic crosslinker that is capable of further crosslinking the particle on degradation of the labile crosslinker and exposure of the anionic sites so as to form a gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into target zone and when the heat and/or suitable pH of the target zone cause degradation of the labile crosslinker and the particle expands, the cationic crosslinker crosslinks the polymer to form a gel, thus diverting water to lower permeability regions and improving oil recovery.Type: GrantFiled: January 17, 2014Date of Patent: February 23, 2016Assignees: ConocoPhillips Company, University of KansasInventors: Ahmad Moradi-Araghi, James H. Hedges, David R. Zornes, Riley B. Needham, Huili Guan, Jenn-Tai Liang, Cory Berkland, James P. Johnson, Min Cheng, Faye Lynn Scully
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Publication number: 20150064425Abstract: An ink composition contains a pigment; a copolymer comprising a phosphoric acid group or phosphonic acid group; a hydrosoluble solvent; and water, wherein the pigment is represented by the following chemical formula 1 and satisfies the following relation 1: Y/X?0.20??Relation 1 where X represents a peak intensity at a Bragg (2?±0.2°) angle in a range of 2? of from 26.5° to 27.5° and Y represents a peak intensity at a Bragg (2?±0.2°) angle in a range of 2? of from 11.0° to 11.5° to a CuK? X-ray having a wavelength of 1.541 ?.Type: ApplicationFiled: August 11, 2014Publication date: March 5, 2015Inventors: Akihiko MATSUYAMA, Mitsuru Naruse, Masayasu Nonogaki, Kazukiyo Nagai, Keita Katoh, Yuusuke Koizuka
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Publication number: 20150031795Abstract: After step (I) of kneading a diene rubber and a carbon black to be mixed with each other, and then discharging the resultant mixture containing the diene rubber and the carbon black from an internal mixer, step (II) of kneading the mixture again in the internal mixer to crush a re-aggregate of the carbon black in the mixture, and step (III) of charging the dihydrazide compound into the internal mixer, and kneading the mixture and the dihydrazide compound to be mixed with each other are carried out. The period of step (II) for the kneading is 15 seconds or longer, and the rotating speed of the stirring rotor of the internal mixer is 35 rpm or more. The period of step (III) for the kneading is 40 seconds or longer, and the rotating speed of the stirring rotor of the internal mixer is from 15 to 25 rpm.Type: ApplicationFiled: March 14, 2014Publication date: January 29, 2015Applicant: TOYO TIRE & RUBBER CO., LTD.Inventor: Ikuo Ihara
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Patent number: 8846788Abstract: A polyacetal resin composition containing 100 parts by weight of a polyacetal resin, 0.01 to 5 parts by weight of a colorant selected from inorganic and organic pigments, 0.01 to 3 parts by weight of a polyamide resin having a melting point or softening point of 180° C. or less, or a polyetheresteramide resin, 0.01 to 1 part by weight of an aromatic dihydrazide compound or an aliphatic dihydrazide compound having a solubility of less than 1 g relative to 100 g of water at 20° C., and 0.01 to 1 part by weight of a sterically hindered phenolic compound, or a combination of a hindered amine-based light stabilizer and an ultraviolet absorber, exhibits an excellent thermal stability and is capable of suppressing formaldehyde generation and mechanical strength deterioration.Type: GrantFiled: September 3, 2009Date of Patent: September 30, 2014Assignee: Mitsubishi Engineering-Plastics CorporationInventors: Masayuki Nagai, Kunihiko Fujimoto
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Publication number: 20140242280Abstract: A method for applying a multilayer coating comprising a basecoat and a clearcoat is disclosed. The basecoat is a curable aqueous composition comprising (1) polymeric particles prepared from ethylenically unsaturated compounds including a multi-ethylenically unsaturated monomer and a keto or aldo-functional monomer, and (2) a polyhydrazide.Type: ApplicationFiled: February 28, 2013Publication date: August 28, 2014Applicant: PPG INDUSTRIES OHIO, INC.Inventors: Shanti Swarup, Xiangling Xu, Richard J. Sadvary, Anthony M. Chasser
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Patent number: 8815003Abstract: Crosslinking systems suitable for use in a polymer melt composition wherein the polymer melt composition comprises a hydroxyl polymer; polymeric structures made from such polymer melt compositions; and processes/methods related thereto are provided.Type: GrantFiled: November 20, 2013Date of Patent: August 26, 2014Assignee: The Procter & Gamble CompanyInventors: Stephen Wayne Heinzman, Linda Evers Smith, Gregory Charles Gordon, Larry Neil Mackey, John Gerhard Michael, Mark Ryan Richards
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Patent number: 8765850Abstract: Provided is a polyacetal resin composition obtained from a raw material composition containing a polyacetal resin, a hydrazine derivative, and a compound for lowering the melting point of the hydrazine derivative, wherein a mixture of the hydrazine derivative and the compound satisfies both of the following conditions: T1<T2 and T1<T3, in which T1 is an apex temperature of an endothermic peak of the mixture having a maximum endothermic capacity by, with DSC, heating and cooling the mixture in accordance with a predetermined temperature program and then heating it at a predetermined rate until the mixture fuses; and T2 and T3 represent apex temperatures of endothermic peaks of the hydrazine derivative and the polyacetal resin having a maximum endothermic capacity, respectively by the similar treatment.Type: GrantFiled: October 27, 2009Date of Patent: July 1, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Takashi Iwamoto, Yukiyoshi Sasaki, Mitsuhiro Horio, Syuuichi Kudou
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Publication number: 20130331494Abstract: A coating for application to the surface of an interior building product comprises: a resin formulation such as a melamine formaldehyde resin characterized by its ability to strengthen the interior building product when applied as a coating to the building product; and an aldehyde scavenger selected from the group consisting of; tetraethylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide and a combination of a polyvinyl alcohol and adipic dihydrazide.Type: ApplicationFiled: August 9, 2013Publication date: December 12, 2013Applicant: USG Interiors, LLCInventors: Runhai Lu, Terry L. Rosenstiel, Salvatore Immordino, Weixin D. Song
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Publication number: 20130289165Abstract: Reinforced rubber composition based at least (a) on an elastomeric matrix comprising natural rubber as the predominant diene elastomer, (b) on a reinforcing filler comprising carbon black in a weight fraction of more than 50% relative to the total weight of the filler, and (c) on a compound belonging to the families of hydrazides or hydrazones or to the family of amines, wherein the carbon black is dispersed in the elastomeric matrix with a Z value of greater than or equal to 80. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for a tyre of motor vehicles.Type: ApplicationFiled: December 19, 2011Publication date: October 31, 2013Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Stéphanie De Landtsheer, Damien Thomasson
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Publication number: 20130035416Abstract: A polyacetal resin composition and molded article having a high metallic gloss, small change in a color tone according to the viewing angle, high weld performance, and high mechanical properties can be provided in which the amount of formaldehyde to be produced in molding and recycle is suppressed, the mold deposit is improved, and the repeated impact resistance after aging is high. A polyacetal resin composition comprising: (A) 100 parts by mass of a polyacetal copolymer resin, and (B) 0.1 to 10 parts by mass of an aluminum pigment, the aluminum pigment having a coin-like or flake-like flat shape, a volume average particle size D50 of 15 to 50 ?m, an average surface roughness Ra of 20 to 50 nm, and an average height Rc of depressions and projections in a surface roughness curve of 80 to 200 nm.Type: ApplicationFiled: April 15, 2011Publication date: February 7, 2013Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Mitsuhiro Horio, Syuichi Kudou, Seizaburoh Asai
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Publication number: 20130023612Abstract: A coating for application to the surface of an interior building product comprises: a resin formulation such as a melamine formaldehyde resin characterized by its ability to strengthen the interior building product when applied as a coating to the building product; and an aldehyde scavenger selected from the group consisting of; tetraethylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide and a combination of a polyvinyl alcohol and adipic dihydrazide.Type: ApplicationFiled: June 7, 2012Publication date: January 24, 2013Applicant: USG INTERIORS, LLCInventors: Runhai Lu, Terry L. Rosenstiel, Salvatore Immordino, Weixin D. Song
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Publication number: 20120277359Abstract: Tire component which is not in contact with air or with an inflation gas, comprising a rubber composition based on (a) an elastomeric matrix based on natural rubber, (b) a reinforcing filler, (c) from more than 2.5 to 8.5 phr of sulphur and (d) a dihydrazide compound corresponding to the following formula: in which R is a divalent hydrocarbon radical chosen from substituted or unsubstituted aromatic radicals having 6 to 20 carbon atoms, linear or branched, saturated or unsaturated, aliphatic radicals having 2 to 20 carbon atoms, and n is equal to 0 or 1. These tire components are more particularly those which comprise thread-like reinforcing elements, more especially metallic thread-like reinforcing elements, such as the carcass or crown plies of the tire.Type: ApplicationFiled: December 22, 2009Publication date: November 1, 2012Applicants: Michelin Recherche et Technique S.A., Societe De Technologie MichelinInventors: Julien Thuilliez, Stephanie De Landtsheer, Brigitte Chauvin
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Publication number: 20120270966Abstract: Reinforced rubber composition based on at least (a) an elastomeric matrix predominantly based on natural rubber, (b) a reinforcing filler predominantly based on an inorganic filler, (c) a coupling agent and (d) a dihydrazide compound corresponding to the following formula I: in which R is a divalent hydrocarbon radical chosen from aromatic radicals having from 6 to 20 carbon atoms or saturated or unsaturated aliphatic radicals having from 2 to 20 carbon atoms and n has the value 0 or 1. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for the tires of motor vehicles.Type: ApplicationFiled: December 22, 2009Publication date: October 25, 2012Applicants: Michelin Recherche et Technique S.A., Societe De Technologie MichelinInventors: Julien Thuilliez, Stephanie De Landtsheer, Brigitte Chauvin
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Publication number: 20120178861Abstract: A polyolefin resin composition is excellent in processing cycle and mechanical characteristics and provides small deformation during molding, i.e., small deformation due to anisotropicity in shrinkage factors. Specifically, provided is a polyolefin resin composition obtained by incorporating 0.01 to 10 parts by mass of, preferably 0.05 to 5 parts by mass of (B) a compound represented by the following formula (I) with respect to 100 parts by mass of (A) a polyolefin resin, preferably a polypropylene. The polyolefin resin composition may also contain, if necessary, a phenolic, phosphorus, thioether or hydroxyamine antioxidant, an ultraviolet absorbent, a hindered amine light stabilizer, or other nucleator, or the like.Type: ApplicationFiled: October 7, 2010Publication date: July 12, 2012Applicant: ADEKA CORPORATIONInventors: Kazukiyo Nomura, Mitsuru Fukushima
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Publication number: 20120123035Abstract: The invention relates to a method for producing a body including: preparing a granular mixture including a) at least 90 wt % of mineral oxide grains; b) 0.3 to 3 wt % of resin polycondensed with formaldehyde and/or the derivatives thereof, the percentage being calculated in terms of dry resin extract; c) 0.001 to 1 wt % of a hardening agent, the percentage being calculated in terms of dry hardener extract; d) 0.005 to 0.35 wt % of a formaldehyde scavenger compound; and e) 0.2 to 3 wt % of water; contacting said granular mixture with a surface of a forming tool; and insufflating a gas flow at 50 to 380 degrees into the granular mixture for 1 to 300 seconds in order to at least partially cure said mixture, the formaldehyde scavenger being carbohydrazide.Type: ApplicationFiled: July 9, 2010Publication date: May 17, 2012Applicant: HUTTENES ALBERTUS FRANCEInventors: Stéphane Sarrazin, Manuel Vargas
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Publication number: 20110230602Abstract: A polyacetal resin composition containing 100 parts by weight of a polyacetal resin, 0.01 to 5 parts by weight of a colorant selected from inorganic and organic pigments, 0.01 to 3 parts by weight of a polyamide resin having a melting point or softening point of 180° C. or less, or a polyetheresteramide resin, 0.01 to 1 part by weight of an aromatic dihydrazide compound or an aliphatic dihydrazide compound having a solubility of less than 1 g relative to 100 g of water at 20° C., and 0.01 to 1 part by weight of a sterically hindered phenolic compound, or a combination of a hindered amine-based light stabilizer and an ultraviolet absorber, exhibits an excellent thermal stability and is capable of suppressing formaldehyde generation and mechanical strength deterioration.Type: ApplicationFiled: September 3, 2009Publication date: September 22, 2011Applicant: MITSUBISHI ENGINEERING-PLASTICS CORPORATIONInventors: Masayuki Nagai, Kunihiko Fujimoto
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Publication number: 20110218279Abstract: The present invention provides a polyolefin-based resin composition containing a crystal nucleating agent having a specific structure, which polyolefin-based resin composition has a superior transparency and whose crystallization is facilitated. The polyolefin-based resin composition is characterized by comprising, with respect to 100 parts by mass of a polyolefin-based resin, 0.Type: ApplicationFiled: August 21, 2009Publication date: September 8, 2011Inventors: Tsuyoshi Urushihara, Kazukiyo Nomura, Naoto Ueda, Yota Tsuneizumi
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Patent number: 7910643Abstract: A polylactic acid resin composition in which polylactic acid is blended with dibasic acid bis(benzoylhydrazide) represented by general formula (I) below; and a process for producing heat-resistant polylactic acid resin moldings, wherein after the polylactic acid resin composition is melted, the polylactic acid resin composition melted is filled in a die of a molding machine and molded accompanied with crystallization, in which the temperature of the die has been set in a range not higher than the initiation temperature of crystallization and not lower than the glass transition temperature determined with a differential scanning calorimeter (DSC).Type: GrantFiled: September 2, 2005Date of Patent: March 22, 2011Assignee: Adeka CorporationInventors: Etsuo Tobita, Naoshi Kawamoto, Tsuyoshi Urushihara, Hitoshi Saito, Hisashi Okuyama, Naomi Okuyama, legal representative, Takeshi Kanamori, Mitsuru Nakano, Hirotaka Okamoto
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Publication number: 20110015321Abstract: Provided is a polyacetal resin composition obtained from a raw material composition containing a polyacetal resin, a hydrazine derivative, and a compound for lowering the melting point of the hydrazine derivative, wherein a mixture of the hydrazine derivative and the compound satisfies both of the following conditions: T1<T2 and T1<T3, in which T1 is an apex temperature of an endothermic peak of the mixture having a maximum endothermic capacity by, with DSC, heating and cooling the mixture in accordance with a predetermined temperature program and then heating it at a predetermined rate until the mixture fuses; and T2 and T3 represent apex temperatures of endothermic peaks of the hydrazine derivative and the polyacetal resin having a maximum endothermic capacity, respectively by the similar treatment.Type: ApplicationFiled: October 27, 2009Publication date: January 20, 2011Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Takashi Iwamoto, Yukiyoshi Sasaki, Mitsuhiro Horio, Syuuichi Kudou
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Publication number: 20100273018Abstract: Aqueous coating composition comprising (1) at least one vinyl polymer having a Mw?15 k Da and a Tg?0° C. formed from (i) 0.1 to 20 wt % of vinyl monomer(s) containing acid functional groups and (ii) 0 to 0.49 wt % of vinyl monomer(s) containing a carbonyl functional group(s) and (2) 0.01 to 10 wt % of at least one polyhydrazine compound B where said composition provides a film coating of König hardness ?40 s.Type: ApplicationFiled: July 6, 2010Publication date: October 28, 2010Inventors: Jurgen SCHEERDER, Yvonne Wihelmina Smak, Gerardus Comelis Overbeek
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Patent number: 7816433Abstract: A polyacetal resin composition comprising (A) 100 parts by mass of polyacetal resin generating formaldehyde in an amount of not more than 100 ppm when heated at a temperature of 200° C. for 50 minutes under the nitrogen atmosphere and (B) 0.01 to 5 parts by mass of a hydrazide compound can provide an article which is remarkably reduced in an emission amount of formaldehyde even though molded either at a higher temperature or under molding conditions wherein the resin temperature rises partially. Therefore, the polyacetal resin composition can be molded according to various molding methods and under a wide range of molding conditions. The article molded from the resin composition has succeeded in reducing the emission amount of formaldehyde, measured according to VDA275 method, to not more than 1 mg/kg, the level never achieved before, and therefore is usable for various applications where a reduced VOC is required.Type: GrantFiled: October 21, 2004Date of Patent: October 19, 2010Assignee: Asahi Kasei Chemicals CorporationInventors: Sumio Komatsu, Yukiyoshi Sasaki
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Publication number: 20100174017Abstract: A polylactic acid resin composition in which polylactic acid is blended with dibasic acid bis(benzoylhydrazide) represented by general formula (I) below; and a process for producing heat-resistant polylactic acid resin moldings, wherein after the polylactic acid resin composition is melted, the polylactic acid resin composition melted is filled in a die of a molding machine and molded accompanied with crystallization, in which the temperature of the die has been set in a range not higher than the initiation temperature of crystallization and not lower than the glass transition temperature determined with a differential scanning calorimeter (DSC).Type: ApplicationFiled: September 2, 2005Publication date: July 8, 2010Applicant: ADEKA CORPORATIONInventors: Etsuo Tobita, Naoshi Kawamoto, Tsuyoshi Urushihara, Hitoshi Saito, Hisashi Okuyama, Naomi Okuyama, Takeshi Kanamori, Mitsuru Nakano, Hirotaka Okamoto
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Publication number: 20100120954Abstract: An olefine polymer composition comprises a stabilizing amount of a metal deactivator comprising a polymeric hydrazine derivative. The deactivator is of formula (I), in which at least one of R1 and R2 comprise a polymeric radical that includes a substituted or unsubstituted aromatic radical. The olefin polymers include polyethylene and polypropylene.Type: ApplicationFiled: March 17, 2008Publication date: May 13, 2010Inventors: Pascal E.R.E.J. Lakeman, Thoi H. Ho, Ronald Wevers
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Patent number: 7691929Abstract: The present invention is directed a method of flame retarding a polymeric substrate using a specific group of azo and peroxide derivatives as flame retardants, to flame retardant compositions as well as to novel azo compounds usable as flame retarding compounds.Type: GrantFiled: January 9, 2009Date of Patent: April 6, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Nicolas Ronan, Carl-Eric Magnus Wilën
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Publication number: 20090005474Abstract: A pigment dispersion includes a color pigment represented by formula (I): wherein R1 to R10 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH, —COOCH3, —SO2NH—C6H5, —CONH—C6H5, —CONH—C6H5—CONH2, and —CONH2; and a polymeric dispersant, having via a linking group covalently linked to its polymeric backbone, at least one pending chromophore group which has a molecular weight smaller than 95% of the molecular weight of said color pigment. The pigment dispersion can be advantageously used in inkjet inks.Type: ApplicationFiled: June 23, 2006Publication date: January 1, 2009Applicant: AGFA GRAPHICS NVInventors: Wojciech Jaunky, Geert Deroover, Johan Loccufier, Lambertus Groenendaal
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Patent number: 7005004Abstract: Aqueous, colloidal gas black suspension, containing a gas black, an azo compound of formula 1, and water. The aqueous, colloidal gas black suspensions is produced in that the gas black and the azo compound of general formula 1 are dispersed in water. It may be used to produce inks, ink jet inks, paints, printing inks, latices, textiles, leather, adhesives, silicones, plastics materials, concrete and construction materials.Type: GrantFiled: March 30, 2004Date of Patent: February 28, 2006Assignee: Degussa AGInventors: Werner Kalbitz, Gerd Tauber, Heinz Zoch, Stephan Lüdtke, Thomas Lüthge, Ralph Mcintosh
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Publication number: 20020103278Abstract: A waterborne coating composition for a cured film having improved film properties and uniform film formation comprising a binder polymer containing a reactive keto group, at least one carboxylic monohydrazide or dihydrazide or polyhydrazide compound, and a reaction moderator. More specifically, the waterborne coating composition comprises (a) at least one binder polymer comprising at least one or more copolymerizable monoethylenically unsaturated monomers, wherein at least one of the monoethylenically unsaturated monomers contains at least one reactive keto group; and (b) at least one monohydrazide or dihydrazide or polyhydrazide compound; and (c) at least one reaction moderator. Reaction moderators moderate or retard the crosslinking process before film formation occurs and then act to catalyze the film formation crosslinking reaction. The final cured film product of the waterborne coatings produced by this invention have a much higher crosslink density per unit time and a uniform film formation.Type: ApplicationFiled: September 14, 2001Publication date: August 1, 2002Inventors: John M. Krajnik, Victor H. Lam, Lynn O. Sabo, James M. Camerson, Martin L. Mittleman, Kuyler M. Wise
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Patent number: 6046252Abstract: A binder composition of a phenolic novolac resin and a (lower) alkoxylated triazine-formaldehyde resin curing agent is disclosed. The triazine resins have sufficient carbon atoms in the alkoxy groups so as to provide a curing agent having a water solubility of less than 15%. The binder cures at high temperatures so as to provide improved flow and prolonged workability to the composition. The compositions are useful in refractory applications having a need for high temperature curing agents such as for maintenance and repair within refractory vessels by gunning/spraying, manufacture of electrodes by the Soderberg method, and for use in blast furnace tap holes.Type: GrantFiled: February 25, 1997Date of Patent: April 4, 2000Assignee: Borden Chemical, Inc.Inventor: Arthur H. Gerber
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Patent number: 5973042Abstract: There is provided a highly water-absorptive polymer composition comprising:(A) 100 parts by weight of a highly water-absorptive polymer having a crosslinked structure, comprising as its constituent a carboxyl group and/or a carboxylate group; and(B) 0.05 to 10 parts by weight of an additive selected from the group consisting of an oxalic acid (salt) compound, a sulfate of a metal selected from titanium, zirconium and vanadium, and a crystalline or noncrystalline, high-purity particulate titania having a mean particle diameter of 1 .mu.m or less, a specific surface area of 10 m.sup.2 /g or more as determined by the Brunauer-Emmett-Teller method, and, when crystalline, a crystal structure of a mixed type of rutile and anatase.Type: GrantFiled: June 11, 1996Date of Patent: October 26, 1999Assignee: Mitsubishi Chemical CorporationInventors: Kenji Yoshinaga, Shozo Kitagawa, Toshiko Nakamura, Miho Tanaka, Kiichi Ito
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Patent number: 5846451Abstract: A crosslinking type liquid crystal polymer, an oriented crosslinking film thereof, and a method of producing the oriented crosslinking film are disclosed. The crosslinking type liquid crystal polymer comprises a liquid crystal polymer containing a polyfunctional azide compound represented by the following formula (A);R.sup.1 --(N.sub.3).sub.n (A)wherein R.sup.1 represents an organic group and n represents an integer of from 1 to 5.Type: GrantFiled: November 26, 1996Date of Patent: December 8, 1998Assignee: Nitto Denko CorporationInventors: Shusaku Nakano, Amane Mochizuki, Hironori Motomura, Kyoko Izumi
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Patent number: 5705549Abstract: A rubber composition comprises a particular copolymer containing isobutylene unit, a paramethylstyrene unit and a parabromomethylstyrene unit; natural rubber and/or diene synthetic rubber; carbon black; and at least one hydrazide compound, and has a low value of tan .delta. at 60.degree. C. with maintaining tan .delta. at 0.degree. C. at a high level.Type: GrantFiled: April 15, 1996Date of Patent: January 6, 1998Assignee: Bridgestone CorporationInventor: Masahiro Hojo
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Patent number: 5648404Abstract: A binder composition of a phenolic novolac resin and a (lower) alkoxylated triazine-formaldehyde resin curing agent is disclosed. The triazine resins have sufficient carbon atoms in the alkoxy groups so as to provide a curing agent having a water solubility of less than 15%. The binder cures at high temperatures so as to provide improved flow and prolonged workability to the composition. The compositions are useful in refractory applications having a need for high temperature curing agents such as for maintenance and repair within refractory vessels by gunning/spraying, manufacture of electrodes by the Soderberg method, and for use in blast furnace tap holes.Type: GrantFiled: April 11, 1994Date of Patent: July 15, 1997Assignee: Borden Inc.Inventor: Arthur Harry Gerber
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Patent number: 5539015Abstract: A synthetic resin composition comprises an aqueous medium, a surfactant, and a resin and filler dispersed in the aqueous medium by the surfactant. The surfactant comprises a first high molecular weight compound having a weight-average molecular weight of at least 10000 and a second high molecular weight compound having a weight-average molecular weight of not less than 150 and less than 10000. In the synthetic resin composition, a solid material is well dispersed and the viscosity doesn't remarkably increase even if a solid content is increased. So, the increased amount of a non-volatile matter may be used and the storage stability improves. Further, flame retardation, deodorization, heat resistance and light fastness also improve. In addition, an interior material coated with the synthetic resin composition is provided.Type: GrantFiled: May 27, 1994Date of Patent: July 23, 1996Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha, Toyoda Boshoku Corporation, Dainippon Ink and Chemicals, IncorporatedInventors: Mitsumasa Horii, Masahiro Sugiura, Seiji Onoda, Yoshio Yamada, Osamu Araki, Yoshiro Umemoto, Kazuo Ito, Takatoshi Sekihara, Akihiro Matsuyama, Masaaki Izumichi, Kiyoshi Umehara, Reizaburo Tomioka
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Patent number: 5534569Abstract: Heat generation of a rubber composition can be lowered by incorporating to the composition a compound of the formula, (I), (II) or (III), ##STR1## where A is an aromatic group, hydantoin ring or C.sub.0-18 straight chain hydrocarbon group, B is an aromatic group, X is hydroxy or amino, Y is pyridyl or hydrozino.Type: GrantFiled: March 8, 1995Date of Patent: July 9, 1996Assignee: Bridgestone CorporationInventor: Akiko Etoh
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Patent number: 5492952Abstract: Provided is an ink comprising a compound having at least one carbonyl group and a hydrazide compound selected from the group consisting of a styrene-maleic acid resin having at least two hydrazide groups, a polyacrylic acid having at least two hydrazide groups and a compound represented by the formula ##STR1## wherein R represents (CH.sub.2).sub.n or C.sub.6 H.sub.Type: GrantFiled: March 15, 1994Date of Patent: February 20, 1996Assignee: Canon Kabushiki KaishaInventors: Masahiko Tonogaki, Yuko Suga, Akio Kashiwazaki, Aya Takaide
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Patent number: 5155151Abstract: A thermoplastic resin composition having improved heat stability which comprises a thermoplastic resin which contains at least 5% by weight of an .alpha.-alkyl-substituted aromatic copolymer comprising .alpha.-alkyl-substituted aromatic vinyl compound and at least one other comonomer copolymerizable therewith, wherein the composition contains a metal-deactivating agent which has a molecular weight of not more than 2,000 and at least one group of the formula: ##STR1## or an organometallic colorant containing free metal in an amount of not more than 2,000 ppm, from which a molded article having no or less silver streaks can be produced.Type: GrantFiled: February 21, 1992Date of Patent: October 13, 1992Assignee: Sumitomo Naugatuck Co., Ltd.Inventors: Kenji Hashimoto, Syuzi Takahashi, Hiroyuki Minematsu
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Patent number: 5153069Abstract: A dispersing agent for dispersing solid particles in an organic liquid having the composition ##STR1## wherein ##STR2## is the residue of a polyester chain having a molecular weight of at least 1700, derived from a hydroxycarboxylic acid containing 16-22 carbon atoms, ##STR3## is the residue of a mono or polyamide having up to 12 amido bonds, which is amino terminated in both ends and wherein R.sub.1 and R.sub.2 are each independently hydrogen or alkyl or alkenyl containing up to 20 carbon atoms;Z is a salt of a carboxylic acid containing 8-18 carbon atoms and a diamine NHR.sub.3 --T--NH.sub.2 wherein T is alkylene or alkenylene containing 2-12 carbon atoms and optionally comprising one or more oxygen or nitrogen bridges and R.sub.3 is hydrogen or alkyl or alkenyl containing up to 20 carbon atoms;Q is a carboxylic acid containing 8-18 carbon atoms or a diamine NHR.sub.3 --T--NH.sub.2, wherein T and R.sub.3 are defined as above.Said dispersing agent can be used for preparing an easily dispersable pigment.Type: GrantFiled: March 5, 1991Date of Patent: October 6, 1992Assignee: Giuseppe CanestriInventor: Giuseppe Canestri
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Patent number: 4973618Abstract: Oligormeric polyether/urethanes with semicarbazide end-groups protect spandex fibers from discoloration in atmospheric fumes and/or light. The oligomers are prepared from polyether glycols, diisocyanates and N,N-dialkylhydrazine.Type: GrantFiled: September 29, 1989Date of Patent: November 27, 1990Assignee: E. I. Du Pont de Nemours & CompanyInventor: Arnoldus J. Ultee
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Patent number: 4855344Abstract: An aqueous printing ink or its semiaqueous or substantially nonaqueous concentrates exemplified as comprising a substantially homogeneous system of the components:(1) from about 4 to about 90 weight % of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from none to about 70 weight % of pigment material;(3) from about 0.01 to about 90 weight % of water; and(4) one or more acetylacetonates of the formula M[CH--(COCH.sub.3).sub.2 ].sub.n wherein M is Al, Zr, Ni, Ca, V, or Fe, and n is the chemical valence of M, the weight ratio of polyester to total acetylacetonates being from about 10,000/1 to about 10/1.Type: GrantFiled: May 16, 1988Date of Patent: August 8, 1989Assignee: Eastman Kodak CompanyInventors: David L. Nealy, Louis A. Wilkin, Fred D. Barlow, Jr.
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Patent number: 4839408Abstract: The invention relates to a stabilized polyolefin composition, which composition is stabilized against deterioration caused by contact with heavy metals and improved in coloration properties. This is achieved by blending a polyolefin with:(A) a phenolic compound represented by the formula (I), ##STR1## wherein R.sub.1 represents a C.sub.1 -C.sub.3 alkyl group, (B) a metal deactivator having one or more ##STR2## groups in the side chain, and (C) a sulfur-containing compound represented by the formula (II-1), (II-2), (II-3) or (II-4): ##STR3## wherein R.sub.2 represents a C.sub.4 -C.sub.20 alkyl group, ##STR4## wherein R.sub.3 represents a C.sub.4 -C.sub.20 alkyl group, ##STR5## wherein R.sub.4 represents a C.sub.3 -C.sub.18 alkyl group, and R.sub.5 and R.sub.6 independently represent a hydrogen atom or a C.sub.1 -C.sub.6 alkyl group, ##STR6## wherein R.sub.7 represents a C.sub.3 -C.sub.18 alkyl group.Type: GrantFiled: August 15, 1988Date of Patent: June 13, 1989Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshiharu Fukui, Kazuhisa Kuroda, Tamaki Ishii, Manji Sasaki
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Patent number: 4826903Abstract: Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate (a) containing a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound or (b) having reacted therewith or copolymerized therein a styryl residue derived from a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound, having the formula ##STR1## wherein R.sup.4 and R.sup.5 represent the acyl radical and the other radicals are as defined in the specification.Preferred compositions comprise a linear polyester containing a styryl residue as an integral part of the polymer chain. The styryl residues absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.Type: GrantFiled: February 22, 1988Date of Patent: May 2, 1989Assignee: Eastman Kodak CompanyInventors: Max A. Weaver, Samuel D. Hilbert, Wayne P. Pruett, Clarence A. Coates, Jr.
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Patent number: 4769410Abstract: Crosslinkable polymeric compositions which are dissolved or dispersed in an organic solvent, a process for their preparation and their use.These polymeric compositions which undergo crosslinking at room temperature or elevated temperatures after drying are obtained by reacting polymeric organic compounds containing carbonyl groups with polyhydrazides in the presence of monoketones or monoaldehydes.They are useful as crosslinking agents for polyepoxide compounds.Type: GrantFiled: October 10, 1986Date of Patent: September 6, 1988Assignee: BASF AktiengesellschaftInventors: Rainer Blum, Gerd Rehmer, Rolf Osterloh, Wolfgang Druschke, Hans Sander
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Patent number: 4666966Abstract: A polyurethane composition comprising an effective amount of a stabilizer compound represented by the general formula ##STR1## wherein, X is a residue represented the formula ##STR2## and at least three of Y.sub.1, Y.sub.2, Y.sub.3, and Y.sub.4 are residues represented by the general formula ##STR3## wherein R.sub.1 and R.sub.2 are each an alkyl or aralkyl group with the proviso that at least one of R.sub.1 and R.sub.2 is attached through its primary carbon to the nitrogen atom and the total number of carbon atoms of R.sub.1 and R.sub.2 is at least 4, the other one of Y.sub.1, Y.sub.2, Y.sub.3, and Y.sub.4, if present, is a glycidyl derivative residue, and Z is a residue represented by the general formula ##STR4## wherein R.sub.3 and R.sub.Type: GrantFiled: March 12, 1986Date of Patent: May 19, 1987Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Yoshihisa Fujimoto, Seizi Gotou, Yoshiharu Fujita
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Patent number: 4618637Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether which have been stabilized with oxalyldihydrazide against oxidative degradation.Type: GrantFiled: December 16, 1985Date of Patent: October 21, 1986Assignee: General Electric CompanyInventors: Johannes H. G. M. Lohmeijer, Jacobus W. M. Noordermeer, Jan Bussink
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Patent number: 4447571Abstract: A process for providing water based anionic polyurethanes having improved thermal oxidation color stability. Water dispersed amine salts of anionic prepolymers prepared from the reaction of polyhydroxy compounds and dihydroxy carboxylic acids with diisocyanates are chain-extended with hydrazine or hydrazide and thereafter optionally with a diamine, when cured at temperatures in excess of 150.degree. C., form polyurethane products having substantially no discoloration and good mechanical properties. Alternately, the hydrazide may be employed as an additive rather than as a chain-extender. The process is particularly useful when employing cross-linking agents which react only at high temperatures.Type: GrantFiled: October 15, 1981Date of Patent: May 8, 1984Assignee: Witco Chemical CorporationInventors: Shmuel Dabi, Peter Loewrigkeit