Aryl-oh Patents (Class 524/193)
  • Publication number: 20120292078
    Abstract: A halogen-free flame-retardant resin composition includes a polyolefin-based resin, a phenolic antioxidant, a metal hydroxide, a pigment comprising one of titanium dioxide, monoazo yellow, benzimidazolone yellow, isoindolinone yellow, quinacridone red and perylene red, and an additive including an amide bond. The additive having the amide bond is added in an amount of 0.01 to 2 parts by weight relative to 100 parts by weight of the polyolefin-based resin.
    Type: Application
    Filed: May 18, 2012
    Publication date: November 22, 2012
    Applicant: HITACHI CABLE, LTD.
    Inventors: Tamotsu KIBE, Ryutaro KIKUCHI
  • Patent number: 8022117
    Abstract: A non-aqueous pigment dispersion includes a color pigment, a polymeric dispersant, and a dispersion synergist wherein the molecular weight of the anionic part of the dispersion synergist containing at least one carboxylate anion is smaller than 98% of the molecular weight of the color pigment and that the anionic part of the dispersion synergist has a similarity coefficient SIM of at least 0.5 with the similarity coefficient defined by: SIM = t · C S + P - C wherein, S represents the number of atoms in the anionic part of the dispersion synergist; P represents the number of atoms in the color pigment; C represents the largest number of atoms in common between the anionic part of the dispersion synergist and the color pigment as one continuous structure; and t is an integer representing the number of times that the largest number of atoms in common C fits into the organic color pigment, without using atoms of the color pigment twice.
    Type: Grant
    Filed: November 28, 2006
    Date of Patent: September 20, 2011
    Assignee: Agfa Graphics NV
    Inventors: Geert Deroover, Nicolas Point
  • Patent number: 7846992
    Abstract: A pigment dispersion includes a color pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group. The at least one pending chromophore group has a molecular weight which is smaller than 85% of the molecular weight of the color pigment; the at least one pending chromophore group occurs as a side group on the polymeric backbone and not as a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; and the at least one pending chromophore group has a similarity coefficient SIM of at least 0.75.
    Type: Grant
    Filed: June 23, 2006
    Date of Patent: December 7, 2010
    Assignee: Agfa Graphics NV
    Inventors: Geert Deroover, Johan Loccufier, Lambertus Groenendaal, Wojciech Jaunky
  • Patent number: 7691929
    Abstract: The present invention is directed a method of flame retarding a polymeric substrate using a specific group of azo and peroxide derivatives as flame retardants, to flame retardant compositions as well as to novel azo compounds usable as flame retarding compounds.
    Type: Grant
    Filed: January 9, 2009
    Date of Patent: April 6, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Nicolas Ronan, Carl-Eric Magnus Wilën
  • Patent number: 6409937
    Abstract: The invention relates to a process for the preparation of melt processable liquid crystalline terpolyesters of the general formula I by the in situ acetylation of a monomer selected from (4-hydroxyphenyl) acetic acid/ 3(4-hydroxyphenyl)propionic acid and hydroquinone/4,4′-biphenol/2,6-naphthylene diol followed by acidolysis polycondensation with or without a solvent and a catalyst, under reduced pressure for the efficient removal of acetic acid to effect higher molecular weight formation. Post polymerisation is effected at higher temperatures below the decomposition temperature purification by soxhlet extraction using solvent mixtures selected from acetone-alcohol, acetone-methylethyl ketone.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: June 25, 2002
    Assignees: Council of Scientific & Industrial Research, Department of Science and Technology
    Inventors: Vadakkethonippurathu Sivankutty Nair Prasad, Chennakkattu Krishna Sadasivan Pillai, Marayil Ravindranathan
  • Patent number: 6187846
    Abstract: An additive composition is provided that comprises: (a) tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate; (b) bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite; and (c) a costabilizer selected from the group consisting of sodium stearoyl lactylate, calcium stearoyl lactylate, calcium lactate, and mixtures thereof. Additionally, polymer compositions are provided that comprise the additive composition and (a) 2-Naphthalenecarboxamide, N,N′-(2-chloro-1,4 phenylene)bis[4-[(2,5-dichlorophenyl)azo]-3-hydroxy- and (b) a stereoregular, branched-mono-1-olefin polymer.
    Type: Grant
    Filed: October 26, 1993
    Date of Patent: February 13, 2001
    Assignee: Phillips Petroleum Company
    Inventor: John P. Walters
  • Patent number: 5705549
    Abstract: A rubber composition comprises a particular copolymer containing isobutylene unit, a paramethylstyrene unit and a parabromomethylstyrene unit; natural rubber and/or diene synthetic rubber; carbon black; and at least one hydrazide compound, and has a low value of tan .delta. at 60.degree. C. with maintaining tan .delta. at 0.degree. C. at a high level.
    Type: Grant
    Filed: April 15, 1996
    Date of Patent: January 6, 1998
    Assignee: Bridgestone Corporation
    Inventor: Masahiro Hojo
  • Patent number: 5604276
    Abstract: A recording liquid comprises at least one of certain specified dyes carbon black, a water-soluble resin, a water-soluble organic solvent and water. The organic solvent includes polyhydric alcohol and/or its alkyl ether and an aliphatic monohydric alcohol. The water-soluble resin has an acid value of 50 to 300. The amount of the dissolved water-soluble resin is not more than 2% by weight. A method for ink jet recording comprises ejecting the recording liquid as liquid droplets from fine orifices by endowing the recording liquid with heat energy.
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: February 18, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventor: Yuko Suga
  • Patent number: 5534569
    Abstract: Heat generation of a rubber composition can be lowered by incorporating to the composition a compound of the formula, (I), (II) or (III), ##STR1## where A is an aromatic group, hydantoin ring or C.sub.0-18 straight chain hydrocarbon group, B is an aromatic group, X is hydroxy or amino, Y is pyridyl or hydrozino.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: July 9, 1996
    Assignee: Bridgestone Corporation
    Inventor: Akiko Etoh
  • Patent number: 5155151
    Abstract: A thermoplastic resin composition having improved heat stability which comprises a thermoplastic resin which contains at least 5% by weight of an .alpha.-alkyl-substituted aromatic copolymer comprising .alpha.-alkyl-substituted aromatic vinyl compound and at least one other comonomer copolymerizable therewith, wherein the composition contains a metal-deactivating agent which has a molecular weight of not more than 2,000 and at least one group of the formula: ##STR1## or an organometallic colorant containing free metal in an amount of not more than 2,000 ppm, from which a molded article having no or less silver streaks can be produced.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: October 13, 1992
    Assignee: Sumitomo Naugatuck Co., Ltd.
    Inventors: Kenji Hashimoto, Syuzi Takahashi, Hiroyuki Minematsu
  • Patent number: 4874803
    Abstract: The present invention comprises reaction products resulting from the reaction of hydrazido-substituted or certain amino-substituted polymer stabilizers and cyclic dianhydrides, as well as the use of such products. The polymer stabilizers of the invention are useful for protecting a large variety of synthetic polymeric organic materials from the degradative effects of heat, light and oxygen. Some of the modifiers are flame retardants and many are metal deactivators in addition to their primary activity.
    Type: Grant
    Filed: September 21, 1987
    Date of Patent: October 17, 1989
    Assignee: Pennwalt Corporation
    Inventors: Arthur L. Baron, Terry N. Myers, Jerome Wicher
  • Patent number: 4845146
    Abstract: A flame-retardant olefin polymer composition containing 100 parts by weight of a resin component, said resin component consisting essentially of the following (a) and (b):(a) 60-99% by weight of a copolymer of ethylene and a carboxyl-containing monomer or a derivative thereof and(b) 1-40% by weight of an olefin polymer modified with an unsaturated carboxylic acid or a derivative thereof; and(c) 20-200 parts by weight of an inorganic flame retardant.
    Type: Grant
    Filed: April 8, 1988
    Date of Patent: July 4, 1989
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Takashi Inoue, Masazi Sunada, Motohide Okamoto, Masayoshi Kariya, Tadashi Inoh
  • Patent number: 4839408
    Abstract: The invention relates to a stabilized polyolefin composition, which composition is stabilized against deterioration caused by contact with heavy metals and improved in coloration properties. This is achieved by blending a polyolefin with:(A) a phenolic compound represented by the formula (I), ##STR1## wherein R.sub.1 represents a C.sub.1 -C.sub.3 alkyl group, (B) a metal deactivator having one or more ##STR2## groups in the side chain, and (C) a sulfur-containing compound represented by the formula (II-1), (II-2), (II-3) or (II-4): ##STR3## wherein R.sub.2 represents a C.sub.4 -C.sub.20 alkyl group, ##STR4## wherein R.sub.3 represents a C.sub.4 -C.sub.20 alkyl group, ##STR5## wherein R.sub.4 represents a C.sub.3 -C.sub.18 alkyl group, and R.sub.5 and R.sub.6 independently represent a hydrogen atom or a C.sub.1 -C.sub.6 alkyl group, ##STR6## wherein R.sub.7 represents a C.sub.3 -C.sub.18 alkyl group.
    Type: Grant
    Filed: August 15, 1988
    Date of Patent: June 13, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshiharu Fukui, Kazuhisa Kuroda, Tamaki Ishii, Manji Sasaki
  • Patent number: 4618637
    Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether which have been stabilized with oxalyldihydrazide against oxidative degradation.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: October 21, 1986
    Assignee: General Electric Company
    Inventors: Johannes H. G. M. Lohmeijer, Jacobus W. M. Noordermeer, Jan Bussink
  • Patent number: 4536527
    Abstract: There is provided an improved molding resin capable of being molded into an article exhibiting reduced tendency to corrode a copper surface when the molded resin and the copper surface are placed in spaced relationship in a common unventilated atmosphere at elevated temperatures, as measured by the Bell Telephone Laboratories Copper Corrosion Test at temperatures within the range of from 150.degree. to 175.degree. C., wherein the molding resin comprises the combination of (a) a butyleneterephthalate polyester comprising a brominated copolyester as a polymeric flame retardant comprising aromatic halogen groups in a flame retardant amount, and (b) an alkylhydroxyphenylalkanoyl-hydrazine in an amount that is within the range of from 0.05 to 0.3% by weight.
    Type: Grant
    Filed: May 7, 1984
    Date of Patent: August 20, 1985
    Assignee: Celanese Corporation
    Inventors: Wilfred L. Shearer, Stephen M. Sinker, Richard A. Wolf
  • Patent number: 4469834
    Abstract: There is provided an improved molding resin capable of being molded into an article exhibiting reduced tendency to corrode a copper surface when the molded resin and the copper surface are placed in spaced relationship in a common unventilated atmosphere at elevated temperatures, as measured by the Bell Telephone Laboratories Copper Corrosion Test at temperatures within the range of from 150.degree. to 175.degree. C., wherein the molding resin comprises the combination of (a) a poly(butylene terephthalate) based polymer and aromatic halogen groups in a flame retardant amount, and (b) an alkylhydroxyphenylalkanoyl-hydrazine in an amount that is within the range of from 0.05 to 0.6% by weight, based on the weight of the molding resin, and less than 0.8% by weight based on the polymer.
    Type: Grant
    Filed: May 11, 1983
    Date of Patent: September 4, 1984
    Assignee: Celanese Corporation
    Inventors: Wilfred L. Shearer, Stephen M. Sinker, Richard A. Wolf
  • Patent number: 4447571
    Abstract: A process for providing water based anionic polyurethanes having improved thermal oxidation color stability. Water dispersed amine salts of anionic prepolymers prepared from the reaction of polyhydroxy compounds and dihydroxy carboxylic acids with diisocyanates are chain-extended with hydrazine or hydrazide and thereafter optionally with a diamine, when cured at temperatures in excess of 150.degree. C., form polyurethane products having substantially no discoloration and good mechanical properties. Alternately, the hydrazide may be employed as an additive rather than as a chain-extender. The process is particularly useful when employing cross-linking agents which react only at high temperatures.
    Type: Grant
    Filed: October 15, 1981
    Date of Patent: May 8, 1984
    Assignee: Witco Chemical Corporation
    Inventors: Shmuel Dabi, Peter Loewrigkeit
  • Patent number: 4446266
    Abstract: The invention relates to the use of N,N'-bis-salicyloyl hydrazine as a metal deactivator for organic materials which are in contact with copper or contain copper or copper ions, and has the object of providing an N,N'-bis-salicyloyl hydrazine which allows processing without danger on an industrial scale. For this purpose, the invention provides an N,N'-bis-salicyloyl hydrazine which is prepared from salicylic-acid alkyl ester and either hydrazine or salicylic-acid hydrazide. N,N'-bis-salicyloyl hydrazine prepared in this manner serves particularly as a metal deactivator in cable and wire insulation for power and communications engineering.
    Type: Grant
    Filed: July 29, 1980
    Date of Patent: May 1, 1984
    Assignee: Siemens Aktiengesellschaft
    Inventors: Wolfgang von Gentzkow, Roland Rubner
  • Patent number: 4418170
    Abstract: A method for stabilizing organic polymers against copper-catalyzed oxidative decomposition by means of N,N-bis-salicyloyl hydrazine as a metal deactivator is described wherein dust development of the metal deactivator is precluded with certainty and negative property changes of the stabilized organic polymers are avoided. For this purpose, it is provided that a paste which contains finely-crystalline N,N'-bis-salicyloyl hydrazine in fine distribution in a liquid to wax-like aliphatic hydrocarbon of low volatility is worked into the polymer. The method is particularly well suited for stabilizing polyolefins for cable and wire insulation.
    Type: Grant
    Filed: July 19, 1982
    Date of Patent: November 29, 1983
    Assignee: Siemens Aktiengesellschaft
    Inventors: Wolfgang von Gentzkow, Manfred Schmiedel