Aryl-oh Patents (Class 524/193)
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Patent number: 12030965Abstract: Provided are a modified conjugated diene-based polymer comprising a conjugated diene-based monomer-derived repeating unit; and a chain extender-derived part which is linked to both terminals of the conjugated diene based monomer-derived repeating unit, respectively, includes one or more urethane groups in a molecular chain, and has different functional groups at both terminals, wherein one of the functional groups is an alkyne group, wherein a terminal of the chain extender-derived part which is not linked to both terminals of the conjugated diene based monomer-derived repeating unit is an alkyne group, a manufacturing method thereof, a binder composition for a solid propellant comprising the same, a modified conjugated diene based binder for a solid propellant, and a manufacturing method thereof.Type: GrantFiled: June 24, 2022Date of Patent: July 9, 2024Assignee: AGENCY FOR DEFENSE DEVELOPMENTInventors: Byoung Sun Min, Jin Hyuk Lee, Hong Min Shim, Sungjune Kim, Minhye Lee
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Publication number: 20120292078Abstract: A halogen-free flame-retardant resin composition includes a polyolefin-based resin, a phenolic antioxidant, a metal hydroxide, a pigment comprising one of titanium dioxide, monoazo yellow, benzimidazolone yellow, isoindolinone yellow, quinacridone red and perylene red, and an additive including an amide bond. The additive having the amide bond is added in an amount of 0.01 to 2 parts by weight relative to 100 parts by weight of the polyolefin-based resin.Type: ApplicationFiled: May 18, 2012Publication date: November 22, 2012Applicant: HITACHI CABLE, LTD.Inventors: Tamotsu KIBE, Ryutaro KIKUCHI
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Patent number: 8022117Abstract: A non-aqueous pigment dispersion includes a color pigment, a polymeric dispersant, and a dispersion synergist wherein the molecular weight of the anionic part of the dispersion synergist containing at least one carboxylate anion is smaller than 98% of the molecular weight of the color pigment and that the anionic part of the dispersion synergist has a similarity coefficient SIM of at least 0.5 with the similarity coefficient defined by: SIM = t · C S + P - C wherein, S represents the number of atoms in the anionic part of the dispersion synergist; P represents the number of atoms in the color pigment; C represents the largest number of atoms in common between the anionic part of the dispersion synergist and the color pigment as one continuous structure; and t is an integer representing the number of times that the largest number of atoms in common C fits into the organic color pigment, without using atoms of the color pigment twice.Type: GrantFiled: November 28, 2006Date of Patent: September 20, 2011Assignee: Agfa Graphics NVInventors: Geert Deroover, Nicolas Point
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Patent number: 7846992Abstract: A pigment dispersion includes a color pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group. The at least one pending chromophore group has a molecular weight which is smaller than 85% of the molecular weight of the color pigment; the at least one pending chromophore group occurs as a side group on the polymeric backbone and not as a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; and the at least one pending chromophore group has a similarity coefficient SIM of at least 0.75.Type: GrantFiled: June 23, 2006Date of Patent: December 7, 2010Assignee: Agfa Graphics NVInventors: Geert Deroover, Johan Loccufier, Lambertus Groenendaal, Wojciech Jaunky
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Patent number: 7691929Abstract: The present invention is directed a method of flame retarding a polymeric substrate using a specific group of azo and peroxide derivatives as flame retardants, to flame retardant compositions as well as to novel azo compounds usable as flame retarding compounds.Type: GrantFiled: January 9, 2009Date of Patent: April 6, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Nicolas Ronan, Carl-Eric Magnus Wilën
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Patent number: 6409937Abstract: The invention relates to a process for the preparation of melt processable liquid crystalline terpolyesters of the general formula I by the in situ acetylation of a monomer selected from (4-hydroxyphenyl) acetic acid/ 3(4-hydroxyphenyl)propionic acid and hydroquinone/4,4′-biphenol/2,6-naphthylene diol followed by acidolysis polycondensation with or without a solvent and a catalyst, under reduced pressure for the efficient removal of acetic acid to effect higher molecular weight formation. Post polymerisation is effected at higher temperatures below the decomposition temperature purification by soxhlet extraction using solvent mixtures selected from acetone-alcohol, acetone-methylethyl ketone.Type: GrantFiled: March 28, 2000Date of Patent: June 25, 2002Assignees: Council of Scientific & Industrial Research, Department of Science and TechnologyInventors: Vadakkethonippurathu Sivankutty Nair Prasad, Chennakkattu Krishna Sadasivan Pillai, Marayil Ravindranathan
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Patent number: 6187846Abstract: An additive composition is provided that comprises: (a) tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate; (b) bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite; and (c) a costabilizer selected from the group consisting of sodium stearoyl lactylate, calcium stearoyl lactylate, calcium lactate, and mixtures thereof. Additionally, polymer compositions are provided that comprise the additive composition and (a) 2-Naphthalenecarboxamide, N,N′-(2-chloro-1,4 phenylene)bis[4-[(2,5-dichlorophenyl)azo]-3-hydroxy- and (b) a stereoregular, branched-mono-1-olefin polymer.Type: GrantFiled: October 26, 1993Date of Patent: February 13, 2001Assignee: Phillips Petroleum CompanyInventor: John P. Walters
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Patent number: 5705549Abstract: A rubber composition comprises a particular copolymer containing isobutylene unit, a paramethylstyrene unit and a parabromomethylstyrene unit; natural rubber and/or diene synthetic rubber; carbon black; and at least one hydrazide compound, and has a low value of tan .delta. at 60.degree. C. with maintaining tan .delta. at 0.degree. C. at a high level.Type: GrantFiled: April 15, 1996Date of Patent: January 6, 1998Assignee: Bridgestone CorporationInventor: Masahiro Hojo
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Patent number: 5604276Abstract: A recording liquid comprises at least one of certain specified dyes carbon black, a water-soluble resin, a water-soluble organic solvent and water. The organic solvent includes polyhydric alcohol and/or its alkyl ether and an aliphatic monohydric alcohol. The water-soluble resin has an acid value of 50 to 300. The amount of the dissolved water-soluble resin is not more than 2% by weight. A method for ink jet recording comprises ejecting the recording liquid as liquid droplets from fine orifices by endowing the recording liquid with heat energy.Type: GrantFiled: December 6, 1994Date of Patent: February 18, 1997Assignee: Canon Kabushiki KaishaInventor: Yuko Suga
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Patent number: 5534569Abstract: Heat generation of a rubber composition can be lowered by incorporating to the composition a compound of the formula, (I), (II) or (III), ##STR1## where A is an aromatic group, hydantoin ring or C.sub.0-18 straight chain hydrocarbon group, B is an aromatic group, X is hydroxy or amino, Y is pyridyl or hydrozino.Type: GrantFiled: March 8, 1995Date of Patent: July 9, 1996Assignee: Bridgestone CorporationInventor: Akiko Etoh
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Patent number: 5155151Abstract: A thermoplastic resin composition having improved heat stability which comprises a thermoplastic resin which contains at least 5% by weight of an .alpha.-alkyl-substituted aromatic copolymer comprising .alpha.-alkyl-substituted aromatic vinyl compound and at least one other comonomer copolymerizable therewith, wherein the composition contains a metal-deactivating agent which has a molecular weight of not more than 2,000 and at least one group of the formula: ##STR1## or an organometallic colorant containing free metal in an amount of not more than 2,000 ppm, from which a molded article having no or less silver streaks can be produced.Type: GrantFiled: February 21, 1992Date of Patent: October 13, 1992Assignee: Sumitomo Naugatuck Co., Ltd.Inventors: Kenji Hashimoto, Syuzi Takahashi, Hiroyuki Minematsu
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Patent number: 4874803Abstract: The present invention comprises reaction products resulting from the reaction of hydrazido-substituted or certain amino-substituted polymer stabilizers and cyclic dianhydrides, as well as the use of such products. The polymer stabilizers of the invention are useful for protecting a large variety of synthetic polymeric organic materials from the degradative effects of heat, light and oxygen. Some of the modifiers are flame retardants and many are metal deactivators in addition to their primary activity.Type: GrantFiled: September 21, 1987Date of Patent: October 17, 1989Assignee: Pennwalt CorporationInventors: Arthur L. Baron, Terry N. Myers, Jerome Wicher
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Patent number: 4845146Abstract: A flame-retardant olefin polymer composition containing 100 parts by weight of a resin component, said resin component consisting essentially of the following (a) and (b):(a) 60-99% by weight of a copolymer of ethylene and a carboxyl-containing monomer or a derivative thereof and(b) 1-40% by weight of an olefin polymer modified with an unsaturated carboxylic acid or a derivative thereof; and(c) 20-200 parts by weight of an inorganic flame retardant.Type: GrantFiled: April 8, 1988Date of Patent: July 4, 1989Assignee: Nippon Petrochemicals Company, LimitedInventors: Takashi Inoue, Masazi Sunada, Motohide Okamoto, Masayoshi Kariya, Tadashi Inoh
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Patent number: 4839408Abstract: The invention relates to a stabilized polyolefin composition, which composition is stabilized against deterioration caused by contact with heavy metals and improved in coloration properties. This is achieved by blending a polyolefin with:(A) a phenolic compound represented by the formula (I), ##STR1## wherein R.sub.1 represents a C.sub.1 -C.sub.3 alkyl group, (B) a metal deactivator having one or more ##STR2## groups in the side chain, and (C) a sulfur-containing compound represented by the formula (II-1), (II-2), (II-3) or (II-4): ##STR3## wherein R.sub.2 represents a C.sub.4 -C.sub.20 alkyl group, ##STR4## wherein R.sub.3 represents a C.sub.4 -C.sub.20 alkyl group, ##STR5## wherein R.sub.4 represents a C.sub.3 -C.sub.18 alkyl group, and R.sub.5 and R.sub.6 independently represent a hydrogen atom or a C.sub.1 -C.sub.6 alkyl group, ##STR6## wherein R.sub.7 represents a C.sub.3 -C.sub.18 alkyl group.Type: GrantFiled: August 15, 1988Date of Patent: June 13, 1989Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshiharu Fukui, Kazuhisa Kuroda, Tamaki Ishii, Manji Sasaki
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Patent number: 4618637Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether which have been stabilized with oxalyldihydrazide against oxidative degradation.Type: GrantFiled: December 16, 1985Date of Patent: October 21, 1986Assignee: General Electric CompanyInventors: Johannes H. G. M. Lohmeijer, Jacobus W. M. Noordermeer, Jan Bussink
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Patent number: 4536527Abstract: There is provided an improved molding resin capable of being molded into an article exhibiting reduced tendency to corrode a copper surface when the molded resin and the copper surface are placed in spaced relationship in a common unventilated atmosphere at elevated temperatures, as measured by the Bell Telephone Laboratories Copper Corrosion Test at temperatures within the range of from 150.degree. to 175.degree. C., wherein the molding resin comprises the combination of (a) a butyleneterephthalate polyester comprising a brominated copolyester as a polymeric flame retardant comprising aromatic halogen groups in a flame retardant amount, and (b) an alkylhydroxyphenylalkanoyl-hydrazine in an amount that is within the range of from 0.05 to 0.3% by weight.Type: GrantFiled: May 7, 1984Date of Patent: August 20, 1985Assignee: Celanese CorporationInventors: Wilfred L. Shearer, Stephen M. Sinker, Richard A. Wolf
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Patent number: 4469834Abstract: There is provided an improved molding resin capable of being molded into an article exhibiting reduced tendency to corrode a copper surface when the molded resin and the copper surface are placed in spaced relationship in a common unventilated atmosphere at elevated temperatures, as measured by the Bell Telephone Laboratories Copper Corrosion Test at temperatures within the range of from 150.degree. to 175.degree. C., wherein the molding resin comprises the combination of (a) a poly(butylene terephthalate) based polymer and aromatic halogen groups in a flame retardant amount, and (b) an alkylhydroxyphenylalkanoyl-hydrazine in an amount that is within the range of from 0.05 to 0.6% by weight, based on the weight of the molding resin, and less than 0.8% by weight based on the polymer.Type: GrantFiled: May 11, 1983Date of Patent: September 4, 1984Assignee: Celanese CorporationInventors: Wilfred L. Shearer, Stephen M. Sinker, Richard A. Wolf
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Patent number: 4447571Abstract: A process for providing water based anionic polyurethanes having improved thermal oxidation color stability. Water dispersed amine salts of anionic prepolymers prepared from the reaction of polyhydroxy compounds and dihydroxy carboxylic acids with diisocyanates are chain-extended with hydrazine or hydrazide and thereafter optionally with a diamine, when cured at temperatures in excess of 150.degree. C., form polyurethane products having substantially no discoloration and good mechanical properties. Alternately, the hydrazide may be employed as an additive rather than as a chain-extender. The process is particularly useful when employing cross-linking agents which react only at high temperatures.Type: GrantFiled: October 15, 1981Date of Patent: May 8, 1984Assignee: Witco Chemical CorporationInventors: Shmuel Dabi, Peter Loewrigkeit
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Patent number: 4446266Abstract: The invention relates to the use of N,N'-bis-salicyloyl hydrazine as a metal deactivator for organic materials which are in contact with copper or contain copper or copper ions, and has the object of providing an N,N'-bis-salicyloyl hydrazine which allows processing without danger on an industrial scale. For this purpose, the invention provides an N,N'-bis-salicyloyl hydrazine which is prepared from salicylic-acid alkyl ester and either hydrazine or salicylic-acid hydrazide. N,N'-bis-salicyloyl hydrazine prepared in this manner serves particularly as a metal deactivator in cable and wire insulation for power and communications engineering.Type: GrantFiled: July 29, 1980Date of Patent: May 1, 1984Assignee: Siemens AktiengesellschaftInventors: Wolfgang von Gentzkow, Roland Rubner
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Patent number: 4418170Abstract: A method for stabilizing organic polymers against copper-catalyzed oxidative decomposition by means of N,N-bis-salicyloyl hydrazine as a metal deactivator is described wherein dust development of the metal deactivator is precluded with certainty and negative property changes of the stabilized organic polymers are avoided. For this purpose, it is provided that a paste which contains finely-crystalline N,N'-bis-salicyloyl hydrazine in fine distribution in a liquid to wax-like aliphatic hydrocarbon of low volatility is worked into the polymer. The method is particularly well suited for stabilizing polyolefins for cable and wire insulation.Type: GrantFiled: July 19, 1982Date of Patent: November 29, 1983Assignee: Siemens AktiengesellschaftInventors: Wolfgang von Gentzkow, Manfred Schmiedel