With Water Nrm Patents (Class 524/253)
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Patent number: 9562178Abstract: The present invention relates to an adhesive for a polarizing plate including a polyvinyl alcohol-based resin, a titanium lactate ammonium salt, hydroxycarboxylic acid and water, and having a pH of 3.5 to 6.5, thereby having improved adhesive strength and water resistance, and a polarizing plate and an image display device including the same.Type: GrantFiled: September 30, 2014Date of Patent: February 7, 2017Assignee: LG Chem, Ltd.Inventors: Ji-Young Kim, Ji-Young Kim, Kyun-Il Rah
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Patent number: 9023981Abstract: The use of non aqueous dispersions NADs has enabled the development of fast setting sheet fed inks, for example. However either due to residual monomers or fractions of initiators, these NAD's have an objectionable odor. A chemical means of dramatically reducing the odor of the NAD's is thus presented. In exemplary embodiments of the present invention, such a chemical treatment can include an amine/alkali mixture in a coupling solvent. In exemplary embodiments of the present invention, the coupling solvent can be one or more of an alcohol, glycol or glycol ether, such as, for example, isopropyl alcohol. In exemplary embodiments of the present invention the amine can be an alkyl amine, such as, for example, diethyl amine, or various other amines, whether alone or in combination. In exemplary embodiments of the present invention, the alkali can be one or more of sodium hydroxide, potassium hydroxide and ammonium hydroxide, whether alone or in any combination thereof.Type: GrantFiled: July 30, 2010Date of Patent: May 5, 2015Assignee: Sun Chemical CorporationInventors: Ramasamy Krishnan, Mark Schneider, David Klein
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Publication number: 20140296382Abstract: An ink used for direct inkjet printing to plate based on nanometer material and a method for preparing same. Of the baseline total amount of the ink, 5 to 30 wt % is of film-forming resin, 0.01 to 5 wt % is of nanometer or micrometer dye, 30 to 60 wt % is of organic solvent, 0.01 to 5 wt % is of humectant, and water provides the balance; these ingredients are stirred and mixed at room temperature, and after the film-forming resin is completely dissolved, impurities and/or insoluble substances in the present invention are removed by means of multi-level filtering, and the obtained filtrate is the present ink. The ink in the present invention is sprayed on a metal base material surface by an inkjet printer o form a printing pattern which, after curing, can be directly printed on the machine, thus reducing chemical pollution and post-processing processes, while a press run of the printing plate can be up to 100,000 copies at a resolution of up to 175 lpi.Type: ApplicationFiled: June 1, 2012Publication date: October 2, 2014Inventors: Haihua Zhou, Minxuan Kuang, Yanlin Song
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Publication number: 20140216300Abstract: A water-based ink for use in a computer-to-plate inkjet printing and a preparation method therefor. A polymer of 5 to 40 wt %, an additive of 0.01 to 10 wt %, a dye or pigment of 0.01 to 10 wt %, an organic solvent of 1 to 30 wt %, an anti-foaming agent of 0 to 5 wt %, and deionized water are stirred and mixed at room temperature. When the polymer is dissolved, the mixed solution is filtered. The filtrate is the water-based ink. The water-based ink is sprayed via a computer-to-plate machine onto a surface of a metal substrate (which may be an aluminum plate, a zinc plate, or a copper plate) to form a graphic region. A printing plate allowing for computer-to-plate printing is acquired after solidification. The printing plate acquired is allowed to achieve a halftone dot reproduction rate between 2 and 99% and a recognition rate of 175 lpi.Type: ApplicationFiled: September 7, 2012Publication date: August 7, 2014Applicant: Institute of Chemistry, Chinese Academy of ScienceInventors: Wei Wu, Haihua Zhou, Yanlin Song
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Publication number: 20120264859Abstract: The present invention provides an aqueous copolymer dispersion comprising a copolymer and a polyamine, the copolymer comprises, as copolymerized units, at least one nonionic monomer selected from (meth)acrylate C6-C22 alkyl ester or Versatic vinyl ester; wherein the amount of the nonionic monomer ranges from 15% to less than 50% and wherein the amount of the polyamine ranges from 0.1 to 2%, by dry weight percentage based on the dry weight of the copolymer. The copolymer dispersion is suitable for use in coating compositions such as stone paints with significant improvement of water whitening resistance.Type: ApplicationFiled: April 17, 2012Publication date: October 18, 2012Inventors: Jianming XU, Tingke ZHANG, Hui LIU
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Patent number: 8222333Abstract: Adhesives containing inter-crosslinked polymeric microparticles are described. The polymeric microparticles include an acrylic polymer. The present disclosure also relates to water-based emulsions containing polymeric microparticles and a suitable inter-crosslinking agent as well as methods of making adhesives from such water-based emulsions.Type: GrantFiled: March 25, 2009Date of Patent: July 17, 2012Assignee: 3M Innovative Properties CompanyInventors: Chi-Ming Tseng, Jingjing Ma, Paul Sedgwick, Peter B. Hall
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Publication number: 20120080120Abstract: The present invention relates to a method for passivating metallic surfaces, wherein the metal surface is contacted with an aqueous composition comprising at least one water-soluble polymer (X) comprising acidic groups and with at least one polyamine (P), the pH of the composition being in the range from 0.5 to 2.Type: ApplicationFiled: October 3, 2011Publication date: April 5, 2012Applicant: BASF SEInventors: Achim Feßenbecker, Jens Haas, Frank Richter, Walter Bertkau, Christian Schade, Helmut Witteler
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Publication number: 20120059101Abstract: The application provides a terpolymer obtainable by copolymerizing (A) 1% to 70% by weight of at least one electron-deficient olefin, an example being an anhydride of a monoethylenically unsaturated C4 to C6 dicarboxylic acid, (B) 1% to 85% by weight of at least one olefin which on its olefinic double bond carries only hydrogen atoms and/or carbon atoms without electron-withdrawing substituents, an example being an isobutene homopolymer or copolymer having a number-average molecular weight of 100 to 500 000, and (C) 1% to 70% by weight of at least one alkoxyvinylsilane, and also derivatives of this terpolymer that are obtainable by modification or crosslinking.Type: ApplicationFiled: September 2, 2011Publication date: March 8, 2012Applicant: BASF SEInventors: Arno Lange, Matthias Scheibitz, Manoranjan Prusty
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Patent number: 7910531Abstract: Compositions and methods for producing colored bubbles, having a single color uniformly dispersed in the film, are described. The composition comprises at least one surfactant mixed with at least one colorant, the colorant forming at least approximately 10% of the composition. The surfactant, or surface-active agent, forms the bubble while the colorant, or pigment, provides the color. Generally, the composition may comprise 10-99% colorant to produce varying degrees of opacity. In addition, glycerin, fragrance, propylene glycol, sodium lauryl sulfate, potassium hydroxide, or other additives may be included.Type: GrantFiled: June 13, 2005Date of Patent: March 22, 2011Assignee: C2C Technologies LLCInventors: Ram W. Sabnis, Timothy D. Kehoe
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Publication number: 20100035073Abstract: An aqueous emulsion comprising an olefin-based copolymer comprising structural units derived from an ?-olefin and/or ethylene and structural units derived from a vinyl compound having a substituent, an emulsifier and a compound having 1 to 13 carbon atoms, wherein the compound having 1 to 13 carbon atoms has a hydroxyl group, an amino group, or both a hydroxyl group and an amino group, and the compound having 1 to 13 carbon atoms has, in the molecule thereof, at least two hydrogen atoms derived from a hydroxyl group or an amino group.Type: ApplicationFiled: December 11, 2007Publication date: February 11, 2010Applicant: SUMIKA CHEMTEX COMPANY, LIMITEDInventors: Shigeto Makino, Masashi Nagano
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Patent number: 7317048Abstract: Variable resistance PEDT/PSS buffer layers are provided for use in electroluminescent devices such as, e.g., OLEDs. In accordance with another embodiment, there are provided OLEDs comprising variable resistance PEDT/PSS buffer layers. In accordance with a further embodiment, methods have been developed for varying the conductivity of a PEDT/PSS layer cast from aqueous solution onto a substrate, by adding a co-solvent to the aqueous solution of PEDT/PSS prior to casting.Type: GrantFiled: December 30, 2003Date of Patent: January 8, 2008Assignee: E.I. du Pont de Nemours and CompanyInventor: Chi Zhang
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Patent number: 7241834Abstract: An aqueous acrylic emulsion polymer including, as copolymerized units, 70 to 99.5% by weight, based on dry polymer weight, monoethylenically unsaturated nonionic (meth)acrylic monomer and from 0.3 to 10% by weight, based on dry polymer weight, monoethylenically unsaturated acid monomer, wherein at least 40% by weight, based on dry polymer weight, of the emulsion polymer is formed by redox polymerization in the presence of 0.001 to 0.05 moles chain transfer agent per kg dry polymer weight is provided. An aqueous coating composition including the acrylic emulsion polymer, a method for improving the scrub resistance of a dry coating, a method for improving the adhesion of a dry coating, and a method for improving the adhesion of a dry coating to an alkyd substrate are provided.Type: GrantFiled: March 31, 2005Date of Patent: July 10, 2007Assignee: Rohm and Haas CompanyInventor: Ralph Craig Even
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Patent number: 6969734Abstract: An aqueous polymer dispersion containing acetoacetoxy functional polymer particles and an alkyl ethoxylated surfactants is provided. A method for preparing a coated substrate employing the aqueous polymer dispersion is also provided. The aqueous polymer dispersion is useful for preparing coatings having improved adhesion to substrates.Type: GrantFiled: November 10, 2004Date of Patent: November 29, 2005Assignee: Rohm and Haas CompanyInventors: Ozzie Moore Pressley, Wei Zhang
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Patent number: 6649679Abstract: This invention provides stable waterborne polymer compositions, which are stabilized against gelling, comprising a stable waterborne polymer composition having a Tg of greater than about 0° C. and comprising an acetoacetoxy-type functional polymer, a poly(alkylenimine), and a nonionic surfactant having a hydrophilic-lipophilic balance (HLB) of at least about 17.5. The waterborne polymer compositions of the invention are particularly useful in a variety of adhesive formulations such as pressure sensitive adhesives, laminating adhesives, and the like. Methods of making stable waterborne polymer compositions are also disclosed.Type: GrantFiled: December 20, 1999Date of Patent: November 18, 2003Assignee: Eastman Chemical CompanyInventors: Rebecca Reid Stockl, Peter Webb Raynolds, Duane Allan Scott
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Patent number: 6531538Abstract: The invention relates to a fast-drying rendering and coating composition comprising a binder in the form of an aqueous polymer dispersion or of a water-redispersible polymer powder, and also an organic precipitant, if desired in combination with an inorganic precipitant.Type: GrantFiled: March 6, 2000Date of Patent: March 11, 2003Assignee: Wacker-Chemie GmbHInventors: Hans-Peter Weitzel, Harald Zeh, Peter Ball, Klaus Marquardt
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Patent number: 6458876Abstract: Improved ink jet paper coatings which impart high optical density images and excellent water resistance to paper and a process for making an improved ink jet recording paper. The coating composition comprises an inorganic pigment preferably silica, and a PVOH composition in which the PVOH is blended with an alkylated non-polymeric polyamine.Type: GrantFiled: August 9, 1999Date of Patent: October 1, 2002Assignee: Air Products and Chemicals, Inc.Inventors: John Joseph Rabasco, Kevin Rodney Lassila, Richard Van Court Carr, Kristen Elaine Minnich
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Patent number: 6384177Abstract: An amine catalyst for production of a polyurethane and a polyisocyanurate is provided which comprises a quaternary ammonium compound represented by General Formula (1): where R1 to R6 are independently a linear or branched saturated hydrocarbon group of 1 to 4 carbon atoms; R7 and R8 are independently a linear or branched, saturated or unsaturated hydrocarbon group of 2 to 12 carbon atoms; n is a number of 0 to 3, provided that at n=o any one of R1, R2 and R3, and R5 and/or R6 may be linked together to form a heterocycle, or at n=1, 2, or 3, R5 or R6 and R4 may be linked together to form a heterocycle; A is a carbonate group or an organic acid group; and X is number of 1 to 2. The catalyst has high activity in formation of polyurethane foams and polyisocyanurate foams, having less odor, and producing foams of high fire retardance, having high curability, high retarding effect, and low corrosiveness.Type: GrantFiled: August 27, 2001Date of Patent: May 7, 2002Assignee: Tosoh CorporationInventors: Katsumi Tokumoto, Yutaka Tamano, Shuichi Okuzono
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Patent number: 6384097Abstract: An amine catalyst for production of a polyurethane and a polyisocyanurate is provided which comprises a quaternary ammonium compound represented by General Formula (1): where R1 to R6 are independently a linear or branched saturated hydrocarbon group of 1 to 4 carbon atoms; R7 and R8 are independently a linear or branched, saturated or unsaturated hydrocarbon group of 2 to 12 carbon atoms; n is a number of 0 to 3, provided that at n=0 any one of R1, R2 and R3, and R5 and/or R6 may be linked together to form a heterocycle, or at n=1, 2, or 3, R5 or R6 and R4 may be linked together to form a heterocycle; A is a carbonate group or an organic acid group; and X is number of 1 to 2. The catalyst has high activity in formation of polyurethane foams and polyisocyanurate foams, having less odor, and producing foams of high fire retardance, having high curability, high retarding effect, and low corrosiveness.Type: GrantFiled: August 27, 2001Date of Patent: May 7, 2002Assignee: Tosoh CorporationInventors: Katsumi Tokumoto, Yutaka Tamano, Shuichi Okuzono
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Patent number: 6376574Abstract: The invention relates to a fast hardening aqueous coating composition comprising from about 95 to about 99 weight percent of an anionically stabilized aqueous emulsion of a copolymer having a Tg of from about 0° C. to about 40° C., the copolymer containing two or more ethylenically unsaturated monomers, wherein from 0 to about 4 weight percent of the monomers are &agr;,&bgr;-ethylenically unsaturated aliphatic carboxylic acid monomers; from about 0.2 to about 5 weight percent of a polyimine having a molecular weight of from about 250 to about 20,000; and from about 0.2 to about 5 weight percent of a volatile base, wherein the composition has a pH from about 8 to about 11, and wherein a cast film of the composition has a hardening rate measurement rating of at least 5 within 20 minutes after casting under ambient conditions of temperature up to 30° C. and relative humidity no less than 50 percent.Type: GrantFiled: May 8, 2000Date of Patent: April 23, 2002Assignee: The Dow Chemical CompanyInventors: Bradley J. Helmer, James W. Young, Jr.
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Publication number: 20020019470Abstract: The present invention relates to an aqueous bubble solution. The solution has at least a surfactant that produces micelles in an aqueous solution, along with an ionic, hydrophobic or hydrogen bonding agent that interacts with the surfactant. When the bubble solution is formed into a bubble the bubble provides a first predetermined effect other than just being formed and popping.Type: ApplicationFiled: June 28, 2001Publication date: February 14, 2002Inventor: Daniel M. Ammon
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Patent number: 6156828Abstract: A gel-like emulsion containing natural rubber and crumb rubber from used vehicle tires which may be added to an asphalt paving emulsion at ambient temperature for chip coating, slurry sealing, microsurfacing, soil stabilization or pavement recycling.Type: GrantFiled: October 26, 1998Date of Patent: December 5, 2000Inventor: Steve R. Wickett
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Patent number: 6075079Abstract: The invention relates to a fast hardening aqueous coating composition comprising from about 95 to about 99 weight percent of an anionically stabilized aqueous emulsion of a copolymer having a Tg of from about 0.degree. C. to about 40.degree. C., the copolymer containing two or more ethylenically unsaturated monomers, wherein from 0 to about 4 weight percent of the monomers are .alpha.,.beta.-ethylenically unsaturated aliphatic carboxylic acid monomers; from about 0.2 to about 5 weight percent of a polyimine having a molecular weight of from about 250 to about 20,000; and from about 0.2 to about 5 weight percent of a volatile base, wherein the composition has a pH from about 8 to about 11, and wherein a cast film of the composition has a hardening rate measurement rating of at least 5 within 20 minutes after casting under ambient conditions of temperature up to 30.degree. C. and relative humidity no less than 50 percent.Type: GrantFiled: November 6, 1997Date of Patent: June 13, 2000Assignee: The Dow Chemical CompanyInventors: Bradley J. Helmer, James W. Young, Jr.
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Patent number: 6005035Abstract: This invention provides waterborne polymer compositions stabilized against gelling due to the addition of a poly(alkylenimine) by addition of nonionic surfactants having a hydrophilic-lipophilic balance (HLB) of at least about 17.5. The waterborne polymer compositions of the invention are useful in a variety of coating formulations such as, for example, paints, inks, sealants, textile backcoatings, adhesives and the like. Methods of making stable waterborne polymer compositions are also disclosed.Type: GrantFiled: February 13, 1998Date of Patent: December 21, 1999Assignee: Eastman Chemical CompanyInventors: Peter Webb Raynolds, Duane Allan Scott
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Patent number: 5972263Abstract: A method of improving the strength and/or plasticity of a clay composition comprising a kandite clay and an organic additive comprising at least one water soluble compound having a plurality of basic groups wherein the organic additive is present in an amount of from about 0.05% by weight to about 0.5% by weight based on the dry weight of the kandite clay present, which method comprises treating the kandite clay by adding thereto a monovalent ion activated smectite clay or a monovalent ion activating agent for a smectite clay or both whereby the amount of monovalent ion activated non-calcined smectite clay present in the clay composition is adjusted to be in the range from about 1% by weight to about 5% by weight based upon the dry weight of the kandite clay present.Type: GrantFiled: December 10, 1997Date of Patent: October 26, 1999Assignee: ECC International Ltd.Inventors: Howard Goodman, Christopher Stirling Hogg, Richard Gerrard Shaw Stewart
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Patent number: 5948837Abstract: Flame retarding additives prepared by way of reaction of:A) one or more nitrogenous organic compounds of a defined formula;B) P.sub.2 O.sub.5 ;C) H.sub.2 O.Type: GrantFiled: December 10, 1997Date of Patent: September 7, 1999Assignee: Montell North America Inc.Inventors: Osvaldo Cicchetti, Alfonso Bevilacqua, Alberto Pagliari
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Patent number: 5886135Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:dissolving a polyamide having an amine value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant and an inorganic alkaline material,adding sufficient water containing an acid to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, the amount of said acid being sufficient to neutralize a portion of said inorganic alkaline material, but insufficient to coagulate said polyamide from the resulting oil-in-water dispersion, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion.Type: GrantFiled: May 8, 1997Date of Patent: March 23, 1999Assignee: Henkel CorporationInventors: Stephen A. Fischer, Michael S. Wiggins, Chase J. Boudreaux
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Patent number: 5804640Abstract: A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.Type: GrantFiled: February 7, 1995Date of Patent: September 8, 1998Assignee: A-Line Products CorporationInventors: Alger E. Laura, Ronald J. Easton, Kurt C. Frisch, Han X. Xiao
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Patent number: 5804682Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:forming a solution of a polyamide having an acid value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant, wherein at least a portion of the acid value of said polyamide is neutralized,adding sufficient water to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.Type: GrantFiled: October 25, 1996Date of Patent: September 8, 1998Assignee: Henkel CorporationInventors: Stephen A. Fischer, David I. Devore, Kartar S. Arora, Reimar Heucher, Michael S. Wiggins, Chase J. Boudreaux, Dwight D. Heinrich
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Patent number: 5777011Abstract: Stabilized formazin compositions suitable as turbidity standards. The compositions can be prepared by diluting a concentrated formazin composition with a diluent containing hexamethylenetetramine and, optionally, a water-soluble sulfate salt such as sodium sulfate. The pH of the stabilized compositions is in the range of about 7 to 11.Type: GrantFiled: December 1, 1995Date of Patent: July 7, 1998Assignee: Hach CompanyInventor: Michael J. Sadar
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Patent number: 5543446Abstract: A water-soluble terpolymer for use as a dry strength additive for paper consists essentially of the following units: (a) (meth)acrylamide, (b) an ethylenically unsaturated, aliphatic carboxylic acid or a salt thereof, and (c) a water-soluble, polyvinyl monomer, wherein (c) comprises <0.07 mole % based on total monomers; a 1% solution of the terpolymer is capable of passing through a 200 mesh screen substantially without retention of polymer solids, and the terpolymer has a reduced specific viscosity of about 3.0 deciliters/g or less. The process for preparing the polymer includes the step of continuously adding both components of a redox initiator at a controlled rate to provide better control of polymerization and heat evolution.Type: GrantFiled: November 23, 1994Date of Patent: August 6, 1996Assignee: Hercules IncorporatedInventor: William Rodriguez
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Patent number: 5498661Abstract: The invention relates to ink binders. In particular, the invention relates to acrylic latex binders for use in preparing zinc-containing water-based inks for printing on plastic films. Inks containing these binders exhibit increased chemical resistance to commonly-used cleaning formulations and excellent heat resistance and water-crinkle resistance properties.Type: GrantFiled: May 9, 1995Date of Patent: March 12, 1996Assignee: Westvaco CorporationInventor: G. Frederick Hutter
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Patent number: 5407985Abstract: Stable aqueous microdispersions of finely divided polyamide resin particles and methods for the manufacture thereof are provided. The properties of these microdispersions are achieved by the addition thereto of an effective amount of a co-surfactant such as a lower alkyl alcohol. The provided microdispersions can be drawn into films which will form clear, continuous films at ambient or near-ambient temperatures regardless of the softening point of the polyamide resin. Dispersions according to this invention find use in hot melt adhesives, coatings, inks, and the like.Type: GrantFiled: March 25, 1991Date of Patent: April 18, 1995Assignee: Union Camp CorporationInventor: George A. Smith
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Patent number: 5403842Abstract: The invention relates to benzopyranone and benzothiopyranone compounds, compositions and methods of use which have adrenergic and serotonergic activity.Type: GrantFiled: May 26, 1992Date of Patent: April 4, 1995Assignee: Recordati S.A., Chemical and Pharmaceutical CompanyInventors: Amedeo Leonardi, Gianni Motta, Carlo Riva, Rodolfo Testa
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Patent number: 5205971Abstract: Non-whiteware ceramic articles having an increased green strength are prepared from slip compositions containing a polyalkylene polyamine as an additive or a mixture of a polyalkylene polyamine and binder as an additive. An example of such an additive is tetraethylenepentamine or a mixture of tetraethylenepentamine and a styrene butadiene latex.Type: GrantFiled: October 2, 1990Date of Patent: April 27, 1993Assignee: The Dow Chemical CompanyInventors: Alan P. Croft, Brian D. Koblinski
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Patent number: 5116895Abstract: Polyamines having at least two amine groups are incorporated into a polymer system comprising an anionic surfactant and a polymer having at least one anionic pendant group. The resulting polymer system typically exhibits at least one improved physical property.Type: GrantFiled: July 15, 1991Date of Patent: May 26, 1992Assignee: Union Oil Company of CaliforniaInventor: Gaylen M. Knutson
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Patent number: 5055506Abstract: Polyamines having at least two amine groups are incorporated into a polymer system comprising an anionic surfactant and a polymer having at least one anionic pendant group. The resulting polymer system typically exhibits at least one improved physical property.Type: GrantFiled: December 30, 1988Date of Patent: October 8, 1991Assignee: Union Oil Company of CaliforniaInventor: Gaylen M. Knutson
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Patent number: 5034448Abstract: A casting process for the preparation of whiteware ceramic articles employs a polyalkylene polyamine, such as tetraethylene pentamine, as an additive to increase the casting rate. The additive can be employed, e.g., in slip casting, vacuum casting and pressure casting. Optionally, the additive includes a binder such as a styrene butadiene latex in an amount effective to maintain the green strength of the articles prepared in the casting process.Type: GrantFiled: March 28, 1990Date of Patent: July 23, 1991Assignee: The Dow Chemical CompanyInventors: Brian D. Koblinski, Alan P. Croft, Alfredo C. Tamez
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Patent number: 4980404Abstract: One-component adhesives for adhesive bonds having increased high-temperature strengths contain(A) aqueous dispersions of carboxyl-containing polyacrylates and(B) organic polyamino compounds having a molecular weight of from 250 to 15,000 and an amino functionality greater than 5.Type: GrantFiled: March 7, 1989Date of Patent: December 25, 1990Assignee: BASF AktiengesellschaftInventors: Oral Aydin, Hans Kast
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Patent number: 4937283Abstract: A polyurethane essentially free of gel formed by reaction of a reactive hydrogen material such as the polyether glycol or polyester polyol or their mixtures, an organic polyisocyanate such as aliphatic or alicycloaliphatic ones and meta-tetramethyl xylene diamine useful for forming water dispersions, 100% solids castings or solvent casting of films or other polyurethane articles.Type: GrantFiled: August 4, 1988Date of Patent: June 26, 1990Assignee: The Goodyear Tire & Rubber CompanyInventor: Daniel A. Chung
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Patent number: 4886844Abstract: A method is provided for the preparation of stable aqueous dispersions of non-solvated, un-neutralized, low amine, low acid number polymerized fatty acid polyamide resins. In the preferred method of this invention, a polymerized fatty acid polyamide resin which has been prepared so as to have a low acid and low amine number is liquified by heating the polyamide resin to a temperature where it is at or above its melting point. The liquified polymerized fatty acid polyamide resin is then blended with a predetermined amount of water which is heated to a temperature such that the resulting blend will have a temperature above the melting point of the polyamide resin. A cationic surfactant which is the salt of the amine of the formula:R--NH--CH.sub.2).sub.n.sbsb.1 (NH--CH.sub.2).sub.n.sbsb.2).sub.n.sbsb.3 NH.sub.2wherein R represents an alkyl having 16-20 carbon atoms and n.sub.1 and n.sub.2 are the same or different and each represents a whole number from 1-3 and n.sub.3 is 0 or 1, is included in the mixture.Type: GrantFiled: February 3, 1988Date of Patent: December 12, 1989Assignee: Union Camp CorporationInventor: Michael E. Hayes
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Patent number: 4853421Abstract: A method is provided for the preparation of stable aqeuous dispersions of non-solvated, un-neutralized, low amine, low acid number polymerized fatty acid polyamider resins. In the preferred method of this invention, a polymerized fatty acid polyamide resin which has been prepared so as to have a low acid and low amine number is liquefied by heating the polyamide resin to a temperature where it is at or above its melting point. The liquified polymerized fatty acid polyamide resin is then blended with a predetermined amount of water which is heated to a temperature such that the resulting blend will have a temperature above the melting point of the polyamide resin. A cationic surfactant which is the salt of the amide of the formula:R--NH--CH.sub.2).sub.n.sbsb.1 (NH--CH.sub.2).sub.n.sbsb.2).sub.n.sbsb.3 NH.sub.2wherein R represents an alkyl having 16-20 carbon atoms and n.sub.1 and n.sub.2 are the same or different and each represents a whole number from 1-3 and n.sub.3 is 0 or 1, is included in the mixture.Type: GrantFiled: March 8, 1989Date of Patent: August 1, 1989Assignee: Union Camp CorporationInventor: Michael E. Hayes
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Patent number: 4824890Abstract: A curable, reinforced polydiorganosiloxane microemulsion is prepared by adding from 5 to 30 parts by weight of colloidal silica per 100 parts by weight of polydiorganosiloxane in the microemulsion and from 1 to 5 parts by weight of dialkyltindicarboxylate catalyst per 100 parts by weight of the microemulsion to polydiorganosiloxane microemulsion. The curable, reinforced polydiorganosiloxane emulsion can be cast into coherent, elastomeric films of less than 0.4 micrometer thickness.Type: GrantFiled: February 2, 1988Date of Patent: April 25, 1989Assignee: Dow Corning CorporationInventors: Shedric O. Glover, Daniel Graiver
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Patent number: 4746697Abstract: An antistatic resin composition prepared by dissolving at least one of lithium nitrate and lithium chloride in cold or hot water, adding a molten surface active agent thereto, mixing them together to give a homogeneous mixture, and blending the same with a molten thermoplastic resin either before or after cooling and solidification. The composition is highly antistatic and gives a film having a high degree of transparency.Type: GrantFiled: March 25, 1986Date of Patent: May 24, 1988Assignee: Kohjin Co., Ltd.Inventors: Naoya Yamaguchi, Sigeyosi Koyabu, Tomoji Mizutani
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Patent number: 4737549Abstract: Terpolymers of 30 to 75% by weight of maleic acid (anhydride), 5 to 60% by weight of (meth)acrylic acid and 5 to 40% by weight of (meth)acrylonitrile are suitable as retanning agents for mineral-tanned leather.Type: GrantFiled: August 1, 1986Date of Patent: April 12, 1988Assignee: Bayer AktiengesellschaftInventors: Bruno Bomer, Franz Schade
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Patent number: 4575527Abstract: Aqueous solutions of water-soluble cationic amine polymers which are stable against viscosity changes are prepared by adding small amounts of amine compounds to the solutions and adjusting the pH of the solutions to a value in the range of about 10.5 to 12.5.Type: GrantFiled: December 12, 1984Date of Patent: March 11, 1986Assignee: Atlantic Richfield CompanyInventors: Kenneth W. Dixon, Steven M. Menchen
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Patent number: 4450251Abstract: Aqueous thermosetting varnish compositions that are particularly water resistant after curing are disclosed. These compositions contain by weight (A) about 20-40 percent of a solution copolymer polymerized from monomers consisting essentially of (a) about 50-75 percent vinyl ester of a C.sub.1 -C.sub.3 carboxylic acid, (b) about 10-45 percent of C.sub.1 -C.sub.8 alkyl acrylate or methacrylate ester and (c) about 5-15 percent of a mixture of (i) at least about 0.5 percent monoethylenically unsaturated C.sub.3 -C.sub.5 carboxylic acid and (ii) at least about 2 percent C.sub.2 -C.sub.4 hydroxyalkyl acrylate or methacrylate. The copolymer is polymerized at a temperature of at least 110.degree. C. and at a non-volatile solids content of 60-80 percent.Type: GrantFiled: March 9, 1983Date of Patent: May 22, 1984Assignee: DeSoto, Inc.Inventors: Edwin A. Zychowski, Ronald L. Richards
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Patent number: 4442241Abstract: A shear thickening composition which comprises a water-in-oil emulsion having dispersed in the continuous, oily phase thereof, hydratable, water-expandable hydrophillic clay, said oily phase having dissolved therein a polyamine derivative surfactant and an oil-soluble amine. The aqueous phase will preferably have dissolved therein a polymer, preferably a polyacrylamide, which will flocculate and congeal the clay when same is mixed with water. These compositions are useful as well control fluids and may be used in deep wells.Type: GrantFiled: June 28, 1982Date of Patent: April 10, 1984Assignee: Exxon Research and Engineering Co.Inventors: Evelyn N. Drake, Peter Calcavecchio
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Patent number: 4407994Abstract: Disclosed is a method for sizing paper wherein the sizing agent employed is a hydrophobic cellulose reactive sizing agent such as a ketene dimer sizing agent. There is employed in combination with the sizing agent a novel sizing accelerator. Disclosed also is a novel sizing composition comprised of the sizing agent and the accelerator, the accelerator being a water-soluble nitrogen-containing reaction product of (1) a water-soluble polyaminopolyamide, such as that derived by reaction of adipic acid and diethylene-triamine; (2) an epihalohydrin, such as epichlorohydrin; and (3) a composition comprising, by weight, from about 20% to about 65% bis(hexamethylene)triamine, said composition being the residue obtained after recovery of hexamethylenediamine from its manufacture by hydrogenation of adiponitrile.Type: GrantFiled: July 2, 1981Date of Patent: October 4, 1983Assignee: Hercules IncorporatedInventors: Ralph A. Bankert, David H. Dumas
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Patent number: 4405532Abstract: A method of storing guayule and guayule-like plant material prior to processing which comprises mixing the material in communited form with at least one essentially water-free organic liquid to form a slurry in which the material is protected from contact with oxygen and storing said slurry for at least about 24 hours is discosed. Preferably, the organic liquid is an alcohol, ether, ester, ketone, or hydrocarbon and optionally the slurry also contains an oxidation stabilizer.Type: GrantFiled: October 1, 1981Date of Patent: September 20, 1983Assignee: The Firestone Tire & Rubber CompanyInventors: Richard Gutierrez, Edward L. Kay, David J. Serbin
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Patent number: 4385150Abstract: An organic solution of a fluorinated copolymer having carboxylic acid groups comprises the copolymer of fluorinated ethylenically unsaturated monomer and a functional monomer having carboxylic acid group (--COOH group) dissolved in a hydrophilic organic solvent with a small amount of water.Type: GrantFiled: October 8, 1981Date of Patent: May 24, 1983Assignee: Asahi Glass Company, Ltd.Inventors: Haruhisa Miyake, Yoshio Sugaya, Tatsuro Asawa