Two Or More Solid Polymers Or At Least One Solid Polymer And At Least One Specified Intermediate Condensation Product Patents (Class 524/271)
-
Patent number: 6953541Abstract: The present invention provides a method for preparing flexible thermoplastic compositions that may be used separately or combined with up to fifty percent thermoplastic scrap. One embodiment of the invention comprises creating a melt-blend of blending composition, up to 50% by weight thermoplastic scrap and up to 15% by weight poly(ethyl-co-vinyl) acetate wherein the blending composition comprises an impact polypropylene, impact modifier and plasticizer. The polypropylene, impact modifier and plasticizer are selected to meet requirements of flexible thermoplastic compositions useful in vehicle interiors. In another embodiment of the invention a random polypropylene is used.Type: GrantFiled: April 4, 2001Date of Patent: October 11, 2005Assignee: Sunoco Inc. (R&M)Inventor: Sehyun Kim
-
Patent number: 6907911Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene) polymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol polymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.Type: GrantFiled: June 29, 2004Date of Patent: June 21, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventor: Hsien-Chang Wang
-
Patent number: 6869985Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.Type: GrantFiled: November 26, 2002Date of Patent: March 22, 2005Assignee: AWI Licensing CompanyInventors: Amar Kumar Mohanty, Lawrence T. Drzal, Brian P. Rook, Manjusri Misra
-
Patent number: 6843292Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene) polymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol polymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.Type: GrantFiled: June 8, 2001Date of Patent: January 18, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventor: Hsien-Chang Wang
-
Patent number: 6828391Abstract: Use, as modifier resin for rubber mixtures, of novolaks ABC plastified with terpene-type olefinically unsaturated natural substances C, where the ratio of the molar amount of the phenol or phenol derivative B and the molar amount of the natural substance C in the modified novolak is from 1:6 to 6:1, process for increasing the tear propagation resistance and reducing the compression set of rubber vulcanizates by adding these modifier resins to rubber mixtures, and components molded from vulcanizates thus prepared.Type: GrantFiled: December 12, 2002Date of Patent: December 7, 2004Assignee: Solutia Germany GmbH & Co. KGInventors: Thomas Burkhart, Siegfried Wallenwein
-
Patent number: 6822029Abstract: Hot-melt pressure-sensitive adhesive based one or more non-thermoplastic elastomers, at least comprising 100 parts by mass of the non-thermoplastic elastomer(s), from 1 to 200 parts by mass of one or more tackifying resins, from 1 to 100 parts by mass of one or more reactive phenolic resins whose methylol content is from 1 to 20% by weight, based on the reactive phenolic resin, from 1 to 100 parts by mass of accelerator substances.Type: GrantFiled: August 18, 2000Date of Patent: November 23, 2004Assignee: tesa AGInventors: Axel Burmeister, Sven Hansen, Heiko Leydecker, Christian Kreft, Jochen Stähr
-
Patent number: 6794443Abstract: A low application temperature, high heat resistant hot melt adhesive comprising an ethylene vinyl acetate and/or ethylene 2-ethyl hexyl acrylate polymer having a melt index of at least 550 grams/10 minutes, a paraffin wax and a rosin derived tackifier.Type: GrantFiled: February 14, 2003Date of Patent: September 21, 2004Assignee: National Starch and Chemical Investment Holding CorporationInventors: Wayne K Chu, Susan M Burdett, David J Good
-
Publication number: 20040162396Abstract: A low application temperature, high heat resistant hot melt adhesive comprising an ethylene vinyl acetate and/or ethylene 2-ethyl hexyl acrylate polymer having a melt index of at least 550 grams/10 minutes, a paraffin wax and a rosin derived tackifier.Type: ApplicationFiled: February 14, 2003Publication date: August 19, 2004Inventors: Wayne K. Chu, Susan M. Burdett, David J. Good
-
Publication number: 20040077759Abstract: The present invention relates to hot-coextrudable hot-melt pressure-sensitive adhesives particularly suitable for the production of multilayer films intended for what are called “repositionable” packages that are opened and reclosed easily. The films used in these packages comprise at least three layers, namely an outer layer intended to be complexed thereafter, a sealing and separable layer, defining all or part of the internal surface of the package, and between them a hot-melt adhesive layer that joins them together. In this type of package, the adhesive plays an essential role insofar as, once the package has been opened by the end user, the quality of the reclosure and of the reopening will depend on the performance of the adhesive, which is of course a pressure-sensitive adhesive, that is to say an adhesive that adheres simply by manual pressure.Type: ApplicationFiled: December 10, 2003Publication date: April 22, 2004Applicant: Bostik Findley, S.A.Inventors: Anne Bardiot, Nicolas Sajot, Pierre Gerard, Christophe Notteau
-
Publication number: 20040051210Abstract: An elastomer composition based on at least one diene elastomer, an inorganic filler as reinforcing filler, a polyfunctional organosilane as (inorganic filler/diene elastomer) coupling agent bearing at least two functions denoted “X” and “Y” which are graftable, on the one hand, to the elastomer by means of the X function and, on the other, to the inorganic filler by means of the Y function, characterised in that said Y function is a hydroxysilyl function (≡Si—OH). Preferably, this organosilane is a hydroxysilane polysulfide, the diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and the reinforcing inorganic filler is a siliceous or aluminous filler of the highly dispersible type. Tires or semi-finished products for tires, in particular treads for tires comprising a composition according to the invention.Type: ApplicationFiled: April 10, 2003Publication date: March 18, 2004Inventors: Jean-Claude Tardivat, Salvatore Pagano
-
Patent number: 6653398Abstract: The invention relates to a novel polyester tackifier, adhesive compositions comprising the tackifier and methods of preparation. More specifically, the polyester tackifier is obtainable by polymerising a mixture comprising a diacid or derivative thereof, a diol, and at least 6 molar % of an organic monofunctional compound, wherein the mixture is essentially free from compounds comprising more than two carboxylic acid groups or alcohol groups.Type: GrantFiled: February 16, 2001Date of Patent: November 25, 2003Assignee: Akzo Nobel N.V.Inventors: John Hazen, Patrick Peter Mario Aarts
-
Patent number: 6632522Abstract: A pressure-sensitive adhesive comprising a blend of at least two components, wherein the first component is at least one pressure-sensitive adhesive and second component is at least one thermoplastic material, wherein the components form a blended composition having more than one domain and, wherein one domain is substantially continuous (generally, the pressure-sensitive adhesive) and the other domain is substantially fibrillous to schistose (generally, the thermoplastic material). The second component can be (a) at least one thermoplastic elastomer, (b) at least one elastomer with a tackifying resin or (c) at least one elastomer.Type: GrantFiled: November 24, 2000Date of Patent: October 14, 2003Assignee: 3M Innovative Properties CompanyInventors: Patrick Darby Hyde, Roy Wong, Dennis Louis Krueger, Robert W. G. Shipman, David James Yarusso, Felix P. Lau, Eumi Pyun, Pamela S. Tucker
-
Patent number: 6613830Abstract: There is disclosed an aqueous-base coating composition containing, as essential components, finely-divided, water-dispersable: colorant, polyethylene, binder and water with sufficient of a surface active agent to form a stable suspension. The coating composition is applied as a film coating onto a polyethylene surface and the binder temporarily binds the coating to the surface until the coating can be thermally treated to incorporate the coating into the polyethylene, permanently coloring the surface. The invention also comprises a method for the preparation of the aqueous-base coating composition in which the essential components are prepared as aqueous dispersions or emulsions which are blended together to form the final coating composition.Type: GrantFiled: January 29, 1999Date of Patent: September 2, 2003Inventors: Michael J. Stevenson, Robert A. Reeves, Matthew P. Stevenson
-
Patent number: 6613813Abstract: An offset printing ink is provided which comprises a colophony-modified phenolic resin and at least one component selected from the group consisting of (A) a maleic resin, (B) a modified hydrocarbon resin, (C) a colophony resin ester and mixtures thereof. The ink further comprises a water-insoluble fatty acid ester of a multivalent alcohol which has a high steric spatial requirement, and/or ethinol.Type: GrantFiled: January 4, 2000Date of Patent: September 2, 2003Inventors: Ursula Borgmann, Thomas Fuss, Klaus Hanke
-
Patent number: 6593407Abstract: A low application temperature, high heat resistant hot melt adhesive comprising an adhesive polymer and a modified rosin and/or modified terpene which has a molecular weight to softening point ratio of less that about 10. The adhesive is particularly well-suited for hot filled packaging applications.Type: GrantFiled: February 6, 2001Date of Patent: July 15, 2003Assignee: National Starch and Chemical Investment Holding CorporationInventors: Dale L. Haner, Brian Carillo, Justin Mehaffy
-
Publication number: 20030125434Abstract: This invention relates to high bonding hot melt adhesive compositions comprising a high molecular weight polystyrene-ethylene/butylene-polystyrene (SEBS) block copolymer as the basic ingredient and articles constructed therefrom. This polymer is useful in a variety of hot melt adhesive applications for consumer product articles subject to hostile use environments such as toys and other play things.Type: ApplicationFiled: December 31, 2001Publication date: July 3, 2003Applicant: Mattel, Inc.Inventor: Abimael Cordova
-
Patent number: 6562888Abstract: Rosin esters that are both light-colored and color stable may be produced by reacting rosin with an organic compound containing two or more hydroxyl groups each separated from each other by at least four carbon atoms. With appropriate choices for the esterification catalyst and antioxidant(s), the rosin ester may be useful as a tackifier, and can be formulated into an adhesive composition. The adhesive compositions will further comprise an appropriate adhesive polymer.Type: GrantFiled: July 27, 1998Date of Patent: May 13, 2003Assignee: Arizona Chemical CompanyInventors: Charles R. Frihart, Nelson E. Lawson, Brett A. Neumann
-
Patent number: 6541553Abstract: This invention relates to curable strippable adhesive and coating films, and also to improved high performance pressure sensitive adhesives. The adhesive comprises: (a) from 10 to 90 percent by weight of a crosslinkable epoxidized diene polymer, (b) from 0 to 70 percent by weight of a diene mono-ol polymer, with the condition that the mono-ol polymer not exceed three times the weight of the epoxidized polymer, (c) from 5 to 40 weight percent of a block copolymer of a vinyl aromatic hydrocarbon and a diene having, on average, more than one vinyl aromatic hydrocarbon block per molecule, and wherein the block copolymer can be functionalized by grafting onto it from 0.1 to 5% by weight of a carboxylic acid or anhydride, preferably maleic anhydride, (d) from 0 to 65% percent by weight of a tackifying resin, and (e) from 0.01 to 3 percent by weight of a photoinitiator.Type: GrantFiled: October 17, 2000Date of Patent: April 1, 2003Assignee: Kraton Polymers U.S. LLCInventors: James Robert Erickson, David Romme Hansen
-
Patent number: 6531544Abstract: The present invention relates to using certain block copolymer based hot melt adhesive compositions for the assembly of disposable absorbent articles such as disposable diapers wherein the adhesive is in contact with an oil-based skin care ingredient, and the resulting disposable absorbent article. The adhesive is particularly useful for adhesively bonding elastic to nonwoven, and exhibits good stress resistance in the presence of lotion.Type: GrantFiled: February 3, 2000Date of Patent: March 11, 2003Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Steve R. Vaughan, Greg J. Van Lith, Larry S. Flanagan
-
Patent number: 6521336Abstract: Disclosed is a composition provided with biodegradable property and transparency which is excellent in heat sealing property at low temperatures, peelability and adhesiveness to substrate as well as a film or laminate of the composition. The composition comprises as indispensable components thereof 27-70% by weight of polylactic acid, 70-27% by weight of an aliphatic polyester, and 1-20% by weight of a tackifier selected from the group consisting of: an aliphatic cyclic hydrocarbon resin, a metal salt of a rosin ester, and a rosin ester having an acid number of 10 or less.Type: GrantFiled: September 25, 2001Date of Patent: February 18, 2003Assignee: Tohcello, Co., Ltd.Inventors: Junichi Narita, Tohru Sawai, Ichiro Takeishi, Suekazu Itoh
-
Patent number: 6518342Abstract: The present invention provides an emulsion for pressure-sensitive adhesive, and a pressure-sensitive adhesive product which exhibits high water resistance and high adhesion properties. The emulsion for pressure-sensitive adhesive includes as essential components: a pressure-sensitive adhesive polymer (A) having a glass-transition temperature of −80 to −20° C., a weight-average molecular weight of 150,000 or larger, and a carboxylic acid value of 30 or smaller; a rosin derivative (B) having a weight-average molecular weight of 100,000 or smaller, and containing at least part of the carboxyl groups being alkali salt with a carboxylic acid value of 190 or larger before alkalization; and a compound (C) having a weight-average molecular weight of 100,000 or smaller, and having no carboxyl group but having at least one functional group reactive with a carboxyl group in its molecule.Type: GrantFiled: October 28, 1999Date of Patent: February 11, 2003Assignee: Nippon Shokubai Co., Ltd.Inventors: Yasumasa Tanaka, Naoki Tsunemine, Osamu Konosu
-
Patent number: 6518334Abstract: This invention relates to polymer blends comprising a polycarboxypolyamide resin with an alkali dispersible resin. This invention also relates to the use of the polymer blends to prepare aqueous dispersions. The aqueous dispersions were obtained by heating polycarboxypolyamide resins with alkali dispersible resins in an aqueous medium. The invention further relates to coating compositions containing the aqueous dispersions. Such coating compositions include inks, floor finishes, overprint varnishes, sizing, paints and adhesives.Type: GrantFiled: March 22, 2000Date of Patent: February 11, 2003Assignee: JohnsonDiversey, Inc.Inventors: Glenn C. Calhoun, Michael T. Sarkis
-
Patent number: 6511743Abstract: A multilayer PSA construction includes a facestock, a hazy, first adhesive layer adjacent the facestock, and a PSA layer adjacent the first adhesive layer, and is protected until use by a release liner. The first adhesive layer includes an immiscible blend of a first elastomer having a first glass transition temperature and forming a continuous phase, and a second elastomer forming a discontinuous phase. The second elastomer has a glass transition temperature greater than the first glass transition temperature. The first adhesive layer also contains a tackifying component, which is preferentially soluble in the discontinuous phase. The PSA layer has a composition different from the first adhesive layer and is formed of at least one tackified elastomer that provides a measurable third maximum glass transition temperature, which is less than the second glass transition temperature. The multilayer PSA construction exhibits reduced migration of tackifiers and plasticizers over time.Type: GrantFiled: September 8, 2000Date of Patent: January 28, 2003Assignee: Avery Dennison CorporationInventors: Chan U. Ko, Hsiao K. Chuang, Ronald Ugolick
-
Patent number: 6486246Abstract: A hot melt adhesive polyolefin composition having a viscosity from 7,000 to less than 500,000 mPa·sec, at 190° C. including (by weight): I) 5-85% of a crystalline propylene polymer selected from a propylene homopolymer and a copolymer of propylene and ethylene or a C4-C10 &agr;-olefin or blends thereof, having an isotactic index from 80 to 98%; II) 5-85% of an heterophasic polyolefin composition including: (i) a crystalline propylene polymer and (ii) and an amorphous copolymer of ethylene and propylene or a C4-C10 &agr;-olefin or blends thereof, containing less than 40% of ethylene; III) 10-75% of a material selected from aliphatic hydrocarbon resins, terpene/phenolic resin, polyterpenes, rosin, rosin esters and blends thereof; and optionally IV) a mineral paraffinic or naphthalenic oil, an amorphous poly(&agr;-olefin) having low molecular weight or a mixture thereof.Type: GrantFiled: October 4, 1999Date of Patent: November 26, 2002Assignee: Montell Technology Company BVInventor: Jean Marc Vion
-
Patent number: 6482878Abstract: This invention relates to solvent-free moisture curable one-part hot melt polyurethane adhesive or sealant compositions which are solid at room temperature. In one embodiment, the polyurethane adhesive or sealant composition comprises in percentages by weight (a) from about 20% to about 75% of a urethane prepolymer; (b) from about 1% to about 66% of a reactive, hydroxyl containing, or a nonreactive polymer formed from ethylenically unsaturated monomers; and (c) from about 20% to about 75% of a thermoplastic resin. In another embodiment, the polyurethane adhesive or sealant composition comprises, in percentages by weight of the polyurethane composition (a) from about 10% to about 90% of a urethane prepolymer; and (b) from about 5% to about 90% of a thermoplastic resin which is an ethylene vinylacetate/ethylene acrylate terpolymer.Type: GrantFiled: April 21, 2000Date of Patent: November 19, 2002Assignee: National Starch and Chemical Investment Holding CorporationInventor: Wayne K. Chu
-
Patent number: 6455627Abstract: The present invention is a hot melt pressure sensitive positioning adhesive for use with an absorbent article. The adhesive comprises: (a) from 6 to less than 15 percent by weight, of the total of (a), (b) and (c) of a blend of (i) from 40 to 95% by weight of a hydrogenated styrene-(butadiene and/or isoprene)-styrene block copolymer; and (ii) from 5 to 60% by weight of a blend of a hydrogenated styrene-isoprene-styrene-isoprene block copolymer; and (iii) from 0 to 40% by weight of an amorphous ethylene/propylene copolymer having a number average molecular weight of 9,000 to 30,000; and (b) from 50 to 80 percent by weight, of the total of (a), (b) and (c), of a tackifying resin which has an aromaticity such that the MMAP cloud point is at least 45° C.; and (c) from 5 to 35 percent by weight, of the total of (a), (b) and (c), of a plasticizer.Type: GrantFiled: June 22, 2000Date of Patent: September 24, 2002Assignee: Kraton Polymers US LLCInventors: Noël Raymond Maurice De Keyzer, Carolyn Ann Stoner
-
Patent number: 6433069Abstract: This invention relates to a removable grade hot melt pressure sensitive adhesive comprising from about 5% to about 30% by weight of the adhesive of a block copolymer having styrene endblocks and ethylene/butylene or ethylene/propylene midblocks and having a coupling efficiency of less than about 65% and a melt index of greater than about 20 grams/10 minutes; from about 10% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%; from about 20% to about 60% by weight of the adhesive of a tackifying resin and from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil.Type: GrantFiled: June 14, 2000Date of Patent: August 13, 2002Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Susan T. Oeltjen, Jeffrey S. Lindquist, Yoshihiro Kodama, Daisuke Asai
-
Patent number: 6428900Abstract: A water-sensitive hot melt adhesive composition based on sulfonated branched copolyester polymers for use with articles such as paper products, disposable nonwoven products, tapes, labels and packaging materials. The adhesive composition includes about 10% to about 90%, by weight, of a sulfonated polyester copolymer or a blend of one or more sulfonated polyester polymers; about 0% to about 80%, by weight, of a tackifying resin; about 0% to about 40%, by weight, of a compatible plasticizer; about 5% to about 50% by weight of a polyethylene glycol having a molecular weight greater than 2000 and a melting point greater than 50° C; and about 0% to about 3% by weight of one or more antioxidant. The adhesive maintains the article in an assembled condition by providing adequate adhesive bond strength during normal use, but dissolves in the presence of water thereby permitting the article to be recycled or otherwise disposed of in an environmentally friendly manner.Type: GrantFiled: March 9, 2000Date of Patent: August 6, 2002Assignee: Ato Findley, Inc.Inventor: Baoyu Wang
-
Patent number: 6417259Abstract: The present invention relates to a process of forming a high damping, soft polymer gel. The method involves mixing a polyalkylene grafted poly(alkenyl-co-maleimide) with a poly(alkenyl-co-maleimide) and an extender so as to form a gel.Type: GrantFiled: June 5, 2000Date of Patent: July 9, 2002Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz
-
Publication number: 20020065345Abstract: Disclosed is a composition provided with biodegradable property and transparency which is excellent in heat sealing property at low temperatures, peelability and adhesiveness to substrate as well as a film or laminate of the composition. The composition comprises as indispensable components thereof polylactic acid, an aliphatic polyester and a tackifier.Type: ApplicationFiled: September 25, 2001Publication date: May 30, 2002Inventors: Junichi Narita, Tohru Sawai, Ichiro Takeishi, Suekazu Itoh
-
Patent number: 6391960Abstract: A multipurpose hot melt adhesive comprising endblock resin in combination with a radial or linear SBS copolymer having a solution viscosity greater than 1000 cPs at 25% in toluene suitable for use as both a construction and elastic attachment adhesive in disposable products is disclosed.Type: GrantFiled: April 13, 2000Date of Patent: May 21, 2002Assignee: National Starch and Chemical Investment Holding CorporationInventors: Mahesh Sambasivam, Charles W. Paul
-
Patent number: 6388002Abstract: An aqueous composition suitable for coating a substrate is described. The composition comprises a reaction product of (i) at least one carboxylic acid containing from 3 to 22 carbon atoms; and (ii) at least one unsubstituted or substituted aliphatic amine or polyfunctional aromatic amine, containing from 2 to 25 carbon atoms; (iii) a complex crosslinking agent of a metal from groups Ia, IIa, IIIa or IVa of the first and second rows of the transition metals from the Periodic Table of Elements; (iv) a resin or oil, the weight ratio of the resin or oil to the sum of (i), (ii) and (iii) being at least 2.5:1; and (v) a thickener, a continuous dry layer obtained by applying the composition to Western Red Cedar providing a contact angle with water not exceeding 80°.Type: GrantFiled: September 11, 2000Date of Patent: May 14, 2002Assignee: Rhodia LimitedInventors: Gary Baker, John William Prince
-
Patent number: 6376598Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene)copolymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol copolymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.Type: GrantFiled: June 15, 2000Date of Patent: April 23, 2002Assignee: Exxon Mobil Chemical Patents Inc.Inventor: Hsien-Chang Wang
-
Patent number: 6310126Abstract: A mixer and method of using the mixer is disclosed in which a closed chambered vessel capable of both holding pressure and vacuum is charged with a mixture of elastomer and materials taken from the group of tall oil, fatty acids and residues of tall oil production. The charge mixture is heated under pressure without excessive friction heat. After the heating cycle, the mixer atmosphere is evacuated under vacuum, and then the mix is discharged.Type: GrantFiled: July 27, 2000Date of Patent: October 30, 2001Assignee: Texas Encore Materials, Inc.Inventor: John D. Osborn
-
Patent number: 6303676Abstract: A method for the production of an improved water soluble resin binder for laminating printing inks has been discovered. The method comprises esterifying the carboxylated Diels Alder adduct produced from the reaction of rosin and at least one carboxylated dienophile with a sufficient amount of at least one polyol to produce a modified rosin having an acid number greater than 157. The modified rosin is reacted with a sufficient amount of an acrylic copolymer having an acid number greater than 180 under esterification conditions between 175 ° C. and 185 ° C. for a time sufficient to produce a resin binder having an acid number greater than 157. A laminating ink formulation of the invention comprises water, pigment, styrene-acrylic varnish, shellac varnish, alkanol and the improved water soluble resin binder of the invention as described above.Type: GrantFiled: June 26, 1998Date of Patent: October 16, 2001Assignee: Sun Chemical CorporationInventors: Robert J. Catena, Mathew C. Mathew, Albert A. Kveglis
-
Patent number: 6274657Abstract: A surfactant for forming stable dispersions of rosin esters compatible with elastomeric latexes, the surfactant having the formula R1—R2—R3. R1 and R3 are each rosin (i.e., rosin, rosin dimer or a mixture of rosin and rosin dimer). R2 is selected from the group consisting of polyethylene glycol and polyethylene glycol-R4-polyethylene glycol wherein R4 is rosin (i.e., rosin, rosin dimer or a mixture of rosin and rosin dimer). The surfactant is prepared by esterifying the rosin material with polyethylene glycol.Type: GrantFiled: January 27, 1994Date of Patent: August 14, 2001Assignee: Arizona Chemical CompanyInventors: John T. Geoghegan, Long S. Wang
-
Patent number: 6258885Abstract: A filling compound for electrical and optical equipment in the form of cables, connectors, plugs, etc. and to assemblies thus produced, is provided. Electrical and optical equipment in the form of cables, connectors, plugs, etc. have to be protected against harmful influences penetrating from outside, particularly water, and also against mechanical damage during laying or as a result of exposure to heat. The filling compound is based on a stellate substance, i.e. a substance having a branched molecular structure in which, ideally, 3 or more branches, more particularly polymeric chains, radiate from a single branching point. The filling compound is flexible at very low temperatures but, on the other hand, does not run out, even at extremely high temperatures.Type: GrantFiled: January 13, 1999Date of Patent: July 10, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Reimar Heucher, Juergen Wichelhaus, Johannes Andres
-
Patent number: 6255395Abstract: Masterbatch including at least about 65 wt % of resin having a R&B softening point as measured in accordance with ASTM 28-67. The masterbatch also includes a carrier polymer having a peak melting temperature, as measured by DSC, up to about 20° C. greater than the R&B softening point of the resin. A masterbatch pellet made by a method, including mixing a resin having a R&B softening point as measured in accordance with ASTM 28-67, and a carrier polymer having a peak melting temperature, as measured by DSC, up to about 20° C. greater than the R&B softening point of the resin, to form masterbatch composition including at least about 65 wt % of resin. The method of making the masterbatch pellet also includes pelletizing the masterbatch composition into masterbatch pellet. Methods of making a masterbatch, methods for making polymer product, and a polymer product.Type: GrantFiled: March 22, 1999Date of Patent: July 3, 2001Assignee: Hercules IncorporatedInventor: Daniel W. Klosiewicz
-
Patent number: 6232391Abstract: A multipurpose hot melt adhesive comprising endblock resin in combination with a radial or linear SBS copolymer having a solution viscosity greater than 1000 cPs at 25% in toluene suitable for use as both a construction and elastic attachment adhesive in disposable products is disclosed.Type: GrantFiled: December 23, 1998Date of Patent: May 15, 2001Assignee: National Starch and Chemical Investment Holding CorporationInventors: Mahesh Sambasivam, Charles W. Paul
-
Patent number: 6207093Abstract: The present invention relates to improved processability of polyolefin films through the addition to the basic isotactic polypropylene (iPP) polymer of a syndiotactic polypropylene (sPP) in an amount within the range of about 2 to 10 weight percent and of a resin or rosin modifier in an amount within the range of 1 to 30 weight percent. Preferably, the composition could contain syndiotactic propylene in an amount within the range of about 2 to 5 weight percent. Preferably, about 3 weight percent of syndiotactic propylene is present in the polyolefin composition. The resin or rosin modifier could, preferably, be present in an amount within the range of 5 to 10 weight percent. Preferably, the composition should contain about 10 weight percent of the modifier. The present invention encompasses both the resulting polyolefin films and the process for producing such films.Type: GrantFiled: April 24, 1998Date of Patent: March 27, 2001Assignee: Fina Technology, Inc.Inventors: Aiko Hanyu, William R. Wheat
-
Patent number: 6183862Abstract: A multilayer PSA construction includes a facestock, a hazy, first adhesive layer adjacent the facestock, and a PSA layer adjacent the first adhesive layer, and is protected until use by a release liner. The first adhesive layer includes an immiscible blend of a first elastomer having a first glass transition temperature and forming a continuous phase, and a second elastomer forming a discontinuous phase. The second elastomer has a glass transition temperature greater than the first glass transition temperature. The first adhesive layer also contains a tackifying component, which is preferentially soluble in the discontinuous phase. The PSA layer has a composition different from the first adhesive layer and is formed of at least one tackified elastomer that provides a measurable third maximum glass transition temperature, which is less than the second glass transition temperature. The multilayer PSA construction exhibits reduced migration of tackifiers and plasticizers over time.Type: GrantFiled: September 23, 1998Date of Patent: February 6, 2001Assignee: Avery Dennison CorporationInventors: Chan U. Ko, Hsiao K. Chuang, Ronald Ugolick
-
Patent number: 6184285Abstract: Novel hot melt construction adhesives for disposable articles, such as diapers, sanitary napkins, medical gowns, surgical drapes, and the like, are described which offer superior properties versus currently available hot melt adhesives. These hot melt construction adhesive compositions comprise a blend of styrene-isoprene block copolymer containing at least about 25 weight percent styrene and styrene-butadiene block copolymer containing at least about 25 weight percent styrene, at least one compatible tackifying resin and at least one plasticizer. The hot melt construction adhesive possesses a viscosity no greater than about 25,000 mPa·s at about 140° C., a shear adhesion failure temperature of at least about 60° C., and a static shear time to failure of no less than about 25 hours at about 23°.Type: GrantFiled: November 5, 1998Date of Patent: February 6, 2001Assignee: Henkel CorporationInventors: Stephen F. Hatfield, Alejandro Matassa, Robert Goodman
-
Patent number: 6172156Abstract: A hot melt pressure sensitive adhesive comprising a) from about 15% to about 40% by weight of a block copolymer having a coupling efficiency of less than about 75%; b) from about 20% to about 50% by weight of a tackifying resin selected from the group consisting of those tackifying resins having a softening point of less than about 100° C.; c) from about 30% to about 50% by weight of a plasticizing oil; and d) up to about 15% of a compatible polymer wherein the total polymer content does not exceed 40% by weight of the adhesive wherein the hot melt pressure sensitive adhesive fails cohesively during use.Type: GrantFiled: June 12, 1997Date of Patent: January 9, 2001Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Jeffrey S. Lindquist, Lisa L. Ryan
-
Patent number: 6169132Abstract: Aqueous composition comprising from 10 to 35% by weight of a water-dispersed polymer A) having a glass transition temperature Tg of below −10° C. from 5 to 22% by weight of a resin B) which is liquid at 23° C. and 1 bar, has a glass transition temperature of below −10° C. and in which abietic acid is soluble at 23° C. and 1 bar such that it is possible to obtain solutions of resin B and abietic acid having a weight content of up to 50% by weight of abietic acid from 5 to 22% by weight of a resin C) which is based on abietic acid or on modified abietic acid and has a glass transition temperature of from 0 to 90° C. and from 21 to 80% by weight of a filler D), the percentages by weight being based on the sum of the constituents of the aqueous composition with the exception of water.Type: GrantFiled: June 3, 1999Date of Patent: January 2, 2001Assignee: BASF AktiengesellschaftInventors: Peter Fickeisen, Eckehardt Wistuba
-
Patent number: 6166110Abstract: A method for producing a pressure sensitive adhesive composition includes at least one elastomer that produces a substantially homogeneous pressure sensitive adhesive composition. The method is particularly well suited for relatively high throughput continuous compounding rates, e.g., at a throughput rate of more than about 5.Type: GrantFiled: November 24, 1998Date of Patent: December 26, 2000Assignee: 3M Innovatives Properties CompanyInventors: Timothy D. Bredahl, Herbert W. Goetsch, Daniel C. Munson, John Michael Oberthier
-
Patent number: 6162868Abstract: The present invention relates to a pressure-sensitive adhesive comprising:a mixture of a block copolymer (A) comprising polystyrene blocks and polybutadiene or polyisoprene blocks which are optionally hydrogenated and of a copolymer (B) of ethylene and of an alkyl (meth)acrylate,at least one tackifying resin and optionally a plasticizer,this adhesive being deposited while hot on a substrate.These products are useful for self-adhesive labels and tapes.Type: GrantFiled: September 24, 1998Date of Patent: December 19, 2000Assignee: Elf Atochem S.A.Inventors: Eric Radigon, Jean Lebez, Jean-Michel Pierrot
-
Patent number: 6162859Abstract: The present invention is directed to hot melt pressure sensitive adhesive compositions, that exhibit excellent adhesion properties and improved thermal stability, said compositions comprising:a) 1 to 30 parts of styrene-butadiene-styrene triblock copolymer;b) 1 to 30 parts of styrene-isoprene-styrene triblock copolymer;c) 5 to 50 parts of a tackifier compatible with the butadiene and isoprene midblocks, but not compatible with the styrene end blocks;d) 5 to 70 parts of a tackifier compatible with the butadiene and isoprene midblocks, and the styrene end blocks;e) 5 to 30 parts of a tackifier compatible with the styrene end blocks, but not compatible with the butadiene and isoprene midblocks;f) 5 to 30 parts oil; andg) 0 to 5 parts wax.Type: GrantFiled: June 7, 1999Date of Patent: December 19, 2000Assignee: National Starch and Chemical Investment Holding CorporationInventors: Xinya Lu, Ingrid Cole
-
Patent number: 6136200Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein: A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH).sbsp.p.sup.(SO.sbsp.4.sup.).sbsp.y.sup.(Aci) (2m+3n)-p-2y].sub.rwhere r=1 to 98% bw; u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ =(PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al--Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.Type: GrantFiled: March 11, 1994Date of Patent: October 24, 2000Assignee: Polymer Research CorporationInventor: John J. Waldmann
-
Patent number: 6121351Abstract: Thermoplastic compositions containing certain anthraquinone polysulfonamide colorants incorporated therein as toners or colorants. The anthraquinone colorant moieties which are incorporated into the polymer chain of the polysulfonamide colorants are not leachable, sublimable or extractable and do not exude from the thermoplastic compositions. The anthraquinone polysulfonamide colorants may be added to the thermoplastic polymers during production or melt blended with the polymer by conventional techniques to produce transparent thermoplastic compositions useful for a variety of end uses where nonmigrating or nonextractable colorants are needed.Type: GrantFiled: August 7, 1997Date of Patent: September 19, 2000Assignee: Eastman Chemical CompanyInventors: Max Allen Weaver, Wayne Payton Pruett, Kay Hunt Shackelford, Samuel David Hilbert
-
Patent number: 6121354Abstract: A high performance, hot melt, single-component sealant which combines the prefered properties of single- and two-component sealants. The sealant comprises a styrene block copolymer, a moisture-curable silylated polyurethane prepolymer, an aromatic tackifier resin, a polar tackifier resin, a polyethylene wax and an organo silane adhesion promoter. Optionally, the sealant may include UV absorbers, antioxidants, plasticizers, catalysts, fillers, pigments, and the like. The sealant does not require mixing before it is applied at a high temperature to the surface that is to be sealed. After application, the sealant forms, upon cooling, a solid elastomer. Upon further exposure to atmospheric moisture, the sealant forms a thermoset crosslinked network having the preferred properties of two-component chemically-cured sealants. The sealant is suitable for use as an edge sealant for insulated glass.Type: GrantFiled: November 19, 1998Date of Patent: September 19, 2000Assignee: Bostik, Inc.Inventor: Michael Chronister