Two Or More Solid Polymers Or At Least One Solid Polymer And At Least One Specified Intermediate Condensation Product Patents (Class 524/271)
  • Patent number: 4652491
    Abstract: Pressure-sensitive adhesive capable of functioning as an adhesive for diaper closure tape, comprising a blend of specified portions of styrene:butadiene AB block copolymer, random SBR and/or milled natural rubber, and rosin ester tackifier of the type capable of tackifying butadiene-based rubbers.
    Type: Grant
    Filed: May 2, 1985
    Date of Patent: March 24, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Ramsis Gobran
  • Patent number: 4622357
    Abstract: A pressure-sensitive adhesive composition comprising a block rubber, a tackifying resin and a plasticizer as major components, the composition being characterized in that the tackifying resin is partially fumarized and/or partially maleinized, disproportionated rosin ester.
    Type: Grant
    Filed: March 8, 1985
    Date of Patent: November 11, 1986
    Assignee: Arakawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Seiichi Tsuchida, Yoshihiro Kodama, Hiroari Hara
  • Patent number: 4618640
    Abstract: A hot-melt adhesive composition containing an ethylene copolymer, wax and a tackifying resin as major components, the composition being characterized in that the tackifying resin is partially fumarinized and/or partially maleinized, disproportionated rosin ester.
    Type: Grant
    Filed: March 20, 1985
    Date of Patent: October 21, 1986
    Assignee: Arakawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Seiichi Tsuchida, Yoshihiro Kodama, Hiroari Hara
  • Patent number: 4590230
    Abstract: Disclosed herein is an adhesive composition which contains specific amounts of (A) an aqueous emulsion, (B) a filler and (C) a resin solution of a resinous tackifier dissolved in a solvent and/or plasticizer. The adhesive composition has a fast setting time in adhesion strength and excellent water-proofness and hence produces superb adhesion force even when applied to a fresh mortar base which has been aged insufficiently.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: May 20, 1986
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Keiichi Kamada, Katuaki Iiyama, Yasushi Yano, Isao Itoh
  • Patent number: 4556464
    Abstract: A cured adhesive composition possessing high cohesive strength at high temperatures along with excellent shear strength and solvent resistance prepared using a block copolymer containing carbon-carbon double bonds in the endblocks which are crosslinked by a crosslinking agent preferentially compatible with the endblock phase.
    Type: Grant
    Filed: April 29, 1985
    Date of Patent: December 3, 1985
    Assignee: Shell Oil Company
    Inventor: David J. St. Clair
  • Patent number: 4536218
    Abstract: Printed materials such as tickets, lottery forms, cards and contest forms, bearing a hidden message which is revealable by scratching off a covering opaque layer, are prepared by printing the message on the substrate, lithographing a protective layer such as a clear varnish or a pigmented varnish-ink over the hidden message, and then lithographing a hiding coat over the applied protective layer. The protective layer formulation and the hiding coat layer are both based upon compatible, preferably the same, film forming resin systems, and are deposited from a common solvent. The protective layer may provide a clear, colorless transparent film through which the message may be viewed, or a colored see-through layer, so that it constitutes one color layer also for the printing of other areas of the substrate.
    Type: Grant
    Filed: February 8, 1984
    Date of Patent: August 20, 1985
    Inventor: Eli A. Ganho
  • Patent number: 4535013
    Abstract: A low temperature binder systen for non-woven polyolefin fabrics and corresponding method for increasing multidirectional web strength thereof whereby the corresponding fiber web is contacted by a system comprised of a copolymer or terpolymer modified with an active amount of a resin ester component of limited abietic acid concentration, of a hydrogenated resin and a glycerol or pentaerythritol, the latter having a specified softening point and molecular weight range.
    Type: Grant
    Filed: August 15, 1983
    Date of Patent: August 13, 1985
    Inventor: Beryl M. Kuhn
  • Patent number: 4532273
    Abstract: A two-part adhesive which comprises(i) as the main ingredient an emulsion consisting essentially of (a) an aqueous emulsion of a polymer or copolymer obtained from an essential monomer of an adduct of a tertiary amino group-containing acrylic or methacrylic acid ester and an epihalohydrin, (b) a tackifier resin selected from the group consisting of a petroleum hydrocarbon resin, a phenolic resin, a terpene resin, a rosin resin, a coumarone resin, and a coumarone-indene resin, and (c) an epoxy compound containing two or more epoxy groups in the molecule; and(ii) a curing agent selected from a primary or secondary amino group-containing compound. The adhesive is particularly useful for preparing automobile interior decorations, such as inside trims (e.g. doors, pillars), instrument panels, formed ceiling, and console box.
    Type: Grant
    Filed: May 21, 1984
    Date of Patent: July 30, 1985
    Assignee: Sunstar Giken Kabushiki Kaisha
    Inventors: Toshio Kadowaki, Koichiro Sanji
  • Patent number: 4528312
    Abstract: This invention relates to novel blends containing degraded crystalline polypropylene or propylene containing copolymer, low density polyethylene, hydrocarbon tackifying resin, and a fatty acid amide useful as extrusion coating compositions which provide coatings having good coatability and good heat sealability. These coated substrates then can be used in fabricating bags and other packaging applications. Particularly, these coatings are a blend of a degraded crystalline polypropylene, or propylene containing copolymer, low density polyethylene, hydrocarbon tackifying resin, and a fatty acid amide containing 16 to 40 carbon atoms.
    Type: Grant
    Filed: June 27, 1984
    Date of Patent: July 9, 1985
    Assignee: Eastman Kodak Company
    Inventor: Ray Edwards
  • Patent number: 4526919
    Abstract: This invention relates to novel blends containing crystalline polypropylene or propylene containing copolymer, low density polyethylene, hydrocarbon tackifying resin, and a fatty acid amide useful as extrusion coating compositions which provide coatings having good coatability and good heat sealability. These coated substrates then can be used in fabricating bags and other packaging applications. These extrusion coating compositions are a blend of a crystalline polypropylene, or propylene containing copolymer, low density polyethylene, hydrocarbon tackifying resin, and a fatty acid amide containing 16 to 40 carbon atoms.
    Type: Grant
    Filed: June 27, 1984
    Date of Patent: July 2, 1985
    Assignee: Eastman Kodak Company
    Inventor: Ray Edwards
  • Patent number: 4521493
    Abstract: A resin-modified fiber filter formulation, fiber filter element, and method for improving dimensional stability, firmness and resiliency of a polyolefin fiber filter element comprised of crimped polyolefin fiber tow, by contacting filaments thereof with a formulation comprising a blend of resin and base polymer emulsions as precursors forming the active formulation "in situ", at a convenient station by removing water, the solid resin component of which must have a low molecular weight and approved softening temperature range to obtain the desired characteristics.Typical resins are polyterpenes and hydrogenated rosin esters; typical base polymers are polyvinyl acetate and copolymers thereof with, e.g., ethylene or acrylates.
    Type: Grant
    Filed: January 12, 1984
    Date of Patent: June 4, 1985
    Assignee: Hercules Incorporated
    Inventor: Jay B. Class
  • Patent number: 4511687
    Abstract: A synthetic resin composition comprises (A) 100 parts by weight of polycaprolactone and (B-1) 10 to 70 parts by weight of a thermoplastic resin and 1 to 30 parts by weight of a tackifier, or (B-2) 10 to 70 parts by weight of a chlorinated polyolefin.
    Type: Grant
    Filed: May 28, 1982
    Date of Patent: April 16, 1985
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Michio Nakanishi, Naoki Nakashima
  • Patent number: 4497926
    Abstract: A substantially solvent-free adhesive composition consists essentially of an elastomer and tackifier, a metal oxide and, optionally, a plasticizer. The elastomer is selected from the group consisting of polar elastomers and unsaturated elastomers which have at least 5 mole percent unsaturation, said elastomer being a non-crystalline elastomer or an elastomer which has a slow rate of crystallization such that after a time period of at least 100 hours has elapsed following subjecting the elastomer to a temperature of 70.degree. C. for 30 minutes, the elastomer has a room temperature Shore A hardness of less than 60. The adhesive compositions can be formed into a shaped article, such as of a tape, film, sheet or tubular sleeve, if desired. The compositions have high adhesive strength for bonding together a variety of substrates. The adhesive is particularly useful with a dimensionally recoverable article, such as a shrinkable sleeve, to bond the recovered sleeve to a substrate such as an electric cable.
    Type: Grant
    Filed: March 6, 1984
    Date of Patent: February 5, 1985
    Assignee: Raychem Corporation
    Inventor: Lester T. Toy
  • Patent number: 4491655
    Abstract: There is disclosed the use of esters especially methyl esters of rosin acids as total or partial replacements for oil in rubber formulations. Vulcanizate properties, low temperature performance, and processibility are comparable when using either the rosin ester or an aromatic oil, however, the rosin ester extended rubber demonstrates improved abrasion resistance and flex resistance.
    Type: Grant
    Filed: January 6, 1984
    Date of Patent: January 1, 1985
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Paul H. Sandstrom
  • Patent number: 4478993
    Abstract: There is disclosed the use of decarboxylated rosins as total or partial replacements for oil in rubber formulations. Vulcanizate properties, low temperature performance, and processibility are comparable when using either the decarboxylated rosins or an aromatic extending oil, however, the decarboxylated rosin extended rubber demonstrates improved abrasion resistance.
    Type: Grant
    Filed: January 6, 1984
    Date of Patent: October 23, 1984
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson G. Wideman, Paul H. Sandstrom
  • Patent number: 4471086
    Abstract: The hot-melt adhesives of the present invention comprise a blend of at least one polyethylene, a tackifying resin, a high density, low viscosity polyethylene wax having a molecular weight of about 1000, and a Fischer-Tropsch hydrocarbon wax. This hot-melt adhesive has a novel combination of properties such as low viscosity and fast setting which meet the requirements necessary for use in rapid bonding or closing in low temperature applications.
    Type: Grant
    Filed: November 9, 1983
    Date of Patent: September 11, 1984
    Assignee: Eastman Kodak Company
    Inventor: Bruce W. Foster
  • Patent number: 4463120
    Abstract: A process for preparing an aqueous adhesive composition which comprises preparing a solvent dispersion by mixing rubber, carbon black, vulcanizing agent, tackifying resin and accelerator with sufficient organic solvent to form a solvent dispersion and thereafter emulsifying the solvent dispersion in the presence of water to form an aqueous emulsion. The aqueous emulsion may be used to bond unvulcanized rubber compounds, such as a tread stock to the carcass portion during the formation of a tire.
    Type: Grant
    Filed: January 24, 1983
    Date of Patent: July 31, 1984
    Assignee: SWS Silicones Corporation
    Inventors: Wendell Collins, Howard L. Brooks
  • Patent number: 4460728
    Abstract: Hot melt adhesive compositions are prepared from ethylene copolymers, atactic polypropylene, tackifying resins and optional additives. The adhesives are non-pressure sensitive and are characterized by high cohesive strength, strong tack, and good heat, creep and cold resistance. In accordance with the preferred embodiment, the adhesives are formulated so as to be particularly adaptable for use in the construction of disposable diapers of the multi-line construction variety.
    Type: Grant
    Filed: February 28, 1983
    Date of Patent: July 17, 1984
    Assignee: National Starch and Chemical Corporation
    Inventors: Robert C. Schmidt, Jr., Stanley J. Decowski, Jr., Paul P. Puletti
  • Patent number: 4427744
    Abstract: A heat-activated pressure-sensitive adhesive which comprises an aqueous emulsion of finely divided solids comprising a rubber polymer, a resin and a plasticizer, which optionally contains urea, a urea-compound and/or a polyhydroxy compound in the aqueous phase. Substrates such as plastic film, metal foil and cigarette paper may be effectively bonded.
    Type: Grant
    Filed: August 19, 1982
    Date of Patent: January 24, 1984
    Assignee: H. B. Fuller Company
    Inventor: Robert M. Hume, III
  • Patent number: 4419494
    Abstract: Conventional hot melt adhesive formulations based on A-B-A type block copolymers are improved with respect to their heat and plasticizer resistance by addition thereto of a polymeric fatty acid polyamide.
    Type: Grant
    Filed: March 16, 1982
    Date of Patent: December 6, 1983
    Assignee: National Starch and Chemical Corporation
    Inventors: Paul P. Puletti, Catherine Stubler Salerno
  • Patent number: 4399249
    Abstract: Pressure sensitive adhesive compositions are provided that are especially suitable for forming contact bonds that are resealable to polyethylene surfaces at room temperature. Such adhesive compositions include a blend of a linear or a radial block copolymer, an end-block modifying resin compatible with the end or thermoplastic block of the copolymer and incompatible with the mid of elastomeric block, a plasticizing process oil compatible with the mid or elastomeric block, and, only if desired, not more than about 14 weight percent of a mid block or elastomeric block associating or modifying resin compatible with the mid or elastomeric block and incompatible with the end or thermoplastic block. A particularly advantageous utilization of these compositions is as a releasable and resealable sealing strip for thin-walled storage or sandwich bag products made of a polyolefin film.
    Type: Grant
    Filed: December 24, 1980
    Date of Patent: August 16, 1983
    Assignee: Eschem Inc.
    Inventor: Leon L. Bildusas
  • Patent number: 4391938
    Abstract: Compositions comprising polyethylene terephthalate and an additive to promote crystallization rate and improve surface appearance selected from the group consisting of monomeric esters of citric acid and epoxidized esters of unsaturated aliphatic carboxylic acids. Compositions comprising polyethylene terephthalate, poly (C.sub.4 -C.sub.6) terephthalate, and a surface appearance and crystallization rate improving additive selected from the group consisting of monomeric esters of citric acid, organic esters of an aromatic carboxylic acid of 7 to 11 carbon atoms containing at least one carboxyl group per aromatic nucleus and an alcohol, oligomeric polyesters, and epoxidized esters of unsaturated aliphatic carboxylic acids.
    Type: Grant
    Filed: February 16, 1982
    Date of Patent: July 5, 1983
    Assignee: Rohm and Haas Company
    Inventors: Nazir A. Memon, Cielo S. Myers
  • Patent number: 4384066
    Abstract: A neutralized sulfonated EPDM terpolymer is rendered amenable to adhesion utilizing typical foot sole primer/adhesive systems by incorporating into the sulfonated EPDM a syndiotactic 1,2-polybutadiene. The composition preferably includes process oils; inorganic fillers and preferential plasticizers for the neutralized sulfonated EPDM terpolymer.
    Type: Grant
    Filed: August 13, 1981
    Date of Patent: May 17, 1983
    Assignee: Uniroyal, Inc.
    Inventor: Francis X. O'Shea
  • Patent number: 4374946
    Abstract: A concrete joint sealant comprising tall pitch, atactic polypropylene, fresh rubber and aliphatic hydrocarbon resin.
    Type: Grant
    Filed: September 22, 1981
    Date of Patent: February 22, 1983
    Assignee: Aoi Chemical Inc.
    Inventors: Yoshifumi Takemura, Hirokazu Miyazaki
  • Patent number: 4373041
    Abstract: Tackifying resins, such as rosin esters, hydrogenated rosin esters, and terpene resins, are used as promoters for silica-filled rubber compositions to improve the physical properties, such as tensile, hysteresis, etc., of the rubber.
    Type: Grant
    Filed: October 29, 1981
    Date of Patent: February 8, 1983
    Assignee: Phillips Petroleum Company
    Inventors: Jerold D. Wood, Carl J. Stacy
  • Patent number: 4367113
    Abstract: Compatible blends of polymers are disclosed which contain (a) a high density ethylene polymer or an isotactic propylene polymer, (b) a copolymer of ethylene and an alkyl ester of acrylic or methacrylic acid or vinyl acetate, (c) an ionomer resin, and (d) a tackifying resin such as a terpene resin.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: January 4, 1983
    Assignee: Gulf Oil Corporation
    Inventors: Khalid A. Karim, Pallavoor R. Lakshmanan, James H. Rea
  • Patent number: 4359551
    Abstract: A hot-melt pressure-sensitive adhesive composition comprising (a) 100 parts by weight of a specific grafted block copolymer material formed by the graft reaction of at least one block copolymer comprising at least one polybutadiene or polyisoprene block and at least two polystyrene blocks with at least one unsaturated carboxylic acid monomer and/or derivative monomer thereof and (b) 50 to 250 parts by weight of a specific tackifier mixture consisting of a tackifier S comprising at least 50% by weight of a terpene resin having a softening point of 60.degree. C. or more and a tackifier L comprising at least 50% by weight of a terpene resin having a softening point of 30.degree. C. or less and having an S/L mixing weight ratio of 9/1 to 3/7, and optionally 1 to 50 parts by weight of a softening agent has been found to be excellent in holding power especially for paper.
    Type: Grant
    Filed: December 18, 1980
    Date of Patent: November 16, 1982
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Yoshikazu Suda, Haruhisa Nagano, Shigeyuki Miyata, Akio Yamori
  • Patent number: 4359570
    Abstract: Disclosed are colored polyester compositions containing copolymerized anthraquinone dyes as colorants, which compositions may be used, for example, for food packaging and to mold colored beverage bottles. The copolymerized dyes are thermally stable at the processing temperatures, and are colorfast and nonextractable. The useful dyes have the general formula: ##STR1## wherein either or both of rings A and B may contain in any position thereon one or two groups of the formula ##STR2## R and R.sup.3 each is hydrogen, lower alkyl or lower hydroxyalkyl; R.sup.1, R.sup.2, R.sup.4 and R.sup.5 each is hydrogen or 1-3 substituents such as lower alkyl, lower alkoxy, phenyl, Cl, Br, or the like; X is --S-- or --NH--; n is 1 or 2; m is 0, 1, or 2.
    Type: Grant
    Filed: October 26, 1981
    Date of Patent: November 16, 1982
    Assignee: Eastman Kodak Company
    Inventors: Thomas G. Davis, Max A. Weaver
  • Patent number: 4358557
    Abstract: The hot-melt adhesives of the present invention comprise a blend of ethylene-vinyl acetate copolymer, hydrocarbon tackifier resin, aromatic low softening point tackifying resin and paraffin wax. These hot-melt adhesive compositions provide adhesives especially useful for bonding polyethylene film to a nonwoven support. The bonds provided by this adhesive have a novel combination of properties such as good static shear lap bond strength, low elongation and good elevated temperature properties.
    Type: Grant
    Filed: March 8, 1982
    Date of Patent: November 9, 1982
    Assignee: Eastman Kodak Company
    Inventor: Brenda J. Boggs
  • Patent number: 4345349
    Abstract: Hot melt adhesives especially suited for use in the perfect binding of books are prepared from(1) 15-30% of a block polymer having the general configurationA-B-Awherein A is a non-elastomeric polymer block derived from the moieties of a monovinyl aromatic hydrocarbon radical and B is an elastomeric polymer block derived from the moieties of a conjugated diene monomer;(2) 5-10% of an ethylene vinyl acetate copolymer containing 17 to 42% vinyl acetate; wherein the ratio of the block polymer to the ethylene vinyl acetate copolymer is within the range of 1.75:1 to 6:1;(3) 25-40% of at least one rosin ester tackifier selected from the group consisting of glycerol and pentaerythritol esters of natural and modified rosins,(4) 25-35% of a wax diluent which is solid at room temperature; and(5) 0.5 to 3% of at least one stabilizer.such composition being characterized by an ability to form a film exhibiting Instron yield strengths of 100-250 psi. and a low temperature flexibility of less than 10.degree. F.
    Type: Grant
    Filed: July 30, 1981
    Date of Patent: August 24, 1982
    Assignee: National Starch and Chemical Corporation
    Inventor: Thomas P. Flanagan
  • Patent number: 4338227
    Abstract: Homogeneous blends of at least two non-crosslinked ethylene copolymers having different polar comonomer contents are mildly crosslinked to reduce their melt index. The crosslinked blend can be mixed with tackifier, plasticizer, filler and antioxidant to yield hot melt pressure sensitive adhesive compositions. In the alternative, at least one of the two ethylene copolymers can be crosslinked prior to blending in the hot melt pressure sensitive adhesive composition.
    Type: Grant
    Filed: April 24, 1981
    Date of Patent: July 6, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Edward C. Ballard
  • Patent number: 4337297
    Abstract: Blends of thermoplastic polymers which may be coextruded to form bonding layers in film laminates contain (a) a copolymer of ethylene with a lower alkyl acrylate or methacrylate or vinyl acetate, (b) a chlorinated ethylene polymer and optionally (c) a tackifying resin.
    Type: Grant
    Filed: July 16, 1981
    Date of Patent: June 29, 1982
    Assignee: Gulf Oil Corporation
    Inventors: Khalid A. Karim, James H. Rea
  • Patent number: 4337298
    Abstract: Compatible blends of polymers are disclosed which contain (a) a low density ethylene polymer, (b) a copolymer of ethylene and an alkyl ester of acrylic or methacrylic acid or vinyl acetate, (c) an ionomer resin, and (4) optionally a tackifying resin such as a glyceryl ester of a rosin acid.
    Type: Grant
    Filed: August 5, 1981
    Date of Patent: June 29, 1982
    Assignee: Gulf Oil Corporation
    Inventors: Khalid A. Karim, Pallavoor R. Lakshmanan, James H. Rea
  • Patent number: 4335026
    Abstract: Pressure-sensitive adhesive compositions having decreased resistance to peel removal while maintaining high shear resistance, i.e., holding-power adhesion, in air and in water comprising an elastomeric blend of a selected rubber and a selected olefin terpolymer having a Modulus, M.sub.60, at 60% elongation of from about 1 to about 1.5 and a polydisparity of no more than about 10, a liquid plasticizer, a reinforcing filler and a solid tackifier.
    Type: Grant
    Filed: March 27, 1981
    Date of Patent: June 15, 1982
    Assignee: Johnson & Johnson Products Inc.
    Inventor: Ivan J. Balinth
  • Patent number: 4331576
    Abstract: This invention relates to water-soluble, pressure-sensitive, hot-melt adhesives; and more specifically to hot-melt adhesives for labels and pressure-sensitive labels. The labels can be readily removed by application of water to the adhesive to facilitate peeling from the article; the adhesives are based upon certain vinyl pyrrolidone polymers.
    Type: Grant
    Filed: January 29, 1981
    Date of Patent: May 25, 1982
    Inventors: Herman Colon, Albert Maletsky