Solid Polymer Derived From Ethylenically Unsaturated Hydrocarbon Only Patents (Class 524/274)
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Patent number: 6075078Abstract: A method for producing a fast drying high solids adhesive wherein a water based polymer emulsion (latex) is modified with unemulsified elasticizing oils and reinforcing-tackifying resins to produce a stable emulsion of polymer, oil and resin without the use of additional emulsifiers or volatile organic solvents. When packaged in pressurizable canisters along with a suitable propellant, the adhesive may be sprayed through a suitable nozzle and deposited in a thin layer to form an adhesive film which has excellent bonding characteristics for many laminates such as fabric or textiles, wood, plastics, metals and rubber, and for adhering flooring materials such as carpet, linoleum, tiles and artificial grass to a variety of substrates.Type: GrantFiled: October 14, 1998Date of Patent: June 13, 2000Assignee: XL CorporationInventors: John W. Braud, Helen Grace Gilbreath
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Patent number: 6040042Abstract: This invention relates to a formulation for making a composite plastics film or sheet comprising a polyolefin, a filler and a voiding agent, characterised in that the voiding agent is a pentaerythritol ester of maleic rosin. This is particularly suitable for use on the printable surfaces of synthetic paper. A feature of this rosin is that it minimises the yellowing of the paper.Type: GrantFiled: March 2, 1998Date of Patent: March 21, 2000Assignee: Arjobex LimitedInventors: David Thomson Dalgleish, Matthew Richard Sands
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Patent number: 6034159Abstract: A hot melt adhesive for multipurpose bookbinding comprising a) from about 35% to about 40% by weight of a styrene-isoprene-styrene bloc copolymer; b) from about 25% to about 50% by weight of at least one compatible tackifying resin; c) from about 5% to about 30% by weight of a synthetic high melt point wax; d) from about 5% to about 30% by weight of a solid benzoate plasticizer; e) up to about 25% of a compatible wax; and f) up to about 15% of a compatible polymer.Type: GrantFiled: July 3, 1996Date of Patent: March 7, 2000Assignee: H.B. Fuller Licensing & Financing, Inc.Inventor: David B. Malcolm
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Patent number: 6022914Abstract: The present invention relates to a pressure-sensitive adhesive composition containing a non-halogen, non-intumescent flame-retardant system comprising at least one flame-retardant agent with the provisos that the flame-retardant system does not comprise Sb.sub.2 O.sub.3 or does not consist only of alumina trihydrate.Type: GrantFiled: November 27, 1995Date of Patent: February 8, 2000Assignee: 3M Innovative Properties CompanyInventors: Petra Nowak, Robert D. Waid, William D. Coggio
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Patent number: 5998576Abstract: This invention provides a rosin-based molecular crystal formed from the following component A and component B:Component A: dehydroabietic acid or a rosin-based resin acid containing dehydroabietic acid as an essential constituentComponent B: at least one rosin-based resin acid alkali metal salt selected from the class consisting of lithium, sodium and potassium salts of said component A,a polyolefin resin nucleating agent comprising the rosin-based molecular crystal, a polyolefin resin composition comprising the nucleating agent and if desired a calcium compound, and a molded article obtainable by molding the resin composition.Type: GrantFiled: April 8, 1998Date of Patent: December 7, 1999Assignee: New Japan Chemical Co., Ltd.Inventors: Kiyoshi Sadamitsu, Masahide Ishikawa, Toshiaki Kobayashi
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Patent number: 5981631Abstract: The within invention is directed at a composite material comprising a product of a combination of materials. The combination of materials comprises an organic filler comprised of cellulosic material, a thermoplastic polymer having a melt temperature of less than the char temperature of the organic filler and a coupling agent comprised of at least one fatty acid having at least 16 carbon atoms and at least one rosin acid having at least 16 carbon atoms. The within invention is further directed at a process for producing the composite material comprising the step of combining the organic filler, the thermoplastic polymer and the coupling agent at a temperature of greater than or equal to the melt temperature of the thermoplastic polymer and less than the char temperature of the organic filler.Type: GrantFiled: June 25, 1997Date of Patent: November 9, 1999Assignee: Wood Composite Technologies Inc.Inventors: Clifford P. Ronden, Joseph C. Morin
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Patent number: 5981649Abstract: A rubber composition suitable for use in grips of articles such as golf clubs, tennis rackets, bicycles and tools, comprising (1) a rubber component containing an ethylene-propylene-diene rubber (EPDM), and (2) 5 to 100 parts by weight of a polyisobutylene having a viscosity average molecular weight of 6,000 to 50,000, which provides grips having good feeling of touch, good non-slipping properties in both fine and rainy weather, and giving a small feeling of impact to mis-shot of golf balls as compared with conventional grips.Type: GrantFiled: May 19, 1993Date of Patent: November 9, 1999Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Hidenori Hiraoka, Akihiko Hamada
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Patent number: 5969025Abstract: The invention provides a water-based adhesive composition comprising a blend of adhesive polymers in an aqueous system, characterized in that the blend of adhesive polymers is: 20-60% by weight of an acrylic polymer having a polarity balance expressed as water absorption according to DIN 53495 of 3 to 20%; and correspondingly 40-80% by weight of a compatible tackifying resin having a degree of hydrophobicity measured as the contact angle between a dried film of the resin and a drop of distilled water of not less than 60.degree.; the percentages being based on the total of acrylic polymer plus tackifying resin expressed as dry solids. The composition shows good bond retention when wet and can be used for bonding polar substrates such as cellulose and non-polar substrates such as polyolefin. When used to bond a water absorbing substrate such as cellulose, the adhesive should have a viscosity of 200 mPas or less.Type: GrantFiled: February 29, 1996Date of Patent: October 19, 1999Assignee: The Procter & Gamble CompanyInventor: Italo Corzani
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Patent number: 5962564Abstract: A method for producing a fast drying high solids adhesive wherein a water based polymer emulsion (latex) is modified with unemulsified elasticizing oils and reinforcing-tackifying resins to produce a stable emulsion of polymer, oil and resin without the use of additional emulsifiers or volatile organic solvents. When packaged in pressurizable canisters along with a suitable propellant, the adhesive may be sprayed through a suitable nozzle and deposited in a thin layer to form an adhesive film which has excellent bonding characteristics for many laminates such as fabric or textiles, wood, plastics, metals and rubber, and for adhering flooring materials such as carpet, linoleum, tiles and artificial grass to a variety of substrates.Type: GrantFiled: April 8, 1998Date of Patent: October 5, 1999Assignee: XL CorporationInventors: John W. Braud, Helen Grace Gilbreath
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Patent number: 5959010Abstract: Reduction of dust formation for particleized resin is achieved by adding low density high molecular weight polyethylene to molten resin at a temperature and under conditions sufficient to cause the polyethylene to become dispersed within the resin. The resin/polyethylene mixture is then formed into solid particles. The addition of low density, high molecular weight polyethylene significantly reduces the generation of dust during handling, such as in the particleizing and packaging stages of the manufacturing process, while providing resin particles with higher effective softening points as compared to resin particles augmented with polyethylene wax.Type: GrantFiled: April 30, 1997Date of Patent: September 28, 1999Assignee: Arizona Chemical CompanyInventor: Robert W. Schluenz
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Patent number: 5952412Abstract: The present invention relates to rubber pellets made of an amount of vulcanized rubber and an amount of binder, with the vulcanized rubber preferably being discarded rubber. Additionally, the rubber pellets will preferably contain an amount of filler materials which are plastic or rubber or combinations thereof so that the preferred rubber pellet contains an amount of rubber equal to between about 50% and about 95% by weight of the rubber pellet, an amount of filler material equal to between about 0 and about 45% by weight of the rubber pellet, and an amount of binder equal to between about 5% and about 10% by weight of the rubber pellet. The rubber pellets are used in the formation of asphalt and are desirable because they provide necessary constituents to the asphalt and allow for elimination of equipment and separate ingredient addition steps from the asphalt formation process. The present invention is also desirable because it provides for a way to desirably dispose of waste rubber materials.Type: GrantFiled: March 19, 1998Date of Patent: September 14, 1999Assignee: Green Edge Enterprises, L.L.C.Inventors: Lee M. Greenberg, Judy A. Smith
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Patent number: 5945472Abstract: A highly filled surface covering, preferably a floor covering and more preferably a floor tile, includes a resin layer which has about 80% to about 95% by weight of filler and a chlorine-free binder. The binder includes a mixture of a maleic anhydride grafted polyethylene and a substantially linear ethylene/octene copolymer. The ratio of maleic anhydride grafted polyethylene and ethylene/octene copolymer is from about 1:5 to about 1:15 by weight. The preferred formulation for the binder includes a solid tackifier selected from the group consisting of a hydrocarbon resin having an ester moiety and hydrogenated aromatic resin.Type: GrantFiled: February 16, 1998Date of Patent: August 31, 1999Assignee: Armstrong World Industries, Inc.Inventors: Chau H. Duong, Harry D. Ward, Lowell E. West
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Patent number: 5942569Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.Type: GrantFiled: August 31, 1998Date of Patent: August 24, 1999Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
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Patent number: 5939483Abstract: A hot melt useful for packaging comprising a) from about 10% to about 40% by weight of a block copolymer; b) up to about 20% of a compatible polymer wherein the total polymer content does not exceed 40% by weight; c) from about 25% to about 60% by weight of at least one tackifying resin; d) from about 5% to about 25% by weight of a compatible plasticizer; and e) from about 10% to about 40% by weight of at least one wax component wherein the viscosity of the hot melt adhesive is less than about 1500 cPs at about 150.degree. C.Type: GrantFiled: July 14, 1997Date of Patent: August 17, 1999Assignee: H.B. Fuller Licensing & Financing, Inc.Inventor: Michelle C. Kueppers
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Patent number: 5932648Abstract: A low viscosity, low VOC content fumigation adhesive formulation which is comprised ofa) 100 parts by weight (pbw) of a blend of a styrene-diene triblock copolymer, hydrogenated or unhydrogenated, having a weight average molecular weight of 30,000 to 200,000 and a polystyrene content of from 10 to 40% by weight of the polymer, and a styrene-diene diblock copolymer having a weight average molecular weight of 10,000 to 40,000 and a polystyrene content of from 10 to 40% by weight of the polymer, wherein the diblock comprises from 60 to 95% by weight of the polymer blend,b) 75 to 275 parts by weight (pbw) of a tackifying resin which is compatible with the diene blocks, andc) 50 to 200 parts by weight (pbw) of a solvent for the polymer.Type: GrantFiled: September 11, 1996Date of Patent: August 3, 1999Assignees: Shell Oil Company, AC ProductsInventors: James Louis Troska, Larry McArthur Kegley, William Brian Dances
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Patent number: 5925459Abstract: Use of a transparent grip tab for a strip of adhesive film for a temporary bond based on thermoplastic rubber and tackifier resins, where the adhesive film is of high elasticity and low plasticity and where the adhesion is lower than the cohesion, the adhesion largely disappears when the film is extended, the ratio of peel force to tear load is at least 1:1.5, and where an adhesive bond produced therewith can be detached by pulling on the adhesive film in the direction of the bond plane.Type: GrantFiled: July 1, 1997Date of Patent: July 20, 1999Assignee: Beiersdorf AGInventors: Dieter Zimmermann, Bernd Luhmann
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Patent number: 5912295Abstract: This invention relates to a removable grade hot melt pressure sensitive adhesive comprising from about 5% to about 30% by weight of the adhesive of a block copolymer having styrene endblocks and ethylene/butylene or ethylene/propylene midblocks and having a coupling efficiency of less than about 65% and a melt index of greater than about 20 grams/10 minutes; from about 10% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%; from about 20% to about 60% by weight of the adhesive of a tackifying resin and from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil.Type: GrantFiled: October 24, 1997Date of Patent: June 15, 1999Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Susan T. Oeltjen, Jeffrey S. Lindquist
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Patent number: 5910527Abstract: A hot melt construction adhesive having a high acid number and which possesses superior properties for the construction of disposable soft goods. The adhesive composition includes an A-B-A block copolymer; a resin; a compatible mineral oil; and an antioxidant; and wherein the hot melt construction adhesive has a viscosity of less than 10,000 cP at 325.degree. F., a melting point of less than 190.degree. F., and an acid number of greater than 30.Type: GrantFiled: August 19, 1997Date of Patent: June 8, 1999Assignee: Ato Findley, Inc.Inventors: Mark D. Alper, Diane Strelow
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Patent number: 5902849Abstract: A filling compound for electrical and optical equipment in the form of cables, connectors, plugs etc. and to assemblies thus produced, is provided. Electrical and optical equipment in the form of cables, connectors, plugs etc. have to be protected against harmful influences penetrating from outside, particularly water, and also against mechanical damage during laying or as a result of exposure to heat. The filling compound is based on a stellate substance, i.e. a substance having a branched molecular structure in which, ideally, 3 or more branches, more particularly polymeric chains, radiate from a single branching point. The filling compound is flexible at very low temperatures but, on the other hand, does not run out, even at extremely high temperatures.Type: GrantFiled: November 12, 1996Date of Patent: May 11, 1999Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Reimar Heucher, Juergen Wichelhaus, Johannes Andres
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Patent number: 5869562Abstract: This invention relates to an envelope coated with a hot melt pressure sensitive adhesive composition preferably comprising a) from about 10% to about 40% by weight in the adhesive of at least one block copolymer selected from the group consisting of styrene-isoprene-styrene block copolymers, styrene-butadiene-styrene block copolymers and mixtures thereof wherein the block copolymers comprise from about 15% to about 35% styrene by weight in the copolymer and diblock contents from about 0% to about 90% by weight in the copolymer; and b) from about 60% to about 90% by weight in the adhesive of a modifier selected from the group consisting of solid tackifying resins, liquid tackifying resins, liquid elastomers and mixtures thereof. The invention further relates to an improved oil-free pressure sensitive adhesive that is low in viscosity and provides a destructive bond and resists deformation of high density spun polyolefin materials.Type: GrantFiled: March 28, 1997Date of Patent: February 9, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Jeffrey S. Lindquist, Janelle C. Cameron, Eugene R. Simmons
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Patent number: 5869555Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.Type: GrantFiled: November 18, 1996Date of Patent: February 9, 1999Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
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Patent number: 5856386Abstract: A crystalline thermoplastic resin composition comprises a rosin acid metallic salt and a crystalline thermoplastic resin. Optionally, a compatibilizing agent may also be included. The rosin acid metallic salt, which acts as a crystal nucleating agent, increases the crystallization rate of the crystalline thermoplastic resin and enables the formation of fine crystals of the resin. Thus, the crystalline thermoplastic resin composition can crystallize at a high rate, and provide molded articles having excellent mechanical properties and/or optical properties.Type: GrantFiled: January 22, 1997Date of Patent: January 5, 1999Assignees: Mitsui Petrochemicals Industries, Ltd., Arakawa Chemical Industries, Ltd.Inventors: Hideki Sakai, Mikio Nakagawa, Tetsuji Kasai, Kimio Ueda, Masao Maeda, Yukiharu Yamada, Hiroyuki Hori, Junji Tan, Kan Matsumoto
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Patent number: 5840797Abstract: A light weight, vibration-damping composition having effective amounts of at least one butyl rubber, at least one tackifying resin, at least one pigment and substantially spherical microspheres is disclosed. The present composition has a specific gravity of about 1.0 to 1.2 and has effective damping effects at low temperatures as well as temperatures up to about 60.degree. C. This composition is effective for use in the transportation industry, the building industry, the aerospace industry and the appliance industry.Type: GrantFiled: September 16, 1996Date of Patent: November 24, 1998Assignee: H. B. Fuller Licensing & Financing, Inc.Inventor: Raj V. Singh
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Patent number: 5837762Abstract: The present invention refers to polymer latex compositions, such as, for example, styrene-butadiene-based or styrene-acrylate-based latices, prepared with sulfur- and halogen-free chain transfer agents, wherein the sulfur- and halogen-free chain transfer agents are abietic acid-containing rosins, such as abietic acid-containing gum rosin. The polymer latex compositions of the present invention exhibit surprisingly high binding strength despite high gel content, and a balanced application profile of paper gloss, ink gloss and ink set-off properties. The polymer latex compositions of the present invention further exhibit the advantage of being of less odor than typical latex-based paper coating compositions.Type: GrantFiled: January 4, 1996Date of Patent: November 17, 1998Assignee: The Dow Chemical CompanyInventors: Friederike Theresia Stollmaier, Dominik Martin Elsaesser, Pekka Johannes Salminen
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Patent number: 5807918Abstract: The invention describes both a method for bonding at least two elastomeric substrates together, wherein one of the substrates is a tire casing and another substrate is a tire tread, and an aqueous color changeable adhesive for effecting the bonding. The method includes the steps of buffing at least one surface of at least one of the substrates to an RMA 2 or RMA 3, applying the color changeable aqueous adhesive to the at least one surface, drying the adhesive for at least a period of time to permit an initial light grey color of the adhesive as applied to change to a flat black, and contacting the substrates under pressure to bond the substrates together. The color changeable aqueous adhesive includes at least a rubber latex emulsion, a tackifier, a pH adjustment agent, and a carbon black emulsion, wherein the carbon black functions both as a reinforcing agent and a visible color indicia means for evaluating the degree of dryness of the adhesive, which correlates to the degree of tack of the adhesive.Type: GrantFiled: March 26, 1996Date of Patent: September 15, 1998Assignee: Patch Rubber CompanyInventor: Marlo Carter
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Patent number: 5786418Abstract: A hot melt adhesive is described which possesses superior properties for the construction of disposal soft articles and more specifically disposable soft articles which may be exposed to moisture for prolonged periods of time. The adhesive composition includes about 10% to about 60% by weight of a butene-1-ethylene copolymer; about 20% to about 80% by weight of a tackifying resin; about 5% to about 30% by weight of a plasticizer; and about 0.1% to about 3% by weight of an antioxidant, wherein the ingredients total 100%, by weight, of the entire adhesive composition.Type: GrantFiled: July 3, 1996Date of Patent: July 28, 1998Assignee: Findley Adhesives, Inc.Inventors: Diane Strelow, Mark Alper
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Patent number: 5777013Abstract: The specification discloses elastomeric compositions and methods for making elastomeric compositions containing silica. The elastomeric composition comprises an elastomeric matrix containing from about 1 to about 40 wt. % silica and from about 0.1 to about 20 wt. % of an additive selected from the group consisting of rosin acid or fatty acid monoesters of glycerol and block copolymers having at least one A-block derived from the group consisting of rosin acids and fatty acids and a B-block having a number average molecular weight in the range of from about 200 to about 2500 daltons derived from the group consisting of a polyethylene glycol (PEG) and a polyepichlorohydrin (PECH) polyol. The additive provides substantial improvement in the dispersion and adhesion of silica in the elastomeric matrix which substantially improves the strength and other properties of the material.Type: GrantFiled: January 24, 1997Date of Patent: July 7, 1998Assignee: Arizona Chemical CompanyInventors: Eric S. Gardiner, Xinya Lu
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Patent number: 5773506Abstract: The present invention provides a block copolymer pressure sensitive adhesive (PSA) composition. The block copolymer has at least one midblock segment and at least one endblock segment. The midblock comprises a polymerized conjugated diene segment or hydrogenated derivative thereof. The endblock comprises a polymerized monovinyl aromatic segment having a number average molecular weight less than about 8,000. The PSA further comprises at least one tackifier or oil that is compatible with the low molecular weight endblock segment of the block copolymer. The PSA composition of the invention has a reduced elastic index and is capable of dissipating stress. This is useful in providing tapes which are capable of withstanding stresses such as those caused by temperature fluctuations, dimensional changes in the backing, or the recovery forces of a backing applied under tension. The present invention also provides a method of reducing the elastic index of a block copolymer PSA composition.Type: GrantFiled: December 9, 1996Date of Patent: June 30, 1998Assignee: Minnesota Mining and ManufacturingInventors: Mark K. Nestegard, Jingjing Ma
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Patent number: 5763516Abstract: Hot-melt adhesive compositions useful for packaging are disclosed. These hot-melt adhesive compositions are based on modified polyethylene and contain a linear, low density copolymer or terpolymer of ethylene and another alpha-olefin, a polyethylene graft copolymer, a tackifying resin, and a high-melting low viscosity wax. The hot-melt adhesive compositions disclosed herein produce very good adhesive bonds, even at high speed packaging conditions under a broad range of ambient packaging temperatures. These inventive adhesive compositions have a novel combination of good hot tack and good adhesive bond properties, even at extreme conditions.Type: GrantFiled: April 24, 1996Date of Patent: June 9, 1998Assignee: H.B. Fuller Licensing & Financing, Inc.Inventor: Darryl Aubrey Godfrey
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Patent number: 5750607Abstract: Hot melt adhesive compositions, comprising(a) a radial multiarmed block copolymer (AB).sub.n X, wherein A is a block predominantly derived from a monovinylaromatic compound, B is a block predominantly derived from butadiene and which optionally has been partially or completely hydrogenated,X is the residue of a multifunctional coupling agent,n is in the range of from 3 to 6,(b) a linear block copolymer AB, the components (a)+(b) being present in an amount of 100 parts by weight,(c) a tackifying resin, which is compatible with the blocks B, in an amount of from 100 to 500 parts by weight,(d) a plasticizer in an amount of from 100 to 300 parts by weight,(e) an antioxidant-UV stabiliser in an amount from 0.Type: GrantFiled: March 6, 1997Date of Patent: May 12, 1998Assignee: Shell Oil CompanyInventors: Eric-Jack Gerard, Noel Raymond Maurice De Keyzer, Birgitte Maria Ludovica Christine Van De Vliet
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Patent number: 5741840Abstract: A hot melt pressure sensitive adhesive comprising a) from about 15% to about 30% by weight of a linear styrene-ethylene/butylene-styrene copolymer having a styrene content from about 15% to about 35% by weight and a coupling efficiency of less than about 75%; b) from about 20% to about 50% by weight of a tackifying resin selected from the group consisting of those tackifying resins having a softening point of less than about 100.degree. C.; c) from about 30% to about 50% by weight of a plasticizing oil; and d) up to about 15% of a compatible polymer wherein the total polymer content does not exceed 30% by weight of the adhesive wherein the hot melt pressure sensitive adhesive fails cohesively during use.Type: GrantFiled: July 3, 1996Date of Patent: April 21, 1998Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Jeffrey S. Lindquist, Lisa L. Ryan
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Patent number: 5728759Abstract: New water base pressure sensitive adhesives with capability of use in production of high temperature quality masking tape are aqueous dispersions of the following mixture of components in the percentages by weight as specified:______________________________________ Component Percentage ______________________________________ Adhesive entity 45 to 65 Tackifier resin 20 to 40 Plasticizer 1 to 20 Stabilizer 0.1 to 10 Curing entity 0.1 to 10 Optional additives 0 to 20 ______________________________________The various components constitute the disperse phase of the aqueous dispersion and have a combined weight of between about 30 to 70% of the total weight, the curing entity is a combination of a plurality of curing agents that exhibit different curing speeds and the adhesive entity is a combination of a plurality of adhesive elastomers having different molecular weights.High temperature quality masking tapes made from the new PS adhesives avoid "freeze down" and "ghosting".Type: GrantFiled: August 15, 1995Date of Patent: March 17, 1998Inventor: Charles O. Pike
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Patent number: 5721302Abstract: A high shear strength, solvent-free water-based adhesive composition for removably fixing flooring materials which includes a major amount of an aqueous latex dispersion of a polymer latex base material with an optional minor amount of polyether or polyester-polyurethane synthetic resin, an amount of rosin acid ester hardener, an amount of a thickener together with an amount of inert filler and an amount of a plasticizer/extender in sufficient water to adjust the percent solids to the desired amount.Type: GrantFiled: September 17, 1996Date of Patent: February 24, 1998Inventors: Benny R. Wood, Howard Burchett, Jr.
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Patent number: 5703153Abstract: An adhesive composition is comprised of a mixture of an EVA copolymer and two tackifying resins, a high temperature tackifying resin and a low temperature tackifying resin. The viscosity of the adhesive composition is between 2,000 cps to 80,000 cps over a temperature range of 250.degree. F. to 380.degree. F. The composition comprises 60% by weight of the copolymer, 15% by weight of the low temperature tackifying resin and 25% by weight of the high temperature tackifying resin.Type: GrantFiled: November 7, 1994Date of Patent: December 30, 1997Assignee: Uniplast, Inc.Inventor: Elias Shukri Maayeh
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Patent number: 5698620Abstract: The present invention relates to rosinate esters of N-hydroxyphenyl maleamic acid which are useful as a total or partial replacement for extender or processing oil in rubber formulations. Addition of these rosinate esters improve the modulus and tear of the vulcanizate.Type: GrantFiled: December 27, 1996Date of Patent: December 16, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, Raymond Benjamin Roennau, Denise Jeannette Keith
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Patent number: 5652298Abstract: The present invention provides an organic solvent-free composition useful as an adhesive for bonding natural rubber compounds, synthetic rubber compounds and a combination of natural and synthetic rubber compounds.Type: GrantFiled: July 24, 1996Date of Patent: July 29, 1997Assignee: Akron Paint & VarnishInventor: Robert Murray
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Patent number: 5652288Abstract: A rapid hardening, solvent-free water-based adhesive composition includes an amount of an aqueous latex dispersion of polyester-polyurethane synthetic resin, an amount of rosin acid ester hardener, an amount of a thickener together with an amount of inert filler and an amount of a plasticizer/extender in sufficient water to adjust the percent solids to the desired amount. Optionally, the adhesive composition also includes an amount of polyisocyanate cross-linker to provide additional environmental stability.Type: GrantFiled: April 19, 1996Date of Patent: July 29, 1997Inventors: Benny R. Wood, Howard Burchett, Jr.
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Patent number: 5635266Abstract: Vinyl heat welding rod for seam sealing vinyl resilient flooring, whether in sheet or tile form, are used to obtain a homogeneous, monolithic appearing surface. This rod is specifically made to duplicate the appearance of the flooring material. For a chip-image flooring structure, a sheet of multicolored chips having a similar, but different formulation from that of the flooring material is prepared and the sheet is cut into suitable strips, heat pressed in a rod mold, end adhered or further molded to form the desired length, and used as a vinyl heat welding rod for sealing seams in flooring. Thus, the chip pattern is evident in the seam area and does not appear different when compared to the adjacent surface.Type: GrantFiled: November 16, 1992Date of Patent: June 3, 1997Assignee: Armstrong World Industries, Inc.Inventors: Edwin J. Quinn, Manuel A. Velez, Richard M. Ringer, Michael E. Buckwalter
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Patent number: 5627234Abstract: A block copolymer composition is disclosed which derives from the copolymerization of a monoalkenyl-arene and a conjugated diene having from 4 to 5 carbon atoms, and comprising:from 30% to 55% by weight, preferably from 34% to 50%, of non-coupled linear structures;from 25% to 40% by weight, preferably from 30% to 35% by weight, of coupled linear structures;from 20% to 40% by weight, preferably from 24% to 35% by weight, of branched structures.The preparation of said composition and its use in the formulation of adhesive tapes and labels are disclosed as well.Type: GrantFiled: March 30, 1995Date of Patent: May 6, 1997Assignee: Enichem Elastomeri S.r.l.Inventors: Sergio Giordano, Antonio Gurnari, Carla Parodi, Giantommaso Viola
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Patent number: 5624986Abstract: The novel adhesives of this invention contain a blend of components that result in the adhesive having a physical property that changes at a controlled rate as a function of time after application until it reaches a final equilibrium value.The adhesives can contain a thermoplastic polymer base, a tackifying resin, and an aromatic plasticizer optionally in combination with other ingredients. The plasticizer tackifier combination is chosen such that the tackifier/plasticizer interaction causes the initial value of the physical property after application to change, at a controlled rate, to a final equilibrium level.Type: GrantFiled: October 17, 1995Date of Patent: April 29, 1997Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: William L. Bunnelle, Christopher M. Ryan
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Patent number: 5618883Abstract: A hot melt pressure sensitive adhesive composition comprising a tackified ethylene-propylene rubber modified with a copolymer of a styrene ethylene-propylene block copolymer and/or a styrene ethylene -butylene block is provided. The pressure sensitive adhesive exhibits high cohesive strength and adhesion to polar and apolar surfaces.Type: GrantFiled: June 7, 1995Date of Patent: April 8, 1997Assignee: Avery Dennison CorporationInventors: Sebastian S. Plamthottam, Ramon Roman, John Landers, Roger H. Mann, Karl Josephy, Ronald Ugolick
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Patent number: 5614577Abstract: There are provided a pressure-sensitive adhesive and other compositions which free radical cured mixtures of at least one unsaturated elastomeric polymer and at least one organic additive which is substantially nonresponsive to action of free radicals and present in an amount sufficient to modify the properties of the cured elastomeric polymer.Type: GrantFiled: April 11, 1994Date of Patent: March 25, 1997Assignee: Avery Dennison CorporationInventors: Yukihiko Sasaki, Kevin Lossner
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Patent number: 5614576Abstract: The present invention provides pressure sensitive adhesives, compositions from which the pressure sensitive adhesives are formed, and articles having therein these pressure sensitive adhesives. The pressure sensitive adhesives, which have a Tg of less than about 20.degree. C., include a poly(.beta.-hydroxyorganoate) or mixture thereof. Preferably, these poly(.beta.-hydroxyorganoate)s include monomeric units of the general formula: ##STR1## wherein: a minor amount (preferably no greater than about 20 mole percent) of the monomeric units have an R group containing 1-3 carbon atoms; and a major amount (preferably at least about 80 mole percent) of the monomeric units have an R group containing 4-30 (preferably 4-20) carbon atoms.Type: GrantFiled: April 15, 1996Date of Patent: March 25, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Denise R. Rutherford, W. James Hammar, Gaddam N. Babu
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Patent number: 5604277Abstract: A dry liquid concentrate mixture is disclosed comprising crumb rubber particles and tall oil, tall oil derivatives or other fatty acids, which may be enhanced by other components, such as modifiers, for use to enhance the properties of parent materials, such as thermoplastic compounding and coatings and elastomers and recycles and asphalt and epoxies and aliphatic urethane.Type: GrantFiled: February 21, 1995Date of Patent: February 18, 1997Assignee: Encore Technologies, Inc.Inventor: John D. Osborn
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Patent number: 5596028Abstract: An anaerobic adhesive which undergoes setting only by attaching it to an article without applying any special energy, and an anaerobically setting adhesive sheet prepared by coating or impregnating a sheet with the above anaerobic adhesive and well-balanced between storage stability and setting properties, the anaerobic adhesive comprising;(A) a rubber-based resin having adhesion properties,(B) a compound which has both the capability of absorbing oxygen and the capability of forming peroxide, and which shows an oxygen absorption amount of 0.1 to 3.0% (weight of absorbed oxygen/weight) and an active oxygen amount of 0.01 to 1.0% (weight of active oxygen/weight),(C) an ethylenically unsaturated monomer or oligomer, and(D) an organic peroxide.Type: GrantFiled: April 7, 1995Date of Patent: January 21, 1997Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Masato Yanagi, Satoru Kagao, Makoto Dohi, Sanae Nakaizumi
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Patent number: 5559165Abstract: A pressure sensitive hot melt adhesive comprising a block copolymer and 60 to 95 parts of a liquid diluent, the adhesive being characterized by a midblock Tg less than -10.degree. C., a G' less than 15.times.10.sup.4 dynes/cm.sup.2 at 10 rad/s, 25.degree. C., a G" of 1 to 6.times.10.sup.4 dynes/cm.sup.2 and a tensile strength greater than 10 psi exhibit superior properties, without the need for any curing operation after cooling.Type: GrantFiled: August 8, 1995Date of Patent: September 24, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventor: Charles W. Paul
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Patent number: 5550175Abstract: A solvent-free hot melt process, for preparing a non-thermosettable, pressure-sensitive adhesive from a tackified non-thermoplastic hydrocarbon elastomer. The process employs a continuous compounding device that has a sequence of alternating conveying and processing zones. The processing zones masticate and mix materials in them. Non-thermoplastic elastomers having high molecular weight may be readily compounded into adhesives in the process.Type: GrantFiled: May 5, 1995Date of Patent: August 27, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Timothy D. Bredahl, Harold Leverty, Robert L. Smith, Richard E. Bennett, David J. Yarusso, Daniel C. Munson, Anthony R. Plepys
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Patent number: RE35621Abstract: A method for placing hydrophobic polyolefin fiber in condition for cutting, carding and production of nonwoven material without substantial sacrifice in desired hydrophobic properties in the corresponding nonwoven, by utilization of a sequential treatment of the fiber with a neutralized phosphoric acid ester and a polysiloxane of defined classes.Type: GrantFiled: June 7, 1995Date of Patent: October 7, 1997Assignee: Hercules IncorporatedInventor: A. Chandler Schmalz
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Patent number: RE36458Abstract: Vinyl heat welding rod for seam sealing vinyl resilient flooring, whether in sheet or tile form, are used to obtain a homogeneous, monolithic appearing surface. This rod is specifically made to duplicate the appearance of the flooring material. For a chip-image flooring structure, a sheet of multicolored chips having a similar, but different formulation from that of the flooring material is prepared and the sheet is cut into suitable strips, heat pressed in a rod mold, end adhered or further molded to form the desired length, and used as a vinyl heat welding rod for sealing seams in flooring. Thus, the chip pattern is evident in the seam area and does not appear different when compared to the adjacent surface.Type: GrantFiled: August 15, 1997Date of Patent: December 21, 1999Assignee: Armstrong World Industries, Inc.Inventors: Edwin J. Quinn, Manuel A. Velez, Richard M. Ringer, Michael E. Buckwalter
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Patent number: RE36618Abstract: Polychloroprene latex adhesive compositions which comprise a) mercaptan-modified or xanthogen disulfide-modified 2-chloro-1,3-butadiene homopolymers having gel contents of 5-.[.70.]..Iadd.78.7 .Iaddend.percent by weight, b) 1 to 75 parts by weight of rosin per 100 parts by weight of a), and c) sufficient water to provide a solids content of 25-65 weight percent based on the weight of component a) exhibit excellent heat resistance and green bond strength.Type: GrantFiled: November 26, 1997Date of Patent: March 14, 2000Assignee: DuPont Dow Elastomers, L.L.C.Inventors: Lance Alan Christell, Richard Misak Tabibian