Abstract: Polyhydric alcohol rosin esters which had been modified with an aromatic dibasic acid such that the softening point of the acid-modified polyhydric alcohol rosin ester is higher than that of a comparable unmodified polyhydric alcohol rosin ester are used as tackifiers in hot melt adhesive compositions. The hot melt adhesives compositions which utilize the acid-modified rosin ester tackifiers contain at least one of an ethylenic copolymer and a styrenic block copolymer, at least one of a wax and an oil, and the acid-modified polyhydric alcohol rosin ester tackifier. The hot melt adhesive compositions may be used as, for example, hot melt carton and package sealing adhesives, sealants, bookbinding adhesives, assembly adhesives, and are useful for the assembly of disposable articles using multiline construction techniques wherein at least one polyethylene or polypropylene substrate is bonded to at least one tissue, non-woven, polyethylene or polypropylene substrate.

Abstract: The present invention relates to bis-amide linked rosin acid derivatives which are useful as a rubber additive. In one embodiment, the amide linked rosin acid derivative may serve as a total or partial replacement for antiozonants. The bis-amide linked rosin acids are prepared by reacting abietic acid and/or dehydroabietic acid with a diamine under amidation conditions.

Abstract: There are provided a pressure-sensitive adhesive and other compositions which free radical cured mixtures of at least one unsaturated elastomeric polymer and at least one organic additive which is substantially nonresponsive to action of free radicals and present in an amount sufficient to modify the properties of the cured elastomeric polymer.

Abstract: A terminal-modified block copolymer having the remainder of an amino group or imido group-containing a terminal-treating agent bonded to the polymer terminal which is obtained by treating the active terminal of a block copolymer comprising conjugated dienes and vinylaromatic hydrocarbon compounds, which is obtained by using as the polymerization initiator at least one member selected from alkali metals or organoalkali metals and has a vinylaromatic hydrocarbon content of 5 to 95% by weight and a number average molecular weight of 5,000 to 1,000,000 with at least one terminal-treating agent selected from imide compounds, cyanamide compounds, aziridinyl compounds, amide compounds, or tertiary amino group-containing compounds other than the compounds.

Abstract: Pressure-sensitive adhesive compositions and an improved refastenable tape closure system comprising a release tape and a fastening tape wherein the fastening tape has a balance of properties such that the tape exhibits a maximum in the peel force between peel rates of 10 cm./minute and 400 cm./minute when peeled from a polyolefin substrate as found in disposable diaper back sheets are disclosed. The adhesive of the fastening tape comprises a specific range of compositions including an elastomeric component based on an A-B-A block copolymer wherein the A blocks are derived from styrene or alphamethylstyrene and the B block are derived from isoprene, butadiene, or hydrogenated versions of these or an (AB) block copolymer of the same type of composition in another geometry such as a tapered block copolymer or a radial block copolymer, a solid tackifier resin, a liquid tackifier resin, and an end block reinforcing resin.

Abstract: A cured composition possessing excellent cohesive strength at high temperatures along with excellent adhesion, shear strength and solvent resistance is prepared by the high energy ionizing radiation initiated curing of a polymer composition comprising an alkenyl arene/conjugated diene block copolymer and a oligomer such that the unsaturation index of the composition is minimized. The radiation initiated curing of the adhesive composition is accomplished without requiring the aid of a coupling agent to promote crosslinking of the block copolymer during exposure to the radiation.

Abstract: There are provided a pressure-sensitive adhesive which are free radical cured mixtures of at least one unsaturated elastomeric polymer and at least one organic additive which is substantially nonresponsive to action of free radicals and present in an amount sufficient to modify thr properties of the cured elastomeric polymer which mixture prior to cure has a viscosity of less than about 30 Pascal-seconds at a hot melt application temperature less thant 175.degree. C.

Abstract: A non-toxic rubber-based composition for use in manufacturing toys which contains styrene butadiene rubber, naphthene oil, ester gum, calcium carbonate and a coloring agent, and a method for making same.

Abstract: The composite articles of this invention can be made more efficiently through the use of a single adhesive having sufficient resistance to creep, sufficiently high bond strength, and a viscosity that is controllable through a range permitting it to be used for elastic attachment and in fine line, multi-line extrusion or sprayed adhesive preparation techniques.

Abstract: The present invention relates to alkyl (C.sub.6 -C.sub.22) amides of rosin acids which are useful as a total or partial replacement for extender or processing oil in rubber formulations. Addition of the alkyl (C.sub.6 -C.sub.22) amides of rosin acid also significantly reduce rheometer t25 and t90 values.

Abstract: Rosin esters are used to reduce the tendency of shaped articles made from polypropylene, especially fibers, to form malodorous decomposition products upon sterilization by gamma-irradiation. Other stabilizers normally used to prevent discoloration and degradation of polyolefins may also be present. Stabilized fibers are used for the manufacture of disposable medical products.

Abstract: Hot melt adhesive compositions for bonding rigid polypropylene substrates comprise intimate blends of an amorphous copolyolefin copolymer, a polyolefin wax, a rosin-based ester resin and a polybutylene copolymer.

Abstract: Hot-melt adhesives, useful for both glue-port and glue-gun applications, are formulated so that they can be applied at temperatures no higher than 280.degree. F. and preferably at temperatures of at most 250.degree. F. The adhesive compositions have a heat resistance of at least 125.degree. F. and are readily shaped into glue sticks for use in glue guns. The adhesive for the hot-melt adhesive compositions is suitably compounded with tackifyin resin and/or wax. The resulting composition has a shape viscosity profile, which is readily achieved, e.g., by using a high melt index adhesive polymer as an essential component.

Abstract: The present invention relates to alkyl (C.sub.12 -C.sub.22) esters of rosin acids which are useful as a total or partial replacement for extender or processing oil in rubber formulations. Addition of the alkyl (C.sub.12 -C.sub.22) esters of rosin acid improve the tear of the vulcanizate.

Abstract: Synthetic polyethylene wax having low molecular weight of 250 to 3000 and a density of 0.930 to 0.950 is prepared in a high pressure process at pressures of at least 800 bar using a carbonyl compound such as acetaldehyde as chain transfer agent. The resulting wax with incorporated CO has good compatibility in hot melt systems, and may be stripped to remove light ends, increase density and crystallinity and improve thermal stability.

Abstract: A layer for preventing sticking of thermal image-forming materials to thermal printheads during thermal printing. The layer comprises polymeric material having a non-cyclic, substantially completely saturated hydrocarbon backbone, said backbone having substantially only hydrogen atoms and methyl groups attached to randomly positioned carbon atoms thereon, with no more than one methyl gorup attached to any one backbone carbon atom. Application of the anti-stick layer to the substrate is facilitated by the solubility of the polymeric material in commonly used organic solvents, thereby allowing very thin layers of the coating to be applied in the form of dilute solutions.

Abstract: Pressure-sensitive adhesive compositions and an improved refastenable tape closure system comprising a release tape and a fastening tape wherein the fastening tape has a balance of properties such that the tape exhibits a maximum in the peel force between peel rates of 10 cm./minute and 400 cm./minute when peeled from a polyolefin substrate as found in disposable diaper back sheets are disclosed. The adhesive of the fastening tape comprises a specific range of compositions including an elastomeric component based on an A-B-A block copolymer wherein the A blocks are derived from styrene or alphamethylstyrene and the B blocks are derived from isoprene, butadiene, or hydrogenated versions of these or an (AB) block copolymer of the same type of composition in another geometry such as a tapered block copolymer or a radial block copolymer, a solid tackifier resin, a liquid tackifier resin, and an end block reinforcing resin.

Abstract: A resinous binder is disclosed which is composed of a metal rosin resinate and a dilution increasing effective amount of a pendant tertiary amine polymer type resin having greater than 50,000 weight average molecular weight.Also disclosed is a gravure printing ink which comprises a solvent, a colorant and a binder wherein all or a portion of the binder consists of the resinous binder of this invention. The use of the resinous binder of this invention in ink compositions results in significant dilution improvement without adversely affecting other desirable properties.

Abstract: A resinous binder is disclosed which is composed of a metal rosin resinate and a dilution increasing effective amount of polystyrene type resin having greater than 50,000 weight average molecular weight and an acid number less than 200.Also disclosed is a gravure printing ink which comprises a solvent, a colorant and a binder component wherein all or a portion of the binder component consists of the resinous binder of this invention. The use of the resinous binder of this invention in ink compositions results in significant dilution improvement without adversely affecting other desirable properties.

Abstract: The present invention relates to the use of a mixture of alkyl (C.sub.6 -C.sub.18) esters of rosin acids which are useful as a total or partial replacement for conventional waxes and diamine antidegradants in rubber formulations. Addition of the mixture of alkyl (C.sub.6 -C.sub.18) esters of rosin acid improve the weathering resistance of cured rubber compositions.

Abstract: Acrylic hot melt pressure sensitive adhesive compositions having a good balance of tack, peel and creep resistance at ambient temperature combined with optical clarity and desirable melt viscosity at elevated temperatures are prepared by copolymerizing acrylic and methacrylic alkyl esters of a non-tertiary alcohol or optionally acids with polymerizable poly methacrylate based macromonomers. The resulting acrylic copolymer has a graft or comb structure in which the acrylic backbone has a low Tg and the pendant macromonomer side chains have a Tg above room temperature.Compounding these acrylic copolymers with tackifiers and plasticizers dramatically improves the balance of pressure sensitive adhesive properties while lowering melt viscosity into a desirable range. The invention provides significant property enhancements even for acrylic copolymers having poor initial peel and shear adhesive properties.

Abstract: The present invention relates to amide linked rosin acid derivatives which are useful as a total or partial replacement for extender or processing oil in rubber formulations. The amide linked rosin acid derivatives improve Strebler adhesion in rubber compositions and also significantly reduce rheometer t25 and t90 values. The amide linked rosin acids are prepared by reacting abietylamine or dehydroabietylamine with abietic acid or dehydroabietic acid under amidation conditions.

Abstract: The present invention relates to a hydroformylated thermal oil which is useful as a total or partial replacement for extender or processing oil in rubber formulations. The hydroformylated thermal oil is prepared by reacting decarboxylated rosin acid with carbon monoxide and hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst and organic reaction solvent.

Abstract: A composition comprising,(a) 1 to 99 parts by weight of a specific hydrogenated product of a block copolymer having at least one polymer block composed mainly of a vinyl aromatic compound and at least one polymer block composed mainly of a conjugated diene compound, a modified product which comprises said product modified with an .alpha.,.beta.-unsaturated carboxylic acid or a derivative thereof, or a mixture of said product and said modified product, wherein the content of the vinyl aromatic compound prior to hydrogenation is 5 to 95% by weight and a content of vinyl linkages [V] prior to hydrogenation which originated from the conjugated diene compound is 10 to 80%, said product satisfying the following conditions;(1) the hydrogenated ratio [A] of the total of aliphatic double bonds which originated from the conjugated diene compound is not lower than 5% and lower than 50%, and[B]/[V].sup.

Abstract: There are provided a pressure-sensitive adhesive and other compositions which free radical cured mixtures of at least one unsaturated elastomeric polymer and at least one organic additive which is substantially nonresponsive to action of free radicals and present in an amount sufficient to modify the properties of the cured elastomeric polymer.

Abstract: There is disclosed a reaction product of a rosin acid and a polyfunctional compound having at least one functional group capable of reacting with a carboxylic acid functionality and another functional group having antidegradant properties.The reaction products of this invention can be used as antidegradants in polymeric compositions and lubricating oil compositions.

Abstract: A method for placing hydrophobic polyolefin fiber in condition for cutting, carding and production of nonwoven material without substantial sacrifice in desired hydrophobic properties in the corresponding nonwoven, by utilization of a sequential treatment of the fiber with a neutralized phosphoric acid ester and a polysiloxane of defined classes.

Abstract: The present invention relates to a two component adhesive composition containing a propylene-hexene copolymer having about 6 to less than 15 mole percent hexene and a compatible tackifying resin.

Abstract: The present invention relates to the hot melt type seal agent for adhering and sealing a head lamp of a vehicle, wherein a lens and a housing are integrally one unit. The necessary component materials of the hot melt type seal agent of the present invention include a mixture produced by butyl rubber, SEBS block copolymer and olefin with high softening point. The hot melt type seal agent of the present invention withstands temperature changes in the head lamp and the gas pressure that is filled therein. Consequently, good adhesion, waterproof and high gas-tight performances are achieved.

Abstract: There is disclosed a method for enhancing the cure of a sulfur vulcanizable elastomer which comprises adding to the vulcanizable elastomer a mixture of tall oil fatty acids comprising at least (a) from about 28% to about 55% by weight of oleic acid, (b) from about 25% to about 40% by weight of linoleic acid, (c) from about 4% to about 20% conjugated linoleic acid and (d) from about 0% to about 8% rosin acids. Use of a mixture of tall oil acids as a cure activator significantly lowers the cost of producing the vulcanizate while concomitantly improving the adhesion and dynamic properties of the elastomer.

Abstract: There is provided an electric conductive resin composition formed into a pellet, which includes an electric conductive filler comprising electric conductive fibers and a low-melting point metal, and being coated on the surface thereof with a thermoplastic resin. Flux and/or a phosphorus-based antioxidant may be added to the filler. There is also provided an electromagnetic wave shielding molded product prepared by using the electric conductive resin composition mentioned above, wherein the electric conductive fibers dispersed within the molded product are fixed each other through the low-melting point metal.

Abstract: A non-toxic rubber-based composition for use in manufacturing toys which contains styrene butadiene rubber, naphthene oil, ester gum, calcium carbonate and a coloring agent, and a method for making same.

Abstract: The polymerization of compositions containing styrene by an aqueous suspension process in which is used a suspending agents system constituted by a mineral agent and, an extending agent which is at least a rosin acid derivative (abietic acid, neoabietic acid, dextropimaric acid) or their salts of a metal belonging to Group IIa of the Periodic Classification of elements. The use of this extending agent has the advantage of ameliorate the surface aspect of moulded articles obtained from expanded polymer pearls prepared with the above polymerization process.

Abstract: Elastomer structures having exposed controlled surface release characteristics can be made by coating at least a portion of their surface with a releasing composition comprising (a) a chlorosulphonated polymer; (b) a reinforcing filler and (c) a green tackifying agent. Optionally, these compositions can also contain a chemical curing system and one or more volatile solvent/diluent viscosity-reducing vehicle. In a specific example, the coating are applied to flexible structures used in machines for the manufacture of articles having natural tack due to their rubber or elastomer content.

Abstract: An adhesive comprising a copolymer and an optionally hydrogenated light color petroleum hydrocarbon resin including an aromatic hydrocarbon component useful for tackifying block copolymers is described which has a softening point of about 0.degree. C. to about 40.degree. C., a number average molecular weight (Mn) of from 350 to 600 and a molecular weight distribution (Mw/Mn) of from 1:1 to about 2.0.

Abstract: A solvent based contact adhesive suitable for bonding cured EPDM membranes is disclosed. The adhesive includes a crosslinked halogenated butyl rubber, a low molecular weight, high softening point, thermoplastic aliphatic-type-based hydrocarbon resin and at least one organic solvent employed as a dispersion medium for the crosslinked halogenated butyl rubber and the resin. The disclosed adhesive exhibits superior heat aging and hot water immersion properties which are significant characteristics in roof applications.

Abstract: An adhesive composition comprising100 parts by weight of a block copolymer (a) containing of at least one polymer block composed mainly ofa vinyl aromatic hydrocarbon and at least one polymer block composed mainly of butadiene in which(i) the vinyl aromatic hydrocarbon content [S] is 10 to 30% by weight,(ii) the 1,2-vinyl content of butadiene portion [V] is 20 to 50%, and(iii) the relationship between said vinyl aromatic hydrocarbon content [S] and said 1,2-vinyl content of butadiene portion [V] satisfies the formula,:40.ltoreq.[S]+[V].ltoreq.7040 to 200 parts by weight of a tackifier (b), and, optionallyvarious stabilizers, and a process for producing said composition.

Abstract: An extrudable composition for forming nonwoven elastomeric material having pressure sensitive adhesive properties, nonwoven elastomeric sheet material (e.g., fibrous nonwoven webs) formed of such composition, stretch bonded laminates using such sheets, and methods of forming such sheets and such laminates, are disclosed. The composition includes an elastomeric polymer and a tackifying resin, and can also include a polyolefin. The nonwoven sheet material can be a meltblown nonwoven web. The laminate can be formed by tensioning the elastomeric sheet material and bonding a gatherable web (e.g., a spunbond polypropylene web) to the tensioned sheet material by application of pressure, the bonding being accomplished due to the adhesivity of the elastomeric sheet material and without application of heat for softening the sheet material and/or gatherable web.

Abstract: Pressure-sensitive adhesive compositions are disclosed which essentially comprise (I) a base block copolymer, (II) a resinous tackifier, (III) a selected naphthenic or paraffinic mineral oil and (IV) a selected aromatic synthetic oil. Tackiness, adhesion, cohesion and corrugated fiber board adhesiveness characteristics can be greatly improved by the addition of specified amounts of such mineral oil and aromatic oil as softeners.

Abstract: A sealant composition comprising:(a) 100 parts by weight of a silane functionalized polymer component which is prepared by reacting enough silane of the general formula R R'.sub.n SiY.sub.

Abstract: Adhesive compositions comprising tackified star block copolymer having at least 12 block copolymer arms are provided. Sheet materials coated with the adhesive composition are also provided.

Abstract: Disclosed is a hot-melt adhesive composition capable of bonding paper to metal, glass and polyethylene terephthalate comprising an amorphous polymer selected from polypropylene or copoly(propylene-butene) having a propylene content of greater than 50%, a hydrocarbon tackifier resin, and a rosin tackifier. Preferably, the composition also contains a polyethylene wax.

Abstract: A coating material for protecting the surfaces of teeth is obtained by dissolving a resinous composition comprising 100 weight parts of a polystreyene resin or a high-impact polystyrene resin and 1 to 60 weight parts of rosin or a rosin derivative added thereto in an organic solvent. The resinous composition may further contain 1 to 100 weight parts of a chlorinated polymer and 1 to 100 weight parts of a coloring matter.

Abstract: A polyurethane adhesive comprising(a) a thermoplastic polyester urethane rubber which is grafted with at least one of the compounds selected from the group consisting of acrylic acid, an acrylic ester, methacrylic acid and a methacrylic ester,(b) a chlorinated rubber, and(c) an isocyanate compound as a crosslinking agent, and optionally(d) a polyoxyalkylene ether polyol having 2 or more ether groups in the molecule, and/or(e) a rosin resin and/or a rosin resin derivative,which is an organic solvent solution type, and exhibits excellent adhesion particularly in case that at least one of the substances to be adhered is a soft polyvinyl chloride sheet or film.

Abstract: A pressure sensitive adhesive composition is provided. The adhesive comprises an ABA block polymer wherein A represents a copolymer of styrene and alpha-methylstyrene and B represents blocks of diene polymer. The diene polymer can be butadiene, isoprene or a mixture thereof. The composition also contains a tackifying resin.

Abstract: A basic aqueous emulsion composition that can be used as a treatment for cellulosic sheets or articles made of cellulosic fibers to provide improved water resistance by forming a discrete coating on the individual fibers that make up the sheet while not substantially limiting the compatibility of the treated sheet with aqueous glues, dyes or inks comprising a major proportion of water, a mixture of wax and rosin, an emulsion stabilizer and a chelating agent.

Abstract: Vulcanizable polymeric compositions comprising certain rubbery polymers or polymer blends, a zinc dimethacrylate adjuvant having a surface area of from about 3.7 to about 5.4 m.sup.2 /g or more and a peroxide curing agent are provided. Polymeric compositions which contain 25 parts by weight or more of the zinc dimethacrylate adjuvant per 100 parts by weight of rubbery polymer in the absence of reinforcing fillers exhibit excellent strength and hysteresis characteristcs when cured. The surface area of the zinc dimethacrylate adjuvant along with its method of preparation are extremely important factors in the excellent properties obtained when polymeric compositions containing the adjuvant are cured.

Abstract: A pressure-sensitive adhesive having non-ghosting characteristic comprising a latex of polymers having pendent oxazoline groups, coreactive groups and a tackifier. The latex comprises discrete polymer particles having both pendent oxazoline and coreactive groups or a blend of discrete polymer particles one portion of which has pendent oxazoline groups and the other portion of which has pendent coreactive groups. The oxazoline group is preferably 2-isopropenyl-2-oxazoline and the coreactive group is a carboxyl, sulfonic acid, anhydride, phenolic, hydroxyl, amide or amine group.

Abstract: A pressure-sensitive adhesive composition comprising a block rubber, a tackifying resin and a plasticizer as major components, the composition being characterized in that the tackifying resin is partially fumarized and/or partially maleinized, disproportionated rosin ester.

Abstract: A hot-melt adhesive composition containing an ethylene copolymer, wax and a tackifying resin as major components, the composition being characterized in that the tackifying resin is partially fumarinized and/or partially maleinized, disproportionated rosin ester.