Carnauba Wax, Beeswax, Montan Wax, Or Oxidized Microcrystalline Wax Or Modified Forms Thereof Patents (Class 524/277)
-
Patent number: 5436287Abstract: The present invention relates to a repulpable laminating adhesive which contains an elastomer, tackifier and a 5:95 to 100:0 by weight blend comprising a high molecular weight oxygen-containing polymer and a wax.The oxygen-containing polymer is preferably of the formulaA-B (I)wherein A is represented by a unit of the formula ##STR1## and B is represented by a unit of the formula ##STR2## and further wherein R and R.sub.1 are independently selected from the group consisting of hydrogen and a C.sub.1 -C.sub.10 alkyl group; R.sub.2 is hydrogen or a C.sub.1 -C.sub.5 alkyl group; x is greater than or equal to 1 but less than 70; and y is between about 0 to about 45; provided the weight percent of B/A+B is between 0 and 50 percent and the molecular weight of the A unit is less than 2,000.Type: GrantFiled: February 16, 1993Date of Patent: July 25, 1995Assignee: Petrolite CorporationInventors: Michael D. Watson, William P. Cottom, Susan M. Teeters, Charles H. Heroux, Terrance D. Duryee
-
Patent number: 5432209Abstract: A propylene resin composition containing a propylene-ethylene block copolymer containing (a) a crystalline polypropylene moiety (constituent A) and an ethylene-propylene random copolymer moiety (constituent B), (b) a styrene-ethylene-butylene-styrene block copolymer which contains 10% to 25% of bound styrene, and (c) at least one filler selected from talc and inorganic whiskers and wherein the surface of the filler is treated with one of the organic compounds (I), (II) and (III) having the formulas, ##STR1## in which the various substituents and R groups are as defined in the specification and claims. The composition of the present invention has excellent mechanical strength, moldability and is capable of producing molded products having an excellent appearance.Type: GrantFiled: April 16, 1993Date of Patent: July 11, 1995Assignee: Mitsubishi Petrochemical Company LimitedInventors: Yoshihiro Sobajima, Keiko Kaba, Yoshihiro Noguchi
-
Patent number: 5425804Abstract: A novel water-repellent glazing agent is disclosed. The agent contains a modified organic silicone oil, which is represented by the general formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3 respectively stand for CH.sub.3 or a long chain alkyl group having 10-30 carbon atoms and at least one of X.sup.1, X.sup.2 and X.sup.3 is a long chain alkyl group having 10-30 carbon atoms and m and n are respectively 20-80 and 3-10. This agent has excellent water repellency and glazing effect as well as excellent operability.Type: GrantFiled: November 23, 1993Date of Patent: June 20, 1995Assignee: Taiho Industries Co., Ltd.Inventors: Seigo Shinohara, Kiyoshi Okamura, Tetsuo Kijima
-
Patent number: 5417756Abstract: In a ceramic or powder metallurgical molding compound which contains waxes as binder, the addition of an ethylene-vinyl acetate copolymer, an organic peroxide, an azo ester and an alcohol in combination with an extraction with a solvent leads to an improvement in the dimensional stability and the dewaxing of injection-molded shaped parts.Type: GrantFiled: November 23, 1993Date of Patent: May 23, 1995Assignee: Hoechst AktiengesellschaftInventors: Michael Bayer, Peter Pyka, Heike Wagner
-
Patent number: 5416152Abstract: A polyacetal molding composition comprising, as the active additive, at least onea) ester of long-chain monocarboxylic acids (C.sub.22 to C.sub.34) with mono- or polyhydric alcohols (C.sub.2 to C.sub.8), in the presence or absence of alkali metal and/or alkaline earth metal salts of the carboxylic acids mentioned, and/orb) polyethylene wax, is distinguished by a reduced tendency toward melt fracture. Such molding compositions can advantageously be employed in the production of shaped articles which show no undesirable defects in the surface.Type: GrantFiled: December 10, 1992Date of Patent: May 16, 1995Assignee: Hoechst AktiengesellschaftInventors: Dietrich Fleischer, Andreas Kirst, Klaus Kohlhepp, Hans-Dieter Sabel
-
Patent number: 5414039Abstract: A composition is which, when added to an ethylene vinyl acetate copolymer having 40 to 60 weight percent of vinyl acetate units, renders a repulpable hot melt adhesive comprises a tackifier and an oxygen-containing polymer. The oxygen-containing polymer may be either (i) a high molecular weight carboxylic acid; (ii) a ethylenically unsaturated cyclic anhydride graft polyolefin or (iii) a primary linear polymeric alcohol of the formulaA-Bwherein A is represented by a unit of the formula ##STR1## and B is represented by a unit of the formula ##STR2## where R and R.sub.1 are independently selected from the group consisting of hydrogen and a C.sub.1 -C.sub.10 alkyl group; R.sub.2 is hydrogen or a C.sub.1 -C.sub.5 alkyl group; x is greater than or equal to 1 but less than 70; and y is between 0 about 45; provided the weight ratio of B/A+B is between 0 and 50 percent. The molecular weight of the alkyl unit of the oxygen-containing polymer is less than 2,000.Type: GrantFiled: February 16, 1993Date of Patent: May 9, 1995Assignee: Petrolite CorporationInventors: Michael D. Watson, William P. Cottom, Susan M. Teeters, Charles H. Heroux, Terrance D. Duryee
-
Patent number: 5412010Abstract: A monomer supression additive comprising and ethylenically unsaturated monomer, ceresin wax, a drying oil such as corn oil and an epoxidized drying oil such as epoxidized soybean oil. The additive when added vinyl ester resins or polyester resins improves secondary adhesion.Type: GrantFiled: May 19, 1994Date of Patent: May 2, 1995Assignee: The Dow Chemical CompanyInventors: Terry W. Cowley, Mary L. N. White
-
Patent number: 5403872Abstract: A solid correction material for covering writing or drawing errors on paper is disclosed. The correction material may be formed into a stick and housed in hollow body and is composed of: (a) 5-40 wt % of a thermoplastic synthetic resin, preferably a homo- or copolymer based on (meth)acrylic compounds; (b) 10-70 wt % of a pigment, preferably a titanium dioxide pigment; (c) 5-20 wt % of a mono- or polyvalent alcohol, preferably glycerin being preferred; (d) 5-30 wt % of carrier mixture composed of (i) a fatty acid with 12 to 32 carbon atoms or a salt of a fatty acid, with stearate being preferred, and (ii) at least one member selected from the group consisting of a polyolefin and an ester wax, possibly 5 to 15 wt % water; and (e) 0 to 10 wt % of conventional additives, such as defoaming agents, dyes, aroma substances, and preservatives. The correction material is solid at room temperature and has a viscosity between about 100 and about 150 cPa.s at 90.degree. C.Type: GrantFiled: December 16, 1993Date of Patent: April 4, 1995Assignee: Kores Holding Zug AGInventor: Peter Koreska
-
Patent number: 5391601Abstract: The present invention relates to a blend of a linear or branched chain saturated aliphatic hydrocarbon wax having a molecular weight of between about 300 to about 5,000 and an alkoxylated alcohol of the formula A--B, wherein A is the unit: CH.sub.3 (CHR--CHR.sub.1).sub.x -- and B is the unit: --CH.sub.2 O(CH.sub.2 CHR.sub.2 O).sub.y H. R and R.sup.1 are independently selected from the group consisting of hydrogen and a C.sub.1 -C.sub.10 alkyl group; R.sub.2 is hydrogen or a C.sub.1 -C.sub.5 alkyl group; x is between about 1 to about 142; and y is between about 2 to about 817, provided the weight ratio of B/A+B is between 51 and 90 percent. Such blends may be used with an elastomer and tackifier to form a repulpable laminating adhesive. The invention further relates to a laminating adhesive containing alkoxylated alcohol, elastomer, wax and tackifier.Type: GrantFiled: February 16, 1993Date of Patent: February 21, 1995Assignee: Petrolite CorporationInventors: Susan M. Teeters, Charles H. Heroux, Michael D. Watson, William P. Cottom, Terrance D. Duryee
-
Patent number: 5382615Abstract: Hot-melt adhesive compositions useful for packaging are disclosed. These hot-melt adhesive compositions are based on modified polyethylene and contain an ethylene-alkylacrylate copolymer, a polyethylene graft copolymer, a tackifying resin, and a high-melting low viscosity wax. The hot-melt adhesive compositions disclosed have fast setting times and a novel combination of desired properties with good high and low temperature bond strength.Type: GrantFiled: October 1, 1993Date of Patent: January 17, 1995Assignee: Eastman Chemical CompanyInventor: Darryl A. Godfrey
-
Patent number: 5380775Abstract: Vinyl ester or polyester resins containing polymerizable, vaporizable, ethylenically unsaturated monomers and an emission suppressing amount of ceresin wax is improved with the addition of a drying oil such as corn oil and an epoxidized drying oil such as epoxidized soybean oil. The improvement is in secondary adhesion.Type: GrantFiled: May 19, 1994Date of Patent: January 10, 1995Assignee: The Dow Chemical CompanyInventors: Terry W. Cowley, Mary L. N. White
-
Patent number: 5356971Abstract: A thermosetting powder coating composition which contains a resin composition containing (a) 60 to 97 weight % of a fluororesin having reactive group for crosslinking in the molecule which contains 10 weight % or more of fluorine and has glass transition temperature in the range from 35.degree. to 120.degree. C., (b) 3 to 40 weight % of a hardener which can form crosslinking by reaction with the reactive group for crosslinking in the fluororesin (a), (c) 0.01 to 10 weight parts of a synthetic wax or a natural wax based on 100 weight parts of the resin composition and (d) 0.001 to 1.0 weight parts of a material as a coupling agent based on 100 weight parts of the resin composition, forms a coating layer which has the same degree of water repellency and slipping property as those formed from polytetrafluoroethylene powder while the excellent weatherability, acid resistance and adhesion to substrates are retained.Type: GrantFiled: June 28, 1993Date of Patent: October 18, 1994Assignee: NOF CorporationInventors: Chiaki Sagawa, Manabu Katagiri, Toru Kurashina
-
Patent number: 5350612Abstract: A multi-ply, wet-strength, removable label or coupon for packages intended for retail use, particularly suitable for items where refrigeration and/or condensation is a condition of the product life cycle. The coupon structure includes a base ply formed of moisture resistant, wet-strength paper with printable or coatable upper and under sides. The base ply is adhered to a removable top ply with a combination of bonding agents and release coatings. The top ply may also be moisture resistant. The coupon structure is preferably supplied in a cut-sheet format for convenient use and storage.Type: GrantFiled: August 4, 1992Date of Patent: September 27, 1994Assignee: Beckett CorporationInventors: Michael D. Stern, Stephen G. Dudley, Dale D. Reschenberg
-
Patent number: 5340863Abstract: Hot melt adhesive compositions which include a base polymer constituent, a tackifying constituent, a wax constituent, and which further includes a low molecular weight polyethylene copolymer constituent which includes ketone functional moieties and/or hydroxyl functional moieties wherein the hot melt adhesive composition may be further characterized as providing improved adhesive strength to polar and non-polar substrates.Type: GrantFiled: October 4, 1993Date of Patent: August 23, 1994Assignee: AlliedSignal, Inc.Inventor: Lawrence Krutzel
-
Patent number: 5331023Abstract: This invention relates to thermoplastic, pressure-sensitive solid adhesives capable of transferring an adhesive film to a substrate by friction rubbing of the adhesive on the substrate. The adhesives of this invention consist essentially of polyisobutylene, wax and optionally an adhesive promoter resin. Said ingredients are within certain proportions, molecular weights, melting points, or hardness values.Type: GrantFiled: March 23, 1992Date of Patent: July 19, 1994Assignee: Borden, Inc.Inventors: Peter S. Columbus, Yogeshbhai B. Patel
-
Patent number: 5330787Abstract: A multi-component polish composition and polishing process for a surface. The polish composition comprises a multi-component mixture which when applied to a surface, e.g., the painted surface of a vehicle, under effective drying conditions forms a substantially dry hydrophilic wax-containing film which may be substantially removed from the surface by water rinsing of the surface whereby a hydrophobic protective layer is provided to the surface.Type: GrantFiled: December 2, 1991Date of Patent: July 19, 1994Assignee: First Brands CorporationInventors: David R. Berlin, Bonnie A. Rishel, Richard R. Wolstoncroft
-
Patent number: 5331033Abstract: Hot melt packaging adhesive compositions consisting essentially of 20 to 50% by weight of an ethylene n-butyl acrylate copolymer containing 25-45% by weight, preferably 30 to 40% n-butyl acrylate and having a melt index of at least 10; 30 to 60% of an aliphatic or cycloaliphatic hydrocarbon resin or hydrogenated derivative thereof or a hydrogenated aromatic hydrocarbon resin; and 10 to 30% by weight of a high melting synthetic wax provide adhesives characterized by an excellent balance of high and low temperature performance without sacrifice to machinability or thermal stability. Further, the adhesive is characterized by a low density and consequently is readily filterable in recycling systems.Type: GrantFiled: February 23, 1993Date of Patent: July 19, 1994Assignee: National Starch and Chemical Investment Holding CorporationInventors: Daniel Stauffer, Paul P. Puletti, Thomas F. Kauffman
-
Patent number: 5328696Abstract: Hot-melt silicone pressure sensitive adhesive compositions containing organic waxes, methods of using the compositions and devices made using the compositions are disclosed. The hot-melt silicone pressure sensitive adhesive compositions include a mixture of (i) a silicate resin, (ii) a silicone fluid, and (iii) an organic wax having a melting point of between 30.degree. C. and 150.degree. C. The organic wax decreases dynamic viscosity of the adhesive at temperatures equal to or below about 200.degree. C.Type: GrantFiled: July 22, 1991Date of Patent: July 12, 1994Assignee: Dow Corning CorporationInventor: Ross A. Noel
-
Patent number: 5326413Abstract: Novel lower temperature hot melt adhesive and coating composition that melts at temperatures less than 190.degree. F. (about 87.8.degree. C). This composition has a sufficient modulus to bind ophthalmic lenses to metal blocks during grinding processes. The composition also exhibits low melt viscosity and may be mechanically removed without leaving significant residue. Composition comprises a resin, a tackifier, a wax (generally with a molecular weight less than 600), and an optional stabilizer.Type: GrantFiled: November 19, 1990Date of Patent: July 5, 1994Assignee: Pearle, Inc.Inventors: Pascal E. Esemplare, Ronald W. Gumbs
-
Patent number: 5300538Abstract: An erasable highlighting composition is provided including a block copolymer, a wax, and a fluorescent pigment. The composition is in solid form, and, when applied to an underlying marking on a substrate, is capable of forming a highlighting marking which may be erased without lifting the underlying marking.Type: GrantFiled: June 2, 1992Date of Patent: April 5, 1994Assignee: The Gillette CompanyInventor: Rachel M. Loftin
-
Patent number: 5270360Abstract: A two-phase thermoplastic composition adapted for forming thermoplastic patterns. The composition comprises an organic thermoplastic pattern material and at least about 5% by weight of discrete particles of cross-linked poly(methylmethacrylate) that are physically stable at temperatures above 130.degree. F. Also disclosed are investment casting patterns of such composition and processes utilizing such composition.Type: GrantFiled: January 3, 1992Date of Patent: December 14, 1993Assignee: Yates Manufacturing CompanyInventor: Paul Solomon
-
Patent number: 5262453Abstract: A cushion or trackbed material for use in a riding-ground is obtained by coating sand with a carboxyl-containing olefin polymer and an oxygen-containing wax.Type: GrantFiled: July 15, 1991Date of Patent: November 16, 1993Assignees: Nippon Oil Company, Limited, Nippon Petrochemicals Company, Limited, Nippon Hodo Company, LimitedInventors: Yutaka Watanabe, Kazuo Aoyama, Hisanobu Niwata, Sumio Ikeda, Katuaki Ishikawa, Yoshiteru Kato
-
Patent number: 5256717Abstract: Hot melt adhesives having suitable open time and crystallinity properties making them especially useful as temporary adhesives are provided by a composition comprising a combination of 5 to 50% by weight of an isotactic thermoplastic polybutylene copolymer or a low density ethylene polymer with 3 to 65% by weight of a solid benzoate plasticizer.Type: GrantFiled: December 19, 1990Date of Patent: October 26, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Daniel Stauffer, Paul Puletti
-
Patent number: 5256716Abstract: A coating formulation for secure bonding attachment to surfaces of resilient or flexible articles, including plastic foam articles and comprising a highly adherent and coherent water-based film forming mixture for coating the surface of flexible foam articles. The working solution of the coating preferably has a formulation containing:ComponentAcrylic emulsion;Plasticizer;Coalescing agent;Polyacrylate thickener/rheology modifier;Defoamer;Surfactant;Ammonium hydroxide; andWater.The working solution is applied to the surfaces of the article being treated and the water solvent which is present evaporates at a significantly rapid rate in the ambient to form a thick coating having a substantially dry outer surface. The film remains securely bonded to the article even though flexed and otherwise roughly treated.Type: GrantFiled: August 20, 1990Date of Patent: October 26, 1993Assignee: PDI, Inc.Inventors: Scott Haasl, Mark Kenow
-
Patent number: 5254613Abstract: In a ceramic or powder-metallurgical molding composition which contains waxes as binders, the addition of an ethylene/vinyl acetate copolymer, optionally in combination with an organic peroxide and an azo ester and crosslinking of the binder, leads to an improvement in the dimensional stability and the dewaxing of injection-molded moldings.Type: GrantFiled: June 16, 1992Date of Patent: October 19, 1993Assignee: Hoechst AktiengesellschaftInventors: Michael Bayer, Iris Nagl
-
Patent number: 5252639Abstract: The molding resin composition of this invention comprises a resin contained a releasing a agents formulated with a release agent and a metal chelate compound.This resin composition is improved an good adhesivity, high moisture resistivity and a good moldability.Type: GrantFiled: November 25, 1991Date of Patent: October 12, 1993Assignee: Kabushiki Kaisha ToshibaInventors: Shinetsu Fujieda, Akira Yoshizumi, Kazutaka Matsumoto, Hisayuki Hirai
-
Patent number: 5234982Abstract: A thermoplastic molding composition containing a polycarbonate resin, glass fibers and oxidized polyethylene is disclosed. The composition is suitable for the preparation of molded articles having an improved level of impact strength.Type: GrantFiled: November 18, 1991Date of Patent: August 10, 1993Assignee: Bayer AktiengesellschaftInventors: Klaus Kircher, Helmut-Martin Meier, Klaus Horn, Helmut Pilzecker
-
Patent number: 5232983Abstract: Acrylate or methacrylate compositions are provided for coating porous surfaces, wherein the composition comprisesa) 90-99.9% acrylate and/or methacrylate monomers, andb) 0.1 to 5 percent wax.The wax in these compositions is soluble in the acrylate and/or methacrylate monomers when the monomers are in a liquid state. The wax is incompatible with a cured coating formed from the polymerization of the acrylate and/or methacrylate monomers.The compositions cure to provide a non-tacky surface in excellent short time periods as compared to prior similarly constituted acrylate or methacrylate compositions.Type: GrantFiled: June 11, 1991Date of Patent: August 3, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventor: George W. Frost
-
Patent number: 5223562Abstract: A thermosetting powder coating composition comprises (a) a fluororesin having reactive group for crosslinking in the molecule which contains 10 weight % or more of fluorine and has glass transition temperature in the range from 35.degree. to 120.degree. C., (b) a hardener which can form crosslinking by reaction with the reactive group for crosslinking in the fluororesin (a) and (c) a synthetic wax or a natural wax. The amount of the fluororesin is in the range from 60 to 97 weight % and the amount of the hardener is in the range from 3 to 40 weight % based on the total of the fluororesin and the hardener. The amount of the synthetic wax or the natural wax is in the range from 0.01 to 10 weight parts based on 100 weight parts of the total of the fluororesin and the hardener.Type: GrantFiled: October 13, 1992Date of Patent: June 29, 1993Assignee: NOF CorporationInventors: Chiaki Sagawa, Manabu Katagiri, Toru Kurashina
-
Patent number: 5190579Abstract: Aqueous application systems for applying additives to polymeric particles, methods of preparing aqueous emulsions which include at least one processing, stabilizing or other functional polymer additive and an emulsifiable wax. Also disclosed are methods of applying additives to polymeric particles and to polymeric particles treated by such methods.Type: GrantFiled: February 7, 1990Date of Patent: March 2, 1993Assignee: Eastman Kodak CompanyInventors: William C. Gose, Kenneth W. Hyche
-
Patent number: 5166242Abstract: A coating composition for application to a thermoplastic film, such as polypropylene film, the coated film and the method for coating the film are disclosed. The coating composition includes an acrylic copolymer, a slip agent and, optionally, a water dispersible wax. The acrylic copolymer can be an emulsion or a solution. The acrylic copolymer preferably includes at least 5 weight percent of a polar, functional comonomer; has an average molecular weight of at least about 10,000; and has a glass transition temperature of about 30.degree. C. to about 100.degree. C.Type: GrantFiled: September 14, 1990Date of Patent: November 24, 1992Assignee: Mobil Oil CorporationInventors: Shaw-Chang Chu, Hee C. Park, Robert E. Touhsaent
-
Patent number: 5164436Abstract: Waxy esters of aromatic alcohols with long-chain carboxylic acids give lubricants and release agents for highly transparent thermoplastics which reduce the transparency of these plastics to a far lesser degree than the previously customary montan wax esters of aliphatic alcohols.Type: GrantFiled: July 15, 1991Date of Patent: November 17, 1992Assignee: Hoechst AktiengesellschaftInventors: Karl Maier, Gerd Hohner, Jan-Peter Piesold
-
Patent number: 5155155Abstract: An oxidized polyethylene wax or other wax in the form of a salt with a metal selected from groups IB, IIB, IIA, IIIA, IIIB, VIB, VIIB and VIIIB of the Periodic Table of the Elements acts as a photoactivator in a polymer composition and degrades the latter. The quantity of the additive can vary from 0.1 to 2.0% by weight, relative to the weight of the composition. The additive can be added directly or, more suitably, via a masterbatch.Type: GrantFiled: August 26, 1991Date of Patent: October 13, 1992Assignee: Hoechst Italia, S.p.A.Inventor: Riccardo Jurlaro
-
Patent number: 5153064Abstract: The invention describes a hot-melt adhesive substance for the coating of fabrics, especially of lining materials of outer wear, comprising a hot-melt adhesive paste on a copolyester basis as the base layer and a covering layer of a hot-melt adhesive. The inventive hot-melt adhesive substance is characterized in that the hot-melt adhesive paste of the base layer contains a mixture of copolyester and low-pressure polyethylene. The covering layer of hot-melt adhesive preferably contains copolyamide. When using the inventive hot-melt adhesive substance, a raster-pattern coated fabric can be obtained in which the hot-melt adhesive substance has substantially improved adhesive strength as well as a high degree of washing and cleaning stability.Type: GrantFiled: May 10, 1991Date of Patent: October 6, 1992Assignee: Kufner Textilwerke GmbHInventor: Josef Hefele
-
Patent number: 5143964Abstract: A moldable unsaturated polyester resin composition having improved antishrinking and shape-retaining properties contains an unsaturated polyester resin/styrene mixture, fillers, glass fibers, an antishrinkage agent and a demolding agent, wherein the demolding agent is calcium montanate and wherein the antishrinkage agent is preferably a methyl methacrylate polymer. The composition is particularly useful for the manufacture of lamp reflectors having superior shape and weight retention integrity and reduced reflector surface fogging.Type: GrantFiled: April 5, 1991Date of Patent: September 1, 1992Assignee: Cray Valley SAInventors: Gilles Behar, Jean-Claude Oginski, Alain Martinet
-
Patent number: 5126390Abstract: Disclosed are water-based transfer element coating formulations suitable for forming transfer elements for impact printing, thermal printing, typewriting, and the like, which comprise a wax-in-water emulsion, an oil, an aqueous polymer emulsion, a colorant, an optional water-soluble leveling agent, and an optional inert filler, said coating formulation containing substantially no volatile organic compounds. Also disclosed are processes for preparing transfer elements with these coating formulations and printing processes employing the transfer elements thus prepared.Type: GrantFiled: November 23, 1990Date of Patent: June 30, 1992Assignee: Xerox CorporationInventor: James M. Duff
-
Patent number: 5115067Abstract: Disclosed is a molecularly oriented molded body of an ultra-high-molecular-weight ethylene/.alpha.-olefin copolymer having an intrinsic viscosity (.eta.) of at least 5 dl/g and such a content of an .alpha.-olefin having at least 3 carbon atoms that the number of molecules of the .alpha.-olefin is 0.1 to 15 on the average per 1000 carbon atoms, wherein the molded body shows at least two crystal fusion endothermic peaks when the measurement is conducted in the restraint state by using a differential scanning calorimeter, the molded body has at least one crystal fusion endothermic peak (Tp) at a temperature higher by at least 20.degree. C. than the inherent crystal fusion temperature (Tm) of the ultra-high-molecular-weight ethylene/.alpha.-olefin copolymer determined as the main fusion endothermic peak at the time of the second elevation of the temperature, and the quantity of heat based on said crystal fusion endothermic peak (Tp) is at least 15% based on the total fusion heat quantity.Type: GrantFiled: April 4, 1990Date of Patent: May 19, 1992Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuo Yagi, Akinori Toyota
-
Patent number: 5098943Abstract: A water repellent having the following components (A), (B), (C) and (D) emulsified in water:(A) a wax having a melting point of from 40.degree. to 90.degree. C.;(B) a styrene-maleic anydride copolymer;(C) a water-soluble alkaline compound; and(D) a polyvinyl alcohol having a saponification degree of at least 85 mol %.Type: GrantFiled: May 9, 1991Date of Patent: March 24, 1992Assignee: Mitsubishi Kasei CorporationInventors: Toru Tagawa, Takao Tadenuma, Yasoji Ozawa
-
Patent number: 5096493Abstract: Aqueous application systems for applying additives to polymeric particles, methods of preparing aqueous emulsions which include at least one processing, stabilizing or other functional polymer additive and an emulsifiable wax. Also disclosed are methods of applying additives to polymeric particles and to polymeric particles treated by such methods.Type: GrantFiled: October 11, 1990Date of Patent: March 17, 1992Assignee: Eastman Kodak CompanyInventors: Kenneth W. Hyche, William C. Gose
-
Patent number: 5085695Abstract: An essentially wax-free cleaner-polisher composition that cleans while maintaining excellent gloss and superior protection against water and a mixture of alcohol and water damage in a one-step application is described. The composition comprises about, a) 30% to 90% water, b) 1 to 4% by weight acrylate polymer, c) 4% to 12% co-solvent and/or 0.5% to 6% surface active agents, d) 4-40 silicone oil and/or mineral oil and optically, e) 0 to 3 percent by weight of fluoroalkyl polymer, f) 0 to 0.5% a fragrance, and g) 0 to 5 percent by weight of a wax emulsion.Type: GrantFiled: July 13, 1990Date of Patent: February 4, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Neil A. Randen, Vinu Patel
-
Patent number: 5082891Abstract: The curable resin composition of the present invention consists of a curable resin having uniformly dispersed therein particles of a cured silicone rubber obtained from an organosiloxane composition curable by a platinum-catalyzed hydrosilation reaction, wherein said organosiloxane composition contains reaction products of an ethylenically unsaturated epoxy compound and an ethylenically unsaturated aromatic compound with the organohydrogenpolysiloxane present in said organosiloxane composition. Either or both of the epoxy compound and the aromatic compound can be prereacted with a portion of the silicon-bonded hydrogen atoms of the organohydrogenpolysiloxane.Type: GrantFiled: December 13, 1989Date of Patent: January 21, 1992Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Yoshitsugu Morita, Noriyasu Yokoyama, Keiji Yoshida
-
Patent number: 5081174Abstract: A formable, weldable, removable protective coating composition for use on metals, said coating comprising a combination of a base-neutralized acid-funtional copolymer and a wax lubricant, and further comprising a removability enhancing means such as phosphoric acid as an additive to the coating composition.Type: GrantFiled: October 2, 1989Date of Patent: January 14, 1992Assignee: PPG Industries, Inc.Inventor: Ellor J. VanBuskirk
-
Patent number: 5075359Abstract: Polymer additive concentrates comprising (a) between about 10 and about 80 weight percent of a polymer additive; (b) between about 2 and about 50 weight percent of an absorbant material which is a consolidated blend of spurted polyolefin pulp treated with a wetting agent, and wood fluff pulp; and (c) between about 5 and about 80 weight percent polymer, possess unexpectedly higher additive loading as well as exhibiting admirable properties when employed in polymers which are extruded into clear films. In addition, a process for manufacturing such concentrates is described.Type: GrantFiled: October 16, 1989Date of Patent: December 24, 1991Assignee: ICI Americas Inc.Inventors: Vincent A. Castagna, Jesse W. Fullerton
-
Patent number: 5049186Abstract: Water-based compositions of the water-based wax emulsion type for protecting coating films are provided by emulsifying and dispersing, as essential components, [A] a disperse phase component and [B] an emulsifier component in water. The disperse phase component [A] is formed of (a) a petroleum fraction wax having a melting point of 50.degree.-90.degree. C., (b) an oxygen-containing wax having an oxygen content of at least 3.0 wt. % and a melting point of 50.degree.-85.degree. C., (c) an ethylene/.alpha.-olefin copolymer having a number average molecular weight of 2,000-20,000, and (d) a higher fatty acid metal salt and/or a metal-modified hard wax. The compositions can form, without the need for a solvent, strong barrier coats which are resistant to rain, moisture, sunlight and air pollutants even under severe environmental conditions. After these barrier coats are used, they can be easily removed with warm water containing a small amount of a solvent or steam.Type: GrantFiled: March 16, 1990Date of Patent: September 17, 1991Assignee: Nippon Oil Co., Ltd.Inventor: Nobuaki Kawabata
-
Patent number: 5045584Abstract: A polish including a film forming wax material and an organopolysiloxane elastomer. The elastomer is in the form of particles mixed with the film forming wax. The particles are spherical and have an average diameter of from about 0.3 um to about 30 um. The polish contains at least one additive selected from the group consisting of organic solvents, silicone oils, and surfactants. The film forming wax material may be one of carnauba wax, montan wax, candelilla wax, ceresin wax, paraffin waxes, and beeswax.Type: GrantFiled: November 3, 1989Date of Patent: September 3, 1991Assignee: Toray Silicone Company, LimitedInventors: Atushi Sasaki, Asao Harashima, Keiji Yoshida
-
Patent number: 5039727Abstract: Thermoplastic polyester compositions comprising at least two groups of polybutylene terephthalate with substantially different intrinsic viscosity values and conventional additives for molding having an improved thermal flow capability under molding conditions expressed in such indices as heat flow (m cal/sec), enthalphy change .DELTA.Hm(Joule/gr) at the solidification of fused polymer, crystalline fraction (Xc), and the time of growth to (sec) of the primary nuclei of embryonic crystalline. The polymer compositions of the present invention result in a larger size of crystalline than the case of independent, single polymer and this enables to carry out injection moulding at about 20 degrees lower cylinder temperature than usual molding practice without sacrificing mechanical and thermal properties of the product.Type: GrantFiled: October 10, 1989Date of Patent: August 13, 1991Assignee: Sumitomo Wiring Systems, Ltd.Inventors: Yasuhiko Onishi, Yoshinobu Kubo, Takao Nozaki
-
Patent number: 5037874Abstract: Synthetic polyethylene wax having low molecular weight of 250 to 3000 and a density of 0.930 to 0.950 is prepared in a high pressure process at pressures of at least 800 bar using a carbonyl compound such as acetaldehyde as chain transfer agent. The resulting wax with incorporated CO has good compatibility in hot melt systems, and may be stripped to remove light ends, increase density and crystallinity and improve thermal stability.Type: GrantFiled: October 5, 1990Date of Patent: August 6, 1991Assignee: Exxon Chemical Patents Inc.Inventors: Hugo J. C. Nuttens, Gerard VanHaeren
-
Patent number: 5034454Abstract: Disclosed herein are crosslinkable water-dispersible acrylic copolymers which are prepared by free-radical initiated polymerization of ethylenically unsaturated monomers containing independently an active hydrogen group, a carboxyl group and a sulfonic group, wherein the polymerization is conducted in the presence of a wax. In combination with curing agents, the crosslinkable compositions are particularly useful in imparting markedly improved flow to dip coatings.Type: GrantFiled: March 3, 1989Date of Patent: July 23, 1991Assignee: PPG Industries, Inc.Inventors: Rudolf Maska, David T. McKeough, David L. Holzinger, Susan D. Klejsmit
-
Patent number: 5025054Abstract: A polish including a film forming wax material and a silicone rubber. The rubber is in the form of particles mixed with the film forming wax, and the silicone rubber particles contain a silicone oil. The particles have an average diameter of from about 0.3 .mu.m to about 30 .mu.m. The polish includes at least one additive selected from the group consisting of organic solvents, a second silicone oil, and surfactants. The film forming wax material is one of carnauba wax, montan wax, candelilla wax, ceresin wax, paraffin waxes, or beeswax. The silicone rubber forming the particles is one of addition reaction curable silicone rubber compositions, condensation reaction curable silicone rubber compositions, organic peroxide curable organopolysiloxane compositions, or high energy curable silicone rubber compositions.Type: GrantFiled: November 9, 1989Date of Patent: June 18, 1991Assignee: Toray Silicone Company, LimitedInventors: Keiji Yoshida, Mitsuo Hamada
-
Patent number: 5015693Abstract: An extrudable composition comprising thermoplastic hydrocarbon polymer, poly(oxyalkylene) polymer and fluorocarbon polymer. The poly(oxyalkylene) polymer and the fluorocarbon polymer are present in the composition in such relative proportions and concentrations as to reduce the occurence of melt defects during the extrusion of said hydrocarbon polymer composition.Type: GrantFiled: May 23, 1989Date of Patent: May 14, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: Denis Duchesne, Bryce V. Johnon