Cycloaliphatic Group Or Bridged Or Fused Ring System, E.g., Camphoric Acid, Etc. Patents (Class 524/285)
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Patent number: 11891495Abstract: A thermoplastic polymer composition comprises a polyethylene polymer composition and a salt of bicyclo[2.2.1]heptane-2,3-dicarboxylic acid. The polyethylene polymer composition can have a Melt Relaxation Product of 50,000 or less. A method for producing an injection molded article comprises the steps of (a) providing a thermoplastic polymer composition as described above, (b) melting the thermoplastic polymer composition, (c) injecting the molten thermoplastic polymer composition into a mold cavity, (d) cooling the molten thermoplastic polymer composition, and (e) ejecting the injection molded article from the mold cavity. A method for producing a film comprises the steps of (a) providing a thermoplastic polymer composition as described above, (b) melting the thermoplastic polymer composition, (c) extruding the molten thermoplastic polymer composition through a slot-shaped die orifice to form a film, (d) cooling the film, and (e) collecting the film.Type: GrantFiled: July 28, 2021Date of Patent: February 6, 2024Assignee: Milliken & CompanyInventors: Walter Forrister, Xiaoyou Xu, Darin Dotson
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Patent number: 11845849Abstract: A process prepares dialkyl 1,4-cyclohexanedicarboxylates by ring hydrogenation of the corresponding dialkyl terephthalate having a CO value of less than 0.3 mg KOH/g. The dialkyl 1,4-cyclohexanedicarboxylates thus produced can be used as plasticizers or as a component of a plasticizer composition for plastics, in particular PVC.Type: GrantFiled: July 26, 2021Date of Patent: December 19, 2023Assignee: Evonik Operations GmbHInventors: Johannes Kraft, Lena Altmann, Johan Anton, Michael Grass, Thomas Schneider
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Patent number: 11807596Abstract: The purpose of the present invention is to provide: novel thiol compounds; a method for synthesizing said thiol compounds; curing agents containing said thiol compounds; resin compositions containing said thiol compounds and an epoxy compound; and resin compositions containing said thiol compounds and an ene compound having a carbon-carbon double bond in a molecule. Furthermore, the purpose of the present invention is to provide adhesives and sealants having these resin compositions as ingredients. The thiol compounds of the present invention are represented by chemical formula (I) to chemical formula (VII).Type: GrantFiled: October 25, 2018Date of Patent: November 7, 2023Assignee: SHIKOKU CHEMICALS CORPORATIONInventors: Naoto Okumura, Akihito Otsuka, Takeshi Kumano, Kazuyuki Fujikawa, Yusuke Araki
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Patent number: 11795299Abstract: Provided is a plasticizer composition including a cyclohexane-1,2-diester-based material of Formula 1 and a trimellitate-based material of Formula 2: wherein in Formula 1 and Formula 2, R1 to R5 are each independently an alkyl group of 8 to 10 carbon atoms.Type: GrantFiled: June 3, 2019Date of Patent: October 24, 2023Assignee: LG Chem, Ltd.Inventors: Hyun Kyu Kim, Yun Ki Cho, Woo Hyuk Choi, Jeong Ju Moon, Joo Ho Kim, Seok Ho Jeong
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Patent number: 11767420Abstract: A plasticizer composition and a resin composition including the plasticizer composition. The resin composition addresses limitations associated with conventional plasticizers by improving various properties such as plasticization efficiency and mechanical properties including migration properties, volatile loss, tensile strength and elongation rate. The plasticizer composition is also capable of improving properties such as elongation retention and cold tolerance.Type: GrantFiled: November 1, 2018Date of Patent: September 26, 2023Assignee: LG CHEM, LTD.Inventors: Hyun Kyu Kim, Yun Ki Cho, Jeong Ju Moon, Joo Ho Kim, Seok Ho Jeong
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Patent number: 11760072Abstract: A multilayer film having a multi-layer structure unit which is a 51-layered or more multiple layer formed by alternately layering a layer (A layer) a main component of which is a polyester resin (resin A) having a dicarboxylic component and a diol component, and a layer (B layer) a main component of which is a thermoplastic resin (resin B) different from the resin A in optical properties; wherein at least one surface of the multi-layer structure unit has a refractive index of 1.68 or more and 1.80 or less, wherein the surface has a critical load of 15 mN or less at 100° C. in a scratch test, and wherein the multilayer film has at least one reflection bandwidth having a reflectance of 30% or more continuous over a wavelength width of 20 nm or more in a profile of reflectance measured on at least one surface side of the multi-layer structure unit.Type: GrantFiled: September 26, 2018Date of Patent: September 19, 2023Assignee: TORAY INDUSTRIES, INC.Inventors: Yoshihiro Masuda, Shigeru Aoyama, Jun Sakamoto, Hiroji Kojima
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Patent number: 11753402Abstract: Provided is a plasticizer composition, including: a cyclohexane-1,2-diester-based substance in which two alkyl groups are bonded to the ester groups, and the alkyl groups each independently are a C4 to C12 alkyl group; and an epoxidized alkyl ester composition comprising one or more compounds of the following Chemical Formula 1: wherein in Chemical Formula 1: R1 is a C8 to C20 alkyl group comprising one or more epoxy groups; and R2 is a C4 to C10 alkyl group.Type: GrantFiled: May 29, 2019Date of Patent: September 12, 2023Assignee: LG CHEM, LTD.Inventors: Hyun Kyu Kim, Yun Ki Cho, Jeong Ju Moon, Joo Ho Kim
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Patent number: 11629116Abstract: Provided is a plasticizer composition including: a cyclohexane-1,2-diester-based substance of the following Chemical Formula 1; and a citrate-based substance of the following Chemical Formula 2: wherein in Chemical Formula 1 and Chemical Formula 2: R1 and R2 each independently are a C8 to C10 alkyl group; and R3 to R5 each independently are a C5 to C10 alkyl group.Type: GrantFiled: May 30, 2019Date of Patent: April 18, 2023Assignee: LG Chem, Ltd.Inventors: Hyun Kyu Kim, Seok Ho Jeong, Woo Hyuk Choi, Yun Ki Cho, Jeong Ju Moon, Joo Ho Kim
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Patent number: 11174418Abstract: Embodiments of the present disclosure pertain to adhesive compositions that include a fluorinated molecule and a hydrogen-containing molecule that are non-covalently associated with one another. The molecules may be non-covalently associated with one another through dipole-dipole interactions that create a fluorine-hydrogen electronegativity difference between at least some of the fluorine atoms of the fluorinated molecule and at least some of the hydrogen atoms of the hydrogen-containing molecule. The fluorinated molecule and the hydrogen-containing molecule may be in different phases, such as a liquid phase for one molecule and a solid phase for the other molecule. Additional embodiments pertain to methods of enhancing an adhesiveness of a surface by applying an adhesive composition of the present disclosure to the surface.Type: GrantFiled: June 27, 2017Date of Patent: November 16, 2021Assignees: William Marsh Rice University, Board of Regents of the University of Texas SystemInventors: Alin C. Chipara, Mircea Chipara, Chandra S. Tiwary, Pulickel M. Ajayan
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Patent number: 10934412Abstract: The present invention discloses a poly(terephthalate-co-sebacate) resin composition, comprising the following components: a. poly(terephthalate-co-sebacate); and b. an alkane, which is at least one selected from the group consisting of hexadecane, heptadecane, octadecane, nonadecane and eicosane; wherein a weight content of the alkane is 5 ppm-1000 ppm based on a total weight of the poly(terephthalate-co-sebacate) resin composition. The present invention controls the content of alkane in the composition within a range of 5 ppm-1000 ppm by adding an alkane, which not only enables the poly(terephthalate-co-sebacate) resin to have obviously improved blow molding properties, a film thickness range of less than 0.3 ?m, and a relative deviation of film thickness of less than 2.Type: GrantFiled: November 30, 2017Date of Patent: March 2, 2021Assignee: Kingfa Sci. & Tech. Co., Ltd.Inventors: Weiwei Wang, Zhimin Yuan, Tongmin Cai, Xianbo Huang, Xiangbin Zeng, Renxu Yuan, Zhilong Guo, Meijun Tang
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Patent number: 10851220Abstract: A plasticizer composition and a resin composition including the same. The plasticizer composition includes a terephthalate-based material including a mixture of dibutyl terephthalate, butyl(2-ethylhexyl) terephthalate and di(2-ethylhexyl) terephthalate; and a triethylene glycol diester-based material including a mixture of triethylene glycol bis(2-ethylhexanoate), (2-ethylhexanoyloxy) triethylene glycol benzoate and triethylene glycol dibenzoate. A material prepared from the resin composition has excellent mechanical properties, such as tensile strength, elongation rate, modulus, transmittance, transparency and plasticization efficiency.Type: GrantFiled: December 4, 2018Date of Patent: December 1, 2020Assignee: LG CHEM, LTD.Inventors: Hyun Kyu Kim, Seok Ho Jeong, Yun Ki Cho, Jeong Ju Moon, Joo Ho Kim
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Patent number: 10811165Abstract: [Problem] To provide an insulation material that has an excellent volume resistivity while retaining the balance among various capabilities including the mechanical strength, the heat resistance, the oil resistance, the bleed-out resistance, the plasticizer migration resistance, and the like, equivalent to a resin composition containing an ordinary phthalate ester. [Solution] An insulation material containing a resin composition containing: an ester (i) having one or more constitutional unit represented by the following formula (A) (wherein R1 and R2 each independently represent an alkyl group having from 1 to 4 carbon atoms); and a resin (ii).Type: GrantFiled: December 3, 2015Date of Patent: October 20, 2020Assignee: KURARAY CO., LTD.Inventors: Yuusuke Saitou, Takahiro Suzuki, Junichi Fuji
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Patent number: 10731026Abstract: The present invention relates to a plasticizer composition and a resin composition including the same, and can provide a plasticizer composition in which three types of terephthalate-based materials and three types of cyclohexane 1,4-diester-based materials are mixed, and by which environmental friendliness can be secured, mechanical properties such as tensile strength and an elongation rate, physical properties such as migration properties and volatile loss can be improved to levels equal to or higher than those of existing products, and effects of improving processability and plasticizing efficiency can be expected, and a resin composition including the same.Type: GrantFiled: September 5, 2017Date of Patent: August 4, 2020Assignee: LG CHEM, LTD.Inventors: Hyun Kyu Kim, Mi Yeon Lee, Yun Ki Cho, Jeong Ju Moon, Joo Ho Kim, Seok Ho Jeong
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Patent number: 10717846Abstract: The present invention relates to a plasticizer composition which includes an epoxidized alkyl ester composition including one or more compounds represented by the following Chemical Formula 1; and a citrate-based material, wherein a weight ratio of the epoxidized alkyl ester composition and the citrate-based material is in a range of 90:10 to 10:90:Type: GrantFiled: June 13, 2017Date of Patent: July 21, 2020Assignee: LG CHEM, LTD.Inventors: Hyun Kyu Kim, Mi Yeon Lee, Yun Ki Cho, Jeong Ju Moon, Joo Ho Kim, Seok Ho Jeong
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Patent number: 10590260Abstract: The present invention relates to a plasticizer composition, a resin composition, and methods for preparing the same. The present invention can provide: a plasticizer capable of improving properties, such as plasticization efficiency, transitivity, tensile strength, elongation, and tension/elongation retention, required for compound treatment when a resin composition is used as a plasticizer, by improving poor properties caused due to structural limitations; and a resin composition containing the same.Type: GrantFiled: October 27, 2016Date of Patent: March 17, 2020Assignee: LG CHEM, LTD.Inventors: Hyun Kyu Kim, Mi Yeon Lee, Jeong Ju Moon, Joo Ho Kim, Seok Ho Jeong
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Patent number: 10208201Abstract: The present invention relates to a plastics composition which comprises at least one platelet-shaped metal pigment from a range of from 0.01 to 25 wt.-%, at least one light stabilizer from a range of from 0.01 to 10 wt.-% and at least one antioxidant from a range of from 0.01 to 2 wt.-%, in each case relative to the proportion by weight of the plastics composition.Type: GrantFiled: October 14, 2014Date of Patent: February 19, 2019Assignee: ECKART GMBHInventors: Dietmar Mäder, Martin Schaal, Wolfgang Trenz
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Patent number: 10106669Abstract: Provided is a vinyl chloride resin composition for powder molding that can provide a molded product having superior flexibility at low temperatures. The vinyl chloride resin composition for powder molding includes (a) vinyl chloride resin particles, (b) a plasticizer, and (c) vinyl chloride resin fine particles having an average degree of polymerization of at least 1,000 and no greater than 5,000.Type: GrantFiled: March 10, 2015Date of Patent: October 23, 2018Assignee: ZEON CORPORATIONInventor: Shota Nishimura
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Patent number: 10072133Abstract: The present invention relates to a plasticizer composition which comprises at least one furan derivative and at least one 1,2-cyclohexanedicarboxylate ester, molding compounds which comprise a thermoplastic polymer or an elastomer and such a plasticizer composition and the use of these plasticizer compositions and molding compounds.Type: GrantFiled: January 8, 2015Date of Patent: September 11, 2018Assignee: BASF SEInventors: Jochen Wagner, Boris Breitscheidel, Martin A. Bohn, Benoit Blank, Alois Kindler
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Patent number: 9969859Abstract: A composition comprising a blend of high density polyethylene (HDPE) and a nucleating component, with optional additives, in amounts effective to provide reduced shrinkage of the extruded composition and components made from the composition.Type: GrantFiled: December 3, 2013Date of Patent: May 15, 2018Assignee: Dow Global Technology LLCInventors: Karl M. Seven, Chester J. Kmiec
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Patent number: 9896570Abstract: Plasticizers of indane and or tetralin esters and blends thereof with thermoplastic polymers, such as PVC, are disclosed.Type: GrantFiled: December 17, 2015Date of Patent: February 20, 2018Assignee: ExxonMobil Chemical Patents Inc.Inventors: Meagan E. Evans, Christopher M. Evans, Christine A. Costello, Stephen Zushma, Madhavi Vadlamudi
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Patent number: 9763888Abstract: A rapidly dispersible, fine-particle film-coating composition which is in powder form and is not prone to segregation for coating pharmaceutical dosage forms, consisting of a) 40-90% by weight of a polyvinyl alcohol-polyether graft copolymer (component A), b) 1-20% by weight of a polyvinylpyrrolidone or of a vinylpyrrolidone-vinyl acetate-copolymer with a K value of from 10 to 100 (component B) c) 10-60% by weight of organic or inorganic pigments having an average particle size of less than 8 ?m (component C) d) 0.5-15% by weight of a surfactant having an HLB of greater than 10 (component D) and e) 0-30% by weight of further customary coating ingredients (components E), in which the particles of component C are embedded in a coherent polymer matrix, where the total amount of components A to E is 100% by weight.Type: GrantFiled: June 22, 2005Date of Patent: September 19, 2017Assignee: BASF SEInventors: Karl Kolter, Maximilian Angel, Andreas Habich
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Patent number: 9758656Abstract: A soft touch composition comprises, based on the total weight of the composition, 50 to 88 wt % of a polymer comprising, based on the total weight of the polymer, 44 to 52 wt % of a polypropylene homopolymer, 3 to 30 wt % of an ethylene-propylene copolymer, and 22 to 52 wt % of an ethylene-C4 to C8 alpha olefin copolymer, and 10 to 40 wt % of glass fibers.Type: GrantFiled: August 27, 2014Date of Patent: September 12, 2017Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Jana Hrachova, Franciscus Elisabeth Jacobus Essers
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Patent number: 9309408Abstract: The invention is directed to an additive composition comprising at least one clarifying and/or nucleating agent for polyolefins, which agent is a powder having a melting point of at least 190° C., in an amount of at least 70 wt. %, based on the weight of the composition, and at least one wax having a viscosity, as defined herein of at least 500 m Pa·s, in an amount between 0.5 and 30 wt. %, based on the weight of the composition.Type: GrantFiled: August 14, 2012Date of Patent: April 12, 2016Assignee: HOLLAND COLOURS N.V.Inventors: Johannes Henricus Hurenkamp, Caspar Jules Albert Anton Roelofs, Jeroen Marissen
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Patent number: 9243123Abstract: Disclosed are a ?-crystal form nucleating agent composition for polypropylene and an application thereof. The composition is prepared by proportionally mixing barium tetrahydrophthalate, calcium tetrahydrophthalate and the like with adjuvants, such as hydrotalcite or calcium carbonate. The composition has better functions than a single-component ?-nucleating agent. The impact strength of polypropylene subjected to nucleation modification by the ?-crystal form nucleating agent composition can be improved by up to 6 times, and the heat distortion temperature is improved by about 10° C. to 20° C.; in addition, while the impact strength is improved, the flexural modulus of polypropylene can be improved, namely, the rigidity of polypropylene is improved. Therefore, the mechanical and thermal properties of polypropylene are improved.Type: GrantFiled: December 21, 2012Date of Patent: January 26, 2016Assignee: GCH TECHNOLOGY CO., LTD.Inventor: Wen lin Zhao
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Publication number: 20150135993Abstract: A method of treating particles by disaggregating, deagglomerating, exfoliating, cleaning, functionalising, doping, decorating and/or repairing said particles, in which the particles are subjected to plasma treatment in a treatment chamber containing a plurality of electrodes which project therein and wherein plasma is generated by said electrodes which are moved during the plasma treatment to agitate the particles.Type: ApplicationFiled: November 12, 2014Publication date: May 21, 2015Inventors: John Buckland, Dylan Walters
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Patent number: 9034950Abstract: The purpose of the present invention is to provide a rubber composition with which it is possible to produce a tire that retains wear resistance and has excellent frictional force on ice, and a pneumatic tire using the rubber composition. The rubber composition of the present invention is a rubber composition comprising a diene rubber, carbon black and/or a white filler, and a master batch prepared by premixing a non-diene rubber and an organic peroxide, wherein a total content of carbon black and white filler is from 20 to 70 parts by mass per 100 parts by mass of diene rubber and a content of the non-diene rubber in the master batch is from 3 to 30 parts by mass per 100 parts by mass of the diene rubber.Type: GrantFiled: August 19, 2011Date of Patent: May 19, 2015Assignee: The Yokohama Rubber Co., Ltd.Inventors: Satoshi Mihara, Katsunori Shimizu, Keisuke Maejima, Yayoi Akahori
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Publication number: 20150112008Abstract: Plasticizers of glycol ether-based cyclohexanoate esters and blends thereof with thermoplastic polymers, such as PVC, are disclosed.Type: ApplicationFiled: October 29, 2014Publication date: April 23, 2015Inventors: Abhimanyu O. Patil, Satish Bodige
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Patent number: 9006317Abstract: The present invention pertains to an additive combination comprising at least two sterically hindered amines, at least one further stabilizer, a dispersing agent and a plasticizer. The present invention also pertains to a composition comprising an organic material susceptible to degradation by light, oxygen and/or heat, and the additive combination and to the use and the process for stabilizing organic material against degradation by light, oxygen and/or heat by the additive combination.Type: GrantFiled: July 19, 2011Date of Patent: April 14, 2015Assignee: BASF SEInventors: Eva Peregi, Benno Blickenstorfer, Frank Oliver Heinrich Pirrung, Petr Kvita
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Patent number: 8969450Abstract: Modified rubber compositions containing an elastomer component and a modifier comprising a steroid and/or a peptide and methods of their production. Such modified rubber compositions can have improved properties and can be useful in making various articles of manufacture, such as, for example, in the manufacture of tires.Type: GrantFiled: December 1, 2010Date of Patent: March 3, 2015Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, Edward D. Kelley
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Publication number: 20140368588Abstract: A phase change ink composition including an amorphous compound; a crystalline compound; a polyester polymer, wherein the polyester has a molecular weight of from about 500 to about 8,000 and a polydispersity index of from about 1.0 to about 8.0; an optional synergist; an optional dispersant; and a colorant. A process including (1) incorporating into an ink jet printing apparatus the phase change ink composition; (2) melting the ink; and (3) causing droplets of the melted ink to be ejected in an imagewise pattern onto a substrate. An ink jet printer stick or pellet including the phase change ink composition.Type: ApplicationFiled: June 18, 2013Publication date: December 18, 2014Inventors: Barkev Keoshkerian, Valerie M. Farrugia, Jenny Eliyahu, Gordon Sisler, Biby Esther Abraham, Stephan V. Drappel
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Publication number: 20140343204Abstract: Processes for the production of compositions including esters and their hydrogenated derivatives are provided. The esters and the hydrogenated derivatives may be produced with among other things alcohols that are derived from biological sources such as photosynthetic microorganisms. The esters and/or the hydrogenated derivatives may be employed as plasticizers for polymeric compositions.Type: ApplicationFiled: June 7, 2012Publication date: November 20, 2014Inventors: Didier Naert, Allen D. Godwin
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Publication number: 20140275376Abstract: A unique monobenzoate useful as a plasticizer in polymeric dispersions, such as plastisols and melt compounds. The monobenzoate comprises 3-phenyl propyl benzoate, a benzoate ester heretofore known as a flavoring and fragrance agent, but not previously utilized as a plasticizer in polymeric applications. Depending on the application, the advantages rendered by the use of the inventive monobenzoate include, among other things, excellent solvating properties, low viscosity, viscosity stability, and improved rheology, as well as health, safety and environmental advantages over traditional plasticizers. The monobenzoate may be used alone or in combination with a variety of plasticizers, including but not limited to phthalates, terephthalates, dibenzoates, other monobenzoates, or 1,2-cyclohexane dicarboxylate esters, and mixtures thereof.Type: ApplicationFiled: May 30, 2014Publication date: September 18, 2014Applicant: EMERALD KALAMA CHEMICAL, LLCInventors: William D. ARENDT, Emily MCBRIDE
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Patent number: 8828181Abstract: Temperature switchable adhesives formed by combining a pressure sensitive adhesive, which does not exhibit temperature switchable properties, with a crystallizable oil are described. These temperature switchable adhesives exhibit a sharp reduction in peel strength when the temperature is raised above the switching temperature. The adhesive properties of these adhesives may be readily tuned by adjusting the ratio of the elastomer, tackifier, and the crystallizable oil, and by choosing different crystallizable oils. The temperature switchable adhesives have use in medical, consumer, and industrial applications.Type: GrantFiled: April 30, 2010Date of Patent: September 9, 2014Assignee: E I du Pont de Nemours and CompanyInventor: Robert Ray Burch
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Patent number: 8809482Abstract: This invention pertains to silsesquioxane resins useful in antireflective coatings wherein the silsesquioxane resin comprises the units (Ph(CH2)rSiO(3-x)/2(OR?)x)m (HSiO(3-x)/2(OR?)x)n (MeSiO(3-x)/2(OR?)x)o (RSiO(3-x)/2(OR?)x)p (R1SiO(3-x)/2(OR?)x)q where Ph is a phenyl group, Me is a methyl group; R? is hydrogen atom or a hydrocarbon group having from 1 to 4 carbon atoms; R is selected from a carboxylic acid group, a carboxylic acid forming group, and mixtures thereof; and R1 is selected from substituted phenyl groups, ester groups, polyether groups; mercapto groups, sulfur-containing organic functional groups, hydroxyl producing group, aryl sulphonic ester groups, and reactive or curable organic functional groups; and r has a value of 0, 1, 2, 3, or 4; x has a value of 0, 1 or 2; wherein in the resin m has a value of 0 to 0.90; n has a value of 0.05 to 0.99; o has a value of 0 to 0.95; p has a value of 0.01 to 0.5; q has a value of 0 to 0.5; and m+n+o+p+q?1.Type: GrantFiled: October 19, 2009Date of Patent: August 19, 2014Assignee: Dow Corning CorporationInventors: Peng-Fei Fu, Eric Moyer, Craig Yeakle
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Publication number: 20140155530Abstract: The present invention provides a fouling-resistant composition which comprises an elastomer and a component comprising sterol(s) and/or sterol derivative(s), wherein the component is selected from acylated lanolin, alkoxylated lanolin, or lanolin oil, or a composition comprising at least 20 weight % of one or more sterol(s), at least 20 weight % of one or more C1-C12 sterol ester(s), or at least 20 weight % of alkoxylated sterol(s), wherein weight % is the percentage of the sterol or sterol derivative to the total weight of the component.Type: ApplicationFiled: August 15, 2012Publication date: June 5, 2014Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.Inventors: Brent Vickers Tyson, Kevin John Reynolds
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Patent number: 8669311Abstract: C7-C12 secondary alcohol esters of cyclohexanecarboxylic acids are especially useful as plasticizers for PVC and other plasticizable polymers. In embodiments, these plasticizers are useful in plastisol formulations to help improved processability of flexible PVC material. In other embodiments these same plasticizers can be used in blends with other plasticizers to improve processability. In preferred embodiments these same plasticizers can be used to prepare flexible PVC compounds with enhanced low temperature flexibility, low toxicity, and improved resistance to outdoor aging.Type: GrantFiled: October 23, 2008Date of Patent: March 11, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Karla S. Colle, Jon E. R. Stanat, Juan J. Reinoso, Allen D. Godwin
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Patent number: 8653184Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations and processes of making these formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials, toys, and food contact articles.Type: GrantFiled: August 30, 2012Date of Patent: February 18, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Claudius P. Gosse, Thomas M. Larson, Pierre J. P. Legrand, Raphael F. Caers, Paul H. Daniels, Allen D. Godwin, Didier Naert
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Patent number: 8653171Abstract: Plastisol compositions are disclosed containing methacrylate core/shell copolymer, non-phthalate ester plasticizers, pigment, filler, and thixotropic agent. Other additives are optional. The plasticizer is a blend of dibenzoate and DINCH. The plastisol can be used an ink of various colors for use in application to textiles. The plastisol compositions avoid polyvinyl chloride polymer resins and phthalate plasticizers conventionally employed in plastisol inks.Type: GrantFiled: February 16, 2011Date of Patent: February 18, 2014Assignee: PolyOne CorporationInventors: James Hurley, James Kevin Seagraves, Erik Saly
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Patent number: 8637597Abstract: Rubber composition comprising at least one diene elastomer, one reinforcing filler and one 1,2-cyclohexanedicarboxylate diester plasticizer corresponding to the formula (R hydrocarbon radical): The invention also relates to the use of such a composition in the manufacture of a tire or of a tire semi-finished product made of rubber, in particular of a tire tread exhibiting an improved wet grip, without adversely affecting its other properties; it also relates to the tires and semi-finished products themselves and to a plasticizing system comprising, in combination, the said diester plasticizer and a plasticizing hydrocarbon resin, the glass transition temperature (Tg) of which is greater than 0° C.Type: GrantFiled: May 13, 2008Date of Patent: January 28, 2014Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.Inventor: Garance Lopitaux
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Publication number: 20140011929Abstract: A thermoplastic elastomer composition, containing a) 5 to 99 wt % of a block copolymer, which is constructed of hard blocks (A) made of vinyl aromatic monomers and one or more random soft blocks (B) of non-hydrogenated or hydrogenated block copolymer materials made of dienes and vinyl aromatic monomers, b) 1 to 95 wt % of a plasticizer having a higher polarity than white oil and a lower polarity than dinonyl adipate, c) 0 to 50 wt % of a polyolefin, and d) 0 to 60 wt % of additives, has advantageous properties in regard to processability.Type: ApplicationFiled: December 20, 2011Publication date: January 9, 2014Applicant: BASF SEInventors: Konrad Knoll, Boris Breitscheidel, Ulrik Stengel
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Publication number: 20130343808Abstract: Disclosed is a high-density polyethylene (HDPE) composition that comprises at least a first high density polyethylene component having a density of 0.940-0.968 g/cm3 and a melt index I2.16 of 0.5-10.0 dg/min and a melt flow ratio (flow index I21.6 at 190° C. divided by melt index I2.16 at 190° C.) of at least 25. A second HDPE component may be included in the composition with melt index I2.16 of greater than 10 dg/min and melt flow ratio of 30 or less. The disclosed compositions are suitable for use in living hinge closure applications.Type: ApplicationFiled: June 10, 2013Publication date: December 26, 2013Inventors: Brett Christopher Domoy, Barrett Albert Unger, Mark T. Joblonka
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Patent number: 8604114Abstract: Provided is a process for making non-phthalate plasticizers, by acylating an aromatic compound with a succinic anhydride to form a keto-acid, and then esterifying the keto-acid with C4-C13 OXO-alcohols to form a plasticizer compound. The aromatic rings of the aromatic compound may also be optionally hydrogenated.Type: GrantFiled: July 21, 2010Date of Patent: December 10, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Jihad Mohammed Dakka, Edmund John Mozeleski, Lisa Saunders Baugh, Karla Schall Colle, Allen David Godwin, Diana S. Smirnova, Jörg Friedrich Wilhelm Weber, Stephen Zushma
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Publication number: 20130310499Abstract: There are provided an exfoliated graphite oxide derivative excellent in dispersibility in a thermoplastic resin, a resin composite material of the exfoliated graphite oxide derivative and a thermoplastic resin, and a process for producing the resin composite material. The exfoliated graphite oxide derivative is obtained by reacting an exfoliated graphite oxide having a C/O ratio as determined by elemental analysis of 8 or less with a compound having a specific structure.Type: ApplicationFiled: March 13, 2012Publication date: November 21, 2013Inventors: Keiichi Osano, Katsunori Takahashi
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Publication number: 20130267639Abstract: This invention is directed to a thermoplastic polyurethanes composition comprising polyether-based thermoplastic polyurethane and 1,2-cyclohexane dicarboxylic acid ester and preparation processes thereof. The thermoplastic polyurethane composition has a good mold release behavior in injection molding without undesirably significant shrinkage and surface blooming of final product.Type: ApplicationFiled: April 5, 2013Publication date: October 10, 2013Applicant: BASF SEInventors: Wei ZHUANG, Bin Chen, Akira Nomura, Etsuhiro Yamamoto, Jianqiang Qu, Michi Kondo, Tienkuan Lim, Frank Schaefer
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Patent number: 8546604Abstract: The invention relates to a diol-ester based plasticizer prepared by reacting a diol and a carboxylic acid for use with a polyvinyl chloride resin composition to impart improved physical properties, such as hardness and tensile strength.Type: GrantFiled: September 4, 2009Date of Patent: October 1, 2013Assignees: SK Innovation Co., Ltd., SK Global Chemical Co., Ltd.Inventors: Hao Wang, Seung Gweon Hong, Tae Wook Kwon, Jae Suk Koh
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Publication number: 20130237939Abstract: Novel solid benzoate ester compositions are mixtures comprising the trans- and cis-structural isomers of 1,4-cyclohexanedimethanol dibenzoate wherein the trans isomer constitutes from 1 to 66 or from 72 to 99 weight percent of the mixture. The properties imparted to a variety of polymer compositions, including hot melt adhesives, cannot be achieved using the commercially available mixture of these isomers.Type: ApplicationFiled: April 25, 2013Publication date: September 12, 2013Applicant: Eastman Specialties Holdings CorporationInventors: William D. Arendt, Makarand V. Joshi, Yvonne Aileen Berry-Walker, Paul Steven Lakomiak, Mirnahini Jeganathan
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Publication number: 20130225737Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations and processes of making these formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials, toys, and food contact articles.Type: ApplicationFiled: August 30, 2012Publication date: August 29, 2013Inventors: Claudius P. Gosse, Thomas M. Larson, Pierre J.P. Legrand, Raphael F. Caers, Paul H. Daniels, Allen D. Godwin, Didier Naert
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Publication number: 20130197140Abstract: It has been discovered that the use of a plasticizer, an ester of a cyclohexanepolycarboxylic acid, especially a 1,2-cyclohexanedicarboxylic acid ester, that is environmentally non-toxic, can replace environmentally unfriendly phthalate plasticizers, such as dioctyl phthalates used in vulcanizable rubber compositions, especially for tires, on a one to one weight basis (phr) without sacrificing beneficial rubber properties.Type: ApplicationFiled: February 25, 2013Publication date: August 1, 2013Applicant: BRIDGESTONE CORPORATIONInventor: Bridgestone Corporation
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Publication number: 20130171385Abstract: Multi-esters of the formula: wherein each R1 is the hydrocarbon residue of a C4 to C13 OXO-alcohol averaging from 0.2 to 5.0 branches per residue, and R2 is hydrogen or an ester group, processes of making the multi-esters, use of the multi-esters as plasticizers, polymer compositions containing such plasticizers, and articles containing such plasticizers.Type: ApplicationFiled: December 21, 2012Publication date: July 4, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventor: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
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Publication number: 20130165561Abstract: A polarizing plate and an optical member, the polarizing plate including an adhesive layer, the adhesive layer being prepared from an adhesive composition including a (meth)acrylic copolymer, a crosslinking agent, and a tackifier, the tackifier including an acrylic modified petroleum resin represented by Formula 1: R?—CO—O—R??[Formula 1] wherein R? is a petroleum resin and R is a C1-C20 alkyl group or a C6-C50 aryl group.Type: ApplicationFiled: December 27, 2012Publication date: June 27, 2013Inventors: Won KIM, Yi Eun KIM, Chul JEONG, Ri Ra JUNG, Hae Ryong CHUNG