Oh Group Other Than As Part Of A Cooh Group, E.g., Salicylic Acid, Etc. Patents (Class 524/291)
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Patent number: 5045586Abstract: The present invention is directed to branched polyesters derived from the reaction product of hydroxy stearic acid or hydroxy stearic alkoxylate, a guerbet alochol or guerbet alcohol alkoxylate, which product is further reacted with a polycarboxylic acid to provide the required branching in the polyester structure. The invention is also directed to the preparation, compositions and application of said internal plastic lubricants, particularly suited for use in forming of polycarbonate thermoplastics.Type: GrantFiled: May 1, 1989Date of Patent: September 3, 1991Inventor: Anthony J. O'Lenick, Jr.
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Patent number: 5032442Abstract: Disclosed herein is a fibrillated weatherproof web having a network structure, which can be produced with ease and is economical. The web comprises a multilayer composite film composed of at least two layers, one being a first layer (I) made of a first thermoplastic resin and the other a second layer (II) made of a second thermoplastic resin having a melting point lower than the first thermoplastic resin and containing at least 300 ppm of a light resistance imparting agent. A number of slits have been formed in a longitudinal or transverse direction. The web has been oriented at a draw ratio in a range of from 1.1 to 15 times. A nonwoven fabric making use of one or more fibrillated webs of the above sort and processes for the production of the web and nonwoven fabric are also disclosed.Type: GrantFiled: October 17, 1989Date of Patent: July 16, 1991Assignee: Nippon Petrochemicals Company, Ltd.Inventors: Shinji Yamazaki, Toshio Kotsuka
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Patent number: 5032633Abstract: Thermoplastic molding compositions that contain(A) 10 to 90 parts by weight of polyamide 12, and 90 to 10 parts by weight of polyamide 10,12 and/or polyamide 12,12; and(B) 0 to 25 wt. % of a plasticizer, exhibit improved low temperature impact strength. The molding compositions may be used for the production of molded objects, especially tubes.Type: GrantFiled: February 28, 1990Date of Patent: July 16, 1991Assignee: Huels AktiengesellschaftInventors: Michael Schlobohm, Franz-Josef Schlautmann
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Patent number: 5032634Abstract: Vinyl halide resins can be stabilized by a stabilizer mixture of a monomeric tetrafunctional organotin stabilizer and a hindered tris phenol antioxidant, preferably 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane.Type: GrantFiled: December 2, 1988Date of Patent: July 16, 1991Assignee: Akzo America Inc.Inventor: Steven Walter
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Patent number: 5032632Abstract: A composition of a copolymer of ethylene and vinyl alcohol, 0.01 to 0.5 weight percent of a monovalent or divalent metal salt of an aliphatic carboxylic acid having 3 to 9 carbon atoms and 0.05 to 0.5 weight percent of a hindered phenolic antioxidant exhibits improved stability toward oxidative gel formation at elevated temperatures.Type: GrantFiled: May 15, 1990Date of Patent: July 16, 1991Assignee: E. I. du Pont de Nemours and CompanyInventor: Ronald L. Saxton
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Patent number: 5030672Abstract: An asymmetric membrane formed from a sulphonated polyarylethersulphone has a salt rejection of at least 99%. Alternatively, a membrane has a good salt rejection and an acceptable water flux such that the ratio ##EQU1## has the value of at least 0.7. The membranes can be obtained using barium salts of the sulphonated polyarylethersulphone, with the proportion of barium being controlled to be at least 85%, preferably at least 86%, and not more than 91%, preferably not more than 90% of the barium required to react with the sulphonic acid groups on the sulphonated polymer.Type: GrantFiled: October 1, 1990Date of Patent: July 9, 1991Assignee: Imperial Chemical Industries PLCInventors: Richard A. Hann, David R. Holmes, John W. Smith
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Patent number: 5025049Abstract: A primer composition dilluted with a suitable organic solvent comprising (A) an organic copolymer comprising an alkoxysilylated monomer, vinyl acetate and other monomers copolymerizable therewith, (B) a polyalkyl (meth)acrylate, (C) a crosslinking agent for said copolymer (A), and (D) an ultraviolet absorber. This primer composition is a very effective primer in forming an organopolysiloxane coating layer excellent in adhesion, endurance, weathering resistance of the surface of a molded article of a thermoplastic resin.Type: GrantFiled: May 30, 1990Date of Patent: June 18, 1991Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Mitsuhiro Takarada, Kazuharu Sato
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Patent number: 5023284Abstract: This invention is directed to a stabilizer useful to retard transesterification in moldable polymer blends containing polyester(s) during processing of the blends at elevated temperatures, particularly at high temperatures above about 285.degree. C. More particularly, the stabilizer comprises a phosphate-epoxy adduct. The stabilizer may optionally further comprise a reactive functionality component comprising a compound having a imide or oxazoline functionality and/or a hindered phenol component. The invention is also directed to a composition comprising the stabilizer and a particularly defined polymer blend.Type: GrantFiled: August 9, 1989Date of Patent: June 11, 1991Assignee: Ford Motor CompanyInventors: Mo-Fung Cheung, Amos Golovoy, Henk van Oene
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Patent number: 5011879Abstract: An engineering plastic composition with excellent flowability, heat stability, and desirable mechanical properties is provided. The composition comprises an engineering plastic material and at least one p-quaterphenyl derivative of specific formula.Type: GrantFiled: May 25, 1989Date of Patent: April 30, 1991Assignees: Sekisui Kagaku Kogyo Kabushiki Kaisha, Kabushiki Kaisha Sanko Kaihatsu Kagaku KenkyushoInventors: Toshio Uesaka, Akihiro Niki, Makoto Ohsuga, Toranosuke Saito, Hiroki Tsunomachi, Makoto Yamaguchi, Kazuo Doyama, Daishiro Kishimoto
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Patent number: 5008312Abstract: Bislactams of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another are each C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4 form a tetra- or pentamethylene radical, and R.sup.5 is hydrogen, carbonyl-C.sub.1 -C.sub.8 -alkyl, benzoyl, C.sub.1 -C.sub.8 -alkyl, C.sub.7 -C.sub.10 -phenylalkyl, the phenyl nucleus being unsubstituted or substituted by one or two C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkyoxy, fluorine, chlorine or bromine radicals, or is C.sub.1 -C.sub.3 -cyanoalkyl, C.sub.2 -C.sub.4 -hydroxyalkyl or C.sub.2 - or C.sub.3 -aminoalkyl, and the acid addition salts and hydrates of these compounds.The compounds (I) are stabilizers for organic materials.Type: GrantFiled: August 7, 1989Date of Patent: April 16, 1991Assignee: BASF AktiengesellschaftInventors: Alexander Aumueller, Peter Neumann, Hubert Trauth
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Patent number: 4996244Abstract: Compounds having defined functional groups are described which color stabilize aromatic carbonate polymers or blends therewith upon exposure to sterilizing radiation.Type: GrantFiled: October 20, 1989Date of Patent: February 26, 1991Assignee: General Electric CompanyInventor: Roger W. Avakian
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Patent number: 4992499Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of a stabilizing amount of a combination of a phenolic compound and an aromatic amine.Type: GrantFiled: November 30, 1989Date of Patent: February 12, 1991Assignee: Shell Oil CompanyInventors: Johannes L. M. Syrier, Hendrik Van De Weg, Robert Q. Kluttz
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Patent number: 4985479Abstract: A stabilized polyolefin composition having improved weathering resistance is provided, whereby the following four components are incorporated into a polyolefin:(A) a hindered piperidine compound having a molecular weight of more than 750, such as poly-{[6-morpholino-1,3,5-triazine-2,4-diyl][2,2,6,6-tetramethyl-4-piperid yl)imino]hexamethylene[2,2,6,6-tetramethyl-4-piperidyl)imino]},(B) a hindered piperidine compound having a molecular weight of less than 500, such as bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate,(C) a benzoate compound such as 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate, and(D) a phosphorus-containing compound such as bis(2,4-di-t-butylphenyl) pentaerythritol diphosphite.Type: GrantFiled: March 28, 1989Date of Patent: January 15, 1991Assignee: Sumitomo Chemical Company, Ltd.Inventors: Hideo Nagasaki, Shinichi Yachigo, Takeshi Takata, Hiroki Yamamoto, Yukoh Takahashi
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Patent number: 4983654Abstract: This invention is directed to a stabilizer useful to retard transesterification in moldable polymer blends containing polyester(s) during processing of the blends at elevated temperatures, particularly at high temperatures above about 285.degree. C. More particularly, the stabilizer comprises a phosphate-epoxy adduct. The stabilizer may optionally further comprise a reactive functionality component comprising a compound having a imide or oxazoline functionality and/or a hindered phenol component. The invention is also directed to a composition comprising the stabilizer and a particularly defined polymer blend.Type: GrantFiled: December 28, 1987Date of Patent: January 8, 1991Assignee: Ford Motor CompanyInventors: Mo-Fung Cheung, Amos Golovoy, Henk van Oene
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Patent number: 4981892Abstract: A thermoplastic resin composition comprising 0.01 to 10 parts by weight of at least one ultraviolet ray absorbent having a peak absorption wavelength at 240-300 nm in the range of 240-400 nm and 100 parts by weight of methacrylimide group-containing polymer containing at least 5% by weight of imide ring structural unit expressed by the following structural formula is disclosed: ##STR1## (wherein R.sub.1 is a hydrogen atom, or a substituted or non-substituted alkyl group having 1-20 carbon atoms, cycloalkyl group, aryl group, alkalyl group, alalkyl group, or allyl group.)This composition has an improved weather durability and thermal resistance as well as light transmittance.Type: GrantFiled: May 10, 1989Date of Patent: January 1, 1991Assignee: Mitsubishi Rayon Company, LimitedInventors: Kozi Nishida, Mikiharu Watanabe
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Patent number: 4972019Abstract: A water-absorbent resin composition having superior gel stability which comprises a water-absorbent resin, at least one oxygen-containing reducing inorganic salt and, optionally, at least one organic antioxidant.Type: GrantFiled: June 20, 1989Date of Patent: November 20, 1990Assignee: Seitetsu Kagaku Co., Ltd.Inventors: Shigeji Obayashi, Morio Nakamura, Takushi Yamamoto, Hitoshi Tanaka, Yuji Sakamoto
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Patent number: 4972014Abstract: Incorporation into polyacetal molding compositions stabilized with a non-meltable polymer stabilizer of 0.02-1.0 weight percent of at least one amide-containing phenolic antioxidant results in significantly improved long term stability, as evidenced by greater retention of physical properties over time, of such compositions.Type: GrantFiled: June 15, 1989Date of Patent: November 20, 1990Assignee: E. I. du Pont de Nemours and CompanyInventors: Richard A. Hayes, Leonard E. R. Kosinski, Mark E. Wagman
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Patent number: 4972015Abstract: Disclosed is a shaped, thin-walled, thermoformed, heat-set article, the composition of which comprises:(a) a crystallizable polyester having repeating units from at least 90 mol % terephthalic acid and repeating units from at least 90 mol % 1,4-cyclohexanedimethanol, the total dicarboxylic acid mol % and the total glycol mol % each being 100 mol %, said polyester having an inherent viscosity of about 0.7-1.1, and(b) a heat stabilizing amount of an antioxidant system comprising a hindered phenol, a thio ester or ether and a phosphate salt.Type: GrantFiled: July 24, 1989Date of Patent: November 20, 1990Assignee: Eastman Kodak CompanyInventors: Joey C. Carico, Wayne P. Pruett, Raymond N. Vachon
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Patent number: 4966960Abstract: A process and nylon release sheet for manufacturing printed circuit boards from epoxy prepregs is disclosed. In such process layers of the prepregs are separated from one another by a release sheet. The release sheet comprises an aliphatic or aromatic nylon or nylon copolymer which is a condensation product of a dicarboxylic acid and a diamine. The nylon film contains a heat stabilizer and an inorganic particulate antiblock additive, e.g. diatomaceous earth, glass beads, amorphous silica, talc, mica and molybdenum disulphide. The nylon may be toughened by the addition of a phosphorus-containing catalyst or an epoxide.Type: GrantFiled: November 2, 1988Date of Patent: October 30, 1990Assignee: Du Pont Canada Inc.Inventors: Peter A. Sipos, Erica M. Besso
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Patent number: 4963607Abstract: Polyolefins are stabilized against the harmful effects of U.V.-light by incorporating therein certain organosulfides. The organosulfides may be used alone or in synergistic combination with two classes of known light stabilizers, namely the benzophenones and the esters of aromatic acids.Type: GrantFiled: June 13, 1989Date of Patent: October 16, 1990Assignee: Pennwalt CorporationInventors: James L. Reilly, Joseph M. Bohen
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Patent number: 4963606Abstract: This invention relates to a styrenic polymer-based thermoplastic formulation containing a brominated cycloaliphatic flame retardant and a thermal stabilizer system comprising an organotin stabilizer, a hindered phenolic antioxidant and, optionally, a polyhydroxy aliphatic compound.Type: GrantFiled: September 6, 1989Date of Patent: October 16, 1990Assignee: Ethyl CorporationInventor: Robert A. Schleifstein
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Patent number: 4960812Abstract: Polyester resin compounds useful as plastic materials which demonstrate good surface characteristics, excellent physical properties and outstanding formability, particularly when processed at a temperature lower than 100.degree. C. are disclosed. Superior characteristics are achieved by accelerating the speed of crystallization thereof by incorporating additives so that crystallization is completed throughout the product.Type: GrantFiled: October 31, 1988Date of Patent: October 2, 1990Assignee: Sam Yang Co., Ltd.Inventors: Han S. Youn, Kim Dong, II, Choi I. Gyu
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Patent number: 4960808Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of certain phenolic compounds.Type: GrantFiled: March 30, 1988Date of Patent: October 2, 1990Assignee: Shell Oil CompanyInventor: Andre Schmitter
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Patent number: 4959403Abstract: A thermoplastic molding composition having good cold impact strength properties, consisting essentially of (I) a polyamide 1212 having a relative viscosity in the range of from 1.5 to 3.0, and (II) 2 to 25% by weight, based on the polyamide, of a plasticizer.Type: GrantFiled: October 24, 1988Date of Patent: September 25, 1990Assignee: Huels AktiengesellschaftInventors: Martin Bartmann, Roland Feinauer, Uwe Hartkopf, Michael Schlobohm
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Patent number: 4957956Abstract: A solid stabilizer composition for organic polymers is formed by a solid, continuous phase and by a dispersed phase in said continuous phase, wherein the continuous phase is constituted by amorphous tetrakis-[3-(3,5-di-tert.-butyl-4-hydroxyphenyl)-propionyloxymethyl]-metha ne and the dispersed phase is constituted by an either amorphous or crystalline organic phosphite, in the form of particles with a particle size of from 10 .mu.m to 2 mm, with the weight ratio of said continuous phase to said dispersed phase being comprised within the range of from 9:1 to 1:9.The processes for preparing said solid stabilizer composition and its use in the stabilization of organic polymers are disclosed.Type: GrantFiled: February 11, 1988Date of Patent: September 18, 1990Assignee: Enichem Synthesis S.p.A.Inventors: Carlo Neri, Nereo Nodari, Erik Bersanetti, Giovanni Sandre
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Patent number: 4958006Abstract: Method and apparatus for the post reaction treatment of resins produced by fluidized bed polymerization of alpha olefins wherein an extruder is coupled in communication with the reactor and all necessary devolatilization of monomer, deactivation of catalysts and addition of additives are performed in the extruder.Type: GrantFiled: June 28, 1988Date of Patent: September 18, 1990Assignee: Union Carbide Chemicals and Plastics Inc.Inventors: Robert J. Bernier, Jorge O. Buhler-Vidal, Urho S. Haapala, Benjamin R. Rozenblat
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Patent number: 4956408Abstract: A conjugated diene/monovinyl substituted aromatic hydrocarbon copolymer is stabilized by the addition of a complex acrylate, in combination with at least one of an alkyl thiopropionate, an organic phosphite and a non-acrylate substituted hindered phenolic compound.Type: GrantFiled: June 13, 1988Date of Patent: September 11, 1990Assignee: Phillips Petroleum CompanyInventors: Ronald D. Mathis, Alonzo G. Kitchen, Frank J. Szalla
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Patent number: 4954548Abstract: Compositions comprising linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against degradation caused by exposure to UV light by the inclusion therein of an aromatic diamine and a certain type of carbon black.Type: GrantFiled: April 27, 1989Date of Patent: September 4, 1990Assignee: Shell Oil CompanyInventor: George B. Klingensmith
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Patent number: 4945017Abstract: A composition for conversion of a rusted metal surface to form a durable coating thereon consists essentially of a reducing agent which reduces an trivalent iron present on the surface, an organic monomer to which is capable of polymerization on the surface in the presence of the reducing agent and a free radical initiator which polymerizes the organic monomer to form the durable coating.Type: GrantFiled: March 3, 1989Date of Patent: July 31, 1990Assignee: Pennzoil Products CompanyInventors: Paul J. DesLauriers, William J. Heilman
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Patent number: 4939196Abstract: A compound represented by the formula of ##STR1## wherein R.sub.1 represents an alkyl having 1 to 5 carbon atoms;R.sub.2 represents an alkyl having 1 to 18 carbon atoms, an alkenyl having 2 to 5 carbon atoms, an aralkyl having 7 to 9 carbon atoms, phenyl, an aliphatic acyl having 2 to 5 carbon atoms, or benzoyl;R.sub.3 represents hydrogen or an alkyl having 1 to 11 carbon atoms; andR.sub.4 represents hydrogen or methyl.The compound is useful as a stabilizer for synthetic resins such as butadiene polymers. The butadiene polymer containing the compound is stable against thermal deterioration in the absence of oxygen, as well as against thermal oxidative deeterioration and thermal oxidative discoloration.Type: GrantFiled: December 30, 1988Date of Patent: July 3, 1990Assignee: Sumitomo Chemical Company, LimitedInventors: Manji Sasaki, Shinichi Yachigo, Kikumitsu Inoue, Shinya Tanaka, Fumitoshi Kojima, Takeshi Takata
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Patent number: 4937138Abstract: A hot melt adhesive, a laminar structure, and non-woven article fabricated from a blend comprising:from about 50 percent by weight to about 5 percent by weight of a butene-1 homopolymer or copolymer;from about 50 percent by weight to about 95 percent by weight of a tackifying resin;from a 0.01 to about 1 phr of a nucleating agent;up to about 1 part per hundred (phr) of a stabilizer;up to about 30 phr of a plasticizer; andup to about 30 phr of a wax.Type: GrantFiled: February 29, 1988Date of Patent: June 26, 1990Assignee: Shell Oil CompanyInventor: Simon Mostert
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Patent number: 4935275Abstract: A polyurethane material for decorative parts is disclosed which is a tow-liquid type material comprising a polyol component and an isocyanate component and having a stabilizer incorporated in the polyol component. The stabilizer is a ternary system of a specific hindered amine type ultraviolet stabilizer, a specific hindered phenol type antioxidant, and a specific benzotriazole type ultraviolet absorbent or acrylontrile type ultraviolet absorbent. A transparent synthetic resin part formed by potting this polyurethane material on the upper surface of a base excels in weatherability and lightfastness. Thus, the present invention provides decorative parts which retain good appearance for a long time.Type: GrantFiled: April 6, 1988Date of Patent: June 19, 1990Assignee: Toyoda Gosei Co., Ltd.Inventors: Yoshio Ushida, Shinji Jinushi, Yoshio Yamazaki
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Patent number: 4923916Abstract: Tetrahalophthalate esters are disclosed herein as flame retardant processing aids for polystyrene resins.Type: GrantFiled: July 19, 1988Date of Patent: May 8, 1990Assignee: Pennwalt CorporationInventors: Joseph M. Bohen, Ronald F. Lovenguth
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Patent number: 4923915Abstract: UV-curable urethane-acrylate resin systems of improved thermal stability in the cured state are provided, the resins being of polyurethane acrylate, polyurea acrylate, and/or polyurethane/polyurea acrylate composition and being thermally stabilized by the addition of a combination of stabilizers which includes a hindered piperidine derivative and a hindered phenol derivative. The stabilized resin systems, useful for example for the protective coating of glass optical fibers, retain their rapid UV curing characteristics.Type: GrantFiled: May 18, 1988Date of Patent: May 8, 1990Assignee: Corning IncorporatedInventor: Eric H. Urruti
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Patent number: 4921623Abstract: A copper-type conductive coating composition which comprises:(A) a copper powder,(B) a coating binder resin, and(C) at least one number selected from the group consisting of salicylic acid, its specific derivatives, and benzotriazolecarboxylic acid hydrazides.The copper-type conductive coating composition provides a conductive coating layer having excellent initial conductivity and capable of maintaining the level of it stable over a long period of the time.Type: GrantFiled: July 21, 1988Date of Patent: May 1, 1990Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Shoji Yamaguchi, Kimiko Yamada, Katsuyoshi Yada, Koichi Sakaguchi, Hiromu Inoue
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Patent number: 4918124Abstract: Stabilizing mixtures, acting synergistically, of phenolic antioxidants and sulphur-containing polymers having terminal thioalkyl groups.Type: GrantFiled: November 17, 1986Date of Patent: April 17, 1990Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Alfred Pischtschan, Karl-Heinz Ott
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Patent number: 4912156Abstract: A polyolefin composition comprises 100 parts by weight of a polyolefine which has been produced with use of a Ziegler catalyst and has a part or residue of the catalyst left therein, 0.005 to 1 part by weight of a phenol compound having the formula (I) and 0.005 to 1 part by weight of an organic phosphite compound having the formula (II). ##STR1## in which R is a residue group of an alcohol being monohydric, dihydric, trihydric or terahydric, R1 is methyl or tert.-butyl, R2 is an alkyl, --CH2CH2COOR3 or --COOR3, R3 being an alkyl, an aryl or an alkylaryl, and n is a number of 1 to 4.Type: GrantFiled: July 27, 1988Date of Patent: March 27, 1990Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Masaki Yagi, Tohru Haruna, Takashi Takeuchi, Toshinori Yukino
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Patent number: 4910239Abstract: The present invention comprises a screen printing ink or coating composition that includes methyl salicylate combined with a resin composition. In the case of ink the composition further includes pigments. The methyl salicylate acts as a solvent and functions to dissolve the resin and pigment compositions.Type: GrantFiled: July 11, 1988Date of Patent: March 20, 1990Inventor: David W. Crabtree
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Patent number: 4898901Abstract: Long chain N-alkyl-alpha-alkyl nitrones represent particularly valuable process stabilizers for polyolefin compositions. The nitrone derived from the long chain alkyl mixture present in di(hydrogenated tallow)amine is especially useful for this purpose.Type: GrantFiled: March 23, 1989Date of Patent: February 6, 1990Assignee: Ciba-Geigy CorporationInventors: Ramanathan Ravichandran, Stephen D. Pastor, Raymond Seltzer, Ambelal R. Patel
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Patent number: 4895884Abstract: There is disclosed the use of microencapsulated antidegradants in rubber and a process for the production of microencapsulated antidegradants. More specifically, this invention is directed to the cellulose acetate microencapsulation of para-phenylene diamine based antiozonants at wall to core ratios greater than 1:1 but less than 4:1. The microcapsules preferably have a particle diameter of less than 50 microns. The microencapsulated antidegradant prepared and used according to this invention provides long term protection to rubber articles that are subject to ozone and oxygen attack.Type: GrantFiled: October 6, 1987Date of Patent: January 23, 1990Assignee: The Goodyear Tire & Rubber CompanyInventors: David A. Benko, Larry R. Evans, James G. Gillick, Walter H. Waddell, Barbara A. Metz, Benjamin F. Benton, Gordon E. Pickett, William R. Krumm
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Patent number: 4894399Abstract: Light-stabilized polymer microparticles, which contain at least one light stabilizer and free epoxy groups, and processes for the preparation of these microparticles by polymerization of suitable monomers, at least one of these monomers being an epoxide which contains at least one further reactive group, and at least part of the polymerization being carried out in the presence of at least one light stabilizer, are described. The polymer microparticles can be used in coating compositions which comprise a disperse phase, containing these particles, and a liquid continuous phase.Coatings and paints based on the compositions according to the invention are distinguished by improved weathering resistance, in particular high light stability.Type: GrantFiled: June 3, 1988Date of Patent: January 16, 1990Assignee: Ciba-Geigy CorporationInventors: Jean Rody, Mario Slongo, Franciszek Sitek, Andreas Valet
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Patent number: 4889879Abstract: Coherent thermoplastic aggregates with very high content of pulverized mineral materials, composed of the said materials, of polyolefin polymers and/or copolymers, and possibly also of various familiar adjuvants, characterized by the fact that, in order for them to have both a volumetric mass close to or at most equal to the theoretical volumetric mass of the pulverized mineral substances entering into their composition and an excellent compatibility with redispersion polymers, the polymers and/or copolymers entering into the composition of the said aggregates in presence of a fluidizing agent are chosen within the group of thermoplastics with melting and/or softening point at least equal to 60.degree. C. and index of fluidity at least 50 (measured according to the standard ASTM D 1238) of the polyolefin type, other than those containing a polar monomer.Type: GrantFiled: July 24, 1987Date of Patent: December 26, 1989Assignee: Pluess Staufer AGInventors: Henry Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
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Patent number: 4885326Abstract: A synthetic resin composition comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic alkylphosphite compound of 2,2'-alkylidene-bisphenol (I) and 0.001 to 10 parts by weight of beta-(3,5-dialkyl-4-hydroxyphenyl)-propionic acid ester (II) and is stabilized to light and heat.Type: GrantFiled: March 24, 1989Date of Patent: December 5, 1989Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Tohru Haruna, Kazunori Nishikawa, Mitsuhiro Hamajima
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Patent number: 4880854Abstract: Compounds having defined triazine functional groups are described which color stabilize aromatic carbonate polymers or blends therewith upon exposure to sterilizing radiation.Type: GrantFiled: December 22, 1987Date of Patent: November 14, 1989Assignee: General Electric CompanyInventor: Roger W. Avakian
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Patent number: 4880859Abstract: Light-stabilized star polymer microparticles are described which are prepared with particular advantage by group transfer polymerization. The light stabilization is effected by carrying out at least a part step of the polymerization in the presence of a light stabilizer, for example a hindered amine or/and a UV absorber. With particular advantage, those light stabilizers are used which contain reactive groups in the molecule and, in this way, can be chemically incorporated into the polymer. The polymer microparticles show excellent light stability and are outstandingly suitable as constituents in coating compositions which can be processed, for example, to give coating films of high light stability.Type: GrantFiled: June 3, 1988Date of Patent: November 14, 1989Assignee: Ciba-Geigy CorporationInventors: Mario Slongo, Jean Rody, Franciszek Sitek, Andreas Valet
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Patent number: 4879141Abstract: The present invention includes:(i) a method for making a coated particulate comprising the steps ofheating until liquid a polyolefin wax;fluidizing with a hot gas, additive particles selected from the group comprising an antioxidant, a processing stabilizer, an acid acceptor, and mixtures thereof;spraying the liquid polyolefin wax on the heated fluidized additive particles; andmaintaining the fluidized additive particles at a temperature which is sufficient to prevent the formation of fibers and adequate to form discrete substantially coated additive particles;(ii) a coated particulate made by the above process; and(iii) a process for providing in-reactor stabilization of a polyolefin during a polymerization reaction, using the coated additives prepared by the above described method.Type: GrantFiled: December 27, 1988Date of Patent: November 7, 1989Assignee: Shell Oil CompanyInventor: Ananda M. Chatterjee
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Patent number: 4876300Abstract: Long chain N,N-dialkylhydroxylamines represent particularly valuable process stabilizers for polyolefin compositions. The hydroxylamine derived from di(hydrogenated tallow)amine is particularly useful for this purpose. These long chain N,N-dialkylhydroxylamines are very resistant to extraction from polyolefin compositions.Type: GrantFiled: December 30, 1987Date of Patent: October 24, 1989Assignee: Ciba-Geigy CorporationInventors: Raymond Seltzer, Ramanathan Ravichandran, Ambelal R. Patel
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Patent number: 4874804Abstract: Hot melt packaging adhesive compositions consisting essentially of 35 to 45% by weight of an ethylene n-butyl acrylate copolymer containing 25-45% by weight, preferably 30 to 40% n-butyl acrylate and having a melt index of at least 50; 35 to 55% of a terpene phenolic tackifier; and 10 to 20% by weight of a high melting synthetic wax provide adhesives characterized by an excellent balance of high and low temperature performance without sacrifice to machinability or thermal stability.Type: GrantFiled: August 24, 1988Date of Patent: October 17, 1989Assignee: National Starch and Chemical CorporationInventors: Francis X. Brady, Thomas F. Kauffman
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Patent number: 4874808Abstract: Compositions comprising (A) cycloolefin random copolymer containing an ethylene component, and a cycloolefin component represented by the general formula [I] or [II] and having an intrinsic viscosity of 0.05-10 dl/g as measured at 135.degree. C. in decalin and a softening temperature (TMA) not lower than 70.degree. C., and (B) a cycloolefin random copolymer containing an ethylene component, and a cycloolefin component represented by the general formula [I] or [II] and having an intrinsic viscosity of 0.01-5 dl/g as measured at 135.degree. C. in decalin and a softening temperature (TMA) of below 70.degree. C., the weight ratio of said (A) component/(B) component ranging from 100/0.1 to 100/10.The composition is particularly useful for molding an information recording base board.Type: GrantFiled: April 29, 1988Date of Patent: October 17, 1989Inventors: Syuji Minami, Keiji Kawamoto, Tetsuji Kasai, Toshiaki Kuroiwa, Akira Todo
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Patent number: 4861814Abstract: A polyoxymethylene composition comprises an antioxidant of 0.05 to 5% by weight and a basic compound containing at least one tertiary nitrogen atom and a metallic salt of carboxylic acid in the same one molecule of 0.01 to 2% by weight based on polyoxymethylene.Type: GrantFiled: April 22, 1988Date of Patent: August 29, 1989Assignee: Polyplastics Co., Ltd.Inventors: Nozomu Nakagawa, Masaru Kubota, Shuichi Chino