Oh Group Other Than As Part Of A Cooh Group, E.g., Salicylic Acid, Etc. Patents (Class 524/291)
  • Patent number: 5045586
    Abstract: The present invention is directed to branched polyesters derived from the reaction product of hydroxy stearic acid or hydroxy stearic alkoxylate, a guerbet alochol or guerbet alcohol alkoxylate, which product is further reacted with a polycarboxylic acid to provide the required branching in the polyester structure. The invention is also directed to the preparation, compositions and application of said internal plastic lubricants, particularly suited for use in forming of polycarbonate thermoplastics.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: September 3, 1991
    Inventor: Anthony J. O'Lenick, Jr.
  • Patent number: 5032442
    Abstract: Disclosed herein is a fibrillated weatherproof web having a network structure, which can be produced with ease and is economical. The web comprises a multilayer composite film composed of at least two layers, one being a first layer (I) made of a first thermoplastic resin and the other a second layer (II) made of a second thermoplastic resin having a melting point lower than the first thermoplastic resin and containing at least 300 ppm of a light resistance imparting agent. A number of slits have been formed in a longitudinal or transverse direction. The web has been oriented at a draw ratio in a range of from 1.1 to 15 times. A nonwoven fabric making use of one or more fibrillated webs of the above sort and processes for the production of the web and nonwoven fabric are also disclosed.
    Type: Grant
    Filed: October 17, 1989
    Date of Patent: July 16, 1991
    Assignee: Nippon Petrochemicals Company, Ltd.
    Inventors: Shinji Yamazaki, Toshio Kotsuka
  • Patent number: 5032633
    Abstract: Thermoplastic molding compositions that contain(A) 10 to 90 parts by weight of polyamide 12, and 90 to 10 parts by weight of polyamide 10,12 and/or polyamide 12,12; and(B) 0 to 25 wt. % of a plasticizer, exhibit improved low temperature impact strength. The molding compositions may be used for the production of molded objects, especially tubes.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: July 16, 1991
    Assignee: Huels Aktiengesellschaft
    Inventors: Michael Schlobohm, Franz-Josef Schlautmann
  • Patent number: 5032634
    Abstract: Vinyl halide resins can be stabilized by a stabilizer mixture of a monomeric tetrafunctional organotin stabilizer and a hindered tris phenol antioxidant, preferably 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: July 16, 1991
    Assignee: Akzo America Inc.
    Inventor: Steven Walter
  • Patent number: 5032632
    Abstract: A composition of a copolymer of ethylene and vinyl alcohol, 0.01 to 0.5 weight percent of a monovalent or divalent metal salt of an aliphatic carboxylic acid having 3 to 9 carbon atoms and 0.05 to 0.5 weight percent of a hindered phenolic antioxidant exhibits improved stability toward oxidative gel formation at elevated temperatures.
    Type: Grant
    Filed: May 15, 1990
    Date of Patent: July 16, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Ronald L. Saxton
  • Patent number: 5030672
    Abstract: An asymmetric membrane formed from a sulphonated polyarylethersulphone has a salt rejection of at least 99%. Alternatively, a membrane has a good salt rejection and an acceptable water flux such that the ratio ##EQU1## has the value of at least 0.7. The membranes can be obtained using barium salts of the sulphonated polyarylethersulphone, with the proportion of barium being controlled to be at least 85%, preferably at least 86%, and not more than 91%, preferably not more than 90% of the barium required to react with the sulphonic acid groups on the sulphonated polymer.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: July 9, 1991
    Assignee: Imperial Chemical Industries PLC
    Inventors: Richard A. Hann, David R. Holmes, John W. Smith
  • Patent number: 5025049
    Abstract: A primer composition dilluted with a suitable organic solvent comprising (A) an organic copolymer comprising an alkoxysilylated monomer, vinyl acetate and other monomers copolymerizable therewith, (B) a polyalkyl (meth)acrylate, (C) a crosslinking agent for said copolymer (A), and (D) an ultraviolet absorber. This primer composition is a very effective primer in forming an organopolysiloxane coating layer excellent in adhesion, endurance, weathering resistance of the surface of a molded article of a thermoplastic resin.
    Type: Grant
    Filed: May 30, 1990
    Date of Patent: June 18, 1991
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mitsuhiro Takarada, Kazuharu Sato
  • Patent number: 5023284
    Abstract: This invention is directed to a stabilizer useful to retard transesterification in moldable polymer blends containing polyester(s) during processing of the blends at elevated temperatures, particularly at high temperatures above about 285.degree. C. More particularly, the stabilizer comprises a phosphate-epoxy adduct. The stabilizer may optionally further comprise a reactive functionality component comprising a compound having a imide or oxazoline functionality and/or a hindered phenol component. The invention is also directed to a composition comprising the stabilizer and a particularly defined polymer blend.
    Type: Grant
    Filed: August 9, 1989
    Date of Patent: June 11, 1991
    Assignee: Ford Motor Company
    Inventors: Mo-Fung Cheung, Amos Golovoy, Henk van Oene
  • Patent number: 5011879
    Abstract: An engineering plastic composition with excellent flowability, heat stability, and desirable mechanical properties is provided. The composition comprises an engineering plastic material and at least one p-quaterphenyl derivative of specific formula.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: April 30, 1991
    Assignees: Sekisui Kagaku Kogyo Kabushiki Kaisha, Kabushiki Kaisha Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Toshio Uesaka, Akihiro Niki, Makoto Ohsuga, Toranosuke Saito, Hiroki Tsunomachi, Makoto Yamaguchi, Kazuo Doyama, Daishiro Kishimoto
  • Patent number: 5008312
    Abstract: Bislactams of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another are each C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4 form a tetra- or pentamethylene radical, and R.sup.5 is hydrogen, carbonyl-C.sub.1 -C.sub.8 -alkyl, benzoyl, C.sub.1 -C.sub.8 -alkyl, C.sub.7 -C.sub.10 -phenylalkyl, the phenyl nucleus being unsubstituted or substituted by one or two C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkyoxy, fluorine, chlorine or bromine radicals, or is C.sub.1 -C.sub.3 -cyanoalkyl, C.sub.2 -C.sub.4 -hydroxyalkyl or C.sub.2 - or C.sub.3 -aminoalkyl, and the acid addition salts and hydrates of these compounds.The compounds (I) are stabilizers for organic materials.
    Type: Grant
    Filed: August 7, 1989
    Date of Patent: April 16, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Aumueller, Peter Neumann, Hubert Trauth
  • Patent number: 4996244
    Abstract: Compounds having defined functional groups are described which color stabilize aromatic carbonate polymers or blends therewith upon exposure to sterilizing radiation.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: February 26, 1991
    Assignee: General Electric Company
    Inventor: Roger W. Avakian
  • Patent number: 4992499
    Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of a stabilizing amount of a combination of a phenolic compound and an aromatic amine.
    Type: Grant
    Filed: November 30, 1989
    Date of Patent: February 12, 1991
    Assignee: Shell Oil Company
    Inventors: Johannes L. M. Syrier, Hendrik Van De Weg, Robert Q. Kluttz
  • Patent number: 4985479
    Abstract: A stabilized polyolefin composition having improved weathering resistance is provided, whereby the following four components are incorporated into a polyolefin:(A) a hindered piperidine compound having a molecular weight of more than 750, such as poly-{[6-morpholino-1,3,5-triazine-2,4-diyl][2,2,6,6-tetramethyl-4-piperid yl)imino]hexamethylene[2,2,6,6-tetramethyl-4-piperidyl)imino]},(B) a hindered piperidine compound having a molecular weight of less than 500, such as bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate,(C) a benzoate compound such as 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate, and(D) a phosphorus-containing compound such as bis(2,4-di-t-butylphenyl) pentaerythritol diphosphite.
    Type: Grant
    Filed: March 28, 1989
    Date of Patent: January 15, 1991
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Hideo Nagasaki, Shinichi Yachigo, Takeshi Takata, Hiroki Yamamoto, Yukoh Takahashi
  • Patent number: 4983654
    Abstract: This invention is directed to a stabilizer useful to retard transesterification in moldable polymer blends containing polyester(s) during processing of the blends at elevated temperatures, particularly at high temperatures above about 285.degree. C. More particularly, the stabilizer comprises a phosphate-epoxy adduct. The stabilizer may optionally further comprise a reactive functionality component comprising a compound having a imide or oxazoline functionality and/or a hindered phenol component. The invention is also directed to a composition comprising the stabilizer and a particularly defined polymer blend.
    Type: Grant
    Filed: December 28, 1987
    Date of Patent: January 8, 1991
    Assignee: Ford Motor Company
    Inventors: Mo-Fung Cheung, Amos Golovoy, Henk van Oene
  • Patent number: 4981892
    Abstract: A thermoplastic resin composition comprising 0.01 to 10 parts by weight of at least one ultraviolet ray absorbent having a peak absorption wavelength at 240-300 nm in the range of 240-400 nm and 100 parts by weight of methacrylimide group-containing polymer containing at least 5% by weight of imide ring structural unit expressed by the following structural formula is disclosed: ##STR1## (wherein R.sub.1 is a hydrogen atom, or a substituted or non-substituted alkyl group having 1-20 carbon atoms, cycloalkyl group, aryl group, alkalyl group, alalkyl group, or allyl group.)This composition has an improved weather durability and thermal resistance as well as light transmittance.
    Type: Grant
    Filed: May 10, 1989
    Date of Patent: January 1, 1991
    Assignee: Mitsubishi Rayon Company, Limited
    Inventors: Kozi Nishida, Mikiharu Watanabe
  • Patent number: 4972019
    Abstract: A water-absorbent resin composition having superior gel stability which comprises a water-absorbent resin, at least one oxygen-containing reducing inorganic salt and, optionally, at least one organic antioxidant.
    Type: Grant
    Filed: June 20, 1989
    Date of Patent: November 20, 1990
    Assignee: Seitetsu Kagaku Co., Ltd.
    Inventors: Shigeji Obayashi, Morio Nakamura, Takushi Yamamoto, Hitoshi Tanaka, Yuji Sakamoto
  • Patent number: 4972014
    Abstract: Incorporation into polyacetal molding compositions stabilized with a non-meltable polymer stabilizer of 0.02-1.0 weight percent of at least one amide-containing phenolic antioxidant results in significantly improved long term stability, as evidenced by greater retention of physical properties over time, of such compositions.
    Type: Grant
    Filed: June 15, 1989
    Date of Patent: November 20, 1990
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Richard A. Hayes, Leonard E. R. Kosinski, Mark E. Wagman
  • Patent number: 4972015
    Abstract: Disclosed is a shaped, thin-walled, thermoformed, heat-set article, the composition of which comprises:(a) a crystallizable polyester having repeating units from at least 90 mol % terephthalic acid and repeating units from at least 90 mol % 1,4-cyclohexanedimethanol, the total dicarboxylic acid mol % and the total glycol mol % each being 100 mol %, said polyester having an inherent viscosity of about 0.7-1.1, and(b) a heat stabilizing amount of an antioxidant system comprising a hindered phenol, a thio ester or ether and a phosphate salt.
    Type: Grant
    Filed: July 24, 1989
    Date of Patent: November 20, 1990
    Assignee: Eastman Kodak Company
    Inventors: Joey C. Carico, Wayne P. Pruett, Raymond N. Vachon
  • Patent number: 4966960
    Abstract: A process and nylon release sheet for manufacturing printed circuit boards from epoxy prepregs is disclosed. In such process layers of the prepregs are separated from one another by a release sheet. The release sheet comprises an aliphatic or aromatic nylon or nylon copolymer which is a condensation product of a dicarboxylic acid and a diamine. The nylon film contains a heat stabilizer and an inorganic particulate antiblock additive, e.g. diatomaceous earth, glass beads, amorphous silica, talc, mica and molybdenum disulphide. The nylon may be toughened by the addition of a phosphorus-containing catalyst or an epoxide.
    Type: Grant
    Filed: November 2, 1988
    Date of Patent: October 30, 1990
    Assignee: Du Pont Canada Inc.
    Inventors: Peter A. Sipos, Erica M. Besso
  • Patent number: 4963607
    Abstract: Polyolefins are stabilized against the harmful effects of U.V.-light by incorporating therein certain organosulfides. The organosulfides may be used alone or in synergistic combination with two classes of known light stabilizers, namely the benzophenones and the esters of aromatic acids.
    Type: Grant
    Filed: June 13, 1989
    Date of Patent: October 16, 1990
    Assignee: Pennwalt Corporation
    Inventors: James L. Reilly, Joseph M. Bohen
  • Patent number: 4963606
    Abstract: This invention relates to a styrenic polymer-based thermoplastic formulation containing a brominated cycloaliphatic flame retardant and a thermal stabilizer system comprising an organotin stabilizer, a hindered phenolic antioxidant and, optionally, a polyhydroxy aliphatic compound.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: October 16, 1990
    Assignee: Ethyl Corporation
    Inventor: Robert A. Schleifstein
  • Patent number: 4960812
    Abstract: Polyester resin compounds useful as plastic materials which demonstrate good surface characteristics, excellent physical properties and outstanding formability, particularly when processed at a temperature lower than 100.degree. C. are disclosed. Superior characteristics are achieved by accelerating the speed of crystallization thereof by incorporating additives so that crystallization is completed throughout the product.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: October 2, 1990
    Assignee: Sam Yang Co., Ltd.
    Inventors: Han S. Youn, Kim Dong, II, Choi I. Gyu
  • Patent number: 4960808
    Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of certain phenolic compounds.
    Type: Grant
    Filed: March 30, 1988
    Date of Patent: October 2, 1990
    Assignee: Shell Oil Company
    Inventor: Andre Schmitter
  • Patent number: 4959403
    Abstract: A thermoplastic molding composition having good cold impact strength properties, consisting essentially of (I) a polyamide 1212 having a relative viscosity in the range of from 1.5 to 3.0, and (II) 2 to 25% by weight, based on the polyamide, of a plasticizer.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: September 25, 1990
    Assignee: Huels Aktiengesellschaft
    Inventors: Martin Bartmann, Roland Feinauer, Uwe Hartkopf, Michael Schlobohm
  • Patent number: 4957956
    Abstract: A solid stabilizer composition for organic polymers is formed by a solid, continuous phase and by a dispersed phase in said continuous phase, wherein the continuous phase is constituted by amorphous tetrakis-[3-(3,5-di-tert.-butyl-4-hydroxyphenyl)-propionyloxymethyl]-metha ne and the dispersed phase is constituted by an either amorphous or crystalline organic phosphite, in the form of particles with a particle size of from 10 .mu.m to 2 mm, with the weight ratio of said continuous phase to said dispersed phase being comprised within the range of from 9:1 to 1:9.The processes for preparing said solid stabilizer composition and its use in the stabilization of organic polymers are disclosed.
    Type: Grant
    Filed: February 11, 1988
    Date of Patent: September 18, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Nereo Nodari, Erik Bersanetti, Giovanni Sandre
  • Patent number: 4958006
    Abstract: Method and apparatus for the post reaction treatment of resins produced by fluidized bed polymerization of alpha olefins wherein an extruder is coupled in communication with the reactor and all necessary devolatilization of monomer, deactivation of catalysts and addition of additives are performed in the extruder.
    Type: Grant
    Filed: June 28, 1988
    Date of Patent: September 18, 1990
    Assignee: Union Carbide Chemicals and Plastics Inc.
    Inventors: Robert J. Bernier, Jorge O. Buhler-Vidal, Urho S. Haapala, Benjamin R. Rozenblat
  • Patent number: 4956408
    Abstract: A conjugated diene/monovinyl substituted aromatic hydrocarbon copolymer is stabilized by the addition of a complex acrylate, in combination with at least one of an alkyl thiopropionate, an organic phosphite and a non-acrylate substituted hindered phenolic compound.
    Type: Grant
    Filed: June 13, 1988
    Date of Patent: September 11, 1990
    Assignee: Phillips Petroleum Company
    Inventors: Ronald D. Mathis, Alonzo G. Kitchen, Frank J. Szalla
  • Patent number: 4954548
    Abstract: Compositions comprising linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against degradation caused by exposure to UV light by the inclusion therein of an aromatic diamine and a certain type of carbon black.
    Type: Grant
    Filed: April 27, 1989
    Date of Patent: September 4, 1990
    Assignee: Shell Oil Company
    Inventor: George B. Klingensmith
  • Patent number: 4945017
    Abstract: A composition for conversion of a rusted metal surface to form a durable coating thereon consists essentially of a reducing agent which reduces an trivalent iron present on the surface, an organic monomer to which is capable of polymerization on the surface in the presence of the reducing agent and a free radical initiator which polymerizes the organic monomer to form the durable coating.
    Type: Grant
    Filed: March 3, 1989
    Date of Patent: July 31, 1990
    Assignee: Pennzoil Products Company
    Inventors: Paul J. DesLauriers, William J. Heilman
  • Patent number: 4939196
    Abstract: A compound represented by the formula of ##STR1## wherein R.sub.1 represents an alkyl having 1 to 5 carbon atoms;R.sub.2 represents an alkyl having 1 to 18 carbon atoms, an alkenyl having 2 to 5 carbon atoms, an aralkyl having 7 to 9 carbon atoms, phenyl, an aliphatic acyl having 2 to 5 carbon atoms, or benzoyl;R.sub.3 represents hydrogen or an alkyl having 1 to 11 carbon atoms; andR.sub.4 represents hydrogen or methyl.The compound is useful as a stabilizer for synthetic resins such as butadiene polymers. The butadiene polymer containing the compound is stable against thermal deterioration in the absence of oxygen, as well as against thermal oxidative deeterioration and thermal oxidative discoloration.
    Type: Grant
    Filed: December 30, 1988
    Date of Patent: July 3, 1990
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Manji Sasaki, Shinichi Yachigo, Kikumitsu Inoue, Shinya Tanaka, Fumitoshi Kojima, Takeshi Takata
  • Patent number: 4937138
    Abstract: A hot melt adhesive, a laminar structure, and non-woven article fabricated from a blend comprising:from about 50 percent by weight to about 5 percent by weight of a butene-1 homopolymer or copolymer;from about 50 percent by weight to about 95 percent by weight of a tackifying resin;from a 0.01 to about 1 phr of a nucleating agent;up to about 1 part per hundred (phr) of a stabilizer;up to about 30 phr of a plasticizer; andup to about 30 phr of a wax.
    Type: Grant
    Filed: February 29, 1988
    Date of Patent: June 26, 1990
    Assignee: Shell Oil Company
    Inventor: Simon Mostert
  • Patent number: 4935275
    Abstract: A polyurethane material for decorative parts is disclosed which is a tow-liquid type material comprising a polyol component and an isocyanate component and having a stabilizer incorporated in the polyol component. The stabilizer is a ternary system of a specific hindered amine type ultraviolet stabilizer, a specific hindered phenol type antioxidant, and a specific benzotriazole type ultraviolet absorbent or acrylontrile type ultraviolet absorbent. A transparent synthetic resin part formed by potting this polyurethane material on the upper surface of a base excels in weatherability and lightfastness. Thus, the present invention provides decorative parts which retain good appearance for a long time.
    Type: Grant
    Filed: April 6, 1988
    Date of Patent: June 19, 1990
    Assignee: Toyoda Gosei Co., Ltd.
    Inventors: Yoshio Ushida, Shinji Jinushi, Yoshio Yamazaki
  • Patent number: 4923916
    Abstract: Tetrahalophthalate esters are disclosed herein as flame retardant processing aids for polystyrene resins.
    Type: Grant
    Filed: July 19, 1988
    Date of Patent: May 8, 1990
    Assignee: Pennwalt Corporation
    Inventors: Joseph M. Bohen, Ronald F. Lovenguth
  • Patent number: 4923915
    Abstract: UV-curable urethane-acrylate resin systems of improved thermal stability in the cured state are provided, the resins being of polyurethane acrylate, polyurea acrylate, and/or polyurethane/polyurea acrylate composition and being thermally stabilized by the addition of a combination of stabilizers which includes a hindered piperidine derivative and a hindered phenol derivative. The stabilized resin systems, useful for example for the protective coating of glass optical fibers, retain their rapid UV curing characteristics.
    Type: Grant
    Filed: May 18, 1988
    Date of Patent: May 8, 1990
    Assignee: Corning Incorporated
    Inventor: Eric H. Urruti
  • Patent number: 4921623
    Abstract: A copper-type conductive coating composition which comprises:(A) a copper powder,(B) a coating binder resin, and(C) at least one number selected from the group consisting of salicylic acid, its specific derivatives, and benzotriazolecarboxylic acid hydrazides.The copper-type conductive coating composition provides a conductive coating layer having excellent initial conductivity and capable of maintaining the level of it stable over a long period of the time.
    Type: Grant
    Filed: July 21, 1988
    Date of Patent: May 1, 1990
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Shoji Yamaguchi, Kimiko Yamada, Katsuyoshi Yada, Koichi Sakaguchi, Hiromu Inoue
  • Patent number: 4918124
    Abstract: Stabilizing mixtures, acting synergistically, of phenolic antioxidants and sulphur-containing polymers having terminal thioalkyl groups.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: April 17, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Alfred Pischtschan, Karl-Heinz Ott
  • Patent number: 4912156
    Abstract: A polyolefin composition comprises 100 parts by weight of a polyolefine which has been produced with use of a Ziegler catalyst and has a part or residue of the catalyst left therein, 0.005 to 1 part by weight of a phenol compound having the formula (I) and 0.005 to 1 part by weight of an organic phosphite compound having the formula (II). ##STR1## in which R is a residue group of an alcohol being monohydric, dihydric, trihydric or terahydric, R1 is methyl or tert.-butyl, R2 is an alkyl, --CH2CH2COOR3 or --COOR3, R3 being an alkyl, an aryl or an alkylaryl, and n is a number of 1 to 4.
    Type: Grant
    Filed: July 27, 1988
    Date of Patent: March 27, 1990
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Masaki Yagi, Tohru Haruna, Takashi Takeuchi, Toshinori Yukino
  • Patent number: 4910239
    Abstract: The present invention comprises a screen printing ink or coating composition that includes methyl salicylate combined with a resin composition. In the case of ink the composition further includes pigments. The methyl salicylate acts as a solvent and functions to dissolve the resin and pigment compositions.
    Type: Grant
    Filed: July 11, 1988
    Date of Patent: March 20, 1990
    Inventor: David W. Crabtree
  • Patent number: 4898901
    Abstract: Long chain N-alkyl-alpha-alkyl nitrones represent particularly valuable process stabilizers for polyolefin compositions. The nitrone derived from the long chain alkyl mixture present in di(hydrogenated tallow)amine is especially useful for this purpose.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: February 6, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Ramanathan Ravichandran, Stephen D. Pastor, Raymond Seltzer, Ambelal R. Patel
  • Patent number: 4895884
    Abstract: There is disclosed the use of microencapsulated antidegradants in rubber and a process for the production of microencapsulated antidegradants. More specifically, this invention is directed to the cellulose acetate microencapsulation of para-phenylene diamine based antiozonants at wall to core ratios greater than 1:1 but less than 4:1. The microcapsules preferably have a particle diameter of less than 50 microns. The microencapsulated antidegradant prepared and used according to this invention provides long term protection to rubber articles that are subject to ozone and oxygen attack.
    Type: Grant
    Filed: October 6, 1987
    Date of Patent: January 23, 1990
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: David A. Benko, Larry R. Evans, James G. Gillick, Walter H. Waddell, Barbara A. Metz, Benjamin F. Benton, Gordon E. Pickett, William R. Krumm
  • Patent number: 4894399
    Abstract: Light-stabilized polymer microparticles, which contain at least one light stabilizer and free epoxy groups, and processes for the preparation of these microparticles by polymerization of suitable monomers, at least one of these monomers being an epoxide which contains at least one further reactive group, and at least part of the polymerization being carried out in the presence of at least one light stabilizer, are described. The polymer microparticles can be used in coating compositions which comprise a disperse phase, containing these particles, and a liquid continuous phase.Coatings and paints based on the compositions according to the invention are distinguished by improved weathering resistance, in particular high light stability.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: January 16, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean Rody, Mario Slongo, Franciszek Sitek, Andreas Valet
  • Patent number: 4889879
    Abstract: Coherent thermoplastic aggregates with very high content of pulverized mineral materials, composed of the said materials, of polyolefin polymers and/or copolymers, and possibly also of various familiar adjuvants, characterized by the fact that, in order for them to have both a volumetric mass close to or at most equal to the theoretical volumetric mass of the pulverized mineral substances entering into their composition and an excellent compatibility with redispersion polymers, the polymers and/or copolymers entering into the composition of the said aggregates in presence of a fluidizing agent are chosen within the group of thermoplastics with melting and/or softening point at least equal to 60.degree. C. and index of fluidity at least 50 (measured according to the standard ASTM D 1238) of the polyolefin type, other than those containing a polar monomer.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: December 26, 1989
    Assignee: Pluess Staufer AG
    Inventors: Henry Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
  • Patent number: 4885326
    Abstract: A synthetic resin composition comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic alkylphosphite compound of 2,2'-alkylidene-bisphenol (I) and 0.001 to 10 parts by weight of beta-(3,5-dialkyl-4-hydroxyphenyl)-propionic acid ester (II) and is stabilized to light and heat.
    Type: Grant
    Filed: March 24, 1989
    Date of Patent: December 5, 1989
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Tohru Haruna, Kazunori Nishikawa, Mitsuhiro Hamajima
  • Patent number: 4880854
    Abstract: Compounds having defined triazine functional groups are described which color stabilize aromatic carbonate polymers or blends therewith upon exposure to sterilizing radiation.
    Type: Grant
    Filed: December 22, 1987
    Date of Patent: November 14, 1989
    Assignee: General Electric Company
    Inventor: Roger W. Avakian
  • Patent number: 4880859
    Abstract: Light-stabilized star polymer microparticles are described which are prepared with particular advantage by group transfer polymerization. The light stabilization is effected by carrying out at least a part step of the polymerization in the presence of a light stabilizer, for example a hindered amine or/and a UV absorber. With particular advantage, those light stabilizers are used which contain reactive groups in the molecule and, in this way, can be chemically incorporated into the polymer. The polymer microparticles show excellent light stability and are outstandingly suitable as constituents in coating compositions which can be processed, for example, to give coating films of high light stability.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: November 14, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Mario Slongo, Jean Rody, Franciszek Sitek, Andreas Valet
  • Patent number: 4879141
    Abstract: The present invention includes:(i) a method for making a coated particulate comprising the steps ofheating until liquid a polyolefin wax;fluidizing with a hot gas, additive particles selected from the group comprising an antioxidant, a processing stabilizer, an acid acceptor, and mixtures thereof;spraying the liquid polyolefin wax on the heated fluidized additive particles; andmaintaining the fluidized additive particles at a temperature which is sufficient to prevent the formation of fibers and adequate to form discrete substantially coated additive particles;(ii) a coated particulate made by the above process; and(iii) a process for providing in-reactor stabilization of a polyolefin during a polymerization reaction, using the coated additives prepared by the above described method.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: November 7, 1989
    Assignee: Shell Oil Company
    Inventor: Ananda M. Chatterjee
  • Patent number: 4876300
    Abstract: Long chain N,N-dialkylhydroxylamines represent particularly valuable process stabilizers for polyolefin compositions. The hydroxylamine derived from di(hydrogenated tallow)amine is particularly useful for this purpose. These long chain N,N-dialkylhydroxylamines are very resistant to extraction from polyolefin compositions.
    Type: Grant
    Filed: December 30, 1987
    Date of Patent: October 24, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Raymond Seltzer, Ramanathan Ravichandran, Ambelal R. Patel
  • Patent number: 4874804
    Abstract: Hot melt packaging adhesive compositions consisting essentially of 35 to 45% by weight of an ethylene n-butyl acrylate copolymer containing 25-45% by weight, preferably 30 to 40% n-butyl acrylate and having a melt index of at least 50; 35 to 55% of a terpene phenolic tackifier; and 10 to 20% by weight of a high melting synthetic wax provide adhesives characterized by an excellent balance of high and low temperature performance without sacrifice to machinability or thermal stability.
    Type: Grant
    Filed: August 24, 1988
    Date of Patent: October 17, 1989
    Assignee: National Starch and Chemical Corporation
    Inventors: Francis X. Brady, Thomas F. Kauffman
  • Patent number: 4874808
    Abstract: Compositions comprising (A) cycloolefin random copolymer containing an ethylene component, and a cycloolefin component represented by the general formula [I] or [II] and having an intrinsic viscosity of 0.05-10 dl/g as measured at 135.degree. C. in decalin and a softening temperature (TMA) not lower than 70.degree. C., and (B) a cycloolefin random copolymer containing an ethylene component, and a cycloolefin component represented by the general formula [I] or [II] and having an intrinsic viscosity of 0.01-5 dl/g as measured at 135.degree. C. in decalin and a softening temperature (TMA) of below 70.degree. C., the weight ratio of said (A) component/(B) component ranging from 100/0.1 to 100/10.The composition is particularly useful for molding an information recording base board.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: October 17, 1989
    Inventors: Syuji Minami, Keiji Kawamoto, Tetsuji Kasai, Toshiaki Kuroiwa, Akira Todo
  • Patent number: 4861814
    Abstract: A polyoxymethylene composition comprises an antioxidant of 0.05 to 5% by weight and a basic compound containing at least one tertiary nitrogen atom and a metallic salt of carboxylic acid in the same one molecule of 0.01 to 2% by weight based on polyoxymethylene.
    Type: Grant
    Filed: April 22, 1988
    Date of Patent: August 29, 1989
    Assignee: Polyplastics Co., Ltd.
    Inventors: Nozomu Nakagawa, Masaru Kubota, Shuichi Chino