Two Or More Aryl Groups Patents (Class 524/299)
  • Patent number: 6008304
    Abstract: An additive for masticating natural rubber comprising at least one compound selected from the group consisting of benzoic acids, naphthoic acids, dicarboxylic acids and compounds represented by Formula (IV): ##STR1## wherein m and n each represent an integer of 1 to 3; p represents an integer of 1 to 4; m+n+p=6; X is O, NR.sup.8 or (R.sup.9 O).sub.q ; R.sup.6 is a C.sub.1 .about.C.sub.24 alkyl, a C.sub.2 .about.C.sub.24 alkenyl, or a C.sub.6 .about.C.sub.24 aryl group; and R.sup.7 is H, OH, an alkyl, alkenyl or aryl group; R.sup.8 is H or a C.sub.1 .about.C.sub.24 alkyl group; R.sup.9 is a C.sub.1 .about.C.sub.4 alkyl group; q is an integer of 1 to 5, a mastication method and a natural rubber composition each of which uses the additive, and a pneumatic tire using the natural rubber composition.
    Type: Grant
    Filed: March 24, 1998
    Date of Patent: December 28, 1999
    Assignees: Bridgestone Corporation, KAO Corporation
    Inventors: Daisuke Nohara, Masaaki Tsuchihashi, Isao Nishi
  • Patent number: 5977223
    Abstract: A method of manufacturing a thin-walled polyurethane article includes dipping a shaped former into a coagulant solution and subsequently dipping the shaped former into an aqueous-phase polyurethane/plasticizer dispersion wherein the unplasticized polyurethane has a mean particle size of between about 0.5 .mu.m and 1.0 .mu.m and wherein the plasticizer causes the polyurethane particles to swell until they have a mean particle size of between about 1.5 .mu.m and 3.0 .mu.m. Articles so produced have a thickness of between 0.03 mm to 1.0 mm, a tensile strength of between 17 MPa and 60 Mpa and an elongation at break of greater than 650%.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: November 2, 1999
    Assignee: Ansell Healthcare Products, Inc.
    Inventors: Allison Marie Ryan, Jeffery G. Nile, Stanley J. Gromelski, Steven Thomas Hardwick, Richard Milner, Paul Cacioli
  • Patent number: 5972263
    Abstract: A method of improving the strength and/or plasticity of a clay composition comprising a kandite clay and an organic additive comprising at least one water soluble compound having a plurality of basic groups wherein the organic additive is present in an amount of from about 0.05% by weight to about 0.5% by weight based on the dry weight of the kandite clay present, which method comprises treating the kandite clay by adding thereto a monovalent ion activated smectite clay or a monovalent ion activating agent for a smectite clay or both whereby the amount of monovalent ion activated non-calcined smectite clay present in the clay composition is adjusted to be in the range from about 1% by weight to about 5% by weight based upon the dry weight of the kandite clay present.
    Type: Grant
    Filed: December 10, 1997
    Date of Patent: October 26, 1999
    Assignee: ECC International Ltd.
    Inventors: Howard Goodman, Christopher Stirling Hogg, Richard Gerrard Shaw Stewart
  • Patent number: 5948832
    Abstract: Provided are a resin composition improved in utilization of active compound by controlling the bleeding of the active compound low in vaporizability and a molded product obtained from the resin composition. The resin composition comprises 100 parts by weight of a resin, 0.01-200 parts by weight of an active compound and 0.1-100 parts by weight of a vaporizable plasticizer having a vapor pressure of 0.001 mmHg or higher at 20.degree. C., and the vapor pressure (P1) of the vaporizable plasticizer at 20.degree. C. and the vapor pressure (P2) of the active compound at 20.degree. C. satisfy the formula: P1/P2.gtoreq.2.
    Type: Grant
    Filed: July 9, 1996
    Date of Patent: September 7, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tatsuhiro Nagamatsu, Hiroki Nakata, Takanori Kume, Tadashi Sakurai
  • Patent number: 5847024
    Abstract: A stable, pigmentless, simulated watermark ink is composed of a drying oil modified polyester, an aluminum alkoxide gelling agent and an ultraviolet light absorber.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: December 8, 1998
    Assignee: Sun Chemical Corporation
    Inventors: Stan Newman, Paul W Hofecker
  • Patent number: 5804257
    Abstract: A polysilane composition including a polysilane and a plasticizer can be coated as a thin film having improved mechanical strength and a high photo decomposition rate. A polysilane composition including a polysilane and an ester can be coated as a thin film which is exposed to UV and readily dyed to form a dyed polysilane film.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 8, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Akira Hayashida, Shigeru Mori, Eiichi Tabei
  • Patent number: 5486559
    Abstract: The invention relates to an optically non-linear active waveguiding material comprising an optically transparent polymer and a donor group and acceptor group-containing triphenylcarbinol as a dopant. Said dopants have a high hyperpolarizability and have a charge-transfer absorption band which is about the same as that of their corresponding compounds having only one donor-.pi.-acceptor unit. The triphenylcarbinols were found to display good solubility in polymers. Nitro-functionalized triphenylcarbinols are preferred because of their charge-transfer absorption band at a low wavelength (.lambda..sub.max at about 290 nm). Aldehyde-functionalized calix(4)arenes were also found to have this low wavelength charge-transfer absorption band (.lambda..sub.max at about 270 nm). Triphenyls comprising stilbene donor-.pi.-acceptor units are preferred because of their high hyperpolarizability.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: January 23, 1996
    Assignee: Akzo Nobel NV
    Inventors: Johannes F. J. Engbersen, Erik Kelderman, David N. Reinhoudt, Willem Verboom
  • Patent number: 5444108
    Abstract: A mechanically peelable masking coating composition particularly useful for metals, and the method of preparing same for use is provided. The composition is heat curable in one or two heatings to produce a firmly adhering yet peelable coating. In its preferred form the composition comprises a mixture of a dispersion grade vinyl, a plasticizer, an adhesion promoter such as an epoxy, and optionally a thixotrope where greater resistance to sag and flow are desired. No fugitive solvents are required.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: August 22, 1995
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: James A. E. Hagquist, Lawrence L. Micek
  • Patent number: 5389711
    Abstract: The present invention provides an aromatic acid, a salt of an aromatic acid, anhydride of an aromatic acid, or mixtures thereof in which at least 50 percent of the carbon atoms are in aromatic rings and which have a melting point above about 100.degree. C. as a plasticizer for polyvinyl aromatic polymers which are functionalized by grafting salt functional groups onto the polyvinyl aromatic blocks. When such a polymer is plasticized with the aromatic acid, salt of an aromatic acid or anhydride of an aromatic acid of this invention, the polymer retains excellent high temperature physical properties.
    Type: Grant
    Filed: February 14, 1990
    Date of Patent: February 14, 1995
    Assignee: Shell Oil Company
    Inventors: Paul A. Westbrook, Leonard E. Gerlowski
  • Patent number: 5328951
    Abstract: A method is disclosed for increasing the surface energy of a surface of an organic polymeric material, particularly polyolefins. The method is comprised of blending from about 99.5% to about 90.0% by weight of the polymeric material with from about 0.5% to about 10.0% by weight of an amphiphile having the formula:RA(CHR.sup.2 [CH.sub.2 ].sub.n A.sup.1).sub.m R.sup.1where R and R.sup.1 are selected from the group consisting of the alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of an aliphatic or aliphatic/aromatic mono-acid with a molecular weight of from about 150 to about 500 daltons, A and A.sup.1 are polar atoms or groups, R.sup.2 is selected from the group consisting of H, CH.sub.3 and C.sub.2 H.sub.5, n is from 0 to 3 and m is from 2 to 20.
    Type: Grant
    Filed: July 1, 1993
    Date of Patent: July 12, 1994
    Assignee: Arizona Chemical Company
    Inventor: Eric S. Gardiner
  • Patent number: 5324762
    Abstract: The subject of this invention is acrylic polymer plastisol compositions, wherein the acrylic polymer component of the plastisol composition is a single-stage methyl methacrylate copolymer derived from methyl methacrylate and a comonomer component comprising isobutyl methacrylate and optionally other comonomer(s). The selection of isobutyl methacrylate as a comonomer with the methyl methacrylate results in good compatibility with a wide range of plasticizers and without undue softness in the resulting plastisol.
    Type: Grant
    Filed: October 22, 1992
    Date of Patent: June 28, 1994
    Assignee: Imperial Chemical Industries PLC
    Inventors: Andrew S. Overend, John C. Padget
  • Patent number: 5302644
    Abstract: Abstract of the Disclosure Stabilizer combination for Ca/Zn-stabilized PVC molding materials, containing (a) Ca salts of saturated, straight-chain C.sub.8 -C.sub.34 fatty acids, (b) Zn salts of saturated, straight-chain or branched C.sub.8 -C.sub.22 fatty acids, (c) epoxidized glycerides of unsaturated, straight-chain C.sub.16 -C.sub.22 fatty acids having an oxirane number of 6 to 8 and iodine number less than 5, and (d) ketofatty acid glycerides of general formula R.sup.1 COO--CH.sub.2 -(R.sup.2 COO)CH-CH.sub.2 -OCR.sub.3, in which the groups R.sup.1 COO--, R.sup.2 COO--, and R.sup.3 COO-- stand for residues of ketofatty acids with 16 to 22 carbon atoms and optionally residues of fatty acids with 12 to 22 carbon atoms, and 60 to 100 wt.% of the groups are derived from the ketofatty acids and 40 to 0 wt.
    Type: Grant
    Filed: December 7, 1992
    Date of Patent: April 12, 1994
    Assignee: Neynaber Chemie GmbH
    Inventors: Kurt Worschech, Gerhard Stoll, Ernst-Udo Brand, Peter Wedl
  • Patent number: 5281645
    Abstract: The present invention relates to new hydroxybenzophenones containing an ester functional group and to the use of these compounds as UV absorbers in organic polymers. More precisely, the new hydroxybenzophenones are 1,3-di(4-benzoyl-3-hydroxyphenoxy)-2-propanol carboxylates which preferably have a molecular mass of at least 500.These benzophenones can be employed as anti-UV agents in organic polymers, either by themselves or jointly with known benzophenones of lower molecular mass, such as 2-hydroxy-4-alkoxybenzophenones.
    Type: Grant
    Filed: July 24, 1992
    Date of Patent: January 25, 1994
    Assignee: Rhone-Poulenc Chimie
    Inventors: Philippe Chicart, Michel Gay
  • Patent number: 5271866
    Abstract: A liquid-crystalline polymer composition comprising a ferroelectric liquid-crystalline polymer and a low molecular weight liquid-crystalline compound which exhibits smectic C phase or chiral smectic C phase. Such liquid-crystalline polymer compositions have not only excellent moldabilities such as ease of orientation, but also exhibit chiral smectic C phase at wide temperature range within room temperatures and exhibit high speed response to changes of external fields and high contrast ratios when they are used for optical display elements.
    Type: Grant
    Filed: May 21, 1991
    Date of Patent: December 21, 1993
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shunji Uchida, Kazuharu Morita, Kenji Hashimoto
  • Patent number: 5240985
    Abstract: A method is disclosed for increasing the surface energy of a surface of an organic polymeric material, particularly polyolefins. The method is comprised of blending from about 99.5% to about 90.0% by weight of the polymeric material with from about 0.5% to about 10.0% by weight of an amphiphile having the formula:RA(CHR.sup.2 [CH.sub.2 ].sub.n A.sup.1).sub.m R.sup.1R and R.sup.1 are selected from the group consisting of the alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of an aliphatic or aliphatic/aromatic mono-acid with a molecular weight of from about 150 to about 500 daltons, A and A.sup.1 are polar atoms or groups, R.sup.2 is selected from the group consisting of H, CH.sub.3 and C.sub.2 H.sub.5, n is from 0 to 3 and m is from 2 to 20.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: August 31, 1993
    Assignee: Arizona Chemical Company
    Inventor: Eric S. Gardiner
  • Patent number: 5194457
    Abstract: Nucleants for thermodegradable crystalline polyolefines made up of zeolitic molecular sieves modified with at least one arylcarboxylic acid. These nucleants may be added before or during the macroradicalic degradation of the polyolefines and allow products having a high degree of nucleation to be obtained.
    Type: Grant
    Filed: January 10, 1992
    Date of Patent: March 16, 1993
    Assignee: Enimont Augusta Industriale S.r.l
    Inventors: Corrado Brichta, Giancarlo Bressan, Claudio Troglia, Giancarlo Barbero
  • Patent number: 5187217
    Abstract: Process for the production of a plasticized polyvinyl butyral particularly used for gluing a base onto glazings. The polyvinyl butyral is obtained by the reaction of a butyric aldehyde with a polyvinyl alcohol, demonstrating a level of hydrolysis greater than 95%, and a viscosity greater than 50 cP, in the presence of an acid catalyst and an emulsifier, the quantity of butyric aldehyde being such that the level of hydroxylation of the polyvinyl butyral obtained is between 22 and 26%.
    Type: Grant
    Filed: July 24, 1991
    Date of Patent: February 16, 1993
    Assignee: Saint-Gobain Vitrage
    Inventors: Robert Degeilh, Daniel Dages
  • Patent number: 5183834
    Abstract: A heat cured pasty composition adapted to form a dental veneer which is resistant or immune to interdental cracks while in use on crowns and bridges. The composition includes polymerizable urethane-acrylic monomer, inorganic fillers, pyrogenic silica, heat activated polymerization initiators, and fractured organic filler particles. Heat polymerization of the composition above about 100.degree. C. forms a polymer which has a microhardness of at least HV 0.1/10 18.0 Kp/mm.sup.2, and an impact strength of at least 2.0 KJ/m.sup.2.
    Type: Grant
    Filed: April 5, 1989
    Date of Patent: February 2, 1993
    Assignee: Dentsply G.m.b.H.
    Inventors: Karl J. Gorlich, Fritz U. Bauer, Joerg Konetzka
  • Patent number: 5151458
    Abstract: This invention relates to new highly fluid polyarylene sulphide-(PAS)-moulding compounds, preferably polyphenylene sulphide-(PPS)-moulding compounds containing low molecular weight, liquid crystalline ester(amide)s.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: September 29, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Detlef Heinz, Harald Pielartzik, Klaus Reinking, Rolf-Volker Meyer, Siegfried Korte
  • Patent number: 5143956
    Abstract: The invention relates to free-flowing polyamide molding compounds which are characterized by a content of new liquid-crystalline compounds corresponding to general formulae (I) and/or (II) and to the new liquid-crystalline compounds corresponding to general formulae (I) and/or (II).
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: September 1, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Pielartzik, Hans-Detlef Heinz, Rolf Dhein, Aziz E. Sayed
  • Patent number: 5104912
    Abstract: An aqueous polymeric gel-forming composition which slowly crosslinks to form stable gels for plugging highly permeable zones in subterranean oil-bearing formations. The composition comprises an aqueous solution of a water-dispersible polymer present in a viscosifying amount and a crosslinking agent present in an amount effective to cause gelation of the polymeric solution which comprises a mixture of an aldehyde and a member selected from the group consisting of phenolic esters, naphtholic esters, halogenated phenolic esters and halogenated naphtholic esters.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: April 14, 1992
    Assignee: Mobil Oil Corporation
    Inventor: Dennis H. Hoskin
  • Patent number: 5102935
    Abstract: The invention relates to new, free-flowing polyamide molding compounds and blends, characterized in that they are prepared by mixing of polyamides known per se in the melt with low molecular weight, liquid-crystalline esters and/or ester amides corresponding to formula (I) and/or liquid-crystalline, oligomeric esters and/or ester amides corresponding to formula (II) and, optionally, other additives, at least one polymeric blending component being used as a further additive in the case of polyamide blends, and to the use of these liquid-crystalline (LC) additives I and/or II as flow promoters in polyamide molding compounds and blends and to a process for the production of the new polyamide molding compounds and blends. The invention also relates to the new oligomeric esters and/or ester amides corresponding to formula (II).
    Type: Grant
    Filed: September 5, 1989
    Date of Patent: April 7, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Detlef Heinz, Harald Pielartzik, Aziz El-Sayed, Rolf-Volker Meyer, Martin Wandel, Peter-Roger Nyssen
  • Patent number: 5041485
    Abstract: Dispersions of stabilizers for plastics in water which contain special reaction products of diols and carboxylic acid anhydrides as auxiliary emulsifiers, and which are characterized by simple preparation, stability and good effectiveness in chemical materials.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: August 20, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Karl-Erwin Piejko, Christian Lindner, Adolf Schmidt, Karl-Heinz Ott
  • Patent number: 5034448
    Abstract: A casting process for the preparation of whiteware ceramic articles employs a polyalkylene polyamine, such as tetraethylene pentamine, as an additive to increase the casting rate. The additive can be employed, e.g., in slip casting, vacuum casting and pressure casting. Optionally, the additive includes a binder such as a styrene butadiene latex in an amount effective to maintain the green strength of the articles prepared in the casting process.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: July 23, 1991
    Assignee: The Dow Chemical Company
    Inventors: Brian D. Koblinski, Alan P. Croft, Alfredo C. Tamez
  • Patent number: 5011879
    Abstract: An engineering plastic composition with excellent flowability, heat stability, and desirable mechanical properties is provided. The composition comprises an engineering plastic material and at least one p-quaterphenyl derivative of specific formula.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: April 30, 1991
    Assignees: Sekisui Kagaku Kogyo Kabushiki Kaisha, Kabushiki Kaisha Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Toshio Uesaka, Akihiro Niki, Makoto Ohsuga, Toranosuke Saito, Hiroki Tsunomachi, Makoto Yamaguchi, Kazuo Doyama, Daishiro Kishimoto
  • Patent number: 4948670
    Abstract: A vinyl chloride resin composition for coating electric wires, which comprises 100 parts by weight of a vinyl chloride resin and from 10 to 200 parts by weight of an alkyl biphenyltetracarboxylate.
    Type: Grant
    Filed: March 31, 1989
    Date of Patent: August 14, 1990
    Assignee: Mitsubishi Kasei Vinyl Company
    Inventors: Seiichi Morimoto, Kazuyuki Shiji, Hisahiro Kusu
  • Patent number: 4897307
    Abstract: The present invention relates to a process for the solvent-induced crystallization of amorphous poly(etheretherketone)-type polymer to produce an article, which process comprises:A. contacting a preformed article of a polymer comprising amorphous poly(etheretherketone)-type polymer with at least one organic compound in its liquid state which consists essentially of atoms of carbon and hydrogen, optionally with oxygen, nitrogen, sulfur, halogen or mixtures thereof having a molecular weight of between about 160 and 320 daltons at a temperature of between about 85.degree. C. and 145.degree. C. for a time effective to crystallize the poly(etheretherketone)-type polymer,B. removing the organic compound, andC. recovering the article comprising crystallized poly(etheretherketone)-type polymer. Poly(etheretherketone), poly(phenylenesulfide) or mixtures thereof are preferred polymer systems.
    Type: Grant
    Filed: August 11, 1987
    Date of Patent: January 30, 1990
    Assignee: The Dow Chemical Company
    Inventors: Henry N. Beck, Robert M. Nowak
  • Patent number: 4873271
    Abstract: The invention relates to thermoplastic polycarbonate molding compositions which are rendered improved resistance to gamma-radiation by the incorporation therewith of about 0.05 to about 5.0 percent by weight of an ester of poly(alkylene)oxide conforming to ##STR1## wherein R is a C.sub.1 -C.sub.20 alkyl, aryl or alkylaryl, Y denotes a hydrogen atom or a C.sub.1 -C.sub.6 alkyl radical, and X is about 1 to 40, preferably 5 to 30.The compositions of the invention exhibit excellent resistance to yellowness and formation of haze which commonly characterize gamma irradiated articles molded from polycarbonate.
    Type: Grant
    Filed: April 25, 1989
    Date of Patent: October 10, 1989
    Assignee: Mobay Corporation
    Inventors: Charles E. Lundy, Sivaram Krishnan
  • Patent number: 4845142
    Abstract: Optical devices such as optical disk substrates and lenses are prepared by molding a resin composition comprising 100 parts by weight of a mixture of 30 to 70% by weight of a polymer in which 50% by weight or more is composed of aromatic vinyl monomer units and 70 to 30% by weight of a polyphenylene ether, and 0.005 to 2 parts by weight of an organic carboxylic acid.
    Type: Grant
    Filed: June 13, 1988
    Date of Patent: July 4, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masahiro Niwano, Kenji Manabe
  • Patent number: 4829115
    Abstract: This invention is concerned with the stabilization of organic materials subject to oxidative degradation. The synergists of this invention possess organothioethyl alcohol segmers or moieties which enhance the antioxidative activity of phenolic and amine stabilizers. The invention is also concerned with compounds that contain an organothioethyl alcohol moiety and their use in oxidizable materials in combination with polymerizable and/or conventional antidegradants.
    Type: Grant
    Filed: March 3, 1988
    Date of Patent: May 9, 1989
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Kirkwood S. Cottman
  • Patent number: 4595722
    Abstract: This invention relates to thermoplastic coating compositions which utilize organic solvent solutions of acrylic copolymer as film-forming media.Enhanced distortion resistance is obtained by utilizing acrylic polymer which comprises two types of polar group, the two types interacting strongly. A further embodiment utilizes in addition a plasticizer which comprises a chain of units of the formula --CO--(CH.sub.2).sub.5 --O--.The compositions are useful as lacquers for the automotive and refinish industries.
    Type: Grant
    Filed: August 29, 1984
    Date of Patent: June 17, 1986
    Assignee: Dulux Australia Ltd.
    Inventor: Christopher H. Such
  • Patent number: 4558085
    Abstract: The fast crystallizing polyalkyleneterephthalate resin compositions disclosed herein contain 0.05-4 percent by weight of a sodium salt of a hydrocarbon acid having the formula R.degree.(COO).sub.y Na.sub.z wherein R.degree. is a hydrocarbon group having a valency of y and having 1-25 carbon atoms therein, preferably 1-10 carbon atoms, y is an integer having a value of at least one, advantageously 1-10 and preferably 1-3, and z is an integer having a value of at least one and no greater than the value of y, this sodium salt of the hydrocarbon acid being in the form of a complex with a polymeric compound, which contains at least two recurring units of the formula --CH.sub.2 CH.sub.2 O--, together with reinforcing agents, fillers and/or additives and optionally a flow promoter selected from low molecular weight organic esters or polymers containing a recurring structure of [(CH.sub.2).sub.x O--].sub.
    Type: Grant
    Filed: August 20, 1984
    Date of Patent: December 10, 1985
    Assignee: Plastics Engineering Company
    Inventor: Chung J. Lee
  • Patent number: 4525521
    Abstract: A coating composition which cures at ambient temperatures of 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, the binder contains about:A. 60-80% by weight, based on the weight of the binder, of an acrylic polymer of polymerized monomers of methyl methacrylate and an alkyl methacrylate, an alkyl acrylate or mixtures thereof, each having 2-12 carbon atoms in the alkyl group and the polymer has pendent amino ester or hydroxy amino ester groups;B. 20-40% by weight, based on the weight of the binder, of a glycidyl acrylic crosslinking polymer of polymerized monomers of glycidyl methacrylate or glycidyl acrylate and an alkyl methacrylate, alkyl acrylate or mixtures thereof, each having 2-12 carbon atoms in the alkyl group.The composition is useful as an exterior finish for automobiles and trucks and for repairing finishes of automobiles and trucks.
    Type: Grant
    Filed: July 27, 1984
    Date of Patent: June 25, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Herman C. DenHartog, Aloysius N. Walus
  • Patent number: 4469651
    Abstract: Disclosed is a process for extruding thermoplastic resinous compositions, comprising the steps of heat plastifying the resinous composition in an extruder; cooling the heat plastified resinous composition exiting from the extruder to a uniform temperature desired for extrusion through an extrusion die, including conveying the resinous composition through at least one enclosed flow path in a cooling device, circulating a cooling medium about the entire circumference of each of the resin flow paths and controlling by the means of orifices the flow of thermoplastic at the inlet and the outlet of the cooling device across substantially the entire cross-section of each of the resin flow paths; and, extruding the cooled thermoplastic resinous composition through an extrusion die downstream of the cooling device.
    Type: Grant
    Filed: May 16, 1983
    Date of Patent: September 4, 1984
    Assignee: Cosden Technology, Inc.
    Inventors: Granville J. Hahn, Raleigh N. Rutledge
  • Patent number: 4467061
    Abstract: This invention relates to a polyolefin composition with an improved weather resistance, which comprises a polyolefin blended with (1) a benzotriazole compound, (2) a heterocyclic hindered amine compound and (3) a phenyl benzoate compound or nickel complex compound.
    Type: Grant
    Filed: December 27, 1982
    Date of Patent: August 21, 1984
    Assignees: Tonen Sekiyu Kagaku Kabushiki Kaisha, Toyota Jidosha Kabushiki Kaisha
    Inventors: Noboru Yamamoto, Masakichi Shimada, Shigeo Yamazaki, Tsuyoshi Kanai, Kazuo Sei, Yoshiro Umemoto
  • Patent number: 4454276
    Abstract: A polyamide acid composition for preparing a polyimide which can extend the pot life of the composition comprising a solution of a polyamide acid in an organic solvent, the polyamide acid being a precursor of the polyimide, a dehydrating agent, a catalyst and a pot life extending agent which can lower a rate of conversion of the polyamide acid to the polyimide, and the process for preparing the polyimide from said polyamide acid composition. According to the present invention the pot life can be extremely extended to give the composition an enough flowability for a long time without reducing the excellent properties such as a heat resistance and an electric insulation of the obtained polyimide.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: June 12, 1984
    Assignee: Kanegafuchi Chkagaku Kogyo Kabushiki Kaisha
    Inventors: Junji Uda, Tsuneo Yamamoto, Takumi Kosugi
  • Patent number: 4444933
    Abstract: A cyanoacrylate-based adhesive composition comprises 55-92% by weight of a 2-cyanoacrylate ester, preferably the ethyl ester, from 40-30% by weight of a vinyl chloride/vinyl acetate copolymer and not more than 25% by weight of a plasticizer (the plasticizer may be omitted entirely). The copolymer is preferably a vinyl chloride/vinyl acetate/maleic acid terpolymer. The adhesive compositions have greatly reduced adhesion to skin, not forming strong skin bonds for at least 30 seconds, in contrast to conventional cyanoacrylate adhesive compositions which form, within in about one second bonds strong enough to tear skin.
    Type: Grant
    Filed: December 2, 1982
    Date of Patent: April 24, 1984
    Assignee: Borden, Inc.
    Inventors: Peter S. Columbus, John Anderson
  • Patent number: 4438233
    Abstract: The fast crystallizing polyalkyleneterephthalate resin compositions disclosed herein contain 0.05-4 percent by weight of lithium bromide, chloride or iodide in the form of a selected complex of the lithium halide (LiX) and an organic compound, such as a polymeric compound, which contains at least two recurring units of the formula --CH.sub.2 CH.sub.2 O-- together with reinforcing agents, fillers and/or additives and optionally a flow promoter selected from low molecular weight organic esters or block copolymers containing a recurring structure of [(CH.sub.2).sub.x O--].sub.m wherein x is an integer of no more than 5 and m is an integer ranging from 2, preferably from 200 to about 5,000. The amount of complex is such as to give 0.05 to 4 percent, preferably 0.1-2 percent by weight of LiX based on the weight of polyalkyleneterephthalate.
    Type: Grant
    Filed: September 20, 1982
    Date of Patent: March 20, 1984
    Assignee: Plastics Engineering Company
    Inventor: Chung J. Lee
  • Patent number: 4431497
    Abstract: An olefinic polymer composition is provided which comprises an olefinic polymer selected from homopolymers and copolymers made from aliphatic, ethylenically unsaturated monomers containing from 2 to about 10 carbon atoms and from about 100 to about 10,000 ppm of a stabilizer selected from benzhydrol or benzhydrol derivative compound of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are each independently selected from an aromatic group having from 6 to about 26 carbon atoms, and R.sub.3 is selected from hydrogen, an alkyl group having from 1 to about 20 carbon atoms, or an acyl group having from about 2 to 20 carbon atoms.
    Type: Grant
    Filed: October 30, 1981
    Date of Patent: February 14, 1984
    Assignee: Milliken Research Corporation
    Inventor: John W. Rekers
  • Patent number: 4429067
    Abstract: Use of a selected benzoate oligomer has been found to reduce mold deposits and to lower volatility without impairing crystallization rates of polyethylene terephthalate molding blends which contain an ionic hydrocarbon copolymer or ionic salt of a hydrocarbon acid, over polyethylene terephthalate blends which contained the ionic component and other additives.
    Type: Grant
    Filed: October 27, 1982
    Date of Patent: January 31, 1984
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Sumner A. Barenberg
  • Patent number: 4423093
    Abstract: A method of applying a coating of polyarylene sulphide to a bearing in which an initmate mixture of a polyarylene sulphide with an aryl ester of an aryl alcohol is applied to a bearing blank and subsequently heated to evaporate the ester and cure the coating. The mixture can be a dry powder mixture, a wet powder mixture, a paste, a suspension, a liquid solution or a solid solution. The preferred mixture comprises polyphenylene sulphide and benzyl benzoate.
    Type: Grant
    Filed: March 3, 1982
    Date of Patent: December 27, 1983
    Assignee: The Glacier Metal Company Limited
    Inventor: Glyndwr J. Davies
  • Patent number: 4421885
    Abstract: A plasticizer for halogen-containing resins which is composed of at least one compound expressed by the general formula ##STR1## wherein R.sub.1 represents an aromatic hydrocarbon group containing 1 or 2 aromatic rings or an alicyclic hydrocarbon group having 4 to 37 carbon atoms, R.sub.2.sup.1, R.sub.2.sup.2, R.sub.2.sup.3 and R.sub.2.sup.4 are identical or different and each represents an aliphatic hydrocarbon group having 2 to 17 carbon atoms, R.sub.3.sup.1, R.sub.3.sup.2, R.sub.3.sup.3 and R.sub.3.sup.4 are identical or different and each represents an aliphatic hydrocarbon group having 2 to 22 carbon atoms, an aromatic hydrocarbon group or a heterocyclic group, each of n.sub.1, n.sub.2, n.sub.3 and n.sub.4 is 0 or an integer of 1 to 20 and the sum of these is 1 to 20, and each of m.sub.1, m.sub.2, m.sub.3 and m.sub.4 is 0 or 1 and the sum of these is 1 to 4. The plastizer has superior thermal stability, processability and compatibility.
    Type: Grant
    Filed: September 17, 1981
    Date of Patent: December 20, 1983
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Katsuhiro Tsuda, Hisao Tanaka, Michio Nagae, Yasuhiko Imanaga
  • Patent number: 4421588
    Abstract: A plastics alloy for a bearing material comprising polyphenylene sulphide and polyether ether ketone. The alloy is formed by powder mixing, melt blending or solvent blending and applied to a metal backing either as a sheet, or in solution or in powder form. The alloy is heated and roll bonded to the backing.
    Type: Grant
    Filed: October 22, 1982
    Date of Patent: December 20, 1983
    Assignee: AEPLC
    Inventor: Glyndwr J. Davies
  • Patent number: 4421795
    Abstract: A method of applying a coating of polyarylene sulphide to a cooking utensil in which an intimate mixture of a polyarylene sulphide with an aryl ester of an aryl alcohol is applied to the surface of the utensil and subsequently heated to evaporate the ester and cure the coating. The mixture can be a dry powder mixture, a wet powder mixture, a paste, a suspension a liquid solution or a solid solution. The preferred mixture comprises polyphenylene sulphide and benzyl benzoate.
    Type: Grant
    Filed: March 3, 1982
    Date of Patent: December 20, 1983
    Assignee: The Glacier Metal Company Limited
    Inventor: Glyndwr J. Davies
  • Patent number: 4413083
    Abstract: A composition comprising an intimate mixture of a polyarylene sulphide with an aryl ester of an aryl alcohol. The mixture can be a dry powder mixture, a wet powder mixture, a paste, a suspension a liquid solution or a solid solution. The preferred mixture comprises polyphenylene sulphide and benzyl benzoate. There is also described a method of curing polyphenylene sulphide comprising dissolving the polyphenylene sulphide in benzyl benzoate and heating the solution so that the benzyl benzoate evaporates and the polyphenylene sulphide cures simultaneously.
    Type: Grant
    Filed: March 3, 1982
    Date of Patent: November 1, 1983
    Assignee: The Glacier Metal Company Limited
    Inventor: Glyndwr J. Davies
  • Patent number: 4405741
    Abstract: The fast crystallizing polyalkyleneterephthalate resin compositions disclosed herein contain 0.05-4 percent by weight of NaSCN in the form of a selected complex of sodium thiocyanate (NaSCN) and an organic compound, such as a polymeric compound, which contains at least two recurring units of the formula -CH.sub.2 CH.sub.2 O- together with reinforcing agents, fillers and/or additives and optionally a flow promoter selected from low molecular weight organic esters or block copolymers containing a recurring structure of [(CH.sub.2).sub.x O--].sub.m wherein x is an integer of no more than 5 and m is an integer ranging from 2, preferably from 200 to about 5,000. The amount of complex is such as to give 0.05 to 4 percent, preferably 0.1-2 percent by weight of NaSCN based on the weight of polyalkyleneterephthalate.
    Type: Grant
    Filed: September 20, 1982
    Date of Patent: September 20, 1983
    Assignee: Plastics Engineering Company
    Inventor: Chung J. Lee
  • Patent number: 4405740
    Abstract: A composition comprising an intimate mixture of a polyarylene sulphide with an aryl ester of an aryl alcohol, the ester being in the liquid phase and the resin being a wet powder mixture, in suspension, in solution or in the form of a paste. The preferred mixture comprises polyphenylene sulphide and benzyl benzoate. There is also described a method of curing polyphenylene sulphide comprising dissolving the polyphenylene sulphide in benzyl benzoate and heating the solution so that the benzyl benzoate evaporates and the polyphenylene sulphide cures simultaneously.
    Type: Grant
    Filed: March 3, 1982
    Date of Patent: September 20, 1983
    Assignee: The Glacier Metal Company Limited
    Inventor: Glyndwr J. Davies
  • Patent number: 4383069
    Abstract: A composition comprising an intimate mixture of a polyarylene sulphide with an aryl ester of an aryl alcohol, the ester being in solid solution in the resin. The preferred mixture comprises polyphenylene sulphide and benzyl benzoate. There is also described a method of curing polyarylene sulphide in which the solid solution of the ester in the resin is formed and this is heated so that the ester evaporates and the resin cures simultaneously.
    Type: Grant
    Filed: March 3, 1982
    Date of Patent: May 10, 1983
    Assignee: The Glacier Metal Company Limited
    Inventor: Glyndwr J. Davies
  • Patent number: RE31874
    Abstract: Propagation of electrical trees and water trees in electrical insulation made of ethylene homopolymers or copolymers with an unsaturated monomer is inhibited by the addition to the insulating composition of an organic carboxylic ester having at least one aromatic ring and at least three carboxylic ester groups, the ester being liquid at the operating temperature of the electrical equipment in which the insulation is used. The main utility of the inhibitors of this invention is in the primary insulation for power transmission cables, especially those used in high voltage applications.
    Type: Grant
    Filed: November 2, 1983
    Date of Patent: April 30, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: John K. Beasley, Edward J. Urban
  • Patent number: RE32595
    Abstract: A plastics alloy for a bearing material comprising polyphenylene sulphide and polyether ether ketone. The alloy is formed by powder mixing, melt blending or solvent blending and applied to a metal backing either as a sheet, or in solution or in powder form. The alloy is heated and roll bonded to the backing.
    Type: Grant
    Filed: February 5, 1986
    Date of Patent: February 9, 1988
    Assignee: AEPLC
    Inventor: Glyndwr J. Davies