Two Or More Aryl-oh Dnrm Compounds Patents (Class 524/348)
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Patent number: 8962116Abstract: The present invention relates to a pipe consisting of a polyethylene composition which comprises—a base resin, comprising •a first ethylene homo- or copolymer (A): and •a second ethylene copolymer (B); and the polyethylene composition further comprises—a phenol-type stabilizer (C); and—a phenol-type stabilizer (D); whereby stabilizers (C) and (D) are different. The present invention is furthermore directed to the use of—a phenol-type stabilizer (C); and—a phenol-type stabilizer (D); whereby stabilizers (C) and (D) are different and, optionally,—a further stabilizer (E) selected from •phosphorous containing stabilizer (E1); •sulphur containing stabilizers (E2); •nitrogen containing stabilizers (E3); and/or •mixtures thereof; for increasing the slow crack growth resistance of pipes.Type: GrantFiled: May 26, 2011Date of Patent: February 24, 2015Assignee: Borealis A.G.Inventor: Siv Rundqvist
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Publication number: 20130122228Abstract: The present invention relates to a pipe consisting of a polyethylene composition which comprises—a base resin, comprising •a first ethylene homo- or copolymer (A): and •a second ethylene copolymer (B); and the polyethylene composition further comprises—a phenol-type stabilizer (C); and—a phenol-type stabilizer (D); whereby stabilizers (C) and (D) are different. The present invention is furthermore directed to the use of—a phenol-type stabilizer (C); and—a phenol-type stabilizer (D); where-by stabilizers (C) and (D) are different and, optionally,—a further stabilizer (E) selected from •phosphorous containing stabilizer (E1); •sulphur containing stabilizers (E2); •nitrogen containing stabilizers (E3); and/or •mixtures thereof; for increasing the slow crack growth resistance of pipes.Type: ApplicationFiled: May 26, 2011Publication date: May 16, 2013Inventor: Siv Rundgvist
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Patent number: 8357749Abstract: The instant invention provides an aqueous dispersion, a coating composition, coating layers and coated article made therefrom.Type: GrantFiled: March 2, 2011Date of Patent: January 22, 2013Assignees: Dow Global Technologies LLC, Rohm and HAAS CompanyInventors: David L. Malotky, Bernhard Kainz, Charles F. Diehl, Denise Lindenmuth, Timothy J. Young, John N. Argyropoulos
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Patent number: 8349965Abstract: A fluororubber composition according to the present invention contains 0.1 to 3 parts by weight of a polyol compound, 0.1 to 4 parts by weight of a peroxide crosslinking agent, and 1 to 9 parts by weight of a co-crosslinking agent per 100 parts by weight of a peroxide-crosslinkable fluoropolymer. A crack-resistant seal according to the present invention contains a crosslinked fluoropolymer and a polyol compound. The crack-resistant seal according to the present invention can be formed by crosslinking the fluororubber composition, and the resultant crack-resistant seal has particularly high crack resistance. With the fluororubber composition according to the present invention, a durable crack-resistant seal having high plasma resistance, crack resistance, and compression set and that produces few particles can be formed at low cost.Type: GrantFiled: March 12, 2009Date of Patent: January 8, 2013Assignee: Nippon Valqua Industries, Ltd.Inventors: Masanori Okazaki, Naoki Ohsumi
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Patent number: 8192813Abstract: A high strength, flexible crosslinked polyethylene (PEX) material is provided wherein the base polymer is intermixed with a polymer modifier which affects the amorphous region of the polymer, leaving the crystalline portion of the base polymer virtually unaffected. Consequently, the amorphous region's density is lowered, resulting in a more flexible final product, while the crosslinked molecular structure and/or crystalline portion of the polymer, which controls the strength of the base polymer, remains strong. The polymer modifier can comprise a hydrocarbon fluid such as PAO, Group III basestocks, or a gas-to-liquid hydrocarbon. A method for producing the plastic material is also provided. The plastic material has particular utility in the production of tubing, piping, and conduits for transporting gases, liquids, and the like, as well as wire and cable coatings such as jacketing and insulation.Type: GrantFiled: June 18, 2008Date of Patent: June 5, 2012Assignees: ExxonMobil Chemical Patents, Inc., Zurn Pex, Inc.Inventors: Gary Lee Runyan, Bruce A. Harrinton, Bryan R. Chapman, David B. Dunaway, Gerd Arthur Allenmann, Robert G. Russell, Rodney Mize
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Patent number: 7652092Abstract: The present invention relates to articles made from plasticized thermoplastic polyolefin compositions comprising a thermoplastic polyolefin, a nucleating agent, and a non-functionalized hydrocarbon plasticizer.Type: GrantFiled: April 19, 2006Date of Patent: January 26, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Mun Fu Tse, Chon-Yie Lin, Bryan R. Chapman, Bruce R. Lundmark
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Patent number: 7439291Abstract: A solvent-resistant polymeric membrane comprising a solvent-inert polymer having a solubility parameter greater than 18 (J/cm3)0.5, such as a polyketone, a polyether ketone, polyarylene ether ketone ketone, a polyimide, a polyetherimide, or a polyphenylene sulfide, is described. The solvent-resistant polymeric membrane can be prepared by methods in which solvent-inert polymers form a solution at room temperature.Type: GrantFiled: September 14, 2005Date of Patent: October 21, 2008Assignee: General Electric CompanyInventors: Hua Wang, Anatoli Kogan, Jared Paul Ray, Gary William Yeager
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Patent number: 6855758Abstract: The invention relates to transparent, biaxially oriented and heat-set films having one or more layers and compris, as main constituent, at least one crystallizable thermoplastic, in particular a polyester, and also comprise at least one hydrolysis stabilizer. The hydrolysis stabilizer is preferably a phenolic compound, an oxazoline, and/or a monomeric or polymeric carbodiimide, where appropriate combined with an organic phosphite. It is preferably added in the form of a masterbatch. The film exhibits low longitudinal and transverse shrinkage. On exposure to moisture and heat it shows practically no embrittlement and retains its ultimate tensile strength. The additional functionality is preferably that the film has been made UV-resistant, or flame-retardant, or on one side or on both sides has been coated, or is sealable, and/or has been corona- or flame-treated.Type: GrantFiled: June 15, 2001Date of Patent: February 15, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Thorsten Kiehne, Harald Hessberger
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Patent number: 6846866Abstract: The invention provides polyurethane containing a) a first additive comprising at least one mono-hindered hydroxyphenyl group and having a molecular weight of at least about 300 Daltons; b) a second additive selected from the group consisting of i) condensation polymers of p-cresol and divinyl benzene and ii) compounds comprising at least one unsymmetrically di-hindered hydroxyphenyl group and having a molecular weight of at least about 300 Daltons; and c) an inorganic chlorine-resist additive. The polyurethane of the invention exhibits improved resistance to degradation by chlorine and by atmospheric fumes.Type: GrantFiled: June 3, 2002Date of Patent: January 25, 2005Assignee: Invista North America S.a.r.L.Inventors: Nathan E. Houser, Gordon W. Selling
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Patent number: 6646036Abstract: A heat stabilized block copolymer composition which comprises a block copolymer comprising a polymer block mainly composed of a monoalkenyl aromatic compound and a polymer block mainly composed of a conjugated diene compound, the content of the monoalkenyl aromatic compound being 5-95% by weight based on the total weight of the block copolymer, and phenolic stabilizers. By adding two or more specific phenolic stabilizers to a block copolymer of a monoalkenyl aromatic compound and a conjugated diene compound, there can be obtained a block copolymer composition which exhibits excellent heat stability even under being heated at high temperatures, is high in the effect of being inhibited from formation of gel-like materials and is excellent in color tone.Type: GrantFiled: January 9, 2002Date of Patent: November 11, 2003Assignee: Japan Elastomer Co., Ltd.Inventors: Masahiro Fujiwara, Keiichi Toda
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Patent number: 6627687Abstract: The invention aims at providing a rubber composition for adhering to steel cords which is excellent in heat-resistant adhesion and moist heat-resistant adhesion as well as initial adhesion and has performance of a level similar to or higher than that of the related art in resistance to rubber fracture, wherein the following component (A) is blended in a metal-converted amount of 0.01 to 10 weight parts to 100 weight parts of rubber components containing natural rubber and/or diene synthetic rubber: Component (A): a mixture of a compound containing nickel, a compound containing molybdenum, and a compound containing cobalt; or a compound containing nickel, molybdenum, and cobalt simultaneously.Type: GrantFiled: May 25, 2001Date of Patent: September 30, 2003Assignee: Toyo Tire & Rubber Co., Ltd.Inventors: Seiji Hatano, Hirofumi Hayashi
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Patent number: 6534578Abstract: A refrigerant hose for an air conditioner has an inner wall layer formed of a laminate of an inner resin layer and an outer rubber layer bonded by its vulcanization to the resin layer. The rubber layer is of a composition comprising butyl rubber, an adhesive material based on resorcinol and a vulcanizing agent based on an alkylphenol-formaldehyde resin, and having a bromine content of at least 0.5% by weight. The hose having the inner wall layer surrounded by a reinforcing layer and an outer wall layer exhibits a high adhesive strength even at an elevated temperature between its refrigerant-impermeable resin layer and its water-impermeable rubber layer.Type: GrantFiled: July 27, 2000Date of Patent: March 18, 2003Assignee: Tokai Rubber Industries, Ltd.Inventors: Eiichi Daikai, Koji Senda
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Patent number: 6525158Abstract: Recycled mixtures of plastics, predominantly thermoplastics, as predominantly produced in the household, in commerce and also in industry and useful material collections, can be stabilized against thermooxidative degradation by adding a combination of a sterically hindered phenol with an organic phosphite or phosphonite and an inorganic compound from the series consisting of metal oxides, hydroxides and carbonates.Type: GrantFiled: September 17, 1997Date of Patent: February 25, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Kurt Hoffmann, Heinz Herbst, Rudolf Pfaendner, Hans-Jürgen Sander, Franciszek Sitek
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Patent number: 6391951Abstract: The invention provides a copolymer of propylene and pentene, together with a process for producing such copolymer and a polymer composition. In the process, propylene and pentene are reacted in a reaction zone at a pressure of 60 kg/cm2 and temperature of 0-100° C. for 20-480 minutes in the presence of a Ziegler-Natta catalyst or catalyst system. The polymer composition has several components, namely the above copolymer, a phenolic stabilizer, an organic phosphite stabilizer, a thioether stabilizer and at least one metal salt of a higher aliphatic acid, with the proviso that at least one of the organic phosphite stabilizer, the thioether stabilizer and said salt must be present, so that up to two thereof can optionally be omitted.Type: GrantFiled: July 13, 2000Date of Patent: May 21, 2002Assignee: Sasol Technology (Proprietary) LimitedInventors: Dawid Johannes Joubert, Antonie Hermanus Potgieter, Ignatius Hendrik Potgieter, Ioan Tincul
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Publication number: 20020028865Abstract: An aqueous emulsion-type release coating composition comprising (i) a product produced by reaction of an ethylene-vinyl alcohol copolymer represented by the formula (1): 1Type: ApplicationFiled: April 21, 1999Publication date: March 7, 2002Inventors: KOUJI KANEMOTO, SADAHIKO NISHIKAWA
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Patent number: 6265475Abstract: A high damping material composition useful as a vibration damper and an acoustic insulating material such as a sound insulating wall for an acoustic room, a sound insulating partition for a construction structure and a soundproofing wall for a vehicle. The high damping material composition of the present invention containing the following components (A) and (B); (A) a polymer having in the molecular chain thereof a chemical structural unit derived from the following (a); (a) at least one selected from the group consisting of an acrylic monomer, a methacrylic monomer, an ethylene-acrylic copolymer, an ethylene-methacrylic copolymer and vinyl acetate; (B) at least one damping property imparting agent selected from the group consisting of a hindered phenol compound, a phosphite ester compound, a phosphate ester compound, a basic compound containing nitrogen and a hindered amine compound.Type: GrantFiled: July 30, 1999Date of Patent: July 24, 2001Assignee: Tokai Rubber Industries, Ltd.Inventors: Wu Chifei, Takeshi Nomura, Toshiyuki Mihara, Kazunobu Hashimoto, Tetsuya Takeuchi
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Patent number: 6191246Abstract: The invention provides a polymer which is a polymerization product obtained by polymerizing at least ethylene, 1-pentene and 1-hexene; and a process for producing a polymer by reacting at least ethylene, 1-pentene and 1-hexene in a reaction zone at a pressure between atmospheric and 60 kg/cm3 and at a temperature between 30° C. and 120° C., in the presence of a catalyst system. The invention also provides a polymer composition which comprises a terpolymer of ethylene, 1-pentene and 1-hexene, a phenolic stabilizer component, a metal salt of a higher aliphatic acid, and, optionally, at least one organic phosphite stabilizer.Type: GrantFiled: January 12, 1998Date of Patent: February 20, 2001Assignee: Sasol Technology (Proprietary) LimitedInventors: Dawid Johannes Joubert, Ignatius Hendrik Potgieter, Ioan Tincul, Peter Loggenberg
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Patent number: 6136902Abstract: To provide a polyacetal resin composition having an excellent corrosion inhibiting effect on metals, particularly reduced in the adverse effect on magnetic tapes or the like, and suitable for use in producing component parts of a magnetic tape cassette such as a reel hub or tape guide, 100 parts by weight of a polyacetal resin (A) is blended with 0.05 to 5 parts by weight of an antioxidant (B), 0.001 to 5 parts by weight of a specified nitrogen-containing compound (C), and 0.001 to 3 parts by weight of a boric acid compound.Type: GrantFiled: June 18, 1997Date of Patent: October 24, 2000Assignee: Polyplastics Co., Ltd.Inventors: Yoshihito Fukasawa, Sachio Anada
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Patent number: 5869185Abstract: A polycarbonate substrate coated with an acrylic coating containing at least one polybenzoylresorcinol, and optionally a silicone hardcoat on the acrylic coating, wherein said at least one polybenzoylresorcinol has the formula ##STR1## wherein each A is independently a substituted or unsubstituted monocyclic aromatic radical wherein any substituents are hydrogen, halogen, alkoxy, C.sub.1-8 alkyl, or hydroxy, and R is hydrogen or a linear or branched aliphatic radical having less that about 10 carbon atoms.Type: GrantFiled: June 21, 1996Date of Patent: February 9, 1999Assignee: General Electric CompanyInventors: Steven Roger Bahr, James Edward Pickett, Karen Kueck Webb
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Patent number: 5760171Abstract: Polyphenylene ethers are decolorized by contact in the melt or in solution with a hydroxy compound containing either another hydroxy group or a double or aromatic bond in a specific location in the molecule. Illustrative decolorizing compounds are benzopinacol, benzoin and acetoin.Type: GrantFiled: January 24, 1997Date of Patent: June 2, 1998Assignee: General Electric CompanyInventors: Dwain Montgomery White, Gary William Yeager
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Patent number: 5395872Abstract: Double-component acrylic adhesive compositions are disclosed, in which:(a) the adhesive component comprises a mono-functional acrylic monomer, a loro-sulfonated polyolefin and a crosslinker selected from difunctional silicon derivatives;(b) the activating component is a typical aldehyde-amine condensation product.Type: GrantFiled: June 10, 1994Date of Patent: March 7, 1995Assignee: Ministero Dell'Universita' e Della Ricerca Scientifica e TecnologicaInventors: Vittorio Di Ruocco, Fabio Garbassi
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Patent number: 5393844Abstract: Rubber compositions having high tensile modulus at 100% and strong metal adhesion. The rubber compositions include chlorinated polyethylene rubber and/or its derivative reformed with maleic anhydride with from 0.2 to 10 parts by weight per 100 parts of the rubber of a 2,4,6-trimercapto-1,3,5-triazine dicyclohexylamine salt.Type: GrantFiled: June 21, 1993Date of Patent: February 28, 1995Assignee: The Yokohama Rubber Co., Ltd.Inventors: Osamu Ozawa, Tetsu Kitami
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Patent number: 5356976Abstract: Compounds of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.4 n-alkyl, isopropyl, s-butyl, cyclopentyl, cyclohexyl or .alpha.-methylbenzyl, R.sub.2 is C.sub.4 -C.sub.18 tert-alkyl or .alpha.,.alpha.-dimethylbenzyl, R.sub.3 is C.sub.1 -C.sub.28 alkyl, and R.sub.4 s methyl or ethyl, with the proviso that the --CHR.sub.3 R.sub.4 group contains at least 4 carbon atoms, are suitable for stabilizing organic material which is susceptible to degradation induced by heat, oxidation or actinic light.Type: GrantFiled: July 12, 1993Date of Patent: October 18, 1994Assignee: Ciba-Geigy CorporationInventors: Paul Dubs, Rita Pitteloud
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Patent number: 5216061Abstract: Hindered phenol stabilized, stereoregular polymers of branched, higher alpha-olefins can be modified with unsaturated silanes, carboxylic acids, and/or carboxylic acid anhydrides in the presence of a free radical generator in the polymer melt. These polymers can also contain additional additives, such as glass fibers. An aliphatic thio compound is added after the grafting procedure for maximum beneficial effect.Type: GrantFiled: January 11, 1991Date of Patent: June 1, 1993Assignee: Phillips Petroleum CompanyInventor: Edwin Boudreaux, Jr.
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Patent number: 5130356Abstract: A novel, optically transparent, isotropic molding for optical purposes which is free of orientation birefringence consists of a mixture of polyphenylene ethers, vinylaromatic polymers and additives. The novel molding contains traces of novel diphenoquinone and/or diphenohydroquinone derivatives as additives and may also contain novel ammonium salts of sulfuric acid half esters of diphenohydroquinones as further additives. The novel molding has a yellowness index (YI) of from 40 to 90. It can be produced in a simple manner by injection molding processes. The novel molding in the form of a circular disk having a central hole is very useful as a dimensionally stable substrate of audio compact disks (CD), audiovisual compact disks (CDV), laser-optical computer disks and magneto-optical computer disks, and data media of this type which contain these novel dimensionally stable substrates have particularly advantageous performance characteristics.Type: GrantFiled: February 1, 1990Date of Patent: July 14, 1992Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Feuerherd, Carola Hedtmann-Rein, Ludger Leber
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Patent number: 4888394Abstract: Stabilized, stereoregular polymers of branched, higher alpha-olefins can be modified with unsaturated silanes, carboxylic acids, and/or carboxylic acid anhydrides in the presence of a free radical generator in the polymer melt. These polymers can also contain additional additives, such as glass fibers.Type: GrantFiled: June 15, 1988Date of Patent: December 19, 1989Assignee: Phillips Petroleum CompanyInventor: Edwin Boudreaux, Jr.
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Patent number: 4792584Abstract: An adhesive composition comprising100 parts by weight of a block copolymer (a) containing of at least one polymer block composed mainly ofa vinyl aromatic hydrocarbon and at least one polymer block composed mainly of butadiene in which(i) the vinyl aromatic hydrocarbon content [S] is 10 to 30% by weight,(ii) the 1,2-vinyl content of butadiene portion [V] is 20 to 50%, and(iii) the relationship between said vinyl aromatic hydrocarbon content [S] and said 1,2-vinyl content of butadiene portion [V] satisfies the formula,:40.ltoreq.[S]+[V].ltoreq.7040 to 200 parts by weight of a tackifier (b), and, optionallyvarious stabilizers, and a process for producing said composition.Type: GrantFiled: April 23, 1987Date of Patent: December 20, 1988Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Toshinori Shiraki, Yasuo Hattori, Masao Karouji
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Patent number: 4579896Abstract: Flame retardant and drip retardant polycarbonate composition comprised of:(i) at least one aromatic carbonate resin;(ii) a flame retardant amount of at least one flame retardant compound; and(iii) a drip retardant amount of at least one bis cyclic carbonate represented by the general formula ##STR1## wherein X, Y, X' and Y' are the same or different and are hydrogen or alkyl of one to about six carbon atoms, inclusive; W, W', Z and Z' are the same or different and are alkyl of one to about six carbon atoms, inclusive, and E is alkylene or alkylidene of two to about twelve carbon atoms, inclusive.Type: GrantFiled: January 2, 1985Date of Patent: April 1, 1986Assignee: General Electric CompanyInventor: Niles R. Rosenquist
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Patent number: 4568715Abstract: An aromatic polyimide composition usable for producing shaped articles, for example, films, or as varnish, lacquer, or bonding agent, comprises a high molecular weight aromatic polyimide resin which is a polycondensation-imidization product of an aromatic tetracarboxylic acid component comprising 50 molar % or more of 3,4,3',4'-biphenyltetracarboxylic acid, anhydride, salt, or ester with an aromatic diamine component including 50 molar % or more of 4,4'-diaminodiphenylether, and which is dissolved in a mixed solvent consisting essentially of 10% by weight or more of a first solvent component selected from naphthol and resorcin and the balance of a second solvent component selected from phenol and cresols.Type: GrantFiled: March 20, 1985Date of Patent: February 4, 1986Assignee: Ube Industries, Ltd.Inventors: Hiroshi Itatani, Toshihiro Inaike, Shuji Yamamoto
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Patent number: 4474918Abstract: Disclosed are polyester compositions having special utility in film or sheet form having improved gas and water barrier properties, and comprising homo- or copolyesters derived from terephthalic acid or mixtures of terephthalic acid with acids such as isophthalic, 2,6-naphthalene dicarboxylic, and the like, and a glycol component such as ethylene glycol or 1,4-cyclohexanedimethanol, blended with from about 1 to about 30 weight % of certain bisphenols such as bisphenol-A, and naphthalene diols. Films or sheets of these compositions are characterized by having greatly reduced oxygen, carbon dioxide and water vapor permeabilities.Type: GrantFiled: May 31, 1983Date of Patent: October 2, 1984Assignee: Eastman Kodak CompanyInventors: Robert W. Seymour, Ronald R. Light
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Patent number: 4428977Abstract: A water soluble composition including an amine or ammonium salt of a polyimide precursor which is obtained by the reaction steps of: reacting a tetracarboxylic compound and a diamine in about equimolar amounts in a water miscible organic solvent to obtain the polyimide precursor; and reacting the polyimide precursor with ammonia, or an aqueous solution of ammonia, or a primary or secondary aliphatic amine in an amount sufficient to neutralize the free carboxyl groups of the polyimide precursor.A process of coating and a substrate are also disclosed.Type: GrantFiled: September 24, 1976Date of Patent: January 31, 1984Assignee: General Electric CompanyInventor: Marvin A. Peterson
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Patent number: 4412025Abstract: A non-volatile, anti-gel compound having a chain of at least about 5 repeat units of an alkylene oxide and which is soluble in olefin polymers, and an inorganic anti-block agent having a substantially neutral pH are added to a film grade transition metal catalyzed resin containing halide residues such as Ziegler-Natta catalyzed olefin polymer compositions to prevent: (1) gel streaking/pinstriping during film extrusion processes; (2) blocking of the extruded film; and (3) discoloration of the extruded film upon aging. The anti-gel compound has a molecular weight between about 200 and about 4,000,000 Daltons.Type: GrantFiled: October 8, 1981Date of Patent: October 25, 1983Assignee: Union Carbide CorporationInventors: Michael A. Corwin, George N. Foster
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Patent number: 4401798Abstract: The polymerization of a monomer component that comprises vinyl chloride in an aqueous medium in the presence of a free radical generating polymerization initiator is terminated by introducing into the polymerization reaction mixture when from 70% to 95% of the monomer component has been polymerized from 0.01% to 0.10% by weight, based on the weight of the monomer component, of a chain-terminating agent that is an alkyl-substituted trisphenol, such as 1,1,3-tris(2-methyl-4-hydroxy-5-tert.butylphenyl)butane.Type: GrantFiled: April 22, 1982Date of Patent: August 30, 1983Assignee: Tenneco Polymers, Inc.Inventors: Mario Q. Ceprini, Donald Goodman, Samuel Hoch