Solid Polymer Derived From Ethylenic Reactants Only Patents (Class 524/365)
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Patent number: 11920092Abstract: The present invention is related to the use of ethylene alkanoate-alkyl acrylate bipolymers with a high randomness monomers distribution, which are synthesized by semicontinuous emulsion polymerization process, characterized because it is carried out using slow addition rate of the pre-emulsion feeding ({dot over (q)}?0.009 kgL·L?1·min?1), stabilized this last one by alkyl glycol ether type surfactants, at temperatures higher than 75° C. and with solids contents above 25 wt %, which avoids the formation of large sequences (blocks) of a same monomer. This structural characteristic gives the ethylene alkanoate-alkyl acrylate bipolymers a high efficiency as chemical agents for removal of complex water/crude oil emulsions of crude oil blends.Type: GrantFiled: May 17, 2023Date of Patent: March 5, 2024Assignee: INSTITUTO MEXICANO DEL PETROLEOInventors: Cesar Andres Flores Sandoval, Flavio Salvador Vazquez Moreno, Fernando Alvarez Ramirez, Gerardo Zavala Olivares, Erika Gomez Buendia, Enrique Cevada Maya, Jessica Valeria Fuentes Santiago, Edgar Benedicto Zamora Guerrero, Citlally Janinne Vargas Martinez
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Patent number: 10655006Abstract: A liquid binder composition for binding fibrous materials in the fabrication of resin-infusible preform is disclosed. The binder composition is an aqueous dispersion containing (a) one or more multifunctional epoxy resins, (b) at least one thermoplastic polymer, (c) one or more surfactants selected from anionic surfactants, nonionic surfactants, and combinations thereof, (d) water, and is essentially free of organic solvents. Also disclosed is an emulsification process for producing the liquid binder composition.Type: GrantFiled: February 1, 2018Date of Patent: May 19, 2020Assignee: CYTEC TECHNOLOGY CORP.Inventors: Carmelo Luca Restuccia, Gerald Hobisch, William Jacobs, Dominique Ponsolle
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Patent number: 10238854Abstract: A method for joining a flexible tube to a connector having a female fitting that allows relatively facile connection and desirable retention force in a short amount of time. Tube assemblies having a tube bonded to the female fitting of the connector with a joining agent composition including an evaporable liquid hydrocarbon are disclosed.Type: GrantFiled: March 12, 2015Date of Patent: March 26, 2019Assignee: TEKNOR APEX COMPANYInventor: Kevin Cai
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Patent number: 10184073Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in an emulsion (for example using a water based carrier liquid), despite the possible reactions between the monomer and water. Polymerization of 1,1-disubstituted alkene compounds in an emulsion provides opportunities to better control the polymerization compared with bulk polymerization. The emulsion polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.Type: GrantFiled: March 23, 2017Date of Patent: January 22, 2019Assignee: Sirrus, Inc.Inventors: Peter Rulon Stevenson, Alexander R. Holzer, Aniruddha Sudhir Palsule, Jeffrey M. Sullivan
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Patent number: 10081685Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in an emulsion (for example using a water based carrier liquid), despite the possible reactions between the monomer and water. Polymerization of 1,1-disubstituted alkene compounds in an emulsion provides opportunities to better control the polymerization compared with bulk polymerization. The emulsion polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.Type: GrantFiled: March 23, 2017Date of Patent: September 25, 2018Assignee: Sirrus, Inc.Inventors: Peter Rulon Stevenson, Alexander R. Holzer, Aniruddha Sudhir Palsule, Jeffrey M. Sullivan
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Patent number: 10000672Abstract: The spray can with pre-mixed fiberglass and resin is a prepackaged application system for fiberglass, which can be used for repair or for new applications. The spray can with pre-mixed fiberglass and resin is a chemical formulation that contains a combination of fiberglass and resin that can be applied in a single coat or a multiple coat in a manner similar to applying paint through a spray paint can. The spray can with pre-mixed fiberglass and resin comprises fiberglass, a solvent, a resin, and a propellant.Type: GrantFiled: December 8, 2015Date of Patent: June 19, 2018Inventor: Bevin Gordon
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Patent number: 9637564Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in an emulsion (for example using a water based carrier liquid), despite the possible reactions between the monomer and water. Polymerization of 1,1-disubstituted alkene compounds in an emulsion provides opportunities to better control the polymerization compared with bulk polymerization. The emulsion polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.Type: GrantFiled: December 11, 2015Date of Patent: May 2, 2017Assignee: SIRRUS, INC.Inventors: Peter Rulon Stevenson, Alexander R. Holzer, Aniruddha Sudhir Palsule, Jeffrey M. Sullivan
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Patent number: 9249265Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in an emulsion (for example using a water based carrier liquid), despite the possible reactions between the monomer and water. Polymerization of 1,1-disubstituted alkene compounds in an emulsion provides opportunities to better control the polymerization compared with bulk polymerization. The emulsion polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.Type: GrantFiled: July 1, 2015Date of Patent: February 2, 2016Assignee: SIRRUS, INC.Inventors: Peter Rulon Stevenson, Alexander R. Holzer, Aniruddha Sudhir Palsule
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Publication number: 20150141563Abstract: The present disclosure provides a hydrophobic and oleophobic coating composition, which comprises the following components based on weight percentage: 0.1-15% of a fluorosiloxane, 1-30% of a polyacrylic resin, 0.1-15% of a silane coupler, 33-98% of an organic solvent, and 0.05-15% of an acid. By combining the polyacrylic resin and the fluorosiloxane which exhibits hydrophobic property, the present composition not only provides good hydrophobic property but also ensures durable hydrophobic property of the coating with the help of good adhesion of polyacrylic resin. The coating composition can form hard coating which has high glossiness and high transparency under relatively low temperatures and has a contact angle of 115-120°.Type: ApplicationFiled: June 27, 2013Publication date: May 21, 2015Inventors: Xinyu Liang, Lifei Hao, Yu Yang, Minhao Song, KeFeng Xia
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Publication number: 20150126661Abstract: A composition including a stimulus-responsive polymer, a base polymer and a catalyst, wherein the surface free energy of the stimulus-responsive polymer is reversibly adjustable from a first surface free energy state to a second surface free energy state when heated to an activation temperature, and wherein the base polymer does not include a platinum catalyst is described. A method of preparing the composition and a method of adjusting a surface free energy of the composition is also described.Type: ApplicationFiled: November 7, 2013Publication date: May 7, 2015Applicant: XEROX CORPORATIONInventors: Gabriel IFTIME, Gordon SISLER, Carolyn MOORLAG, Matthew HEUFT, Gail SONG, Brynn DOOLEY
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Publication number: 20150083321Abstract: A curable adhesive that is modified to allow spray application and polymerization seamlessly during the process of epoxy resin vacuum infusion.Type: ApplicationFiled: September 23, 2014Publication date: March 26, 2015Inventor: Robert R. Yuodelis
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Patent number: 8975330Abstract: A coating composition comprising: at least one polyacrylimide polymer (A)] comprising recurring units of formula (I), and further comprising recurring units complying with one or more of the following structures: J, JJ, JJJ, wherein R1, R2, R4, R5, R6, R7, equal to or different from each other are independently H or C1-20 alkyl group, R3 and R8, equal to or different from each other, are independently H, alkyl, cycloalkyl, alkaryl, aryl, heterocyclic C1-36 group, wherein said polymer (A) possesses an imidization degree of less than 80%; a liquid medium; and at least one vinylidene fluoride polymer (F) at least partially dissolved and/or at least partially dispersed in said liquid medium, wherein the amount of polymer (F) ranges from 50 to 90% wt. with respect to the total weight of polymer (A) and polymer (F).Type: GrantFiled: October 14, 2010Date of Patent: March 10, 2015Assignee: Solvay Specialty Polymers Italy S.p.A.Inventor: Shiow-Ching Lin
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Publication number: 20140353552Abstract: The present invention relates to newly functionalized polythiophenes and the syntheses thereof. The present invention also demonstrates that the new polythiophenes and their derivatives are suitable for fabricating organic light emitting diodes (OLEDs), light emitting diodes (PLEDs), organic photovoltaic devices (OPVs) and conducting polymers for printed electronic devices.Type: ApplicationFiled: May 28, 2014Publication date: December 4, 2014Applicant: NANO AND ADVANCED MATERIALS INSTITUTE LIMITEDInventors: Paul Kwok Keung HO, Wing Leung WONG
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Publication number: 20140350151Abstract: A high dielectric contrast composition for particle formation that includes a high dielectric solvent, and a polymer dissolved into the high dielectric solvent. A method of forming particles including dissolving a polymer in a high dielectric solvent to form a high dielectric composition, and dielectrophoretically spinning the high dielectric composition in an electric field to form particles.Type: ApplicationFiled: February 11, 2014Publication date: November 27, 2014Applicant: GABAE Technologies, LLCInventors: Evan Koslow, Jocelyn Tindale, Ryan Gerakopulos, Tatiana Lazareva, Angela Kim, Chitral Angammana
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Publication number: 20140343206Abstract: To provide a fluorinated copolymer and a water/oil repellent composition, whereby adequate water/oil repellency and excellent dynamic water repellency are obtainable and environmental impact is low. A fluorinated copolymer comprising units (A1) derived from a macromonomer wherein the average polymerization degree of e.g. 2-perfluorohexylethyl acrylate is from 20 to 30, and units (B) derived from a monomer (b) which has no fluoroalkyl group and no cross-linkable functional group and of which the glass transition temperature, when formed into a homopolymer, is from 50 to 150° C., wherein the average polymerization degree of the macromonomer per one molecule of the fluorinated copolymer is at least 1, and a water/oil repellent composition containing such a fluorinated copolymer.Type: ApplicationFiled: July 31, 2014Publication date: November 20, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Miyako SASAKI, Taiki Hoshino, Nobuyuki Otozawa
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Publication number: 20140343207Abstract: To provide a fluorinated copolymer and a water/oil repellent composition having adequate water/oil repellency, excellent washing durability and low environmental impact. A fluorinated copolymer comprising units (A) derived from a macromonomer (a) which has, on average, at least two units (X) derived from 2-perfluorohexylethyl (meta)acrylate or the like, units (B) derived from a monomer (b) which has no fluoroalkyl group and no cross-linkable functional group and of which the glass transition temperature, when formed into a homopolymer, is from 50 to 150° C., and units (C) derived from a monomer (c) which has a cross-linkable functional group and no fluoroalkyl group, and a water/oil repellent composition containing such a fluorinated copolymer.Type: ApplicationFiled: July 31, 2014Publication date: November 20, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Miyako SASAKI, Taiki HOSHINO, Nobuyuki OTOZAWA
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Patent number: 8871850Abstract: There is provided a highly dielectric film which has high dielectric property, can be formed into a think film and is excellent in winding property (flexibility). The highly dielectric film comprises (A) a vinylidene fluoride polymer, (B) barium titanate oxide particles and/or lead zirconium titanate oxide particles, and (C) an affinity improving agent, wherein the barium titanate oxide particles and/or lead zirconium titanate oxide particles (B) and the affinity improving agent (C) are contained in amounts of 10 to 500 parts by mass and 0.01 to 30 parts by mass, respectively based on 100 parts by mass of the vinylidene fluoride polymer (A).Type: GrantFiled: June 27, 2011Date of Patent: October 28, 2014Assignee: Daikin Industries, Ltd.Inventors: Meiten Koh, Kouji Yokotani, Miharu Matsumura
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Publication number: 20140299969Abstract: Compositions for directed self-assembly (DSA) patterning techniques are provided. Methods for directed self-assembly are also provided in which a DSA composition comprising a block copolymer is applied to a substrate and then self-assembled to form the desired pattern. The block copolymer includes at least two blocks of differing etch rates, so that one block (e.g., polymethylmethacrylate) is selectively removed during etching. Because the slower etching block (e.g., polystyrene) is modified with an additive to further slow the etch rate of that block, more of the slow etching block remains behind to fully transfer the pattern to underlying layers.Type: ApplicationFiled: April 1, 2014Publication date: October 9, 2014Applicant: Brewer Science Inc.Inventors: Kui Xu, Mary Ann Hockey, Douglas Guerrero
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Publication number: 20140290856Abstract: Pressure sensitive adhesive (“PSA”) compositions comprising a polymer having at least one vinyl group and a Type I photoinitiator bound to the polymer. The polymer is derivatized with a derivatizing agent comprising a vinyl group. The PSA can be cured by exposure to ultraviolet radiation.Type: ApplicationFiled: March 26, 2014Publication date: October 2, 2014Inventors: Terry Emerson Hammond, Zhaohui Sun
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Publication number: 20140296409Abstract: The present disclosure describes compositions comprising an acrylic polymer binder and nano-particles less than about 100 nm that provide a hydrophobic or superhydrophobic coating that may also display oleophobicity. The coating composition may advantageously be prepared using VOC exempt compounds that are compatible with a variety of surface materials including many electronic components. In addition, the coating composition may also be rapidly dried rendering it useful for the rapid preparation of coated objects and surfaces in manufacturing/assembly line environments.Type: ApplicationFiled: June 16, 2014Publication date: October 2, 2014Inventors: Vinod K. Sikka, Michael Hurley, Zenas W. Lim
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Publication number: 20140287061Abstract: A biocompatible polymeric composition for cross-linking in-situ in a wound is disclosed comprising 1) one or more polyanionic polymers such as alginates or hyaluronates, able to be cross-linked the surface of the wound and 2) one or more polycationic polymers such as chitosan or DEAE-Dextran, that assists in the solidification process as well as speeds up hemostasis without the need for applying pressure. The biocompatible polymeric composition may further comprise a cross-linking agent such as aqueous calcium chloride. The invention encompasses an initial polymeric composition, the solidified matrix cross-linked and integrated at the wound site, including the methods of using, applying, and cross-linking the composition.Type: ApplicationFiled: November 12, 2012Publication date: September 25, 2014Applicant: Suneris, Inc.Inventor: Joseph A. Landolina
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Patent number: 8835532Abstract: An ink is provided that does not easily cause an offset or blocking upon winding a print, even when the ink contains a lactic acid ester or a lactone solvent. In order to solve such a problem, the ink of the present invention includes: a colorant; and a ketone compound of the following general formula (1), R1—CO—R2??(1), wherein R1 and R2 each independently represent an alkyl group of 1 to 10 carbon atoms, where the total number of carbon atoms in R1 and R2 is 5 to 11, and R1 and R2 may form a ring when the sum of the carbon atoms in R1 and R2 is 6 or more.Type: GrantFiled: December 2, 2010Date of Patent: September 16, 2014Assignee: Mimaki Engineering Co., Ltd.Inventors: Tomoko Mitsuishi, Takashi Namiki, Ryuji Yamada, Isao Tabayashi
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Publication number: 20140249256Abstract: A texture material composition contains, by weight of the texture material, between 11.0% and 72.0% of solvent, between 3.0% and 8.0% of binder, between 0.5% and 3.0% of pigment, between 0.01% and 0.20% of an anti-settling agent, between 0.20% and 3.0% of a dispersant, and between 50.0% and 80.0% of filler.Type: ApplicationFiled: March 12, 2013Publication date: September 4, 2014Inventor: John Kordosh
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Publication number: 20140227530Abstract: The present invention is directed to anti-corrosion coatings. It is particularly directed to coatings comprising a monomer, such as pyrrole, aniline, thiophene, or their analogs, and a resin. These coatings can be used with substrates such as cold-rolled steel and other metals to inhibit surface oxidation.Type: ApplicationFiled: May 23, 2012Publication date: August 14, 2014Inventors: Simona Percec, Kayleigh J. Ferguson
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Publication number: 20140227593Abstract: The present disclosure relates to an invention directed to controlling a viscosity of a slurry used to manufacture an electrochemical device, by adjusting a particle diameter of an inorganic matter that is an ingredient of the slurry, so that a sinking rate of the inorganic particles may remarkably slow down and dispersibility may be dramatically improved, and as a result, the content of the inorganic particles may relatively increase and the inorganic particles may be uniformly distributed in a coating layer on a substrate, thereby preventing a reduction in battery performance.Type: ApplicationFiled: April 22, 2014Publication date: August 14, 2014Applicant: LG CHEM, LTD.Inventors: Joo-Sung Lee, Su-Jin Yoon, Da-Kyung Han, Bo-Kyung Ryu, Jong-Hun Kim
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Patent number: 8802238Abstract: An optical compensation film composition is disclosed herein having a polymer film and a substrate, wherein the polymer film has a positive birefringence greater than 0.005 throughout the wavelength range of 400 nm<?<800 nm, the film having been cast from a polymer solution comprising a solvent and a polymer having a moiety of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is hydrogen or a substituent on the styrenic ring.Type: GrantFiled: September 24, 2010Date of Patent: August 12, 2014Assignee: Akron Polymer Systems, Inc.Inventors: Xiaoliang Zheng, Dong Zhang, Jiaokai Jing, Frank Harris, Brian King, Ted Germroth, Thauming Kuo
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Publication number: 20140079939Abstract: A producing method of a plasma polymerized film includes irradiating a composition containing at least one kind of radically polymerizable compound, and at least one of a polymerization initiator and a chain transfer agent with plasma. The plasma polymerized film is formed by polymerizing a composition containing at least one of a polymerization initiator and a chain transfer agent, and at least one kind of radically polymerizable compound by irradiation of plasma.Type: ApplicationFiled: November 26, 2013Publication date: March 20, 2014Applicant: Fujifilm CorporationInventors: Naoyuki HAYASHI, Yoshio INAGAKI, Ryo FUJIWARA
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Patent number: 8632856Abstract: Highly water repellent coated articles may be made by applying to a substrate a coating having dispersed therein or sprinkled thereon partially or fully fluorinated polymer microparticles. The coating includes a partially fluorinated hexafluoropropylene copolymer binder in a nonfluorinated solvent that dissolves the binder and does not dissolve the microparticles. The coating is heated sufficiently to bond the microparticles to the binder but not so much as to cause the receding water contact angle for the coating to fall below 80°.Type: GrantFiled: December 20, 2006Date of Patent: January 21, 2014Assignee: 3M Innovative Properties CompanyInventors: Naiyong Jing, Lisa P. Chen
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Publication number: 20140001453Abstract: An organic insulating layer composition includes a polymer mixture including 50 parts to 90 parts by volume of an organic polymer and 10 parts to 50 parts by volume of an amorphous polymer, wherein the organic polymer includes at least a first repeating unit and a second repeating unit, the first and second repeating units each being substituted with at least one of fluorine or chlorine, a total number of fluorine and chlorine atoms in the first repeating unit being different from a total number of fluorine and chlorine atoms in the second repeating unit, and an organic solvent.Type: ApplicationFiled: June 25, 2013Publication date: January 2, 2014Inventors: Joon-Hyuk CHO, Yong-Young NOH, Kang-Jun BAEG
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Publication number: 20130302522Abstract: A method for coating a component and forming at least one cooling hole in a component is provided. The method includes providing the component having a surface and including a plurality of apertures formed therein. The method includes masking at least one of the plurality of apertures with a plug comprising a removable material. The method includes applying at least one coating to the surface of the component. The method includes eliminating the plug including removable material leaving open apertures in the surface of the coated component. Also provided is a water-soluble aperture plug including water soluble high temperature resistant filler materials including aluminum oxide, zirconium oxide, magnesium oxide, silicon dioxide, zircon, graphite, tungsten carbide, silicon carbide, silicon nitride, boron nitride, aluminum nitrides and binding agents and dispersants including phosphates, silicates, sugar, salt, gum, resin, polyvinyl alcohol (PVA), polyethylene glycol, and combinations thereof.Type: ApplicationFiled: May 11, 2012Publication date: November 14, 2013Applicant: GENERAL ELECTRIC COMPANYInventors: Cem Murat EMINOGLU, Canan Uslu HARDWICKE, Lawrence Matthew LEVY
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Publication number: 20130229471Abstract: A process for preparing a dispersion of encapsulated solid particles in a predominantly organic liquid vehicle, comprising the following steps: i) providing a dispersion comprising a particulate solid, a liquid medium and a polymeric dispersant having at least 3.0 mmoles of reactive groups per g of dispersant; ii) cross-linking the polymeric dispersant via at least some, but not all, of the reactive groups, said cross-linking being performed in the presence of the particulate solid and the liquid medium and resulting in the encapsulation of each solid particle with a cross-linked polymeric dispersant shell; iii) covalently bonding an end-capping agent to the polymeric dispersant via the reactive groups; said process being such that the final organic liquid vehicle comprises one or more organic liquids and optionally water, provided that water is present at no more than 30% by weight based on the dispersion.Type: ApplicationFiled: November 8, 2011Publication date: September 5, 2013Applicant: FUJIFILM IMAGING COLORANTS LIMITEDInventors: Owen Roger Lozman, Thomas Paul, Christopher John Potter
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Publication number: 20130225739Abstract: The present disclosure provides an ink-jet ink made with a pigment dispersion containing a dispersant, and a pigment coated by a polymer that is cross-linked with a crosslinker. The polymer swells in an application medium resulting in improved stability for the pigment dispersion.Type: ApplicationFiled: December 15, 2011Publication date: August 29, 2013Inventor: Harry Joseph Spinelli
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Publication number: 20130225020Abstract: The invention relates to unique applications for the novel high melt flow, low viscosity, selectively hydrogenated styrene-butadiene-styrene (hSBS) or selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene (hSBSS) block copolymers, wherein the melt flow rate of said block copolymer is at least 100 g/10 min at 230° C. under 2.16 kg mass according to ASTM D1238. These block copolymers are novel and have the highest melt flow rate of any styrenic block copolymer also possessing high strength and elasticity. It has applications that prior to the present invention were not normally possible due to the normal low melt flow rate of styrenic block copolymers. The present invention also encompasses various fields of use such as a fiberglass hSBS or hSBSS reinforced mat, low viscosity hSBS or hSBSS coatings for industrial uses, hot melt adhesives prepared from hSBS or hSBSS blended with polyalpha-olefins, and elastic film, fiber, and nonwoven constructions using hSBS or hSBSS.Type: ApplicationFiled: February 24, 2012Publication date: August 29, 2013Applicant: KRATON POLYMERS US LLCInventors: John Flood, Kathryn Wright, Lydia Salazar, Robert Q. Kluttz, Donn Dubois, Troy Wiegand, Norio Masuko
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Publication number: 20130189503Abstract: A method for printing images on a substrate with an ink jet printer includes providing a liquid ink composition. The liquid ink composition includes an organic solvent, a binder, and a colorant. Droplets of the ink jet ink composition are directed to a plastic film substrate. The droplets are allowed to dry, thereby printing a durable graphic image on the substrate.Type: ApplicationFiled: November 9, 2011Publication date: July 25, 2013Applicant: VIDEOJET TECHNOLOGIES INC.Inventors: Michael Kozee, Michael Sullivan, Ondrej Kruk, Linfang Zhu
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Patent number: 8415419Abstract: To provide a hydrophilic coating composition excellent in hydrophilicity, wear resistance, transparency, storage stability, antifogging properties, antifouling properties, visible light transmittivity, adhesion properties, chemical resistance, weather resistance, and water resistance and a hydrophilic member using the composition. The hydrophilic coating composition has (A) a ternary copolymer having a1) a repeating unit having a hydrophilic group, a2) a repeating unit having a hydroxyl group, an epoxy group, an isocyanato group, a blocked isocyanato group, a carboxylic acid anhydride group, or an amino group, and a3) a repeating unit having a hydrolyzable silyl group; and (B) a metal complex catalyst, wherein a content of the repeating unit a1) having a hydrophilic group is 50 mol % or greater.Type: GrantFiled: May 15, 2008Date of Patent: April 9, 2013Assignee: FUJIFILM CorporationInventors: Sumiaki Yamasaki, Satoshi Tanaka, Yuichiro Murayama, Yoshiaki Kondo
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Patent number: 8394877Abstract: A pattern forming material contains a block copolymer or graft copolymer and forms a structure having micro polymer phases, in which, with respect to at least two polymer chains among polymer chains constituting the block copolymer or graft copolymer, the ratio between N/(Nc?No) values of monomer units constituting respective polymer chains is 1.4 or more, where N represents total number of atoms in the monomer unit, Nc represents the number of carbon atoms in the monomer unit, No represents the number of oxygen atoms in the monomer unit.Type: GrantFiled: October 21, 2011Date of Patent: March 12, 2013Assignee: Kabushika Kaisha ToshibaInventors: Koji Asakawa, Toshiro Hiraoka, Yoshihiro Akasaka, Yasuyuki Hotta
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Publication number: 20130053493Abstract: This invention relates to a method for producing a fluorinated copolymer composition, capable of uniformly mixing a fluorinated copolymer (A) having repeating units derived from ethylene and repeating units derived from tetrafluoroethylene, and a thermoplastic resin (B), at a relatively low temperature. The invention also relates to a method for producing a fluorinated copolymer composition comprising a fluorinated copolymer (A), a thermoplastic resin (B) which excludes the fluorinated copolymer (A), and a medium (C) capable of dissolving at least the fluorinated copolymer (A). The invention also relates to a coating composition capable of forming a coating film provided with characteristics of the fluorinated copolymer (A) and the thermoplastic resin (B), an article having such a coating film, and a molded product.Type: ApplicationFiled: September 13, 2012Publication date: February 28, 2013Applicant: Asahi Glass Company, LimitedInventors: Takashi Nakano, Kuniko Okano
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Publication number: 20130035425Abstract: Fluid activatable adhesive compositions and activating fluid(s) for activating the adhesive composition are described herein. The adhesive compositions contain at least two polymers with different hydrophilicities. The hydrophilic polymer has quick tack when exposed to a hydrophilic solvent, such as water or other aqueous solvent, while the hydrophobic polymer provides strong adhesion to a paper or polymeric substrate. The adhesive composition may contain particulate fillers which enable fast exhaustion of the activation fluid out of the adhesive when applied to a substrate, thereby allowing the hydrophobic polymers of the adhesive composition to achieve strong adhesion of the liner-free label to the paper or polymeric substrate. The particulate fillers may also function as anti-blocking agents when liner-free label media are tightly wound in a roll.Type: ApplicationFiled: February 6, 2012Publication date: February 7, 2013Inventors: Benjamin David Lux, Daniel Youngwhan Cho, Felix Perets Shvartsman
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Publication number: 20120283371Abstract: A method for casting a styrenic fluoropolymer film on a substrate includes preparing a polymer solution by dissolving the fluoropolymer in a solvent or solvent blend whose Hansen solubility parameters (HSPs. MPa1/2) satisfy the following relations: |SPb?SPp|<5, |SPb?SPs|<4, |SPb(H)?SPp(H)|<7, and 2<|SPb(H)?SPs(H)|<10 wherein SPb, SPp, SPs, are the total Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; SPb(H), SPp(H), and, SPs(H) are the hydrogen-bond Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; wherein the fluoropolymer comprises a moiety of: wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring.Type: ApplicationFiled: May 1, 2012Publication date: November 8, 2012Applicant: AKRON POLYMER SYSTEMS, INC.Inventors: BIN WANG, THAUMING KUO, DOUGLAS STEPHENS McWILLIAMS, FRANK W. HARRIS, TED CALVIN GERMROTH, JIAOKAI JING, DONG ZHANG, XIAOLIANG ZHENG
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Publication number: 20120270984Abstract: An ink is provided that does not easily cause an offset or blocking upon winding a print, even when the ink contains a lactic acid ester or a lactone solvent. In order to solve such a problem, the ink of the present invention includes: a color; and a ketone compound of the following general formula (1), R1—CO—R2??(1), wherein R1 and R2 each independently represent an alkyl group of 1 to 10 carbon atoms, where the total number of carbon atoms in R1 and R2 is 5 to 11, and R1 and R2 may form a ring when the sum of the carbon atoms in R1 and R2 is 6 or more.Type: ApplicationFiled: December 2, 2010Publication date: October 25, 2012Applicant: MIMAKI ENGINEERING CO., LTD.Inventors: Tomoko Mitsuishi, Takashi Namiki, Ryuji Yamada, Isao Tabayashi
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Publication number: 20120202920Abstract: Disclosed are solvent borne thermosetting coating compositions that contain a curable polyester resin blended with an acrylic copolymer, a crosslinker, and a solvent. The polyester resin contains 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibits good dry time, compatibility with acrylic resins, sag resistance and hardness development in a coating composition. The coating compositions can be used to prepare clear coat or pigmented coatings for automotive OEM, auto refinish, and other applications.Type: ApplicationFiled: March 30, 2012Publication date: August 9, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Stacey James Marsh, Angela Hartley Honeycutt, Deepanjan Bhattacharya
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Publication number: 20120202935Abstract: A coating composition comprising: at least one polyacrylimide polymer (A)] comprising recurring units of formula (I), and further comprising recurring units complying with one or more of the following structures: J, JJ, JJJ, wherein R1, R2, R4, R5, R6, R7, equal to or different from each other are independently H or C1-20 alkyl group, R3 and R8, equal to or different from each other, are independently H, alkyl, cycloalkyl, alkaryl, aryl, heterocyclic C1-36 group, wherein said polymer (A) possesses an imidization degree of less than 80%; a liquid medium; and at least one vinylidene fluoride polymer (F) at least partially dissolved and/or at least partially dispersed in said liquid medium, wherein the amount of polymer (F) ranges from 50 to 90% wt. with respect to the total weight of polymer (A) and polymer (F).Type: ApplicationFiled: October 14, 2010Publication date: August 9, 2012Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventor: Shiow-Ching Lin
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Publication number: 20120178629Abstract: Disclosed herein are apparatus and methods for producing emulsions, and, in particular, for maintaining laminar flow during production of emulsions containing microsuspensions.Type: ApplicationFiled: December 22, 2011Publication date: July 12, 2012Inventors: Bruce W. Hudson, Gary W. Opperman, Adrian T. Raiche
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Publication number: 20120108723Abstract: To provide a composition comprising a fluorocopolymer such as an ETFE which can be produced at a relatively low temperature, and its production process. A fluorocopolymer composition which comprises a fluorocopolymer such as an ETFE and a C6-10 aliphatic compound having one carbonyl group, and which is in a solution state being at a temperature of at most the melting point of the fluorocopolymer, and a process for producing the fluorocopolymer composition, which comprises a step of dissolving the fluorocopolymer in the aliphatic compound having one carbonyl group at a temperature of at most the melting point of the fluorocopolymer.Type: ApplicationFiled: January 3, 2012Publication date: May 3, 2012Applicant: Asahi Glass Company, LimitedInventors: Takashi NAKANO, Tomoyuki Fujita, Hiroshi Yamamoto, Yoshitomi Morizawa
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Publication number: 20120077916Abstract: An emulsion polymerization copolymer comprising 59-77 phr butadiene, 10-16 phr styrene; 10-16 phr acrylonitrile; and from 3-9 phr methacrylic acid is soluble in acetone for U.S. EPA-exempt, low-VOC emissions, while also soluble in toluene. The composition is formulated with a tackifying resin; a plasticizer oil; and a U.S. EPA-exempt solvent, preferably acetone, to make an adhesive. The formulation is particularly useful as a pressure sensitive adhesive for tape and for making shoes.Type: ApplicationFiled: September 28, 2011Publication date: March 29, 2012Applicant: INDUSTRIAS NEGROMEX, S.A. DE C.VInventors: José Maria Islas Manzur, Christopher J. Hardiman, Enrique Alejandro Rodríguez Resendiz
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Publication number: 20120064351Abstract: A primer composition is provided that includes a reactant having an alkoxysilyl group, the reactant being obtained by reacting a polyisocyanate (I), an isocyanate group, and an alkoxysilane having a reactable functional group; a polyisocyanate (II); a polyurethane compound; a (meth) acrylic resin; and a solvent. In the primer composition, a molecular weight of the (meth) acrylic resin is from 15,000 to 150,000 and a weight ratio [(meth) acrylic resin/polyurethane compound] of the (meth) acrylic resin to the polyurethane compound is from 90/10 to 10/90. Additionally, a laminate is provided that includes an inorganic material and a primer layer obtained from the primer composition.Type: ApplicationFiled: August 30, 2011Publication date: March 15, 2012Applicant: THE YOKOHAMA RUBBER CO., LTD.Inventor: Akihiro Miyata
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Publication number: 20120041121Abstract: A pattern forming material contains a block copolymer or graft copolymer and forms a structure having micro polymer phases, in which, with respect to at least two polymer chains among polymer chains constituting the block copolymer or graft copolymer, the ratio between N/(Nc?No) values of monomer units constituting respective polymer chains is 1.4 or more, where N represents total number of atoms in the monomer unit, Nc represents the number of carbon atoms in the monomer unit, No represents the number of oxygen atoms in the monomer unit.Type: ApplicationFiled: October 21, 2011Publication date: February 16, 2012Inventors: Koji ASAKAWA, Toshiro Hiraoka, Yoshihiro Akasaka, Yasuyuki Hotta
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Publication number: 20120027964Abstract: An inkjet-receptive article comprising a substrate having a coating thereon comprising a vinyl lactam polymer or copolymer and a polymer resin diluent coated from a solvent. A preferred vinyl lactam copolymer is polyvinylcaprolactam (PVCap)—vinyl acetate (VA). Also disclosed are solvent-based compositions for forming an inkjet-receptive coating on a substrate comprising: (i) a vinyl lactam polymer or copolymer; (ii) a solvent; (iii) optionally, a pigment; and (iv) polymer resin diluent.Type: ApplicationFiled: August 26, 2011Publication date: February 2, 2012Inventors: David K. Hood, Surya Kamin, Karyn Visscher
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Publication number: 20120013677Abstract: An inkjet ink includes an organic solvent, a resin, a surfactant, and a colorant. The ink has a decap time of at least about 1 minute.Type: ApplicationFiled: September 23, 2011Publication date: January 19, 2012Applicant: Videojet Technologies Inc.Inventors: Casey Robertson, Anthony Selmeczy, John P. Folkers
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Publication number: 20120003892Abstract: The present invention relates to a phosphoric acid resistant advanced polymaleimide prepolymer composition including a polymaleimide prepolymer resulting from the advancement reaction of a polyimide and an alkenylphenol, alkenylphenol ether or mixture thereof in the presence of an amine catalyst; a solvent and a heteropolyacid. The phosphoric acid resistant advanced polymaleimide prepolymer composition may be used in various applications such as prepregs, laminates, printed circuit boards, castings, composites, moulded articles, adhesives and coatings.Type: ApplicationFiled: March 16, 2010Publication date: January 5, 2012Applicant: Huntsman Advanced Materials Americans LLCInventors: Roger Tietze, Yen-Loan Nguyen