Atom Other Than C, H, O, Or Halogen Patents (Class 524/368)
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Patent number: 9018312Abstract: A thermoplastic resin composition with improved impact resistance can include (A) about 30 to about 99 parts by weight of an epoxy group-containing styrenic polymer comprising (A1) about 5 to about 100% by weight of an epoxy group-containing vinyl copolymer containing about 0.001 to about 5.0 mol % of an epoxy compound; and (A2) about 0 to about 95% by weight of a rubber modified styrenic copolymer resin; (B) about 1 to about 70 parts by weight of a polyester resin; (C) about 0.001 to about 10 parts by weight of a silicone oil, per 100 parts by weight of a base resin comprising (A) and (B); (D) about 3 to about 20 parts by weight of a bromine-containing flame retardant, per 100 parts by weight of a base resin comprising (A) and (B); and (E) about 0.1 to about 6 parts by weight of a flame retardant aid, per 100 parts by weight of a base resin comprising (A) and (B).Type: GrantFiled: December 27, 2007Date of Patent: April 28, 2015Assignee: Cheil Industries Inc.Inventors: Se Bum Son, Sung Hee Ahn, In Hwan Oh, Sung Duk Hwang
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Patent number: 8889774Abstract: Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.Type: GrantFiled: September 23, 2009Date of Patent: November 18, 2014Assignee: Rhodia OperationsInventors: Zhengang Zong, Yi-Zhong Li, Jose Ruiz
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Publication number: 20140206201Abstract: Compositions suitable for forming oxymetal hardmask layers are provided. Methods of forming oxymetal hardmask layers using such compositions are also provided, where the surface of the oxymetal hardmask layer formed has a water contact angle substantially matched to that of subsequently applied organic coatings.Type: ApplicationFiled: January 19, 2013Publication date: July 24, 2014Applicant: ROHM AND HAAS ELECTRONIC MATERIALS LLCInventors: Deyan WANG, Peter TREFONAS, III, Shintaro YAMADA, Kathleen M. O'Connell
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Patent number: 8772405Abstract: A polymer polyol (I) is provided that is formed of a polyol (A), polymer particles (B) obtained by polymerization of an ethylenically unsaturated compound (b), and an active-hydrogen-containing compound (d) having an aromatic ring and having a number-average molecular weight of 150 to 2,000, wherein a content of (d) is 1 to 20% on the basis of a weight of (B). The polymer polyol of the present invention contains polymer particles having sufficiently small particle diameters, has a low viscosity, and has excellent handleability. A polyurethane resin obtained by using the polymer polyol of the present invention has excellent mechanical strengths such as elongation at break.Type: GrantFiled: September 25, 2008Date of Patent: July 8, 2014Assignee: Sanyo Chemical Industries, Ltd.Inventors: Takayuki Tsuji, Shigekuni Nakada, Yukiya Kobayashi, Katsuya Uchida
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Patent number: 8604101Abstract: The present invention relates to a process for producing aqueous dispersions of thermoplastic polymers which have a plurality of ester groups and/or carbonate groups in the main polymer chain and which have an acid number of less than 5 mg KOH/g, in particular at most 3 mg KOH/g, and which have a zero-shear viscosity ?0 (180° C.) of at least 60 Pa·s at 180° C. The invention also relates to the polymer dispersions obtainable by said process, and to the use thereof.Type: GrantFiled: March 24, 2011Date of Patent: December 10, 2013Assignee: BASF SEInventors: Liqun Ren, Gimmy Alex Fernandez Ramirez, Motonori Yamamoto, Hermann Seyffer, Gabriel Skupin
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Patent number: 8399550Abstract: A process for forming a tire component, the process comprising the steps of introducing a vulcanizable polymer, a curative, a first carbon black characterized by an iodine adsorption number, per ASTM D1510, that is greater than 60 g/kg, and a second carbon black characterized by an iodine adsorption number, per ASTM D1510, that is less than 60 g/kg to form a vulcanizable composition, fabricating a tire component from the vulcanizable composition, and curing the tire component.Type: GrantFiled: October 28, 2011Date of Patent: March 19, 2013Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, Christopher G. Robertson, Alberto Scurati
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Patent number: 8354173Abstract: Provided are compositions comprising a) a fluoroplastic; b) an aromatic material having exactly one hydroxyl group, wherein the aromatic material is free of thiol groups, and wherein the hydroxyl group is bonded to an aromatic carbon; c) a salt former compound capable of forming a salt with the aromatic material; and d) optionally a phase transfer catalyst. Also provided are reaction products of the described compositions, multi-layer articles comprising the compositions and reaction products, and methods for making the compositions, reaction products, and articles.Type: GrantFiled: October 12, 2007Date of Patent: January 15, 2013Assignee: 3M Innovative Properties CompanyInventors: Naiyong Jing, Blake E. Chandler, Gregg D. Dahlke
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Patent number: 8304479Abstract: Disclosed are low Tg latex polymers and low VOC aqueous coating compositions having an improved open time profile, as well as drying time, stain resistance, wet edge time, low temperature film formation, block resistance, adhesion, water sensitivity and low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or alkoxylated compounds or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating or adhesive composition including at least one latex polymer, water and one or a blend of two or more open time additives or drying time additives. The blend can comprise nonionic and anionic open time additives. Typically, the open time and/or drying time additive is present in an amount greater than about 1.Type: GrantFiled: April 13, 2010Date of Patent: November 6, 2012Assignee: Rhodia OperationsInventors: Zhengang Zong, Yi-Zhong Li, Jose Ruiz, Herve Adam
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Patent number: 8258217Abstract: The instant invention relates to a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least one compound of the formula (I) wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH2—CH(CH3)—S(O)p—R12, —CH2—CH2—CH2—S(O)p—R12, —CH2—CH(R11)—CH2—R12 or —CH2—CH?CH—R12, R11 is hydrogen or halogen, R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms; or —CH2CH2(CF2)mCF3, m is 3 to 12, and p is 0, 1 or 2. The compounds of the formula I are useful as reducers of surface energy for organic materials, for example synthetic polymer.Type: GrantFiled: August 29, 2007Date of Patent: September 4, 2012Assignee: BASF SE LudwigshafenInventors: Michèle Gerster, Manuel Mihalic
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Publication number: 20120188312Abstract: To provide an inkjet recording ink, which contains water, a water-soluble organic solvent, a colorant, and a surfactant, wherein the colorant contains a surfactant-dispersible pigment (A) dispersed by the surfactant, and a resin-coated pigment (B), and wherein the surfactant is a surfactant selected from the group consisting of anionic surfactants represented by the following formula (1), and having HLB value of 12 or higher: R1—O—(CH2CH2O)m-A??(1) where R1 is a C2-C24 alkyl group, alkenyl group, alkylphenyl group, or alkylallyl group; A is —COOM1, —SO3M2, or —PO(OM3)OM4, where M1, M2 and M4 are each independently alkali metal, quaternary ammonium, quaternary phosphonium, or alkanolamine, and M3 is a hydrogen atom or R2(CH2CH2O)n with proviso that R2 is a C1-C4 alkyl group, alkenyl group, alkylphenyl group, or alkylallyl group, and n is an integer of 4 to 20; and m is and integer of 15 to 40.Type: ApplicationFiled: January 24, 2012Publication date: July 26, 2012Inventor: Tomohiro NAKAGAWA
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Patent number: 8197590Abstract: Disclosed is a composition containing a fluorine-containing urethane compound (A) and a fluorine-containing polymer (B) having a repeating unit derived from a fluorine-containing monomer represented by the following formula (I): CH2?C(—X)—C(?O)-A-Rf??(I) (wherein X represents a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a CFX1X2 group (wherein X1 and X2 respectively represent a hydrogen atom, a fluorine atom or a chlorine atom), a cyano group, a straight or branched chain fluoroalkyl group having 1-20 carbon atoms, a substituted or unsubstituted benzyl group, or a substituted or unsubstituted phenyl group; A represents a divalent group; and Rf represents a straight or branched chain perfluoroalkyl group having 1-6 carbon atoms).Type: GrantFiled: October 27, 2005Date of Patent: June 12, 2012Assignee: Daikin Industries, Ltd.Inventors: Ikuo Yamamoto, Shinichi Minami
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Patent number: 8193264Abstract: A thermoplastic resin composition and a molded article thereof, respectively excellent in flowability and mechanical properties, and, in a preferred mode, also excellent in low warping property, laser transmittance and laser weldability, is obtained by mixing (B) 0.1 to 4 parts by weight of a polyfunctional compound having three or more functional groups, in which at least one of the terminal structures having the functional groups is a structure containing alkylene oxide units, with (A) 100 parts by weight of a thermoplastic resin, and further provides a molded particle thereof. It is preferred that the (A) thermoplastic resin is one or more selected from a polyester resin and polycarbonate resin.Type: GrantFiled: June 27, 2007Date of Patent: June 5, 2012Assignee: Toray Industries, Inc.Inventors: Sadanori Kumazawa, Hiroyuki Ohme, Yuki Amano, Takamasa Owaki
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Publication number: 20110105664Abstract: A thermoplastic polymer composition comprises a thermoplastic polymer and a nucleating agent.Type: ApplicationFiled: October 13, 2010Publication date: May 5, 2011Inventors: Darin L. Dotson, Robbie Willem Johan M. Hanssen, Jiannong Xu
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Publication number: 20110082246Abstract: A pressure-sensitive adhesive containing a near infrared absorbing dye having excellent shielding function for near infrared rays and excellent in durability is provided. In a light resistance test, a layer of the pressure-sensitive adhesive having a thickness of 25±5 ?m has an absorption intensity at the maximum absorption wavelength of the near infrared absorbing dye after a light resistance test of 50% or more of the absorption intensity before the test in which light with an irradiance of 64.5 W/m2 at a wavelength of 300 to 400 nm is irradiated on the layer for 160 hours.Type: ApplicationFiled: September 30, 2010Publication date: April 7, 2011Applicant: API CORPORATIONInventors: Wataru SATO, Kumiko Okamoto, Yasuyo Saito, Masahiro Kawashima, Takeshi Kaneda
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Publication number: 20100234504Abstract: A thermochromic ink composition comprises at least one thermochromic optical-state change material, at least one thermally responsive pH modifier, and at least one base and at least one binder material. The quantity of the thermally responsive pH modifier is less than or equal to about 0.25 milli moles based on the amount of optical-state change material. The ink composition is capable of transforming from a first optical state to a second optical state upon exposure to a thermal stimulus. The thermochromic ink composition may comprise a nitro dye. A thermochromic coating composition formed using the thermochromic ink composition is also disclosed.Type: ApplicationFiled: March 13, 2009Publication date: September 16, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Thomas Joseph Fyvie, David Gilles Gascoyne, Andrea Jeannine Peters, Marc Brian Wisnudel
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Publication number: 20100160514Abstract: The present invention relates to a plastic comprising zinc sulphide and to its use.Type: ApplicationFiled: June 21, 2007Publication date: June 24, 2010Inventors: Stephane David, Petra Fritzen, Ludger Heiming, Thomas Rentschler
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Patent number: 7714051Abstract: The present invention is directed to a rubber compound, such as for use in tires, containing one or more polyoxyalkylene amines, such as to reduce the amount of silane coupling agent conventionally used therein. The presence of the polyoxyalkylene amine(s) allows for the silane coupling agent to be present in a low percent by weight of silica without substantially sacrificing the performance characteristics of the rubber compound. In one embodiment, the rubber compound includes 100 phr of a natural elastomer, a synthetic elastomer, or combinations thereof, no less than about 20 phr silica, a silane coupling agent present in an amount no more than 8% by weight of the silica, and about 2 phr to about 10 phr of at least one polyoxyalkylene amine defined by a primary amino group attached to the terminus of a polyether backbone.Type: GrantFiled: August 7, 2006Date of Patent: May 11, 2010Assignee: The Goodyear Tire & Rubber CompanyInventor: Bruce Raymond Hahn
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Publication number: 20100113665Abstract: To provide a method for producing a water/oil repellent composition which can impart water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability) and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain.Type: ApplicationFiled: January 6, 2010Publication date: May 6, 2010Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Takao HIRONO, Kazunori Sugiyama, Yuuichi Oomori, Minako Shimada
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Patent number: 7705074Abstract: A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, the polymerization agent comprising: fluoropolyether acid or salt thereof having a number average molecular weight of at least about 800 g/mol; and fluorosurfactant having the formula: [R1—On-L-A?] Y+ wherein: R1 is a linear or branched partially or fully fluorinated aliphatic group which may contain ether linkages; n is 0 or 1; L is a linear or branched alkylene group which may be nonfluorinated, partially fluorinated or fully fluorinated and which may contain ether linkages; A? is an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion, and phosphonate; and Y+ is hydrogen, ammonium or alkali metal cation; with the proviso that the chain length of R1—On-L- is not greater than 6 atoms.Type: GrantFiled: November 9, 2007Date of Patent: April 27, 2010Assignee: E. I. du Pont de Nemours and CompanyInventors: Paul Douglas Brothers, Subhash Vishnu Gangal
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Patent number: 7666940Abstract: Aqueous dispersions comprising a mixture of: A) from 0.05% by weight to 10% by weight of salts of perfluoropolyether di-carboxylic derivatives having formula: T-O—Rf-T??(IA) wherein T=—CF2—COOZ or —CF2CF2—COOZ wherein Z=Na, K, NH4, R1(R2)(R3)N wherein R1=R2=alkyl or hydroxyalkyl, R3=H, alkyl or hydroxyalkyl, Rf is a (per)fluoropolyoxyalkylene chain having number average molecular weight between 500 and 10,000. B) from 0.01% to 5% by weight of water-dispersible or water-soluble cationic polymers, having a charge density, defined as number of equivalents per weight unit of dry polymer, higher than 1 meq/g of dry polymer.Type: GrantFiled: February 10, 2006Date of Patent: February 23, 2010Assignee: Solvay Solexis S.p.A.Inventors: Paolo Iengo, Mahesh Padigala, Piero Gavezotti
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Patent number: 7612136Abstract: An anionic surfactant concentrate and method for making includes providing compound (I) R1—OH where R1 represents a branched C6-22 radical with average branching of about 2-8 per radical; providing compound (II): where R2 represents a C8-16 radical; mixing (I) and (II); ethoxylating to obtain a reaction product; reacting with a sulfating, phosphating, or sulfitation agent to obtain R1—O—[CH2—CH2O]n-A and where R1 represents a branched C6-22 radical with average branching of about 2-8, R2 represents a C8-16 radical, A represents —SO3M, —PO3M, —PO3M2, —OCCH2CH(SO3Na)COO—, or HOOCCH2CH(SO3Na)COO—, M represents a positive counterion, n represents a value from 0-100, and x and y each represents a value from 0-100, where the sum of x and y represents a value of at least 1 to 100 are provided. Anionic surfactant compositions containing the concentrate and methods for stabilizing are also provided.Type: GrantFiled: October 31, 2007Date of Patent: November 3, 2009Assignee: Cognis IP Management GmbHInventors: Ana Maria Fernandez, Michael Allen, Richard Crews
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Publication number: 20080160240Abstract: A thermoplastic resin composition with improved impact resistance can include (A) about 30 to about 99 parts by weight of an epoxy group-containing styrenic polymer comprising (A1) about 5 to about 100% by weight of an epoxy group-containing vinyl copolymer containing about 0.001 to about 5.0 mol % of an epoxy compound; and (A2) about 0 to about 95% by weight of a rubber modified styrenic copolymer resin; (B) about 1 to about 70 parts by weight of a polyester resin; (C) about 0.001 to about 10 parts by weight of a silicone oil, per 100 parts by weight of a base resin comprising (A) and (B); (D) about 3 to about 20 parts by weight of a bromine-containing flame retardant, per 100 parts by weight of a base resin comprising (A) and (B); and (E) about 0.1 to about 6 parts by weight of a flame retardant aid, per 100 parts by weight of a base resin comprising (A) and (B).Type: ApplicationFiled: December 27, 2007Publication date: July 3, 2008Applicant: CHEIL INDUSTRIES INC.Inventors: Se Bum SON, Sung Hee AHN, In Hwan OH, Sung Duk HWANG
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Patent number: 7375156Abstract: The present invention provides a rubber composition for a tire tread comprising 100 parts by weight of a rubber component containing at least 5% by weight of natural rubber graft-copolymerized with an organic compound having an unsaturated bond andlor epoxidized natural rubber, and 5 to 150 parts by weight of carbon black and!or silica with a nitrogen-absorbing specific surface are of 100 to 300m2/g.Type: GrantFiled: December 4, 2003Date of Patent: May 20, 2008Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Noriko Yagi, Kiyoshige Muraoka
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Publication number: 20080033082Abstract: The present invention is directed to a rubber compound, such as for use in tires, containing one or more polyoxyalkylene amines, such as to reduce the amount of silane coupling agent conventionally used therein. The presence of the polyoxyalkylene amine(s) allows for the silane coupling agent to be present in a low percent by weight of silica without substantially sacrificing the performance characteristics of the rubber compound. In one embodiment, the rubber compound includes 100 phr of a natural elastomer, a synthetic elastomer, or combinations thereof, no less than about 20 phr silica, a silane coupling agent present in an amount no more than 8% by weight of the silica, and about 2 phr to about 10 phr of at least one polyoxyalkylene amine defined by a primary amino group attached to the terminus of a polyether backbone.Type: ApplicationFiled: August 7, 2006Publication date: February 7, 2008Inventor: Bruce Raymond Hahn
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Patent number: 7312266Abstract: Organic thiol compounds based on pentaerythritol and dipentaerythritol are described herein. More specifically, the compounds of the present invention are mixed esters of pentaerythritol and dipentaerythritol having at least one sulfhydryl group and preferably a plurality of sulfhydryl groups as well as at least one non-thiol-containing group. The organic thiol compounds are utilized to plasticize and/or heat stabilize halogen-containing polymer compositions especially poly(vinyl chloride) compositions. The compositions are substantially free or free of metal-based stabilizers, Lewis acids and terpenes. The compounds of the present invention are ideally utilized in polymers normally susceptible to deterioration and color change which can occur during processing of the polymer or exposure of the polymer to certain environments and surprisingly also serve as excellent plasticizers.Type: GrantFiled: October 12, 2004Date of Patent: December 25, 2007Assignee: The College of William and MaryInventors: William Herbert Starnes, Jr., Bin Du
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Patent number: 7238744Abstract: An article of manufacture comprises an ultrahigh molecular weight polyethylene (UHMWPE) mixed with a processing oil and a lubricant selected from the group consisting of fatty acid esters, ethoxylated fatty acid esters, glycol esters, PEG esters, glycerol esters, ethoxylated esters, sorbitol esters, ethoxylated sorbitol esters, aromatic ethoxylates, alcohol ethoxylates, mercaptan ethoxylates, modified ethoxylates, amide surfactants, phosphate esters, phosphonate esters, phosphite esters, alkyl sulfates, fatty acid ethers, alkyl ether sulfates, alkylaryl ether sulfates, sulfonates, naphthalene sulfonates, sulfosuccinates, sulfonated esters, sulfonated amides, alkyl ether carboxylates, alkylaryl ether carboxylates, quaternary amines, amino quaternary amines, ethoxylated amines, imidazoline derivatives, betaines, sultaines, aminopropionate, catechol derivatives, saturated fatty acids, unsaturated fatty acids, and combinations thereof. The method for making those articles is also disclosed.Type: GrantFiled: April 12, 2002Date of Patent: July 3, 2007Assignee: Daramic, Inc.Inventors: Joseph G. Yaritz, J. Kevin Whear
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Patent number: 7211611Abstract: Non-petroleum based oils replace traditional process oils used in rubber compositions in general and specifically in footwear applications. The replacement oils, derived from plant or animal sources, represent a renewable resource and provide other advantages. The oils contain a sufficient level and distribution of fatty acid side chains to partially incorporate into the rubber at low levels, and to act as internal plasticizers at higher levels. Other compositions are free of silane coupling agents and additives that generate carcinogenic nitrosamines.Type: GrantFiled: December 11, 2003Date of Patent: May 1, 2007Assignee: Nike, Inc.Inventor: Thomas W Wilson, III
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Patent number: 7094918Abstract: Novel ultraviolet absorbing compounds that are liquid in nature, are low in color (and thus permit use without the concomitant necessity of adding large amounts of other coloring agents to combat such discoloring), and are highly effective in providing protection in wavelength ranges for which previous attempts at low-color ultraviolet absorbers have failed are provided herein. Such compounds provide such excellent, inexpensive, and beneficial protection from ultraviolet exposure within various media, including, but not limited to, clear thermoplastics. The particular compounds are generally polymeric in nature including various chain lengths of polyoxyalkylenes thereon and are liquid in nature to facilitate handling and introduction within the target media. In addition, such ultraviolet absorbers also exhibit extremely low migratory properties thereby providing long-term protective benefits to the target media as well.Type: GrantFiled: April 28, 2003Date of Patent: August 22, 2006Assignee: Milliken & CompanyInventors: Jusong Xia, Mary E. Mason, Eric B. Stephens
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Patent number: 7041721Abstract: The present invention is directed to a golf ball and to a process for forming a golf ball having at least one layer, where the layer is formed of a polymer blend including a highly neutralized polymer formed from an oxa acid, a thermoplastic resin, and an inorganic metal compound, an organic amine, or a combination thereof, wherein greater than about 70 percent of the acid groups in the polymer blend are neutralized.Type: GrantFiled: May 15, 2003Date of Patent: May 9, 2006Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Kevin M. Harris
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Patent number: 7019055Abstract: A polymer of polyvinyl chloride, polyvinylidene chloride, polycarbonate, polyethylene, polypropylene, polyimide, polyester, or polyvinyl acetate contains about 0.005 to about 10 phr of a stabilizer to prevent discoloration due to oxidation, particularly gamma radiation.Type: GrantFiled: January 17, 2001Date of Patent: March 28, 2006Inventor: Qi Wang
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Patent number: 7015303Abstract: A solution of a polyketone as a copolymer of carbon monoxide and one or more olefins, wherein 90 wt % or more of said copolymer comprises carbon monoxide units and olefin units, and a solvent is an aqueous solution of at least one member selected from the group consisting of zinc salts, calcium salts, thiocyanates and iron salts.Type: GrantFiled: August 5, 1999Date of Patent: March 21, 2006Assignee: Asahi Kasei Kabushiki KaishaInventors: Jinichiro Kato, Toru Morita, Kiyoshi Fujieda
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Patent number: 6964991Abstract: Pressure sensitive adhesive compositions having enhanced resistance to water-whitening comprising an aqueous emulsion polymer are disclosed. The polymer comprises the polymerization reaction product of a polymerizable aqueous emulsion comprising: (i) a hydrophobic monomer mixture of at least one alkyl acrylate or alkyl methacrylate ester of an alcohol wherein the alkyl portion of the alcohol is linear or branched and contains at least 4 carbon atoms, and at least one styrenic monomer, wherein the styrenic monomer is up to about 30 wt. % of the total hydrophobic monomer mixture, (ii) at least about 1 wt. % of at least one hydrophilic monomer, (iii) at least about 5 wt.Type: GrantFiled: May 23, 2002Date of Patent: November 15, 2005Assignee: Surf Chip, Inc.Inventors: Augustin T. Chen, Jong-Shing Guo, Tibor Pernecker
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Patent number: 6949596Abstract: A flame resistant anti-electrostatic polycarbonate composition that is chlorine- and bromine-free is disclosed. Good melt flowability and low tendency to juicing, coupled with its good mechanical and thermal properties make the composition especially suitable for injection molding. The composition finds use in the production of a variety of molded articles.Type: GrantFiled: May 21, 2001Date of Patent: September 27, 2005Assignee: Bayer AktiengesellschaftInventors: Andreas Seidel, Thomas Eckel, Michael Zobel, Dieter Wittmann, Manfred Dietrich
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Patent number: 6927247Abstract: Organic thiol compounds including mercaptophenylcarboxylates are disclosed which can be utilized to plasticize and/or stabilize halogen-containing polymer compositions, especially poly(vinyl chloride) compositions. Compounds of the present invention are utilized in polymers normally susceptible to deterioration and color change, which typically occurs during processing of the polymer or exposure to certain environments.Type: GrantFiled: June 12, 2003Date of Patent: August 9, 2005Assignee: The College of William and MaryInventors: William Herbert Starnes, Jr., Soungkyoo Kim
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Patent number: 6878763Abstract: The free radical initiated addition polymerization of ethylenically unsaturated, particularly acrylic monomers in which the dispersed phase is stabilised by a surfactant including at least one anionic surfactant compound of the formula (I): R1—(OA)n—X where R1 is C16 to C22 hydrocarbyl including at least two double bonds; OA is oxyalkylene group; n is from 2 to 60; and X includes at least one acidic H atom, and is particularly a phosphate ester group, or a salt thereof, is described. The use of the surfactants of the formula (I) enable efficient emulsification and thus polymerization at temperatures above those at which non-ionic unsaturated surfactants are effective. The polymer latex products give polymer films having good water resistance properties.Type: GrantFiled: April 17, 2002Date of Patent: April 12, 2005Assignee: Imperial Chemical Industries PLCInventors: Trevor Graham Blease, Johny Denis Grade
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Patent number: 6849674Abstract: A rubber composition comprising a vulcanizable rubber, a reinforcing filler, a softening agent, and other reagents for rubber to which is added in a specific amount of a sulfur compound having the formula (I): —(SxR1)n—??(I) wherein R1 represents an organic group, x is a number of 3 to 5 on average, and n is an integer of 1 to 100, or a specific sulfur compound (1) and sulfur (2), and optionally a thiazole base, sulfenamide base, thiuram base, and/or diothio acid base vulcanization accelerator (3).Type: GrantFiled: December 23, 2002Date of Patent: February 1, 2005Assignee: The Yokohama Rubber Co., Ltd.Inventors: Fumito Yatsuyanagi, Kazunori Ishikawa, Shuichi Fukutani
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Patent number: 6803100Abstract: The invention relates to new rewettable adhesive systems containing colloidal dispersion mixtures obtained by copolymerization of at least one water-soluble monomer with at least one non-water-soluble comonomer in the presence of a micelle-forming emulsifier. The invention also relates to the use of the new adhesive systems.Type: GrantFiled: January 8, 2002Date of Patent: October 12, 2004Assignee: Celanese Emulsions GmbHInventors: Helmut Hintz, Ivan Cabrera
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Patent number: 6750277Abstract: A composition comprising (A) a copolymer which comprises (I) repeating units which are derived from a monomer having a fluoroalkyl group, a carbon-carbon double bond, (II) optional repeating units which are derived from a monomer having at least two urethane or urea bonds and a carbon-carbon double bond, but no fluorine atom, (III) optional repeating units which are derived from a monomer, the homopolymer of which having a glass transition temperature (Tg) of 50° C. or less, (IV) optional repeating units which are derived from a monomer having a hydrophilic group and a carbon-carbon double bond, and (V) optional repeating units which are derived from a monomer having a chlorine atom and a carbon-carbon double bond; and (B) a film-forming auxiliary can impart high water and oil repellency by drying at room temperature (0 to 30° C.) without requiring a heat treatment step.Type: GrantFiled: August 19, 1999Date of Patent: June 15, 2004Assignee: Daikin Industries Ltd.Inventors: Masayuki Yamana, Ikuo Yamamoto, Masato Kashiwagi, Koji Kubota
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Patent number: 6747081Abstract: Organic thiol compounds including aromatic, aliphatic, and diester ether compounds containing sulfhydryl groups are disclosed which can be utilized to plasticize and/or stabilize halogen-containing polymer compositions, especially poly(vinyl chloride) compositions. Compounds of the present invention are utilized in polymers normally susceptible to deterioration and color change, which typically occurs during processing of the polymer or exposure to certain environments.Type: GrantFiled: June 14, 2002Date of Patent: June 8, 2004Assignee: The College of William and MaryInventor: William Herbert Starnes, Jr.
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Patent number: 6683131Abstract: A water-based liquid treatment composition for metal surfaces comprises water, (A) dissolved, dispersed, or both dissolved and dispersed urethane resin, acrylic resin; or both urethane and acrylic resins; (B) dissolved, dispersed, or both dissolved and dispersed curing agent molecules; (C) dispersed silica powder; (D) dispersed oxidized polyethylene wax with an average particle size of 0.01 to 0.Type: GrantFiled: November 28, 2001Date of Patent: January 27, 2004Inventors: Yasuhiro Kinoshita, Keiichi Ueno, Takashi Koyama
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Patent number: 6652976Abstract: Conductive, highly abrasion-resistant coatings on mouldings, consisting of at least one conductive layer and at least one highly abrasion-resistant layer, a process for their production and their use.Type: GrantFiled: July 3, 2001Date of Patent: November 25, 2003Assignee: Bayer AktiengesellschaftInventors: Michael Mager, Klaus Wussow, Udo Guntermann
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Patent number: 6599970Abstract: Aqueous compositions having enhanced thickening properties containing lipophilically-modified copolymer thickeners and one or more hydrophilic surfactants are disclosed. In particular, aqueous compositions containing (i) lipophilically-modified copolymers containing at least 5% of selected lipophilically-modified components and (ii) surfactants having an HLB value of greater than 15 are useful for the thickening of a range of personal, domestic and industrial products.Type: GrantFiled: May 30, 2001Date of Patent: July 29, 2003Assignee: Rohm and Haas CompanyInventor: Paul Francis David Reeve
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Publication number: 20030092806Abstract: The free radical initiated addition polymerisation of ethylenically unsaturated, particularly acrylic monomers in which the dispersed phase is stabilised by a surfactant including at least one anionic surfactant compound of the formula (I): R1—(OA)n—X where R1 is C16 to C22 hydrocarbyl including at least two double bonds; OA is oxyalkylene group; n is from 2 to 60; and X includes at least one acidic H atom, and is particularly a phosphate ester group, or a salt thereof, is described. The use of the surfactants of the formula (I) enable efficient emulsification and thus polymerisation at temperatures above those at which non-ionic unsaturated surfactants are effective. The polymer latex products give polymer films having good water resistance properties.Type: ApplicationFiled: April 17, 2002Publication date: May 15, 2003Inventors: Trevor Graham Blease, Johny Denis Grade
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Patent number: 6559216Abstract: Novel ultraviolet absorbing compounds that are liquid in nature, are extremely low in color (and thus permit use without the concomitant necessity of adding large amounts of other coloring agents to combat such discoloring), and are highly effective in providing protection in wavelength ranges for which previous attempts at low-color ultraviolet absorbers have failed are provided herein. Such compounds provide such excellent, inexpensive, and beneficial protection from ultraviolet exposure within various media, including, but not limited to, clear thermoplastics. The particular compounds are generally polymeric in nature including various chain lengths of polyoxyalkylenes thereon and are liquid in nature to facilitate handling and introduction within the target media. In addition, such ultraviolet absorbers also exhibit extremely low migratory properties thereby providing long-term protective benefits to the target media as well.Type: GrantFiled: August 21, 2001Date of Patent: May 6, 2003Assignee: Milliken & CompanyInventors: Xiaodong E. Zhao, Todd D. Danielson, Mary E. Mason, Daniel M. Connor, Eric B. Stephens, Jason D. Sprinkle, Jusong Xia
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Patent number: 6534574Abstract: Compounds and compositions comprising specific metal salts of bicyclo[2.2.1 ]heptane dicarboxylate salts in order to provide highly desirable properties within polyolefin articles are provided. The inventive salts and derivatives thereof are useful as nucleating and/or clarifying agents for such polyolefin, provide excellent crystallization temperatures, stiffness, and calcium stearate compatibility within target polyolefin. Also, such compounds exhibit very low hygroscopicity and therefore excellent shelf stability as powdered or granular formulations. Polyolefin additive compositions and methods of producing polyolefin with such compounds are also contemplated within this invention.Type: GrantFiled: November 27, 2001Date of Patent: March 18, 2003Assignee: Milliken & CompanyInventors: Xiaodong Edward Zhao, Darin L. Dotson, Brian G. Morin, Brian M. Burkhart, Martin E. Cowan, Jeffrey R. Jones
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Publication number: 20030008958Abstract: A photochromic cured product exhibiting excellent photochromic properties such as a high color density and a high fading rate, as well as excellent base material properties such as a high hardness and a large heat resistance.Type: ApplicationFiled: April 15, 2002Publication date: January 9, 2003Inventors: Junji Momoda, Hironobu Nagou, Toshiaki Otani
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Patent number: 6503994Abstract: Among other things, a silicone composition curing by condensation at room temperature is prepared from a base dough containing filler and polyorganosiloxane having hydroxy groups, as well as from an activator component containing crosslinker and a catalyst of an organometallic compound, which is characterized in that the activator component additionally contains a polyether having at most one alkoxysilyl group and/or a polyaddition product based on polyether and having at most one alkoxysilyl group.Type: GrantFiled: August 31, 2000Date of Patent: January 7, 2003Assignee: Heraeus Kulzer GmbH & Co. KGInventors: Klaus-Dieter Nehren, Michael Freckmann, Matthias Schaub
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Patent number: 6489382Abstract: Preparations of solids comprising a) at least one particulate solid and b) a water-dispersible graft copolymer built up from at least one hydrophobic, ethylenically unsaturated monomer, optionally one or more ethylenically unsaturated hydrophilic monomers, and at least one natural protective colloid or protective colloid obtained from a natural protective colloid by derivatization or thermal, enzymatic, oxidative, hydrolytic or bacteriological degradation having an average molar mass of Mn>500 g/mol.Type: GrantFiled: May 15, 2000Date of Patent: December 3, 2002Assignee: Bayer AktiengesellschaftInventors: Heinz Giesecke, Bernd Hauschel, Peter-Roger Nyssen, Dirk Pfützenreuter
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Patent number: 6462116Abstract: The zinc bum experienced during the processing of a composition comprising a halogen-containing polymer and a zinc mercaptoester is eliminated by the addition of an organothio compound selected from dithioglycol, polyformals and polyacetals of said dithioglycol, and a mercaptoalkanol.Type: GrantFiled: May 30, 2001Date of Patent: October 8, 2002Assignee: Morton International, Inc.Inventors: George F. Beekman, Lionel R. Price, Keith A. Mesch
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Patent number: 6423764Abstract: Colored polyester plastics produced through the introduction of coloring agents prior to extrusion but after pellet production of the base polymer are provided. As a result, the plastic is melt-extruded and mixed with the coloring agent and subsequently subjected to solid stating wherein the base polymer is accorded an increase in molecular weight and the coloring agent becomes integrated therein. Such a method permits avoidance of introduction of a coloring agent to the polymerization reaction chamber that results in extensive staining (particularly upon a change of desired colors for the next batch of plastic). Such a method also permits avoidance of the introduction of a coloring agent to an injection molding process that results in uneven color dispersion and sub-optimal physical properties within the ultimate article. The inventive procedure produces colored thermoplastics of substantially the same shades and uniformity as with the aforementioned precoloring or masterbatch process.Type: GrantFiled: August 24, 2000Date of Patent: July 23, 2002Assignee: Milliken & CompanyInventors: Edward X. Zhao, Todd D. Danielson, Daniel M. Connor, Jason D. Sprinkle