Abstract: A resin composition comprises 100 parts by weight of a thermoplastic resin and 9 to 55 parts by weight of an additive mixture comprising (A) 3 to 35 parts by weight of a tetrahalogenated bisphenol A carbonate oligomer, (B) 3 to 35 parts by weight of bis(tribromo-phenoxy)ethane and (C) 0.5 to 15 parts by weight of antimony trioxide. It is advantageous in respect to flame retardancy, impact resistance and light durability.
Abstract: There is disclosed a flame-retarded acrylonitrile-butadiene-styrene composition containing from about 5 to about 35 percent (by weight) bis(2,4,6-tribromophenoxyethyl) tetrabromobisphenol A ether and a method for forming such a composition.
Abstract: Compounds useful as flame retarders for organic high molecular compounds are obtained by reacting a polycondensate of a halogenated phenol, e.g. a tribromophenol polycondensate, with a metal compound or organic compound having at least two functional groups capable of reacting with the terminal hydroxyl group of the polycondensate, e.g. an alkaline earth metal halide, an alkyl dihalide or an acyl dihalide.
Abstract: Flame retardant reinforced with thermoplastic polyester resin compositions are disclosed glass fiber and a system of flame retardants represented by the following general formulas (I) and (II), together with antimony trioxide. The flame retardant system is a blend of 1-20 parts by weight of component (I), and 2-40 parts by weight of component (II), provided the weight ratio (I)/(II) of the flame retardant components (I) to (II) is in the range of 0<(I)/(II).ltoreq.5, and that the total amount of flame retardants (I) plus (II) is in the range of 3-40 parts by weight. From 2 to 3 parts by weight of antimony trioxide is present and 5 to 60% by weight of glass fiber is also present, these two percentages being expressed on the basis of the weight of the total resin composition. The resin compositions exhibit outstanding mechanical, thermal, forming and machining properties in addition to being fire retardant.
Type:
Grant
Filed:
January 5, 1984
Date of Patent:
December 31, 1985
Assignee:
Mitsubishi Rayon Co., Ltd.
Inventors:
Kazuo Kishida, Isao Sasaki, Hiroshi Mori
Abstract: Transparent flame-retardant poly(arylether-arylsulfone) molding materials preferably contain not less than 50% by weight of units of the formula ##STR1## and, as a flameproofing agent, from 0.1 to 10% by weight, based on the weight of poly(arylether-arylsulfone), of a poly(2,6-dibromophenylene 1,4-oxide) having a molecular weight of from 1000 to 20000, and, if required, a heat stabilizer.The molding materials are useful for the production of shaped articles, films and fibers.
Abstract: Compositions for flameproofing polymeric material comprising:(a) a halogenated alkylaryl ether, the aryl group of which may be substituted by halogen;(b) an organo-tin compound; and(c) a sterically hindered phenol or a bisphenol containing a sterically hindered --OH group on each phenyl.In this specification by the term "bisphenol" is meant a compound containing two phenol groups linked by a bridging group that is not attached to any other bisphenol groups and by the term "phenol" is meant compounds containing only a single phenol group.
Abstract: There is provided a novel flame retardant system or additive which when incorporated in a polymer, such as polyphenylene ether resin compositons, produces novel flame resistant non-discolored polyphenylene ether resin compositions. The flame retardant system comprises a composition of stable halogenated organic compounds and boron containing salts or esters which are stable at 250.degree.-300.degree. C.
Abstract: A polyolefin plastic composition is provided having improved transparency, which comprises:(a) a major portion of a linear, low density polyethylene polymer;(b) a di-acetal of sorbitol and an aromatic aldehyde in an amount sufficient to improve transparency characteristics; and(c) a di-acetal decomposition inhibitor in an amount sufficient to inhibit decomposition of said di-acetal.
Abstract: An expandable polymeric styrene particle is provided from which molded foamed articles can be produced exhibiting reduced flammability characteristics. The expandable polymeric styrene particle contains a blowing agent, a minor amount of bis(allyl ether) of tetrabromobisphenol A and a minor amount of dibromoethyldibromocyclohexane. The additives can be incorporated during impregnation with the blowing agent or by blending with the expandable particles after impregnation.
Abstract: An expandable polymeric styrene particle is provided from which molded foamed articles can be produced exhibiting reduced flammability characteristics. The expandable polymeric styrene particle contains a blowing agent, a minor amount of bis(allyl ether) of tetrabromobisphenol A and a minor amount of pentabromomonochlorocyclohexane. The additives can be incorporated during impregnation with the blowing agent or by blending with the expandable particles after impregnation.
Abstract: An expandable polymeric styrene particle is provided from which molded foamed articles can be produced exhibiting reduced flammability characteristics. The expandable polymeric styrene particle contains a blowing agent, a minor amount of bis (allyl ether) of tetrabromobisphenol A and a minor amount of dibromoethyldibromocyclohexane. The additives can be incorporated during impregnation with the blowing agent or by blending with the expandable particles after impregnation.
Abstract: Thermoplastic compositions are disclosed which comprise blends of about 50 to about 85 percent by weight of a thermoplastic polyurethane and the balance of the blend comprising (a) a polyvinyl halide resin and (b) a diene-nitrile copolymer rubber, the weight ratio of (a) to (b) being within the range of from about 1:4 to about 1.5:1.The novel blends do not melt or spread flaming drip when combusted but rather form chars. The blends are optionally fire retarded by the addition of flame retardants.The fire retarded blends find utility in, inter alia, electric wire and cable jacketing where a high degree of fire retardance is required. The blends without fire retardants provide a good thermoplastic polyurethane at lower cost than the polyurethanes alone and find utility in those applications normally associated with polyurethanes such as films, footwear, wire jacketing, and particularly those applications calling for a higher degree of oil resistance than polyurethanes alone.
Type:
Grant
Filed:
June 14, 1982
Date of Patent:
April 26, 1983
Assignee:
The Upjohn Company
Inventors:
Costas N. Georgacopoulos, Curtis P. Smith
Abstract: A flame retardant polycarbonate resin composition comprising a polycarbonate resin, a nuclear substituted benzoic acid containing at least one substituent selected from the group consisting of thiosalicylic acid and dihydroxy benzoic acid, and tetrabromobisphenol A or ##STR1## .
Abstract: Process and composition relating to novel, fine denier, homogeneous, curly synthetic fibers are set out. The process comprises orientation of a fiber-forming, slowly crystallizing, synthetic polymer composition in fiber form, generally after melt spinning, such orientation resulting from application of a longitudinal tensile force to said fiber above the crystallization temperature range and maintaining it at least through such range during a controlled, substantially axially symmetric cooling of the fiber. The novel fibers have a substantially axially symmetric, residual tensile force differential between their outer sheaths and inner portions, are generally of helical configuration and can exhibit more than about fifteen turns per linear centimeter.
Abstract: Styrene/maleic anhydride polymers can be made more resistant to combustion by incorporation therein of minor amounts of polyvinyl chloride. The compositions can also comprise MBS, ABS and other flame retardant additives.