Only C, H, And O Atoms Patents (Class 524/378)
  • Patent number: 5700857
    Abstract: A polyester resin composition made of a polyester resin containing a polyalkylene oxide soft segment component, a plasticizer, a crystallization promoter, and a brominated flame retardant is developed, said composition having good flame resistance and mechanical properties.
    Type: Grant
    Filed: June 25, 1996
    Date of Patent: December 23, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Atsushi Mukohyama
  • Patent number: 5688855
    Abstract: A hydrophilic coating composition used to impart increased lubricity and wettability to the surface of a hydrophobic substrate which is comprised of three essential components:1) Hydrogel-forming polymer component A2) Water-soluble polymer component B3) Common solvent C for the components A and BThe water-insoluble, hydrogel-forming component A consists of a segmented copolymer with long, hydrophilic terminal blocks and the essentially hydrophobic central section. The two polymer components A and B have a limited miscibility in the absence of a common solvent C. Therefore, their blend tends to separate spontaneously into two polymer phases. The phase separation takes place during the solvent evaporation or extraction. A gradient of hydrophilicity and swelling within the coating layer is thus spontaneously created achieving a good adhesion to the substrate and high surface hydrophilicity at the same time.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: November 18, 1997
    Assignee: S.K.Y. Polymers, Inc.
    Inventors: Vladimir A. Stoy, Gerald A. Gontarz, Jr., Patrick Stoy
  • Patent number: 5684074
    Abstract: The invention provides a novel coating composition comprising a first component (i.e. 100 parts by weight of a fluorine-containing copolymer), a second component (i.e. 0.1-20 parts by weight of an alkyl silicate), and a third component (i.e. 0.05-3 parts by weight of a water-soluble polyether-modified silicone oil and/or 1-25 parts by weight of a polyoxytetramethylene glycol). The fluorine-containing copolymer has a hydroxyl value of 80-200 mg KOH per 1g thereof and is prepared by copolymerizing 40-65 mol % of a fluoroolefin, 14-50 mo1% of a copolymerizable vinyl-containing compound, 12-25 mol % of a polymerizable hydroxyl-containing compound, and 0.1-12 mol % of at least one other copolymerizable compound. A cured coated film prepared from the coating composition is superior in elasticity and weathering and stain resistances.
    Type: Grant
    Filed: October 25, 1995
    Date of Patent: November 4, 1997
    Assignee: Central Glass Company, Limited
    Inventors: Yoshi Hirashima, Kazuhiko Maeda, Kentaro Tsutsumi
  • Patent number: 5661205
    Abstract: A method for producing a polychloroprene latex, which comprises copolymerizing chloroprene and an ethylenically unsaturated carboxylic acid in the presence of a polyvinyl alcohol, wherein a glycol ether is also present during the copolymerization.
    Type: Grant
    Filed: January 18, 1996
    Date of Patent: August 26, 1997
    Assignees: Denki Kagaku Kogyo Kabushiki Kaisha, Konishi Co., Ltd.
    Inventors: Mikitoshi Satoh, Masao Koga, Shigeru Nagasawa, Kunihiko Asano, Toshiyuki Uenoyama, Kunihiro Onishi
  • Patent number: 5661206
    Abstract: An admixture for modifying the fluidity of a cementitious mixture comprises a cement-dispersing agent which is an aqueous solution of polymer, in which solution an oxyalkylene-based defoaming agent is dissolved or dispersed in particles of no greater that 20 .mu.M diameter. The polymer is preferably a polymer which comprises units derived from unsaturated carboxylic acid monomer and the polymer is preferably prepared in the presence of the defoaming agent. Particular addition copolymers give particularly good results. The admixture permits good control of the fluidity of cementitious compositions and has extended shelf life.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: August 26, 1997
    Assignees: MBT Holding AG, Nippon Shokubai Co., Ltd.
    Inventors: Yoshio Tanaka, Akira Ohta, Hideyuki Tahara, Tsuyoshi Hirata
  • Patent number: 5643992
    Abstract: A water-based pressure sensitive adhesive formulation is provided with one or more high molecular weight linear aliphatic polymers. The resulting composition can be used to form stable filaments or delivered from the coating die of a premetered coater in the form of a stable sheet at a flow rate substantially less than the minimum delivery flow rate achievable using the formulation without polymer. Low levels of polymer can provide dramatic improvement in the viscosity of such compositions, without detrimental effect on the adhesive and other desireable qualities of the composition.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: July 1, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Paul J. Northey
  • Patent number: 5637387
    Abstract: The present invention relates to storage-stable advanced polymaleimide compositions and prepreg products manufactured therefrom comprising (A) an advanced polymaleimide reaction product resulting from the advancement reaction of a polyimide and an alkenyl phenol; and (B) a phenothiazine added to component (A) after advancement.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: June 10, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Benjamin G. Chin, Roger Tietze
  • Patent number: 5633332
    Abstract: Polymers can be obtained by free-radical polymerization of monomers in the presence of a dissolved polysiloxane. The free-radical-polymerizable monomers used are at least one compound of the formula I ##STR1## where R.sup.1 and R.sup.2 are, independently of one another, hydrogen, COOH, C.sub.1 -C.sub.18 -alkyl, cyclohexyl, C.sub.1 -C.sub.4 -alkyl-cyclohexyl, C.sub.6 -C.sub.10 -bicycloalkyl, C.sub.6 -C.sub.18 -tricycloalkyl,R.sup.3 is hydrogen or methyl,R.sup.4 is hydrogen, (C.sub.1 -C.sub.20)-alkyl, 2-hydroxypropyl, glycidyl,--[CH.sub.2 CH.sub.2 --O].sub.n H, having n=1 to 5,--[CH.sub.2 ].sub.m --OH, having m=3 to 18, in particular m=3 to 8,--[CH.sub.2 ].sub.2 O--[CO--(CH.sub.2).sub.5 ].sub.x OH, where x=a number from 1 to 3, or--[CH.sub.2 CHOHCH.sub.2 ]--O--(CO)R,where R is a C.sub.1 to C.sub.18 -alkyl radical.The polysiloxane used is at least one aromatic polyarylene siloxane of the formula III ##STR2## where R.sup.9 and R.sup.10 are, independently of one another, a C.sub.1 -C.sub.12 -alkyl radical, a C.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: May 27, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Horst-Tore Land, Walter Schubert, Reinhardt Kalus
  • Patent number: 5624987
    Abstract: This invention relates to a polyester composition comprising a blend of:(A) 99.5 to 75 weight % of a copolyester having an inherent viscosity of 0.1 to 1.2 dL/g and having a melting point in excess of 250.degree. C., comprising:(a) one or more dicarboxylic acids, and(b) a glycol component comprising at least 80 mole % 1,4-cyclohexanedimethanol; and(B) 0.5 to 25 weight % of one or more polyalkylene ethers,wherein the weight percentages of all components in said blend total 100 weight %.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: April 29, 1997
    Inventors: Andrew E. Brink, Sam R. Turner, Gerald T. Keep
  • Patent number: 5599863
    Abstract: Provided are methyl methacrylate polymers admixed with particular polyalkylene glycols, ethers or esters, optionally with BHT, which show good chemical resistance, as well as maintenance of optical properties and minimal yellowing on exposure to sterilizing gamma radiation.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: February 4, 1997
    Assignee: Cyro Industries
    Inventor: Daniel Zimmerman
  • Patent number: 5585426
    Abstract: A process for improving the electrostatic charge developed on a resin powder composition for electrostatic coating of solid objects and the method of application thereof. The resin powder comprises (i) a thermosetting or thermoplastic resin and (ii) an electrostatic property modifying agent (polyalkylene ether, polyalkylene glycol, polyethoxylated stearyl alcohol) incorporated in the resin or on the surface of the resin. The methods of application of the powder involves charging the powder by electrical induction/conduction and spraying the charged powder onto a grounded solid object to which it adheres prior to the thermal fusing to produce a permanent finish.
    Type: Grant
    Filed: October 5, 1994
    Date of Patent: December 17, 1996
    Assignee: Nexus Corporation
    Inventors: Barbara E. Williams, Ian Harpur, Graham Hearn
  • Patent number: 5569691
    Abstract: The invention relates to a rubber-elastic composition which comprises a polyether material, and which in the completely vulcanized and completely polymerized form, contain 0.1 to 15 wt. %, relative to the total weight of the composition, of at least one hydrophilic nature imparting agent selecting from the group consisting of a hydrophilic silicone oil having one or more siloxane groups as a hydrophobic part and one or more ether groups as a hydrophilic part, a fluorinated hydro-carbon, a block copolymer of ethylene oxide/propylene oxide, a fatty alcohol derivative, an alkyl phenol derivative, a fatty amine, an amine oxide, a fatty acid glycol and glycerin derivative, a fatty acid, and a fatty acid monoester. The composition is suitable as dental impression composition and has, in the completely polymerized state, even with multiple disinfections in an aqueous disinfecting solution, a continuing good ability to flow on (small wetting angle) and an unchanged dimensional stability.
    Type: Grant
    Filed: March 7, 1994
    Date of Patent: October 29, 1996
    Assignee: Thera Patent GmbH & Co. KG Gesellschaft fur Industrielle Schutzrechte
    Inventors: Rainer Guggenberger, Erich Wanek, Oswald Gasser
  • Patent number: 5565027
    Abstract: The invention relates to a cement composition containing a water reducing amount of the product formed by reaction of polyvinyl alcohol and an hydroxyaldehyde such as 4-hydroxybutanal.
    Type: Grant
    Filed: April 2, 1996
    Date of Patent: October 15, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Edward T. Shawl, Jeffrey A. Klang
  • Patent number: 5559176
    Abstract: An aqueous polyolefin resin composition characterized by containing a substance with a structure of poly(alkylene oxide) and a solubility parameter (SP value) of not lower than 7 to not higher than 12 at a proportion of not less than 0.001 wt. % to not more than 50 wt. % as a constitutional ingredient upon aqueous conversion of polyolefin or modified polyolefin, and film formers such as paint, primer, ink and coating material, sealant and adhesive containing it as a part of constitutional ingredients are disclosed. As the substances with a structure of poly(alkylene oxide), several examples are given.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: September 24, 1996
    Assignee: Nippon Paper Industries, Co., Ltd.
    Inventors: Hiroaki Namba, Ken-ichi Fujino
  • Patent number: 5554675
    Abstract: A composition useful in printing inks exemplified as comprising:(1) from about 4 to about 80% by weight of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from about 1.0 to about 60% by weight of pigment material;(3) from about 0.05 to about 30% by weight of a nonionic, polyether type property modifier; and(4) from substantially none to about 90% by weight of water.
    Type: Grant
    Filed: May 9, 1994
    Date of Patent: September 10, 1996
    Inventors: Gary T. Clark, John N. Rasar, Rebecca R. Stockl
  • Patent number: 5534578
    Abstract: The present invention relates to a silica reinforced rubber composition and pneumatic tires having treads comprised of the silica reinforced rubber compositions. The silica reinforced rubber composition comprises an elastomer, silica, optionally carbon black and a silica coupler comprised of the zinc salt, the ammonium salt or the sodium salt of salicylic acid.
    Type: Grant
    Filed: September 6, 1994
    Date of Patent: July 9, 1996
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson G. Wideman, Paul H. Sandstrom
  • Patent number: 5534577
    Abstract: An aqueous polyolefin resin composition of (a) a polyolefin or a modified polyolefin selected from the group consisting of polyolefins which have been modified by graft copolymerization with an unsaturated carboxylic acid, unsaturated carboxylic acid anhydride or mixture thereof, polyolefins which have been modified by graft copolymerization with a reactive monomer having radical polymerizability and mixtures thereof and (b) a substance with a structure of poly(alkylene oxide) and a solubility parameter (SP value) of not lower than 7 cal.sup.1/2 .multidot.cm.sup.-3/2 to not higher than 12 cal.sup.1/2 .multidot.cm.sup.-3/2 at a proportion of not less than 0.001 wt. % to not more than 50 wt. % upon aqueous conversion of the polyolefin or modified polyolefin and its use in film forming compositions such as paints, primers, inks and coating materials.
    Type: Grant
    Filed: December 15, 1993
    Date of Patent: July 9, 1996
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Hiroaki Namba, Ken-ichi Fujino
  • Patent number: 5530043
    Abstract: A pigment grind composition contains pigment, water dispersible acrylic polymer and a reactive diluent. The reactive diluent has a number average molecular weight of between about 200 and about 2500 and is selected from polyalkylene glycols, polyalkylene glycol ethers, glycol ether formals or mixtures of these. The pigment grind composition has a volatile organic content of less than two pounds per gallon.
    Type: Grant
    Filed: May 25, 1994
    Date of Patent: June 25, 1996
    Assignee: PPG Industries, Inc.
    Inventors: Steven R. Zawacky, Jeffrey G. Koren, Mark L. Follet, Patricia A. Aikens
  • Patent number: 5527858
    Abstract: This invention provides a melt-processable fluoroplastic composition comprising a blend of a melt-processable thermoplastic fluoropolymer component of interpolymerized units derived from vinylidene fluoride and at least one ethylenically-unsaturated, copolymerizable, fluorinated comonomer, and a hydrocarbon polymer component comprising poly(oxyalkylene). The composition is useful for making shaped articles including tubing or film.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: June 18, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Thomas J. Blong, Claude Lavallee
  • Patent number: 5525669
    Abstract: Aqueous emulsions which include polyvinyl butyral are prepared by mixing a nonionic emulsifier with polyvinyl butyral and, if desired, with a plasticizer resin and, if desired, with one or more solvents, and adding water under the action of shear forces.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: June 11, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Markus A. Schafheutle, Gerhard Merten
  • Patent number: 5521238
    Abstract: The present invention relates to an organopolysiloxane emulsion composition comprising a hydroxy or alkoxy-endblocked diorganopolysiloxane, an alkoxy-group containing organosilicon compound, surfactant, and water. The compositions of this invention are characterized by a lack of offensive odor, high productivity and good storage stability. The organopolysiloxane emulsions of this invention are useful as fiber treatment agents. The fibers treated with the organopolysiloxane emulsion of this invention exhibit good feel.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: May 28, 1996
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Isao Ona, Masaru Ozaki, Toshio Saruyama, Masahiko Suzuki
  • Patent number: 5519075
    Abstract: The present invention provides a polyoxymethylene resin composition comprising:(A) 100 parts by weight of a polyoxymethylene resin,(B) 0.1 to 2.0 parts by weight of a sterically hindered phenol compound,(C) 0.01 to 5.0 parts by weight of an olefin resin,(D) 0.1 to 2.0 parts by weight of specific polyalkylene glycol,(E) 0.01 to 5.0 parts by weight of a specific amide compound,(F) 0.01 to 2.0 parts by weight of melamine, and(G) 0 to 5.0 parts by weight of a polymer containing formaldehyde-reactive nitrogen.The extrusion molded article obtained from the polyoxymethylene resin composition of the present invention has smaller whitened and void parts internally which, when not so small, are unfavorable with respect to physical properties and appearance of the molded article.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: May 21, 1996
    Inventors: Masao Matsumoto, Kenji Kagawa, Toshiharu Seyama
  • Patent number: 5514767
    Abstract: The method of the present invention is a hot-melt polycondensation for an aromatic dihydroxy compound and a dicarbonate in the presence of a basic catalyst, adding sulfur-containing acid compound with a pKa value less than 3 or the derivative thereof, and 5-1,000 ppm of water, and additives as needed for the polycarbonate while the reaction product polycarbonate is still in a molten state, and kneading the material.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: May 7, 1996
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai, Kenichi Tominari, Akio Kanezawa
  • Patent number: 5506290
    Abstract: A cross-linked gel-like composition of matter. The composition is capable of being used as a modeling compound, as well as being moldable, extrudable, stretchable, and being inflated into bubbles for use as a play activity. The composition is based on a cohesive polyvinyl alcohol non-adhesive and substantially non-drying composition that is safe if accidentally ingested and can be washed from fabrics and carpets with water.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: April 9, 1996
    Inventor: Wallace Shapero
  • Patent number: 5502089
    Abstract: A crosslinkable polymeric emulsion has a pH from about 1.5 to about 8.5 and includes a carboxyl-substituted latex polymer dispersed in an aqueous medium, an Iron (III) compound and an amount of a stabilizer, selected from the group consisting of nonionic surfactants and protective colloids, effective to sterically stabilize the emulsion. A method for making a crosslinked polymer film includes forming a layer of the crosslinkable polymer emulsion and drying the layer to form the crosslinked polymer film wherein the film is ionically crosslinked between carboxyl substituent groups of the polymer by Iron (III) cations. A crosslinking agent for carboxyl-substituted polymers includes particles of a water-insoluble Iron (III) compound having an average maximum characteristic linear dimension of less than or equal to about 5 microns.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: March 26, 1996
    Assignee: Rohm and Haas Company
    Inventors: Mark C. Bricker, Paul R. Van Rheenen
  • Patent number: 5500456
    Abstract: A new tire sealant and inflator composition is described which utilizes a sealant having superior performance, presented in a water-based carrier, and with an inflator composition consisting of mainly dimethyl ether, modified by trichloroethylene and nitrogen gas. The composition comprises a terpolymeric latex sealant emulsion, prevented from coagulating or vulcanizing in the dispenser by the addition of additives, and made more potent by the inclusion of certain wood flours having selected particle size distributions. Other ingredients, such as propylene glycol, a surfactant, triethanolamine and ammonia, confer special attributes; for example, softening the wood flour particles and keeping them dispersed in the aerosol can, while causing them to pack down into a sealing matrix once added to a tire having a puncture.
    Type: Grant
    Filed: January 26, 1994
    Date of Patent: March 19, 1996
    Assignee: Snap Products, Inc.
    Inventors: Paul D. Hughett, Montfort A. Johnsen
  • Patent number: 5500476
    Abstract: A polymer mixture on the basis of a polyalkylene phthalate ester, a copolyether ester and an agent to improve the impact to which an agent to improve the bonding of lacquer systems on an aqueous base has been added. The polymer mixture according to the invention comprises a polyalkylene glycol polymer or a polyalkylene glycol copolymer as an agent to improve the lacquer bonding.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: March 19, 1996
    Assignee: General Electric Company
    Inventors: Robertus E. de Jong, Jacobus J. C. van der Kort
  • Patent number: 5470897
    Abstract: A radically curable coating composition containing) 50 to 95 parts by weight of an unsaturated polyester component having a viscosity at 23.degree. C. of 1,000 to 15,000 mPa.s, B) 5 to 50 parts by weight of compounds containing (meth)acryloyl groups and/or vinyl ether groups, C) 0.01 to 0.3 wt. %, based on the total weight, of waxes and/or paraffins having a melting point of 35+ to 100.degree. C. and D) 0 to 10 wt. %, based on the total weight, of at least one plasticizer or carbamic acid resin, and the use of the coating composition for coating substrates, in particular wood substrates.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: November 28, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Meixner, Wolfgang Fischer, Manfred Muller
  • Patent number: 5464687
    Abstract: Compositions of ethylene alkyl acrylate grafted onto a polyolefin such as isotactic polypropylene are provided. The composition is highly wettable by adding both a polar group material and a hydrophilic modifier to the polypropylene. The process comprises extruding the polyolefin into a fiber which is spinnable and may be used to form woven or nonwoven materials. The composition products are particularly well suited for forming various goods, including diaper coverstock, personal hygiene pads, battery separators, filters, tea bag pouches and filter stock.
    Type: Grant
    Filed: July 12, 1994
    Date of Patent: November 7, 1995
    Assignee: Lyondell Petrochemical Company
    Inventor: Paresh J. Sheth
  • Patent number: 5451626
    Abstract: This invention relates to a polyester composition comprisinga) a polyester having repeat units from terephthalic acid and 1,4-cyclohexane dimethanol, said polyester having an I.V. of 0.5-2.0 g/dL, andb) about 1-10% by weight of the total composition of an ether compound having the formulawherein R and R' having from about 1 to about 30 carbon atoms are univalent hydrocarbon radicals, A and A' having from about 6 to about 18 carbon atoms are aromatic radicals, and --X-- is a chemical bond or divalent coupling radical.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: September 19, 1995
    Assignee: Eastman Chemical Company
    Inventors: Jiro Kumaki, Kiyomi Okita, Hidetoshi Ohtawa
  • Patent number: 5441998
    Abstract: A composition is provided which, when added to an elastomer or tackifier, renders a repulpable hot melt adhesive. The compositions consists of an alkoxylated alcohol of the formulaA-B (I)wherein A is the unit ##STR1## and B is the unit ##STR2## and further wherein R and R.sub.1 are independently selected from the group consisting of hydrogen and a C.sub.1 -C.sub.10 alkyl group; R.sub.2 is hydrogen or a C.sub.1 -C.sub.5 alkyl group; x is between about 1 to about 142; and y is between about 2 to about 817, provided the weight ratio of B/A+B is between 51 and 90 percent. Such adhesive compositions may further contain wax or a primary linear polymeric alcohol. When combined with an elastomer and tackifier, such adhesives are repulpable and thus have particular applicability when used in combination with recyclable paper.
    Type: Grant
    Filed: February 16, 1993
    Date of Patent: August 15, 1995
    Assignee: Petrolite Corporation
    Inventors: Susan M. Teeters, Charles H. Heroux, Michael D. Watson, William P. Cottom, Terrance D. Duryee
  • Patent number: 5432217
    Abstract: A stable composition and process for cleaning, protecting, preserving, and renewing surfaces, especially rubber and other polymers is disclosed. The treatment chemical is formulated to clean, protect, renew and preserve the polymer surface being treated. The inclusion of an alkanolamine selected from the group consisting of mono-ethanolamine, di-ethanolamine, tri-ethanolamine, mono-isopropanolamine, di-isopropanolamine and tri-isopropanolamine which causes provide outstanding detergency to the formulation without adversely affecting the emulsion stability. Each component contributes to the performance of the composition and facilitates the proper deposition of treatment chemical.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: July 11, 1995
    Assignee: Siltech Inc
    Inventor: Anthony J. O'Lenick
  • Patent number: 5426142
    Abstract: The present invention relates to the preparation of aqueous based polymers bearing reactive functional groups. More particularly, this invention relates to waterborne or water dispersed polymers that are equivalent in performance in applications formerly dominated by solvent based polymers.Polymers of the present invention have many uses including adhesives, saturant applications, solutions or dispersions in water or water-cosolvent mixtures, and are most useful as coatings and sealants for wood, glass, metal, concrete and binders for mortars and non-wovens.More specifically, surface coatings produced from polymers of the present invention exhibit improved properties such as: for example, durability, toughness, solvent resistance, dirt pickup resistance, print and block resistance and mar resistance.
    Type: Grant
    Filed: August 25, 1993
    Date of Patent: June 20, 1995
    Assignee: Rohm and Haas Company
    Inventors: William J. Rosano, Frederick J. Schindler
  • Patent number: 5424122
    Abstract: The invention relates to a neutral nonionic latex comprising:(a) about 5 to about 70 weight percent of a nonionic polymer comprising polymerized free-radically polymerizable nonionic monomer, based upon the total weight of the neutral nonionic latex, wherein the free radically polymerizable nonionic monomer comprises:(i) about 90 to about 99 percent by weight of nonionic alkyl acrylate monomer; and(ii) about 1 to about 10 percent by weight of nonionic amide monomer; wherein the weight percentages of (i) and (ii) are based upon the total weight of (i) plus (ii);(b) about 30 to about 95 weight percent of an aqueous phase, based upon the total weight of the neutral nonionic latex; and(c) about 2 to about 10 weight percent of a nonionic emulsifier based upon the total weight of the nonionic polymer plus the nonionic emulsifier;wherein particles of the nonionic polymer are stabilized by the nonionic emulsifier and dispersed within the aqueous phase.
    Type: Grant
    Filed: December 9, 1991
    Date of Patent: June 13, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Michael D. Crandall, Robert L. Nelson
  • Patent number: 5424351
    Abstract: An antistatic agent imparting excellent antistatic property to the polyacetal resins and the polyacetal resins using this antistatic agent. The antistatic agent for polyacetal resins is obtained by including polyalkylene polyols or metal salt-dissolved polyalkylene polyols in a basic carbonate of metals consisting chiefly of alkali metals and aluminum having a porous volume of 0.5 cc/g or larger over a region of meso pores to quasi-macro pores of porous radii of from 200 to 1000 angstroms or in an anion exchanger thereof, said porous volume being greater than 30% of the whole porous volume, and a polyacetal resin composition in which said antistatic agent is blended. The antistatic agent of the invention imparts stable antistatic properties to the above resins and is little dependent upon the environment, and further does not lose thermal property or mechanical strength that occurred with the conventional antistatic agents.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: June 13, 1995
    Assignees: Mizusawa Industrial Chemicals, Ltd., Polyplastics Corporation Ltd.
    Inventors: Yoshinobu Komatsu, Hiroshi Igarashi, Takahisa Erami
  • Patent number: 5415893
    Abstract: The invention relates to a dispersion of electrically conductive particles, comprising a binder and an electrically conductive polymer, and a stabiliser in a dispersing medium. The dispersion according to the invention is characterised in that the particles contain a non-ionic stabiliser. It has been found that the stability of the dispersion according to the invention is very good. In addition the dispersion according to the invention is extremely suitable for providing objects with a coating in a simple manner. The applied coating has good electrically conductive properties as well as good coating properties. The applied coating is homogeneously distributed over the coated object. Moreover the applied coating appears to adhere well to the object.
    Type: Grant
    Filed: September 23, 1993
    Date of Patent: May 16, 1995
    Inventors: Aaltie E. Wiersma, Lucia M. A. van de Steeg
  • Patent number: 5405888
    Abstract: A photocurable and moisture-curable silione composition comprising a reactive organosilane which has acryldialkoxysilyl or acryldiallyloxysilyl groups at both ends, a silicone oil, a photosensitizer and a moisture-curing catalyst.
    Type: Grant
    Filed: December 28, 1993
    Date of Patent: April 11, 1995
    Assignee: Three Bond Co, Ltd.
    Inventor: Toru Takeoka
  • Patent number: 5399604
    Abstract: An epoxy group-containing thermosetting resin composition comprising (A) a copolymer obtained from (a) at least one member selected from an unsaturated carboxylic acid and an unsaturated carboxylic acid anhydride, (b) an epoxy group-containing unsaturated compound, (c) a monoolefin unsaturated compound, and optionally (d) a conjugated diolefin unsaturated compound, and (B) an organic solvent for dissolving the above copolymer. There is also provided another epoxy-group containing thermosetting resin composition which contains the above component (A), (C) a polymerizable compound having at least one ethylenically unsaturated double bond, and (D) a photopolymerization initiator. These epoxy-group containing thermosetting resin compositions are excellent in storage stability.
    Type: Grant
    Filed: July 21, 1993
    Date of Patent: March 21, 1995
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Kimiyasu Sano, Masayuki Endo, Atsufumi Shimada, Yasuaki Yokoyama, Nobuo Bessho
  • Patent number: 5382605
    Abstract: A thermoplastic molding composition resistant to the degradation induced by ionizing-radiation is disclosed. The composition contains an aromatic polycondensate and an agent which is a compound conforming structurally to formula (I) ##STR1## or which is a member selected from the group consisting of oligocarbonate, polycarbonate, copolycarbonate, polyestercarbonate and polyesters which contain structural units conforming to formula (Ia) ##STR2## wherein R.sup.1 to R.sup.10 and X are defined. The composition is suitable for the manufacture of shaped articles, especially articles useful in medical applications.
    Type: Grant
    Filed: February 15, 1994
    Date of Patent: January 17, 1995
    Assignees: Miles Inc., Bayer Aktiengesellschaft
    Inventors: Douglas G. Powell, Charles E. Lundy, Gerhard Fennhoff, Ralf Hufen, Klaus Kircher
  • Patent number: 5380597
    Abstract: Plasticized polyvinyl acetal resins based on 4-hydroxybutanal are disclosed. Laminar structures that include the resins, a process for making the resins, and a process for making an internally plasticized polyvinyl acetal resin by esterification, are also revealed.
    Type: Grant
    Filed: May 3, 1994
    Date of Patent: January 10, 1995
    Assignee: Arco Chemical Technology L.P.
    Inventors: Jeffrey A. Klang, Michael J. Cannarsa, Frank J. Liotta, Jr., Scott E. Smyth
  • Patent number: 5374679
    Abstract: A sizing agent for paper, which comprises 100 parts by weight of a polyvinyl alcohol (component A) and from 1 to 20 parts by weight of a compound (component B provided with the following requisites (1) to (4):(1) the backbone chain is a random copolymer of ethylene oxide and propylene oxide, (2) in the backbone chain, the proportion of oxyethylene units is from 20 to 40% by weight, and the proportion of oxypropylene units is from 60 to 80% by weight, (3) of the two terminals, one terminal is a hydroxyl group, and the other terminal is a C.sub.1-10 alkoxyl group or a hydroxyl group, and (4) the weight average molecular weight is from 600 to 1,200.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: December 20, 1994
    Assignees: Denki Kagaku Kogyo Kabushiki Kaisha, Nippon Paper Industries Co., Ltd.
    Inventors: Yoshihumi Nosaka, Osamu Ishiguro
  • Patent number: 5360851
    Abstract: Aqueous silicone dispersions crosslinkable into elastomeric state on removal of water therefrom under ambient conditions, well adapted, e.g., for the production of elastomeric silicone seals in the construction industry, include an oil-in-water base emulsion (A) of an .alpha.,.omega.-(dihydroxy)polydiorganosiloxane stabilized with at least one anionic or nonionic surface-active agent, or mixture thereof, (B) an aqueous latex of an organic (co)polymer having a particle size ranging from 0.01 to 0.5 .mu.m and a solids content ranging from 20% to 70% by weight, (C) an effective crosslinking amount of at least one crosslinking agent, (D) an effective amount of at least one nonsiliceous filler material, and (E), optionally, a catalytically effective amount of a metal curing catalyst, such aqueous dispersions further having a solids content of at least 40% by weight.
    Type: Grant
    Filed: June 18, 1990
    Date of Patent: November 1, 1994
    Assignee: Rhone-Poulenc Chimie
    Inventors: Michel Feder, Jean-Pierre Jaubert, Jean-Marie Pouchol
  • Patent number: 5358988
    Abstract: Described are water-in-oil emulsions containing an emulsion polymerizate which is soluble in or swells in water and an oil phase, consisting at least partly of monoether compounds, that is not miscible with water in all proportions. Also described are a method of preparing such emulsions and their use as agents for precipitation, sedimentation, and/or thickening.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: October 25, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ludwig Schieferstein, Herbert Fischer, Hermann Kroke, Brigitte Spei, Volker Wehle, Rainer Jeschke, Uwe Ploog
  • Patent number: 5332774
    Abstract: Plasticized polyvinyl acetal resins based on 4-hydroxybutanal are disclosed. Laminar structures that include the resins, a process for making the resins, and a process for making an internally plasticized polyvinyl acetal resin by esterification, are also revealed.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: July 26, 1994
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Jeffrey A. Klang, Michael J. Cannarsa, Frank J. Liotta, Jr., Scott E. Smyth
  • Patent number: 5331034
    Abstract: In plastic molding compositions, in particular those based on olefin polymers, which contain phenolic stabilizers and metal ions as catalyst residues, the discoloration at the processing temperature is reduced if they contain triglycerol or ditrimethylolpropane as catalyst deactivators.
    Type: Grant
    Filed: November 13, 1991
    Date of Patent: July 19, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gerhard Pfahler, Georg Schmailzl
  • Patent number: 5321054
    Abstract: Compositions, with controlled and programmed hardening, to record mucodynamic dental impressions, characterized in that they comprise:______________________________________ Polyvinyl acetate (PVAc) 50-85% by weight C.sub.3 to C.sub.6 aliphatic ketones 2-25% by weight C.sub.3 to C.sub.8 aliphatic esters 1-25% by weight C.sub.2 to C.sub.10 aliphatic alcohols 1-25% by weight and/or aliphatic ethers Non-toxic, non-aromatic 0.5-10% by weight plasticizing oils selected from the group consisting of dioctyl adipate, glycerol triacetate and polyglycols Non-toxic and non-extractable 0-2% by weight black, yellow, red or white organic pigments or a combination thereof ______________________________________and is free of any gel-forming components, peroxide-based catalysts, aromatic compounds and incompatible plasticizers.
    Type: Grant
    Filed: September 18, 1992
    Date of Patent: June 14, 1994
    Inventor: Giovanni Pasini
  • Patent number: 5318841
    Abstract: An adhesive tape is disclosed. The adhesive tape comprises a high surface energy polyolefin film in combination with a water-dispersed adhesive. The polyolefin is prepared by blending from about 99.5% to about 90.0% by weight of a polymeric material with from about 0.5% to about 10.0% by weight of an amphiphile having the formula:RA(CHR.sup.2 [CH.sub.2 ].sub.n A.sup.1).sub.m R.sup.1where R and R.sup.1 are selected from the group consisting of the alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of an aliphatic or aliphatic/aromatic mono-acid with a molecular weight of from about 200 to about 500 daltons, A and A.sup.1 are selected from the group consisting of O, --NR.sup.3 --, carboxyl and S, R.sup.2 and R.sup.3 are selected from the group consisting of H, CH.sub.3 and C.sub.2 H.sub.5, n is from 0 to 3 and m is from 2 to 20.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: June 7, 1994
    Assignee: Arizona Chemical Company
    Inventors: Eric S. Gardiner, Dale L. Haner
  • Patent number: 5306756
    Abstract: Method for patterning organic polymer layers comprising the sequential steps:A. Applying to a substrate an unpatterned layer of acidic polymer dissolved in a plasticizer,B. Applying to the unpatterned layer a second patterned layer which is a liquid solution of organic base dissolved in a volatile solvent;C. Heating the patterned layer to effect removal of the volatile solvent from the layer and diffusion of the second layer plasticizer and organic base into the underlying areas of the acidic polymer layer; andD. Washing the layers with aqueous solution to effect solubilization of the acidic polymer underlying the patterned areas and removal therefrom of the solubilized polymer and plasticizers.
    Type: Grant
    Filed: November 18, 1992
    Date of Patent: April 26, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: John J. Felten, Sheau-Hwa Ma
  • Patent number: 5292861
    Abstract: Trisphenol PA tricyanate, prepolymers and crosslinked polymers thereof are provided. Blends of trifunctional cyanates and fluorinated or non-fluorinated difunctional cyanate are provided. The crosslinked polymers exhibit low dielectric loss properties and high glass transition temperatures and are suitable as the matrix material for structural composites including printed circuit boards.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: March 8, 1994
    Assignee: International Business Machines Corporation
    Inventor: Konstantinos I. Papathomas
  • Patent number: 5284895
    Abstract: This invention provides a unique formulation for a user-safe pneumatic tire sealer and inflator which is non-flammable, non-toxic, ozone-friendly, and environmentally safe. Modifications are possible within the scope of this invention.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: February 8, 1994
    Inventor: Pradeep Y. Gupta