Organic Chalcogen Other Than Oxygen As Dnrm Patents (Class 524/392)
  • Patent number: 6803166
    Abstract: A process comprising heating a latex and a colorant, and optionally a wax, and wherein the latex contains a polymer with a Mz value of from about 60,000 to about 150,000.
    Type: Grant
    Filed: February 18, 2003
    Date of Patent: October 12, 2004
    Assignee: Xerox Corporation
    Inventors: Chieh-Min Cheng, Emily L. Moore, Amy A. Albright, Tie Hwee Ng
  • Patent number: 6797755
    Abstract: Elastomers which have excellent stability to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation comprise, as stabilizers, at least one compound of the formula (I): [R—S(═O)m—CH2—CH(OH)—CH2]n—N(R1)2−n—R2, in which R is C4-C20alkyl, hydroxyl-substituted C4-C20alkyl; phenyl, benzyl, &agr;-methylbenzyl, &agr;,&agr;-dimethylbenzyl, cyclohexyl or —(CH2)qCOOR3, and, if m is 0, R may additionally be (a); and, if n is 1 and R4 is hydrogen, R may additionally be R2—R1N—CH2—CH(OH)—CH2—S(═O)m—(CH2)x— or R2—R1N—CH2—CH(OH)—CH2—S(═O)m—CH2—CH2—(OCH2—CH2)y—, R1 is hydrogen, cyclohexyl or C3-C12alkyl, R2 is (b), R3 is C1-C18alkyl, R4 is hydrogen or —CH2—CH(OH)—CH2—S(═O)m—R, X is C1-C8alkyl, Y is C1-C8alkyl, m is 0 or 1, n is 1 or 2, q is 1 or 2, x is from 2 to 6, and y is 1 or 2.
    Type: Grant
    Filed: April 15, 2002
    Date of Patent: September 28, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hans-Rudolf Meier, Gerrit Knobloch, Samuel Evans
  • Patent number: 6794454
    Abstract: Disclosed is a rubber composition for forming a core of a solid golf ball, the composition containing a base rubber (A); a filler (B); an organic peroxide (C); and a dry blend and/or a solvent slurry blend (D) of an unsaturated carboxylic acid metallic salt and a metal-containing organic sulfur compound represented by the following formula (1): (wherein X represents a halogen atom, each of m and n represents an integer of 0 to 5 inclusive, and M represents a divalent metallic atom). The rubber composition exhibits high curing rate, and can be cured within shorter time, whereby productivity of a core can be improved.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: September 21, 2004
    Assignee: Bridgestone Sports Co., Ltd.
    Inventor: Nobuyuki Kataoka
  • Patent number: 6790892
    Abstract: Halogen-containing polymer compositions comprising a latent mercaptan-containing heat stabilizer composition substantially free from the offensive odor typically associated with mercaptans are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan may be the sole heat stabilizer additive but the free mercaptan released during processing may also synergize the activity of metal-based heat stabilizers such as metal salts and organometallic stabilizers such as organotin carboxylates and mercaptides in the polymer composition. The odor of primary mercaptan-containing heat stabilizers in halogenated polymer compositions is masked by a small amount of a latent mercaptan.
    Type: Grant
    Filed: August 4, 1999
    Date of Patent: September 14, 2004
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Paul B. Adams, Gene K. Norris
  • Patent number: 6787609
    Abstract: The present invention provides a solid golf ball which imparts a superior shot feeling to the golfer and exhibits stabilized repulsion performance when it is hit at any head speed. The solid golf ball of the present invention comprises a core containing at least one layer which is molded by vulcanizing the rubber composition including: (a) a base rubber, (b) a co-crosslinking agent, (c) an organic peroxide, and (d) a bromine-substituted thiophenol compound represented by the formula, or a monovalent or divalent metal salt thereof: (wherein at least one of R1 to R5 is Br).
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: September 7, 2004
    Assignee: Sumitomo Rubber Industries Limited
    Inventors: Seigou Sakagami, Satoshi Mano
  • Publication number: 20040162373
    Abstract: A process comprising heating a latex and a colorant, and optionally a wax, and wherein the latex contains a polymer with a Mz value of from about 60,000 to about 150,000
    Type: Application
    Filed: February 18, 2003
    Publication date: August 19, 2004
    Applicant: Xerox Corporation
    Inventors: Chieh-Min Cheng, Emily L. Moore, Amy A. Albright, Tie Hwee Ng
  • Patent number: 6777467
    Abstract: Halogen-containing polymer compositions comprising a latent mercaptan-containing heat stabilizer composition substantially free from the offensive odor typically associated with mercaptans are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan may be the sole heat stabilizer additive but the free mercaptan released during processing may also synergize the activity of metal-based heat stabilizers such as metal salts and organometallic stabilizers such as organotin carboxylates and mercaptides in the polymer composition. The odor of primary mercaptan-containing heat stabilizers in halogenated polymer compositions is masked by a small amount of a latent mercaptan.
    Type: Grant
    Filed: April 22, 2003
    Date of Patent: August 17, 2004
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Paul B. Adams, Gene K. Norris
  • Patent number: 6762231
    Abstract: Aromatic and aliphatic organic thiol compounds are disclosed which can be utilized to plasticize and/or stabilize halogen-containing polymer compositions, especially poly(vinyl chloride) compositions. Compounds of the present invention are utilized in polymers normally susceptible to deterioration and color change, which typically occurs during processing of the polymer or exposure to certain environments.
    Type: Grant
    Filed: June 19, 2001
    Date of Patent: July 13, 2004
    Assignee: The College of William and Mary
    Inventors: William Herbert Starnes, Jr., Bin Du
  • Patent number: 6753374
    Abstract: A rubber composition is disclosed wherein the rubber composition contains at least (a) a rubber component; (b) a silica filler; and, (c) at least one thiuram disulfide accelerator, it being provided that diphenyl guanidine is substantially absent in the rubber composition. The compositions may also include suitable amounts of other ingredients such as carbon black, coupling agents, antiozonants, antioxidants, etc.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: June 22, 2004
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Martin J. Hannon, Robert J. Cornell, Sung W. Hong
  • Patent number: 6747081
    Abstract: Organic thiol compounds including aromatic, aliphatic, and diester ether compounds containing sulfhydryl groups are disclosed which can be utilized to plasticize and/or stabilize halogen-containing polymer compositions, especially poly(vinyl chloride) compositions. Compounds of the present invention are utilized in polymers normally susceptible to deterioration and color change, which typically occurs during processing of the polymer or exposure to certain environments.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: June 8, 2004
    Assignee: The College of William and Mary
    Inventor: William Herbert Starnes, Jr.
  • Patent number: 6743840
    Abstract: Halogen-containing polymer compositions comprising a latent mercaptan-containing heat stabilizer composition substantially free from the offensive odor typically associated with mercaptans are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan may be the sole heat stabilizer additive but the free mercaptan released during processing may also synergize the activity of metal-based heat stabilizers such as metal salts and organometallic stabilizers such as organotin carboxylates and mercaptides in the polymer composition. The odor of primary mercaptan-containing heat stabilizers in halogenated polymer compositions is masked by a small amount of a latent mercaptan.
    Type: Grant
    Filed: January 16, 1998
    Date of Patent: June 1, 2004
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Paul B. Adams, Gene K. Norris
  • Patent number: 6740709
    Abstract: A resin molding having welding properties, flexibility, and shock impact resistance in a balanced manner. The resin molding has a welded seam, consisting of a resin composition, wherein the resin composition comprises (a) a polyphenylene sulfide resin and (b) an olefin based resin: wherein an amount of the (a) polyphenylene sulfide resin and the (b) olefin based resin is 80 weight % or more of the entire resin composition, and the content of the (b) olefin based resin is 10 to 100 parts by weight relevant to 100 parts by weight of the (a) polyphenylene sulfide resin, and wherein the tensile elongation at break is 20% or more.
    Type: Grant
    Filed: January 31, 2002
    Date of Patent: May 25, 2004
    Assignees: Toyoda Gosei Co., Ltd., Toray Industries Inc.
    Inventors: Satoru Ono, Junji Koizumi, Kuniyoshi Kondo, Michiyoshi Matsumoto, Yoshihiro Yamami, Setsuo Morizane
  • Patent number: 6727304
    Abstract: A metal-containing monomer dissolved mixture comprising a reaction product of an inorganic metal compound with a carboxyl group-containing radical polymerizable monomer, an organic solvent including at least an alcohol-based solvent, and water, wherein the water content is from 0.01 to 30% by weight; a metal-containing resin obtained by copolymerizing the metal-containing monomer (A) in this dissolved mixture with the other radical-polymerizable unsaturated monomer (B); an antifouling paint composition obtained by using this metal-containing resin; and an antifouling paint composition comprising a divalent metal-containing resin (C), a compound (D) of R1—SH (wherein, R1 represents an organic group having 1 to 30 carbon atoms.), and copper oxide (E), are disclosed.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: April 27, 2004
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Mitsunori Sugihara, Yukihiro Ikegami, Kazuhiko Hotta, Toshio Nagasaka, Kunio Iwase
  • Publication number: 20040077753
    Abstract: Flexible and semi-rigid vinyl chloride resin compositions comprising a combination of a latent mercaptan and a zinc salt of oxidized polyethylene (a zinc ionomer) as a heat stabilizer are substantially free from the offensive odor typically associated with mercaptans and are protected during processing by the degradation products of the latent mercaptan and the zinc ionomer. The oxidized polyethylene is split out from the ionomer to act as an adhesion promoter for aqueous inks and paints, and the residual zinc carboxylate functions as a co-stabilizer with the latent mercaptan in the composition. The latent mercaptan is exemplified by a 2-S-(tetrahydropyranyl)thioalkanol., a carboxylic acid ester thereof, a 2-S-(tetrahydropyranyl)thiocarboxylic acid, an ester thereof, and the furanyl homologs of each.
    Type: Application
    Filed: September 4, 2003
    Publication date: April 22, 2004
    Inventors: Tod C. Duvall, Jeffery L. Carpenter
  • Patent number: 6706792
    Abstract: Flexible and semi-rigid vinyl chloride resin compositions comprising a combination of a latent mercaptan and a zinc salt of oxidized polyethylene (a zinc ionomer) as a heat stabilizer are substantially free from the offensive odor typically associated with mercaptans and are protected during processing by the degradation products of the latent mercaptan and the zinc ionomer. The oxidized polyethylene is split out from the ionomer to act as an adhesion promoter for aqueous inks and paints, and the residual zinc carboxylate functions as a co-stabilizer with the latent mercaptan in the composition. The latent mercaptan is exemplified by a 2-S-(tetrahydropyranyl)thioalkanol, a carboxylic acid ester thereof, a 2-S-(tetrahydropyranyl)thiocarboxylic acid, an ester thereof, and the furanyl homologs of each.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: March 16, 2004
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Jefferey L. Carpenter
  • Publication number: 20040034139
    Abstract: The present invention relates to a stabilizer composition, for use in polyvinyl chloride formulations, which comprises a mixture of: at least one organotin sulfide; at least one organotin chloride; and at least one free mercaptan.
    Type: Application
    Filed: May 19, 2003
    Publication date: February 19, 2004
    Inventor: Henry J Barda
  • Publication number: 20040034150
    Abstract: A rubber composition is disclosed wherein the rubber composition contains at least (a) a rubber component; (b) a silica filler; (c) a coupling agent; (d) a cure-enhancing amount of at least one polyalkylene oxide; and (e) at least one high molecular weight thiuram disulfide. The compositions may also include suitable amounts of other ingredients such as carbon black, antiozonants, antioxidants, etc.
    Type: Application
    Filed: August 15, 2003
    Publication date: February 19, 2004
    Applicant: UNIROYAL CHEMICAL COMPANY, INC.
    Inventors: Sung W. Hong, Martin J. Hannon, Peter K. Greene
  • Patent number: 6683135
    Abstract: Disclosed herein is a rubber composition comprising: a) a blocked mercaptosilane of a defined structure, wherein the blocking group contains an unsaturated heteroatom or carbon chemically bound directly to sulfur via a single bond and, optionally, may be substituted with one or more carboxylate ester or carboxylic acid functional groups; b) an organic polymer; c) a filler; and d) a deblocking agent.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: January 27, 2004
    Inventors: Richard W. Cruse, Robert J. Pickwell, Keith J. Weller, Eric R Pohl
  • Publication number: 20040006163
    Abstract: A rubber composition is disclosed wherein the rubber composition contains at least (a) a rubber component; (b) a carbon black filler and (c) an effective amount of a thiuram disulfide accelerator of the general formula 1
    Type: Application
    Filed: June 27, 2002
    Publication date: January 8, 2004
    Applicant: UNIROYAL CHEMICAL COMPANY
    Inventors: Sung W. Hong, Peter K. Greene
  • Publication number: 20040006162
    Abstract: A composition comprising alkylthio- or aryl(heteroyl)thio-substituted p-phenylenediamine, its method of preparation, and its use as an antidegradant in natural or synthetic rubber.
    Type: Application
    Filed: May 20, 2003
    Publication date: January 8, 2004
    Inventors: Otto William Maender, Charles John Rostek, Alan Roy Katritzky, Herman Howard Odens, Michael Victor Voronkov
  • Patent number: 6667357
    Abstract: Organic thiol compounds are disclosed which can be utilized to plasticize and stabilize halogen-containing polymer compositions, especially poly(vinyl chloride) compositions. Compounds of the present invention are utilized in polymers normally susceptible to deterioration and color change, which typically occurs during processing of the polymer or exposure to certain environments.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: December 23, 2003
    Assignee: The College of William and Mary
    Inventors: William Herbert Starnes, Jr., Bin Du
  • Publication number: 20030225195
    Abstract: Disclosed herein is a rubber composition comprising:
    Type: Application
    Filed: February 10, 2003
    Publication date: December 4, 2003
    Applicant: Crompton Corporation
    Inventors: Richard W. Cruse, Robert J. Pickwell, Keith J. Weller, Eric Pohl
  • Patent number: 6653380
    Abstract: The invention relates to a method of enhancing the tear resistance, tensile strength, and the aging properties of a latex product by adding an antioxidant synergist with an antioxidant to a latex compound comprising of a polymer, a stabilizing system, a film surface conditioner and a curing system comprised of an activator, crosslinker and accelerator and to the latex products formed therefrom. Antioxidant synergists which can be used with the present invention include 2-mercaptobenzimidazole (MBI), 2-mercaptotoluimidazole (MTI), zinc 2-mercaptobenzimidazole (ZMBI) and zinc 2-mercaptotoluimidazole (ZMTI). The latex products formed may be gloves but can also include threads, balloons and other latex-related products.
    Type: Grant
    Filed: July 18, 2001
    Date of Patent: November 25, 2003
    Assignee: R. T. Vanderbilt Company, Inc.
    Inventor: Robert Thomas Dzikowicz
  • Publication number: 20030193110
    Abstract: An article of manufacture comprises an ultrahigh molecular weight polyethylene (UHMWPE) mixed with a processing oil and a lubricant selected from the group consisting of fatty acid esters, ethoxylated fatty acid esters, glycol esters, PEG esters, glycerol esters, ethoxylated esters, sorbitol esters, ethoxylated sorbitol esters, aromatic ethoxylates, alcohol ethoxylates, mercaptan ethoxylates, modified ethoxylates, amide surfactants, phosphate esters, phosphonate esters, phosphite esters, alkyl sulfates, fatty acid ethers, alkyl ether sulfates, alkylaryl ether sulfates, sulfonates, naphthalene sulfonates, sulfosuccinates, sulfonated esters, sulfonated amides, alkyl ether carboxylates, alkylaryl ether carboxylates, quaternary amines, amino quaternary amines, ethoxylated amines, imidazoline derivatives, betaines, sultaines, aminopropionate, catechol derivatives, saturated fatty acids, unsaturated fatty acids, and combinations thereof. The method for making those articles is also disclosed.
    Type: Application
    Filed: April 12, 2002
    Publication date: October 16, 2003
    Inventors: Joseph G. Yaritz, J. Kevin Whear
  • Patent number: 6620875
    Abstract: A rubber composition is disclosed wherein the rubber composition contains at least (a) a rubber component; (b) a silica filler; (c) a coupling agent; (d) a cure-enhancing amount of at least one polyalkylene oxide; and (e) at least one high molecular weight thiuram disulfide. The compositions may also include suitable amounts of other ingredients such as carbon black, antiozonants, antioxidants, etc.
    Type: Grant
    Filed: September 4, 2001
    Date of Patent: September 16, 2003
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Sung W. Hong, Martin J. Hannon, Peter K. Greene
  • Patent number: 6620871
    Abstract: Rubber compositions contain, in addition to synthetic or natural rubber and conventional curing agents, an auxiliary composition containing a titanium or zirconium compound. The compositions are characterized by an enhanced cure rate at elevated temperatures such as would be useful for producing molded articles. At the same time the compositions exhibit an increased shelf life whereby uncured compositions of the invention are stable and can be molded for a considerable period of time even after storage at room temperature. Titanium compounds of the invention have at least one alkoxy group bonded to titanium, and zirconium compounds of the invention have at least one alkoxy group bonded to zirconium. In preferred embodiments, the auxiliary composition contains chelates of the titanium or zirconium compound. In particular, the auxiliary composition enhances the rate of cure at elevated temperature, and retards curing at room temperature.
    Type: Grant
    Filed: June 7, 2001
    Date of Patent: September 16, 2003
    Assignee: Nike, Inc.
    Inventor: Thomas Woodrow Wilson, III
  • Patent number: 6610218
    Abstract: Halogen-containing polymer compositions comprising a latent mercaptan-containing heat stabilizer composition substantially free from the offensive odor typically associated with mercaptans are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan may be the sole heat stabilizer additive but the free mercaptan released during processing may also synergize the activity of metal-based heat stabilizers such as metal salts and organometallic stabilizers such as organotin carboxylates and mercaptides in the polymer composition. The odor of primary mercaptan-containing heat stabilizers in halogenated polymer compositions is masked by a small amount of a latent mercaptan.
    Type: Grant
    Filed: August 4, 1999
    Date of Patent: August 26, 2003
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Paul B. Adams, Gene K. Norris
  • Publication number: 20030158311
    Abstract: Halogen-containing polymer compositions containing a heat stabilizer comprising a latent mercaptan, a zinc salt, and a free mercaptan as a separate entity are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan. A free mercaptan is among those products. The separate free mercaptan (i.e., an alien free mercaptan) enhances the activity of the latent mercaptan in a synergistic manner.
    Type: Application
    Filed: December 2, 2002
    Publication date: August 21, 2003
    Inventors: Paul Brian Adams, Gene Kelly Norris
  • Patent number: 6608125
    Abstract: A blocked mercaptosilane of the structure: G—C(═O)—S—CH2CH2CH2SiX3 is disclosed wherein each X is an independently selected RO— group wherein each R is independently selected from the group consisting of hydrogen, alkyl that may or may not contain unsaturation, alkenyl groups, aryl groups, and aralkyl groups, such moieties other than hydrogen having from 1 to 18 carbon atoms, and G is a monovalent alkyl of from 2 to 12 carbon atoms.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: August 19, 2003
    Assignee: Crompton Corporation
    Inventors: Richard W. Cruse, Robert J. Pickwell, Keith J. Weller, Eric R. Pohl
  • Patent number: 6608145
    Abstract: Sulfur-vulcanizable elastomeric compounds and pneumatic tire components having improved tensile mechanical and dynamic viscoelastic properties are produced by compounding polymers with silica at a temperature of 165° C. to about 200° C., in the presence of a silica dispersing agent, and a very small amount (e.g., about 0.01% to about 1% by weight, based on the weight of the silica) of a bis(trialkoxysilylorgano) tetrasulfide silica coupling agent.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: August 19, 2003
    Assignee: Bridgestone Corporation
    Inventors: Chenchy Jeffrey Lin, William L. Hergenrother, Ashley S. Hilton
  • Publication number: 20030153640
    Abstract: The present invention relates to powdered thermosetting compositions including a binder which comprises a carboxyl group containing amorphous isophthalic acid containing polyester, a carboxyl group containing semi-crystalline polyester, at least 10 parts by weight, based on the total weight of the binder, of a specific glycidyl group containing acrylic copolymer and a curing agent having functional groups reactive with the polyesters' carboxyl groups. The powdered thermosetting compositions are useful for the preparation of powdered paints and varnishes which give low gloss coatings having an outstanding flow, a remarkable weatherability and excellent mechanical properties.
    Type: Application
    Filed: November 18, 2002
    Publication date: August 14, 2003
    Inventors: Luc Moens, Nele Knoops, Daniel Maetens
  • Publication number: 20030130396
    Abstract: A golf ball consisting of a core having a diameter of between about 1.54 and about 1.61 inches and a compression of between about 70 and about 80, the core comprising a polybutadiene rubber having a Mooney viscosity of less than about 50 and a halogenated organosulfur compound, or a salt thereof, present in an amount of at least about 2.
    Type: Application
    Filed: December 3, 2002
    Publication date: July 10, 2003
    Inventors: Peter Voorheis, Murali Rajagopalan, Michael D. Jordan, Christopher Cavallaro
  • Patent number: 6586509
    Abstract: A composition for an insulating layer of an electric cable wherein the composition contains an ethylene plastic as the base resin and further contains up to about 5% by weight of additives including antioxidant, and peroxide cross-linking agent. The composition is characterised in that the antioxidant additive includes a compound of the formula (V): R1(—(C+O)O—)k(CH2)1—S—(CH2)m(—OO(C═O)—)nR2 where R1 and R2, which are the same of different, are C7-C23 alkyl, C7-C23 alkenyl, R3—Ar—, Ar—R3—, or AR—, where R3 is C8-C24 alkyl and Ar is c6-c14 aryl; k and n, which are the same of different, are 0 or 1, l and m, which are the same or different, are integers ≧0; with the proviso that the compound is free from phenolic groups; and that the compositions is free from compounds having the formula (VI): R—O—(C═O)—CH2CH2SCH2CH2—(C═O)—O—R where R is a C8-C20 alkyl group.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: July 1, 2003
    Assignee: Borealis Technology Oy
    Inventors: Jan-Ove Bostrƶm, Ruth Dammert, Bill Gustafsson, Annika Smedberg
  • Patent number: 6583229
    Abstract: The present invention provides a solid golf ball having exceptional rebound characteristics and flight performance, as well as good shot feel. The present invention relates to a solid golf ball comprising at least one layer of a core, and at least one layer of a cover formed on the core, wherein at least one of the layers of the core is formed by vulcanizing and press-molding a rubber composition comprising a base rubber, co-crosslinking agent, organic peroxide, filler and specific organic sulfur compound which contains substituent groups having a substituent constant of not less than 1.42.
    Type: Grant
    Filed: May 24, 2001
    Date of Patent: June 24, 2003
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Satoshi Mano, Masatoshi Yokota, Kiyoto Maruoka, Seigou Sakagami, Tetsuo Yamaguchi
  • Publication number: 20030073771
    Abstract: The present invention relates to a process for improving the shelf life of a hindered phenol antioxidant comprising the step of intimately mixing the hindered phenol antioxidant with a sulfur-containing peroxide decomposer. The inventors have discovered that mixing the peroxide decomposer with the hindered phenol antioxidant reduces the tendency of hindered phenols to yellow with age. This increases the desirability of the hindered phenol because it will not impart color to polymer systems. The present invention also relates to a composition produced from the process described above, and stabilized compositions and additive packages containing the composition produced from the above-described process.
    Type: Application
    Filed: April 24, 2002
    Publication date: April 17, 2003
    Inventors: Brent M. Sanders, Darryl R. Kincaid, Sari-Beth Samuels
  • Patent number: 6548707
    Abstract: Halogen-containing polymer compositions comprising a latent mercaptan-containing heat stabilizer composition substantially free from the offensive odor typically associated with mercaptans are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan may be the sole heat stabilizer additive but the free mercaptan released during processing may also synergize the activity of metal-based heat stabilizers such as metal salts and organometallic stabilizers such as organotin carboxylates and mercaptides in the polymer composition. The odor of primary mercaptan-containing heat stabilizers in halogenated polymer compositions is masked by a small amount of a latent mercaptan.
    Type: Grant
    Filed: August 4, 1999
    Date of Patent: April 15, 2003
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Paul B. Adams, Gene K. Norris
  • Patent number: 6537466
    Abstract: Halogen-containing polymer compositions comprising a latent mercaptan-containing heat stabilizer composition substantially free from the offensive odor typically associated with mercaptans are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan may be the sole heat stabilizer additive but the free mercaptan released during processing may also synergize the activity of metal-based heat stabilizers such as metal salts and organometallic stabilizers such as organotin carboxylates and mercaptides in the polymer composition. The odor of primary mercaptan-containing heat stabilizers in halogenated polymer compositions is masked by a small amount of a latent mercaptan.
    Type: Grant
    Filed: August 4, 1999
    Date of Patent: March 25, 2003
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Paul B. Adams, Gene K. Norris
  • Patent number: 6528566
    Abstract: Flexible, semi-rigid, and rigid vinyl chloride polymer compositions comprising a latent mercaptan-containing heat stabilizer are substantially free from the offensive odor typically associated with mercaptans and are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. The free mercaptan thus released enhances the activity of metallic-based heat stabilizers such as zinc carboxylates and organotin carboxylates and mercaptides in the polymer composition. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan is selected from the group consisting of a 2-S-(tetrahydropyranyl)-thioalkanol, a carboxylic acid ester thereof, a 2-S-(tetrahydropyranyl)-thioglycolic acid, and an ester thereof.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: March 4, 2003
    Assignee: Rohm and Haas Company
    Inventors: Tod C. Duvall, Paul B. Adams, Gene K. Norris
  • Patent number: 6528567
    Abstract: An anionic surfactant having a thermal weight loss initiation temperature of at least 250° C. is incorporated with a thermoplastic resin comprising a graft copolymer formed by graft-polymerizing an ethylenically unsaturated monomer onto a rubber trunk polymer obtained by emulsion polymerization using a carboxylic acid-type surfactant. As a result, it is possible to obtain an antistatic resin composition which can be effectively produced on an industrial scale and can provide a shaped product excellent in permanent antistatic property and free from haze or discoloration even when processed under severe processing conditions.
    Type: Grant
    Filed: May 3, 2001
    Date of Patent: March 4, 2003
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shiro Arai, Teruhide Watabe
  • Patent number: 6525141
    Abstract: A rubber composition comprising (A) a base rubber, (B) a metal salt of an unsaturated carboxylic acid and/or a mixture of an unsaturated carboxylic acid and zinc oxide, (C) an organic peroxide, and (D) a non-aromatic mercaptan and/or (E) a dialkyl disulfide whose alkyl has 3-10 carbon atoms is suitable for forming center cores of solid golf balls and wound golf balls and one-piece golf balls by a pressure molding process.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: February 25, 2003
    Assignee: Bridgestone Sports Co., Ltd.
    Inventor: Nobuyuki Kataoka
  • Patent number: 6515057
    Abstract: A method and product which provides a solid, non-powdered homogeneous form to liquid and low melting point solid compounds which facilitates stability, storage, dispersability and handling and which may be added directly to formulations requiring the liquid compound or low melting point solid compound. The liquid or low melting point solid ingredient is combined with a binder which is comprised of at least a wax and thermoplastic polymer. During the method of forming the product, both the binder and the liquid compound (or low melting point solid compound) pass through a liquid phase during which they are mixed. The product is then formed and cooled.
    Type: Grant
    Filed: November 21, 2000
    Date of Patent: February 4, 2003
    Assignee: Rhein Chemie Corporation
    Inventors: Richard D. Cortelezzi, Clifford C. Martin
  • Publication number: 20020183424
    Abstract: Flexible, semi-rigid, and rigid vinyl chloride polymer compositions comprising a latent mercaptan-containing heat stabilizer are substantially free from the offensive odor typically associated with mercaptans and are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. The free mercaptan thus released enhances the activity of metallic-based heat stabilizers such as zinc carboxylates and organotin carboxylates and mercaptides in the polymer composition. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan is selected from the group consisting of a 2-S-(tetrahydropyranyl)-thioalkanol, a carboxylic acid ester thereof, a 2-S-(tetrahydropyranyl)-thioglycolic acid, and an ester thereof.
    Type: Application
    Filed: August 13, 1998
    Publication date: December 5, 2002
    Inventors: TOD C. DUVALL, PAUL B. ADAMS, GENE K. NORRIS
  • Publication number: 20020177643
    Abstract: A flame-retardant composition having anti-electrostatic properties is disclosed. The composition contains (co)polycarbonate, a flame retardant selected from a specifically defined group and a polyalkylene ether compound.
    Type: Application
    Filed: April 12, 2002
    Publication date: November 28, 2002
    Inventors: Martin Dobler, Walter Kohler, Michael Erkelenz, Andreas Seidel, Hugo Obermann
  • Patent number: 6482882
    Abstract: Polymerization process of unsaturated pefluoromonomers, fluoro-containing monomers and optionally in the presence of hydrogen containing olefins, for obtaining polymers contaning hydrogen and fluorine, which utilizes a microemulsion comprising the following components: (a) water; (b) a fluoropolyoxyalkylene having hydrogen-containing end groups and/or hydrogen-containing repeating units; (c) a fluorine-free organic radicalic initiator for the polymerization of fluoro-containing monomers, soluble in component (B); (d) a fluoro-containing surfactant.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: November 19, 2002
    Assignee: Ausimont S.P.A.
    Inventors: Julio A. Abusleme, Alba Chittofrati
  • Patent number: 6462116
    Abstract: The zinc bum experienced during the processing of a composition comprising a halogen-containing polymer and a zinc mercaptoester is eliminated by the addition of an organothio compound selected from dithioglycol, polyformals and polyacetals of said dithioglycol, and a mercaptoalkanol.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: October 8, 2002
    Assignee: Morton International, Inc.
    Inventors: George F. Beekman, Lionel R. Price, Keith A. Mesch
  • Patent number: 6455617
    Abstract: The invention concerns the use, for increasing the durability of moulds made of silicone elastomer crosslinkable by a poly addition or polycondensation reaction, of additive capable of stabilizing the silicone elastomer constituting the mold with respect to materials to be molded, of an additive selected among: (a) antioxidant additives comprising, in their structure additives containing at least one R—Sq—R′ group in which R and R′ are monovalent hydrocarbon groups with at least 3 carbon atoms or a monovalent hydrocarbon group with an ester bond or R and R′ together form a cycle, q being a whole number between 1 and 3 inclusively, (b) additives inhibitors of free radicals capable, in moulding conditions of generating radicals ═N—O; the invention concerns the synergistic combination of (a)+(b), the synergistic combination of (a) and/or (b) with phosphites (c), except for the use of bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate as only additive in a silic
    Type: Grant
    Filed: June 23, 2000
    Date of Patent: September 24, 2002
    Assignee: Rhodia Chimie
    Inventors: Michel Gay, Fabienne Howe, Christian Pusineri, Joƫlle Viennet
  • Publication number: 20020132888
    Abstract: A composition comprising 2-alkylthio- or 2-aryl(heteroyl)thio-substituted p-phenylenediamine, its method of preparation, and its use as an antidegradant in natural or synthetic rubber.
    Type: Application
    Filed: November 20, 2001
    Publication date: September 19, 2002
    Inventors: Otto William Maender, Charles John Rostek, Alan Roy Katritzky, Herman Howard Odens, Michael Victor Voronkov
  • Publication number: 20020128363
    Abstract: Organic thiol compounds are disclosed which can be utilized to plasticize and stabilize halogen-containing polymer compositions, especially poly(vinyl chloride) compositions. Compounds of the present invention are utilized in polymers normally susceptible to deterioration and color change, which typically occurs during processing of the polymer or exposure to certain environments.
    Type: Application
    Filed: December 15, 2000
    Publication date: September 12, 2002
    Applicant: THE COLLEGE OF WILLIAM & MARY
    Inventors: William Herbert Starnes, Bin Du
  • Patent number: 6444724
    Abstract: Composite materials particularly suitable in the dental art as a tooth filling material including a polymer matrix, a metal, metal alloy, metal oxide particulate, or combinations thereof, in the presence or absence of colloidal silica, and a coupling agent to adhere the particulate to the polymer matrix. Adhesion can also be facilitated by cleaning and/or coating the particulates prior to incorporation into the polymer matrix. One or two paste systems of the composition with suitable initiators, accelerators, etc. can be formulated.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: September 3, 2002
    Assignee: BioMat Sciences, Inc.
    Inventors: Ivan Stangel, Thomas Ellis, Erik Kruus, Edward Sacher, Robin Drew, Jingwei Xu
  • Publication number: 20020103277
    Abstract: Compositions comprising halogen-containing polymers such as PVC resins are stabilized against heat by a synergistic combination of a free mercaptan and a metal-based stabilizer and/or a Lewis acid such as zinc chloride.
    Type: Application
    Filed: June 17, 1998
    Publication date: August 1, 2002
    Inventor: TOD C. DUVALL