Transition Metal Atom (atomic No. 21-29, 39-47, 57-79) Patents (Class 524/398)
  • Patent number: 6777479
    Abstract: Polymer composite materials comprising of least one polymer resin and platelet particles from at least one layered silicate material uniformly dispersed in the resin and articles prepared from the polymer composite materials. The polymer composite contains at least one polyamide resin, at least one oxygen scavenging system, and at least one layered silicate material. These polymer composite materials are especially useful for manufacturing clear polyester bottles and polyester film that are recyclable have improved active gas barrier properties to oxygen, and have improved passive barrier properties to carbon dioxide and other gases. The polymer composite materials can be used in relatively minor amounts as either a blend or a coextruded thin layer with virgin or post consumer recycled polyesters and related copolymners.
    Type: Grant
    Filed: August 2, 2000
    Date of Patent: August 17, 2004
    Assignee: Eastman Chemical Company
    Inventors: Linda Gail Bernard, Horst Clauberg, Michael John Cyr, John Walker Gilmer, Jeffrey Todd Owens, Mark Edward Stewart, Sam Richard Turner, Shriram Bagrodia, James Christopher Matayabas, Jr.
  • Patent number: 6762314
    Abstract: An organometallic composition is described which comprises a complex of at least one orthoester of a metal having a formula M(ROAcAc)x(OR′)y in which M is selected from the group consisting of titanium, zirconium and hafnium; ROAcAc denotes an ester of an alochol ROH, in which R comprises an (optionally substituted) C1-30 cyclic, branched or linear, alkyl, alkenyl, aryl or alkyl-aryl group or a mixture thereof, with acetoacetic acid; OR′ is the residue of an alcohol R′OH in which R′ comprises an (optionally substituted) C7-30 cyclic, branched or linear, alkyl, alkenyl, aryl or alkyl-aryl group or a mixture thereof, and x and y are each in the range 1-3. The composition is useful as a curing agent for polyurethanes used in various applications.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: July 13, 2004
    Assignee: Imperial Chemical Industries PLC
    Inventors: Martin G Partridge, Bruno F Stengel, John Ridland
  • Patent number: 6756444
    Abstract: Oxygen scavenging barrier polyamide compositions exhibiting high oxygen scavenging capability as well as good coinjection stretch blow moldability characteristics suitable for making multilayer PET bottles with good clarity and delamination resistance are claimed in this invention. The polyamide compositions of this invention comprise a slow crystallizing polyamide blend comprising (i) an amorphous, semiaromatic polyamide homopolymer, copolymer or mixture thereof and (ii) a semicrystalline, aliphatic polyamide homopolymer, copolymer or mixture thereof wherein in the weight ratio of (i):(ii) ranges from about 99:1 to about 30:70; at least one polyamide-compatible, oxidizable polydiene; and at least one oxidation promoting metal salt catalyst. The multilayer PET bottles, made with the polyamide compositions of this invention as the barrier layer, are suitable for extended shelf-life packaging of oxygen-sensitive food and beverage products such as beer and juices.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: June 29, 2004
    Assignee: Honeywell International Inc.
    Inventors: Murali K. Akkapeddi, Edward P. Socci, Timothy J. Kraft
  • Patent number: 6750280
    Abstract: A thermosetting composition consists essentially of a mixture of (A) a polymer containing acid anhydride groups, (B) a molecular sieve being partially loaded with at least one amine, and (C) a filler capable of releasing water upon heating at a temperature above the processing temperature of the mixture of (A), (B) and (C). The processing temperature is chosen so as to be below the desorption temperature of the amine from the molecular sieve. The composition is particularly useful in making hot melt adhesives and sheetings of electric cables.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: June 15, 2004
    Assignee: Atofina
    Inventors: Thomas Abend, Jean-Michel Pierrot, Patrice Robert
  • Patent number: 6747082
    Abstract: The present invention provides a metal composition for making a conductive film and a metal composition for making an electron emission element. The metal composition includes a vinylpyrrolidone-acrylic acid copolymer represented by formula (I).
    Type: Grant
    Filed: June 17, 2003
    Date of Patent: June 8, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuko Tomida, Taku Shimoda
  • Patent number: 6740698
    Abstract: Oxygen barrier polyamide compositions exhibiting high oxygen scavenging capability suitable for extended shelf-life packaging applications. Thus a polyamide composition comprises a polyamide homopolymer, copolymer, or blends thereof, and at least one polyamide reactive, oxidizable polydiene or oxidizable polyether. The polyamide products are particularly suited to making barrier packaging articles such as monolayer or multi-layer films, sheets, thermoformed containers and coinjection/coextrusion blow molded bottles comprising PET, polyolefin or polycarbonate as structural layers. Such articles are useful in a variety of oxygen-sensitive food, beverage, pharmaceutical and health care product packaging applications.
    Type: Grant
    Filed: October 4, 2001
    Date of Patent: May 25, 2004
    Assignee: Honeywell International Inc.
    Inventors: Murali K. Akkapeddi, Timothy J. Kraft, Edward P. Socci
  • Publication number: 20040087690
    Abstract: Photoacid generator salts comprising photoactive cationic moieties and segmented, highly fluorinated-hydrocarbon anionic moieties are disclosed which provide high photoacid strength and can be tailored for solubility and polarity. The present invention further relates to photoacid generators as they are used in photoinitiated acid-catalyzed processes for uses such as photoresists for microlithography and photopolymerization.
    Type: Application
    Filed: November 1, 2002
    Publication date: May 6, 2004
    Applicant: 3M Innovative Properties Company
    Inventors: William M. Lamanna, Gregory D. Clark, Richard M. Flynn, Zai-Ming Qiu
  • Publication number: 20040058178
    Abstract: Herein is disclosed a modified ethylene vinyl alcohol polymer (EVOH) comprising an oxygen scavenging functional group.
    Type: Application
    Filed: June 19, 2003
    Publication date: March 25, 2004
    Applicant: Chevron Phillips Chemical Company LP.
    Inventors: Hu Yang, Ta Yen Ching, Gangfeng Cai
  • Publication number: 20040014862
    Abstract: A process for solubilizing an organometallic compound in a fluorinated solvent to form an organometallic solution by adding and reacting a co-solubilizer having a fully fluorinated polymer, an organometallic compound, and a fluorinated solvent, and the co-solubilizer has the ability to cause the organometallic compound to become miscible in a fluorinated solvent, and further, the co-solubilizer is not a catalyst and is present in the final organometallic solution.
    Type: Application
    Filed: July 18, 2002
    Publication date: January 22, 2004
    Applicant: Xerox Corporation
    Inventors: David J. Gervasi, Santokh S. Badesha, George J. Bingham
  • Patent number: 6675851
    Abstract: The present invention relates to a rubber-based product, having at least one buffer zone to trap oxygen external to said product in order to protect at least one sensitive zone of said product from oxidation, said buffer zone comprising a composition containing at least one elastomer and at least one iron (III) salt selected from iron (III) acetylacetonate and an iron (III) salt of a carboxylic acid having the formula Fe(CnH2nO2)3 in which n is between 13 and 23. This product is produced by incorporating, by mechanical working, said iron (III) salt into the composition in order to obtain said buffer zone. The buffer zone composition is advantageously used in a tire and imparts improved rolling resistance.
    Type: Grant
    Filed: May 9, 2000
    Date of Patent: January 13, 2004
    Assignee: Michelin & Cie
    Inventors: Francois Masson, Francis Renault
  • Patent number: 6664320
    Abstract: Herein are disclosed metal oleate, especially cobalt oleate, masterbatch compositions useful in preparing oxygen scavenging packaging articles, as well as methods of making the masterbatch compositions. In one embodiment, the masterbatch comprises porous beads comprising a first polymer; the metal oleate dispersed in the porous beads; and a second polymer a photoinitiator, in powder form, dispersed on the exteriors of the porous beads. In another embodiment, the masterbatch comprises a metal oleate and a polymer, wherein the metal oleate is in the form of pellets or, a powder, and the polymer is in thug form of a powder dispersed on the exteriors of the pellets or powder. In yet another embodiment, the masterbatch comprises a metal oleate and a polymer, wherein the metal oleate and the polymer are compounded.
    Type: Grant
    Filed: February 22, 2000
    Date of Patent: December 16, 2003
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Gangfeng Cai, Ta Yen Ching, Brad D. Rodgers
  • Patent number: 6653381
    Abstract: Novel compounds derived from traditional semi- drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10 ° C. and cure to above ambient glass transition (Tg polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: November 25, 2003
    Assignee: University of Southern Mississippi
    Inventors: Shelby Freland Thames, Kamlesh Gopichand Panjnani, Rajan Hariharan, Zhiyu Wang
  • Publication number: 20030216532
    Abstract: The present invention provides a metal composition for making a conductive film and a metal composition for making an electron emission element. The metal composition includes a vinylpyrrolidone-acrylic acid copolymer represented by formula (I).
    Type: Application
    Filed: June 17, 2003
    Publication date: November 20, 2003
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Yasuko Tomida, Taku Shimoda
  • Patent number: 6624221
    Abstract: A resin composition comprising, in admixture, (A) a specific thermoplastic resin component, (B) at least one wax component selected from among (b-1) a fatty acid having 20-80 carbon atoms and/or a derivative thereof and (b-2) an oxidized natural wax and/or derivative having a neutralization value of 60-190 mg KOH/g, and optionally, (C) a basic inorganic metal compound capable of neutralizing acid groups in the thermoplastic resin component (A) and/or the wax component (B) is improved in flow, moldability and heat resistance and thus suitable to form a layer of a golf ball which exhibits improved rebound and distance properties.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: September 23, 2003
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Rinya Takesue, Yasushi Ichikawa
  • Patent number: 6624223
    Abstract: Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: September 23, 2003
    Assignee: University of Southern Mississippi
    Inventors: Shelby Freland Thames, Zhiyu Wang, Elizabeth H. Brister, Rajan Hariharan, Corey L. King, Kamlesh Gopichand Panjnani
  • Patent number: 6620871
    Abstract: Rubber compositions contain, in addition to synthetic or natural rubber and conventional curing agents, an auxiliary composition containing a titanium or zirconium compound. The compositions are characterized by an enhanced cure rate at elevated temperatures such as would be useful for producing molded articles. At the same time the compositions exhibit an increased shelf life whereby uncured compositions of the invention are stable and can be molded for a considerable period of time even after storage at room temperature. Titanium compounds of the invention have at least one alkoxy group bonded to titanium, and zirconium compounds of the invention have at least one alkoxy group bonded to zirconium. In preferred embodiments, the auxiliary composition contains chelates of the titanium or zirconium compound. In particular, the auxiliary composition enhances the rate of cure at elevated temperature, and retards curing at room temperature.
    Type: Grant
    Filed: June 7, 2001
    Date of Patent: September 16, 2003
    Assignee: Nike, Inc.
    Inventor: Thomas Woodrow Wilson, III
  • Patent number: 6617006
    Abstract: A biaxially oriented polyester film to be laminated on a metal plate and molded, which comprises an aromatic polyester composition comprising: (A) an aromatic polyester which comprises ethylene terephthalate as the main recurring unit and a titanium compound and a phosphorus compound both of which satisfy at least one of the following expressions (1) and (2): 0.1≦Ti/P≦3.0  (1) 5≦Ti+P≦60  (2) wherein Ti is the amount (mmol %) of elemental titanium of the titanium compound contained in this aromatic polyester and P is the amount (mmol %) of elemental phosphorus of the phosphorus compound contained in the aromatic polyester, and the following expression (3): 2≦Ti≦20  (3) wherein Ti is as defined hereinabove, and which contains alkali metal compounds, germanium compound and antimony compound in a total amount of not more than 3 ppm in terms of the total of elemental alkali metals, elemental germanium and elemental antimony; and (B) 0.05 to 5.
    Type: Grant
    Filed: September 7, 2001
    Date of Patent: September 9, 2003
    Assignee: Teijin Limited
    Inventors: Koji Kubo, Masahiko Kosuge, Shunsuke Kubota, Kinji Hasegawa, Nobuo Minobe, Kimihiko Sato
  • Publication number: 20030166753
    Abstract: A carbon monoxide modified ethylene-vinyl acetate copolymer composition is disclosed, having diminished tendency to cause discoloration on heating at 177° C. of a plastic composition whose major polymeric component is polyvinyl chloride, comprising carbon monoxide modified ethylene-vinyl acetate copolymer and an amount, effective in diminishing discoloration, of at least one inorganic perchlorate salt selected from the group consisting of alkali metal perchlorates and alkaline earth metal perchlorates.
    Type: Application
    Filed: January 14, 2002
    Publication date: September 4, 2003
    Applicant: CROMPTON CORPORATION
    Inventors: Kook Jin Bae, Stuart D. Brilliant, Johannes Kaufhold
  • Patent number: 6610772
    Abstract: The present invention relates to oxygen scavenging compositions comprising a) platelet particles having attached thereto at least one oxygen scavenging organic cation and b) at least one oxidation catalyst. The oxygen scavenging compositions of the present invention maybe readily incorporated into a variety of matrix polymers to create polymer composites, which display improved passive barrier and oxygen scavenging capabilities. Articles formed from these composites are also disclosed.
    Type: Grant
    Filed: August 2, 2000
    Date of Patent: August 26, 2003
    Assignee: Eastman Chemical Company
    Inventors: Horst Clauberg, Michael John Cyr, Robert Boyd Barbee, Tony Wayne Helton
  • Publication number: 20030153661
    Abstract: An aluminum hydroxide composition is disclosed, having diminished tendency to cause discoloration on heating at 177° C. of a plastic composition whose major polymeric component is polyvinyl chloride, comprising aluminum hydroxide and an amount, effective in diminishing discoloration, of at least one inorganic perchlorate salt selected from the group consisting of alkali metal perchlorates and alkaline earth metal perchlorates.
    Type: Application
    Filed: January 4, 2002
    Publication date: August 14, 2003
    Applicant: CROMPTON CORPORATION
    Inventors: Kook Jin Bae, Stuart D. Brilliant
  • Publication number: 20030149151
    Abstract: A coating composition for the linerboard of corrugated paperboard provides water and grease resistance but is water vapor permeable, and thus permits a different mode of manufacture of corrugated paperboard when aqueous adhesives are employed in the assembly of the linerboards and corrugated medium; in particular the linerboards may be coated with the coating composition prior to assembly of the corrugated paperboard because the water vapor permeable coating permits escape of the water of the aqueous adhesive, during drying of the assembled components of the corrugated paperboard; the coating composition employs a styrene-acrylate copolymer and a C14-C18 fatty acid complex of a metal ion having an oxidation state of at least 3, such as chromium.
    Type: Application
    Filed: January 27, 2003
    Publication date: August 7, 2003
    Applicant: Le Groupe Recherche I.D. Inc.
    Inventor: Serge Berube
  • Patent number: 6599972
    Abstract: Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated derivatives of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of fatty alcohols. A process for the synthesis of the latex composition is also disclosed, which involves (a) polymerization of the ethylenically unsaturated derivatives of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C.
    Type: Grant
    Filed: January 12, 2001
    Date of Patent: July 29, 2003
    Assignee: University of Southern Mississippi
    Inventors: Shelby Freland Thames, Kamlesh Gopichand Panjnani, Olan Stanley Fruchey
  • Patent number: 6583206
    Abstract: Compounds of and compositions comprising specific salts of saturated [2.2.2] dicarboxylate in order to provide highly desirable properties within thermoplastic (e.g., polyolefin) articles are provided. The inventive salts and derivatives thereof are useful as nucleating and/or clarifying agents for such thermoplastics, are easy to produce and handle, and relatively inexpensive to manufacture. Such compounds induce high peak crystallization and improved stiffness within thermoplastics. Also, thermoplastic compositions comprising such novel nucleating agents exhibit improved heat distortion properties and clarity levels in comparison with the closest unsaturated salt nucleating agents. Thermoplastic additive compositions and methods of producing thermoplastics with such compounds are also contemplated within this invention.
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: June 24, 2003
    Assignee: Milliken & Company
    Inventor: Xiaodong Edward Zhao
  • Patent number: 6579356
    Abstract: One aspect of the invention relates to a brown pigment composition with excellent weathering resistance containing iron oxide, chromium oxide, and one or more alumina and/or silica components. Another aspect of the invention relates to a method of making a brown pigment involving combining iron oxide, chromium oxide, and one or more alumina and/or silica components to form a mixture and heating the mixture to provide brown pigment particles. Yet another aspect of the invention relates to a plastic composition containing a major amount of a plastic material and a minor amount of a brown pigment composition containing iron oxide, chromium oxide, and one or more alumina and/or silica components.
    Type: Grant
    Filed: July 17, 2001
    Date of Patent: June 17, 2003
    Assignee: Engelhard Corporation
    Inventors: William Gerald Loucka, Mark Edward Gall, John Gilbert Richardson
  • Patent number: 6573319
    Abstract: Methods of preparing polyolefin-based molded materials with improved adhesive/coating compatibility by incorporating aromatic carboxylic acid amides and transition metal compounds in the polyolefin-based material prior to molding are described. Methods of producing coated or bonded polyolefin-based, molded materials are also described.
    Type: Grant
    Filed: August 15, 2001
    Date of Patent: June 3, 2003
    Assignee: Cognis Deütschland GmbH
    Inventors: Paul Birnbrich, Joerg-Dieter Klamann, Rolf Tenhaef
  • Patent number: 6565965
    Abstract: A metal-organic polymer composite structure comprising a microphase-separated structure from a block copolymer composed of two or more polymer chains which are incompatible with each other bonded in an end-to-end manner, wherein one of the polymer phases of said microphase-separated structure selectively contains ultrafine metal particles arranged in a row or rows. A process for producing said metal-organic polymer composite structure, which comprises (i) the step of dissolving “metal ions” and “a block copolymer comprising one or more polymer chains having an affinity for the metal and, bonded thereto in an end-to-end manner, one or more polymer chains having no or little affinity for the metal” in a mixed solvent of “a high-boiling solvent having the ability to reduce the metal ion and having a boiling point of 80 to 200° C.” and “a low-boiling solvent having a boiling point of 10 to 80° C.
    Type: Grant
    Filed: April 21, 2000
    Date of Patent: May 20, 2003
    Assignee: Japan Science and Technology Corporation
    Inventors: Masafumi Harada, Takeji Hashimoto
  • Publication number: 20030087175
    Abstract: This invention related to an intermediate transfer member for electrophotography that includes a substrate; and a polymeric layer on said substrate wherein the polymeric layer comprises an organic titanate and a polymer selected from the group consisting of fluorosilicone, silicone, and a combination thereof.
    Type: Application
    Filed: October 31, 2002
    Publication date: May 8, 2003
    Applicant: Samsung Electronics Co. Ltd.
    Inventors: Charles W. Simpson, Leonard J. Stulc
  • Patent number: 6541556
    Abstract: A coating composition for the linerboard of corrugated paperboard provides water and grease resistance but is water vapor permeable, and thus permits a different mode of manufacture of corrugated paperboard when aqueous adhesives are employed in the assembly of the linerboards and corrugated medium; in particular the linerboards may be coated with the coating composition prior to assembly of the corrugated paperboard because the water vapor permeable coating permits escape of the water of the aqueous adhesive, during drying of the assembled components of the corrugated paperboard; the coating composition employs a styrene-acrylate copolymer and a C14-C18 fatty acid complex of a metal ion having an oxidation state of at least 3, such as chromium.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: April 1, 2003
    Assignee: Le Groupe Recherche I.D. Inc.
    Inventor: Serge Berube
  • Patent number: 6541555
    Abstract: High density, low epsilon ballast materials are disclosed. The materials comprise dielectric ceramic particles in a polymeric matrix. The composite material possesses higher density/dielectric ratios in comparison with conventional ballast materials.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: April 1, 2003
    Assignee: Lockheed Martin Corporation
    Inventor: Kirk T. Roetcisoender
  • Publication number: 20030054093
    Abstract: The present invention provides a metal composition for making a conductive film and a metal composition for making an electron emission element.
    Type: Application
    Filed: April 4, 2002
    Publication date: March 20, 2003
    Inventors: Yasuko Tomida, Taku Shimoda
  • Patent number: 6534581
    Abstract: A silicone composition for preparing a silicone adhesive, the composition prepared by mixing (A) an organopolysiloxane containing an average of at least two silicon-bonded hydroxy groups per molecule; (B) a crosslinking agent in an amount sufficient to cure the composition; wherein the agent is selected from (i) at least one silane having the formula R2nSiX4−n wherein each R2 is independently selected from monovalent hydrocarbon and monovalent halogenated hydrocarbon groups having from 1 to about 8 carbon atoms, n is 0 or 1, and X is —OR2 or —OCH2CH2OR2; (ii) a partial hydrolyzate of (i), and (iii) mixtures comprising (i) and (ii); (C) an electrically conductive filler in an amount sufficient to impart electrical conductivity to the silicone adhesive, wherein the filler comprises particles having at least an outer surface of a metal selected from the group consisting of silver, gold, platinum, palladium, and alloys thereof; (D) an effective amount of a hydroxy-functional organic compound hav
    Type: Grant
    Filed: July 20, 2000
    Date of Patent: March 18, 2003
    Assignee: Dow Corning Corporation
    Inventors: Don Lee Kleyer, Michael Andrew Lutz
  • Publication number: 20030050375
    Abstract: A group of sealants are described which utilize a by-product of paint booth spray operations. Processed paint booth overspray particles are combined with various resins, curing agents to form the sealant compositions.
    Type: Application
    Filed: January 28, 2002
    Publication date: March 13, 2003
    Inventors: David C. Carlson, Abraham Kassa, Thomas Guenther
  • Publication number: 20030045620
    Abstract: A group of sealants are described which utilize a by-product of paint booth spray operations. Processed paint booth overspray particles are combined with various resins, curing agents to form the sealant compositions.
    Type: Application
    Filed: August 31, 2001
    Publication date: March 6, 2003
    Inventors: David L. Carlson, Abraham Kassa, Thomas Guenther
  • Patent number: 6525123
    Abstract: Herein is disclosed an oxygen barrier composition comprising ethylene/vinyl alcohol copolymer (EVOH), an oxygen scavenging polymer, and a transition metal salt. The composition can be in the form of a physical blend or a cross-linked blend, and can further comprise a compatibilizer, a transesterification catalyst, or both. Also disclosed is a packaging article comprising at least one high oxygen barrier layer comprising the blend of EVOH, the oxygen scavenging polymer, and the transition metal salt. The packaging article can be a single-layer or a multilayer article, and can be flexible or rigid. A multilayer packaging article can further comprise a structural layer or layers, an oxygen barrier layer, an oxygen scavenging layer, an oxygen permeable layer or layers, or an adhesive layer or layers, among others. In addition, herein is disclosed a method of making the blend of EVOH, the oxygen scavenging polymer, and the transition metal salt, comprising providing and blending the materials.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: February 25, 2003
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Hu Yang, Ta Yen Ching, Gangfeng Cai
  • Publication number: 20030036596
    Abstract: An adhesion accelerator for bonding rubber to metal contains a metal organic compound containing nickel and another metal organic compound containing zinc. Further, there is provided a rubber composition containing the above adhesion accelerator in an amount of 0.
    Type: Application
    Filed: June 10, 2002
    Publication date: February 20, 2003
    Inventors: Toru Imori, Kazunori Iida
  • Patent number: 6514606
    Abstract: A pressure-sensitive adhesive sheet for skin adhesion in which an adhesive force of the pressure-sensitive adhesive on the backing film does not lower greatly even with the lapse of long term and the initial adhesive force is substantially maintained, and a first-aid adhesive plaster using the same are disclosed. The pressure-sensitive adhesive sheet for skin adhesion comprises a backing film and a pressure-sensitive adhesive layer for skin adhesion formed on one side of the backing film, wherein the backing film comprises about 40 to about 70 parts by weight of a polyester plasticizer having a number average molecular weight of about 1,500 to about 3,000, an appropriate amount of a stabilizer comprising at least one metallic soap selected from the group consisting of fatty acid calcium, fatty acid zinc and fatty acid barium, and about 0.1 to about 1.0 part by weight of hydrotalcite per 100 parts by weight of a vinyl chloride polymer.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: February 4, 2003
    Assignee: Nitto Denko Corporation
    Inventors: Takashi Kinoshita, Yasuyuki Sasaki, Masayoshi Kuniya
  • Publication number: 20030013793
    Abstract: Rubber compositions contain, in addition to synthetic or natural rubber and conventional curing agents, an auxiliary composition containing a titanium or zirconium compound. The compositions are characterized by an enhanced cure rate at elevated temperatures such as would be useful for producing molded articles. At the same time the compositions exhibit an increased shelf life whereby uncured compositions of the invention are stable and can be molded for a considerable period of time even after storage at room temperature. Titanium compounds of the invention have at least one alkoxy group bonded to titanium, and zirconium compounds of the invention have at least one alkoxy group bonded to zirconium. In preferred embodiments, the auxiliary composition contains chelates of the titanium or zirconium compound. In particular, the auxiliary composition enhances the rate of cure at elevated temperature, and retards curing at room temperature.
    Type: Application
    Filed: June 7, 2001
    Publication date: January 16, 2003
    Inventor: Thomas Woodrow Wilson
  • Publication number: 20030004242
    Abstract: Compounds of and compositions comprising specific salts of saturated [2.2.2] dicarboxylate in order to provide highly desirable properties within thermoplastic (e.g., polyolefin) articles are provided. The inventive salts and derivatives thereof are useful as nucleating and/or clarifying agents for such thermoplastics, are easy to produce and handle, and relatively inexpensive to manufacture. Such compounds induce high peak crystallization and improved stiffness within thermoplastics. Also, thermoplastic compositions comprising such novel nucleating agents exhibit improved heat distortion properties and clarity levels in comparison with the closest unsaturated salt nucleating agents. Thermoplastic additive compositions and methods of producing thermoplastics with such compounds are also contemplated within this invention.
    Type: Application
    Filed: June 5, 2001
    Publication date: January 2, 2003
    Inventor: Xiaodong Edward Zhao
  • Publication number: 20020188047
    Abstract: An organometallic composition, suitable for use in curing polyisocyanate compositions, includes a complex of at least one metal selected from iron, cobalt and aluminum and at least one &bgr;-dicarbonyl compound wherein when the metal is iron (II) or cobalt (II) the molar ratio of &bgr;-dicarbonyl compound to metal is in the range from 2.1:1 to 10:1, and when the metal is aluminum (III), iron (III) or cobalt (III) the molar ratio of &bgr;-dicarbonyl compound to metal is in the range from 3.1:1 to 10:1. A polyisocyanate composition containing the organometallic composition and a process for binding lignocellulosic material is also described.
    Type: Application
    Filed: February 1, 2002
    Publication date: December 12, 2002
    Applicant: Imperial Chemical Industries PLC
    Inventors: Christopher J. Skinner, Martin G. Partridge
  • Patent number: 6482879
    Abstract: A resin composition having laser marking properties on radiation from a Nd:YAG laser wherein said composition comprises a polyester thermoplastic resin, a sufficient amount of light pigment for forming a light background coloration, and an effective amount of marking agent wherein said polyester thermoplastic resin decomposes in laser struck areas to form dark colored markings in laser struck areas on the light background coloration wherein the marking agent is selected from the group consisting of copper fumarates and copper maleates and mixtures thereof.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: November 19, 2002
    Assignee: General Electric Company
    Inventors: Gerben Bernardus Wilhelmus Hieltjes, Johannes Hubertus G. M. Lohmeijer, Franciscus Petrus Maria Mercx
  • Patent number: 6455621
    Abstract: The invention concerns a composition comprising calcium or magnesium acetylacetonate and at least a free &bgr;-diketone and/or in the form of a metal chelate, and having a melting point at most equal to 200° C. The invention also concerns the use of said composition for forming a formulation comprising at least a halogenated polymer, to prevent heterogeneity resulting from the presence of calcium or magnesium acetylacetonate, in said polymer.
    Type: Grant
    Filed: March 6, 2000
    Date of Patent: September 24, 2002
    Inventors: Michel Gay, Françoise Henrio
  • Publication number: 20020128502
    Abstract: Enclosed are high refractive index and low birefringence organic/inorganic hybrid materials useful for optical applications. They are prepared from solventless metal aliphatic acryl alkoxides. The metal acryl alkoxides are synthesized from exchanging acryl alcohol with metal alkoxides, and are hydrolyzed into metal oxide nanoparticles and are well dispersed in the acrylate matrix. Then they are polymerized into organic/inorganic hybrid materials containing metal oxide in polyacrylate.
    Type: Application
    Filed: January 30, 2002
    Publication date: September 12, 2002
    Applicant: POLE-CHIC CORPORATION
    Inventors: Wei-Fang Su, Hsiao-Kuan Yuan
  • Patent number: 6448306
    Abstract: Certain butadiene and/or natural rubber articles, such as acrylonitrile-butadiene rubber (NBR), natural rubber, and derivatives thereof, that exhibit highly desirable long-term effective antimicrobial characteristics. Such formulations are intended to be vulcanized to provide solid or foam rubber articles which can be utilized in a variety of different applications. Preferably such butadiene rubber formulations comprise silver-based antimicrobial compounds. As such silver-based compounds are deleteriously affected by utilization of standard non-silicone-rubber curing agents, such as sulfur-based catalysts, the ability to provide such an effective antimicrobial vulcanized rubber article is rather difficult. However, the invention encompasses the utilization of different catalyst species that permit vulcanization and silver stability for long-term antimicrobial performance of the silver-based compounds.
    Type: Grant
    Filed: March 23, 2001
    Date of Patent: September 10, 2002
    Assignee: Milliken & Company
    Inventors: John G. Lever, Geoffrey R. Haas, Bhawan Patel, William O. Burke, III, Robert C. Kerr
  • Patent number: 6433055
    Abstract: An electrically conductive hot-melt silicone adhesive composition, comprising (A) a hot-melt silicone adhesive; (B) an electrically conductive filler in an amount sufficient to impart electrical conductivity to the composition, wherein the filler comprises particles having at least an outer surface of a metal selected from silver, gold, platinum, palladium, and alloys thereof; and (C) an effective amount of a hydroxy-functional organic compound having a molecular weight up to about 1000 and containing at least one hydroxy group per molecule, provided that when the composition is curable, the compound does not substantially inhibit cure.
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: August 13, 2002
    Assignee: Dow Corning Corporation
    Inventors: Don Lee Kleyer, Michael Andrew Lutz
  • Patent number: 6429243
    Abstract: (A) A polyester resin composition comprising a copolymerized polyethylene terephthalate (copolymerized PET) comprising 5 to 40 mole % of naphthalenedicarboxylic acid units, a cobalt compound and/or a manganese compound, an olefin polymer and a compatibility-improving agent, in specific amounts; and (B) a polyester resin composition comprising the above copolymerized PET which contains specific amounts of both a cobalt compound and a manganese compound are excellent in resistance to hydrogen peroxide, flavor-barrier properties, gas-barrier properties, heatsealability and mechanical properties such as elongation and strength and, utilizing these features, are effectively usable for various end-uses in particular as packaging materials for beverages such as fruit juices containing flavor components.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: August 6, 2002
    Assignee: Kuraray Co., Ltd.
    Inventors: Chihiro Okamoto, Shunro Taniguchi
  • Patent number: 6428613
    Abstract: One object is to provide a curing accelerator which does not contain a lead soap, but has a curing property comparable to or surpassing that of a curing accelerator which contains a lead soap, and which does not color the coating. Another object is to minimize the amount of the cobalt soap if such is used. The curing accelerator for a resin having an unsaturated fatty acid group in its molecules contains a cobalt soap (A), a manganese soap (B), and an amino alcohol (C).
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: August 6, 2002
    Assignee: Dainippon Ink and Chemicals Inc.
    Inventors: Shigeki Matsunaga, Sachiyo Shiiki
  • Patent number: 6426380
    Abstract: A method is described for producing an improved addition-crosslinked silicone rubber which is used as a damping material in hermetically sealed housings having a semiconductor.
    Type: Grant
    Filed: July 24, 2000
    Date of Patent: July 30, 2002
    Assignee: Robert Bosch GmbH
    Inventors: Kurt Bovensiepen, Mathias Pieper, Detlef Spachmann
  • Patent number: 6423776
    Abstract: Oxygen barrier polyamide compositions exhibiting high oxygen scavenging capability suitable for extended shelf-life, packaging applications. Thus a polyamide composition comprises a polyamide homopolymer, copolymer, or blends thereof, and at least one polyamide reactive, oxidizable polydiene or oxidizable polyether. The polyamide products are particularly suited to making barrier packaging articles such as monolayer or multi-layer films, sheets, thermoformed containers and coinjection/coextrusion blow molded bottles comprising PET, polyolefin or polycarbonate as structural layers. Such articles are useful in a variety of oxygen-sensitive food, beverage, pharmaceutical and health care product packaging applications.
    Type: Grant
    Filed: May 2, 2000
    Date of Patent: July 23, 2002
    Assignee: Honeywell International Inc.
    Inventors: Murali K. Akkapeddi, Timothy J. Kraft, Edward P. Socci
  • Publication number: 20020086925
    Abstract: An improved enhancer formulation for use in forming precision molded articles from a furnace process is disclosed wherein an organometallic zirconia coupling agent is used in conjunction with a polymer in solvent to inhibit the bleed-through of infiltrant metal in a finished part formed in a single-step furnace process.
    Type: Application
    Filed: November 9, 2001
    Publication date: July 4, 2002
    Inventor: Kris Alan Schmidt
  • Patent number: 6414063
    Abstract: The application relates to a composition poly[ethylene terephthalate] (PET) and poly[ethylene naphthalate] (PEN), in the form of a polymer blend and/or copolymer, in which the PET:PEN mol ratio is from 20:80 to 80:20, and from 0.1 to 5.0 wt. %, based on the total weight of the composition, of a transition metal salt of a carboxylic acid.
    Type: Grant
    Filed: September 20, 2000
    Date of Patent: July 2, 2002
    Assignee: Kobe Steel, Ltd.
    Inventors: Farideh Bassam, Michael David Thompson, Barry Woodfine