Group V Metal Atom Dnrm (i.e., V, Nb, Ta, As, Bi, Sb) Patents (Class 524/408)
  • Patent number: 11345780
    Abstract: A thermoplastic polyester resin composition includes a thermoplastic polyester resin (A), an epoxy compound (B) having an epoxy equivalent of from 200 to 3,000 g/eq, and a hydroxy group-containing resin (C) having a number average molecular weight of from 2,000 to 500,000 and a halogen element content of 1,000 ppm or less, wherein the epoxy compound (B) is blended in an amount of from 0.05 to 10 parts by weight with respect to 100 parts by weight in total of 70 to 99.9 parts by weight of the thermoplastic polyester resin (A) and 0.1 to 30 parts by weight of the hydroxy group-containing resin (C). The thermoplastic resin composition and a molded article achieve both long-term hydrolysis resistance and heat aging resistance at a high level, and can further suppress bleed-out to the surface of the molded article during heat-dry and heat-moisture treatments.
    Type: Grant
    Filed: June 20, 2018
    Date of Patent: May 31, 2022
    Assignee: Toray Industries, Inc.
    Inventors: Kenichi Okunaga, Yusuke Tojo, Makito Yokoe, Hideyuki Umetsu
  • Publication number: 20150126663
    Abstract: A resin composition [composition (C)] comprising: from 40 to 95% by volume (% v) of at least one aromatic polyimide [polymer (PI)], from 0.1 to 15% by volume (% v) of at least one compound having the general formula AnXm [compound (AnXm)], wherein each A is independently selected from a group consisting of a metal atom (M) which is selected from the group consisting of Fe, Co, Ni, Cu, Zn, Mo, Ag, Cd, Sn, Pt, Au, Hg, Pb and Tl and a semimetal atom (SM) which is selected from the group consisting of As, Sb and Bi; wherein each X is independently selected from a group consisting of As, Sb, S, Se and Te; with the proviso that when A is As or Sb then X is different from A; and wherein n and m equal or different from each other, are independently 1, 2, 3 and 4, from 0.
    Type: Application
    Filed: May 16, 2013
    Publication date: May 7, 2015
    Applicant: SOLVAY SPECIALTY POLYMERS USA, LLC.
    Inventors: Thomas Burkhart, Rolf Walter, Hans-Peter Feldner, Yuhong Wu, Geoffrey Scott Underwood, Brian A. Stern
  • Patent number: 9006354
    Abstract: A method of manufacturing a composite composition, having: bonding a dispersant to the surfaces of inorganic oxide particles to provide dispersibility in a hydrophobic solvent to the inorganic oxide particles, and then dispersing the inorganic oxide particles in a hydrophobic solvent; substituting the dispersant bonded to the surfaces of the inorganic oxide particles with a surface modifier, which is a polydimethylsiloxane-skeleton polymer having one functional group at one terminal end, in the hydrophobic solvent in which the organic oxide particles are dispersed to bond the functional group of the polydimethylsiloxane-skeleton polymer to the surfaces of the inorganic oxide particles; and conjugating a silicone resin and the inorganic oxide particles obtained in the previous step, wherein the surface thereof is modified by bonding the polydimethylsiloxane-skeleton polymer having one functional group at one terminal end thereof, to obtain a composite composition.
    Type: Grant
    Filed: July 12, 2011
    Date of Patent: April 14, 2015
    Assignees: Sumitomo Osaka Cement Co., Ltd., Kyoto University
    Inventors: Takeshi Otsuka, Yoshiki Chujo
  • Patent number: 8986854
    Abstract: The present invention provides a composite material for a light-emitting element including a high molecular compound having an arylamine skeleton and an inorganic compound showing an electron accepting property to the high molecular compound. The absorption spectrum of the composite material is different from absorption spectra of the high molecular compound and the inorganic compound which each form the composite material. In other words, a composite material having an absorption peak in a wavelength which is seen in the absorption spectra of neither the high molecular compound nor the inorganic compound forming the composite material is superior in carrier transporting and injecting properties and a favorable material. In addition, the composite material can be formed by a wet method such as a sol-gel method, it can be apply to the increase of substrate size easily in a manufacturing process and advantageous industrially.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: March 24, 2015
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Tsunenori Suzuki, Satoshi Seo, Takako Takasu
  • Patent number: 8962711
    Abstract: A copper-flee friction material composition for brake pads consists of: 0.43 parts of aramid fiber, 1.9 parts of tire powder, 6 parts of heavy magnesia, 2.55 parts of calcined petroleum coke, 8 parts of ceramic fiber, 6.5 parts of phenolic resin, 14 parts of aluminum silicate fiber, 22 parts of potassium hexatitanate crystal whisker, 25 parts of barite powder, 5 parts of granular graphite, 2 parts of antimony sulfide, 2.8 parts of friction powder of cashew nut oil, 0.9 part of boron nitride, 5 parts of flake aluminum powder, and 0.6 parts of tantalum carbide. Trials show that it has satisfactory high temperature and thermal decay resistant performance, long service life, good abrasion resistance and stable friction coefficient. With the friction material of the present invention used, the brake pad of vehicles is sensitive and stable during braking, produces no screech, is comfortable and has no damage on coupling plate.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: February 24, 2015
    Assignee: Ruiyang Automotive Materials (Xiantao) Co., Ltd.
    Inventor: Jim Zewei Zhang
  • Patent number: 8946332
    Abstract: A composition that contains from 30 to 95 wt. %, based on the total weight of the composition, of a thermoplastic component and an effective amount of a flow-enhancing component. The effective amount of the flow-enhancing component reduces the viscosity of the composition by at least 10% compared to the viscosity of a composition comprising the thermoplastic component, but not an effective amount of the flow-enhancing component. The thermoplastic component is selected from the group consisting of polycarbonates, polyesters, and combinations thereof. The flow-enhancing component comprises b1) a component selected from the group consisting of metal oxides, metalloid oxides, metal alkoxides, metalloid alkoxides, and combinations thereof and b2) a mineral filler component. The weight ratio of component b1) to component b2) ranges from 1:25 to 25:1. A method for enhancing the flow of compositions comprising thermoplastic components is also disclosed.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: February 3, 2015
    Assignee: Sabic Global Technologies B.V.
    Inventors: Josephus Gerardus van Gisbergen, Chris van der Weele, Sreepadaraj Karanam, Mark van der Mee
  • Publication number: 20140349030
    Abstract: A method for selective metallization of a surface of a polymer article is provided. The polymer article contains a base polymer and at least one metal compound dispersed in the base polymer. The method includes gasifying at least a part of a surface of the polymer article by irradiating the surface with an energy source, and forming at least one metal layer on the surface of the polymer article by chemical plating. The metal compound contains a tin oxide doped with at least one doping element selected from a group including: V, Sb, In, and Mo.
    Type: Application
    Filed: May 22, 2014
    Publication date: November 27, 2014
    Applicants: SHENZHEN BYD AUTO R&D COMPANY LIMITED, BYD COMPANY LIMITED
    Inventors: Qing GONG, Wei ZHOU, Weifeng MIAO
  • Publication number: 20140334937
    Abstract: Mechanical strength of a composite material is enhanced by a simple process. In a composite material comprising a resin or a rubber and an oxide glass, the resin or the rubber is dispersed in the oxide glass, or the oxide glass is dispersed in the resin or the rubber, and the oxide glass is softened and fluidized by heating at or lower than a heat decomposition temperature of the resin or the rubber.
    Type: Application
    Filed: November 1, 2012
    Publication date: November 13, 2014
    Applicant: HITACHI, LTD.
    Inventors: Tadashi Fujieda, Takashi Naito, Takuya Aoyagi, Yuichi Sawai, Hajime Murakami, Hiroshi Yoshida, Akihiro Miyauchi, Masahiko Ogino
  • Patent number: 8883916
    Abstract: Disclosed is cross-linking process for cross-linking polymeric chains in a coating composition. In one embodiment the process utilizes a Hantzsch dihydropyridine reaction to form reaction products including cross-linking polymeric resin chains having beta-keto ester functions using a source of aldehyde and a source of ammonia or a primary amine to form a permanent dihydropyridine bond between the beta-keto ester functions. The novel cross-linking reaction can occur at lower temperatures compared to typical cross-linking reactions and can occur in aqueous solutions that have a neutral to mildly alkaline pH of from 6 to 11. The novel cross-linking reaction provides many advantages to performing cross-linking of polymeric chains in coating resins.
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: November 11, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Thomas S. Smith, II, Brian D. Bammel
  • Patent number: 8871826
    Abstract: A hybrid polymer composition can include a polymeric material that has dispersed within it a plurality of photocatalytic particles and a plurality of conductive particles at least some of which are in contact with one or more of the plurality of photocatalytic particles such that the conductive particles provide electron donating and electron accepting properties to the photocatalytic particles to enhance the creation of free radicals upon exposure of the hybrid polymer composition to one or more degradation enhancing factors. Examples of degradation enhancing factors can include, but are not limited to, one or more of visible light, ultraviolet light, moisture, and ozone. The photocatalytic particles can include a metal oxide, such as for example titanium dioxide and/or another non-toxic metal oxide. Related methods, articles, and the like are described.
    Type: Grant
    Filed: January 6, 2011
    Date of Patent: October 28, 2014
    Assignee: GraphicPak Corporation
    Inventors: Peter Butzloff, Robert Berger, Jamie Antongiovanni
  • Patent number: 8871310
    Abstract: The present invention relates to a surface-modified tantalum oxide nanoparticle, a method for preparation thereof, a contrast agent (medium) for X-ray computed tomography, and a highly dielectric (high-?) film using the same. In particular, the present invention is directed to a surface-modified tantalum oxide nanoparticle, a method for preparing surface-modified tantalum oxide nanoparticles, comprising: (i) adding an aqueous phase to an organic solvent which contains a surfactant, to prepare a water-in-oil microemulsion; (ii) introducing a tantalum precursor to said microemulsion; (iii) adding a surface-modifier having an organic silane group or phosphine group to a solution obtained at the step (ii); (iv) removing said organic solvent from a product obtained at the step (iii); and (v) separating surface-modified tantalum oxide nanoparticles from a mixture obtained at the step (iv), a contrast agent for X-ray computed tomography, and a highly dielectric (thin) film using the same.
    Type: Grant
    Filed: February 22, 2011
    Date of Patent: October 28, 2014
    Assignee: SNU R&DB Foundation
    Inventors: Taeghwan Hyeon, Myoung Hwan Oh
  • Publication number: 20140234544
    Abstract: A surface treatment agent for aluminum heat exchangers, which includes a zirconium element, vanadium element, fluorine element, aluminum element and an acrylic polymer, with the concentration of zirconium element in terms of zirconium being 100-100,000 ppm by mass, the concentration of vanadium element in terms of vanadium being 50-100,000 ppm by mass, the fluorine element concentration being 125-125,000 ppm by mass, the concentration of aluminum element in terms of aluminum being 5-10,000 ppm by mass and the concentration of the acrylic polymer being 100-100,000 ppm by mass. The surface treatment agent has a pH of 0.5-3, and suppresses odor generated from an aluminum heat exchanger, and the generation of white rust that deposits on the surface of an aluminum fin.
    Type: Application
    Filed: September 20, 2012
    Publication date: August 21, 2014
    Applicant: Noppon Paint Co., Ltd.
    Inventors: Hiroshi Takada, Hidekimi Hirasawa, Kenji Tsuge
  • Patent number: 8796364
    Abstract: The present invention relates to a method of obtaining an additive for coatings that contains nanoparticles of one or more compounds, preferably metallic, selected in relation to the property that is desired to be transferred to the coating, which comprises a first pretreatment phase in which the water content of the active agent is reduced, replacing it with a vehicle compatible with the coating, and a second phase in which it is mixed with a resin compatible with the coating, a dispersant and a solvent, which are also compatible with it. The additive produced by this method contains nanoparticles of one or more compounds, preferably metallic, which become dispersed homogeneously in the coating once incorporated therein.
    Type: Grant
    Filed: November 5, 2007
    Date of Patent: August 5, 2014
    Assignee: Servicios Administrativos Penoles S.A. de C.V.
    Inventors: Ricardo Benavides Pérez, José Gertrudis Bocanegra Rojas, Jesús Manuel Martínez Martínez, Julio César Rangel Mata
  • Patent number: 8791186
    Abstract: A method of determining that a thermoplastic was insufficiently dried before forming into a molded plastic part. The method comprises preparing a mixture of a thermoplastic polymer and an off-gassing compound, wherein the off-gassing compound is selected to release all water of hydration in response to target drying conditions specified for the thermoplastic polymer. The mixture is dried at actual drying conditions, and then heated to reduce the viscosity of the thermoplastic polymer and allow the mixture to flow. The mixture is then made to flow into a mold to form a plastic part at a molding temperature, wherein the molding temperature will cause any remaining water of hydration in the off-gas sing compound to off-gas and form surface irregularities in the plastic part. Non-limiting examples of the off-gassing compound include hydrated metal halides and ionic hydrates.
    Type: Grant
    Filed: December 6, 2011
    Date of Patent: July 29, 2014
    Assignee: International Business Machines Corporation
    Inventors: Joseph Kuczynski, Melissa K. Miller, Heidi D. Williams, Jing Zhang
  • Patent number: 8722761
    Abstract: The disclosure provides a melt processible theromoplastic composition, comprising a major proportion of a base polymer comprising a first melt processible thermoplastic polymer having a first Fedor's solubility parameter and a first viscosity; and a combination of a carrier polymer and a surface modifying additive, the carrier polymer comprising a second melt processible thermoplastic polymer which has a second Fedor's solubility parameter that is at least about 2.5 (J/cm3)1/2 lower than the first Fedor's solubility parameter, and a second viscosity, the carrier polymer being adhered to the surface modifying additive, and wherein the first viscosity is at least about 10 times the second viscosity.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: May 13, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Narayanan Sankara Subramanian, David D. Zhang
  • Patent number: 8716386
    Abstract: A method for producing polymeric balls or polymeric beads doped with at least one metal element is provided. The method may comprise the following steps: a) a step for forming polymeric balls or beads by polymerization, in an organic phase comprising a polymerization initiator, of at least one ethylenic monomer comprising at least one chelating ligand of at least one metal element; and b) a step for putting said polymeric balls or beads in contact with a solution comprising at least one metal element.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: May 6, 2014
    Assignee: Commissariat a l'Energie Atomique et aux Energies Alternative
    Inventors: Alexia Balland Longeau, Louis Moreau, Christian Levassort, Lyonel Guillot
  • Patent number: 8697791
    Abstract: An optical material including a polymer of a mixture which contains a sulfur-containing compound, a fluorene compound with a fluorene skeleton, and an energy polymerization initiator. The sulfur-containing compound contains, in a molecule, at least one kind of group selected from the group consisting of a sulfide group, a sulphone group, a sulfoxide group, a thiol group, and a thioester group. A refractive index of the polymer of the mixture is 1.65 or more to less than 1.92, an Abbe constant thereof is 15 or more to less than 22, and a difference ??g,F between a secondary dispersion property ?g,F thereof and a secondary dispersion property ?g,F of a normal optical material which is expressed by ?g,F=0.6438?0.001682?d is 0.05 or more to less than 0.13.
    Type: Grant
    Filed: September 8, 2009
    Date of Patent: April 15, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventor: Hidefumi Iwasa
  • Publication number: 20140087186
    Abstract: Flexible polyolefin compositions with improved balance of properties particularly for applications where softness and ductility at low temperature is requested comprising: A) from 20 to 40% by weight of a crystalline polymer fraction consisting of a propylene homopolymer, or a copolymer of propylene, or mixtures thereof, said crystalline fraction having a xylene insoluble fraction at 25° C. of at least 90% by weight. B) from 60 to 80% by weight of an elastomeric fraction consisting of a copolymer or blend of copolymers of propylene with one or more alpha-olefins, and optionally with minor quantities of a diene; said copolymer or blend containing ethylene in a quantity lower than 40% by weight. the fraction soluble in xylene at 25° C. of said polyolefin composition having IVgpc lower than 2.5 dl/g, Mw/Mn (GPC) equal to or higher than 4, Mz/Mw (GPC) equal to or higher than 2.
    Type: Application
    Filed: May 9, 2012
    Publication date: March 27, 2014
    Applicant: Basell Poliolefine Italia S.r.l.
    Inventors: Paolo Goberti, Giampaolo Pellegatti, Luca Lunghi
  • Publication number: 20140087117
    Abstract: Provided are polyphenylene sulfide compositions having improved thermo-oxidative stability, methods for obtaining them, and articles comprising the compositions. The compositions comprise polyphenylene sulfide and a bismuth additive. The bismuth additive comprises a bismuth halide, an inorganic bismuth salt, a bismuth carboxylate, an oxide comprising bismuth and a transition metal, bismuth metal, or a mixture thereof. Optionally, the compositions further comprise at least one zinc(II) compound.
    Type: Application
    Filed: September 27, 2012
    Publication date: March 27, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Robert John Duff, Joachim C. Ritter, Joel M. Pollino
  • Publication number: 20140080953
    Abstract: Flexible highly filled polyolefin compositions with improved balance of properties particularly for applications where softness and ductility at low temperature is requested comprising a soft heterophasic polyolefin composition the fraction soluble in xylene at 25° C. of said polyolefin composition having IVgpc lower than 2.5 dl/g. Mw/Mn (GPC) equal to or higher than 4. Mz/Mw (GPC) equal to or higher than 2.5. Said polyolefin composition further comprising an inorganic filler (II) selected from flame-retardant inorganic fillers and inorganic oxides or salts and a further elastomeric polymer or polymer composition component (c) having flexural modulus (ISO 178) lower than 60 MPa, Shore A (ISO 868) lower than 90 and Tg (DMTA) lower than ?20° C.
    Type: Application
    Filed: May 9, 2012
    Publication date: March 20, 2014
    Applicant: Basell Poliolefine Italia S.r.l.
    Inventors: Paolo Goberti, Giampaolo Pellegatti, Luca Lunghi
  • Patent number: 8664316
    Abstract: Provided are resin-based and metal-based anti-thermally-expansive members each having small thermal expansion. More specifically, provided are an anti-thermally-expansive resin and an anti-thermally-expansive metal, each including a resin or a metal having a positive linear expansion coefficient at 20° C. and a solid particle dispersed in the resin or metal, in which the solid particle includes at least an oxide represented by the following general formula (1): (Bi1-xMx)NiO3??(1), where M represents at least one metal selected from the group consisting of La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y, and In; and x represents a numerical value of 0.02?x?0.15.
    Type: Grant
    Filed: August 8, 2011
    Date of Patent: March 4, 2014
    Assignees: Canon Kabushiki Kaisha, Kyoto University
    Inventors: Makoto Kubota, Kaoru Miura, Hisato Yabuta, Yoshihiko Matsumura, Yuichi Shimakawa, Masaki Azuma
  • Patent number: 8658725
    Abstract: Disclosed are a material having high flexibility and a high dielectric constant, and a method for producing same: a material having a first polyrotaxane and a second polyrotaxane, wherein the first polyrotaxane comprises first blocking groups being disposed at both ends of a first pseudo-polyrotaxane—formed from the opening of a first circular molecule being enclathrated by being skewered by a first linear chain molecule—in a manner so that the first circular molecule does not detach; the second polyrotaxane comprises second blocking groups being disposed at both ends of a second pseudo-polyrotaxane—formed from the opening of a second circular molecule being enclathrated by being skewered by a second linear chain molecule—in a manner so that the second circular molecule does not detach; said first and second polyrotaxane are formed from crosslinking with the first and second circular molecules therebetween; said material is solvent free; and the material has a dielectric constant at 1 kHz of at least 6.0.
    Type: Grant
    Filed: March 1, 2011
    Date of Patent: February 25, 2014
    Assignee: Advanced Softmaterials Inc.
    Inventors: Katsunari Inoue, Yuki Hayashi, Junko Inamura
  • Patent number: 8633270
    Abstract: The present invention relates to a dispersion for the application of a metal layer on a non-electrically-conductive substrate comprising an organic binder component, a metal component, and also a solvent component. The invention further relates to processes for the production of the dispersion, processes for the production of a non-structured or structured metal layer with the aid of the dispersion, and also to the resultant substrate surfaces and their use.
    Type: Grant
    Filed: June 8, 2009
    Date of Patent: January 21, 2014
    Assignee: BASF SE
    Inventors: Rene Lochtman, Norbert Wagner, Jürgen Kaczun, Jürgen Pfister
  • Publication number: 20140011903
    Abstract: In various embodiments a urethane/molecular rebar formulation comprising a specific composition is disclosed. The composition comprises a urethane polymer or prepolymer/discrete carbon nanotube formulation. Utility of the urethane/molecular rebar composition includes improved foams and adhesives.
    Type: Application
    Filed: July 8, 2013
    Publication date: January 9, 2014
    Inventors: Clive P. Bosnyak, Kurt W. Swogger
  • Patent number: 8618202
    Abstract: The present invention relates to the use of surface-modified nanoparticles to alter the morphology and microstructure of polymer blends. The addition of surface modified nanoparticles to polymer blends comprised of immiscible polymers facilitates the uniform distribution of the dispersed phase of the polymer blend. In an embodiment, the present invention relates to a polymer blend comprising (1) a continuous phase comprising at least one polymer, monomer or oligomer, and a plurality of surface-modified nanoparticles, having a particle diameter of less than about 100 nanometers, distributed in the continuous polymer phase; and (2) a dispersed phase comprising at least one polymer, monomer or oligomer, wherein the continuous polymer phase and the dispersed polymer phase are immiscible.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: December 31, 2013
    Assignee: 3M Innovative Properties Company
    Inventors: Jimmie R. Baran, Jr., Michael A. Johnson, James D. Laperre
  • Patent number: 8598268
    Abstract: A material is disclosed having improved flame retardant properties and is particularly applicable as a jacket for a fiber optic cable. The material is comprised of a polymeric base compounded with a vanadium phosphate glass composition. The polymeric base may be a flame retardant polyethylene and the vanadium phosphate glass composition contains vanadium oxide, phosphorus oxide and antimony oxide. The material achieves a V-0 rating when tested per Underwriters Laboratory test UL-94 and has a heat release rate value consistent with a self extinguishing material when combusted.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: December 3, 2013
    Assignee: Corning Cable Systems LLC
    Inventors: Bruce G. Aitken, Linda S. Baker, Atanas V. Gagov
  • Publication number: 20130269976
    Abstract: The invention relates to cover (insulation or jacket) compositions for wires or cables having a base polymer and a bismuth compound. The composition contains no significant amount of lead and no added fire retardant.
    Type: Application
    Filed: August 8, 2012
    Publication date: October 17, 2013
    Applicant: General Cable Technologies Corporation
    Inventors: Sarah Gerretsen, Amalendu Sarkar
  • Patent number: 8552099
    Abstract: A polymer additive for improving the reheat characteristics of a polymer or polymeric composition comprises an inorganic material which is such that a 2.5 mm thick polyethylene terephthalate plaque incorporating the inorganic material has, when tested, an absorption ratio of less than 0.9, wherein the absorption ratio is either the ratio of A1/A2 or the ratio A1/A3, wherein: A1 is the maximum absorption between 400 nm and 550 nm; A2 is the maximum absorption between 700 to 1100 nm; A3 is the maximum absorption between 700 to 1600 nm. Preferred inorganic materials are titanium nitride, indium tin oxide and lanthanum hexaboride.
    Type: Grant
    Filed: May 15, 2012
    Date of Patent: October 8, 2013
    Assignee: Colormatrix Europe Limited
    Inventors: Anthony Jarvis, Mark Frost, Mark Rule
  • Patent number: 8530542
    Abstract: A method for forming an interlayer having improved solar control properties is disclosed. The method includes: a) forming a polymer material from a reaction mixture; b) adding one or more solar control components to the reaction mixture while the polymer material is being formed; and c) curing the reaction mixture.
    Type: Grant
    Filed: January 12, 2007
    Date of Patent: September 10, 2013
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Thomas G. Rukavina
  • Publication number: 20130202878
    Abstract: A thermoplastic fluoropolymer composition comprising at least one semi-crystalline polymer (A) comprising recurring units derived from ethylene and at least one of chlorotrifluoroethylene (CTFE) and tetrafluoroethylene (TFE), said polymer having a heat of fusion of at most 35 J/g and from 0.05 to 5% by weight, based on weight of said semi-crystalline polymer (A), of particles of at least one inorganic UV blocker compound, said particles having an average particle size of 1 to 150 nm, said composition being suitable for manufacturing UV-opaque films having outstanding transparency and haze properties.
    Type: Application
    Filed: October 13, 2011
    Publication date: August 8, 2013
    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: Serena Carella, Mattia Bassi, Paolo Toniolo, Julio A. Abusleme, Stefano Mortara
  • Publication number: 20130188003
    Abstract: Laser marking additives of at least one the core particle selected from the group consisting of copper oxide, chromium oxide, ceramic yellow, cobalt oxide, tungsten oxide, vanadium oxide, titanium oxide, ceramic red, molybdenum oxide, zinc sulfide and any combination thereof, and a coating covering at least part of the core particle comprising at least one oxide of a metal selected from the group consisting of Si, Ti, Ce, Zr, Zn, Al, Ba, Sr, La, Mg, Ca, V, Ta and mixtures thereof. This powder is used with 1064 nm wavelength laser (semiconductor lasers, fiber lasers) to change color in a plastic or polymer substrate to give contrast in laser marking plastics.
    Type: Application
    Filed: January 22, 2013
    Publication date: July 25, 2013
    Inventor: Jagdip Thaker
  • Publication number: 20130171468
    Abstract: The present invention provides a chromium-free surface treatment liquid which enables forming, on a metal material surface, a film excellent in corrosion resistance at bent portions of a steel sheet, solvent resistance, coating properties after alkaline degreasing, and sweat resistance. The surface treatment liquid contains a resin compound having a specific bisphenol skeleton, a cationic urethane resin emulsion, a silane coupling agent, an organic titanium chelate compound, a quadrivalent vanadyl compound, a molybdate compound, a fluorine compound, and water at predetermined proportions. The pH of the surface treatment liquid is in the range of 4 to 5.
    Type: Application
    Filed: September 20, 2011
    Publication date: July 4, 2013
    Applicant: JFE Steel Corporation
    Inventors: Toru Imokawa, Takahiro Kubota, Etsuo Hamada, Masayasu Nagoshi
  • Publication number: 20130143993
    Abstract: A method of determining that a thermoplastic was insufficiently dried before forming into a molded plastic part. The method comprises preparing a mixture of a thermoplastic polymer and an off-gassing compound, wherein the off-gassing compound is selected to release all water of hydration in response to target drying conditions specified for the thermoplastic polymer. The mixture is dried at actual drying conditions, and then heated to reduce the viscosity of the thermoplastic polymer and allow the mixture to flow. The mixture is then made to flow into a mold to form a plastic part at a molding temperature, wherein the molding temperature will cause any remaining water of hydration in the off-gas sing compound to off-gas and form surface irregularities in the plastic part. Non-limiting examples of the off-gassing compound include hydrated metal halides and ionic hydrates.
    Type: Application
    Filed: December 6, 2011
    Publication date: June 6, 2013
    Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Joseph Kuczynski, Melissa K. Miller, Heidi D. Williams, Jing Zhang
  • Publication number: 20130106659
    Abstract: A thermoplastic composition that contains a unique combination of a thermotropic liquid crystalline polymer, dielectric material, laser activatable additive, and a fibrous filler is provided. The nature of the components and/or their concentration are selectively controlled in the present invention to maintain a high dielectric constant, good mechanical properties (e.g., deflection under load), and good processibility (e.g., low viscosity), yet still be laser activatable. Thus, the thermoplastic composition can be readily shaped into a thin substrate and subsequently applied with one or more conductive elements using a laser direct structuring process (“LDS”).
    Type: Application
    Filed: October 23, 2012
    Publication date: May 2, 2013
    Applicant: TICONA LLC
    Inventor: Ticona LLC
  • Patent number: 8431640
    Abstract: The present disclosure describes composite materials containing a polymer material and a nanoscale material dispersed in the polymer material. The nanoscale materials may be biologically synthesized, such as tellurium nanorods synthesized by Bacillus selenitireducens. Composite materials of the present disclosure may have optical limiting properties and find use in optical limiting devices.
    Type: Grant
    Filed: November 2, 2009
    Date of Patent: April 30, 2013
    Assignee: University of Houston
    Inventors: Seamus Curran, Sampath Dias, Werner Blau, Jun Wang, Ronald S. Oremland, Shaun Baesman
  • Patent number: 8415410
    Abstract: A resin composition for giving molded articles that effectively block heat radiation from sunlight and are excellent in transparency, and molded articles thereof. The resin composition comprises an aromatic polycarbonate resin (Component A), hexaboride particles of at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sr and Ca (Component B-1) and other resin different from Component A (Component B-2), wherein the total content of Component B-1 and Component B-2 is 0.001 to 1 part by weight per 100 parts by weight of Component A, the resin composition contains particles (1) composed of Component B-1 and particles (2) composed of Component B-1 and Component B-2, both the particles (1) and (2) having a number average secondary particle diameter of 50 ?m or less and a maximum secondary particle diameter of 300 ?m or less.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: April 9, 2013
    Assignee: Teijin Chemicals, Ltd.
    Inventor: Akihiro Nitta
  • Publication number: 20130082369
    Abstract: The present invention aims to provide a curable resin composition which gives a cured product having a low linear expansion coefficient. The curable resin composition of the present invention contains, as essential components, (A) an organic compound having at least two carbon-carbon double bonds reactive with SiH groups per molecule, (B) a compound containing at least two SiH groups per molecule, (C) a hydrosilylation catalyst, (D) a silicone compound having at least one carbon-carbon double bond reactive with a SiH group per molecule, and (E) an inorganic filler.
    Type: Application
    Filed: March 30, 2011
    Publication date: April 4, 2013
    Applicant: KANEKA CORPORATION
    Inventors: Tadashi Kokubo, Katsuya Ouchi, Takahisa Iwahara, Kazuhiko Hirabayashi, Hiroshi Okoshi, Tomokazu Tozawa, Shuhei Ozaki
  • Patent number: 8399099
    Abstract: The present invention relates to cationically and radically curable coating compositions for coating a surface. The coating compositions consist essentially of a radically or cationically curable monomer, and a metal salt. The metal salt is chosen so that it is reduced at the surface to be coated, and where the standard reduction potential of the metal salt is greater than the standard reduction potential of the surface, and where when the composition is placed in contact with the surface, the metal salt of the composition is reduced at the surface, thereby initiating cure of the curable component in the compositions. Redox mediated cure of the coating compositions results in a coating or film on the surface. The invention also provides for functionalization of surfaces. Cross-linking of the coating occurs directly on the surface.
    Type: Grant
    Filed: May 22, 2009
    Date of Patent: March 19, 2013
    Assignee: Henkel Ireland Limited
    Inventors: David Farrell, Ciaran B. McArdle, Michael Doherty
  • Patent number: 8389627
    Abstract: The present invention provides novel filled silicone compositions comprising a nano-particulate metal oxide filler selected from nano-particulate monoclinic alpha-phase bismuth oxide, nano-particulate erbium oxide, and mixtures thereof. The new composite compositions exhibit a combination of outstanding performance characteristics in both the cured and uncured states. Thus, the uncured formulations are typically free flowing liquids which are self-leveling, which de-gas readily under vacuum, are readily colorable through the addition of pigments, and which cure at temperatures of about 60° C. The cured compositions possess outstanding acoustic characteristics which make them ideally suited for use in applications such as acoustic lenses for medical imaging and therapy. For example, the acoustic impedance of compositions provided by the present invention is closely matched to the acoustic impedance of human tissue.
    Type: Grant
    Filed: January 14, 2011
    Date of Patent: March 5, 2013
    Assignee: General Electric Company
    Inventors: Slawomir Rubinsztajn, Lowell Scott Smith, Charles Edward Baumgartner
  • Patent number: 8383707
    Abstract: The invention relates to a colored ?-nucleated polypropylene composition having a high content of ?-modification, wherein the polypropylene composition comprises at least one ?-nucleating agent and an inorganic blue pigment and an inorganic yellow pigment.
    Type: Grant
    Filed: January 20, 2009
    Date of Patent: February 26, 2013
    Assignee: Borealis Technology Oy
    Inventor: Franz Ruemer
  • Publication number: 20130005891
    Abstract: A dielectric material (14) for a capacitor comprising a first material and a second material, the first material being a polymer and the second material comprising particles. The particles are dispersed within the polymer, and are selected to have a relative permittivity higher than that of the polymer, characterised in that the diameter of the particles is in the nanometer range and the particles are geometrically controlled to a predetermined shape.
    Type: Application
    Filed: March 16, 2011
    Publication date: January 3, 2013
    Applicant: THE SECRETARY OF STATE FOR DEFENCE
    Inventors: Richard James Lynch, Matthew Adrian Brown, Adele Sarah Donovan, Michelle Silverstone
  • Patent number: 8334332
    Abstract: A flame-retardant thermoplastic resin composition that can have excellent color tone according to the present invention comprises a base resin comprising (A) about 50 to about 99% by weight of a rubber modified aromatic vinyl resin; and (B) about 1 to about 50% by weight of an acryl resin; and further comprising (C) about 1 to about 30 parts by weight of a bromodiphenyl ethane mixture, based on about 100 parts by weight of the base resin comprising (A) and (B); and (D) about 1 to about 10 parts by weight of an antimony oxide, based on about 100 parts by weight of the base resin comprising (A) and (B). The resin composition of the present invention can have improved physical properties and color properties as well as flame resistance.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: December 18, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Se Bum Son, Sung Hee Ahn, In Hwan Oh
  • Publication number: 20120316277
    Abstract: The invention relates to aqueous formulations comprising silane-modified polymeric binders having a siloxane content and inorganic nanoparticles, a process for the preparation thereof and the use thereof for the preparation of aqueous coating compositions.
    Type: Application
    Filed: August 17, 2012
    Publication date: December 13, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Thomas Münzmay, Arno Nennemann, Christoph Irle, Nusret Yuva, Alice Münzmay
  • Patent number: 8309641
    Abstract: Disclosed herein is a curable composition comprising a curable fluoroelastomer, a curative and an acid acceptor selected from the group consisting of a hydrous bismuth oxide nitrate compound and bismuth oxide. Cured articles made therefrom are resistant to volume swell in acids, coolant and in biofuel.
    Type: Grant
    Filed: July 28, 2011
    Date of Patent: November 13, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Donald F. Lyons, Tsuyoshi Kawai
  • Patent number: 8304092
    Abstract: An aqueous surface-treatment liquid is a treatment liquid containing a water-soluble zirconium compound, water-dispersive particulate silica, a silane coupling agent, a vanadic acid compound, a phosphoric acid compound, a nickel compound, and an acrylic resin emulsion in particular proportions. A surface-treated galvanized steel sheet produced using the treatment liquid is a galvanized steel sheet having a surface-treatment coating on a surface thereof, and the coating contains a zirconium compound, particulate silica, a silane-coupling-agent-derived component, a vanadic acid compound, a phosphoric acid compound, a nickel compound, and an acrylic resin in particular proportions. The amount of coating on a zirconium basis is 10 to 200 mg/m2. This surface-treated galvanized steel sheet is chromate-free and has superior flat-portion corrosion resistance, blackening resistance, and appearance and corrosion resistance after press forming.
    Type: Grant
    Filed: December 10, 2007
    Date of Patent: November 6, 2012
    Assignee: JFE Steel Corporation
    Inventors: Kazuhisa Okai, Rie Umebayashi, Etsuo Hamada, Akira Matsuzaki, Satoru Ando
  • Patent number: 8241524
    Abstract: Disclosed is a release on demand type corrosion inhibitor composition for a metal substrate formed from only non-electrically conductive film forming copolymer(s); a nitrogen containing functional group X, where the group X comprises a pyridine, a dihydropyridine, a pyrrole, an imidazole, or a mixtures thereof; and a metallate anion. The metallate anion binds to a nitrogen in the functional group X by ion pairing. A localized rise in pH is believed to cause release of the anion via a protonation/deprotonation reaction and the released anion suppresses the corrosion formation. The coating composition includes no electrically conductive polymers.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: August 14, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: John D. McGee, Thomas S. Smith, II, Brian D. Bammel, Todd R. Bryden
  • Publication number: 20120190783
    Abstract: A composition that contains from 30 to 95 wt. %, based on the total weight of the composition, of a thermoplastic component and an effective amount of a flow-enhancing component. The effective amount of the flow-enhancing component reduces the viscosity of the composition by at least 10% compared to the viscosity of a composition comprising the thermoplastic component, but not an effective amount of the flow-enhancing component. The thermoplastic component is selected from the group consisting of polycarbonates, polyesters, and combinations thereof. The flow-enhancing component comprises b1) a component selected from the group consisting of metal oxides, metalloid oxides, metal alkoxides, metalloid alkoxides, and combinations thereof and b2) a mineral filler component. The weight ratio of component b1) to component b2) ranges from 1:25 to 25:1. A method for enhancing the flow of compositions comprising thermoplastic components is also disclosed.
    Type: Application
    Filed: October 20, 2009
    Publication date: July 26, 2012
    Inventors: Josephus Gerardus van Gisbergen, Chris van der Weele, Sreepadaraj Karanam, Mark van der Mee
  • Patent number: 8227536
    Abstract: A solder paste comprising a solder alloy powder and a flux. The volumetric expansion at the time of melting of the solder alloy is at most 0.5%. The flux contains a bisphenol A epoxy resin and a curing agent selected from a carboxylic anhydride and a dicarboxylic acid. The solder paste can be used in applications suitable for high-temperature solders. The solder alloy has an alloy composition comprising, in mass percent, 70-98% of Bi, a total of 0-0.5% of at least one substance selected from Ag, Cu, Sb, In, Zn, Ni, Cr, Fe, Mo, P, Ge, and Ga, and a remainder of Sn.
    Type: Grant
    Filed: August 11, 2006
    Date of Patent: July 24, 2012
    Assignees: Senju Metal Industry Co., Ltd., Murata Manufacturing Co., Ltd.
    Inventors: Shizuharu Watanabe, Hidekiyo Takaoka, Kosuke Nakano, Masafumi Seino, Ko Inaba
  • Patent number: 8211983
    Abstract: A polymer additive for improving the reheat characteristics of a polymer or polymeric composition comprises an inorganic material which is such that a 2.5 mm thick polyethylene terephthalate plaque incorporating the inorganic material has, when tested, an absorption ratio of less than 0.9, wherein the absorption ratio is either the ratio of A1/A2 or the ratio A1/A3, wherein: A1 is the maximum absorption between 400 nm and 550 nm; A2 is the maximum absorption between 700 to 1100 nm; A3 is the maximum absorption between 700 to 1600 nm. Preferred inorganic materials are titanium nitride, indium tin oxide and lanthanum hexaboride.
    Type: Grant
    Filed: September 22, 2010
    Date of Patent: July 3, 2012
    Assignee: Colormatrix Europe Limited
    Inventors: Anthony Jarvis, Mark Frost, Mark Rule
  • Patent number: 8192508
    Abstract: Disclosed are ceramic-polymer composite consisting of aggregates of dielectric ceramic particles and polymer resin, and a fabrication method thereof, the method including aggregating dielectric ceramic particles to create aggregates, melting polymer resin in a solvent to prepare a polymer solution, dispersing the aggregates in the polymer solution to prepare a mixed solution, and hardening the mixed solution to obtain ceramic-polymer composites.
    Type: Grant
    Filed: December 2, 2009
    Date of Patent: June 5, 2012
    Assignee: Korea Institute of Science and Technology
    Inventors: Hae June Je, Byung Kook Kim, Min Park, Dong Ho Lee