Ammonium Phosphate Patents (Class 524/416)
  • Patent number: 7754808
    Abstract: A halogen-free, fire-resistant rubber composition comprising: 100 parts by weight of elastomer comprising 50-100 parts of at least one olefin-type elastomer; at least one fire-retardant boron source; at least one phosphorous source; at least 75 parts of at least one fire-retardant metal-hydrate; and at least one selected from the group consisting of a fire-retardant nitrogen compound and a nitrile-containing elastomer. The composition is suitable for use in fire-resistant, low-smoke hose. The hose may be used in fluid-handling systems requiring flame resistance and/or low smoke generation in fire.
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: July 13, 2010
    Assignee: The Gates Corporation
    Inventor: Jan Goossens
  • Patent number: 7705080
    Abstract: The invention relates to an adhesive according to a conventional formulation, comprising additives capable of binding metal ions in the sense of chemical interactions, electrochemical interactions and/or physical interactions.
    Type: Grant
    Filed: December 7, 2007
    Date of Patent: April 27, 2010
    Assignee: tesa SE
    Inventors: Kai Ellringmann, Stefan Wulf, Philipp Preuβ
  • Publication number: 20100080920
    Abstract: A flame retardant coating is disclosed. The flame retardant coating comprises polyurea elastomer, spray processable graphite, a graphite stabilizer agent, and a flame retardant. A method of manufacturing a flame retardant polyurea elastomer coating is also disclosed. A two part polymerizable system is provided comprising a first part containing isocyanates, and a second part containing polyamines. At least one of the first part and the second part contains a flame retardant, and both of spray processable graphite and a graphite stabilizer agent. The first part and the second part are then mixed to form the flame retardant polyurea elastomer coating.
    Type: Application
    Filed: September 26, 2008
    Publication date: April 1, 2010
    Inventors: TONY LAGRANGE, SHAWN CHIZEN
  • Patent number: 7683117
    Abstract: A resin composition includes an aliphatic polyester; a second polymer compound other than the aliphatic polyester; and an organic phosphoric acid compound that has a phosphorus content of about 20% by mass or more.
    Type: Grant
    Filed: January 31, 2008
    Date of Patent: March 23, 2010
    Assignees: Fuji Xerox Co., Ltd., Fujifilm Corporation
    Inventors: Masahiro Moriyama, Kenji Yao, Seiichi Takagi, Masayuki Okoshi, Fumiyuki Suzuki, Tadashi Mochizuki, Hidetoshi Kawasaki
  • Publication number: 20100069488
    Abstract: A composition can embrace a fire retardant can be combined with a fluoropolymer, which can be a coating, for example, a paint, especially a latex paint, or which can be an organic solvent based coating, for example, a paint. The fire retardant can be an ammonium phosphate containing fire retardant, which can be combined with a fluoropolymer, a penetrating barrier, borate-containing formulation having resistance to water damage with protective properties coming from materials used in food packaging and cosmetics, and/or a medium-to-long chain polar carboxyl substance to make a composition. Also, a composition can embrace a fire retardant formulation having a cross-linked component, which composition may be a coating, for example, a paint or stain, especially a latex paint. The cross-linked component may be a base of the paint or stain, say, a vinyl acetate base of the fire retardant latex paint. At least one other active agent, for example, a mold inhibitor and/or an insecticide, may be included.
    Type: Application
    Filed: September 16, 2009
    Publication date: March 18, 2010
    Inventors: Michael John Mabey, William Kish
  • Patent number: 7618563
    Abstract: A fire-retardant coating material includes an intumescent material and a binder. The intumescent material is cured and powdered. The intumescent material includes a hydrocarbon, acid source and blowing agent. The hydrocarbon includes a plurality of alcohol groups. The fire-retardant coating material dries at room temperature.
    Type: Grant
    Filed: October 19, 2005
    Date of Patent: November 17, 2009
    Assignee: The Boeing Company
    Inventor: John N. Harris
  • Publication number: 20090253836
    Abstract: The present invention relates to flame-retarded flexible thermoplastic compositions of high thermomechanical strength, containing no halogen compound, comprising a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the radicals of an unsaturated monomer (X) having a function capable of reacting with an amine-terminal polyamide, the radicals of the unsaturated monomer (X) being fixed to the backbone by grafting or copolymerization from its double bond, wherein said composition comprises, in a mixture: 50% to 70% by weight of the graft copolymer containing polyamide blocks, 25% to 35% by weight of a flame retardant selected from ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, approximately 2% by weight of molecular sieve, such as a zeolite, or of hydrotalcite(s).
    Type: Application
    Filed: June 1, 2007
    Publication date: October 8, 2009
    Applicant: Arkema France
    Inventors: Jean-Jacques Flat, Philippe Blondel, David Meslet
  • Patent number: 7576145
    Abstract: The present invention relates to a composition for producing naturally-degradable substitutes of plastics and to a method for producing a granular combination of naturally-degradable polymers suitably usable in the plastic transformation industry.
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: August 18, 2009
    Assignee: Plasbio, Inc.
    Inventor: Michel Mezza
  • Patent number: 7521495
    Abstract: Intumescent, electrical installation systems which comprise an injection molding material of polyolefins or polyimides in combination with intumescent additives, the melting points of the polyolefins and of the polyimides being lower than the intumescence temperature of the intumescent additives.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: April 21, 2009
    Assignee: Intumex GmbH
    Inventors: Heinrich Horacek, Walter Pickhard
  • Publication number: 20090088508
    Abstract: The present invention relates to a powder which, in addition to a polymer, comprises a flame retardant based on ammonium polyphosphate, to the use of this powder for the layer-by-layer production of moldings, and also to moldings produced from this powder. The moldings constructed using the inventive powder have marked advantages with regard to their flammability, when comparison is made with conventional products, and this permits use in aircraft, for example.
    Type: Application
    Filed: December 11, 2008
    Publication date: April 2, 2009
    Applicant: Degussa AG
    Inventors: Sylvia MONSHEIMER, Maik Grebe, Franz-Erich Baumann
  • Patent number: 7491763
    Abstract: A polyamide composition has (a) a polyamide, (b) at least one phosphorus compound selected from the group consisting of phosphoric acids, phosphorous acids, hypophosphorous acids, metal phosphates, metal phosphites, metal hypophosphites, phosphoric esters, and phosphorous esters, and (c) a soluble metal aluminate compound represented by the general formula (M2O)x(Al2O3)y (wherein X+Y=1 and M is a Group 1 metal of the Periodic Table), wherein the molar ratio of polyvalent metal to monovalent metal in the composition (polyvalent metal/monovalent metal) is from 0.25 to 1.0.
    Type: Grant
    Filed: July 9, 2003
    Date of Patent: February 17, 2009
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Masaaki Aramaki, Asami Ohashi
  • Publication number: 20090036561
    Abstract: The present invention relates to a fire-resistant composition for coating, filling, sealing, and protection comprising an isocyanate curable polymer, a polymer curable isocyanate, an aliphatic polyether glycol, and rubber, whereby it further comprises ammonium polyphosphate, expanding graphite, and aluminum trihydrate.
    Type: Application
    Filed: April 23, 2008
    Publication date: February 5, 2009
    Inventor: Sune Bertil Nygren
  • Publication number: 20090018241
    Abstract: The present invention relates to a halogen-free phosphorous epoxy resin composition, primarily used as an adhesive for the printed circuit board. The composition comprises a halogen-free phosphorous contained epoxy resin which reduces the addition amount of additional flame retardant; in order to offer flame retardancy while maintaining high flexibility of flexible printed circuit board.
    Type: Application
    Filed: February 22, 2007
    Publication date: January 15, 2009
    Inventors: Yu Hsain Cheng, We Ming Te
  • Publication number: 20080257507
    Abstract: A paper adhesive composition includes a cationic non-crosslinked acidified solution of a polyamidoamine with the repeating units wherein n?1; m=1 or 2; X?m is chloride, bromide, iodide, sulfate, bisulfate, nitrate, oxalate, alkyl carboxylate, aryl carboxylate, hydrogen phosphate, dihydrogen phosphate, alkyl sulfonate, aryl sulfonate, or a combination comprising at least one of the foregoing anions; R1 is a divalent aliphatic, cycloaliphatic, or araliphatic group having from 1 to 24 carbon atoms; R2 is hydrogen or a monovalent aliphatic, cycloaliphatic, or araliphatic group having from 1 to 24 carbon atoms; and R3 is a divalent hydrocarbon radical derived from a dibasic carboxylic acid.
    Type: Application
    Filed: April 17, 2008
    Publication date: October 23, 2008
    Inventor: Clayton J. Campbell
  • Patent number: 7417083
    Abstract: A flame retardant additive composition comprising a phosphoric acid salt selected from the group consisting of melamine phosphate, melamine pyrophosphate, melamine orthophosphate, diammonium phosphate, monoammonium phosphate, phosphoric acid amide, melamine polyphosphate, ammonium polyphosphate, polyphosphoric acid amide and combinations of two or more of the foregoing; a metal hydroxide; and an organic phosphate. The flame retardant additive is useful in a wide range of thermoplastic compositions.
    Type: Grant
    Filed: March 28, 2005
    Date of Patent: August 26, 2008
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Kazunari Kosaka, Xiucuo Li, Xuedong Li, Vijay Mhetar, Weiguang Yao
  • Publication number: 20080166559
    Abstract: A fire retardant material comprising both ammonium polyphosphate particles microencapsulated within a melamine or melamine-based resin and melamine-based particles retained in a base material. The material may be applied to a textile article or incorporated into an article during formation thereof.
    Type: Application
    Filed: January 5, 2006
    Publication date: July 10, 2008
    Applicant: DARTEX COATINGS LIMITED
    Inventors: Tilo Schwarzbach, Jo McKnight
  • Patent number: 7393888
    Abstract: The aqueous resin composition comprises components (A) and (B), wherein (A) is a synthetic resin emulsion prepared by emulsion-polymerizing a radical-polymerizable unsaturated monomer using a surfactant having at least one polymerizable unsaturated bond, and (B) is a polyphosphate salt. To provide an aqueous flame retardant resin composition which is excellent in flame retardancy and storage stability, and is less likely to produce a fogging phenomenon.
    Type: Grant
    Filed: June 23, 2006
    Date of Patent: July 1, 2008
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventor: Nobuyoshi Yoshimura
  • Patent number: 7291664
    Abstract: The invention relates to a multicomponent composition for photodegradable and biodegradable plastic articles, and the use of said composition in the manufacture of various disposable and packaging plastic articles and the articles made therefrom. The multicomponent composition does not contain starch, and is a multicomponent compounded composition of new bioactive material of chitin, casein and the like, with biodegradable aid component, photodegradable and auto-oxidation catalysis component, and nonmetallic minerals and the like. Under natural condition, the degraded material can be utilized by microorganism to release carbon dioxide and water, and acts as an eco-friendly plastic material.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: November 6, 2007
    Inventor: Benzhong Hao
  • Patent number: 7235604
    Abstract: The present invention relates to fire-retarded compositions comprising, by weight, the total being 100 parts: 50 to 75 parts of a blend of a polyamide (A) and a polyolefin (B), 25 to 50 parts of a blend comprising: 0.1 to 48.8 parts of a fire retardant, 0.1 to 30 parts of a phosphorus-containing plasticizer, 0.1 to 10 parts of a zeolite, the total of these three products being between 25 and 50. These compositions have a V0 or V1 classification according to the UL94-VB test when a fire test is carried out on test specimens 1.6 mm in thickness. They have many advantages, in particular the elongation at break measured according to ISO R 527-1B exceeds 100%. As regards the impact strength, they have a non-brittle behaviour in multiaxial impact at room temperature according to ISO 6603-2 (at a rate of 7.7 m/s). They retain at least 50% of their mechanical properties after ageing for seven days at 120° C. in hot air.
    Type: Grant
    Filed: June 24, 2003
    Date of Patent: June 26, 2007
    Assignee: Atofina
    Inventors: Philippe Blondel, Benoît Brule, Nicolas Frenois, Jean-Jacques Flat
  • Patent number: 7217753
    Abstract: A fire retardant intumescent coating composition comprises: (a) 30 to 60% by weight of a phosphorous containing material which decomposes to produce phosphoric acid when the coating is exposed to fire; (b) 10 to 30% by weight of a thermosetting binder; (c) 2.5 to 10% by weight of a curing agent for the thermosetting binder; and (d) 5 to 40% by weight of a thermoplastic binder, wherein the active groups of the thermosetting and thermoplastic binders are chosen so as to impart charring and blowing functions to the intumescent coating composition. The thermosetting binder is advantageously a hydroxylated thermosetting binder, suitably an epoxy resin. The thermoplastic binder is advantageously an oxygenated heterocyclic thermoplastic binder, suitably an aldehyde and/or ketone resin. The coating composition may contain 1 to 10% by weight of a colouring agent, suitably titanium dioxide. The coating composition may contain 0.1 to 10% by weight of melt viscosity modifier, suitably hydrogenated castor oil.
    Type: Grant
    Filed: September 19, 2003
    Date of Patent: May 15, 2007
    Assignees: Rohm and Haas Company, Chance & Hunt Limited
    Inventors: Michael John Sinclair, James Edward Watts
  • Patent number: 7205346
    Abstract: A flame-retardant resin composition comprises a thermoplastic resin; a flame retardant comprising a phosphorus-containing compound (A), a aromatic resin (B), and at least one flame-retardant auxiliary (C) selected from a nitrogen-containing compound and a metal salt of an inorganic acid; and at least one stabilizer auxiliary (D) selected from a compound having a functional group reactive to an active hydrogen atom and a water-repellent compound. The phosphorus-containing compound may be a phosphoric ester. The aromatic resin may be a polyphenylene sulfide-series resin or a polyphenylene oxide-series resin. The nitrogen-containing compound is a salt of an amino group-containing triazine compound with an oxygen acid, a salt of an amino group-containing triazine compound with a hydroxyl group-containing triazine compound, a polyphosphoric acid amide, a cyclic urea compound, or others.
    Type: Grant
    Filed: November 28, 2002
    Date of Patent: April 17, 2007
    Assignee: Polyplastics Co., Ltd.
    Inventor: Hatsuhiko Harashina
  • Patent number: 7202288
    Abstract: Laser-markable pigments which are distinguished by the fact that an absorber is coated with a marker and optionally with a diffusion barrier are described. Further, processes for the preparation of the laser-markable pigments and methods for using them are described. The absorber is preferably an inorganic pigment or a filler. The marker is preferably an intrinsically laser-markable polymer, particularly a polyethylene terephthalate, acrylonitrile-butadiene-styrene, polystyrene, polyphenylene ether, liquid-crystal polymer or polyphenylene sulfide.
    Type: Grant
    Filed: November 5, 2003
    Date of Patent: April 10, 2007
    Assignee: Merck Patent GmbH
    Inventors: Helge Bettina Kniess, Gerhard Pfaff, Matthias Kuntz, Hans-Juergen Brehm, Reiner Delp
  • Patent number: 7132466
    Abstract: The invention relates to a compound of the general formula: Z1-O-[m(R1PO3),n(R2HPO3]Z2, represent a copolyphosphate, with m (R1PO3) units and n (R2HPO3) units; R3 represents an ammonium building block; R2 represents a 1,3,5-triazine building block; Z1 and Z2 represent ammonium or 1,3,5-triazine building blocks, to be chosen independently of each other; m and n represent whole numbers greater than or equal to 1; and m+n numbers greater than 3. The invention further relates to a method for the preparation of the above compound and to flame-retardant polymer compositions in which compounds with the above formula are applied as flame retardant, the use of the halogen-free compound in a coating composition and a substrate containing a coating formed from the coating composition that has been cured.
    Type: Grant
    Filed: October 1, 2002
    Date of Patent: November 7, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Renier Henricus Maria Kierkels, Nicolaas Johanna Jozef Aelmans, Patricia Hubertina Cornelis Grolleman, Adrianus Wilhelmus Maria Braam
  • Patent number: 7094819
    Abstract: A flame retardant polytrimethylene terephthalate resin composition, comprising: 30 to 99 parts by weight of (A) a polytrimethylene terephthalate resin, and 1 to 70 parts by weight of at least one flame retardant selected from the group consisting of (B-1) phosphorus-containing flame retardant and (B-2) nitrogen-containing flame retardant, is disclosed. The composition has superior mechanical characteristics, chemical resistance, electrical characteristics, weatherability, heat aging resistance and hydrolysis resistance, and has superior moldability, good appearance with less warpage deformation when molded, and furthermore has superior flame retardance and does not generate highly corrosive hydrogen halide gas upon combustion.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: August 22, 2006
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Junko Kakegawa, Tomofumi Maekawa, Hideki Nakamura
  • Patent number: 7084196
    Abstract: Polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of (i.) at least one compound selected from the group consisting of nitroxyl stabilizers, hydroxylamine stabilizers, nitrone stabilizers, substituted hydroxylamine stabilizers, amine oxide stabilizers, benzofuranone stabilizers phosphite and phosphonite stabilizers, quinone methide stabilizers and monoacrylate esters of 2,2?-alkylidenebisphenol stabilizers and (ii.) at least one compound selected from the group consisting of brominated flame retardants, phosphorus containing flame retardants and inorganic flame retardants such as ammonium polyphosphate or decabromodiphenyl oxide; wherein the amount of organic or inorganic flame retardant of component (ii.) required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when component (i.) is not present.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: August 1, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Malisa V. Troutman, Ramanathan Ravichandran, Rangarajan Srinivsan, Roswell Easton King, Douglas Wayn Horsey
  • Patent number: 6951896
    Abstract: The invention relates to a flame-retardant thermoplastic composition which comprises at least (A) a thermoplastic polymer and (B) a flame-retardant system and which also contains (C) an n-alkanelactam-substituted polymer. Such a composition shows both a good flame retardancy, in particular a short afterflame time and little dripping, and also excellent mechanical properties. In particular, the n-alkanelactam-substituted polymer is a polyolefine, substituted with n-alkanelactam groups, with n being chosen from between 2 and 12. More in particular, the n-alkanelactam is polyvinyl pyrrolidone. Preferably, the thermoplastic polymer is a polycondensation polymer, in particular a polyamide, a polyester or a polycarbonate. Particularly suitable for use as the polyamide are PA-6, PA-6,6, PA-4,6 and semi-aromatic polyamides. The flame-retardant system may be both a halogen-containing and a halogen-free system.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: October 4, 2005
    Assignee: DSM IP Assets B.V.
    Inventor: Johannes H. G. Ottenheijm
  • Patent number: 6930139
    Abstract: Coatings for agricultural grade fertilizer particles and industrial grade ammonium nitrate are provided which when applied to particles form a protective film which acts as a barrier to inhibit or prevent hydrocarbon infiltration of the fertilizer particle pores and also to physically separate the fertilizer particles and hydrocarbon materials. In so doing, the coating greatly reduces the efficacy of the fertilizer particles as an oxidizing agent for use in incendiary devices, thereby deterring or preventing the use of agricultural grade fertilizers or industrial grade ammonium nitrate in creating weapons of terror.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: August 16, 2005
    Assignee: Specialty Fertilizer Products, LLC
    Inventors: John Larry Sanders, Grigory Mazo, Jacob Mazo
  • Patent number: 6930138
    Abstract: A flame retarding and smoke suppressing additive powder that can be mixed with resins includes a carbonific material, a heat activated blowing agent, a heat activated halogen material, a phosphate material, and an inorganic material. The additive powder, when added to a curable or hardenable resin, forms a mixture where the additive powder is about 20-30%, by weight, of the mixture. The resin can be styrenic, olefinic, acrylic, cellulosic, polyester, or polyamide such as are commonly used in the manufacture of fiberglass reinforced structures and moldable plastics.
    Type: Grant
    Filed: August 5, 2004
    Date of Patent: August 16, 2005
    Assignee: Avtec Industries, Inc.
    Inventors: Kevin Schell, John B. Rowen, Anthony S. Camarota
  • Patent number: 6893583
    Abstract: A flame-retardant curable resin composition which comprises (1) a polymerizable vinyl monomer having a glass transition temperature of its homopolymer of at most 0° C., (2) a polymerization initiator, (3) a reducing agent and (4) a flame retardant in an amount of from 25 to 75 parts by mass based on 100 parts by mass of the total of (1) the polymerizable vinyl monomer having a glass transition temperature of its homopolymer of at most 0° C., (2) the polymerization initiator and (3) the reducing agent.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: May 17, 2005
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tetsuya Sakurai, Hidehiro Mihara, Kohichi Taguchi
  • Patent number: 6838503
    Abstract: A resin composition useful for wire and cable covering material is formed by compounding a phosphate ester retardant, boron phosphate, and zinc borate hydrate with a polyphenylene ether group resin or a combination of a polyphenylene ether group resin and an aromatic vinyl group resin, in a specific ratio.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: January 4, 2005
    Assignee: General Electric Compa
    Inventors: Ming Yin, Takuro Kitamura, Atsuo Oshiro, Kenichi Ishiwa, Kazunari Kosaka, Hiroshi Kubo
  • Patent number: 6822026
    Abstract: The present invention relates to a flame-retardant polypropylene resin composition comprising (A) polypropylene resin 20-60% by weight, (B) polyphenylene ether-based resin 1-50% by weight, (C) hydrogenated block copolymer of a vinylaromatic compound and conjugated diene, which mainly is based on vinylaromatic compound, 0.1-15% by weight, (D) aromatic phosphoric ester in phenol strucure 1-20% by weight, (E) polyammonium phosphate 1-20% by weight, and (F) pentaerythritol-based flame retardant auxiliary agent 0.1-13% by weight. The weight ratio of the aromatic phosphoric ester in phenol structure to the polyammonium phosphate is preferably 0.2-5.0. The composition has advanced flame-retardant and heat-resistant property, and processing property.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: November 23, 2004
    Assignee: Sansung General Chemicals Co.
    Inventors: In Sik Jung, Jong Soo Hong, Man Seang Her, Won Beum Jung
  • Patent number: 6809129
    Abstract: A moldable elastomeric intumescent material comprises chlorinated polyethylene, plasticizers, phosphate based foaming agents, char forming materials, antioxidants, intumescent materials, flame retardant materials, and graphite and/or expandable graphite. A curing agent, and optionally a co-curing agent or an accelerator, may further be incorporated into the material to improve the rigidity of the material when it is exposed to fire. The composition also possesses enhanced intumescence and flame retardancy properties by the addition of graphite, and preferably expandable graphite, to the composition.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: October 26, 2004
    Assignee: Delphi Technologies, Inc.
    Inventor: Ismat A. Abu-Isa
  • Patent number: 6800678
    Abstract: Polyolefins, especially polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of a selected hindered amine substituted by an alkoxy, cycloalkoxy or hydroxyalkoxy moiety and a selected organic or inorganic brominated and/or phosphorus containing flame retardant, such as ammonium polyphosphate or decabromodiphenyl oxide wherein the amount of organic or inorganic flame retardant required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when the hindered amine is not present.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: October 5, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Douglas Wayne Horsey, Stephen Mark Andrews, Leonard Harris Davis, Darrell David Dyas, Jr., Robert Leo Gray, Anunay Gupta, Bruce Vincent Hein, Joseph Stephen Puglisi, Ramanathan Ravichandran, Paul Shields, Rangarajan Srinivasan
  • Publication number: 20040167267
    Abstract: The invention relates to a process for the preparation of an aqueous dispersion of halogenated vinyl polymers by polymerization, according to which, after polymerization, a basic agent is added in an amount such that the pH of the aqueous dispersion is less than approximately 5. The invention also relates to the aqueous dispersion obtained, which can be coated onto polymeric substrates made of paper or of regenerated cellulose.
    Type: Application
    Filed: February 24, 2004
    Publication date: August 26, 2004
    Applicant: SOLVAY (SOCIETE ANONYME)
    Inventors: Yves Vanderveken, Bernard Guenaire, Xavier Bacque
  • Patent number: 6780914
    Abstract: The present invention provides a flame retardant resin composition, or more particularly, a flame retardant polypropylene resin composition which comprises polypropylene having improved flow melt characteristics, flame retardants, a flame retardant aid, and a tetrafluoroethylene polymer. The composition of the present invention has high melt tension, without deterioration of the mechanical properties of flame retardant polypropylene, and drastically enhanced characteristics of shape maintenance and a flaming drip during burning.
    Type: Grant
    Filed: November 4, 2002
    Date of Patent: August 24, 2004
    Assignee: Samsung General Chemicals Co., Ltd.
    Inventors: In-Sik Jung, Man-Seang Her, Jong-Su Hong, Sung-Man Lee
  • Patent number: 6765046
    Abstract: Products based on polymethylmethacrylate (PMMA) so resistant to yellowing and so highly transparent that even the edges of plates produced from this material have a neutral colour, i.e. do not display any yellow tone. This effect is obtained by the admixture of 5 to 50 ppm inorganic, reducing phosphorus compounds after polymerisation. This enables the brightener content to be reduced under 10 ppb, and so the end product may also be used in contact with foodstuffs.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: July 20, 2004
    Assignee: Roehm GmbH & Co. KG
    Inventors: Uwe Numrich, Michael Wicker, Klaus Albrecht, Heinz Vetter, Hermann Jaksch, Ernst Mohr
  • Patent number: 6756430
    Abstract: A flame-retarding thermoplastic resin composition which is composed essentially of (A) a component of thermoplastic resin, (B) a component of nitrogen atom-containing phosphatic compound, (C) a component of hydroxyl group-containing compound or partly esterified product thereof and (D) a component of neutralizer for acids, with optional component (E) of triazine derivative or (F) of metal alkoxide, wherein the proportion of each component is such that the component (A) is in the range from 60 to 90 parts by weight, the sum of the components (B)+(C) is in the range from 10 to 40 parts by weight and the component (D) is in the range from 0.1 to 5 parts by weight, per 100 parts by weight of the total sum of (A)+(B)+(C), respectively, wherein the weight ratio of (B)/(C) amounts to at least 1.
    Type: Grant
    Filed: June 12, 2001
    Date of Patent: June 29, 2004
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yuichi Matsuda, Mikio Hashimoto, Ikunori Sakai
  • Patent number: 6753370
    Abstract: A resin composition comprises a copolymer (A) comprising ethylene as a major component produced with a single-site catalyst, and an ethylene-vinyl alcohol copolymer (B) having an ethylene content of 20-60 mol. % and a degree of hydrolysis of 95% or above, the resin composition satisfying the equation (1): 1/99≦{weight of (A)}/{weight of (B)}≦<99/1  (1) A preferred resin composition comprises a copolymer (A) which has a density of 0.90-0.94 g/cm3 and the resin composition further comprises a carboxylic acid-modified polyolefin (C) and satisfies the equations (2) and (3): 60/40≦{weight of (A)}/{(weight of (B)}≦: 99/1  (2) 0.1/99.9≦X≦: 20/80  (3) wherein X={weight of (C)}/{total weight of (A) and (B)}. Another preferred resin composition comprises a copolymer (A) which has a density of 0.85-0.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: June 22, 2004
    Assignee: Kuraray Co., Ltd.
    Inventors: Shigeki Nakatsukasa, Hiroyuki Ohgi, Kazuyori Yoshimi
  • Patent number: 6730726
    Abstract: The invention relates to a process for the preparation of an aqueous dispersion of halogenated vinyl polymers by polymerization, according to which, after polymerization, a basic agent is added in an amount such that the pH of the aqueous dispersion is less than approximately 5. The invention also relates to the aqueous dispersion obtained, which can be coated onto polymeric substrates made of paper or of regenerated cellulose.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: May 4, 2004
    Assignee: Solvay (Societe Anonyme)
    Inventors: Yves Vanderveken, Bernard Guenaire, Xavier Bacque
  • Publication number: 20040059035
    Abstract: A polymeric composition comprises a thermosetting resin and a polyolefin resin that cures to a semi-interpenetrating polymer network and is useful for producing plastic shipping and storage containers. The containers exhibit one or more friction surfaces, and can include fire resistance and other properties derived from property enhancing agents.
    Type: Application
    Filed: September 26, 2003
    Publication date: March 25, 2004
    Applicant: 3M Innovative Properties Company
    Inventors: John E. Krech, Paul D. Driscoll, James R. Harrison, Denis M. Miling, Domasius Nwabunma, Mario A. Perez, Donald F. Reuter
  • Publication number: 20040054054
    Abstract: The present invention relates to fire-retarded compositions comprising, by weight, the total being 100 parts:
    Type: Application
    Filed: June 24, 2003
    Publication date: March 18, 2004
    Applicant: ANTOFINA
    Inventors: Philippe Blondel, Benoit Brule, Nicolas Frenois, Jean-Jacques Flat
  • Patent number: 6686403
    Abstract: A paint has a film-forming binder component, a color-producing component, and a fire-retardant component adapted to least substantially protect from fire a surface of which the paint is applied; and the paint is produced by a method including providing a film-forming binder component; providing a color-producing component; mixing the components with some of dried powder components missing; and adding afire retardant component to replace the dry powder component.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: February 3, 2004
    Assignee: Moles Technology a.s.
    Inventors: Roman Magdina, Bohuslav Jacko
  • Publication number: 20030212177
    Abstract: Fire retardant compositions and methods of making and using the same are provided. The fire retardant compositions are comprised of at least one fire retardant component, including at least one ammonium polyphosphate and at least one biopolymer having a weight average particle diameter of less than about 100 microns. In a specific embodiment, the fire retardant composition is comprised of a xanthan biopolymer.
    Type: Application
    Filed: April 23, 2003
    Publication date: November 13, 2003
    Inventors: Howard L. Vandersall, Gary H. Kegeler
  • Publication number: 20030204004
    Abstract: Fire retardant compositions and methods of making and using the same are provided. The fire retardant compositions are comprised of at least one fire retardant component, including at least one ammonium polyphosphate and at least one biopolymer having a weight average particle diameter of less than about 100 microns. In a specific embodiment, the fire retardant composition is comprised of a xanthan biopolymer.
    Type: Application
    Filed: April 23, 2003
    Publication date: October 30, 2003
    Inventors: Howard L. Vandersall, Gary H. Kegeler
  • Patent number: 6639045
    Abstract: A method of producing an aliphatic polyester, including polycondensing an aliphatic diol and an aliphatic dicarboxylic acid compound, or a prepolymer thereof in the presence of a metal-containing ester interchange catalyst and a phosphorus-containing co-catalyst such as an ammonium, calcium or magnesium salt of hydrogen-containing phosphoric acid or an organic phosphinic acid. An oxycarboxylic acid compound or its prepolymer may also be used as a raw material.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: October 28, 2003
    Assignees: National Institute of Advanced Industrial Science and Technology
    Inventors: Takashi Masuda, Amin Cao
  • Patent number: 6635697
    Abstract: The present invention provides a flame-retardant which is not only excellent in flame-retarding property but also devoid of lowering moisture-resisting property specially in the course of molding of a resin so that the flame-retardant has little limitation for the molding method, the molding conditions and the intended use thereof. What is characterized is a flame-retardant comprising (a) an aliphatic amine salt of a phosphoric ester with 2-25 carbon atoms in the ester moiety thereof having a melting point of at least 100° C. but not more than a molding temperature of a thermoplastic resin and (b) a salt of phosphoric and/or polyphosphoric acid, the proportion of the component (a) to the component (b), i.e. (a)/(b) being 1/2-5/1 by weight ratio.
    Type: Grant
    Filed: January 24, 2001
    Date of Patent: October 21, 2003
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Tetsuo Kuwaki, Yasunobu Nakamura, Yasuhiro Muneuchi
  • Publication number: 20030139492
    Abstract: A moldable elastomeric intumescent material comprises chlorinated polyethylene, plasticizers, phosphate based foaming agents, char forming materials, antioxidants, intumescent materials, flame retardant materials, and graphite and/or expandable graphite. A curing agent, and optionally a co-curing agent or an accelerator, may further be incorporated into the material to improve the rigidity of the material when it is exposed to fire. The composition also possesses enhanced intumescence and flame retardancy properties by the addition of graphite, and preferably expandable graphite, to the composition.
    Type: Application
    Filed: January 23, 2002
    Publication date: July 24, 2003
    Inventor: Ismat A. Abu-Isa
  • Patent number: 6596202
    Abstract: Cellulosic materials such as wood chips, textile fibers and the like are treated to produce products such as particle board having enhanced fire and heat resistant properties. For example, wood chips are saturated with an eqimolar aqueous solution of monoammonium phosphate and diammonium phosphate. A metal hydroxide is added to the solution. The saturated wood chips are dried and mixed with a modified glue composition. The glue that which contains urea formaldehyde and/or phenolic resin is in powdered form and dissolved in water. The treated wood chips and modified glue is then mixed, formed into a mat and placed under pressure at about 120° C. for 8 to 15 minutes. The pressure may range from about 300 to 400 psi.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: July 22, 2003
    Assignee: Cool Dot Ltd.
    Inventor: Ghassan F. Afiouni
  • Publication number: 20030130394
    Abstract: The present invention provides a flame retardant resin composition, or more particularly, a flame retardant polypropylene resin composition which comprises polypropylene having improved flow melt characteristics, flame retardants, a flame retardant aid, and a tetrafluoroethylene polymer. The composition of the present invention has high melt tension, without deterioration of the mechanical properties of flame retardant polypropylene, and drastically enhanced characteristics of shape maintenance and a flaming drip during burning.
    Type: Application
    Filed: November 4, 2002
    Publication date: July 10, 2003
    Inventors: In-Sik Jung, Man-Seang Her, Jong-Su Hong, Sung-Man Lee
  • Patent number: 6590013
    Abstract: A hardener for use in urea-formaldehyde and urea-melamine-formaldehyde based adhesives comprises a polyvinyl acetate emulsion together with a metal chloride and an ammonium salt. The adhesive composition comprising a urea-formaldehyde or urea-melamine-formaldehyde resin, and the above hardener provides an increased curing rate, an acceptable viscosity, better adhesion and greater tolerance towards substrate type.
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: July 8, 2003
    Assignee: A/S F. Heimann & Co.
    Inventors: Bjørn Andersen, Bo Gao Brehmer