Solid Polymer Derived From At Least One Diene Monomer Patents (Class 524/426)
  • Patent number: 4419497
    Abstract: According to the present invention, there is disclosed a process for producing a novel resin which comprises the step of copolymerizing a five-member cyclic compound (component A) having a conjugated double bond and represented by the general formula (A) given below: ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers not less than 1 and are in the relation of m+n=6; and/or a Diels-Alder addition product thereof (A) with a co-dimer (component B) of said five-member cyclic compound and 1,3-butadiene by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 200.degree. C. to 350.degree. C. Also disclosed are a process for hydrogenating said novel resin to produce a novel hydrogenated resin and resin compositions containing said hydrogenated resin.
    Type: Grant
    Filed: May 17, 1982
    Date of Patent: December 6, 1983
    Assignee: Nippon Oil Company, Limited
    Inventors: Shozo Tsuchiya, Akio Oshima, Hideo Hayashi
  • Patent number: 4414340
    Abstract: A thermosetting composition exhibiting improved physical properties and little or no blistering is provided consisting essentially of a CO.sub.2 or O.sub.2 terminated high vinyl alkadiene polymer, an inorganic filler, an organic peroxide compound, and a polyolefin modifier.
    Type: Grant
    Filed: February 15, 1983
    Date of Patent: November 8, 1983
    Assignee: Phillips Petroleum Company
    Inventors: Guy Senatore, Ralph C. Farrar
  • Patent number: 4413067
    Abstract: According to the present invention, there is disclosed a process for producing a novel resin which comprises the step of copolymerizing a five-member cyclic compound (component A) having a conjugated double bond and represented by the general formula (A) given below:GENERAL FORMULA (A): ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers not less than 1 and are in the relation of m+n=6; and/or a Diels-Alder addition product thereof (A) with a co-dimer (component B) of said five-member cyclic compound and 1,3-butadiene by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 200.degree. C. to 350.degree. C. Also disclosed are a process for hydrogenating said novel resin to produce a novel hydrogenated resin and resin compositions containing said hydrogenated resin.
    Type: Grant
    Filed: May 17, 1982
    Date of Patent: November 1, 1983
    Assignee: Nippon Oil Company, Limited
    Inventors: Shozo Tsuchiya, Akio Oshima, Hideo Hayashi
  • Patent number: 4403059
    Abstract: An adhesive composition based upon an aqueous solution of alkali metal silicate with a content of powdered inorganic filler, having good storage stability, which comprises an aqueous alkali metal silicate solution containing:(a) from 10% to 40% by weight of at least one powdered inorganic filler,(b) a suspension effective amount of at least one zinc soap of a fatty acid having from 12 to 22 carbon atoms and(c) from 0 to about 24% by weight of a 50% by weight stable, aqueous dispersion of an alkali-resistant organic polymer, based on the weight of the total composition.Preferably zinc stearate in amounts of from 1% to 5% by weight are added to the adhesives containing powdered inorganic fillers and optionally organic additives on a base of aqueous water glass solutions, to prevent separation phenomena. Sodium and/or potassium silicate solutions can be used, the sodium silicate solution being preferably present in the ratio by weight of 3.3 to 3.9:1 for SiO.sub.2 /Na.sub.
    Type: Grant
    Filed: February 18, 1982
    Date of Patent: September 6, 1983
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernhard Laut, Wolfgang Friedemann, Gerd Krapp
  • Patent number: 4400478
    Abstract: The invention relates to molding compounds modified with a high 1,2 unsaturated carboxylated styrene-butadiene block polymer and a saturated styrene-alpha-olefin block polymer, said molding compounds containing an unsaturated crosslinkable resin, ethylenically unsaturated monomer, filler, reinforcing agent, catalyst, and thickener.
    Type: Grant
    Filed: December 23, 1982
    Date of Patent: August 23, 1983
    Assignee: Shell Oil Company
    Inventors: William P. Gergen, Walter M. Halper
  • Patent number: 4395512
    Abstract: The invention provides a novel resin composition based on a polyphenylenesulfide resin which can be molded into shaped articles imparted with remarkably improved impact strength, cracking resistance and heat shock resistance. The inventive resin composition comprises 100 parts by weight of a polyphenylenesulfide resin, from 10 to 300 parts by weight of an inorganic filler and from 1 to 100 parts by weight of a fluorine-containing rubber such as a copolymer of vinylidene fluoride and hexafluoropropylene having specified Mooney viscosity.
    Type: Grant
    Filed: May 24, 1982
    Date of Patent: July 26, 1983
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshihiro Kubota, Osamu Kuriyama
  • Patent number: 4394471
    Abstract: The disclosure of this application is directed to compositions having improved flame retardant properties containing an alkylene-alkyl acrylate copolymer, a halogenated flame retardant additive and an oxide, carbonate, hydroxide or sulfate of magnesium or calcium in an amount more than 20 and up to about 30 percent by weight. The compositions disclosed are useful as jacketing material and as insulation about wire and cable.
    Type: Grant
    Filed: February 11, 1981
    Date of Patent: July 19, 1983
    Assignee: Union Carbide Corporation
    Inventor: Michael J. Keogh
  • Patent number: 4376179
    Abstract: This invention relates to hot melt adhesive compositions which include a highly unsaturated hydrocarbon rubber, about 5 to about 100 parts by weight of a neutralized sulfonated elastomeric polymer per 100 parts by weight of the highly unsaturated hydrocarbon rubber, wherein the neutralized sulfonated elastomeric polymer has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated elastomeric polymer, and about 25 to about 200 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, aliphatic dienes and mono- and di-olefins, cyclic olefins of 5 or 6 carbon atoms and hydrogenated polycyclics per 100 parts by weight of the highly unsaturated hydrocarbon rubber.
    Type: Grant
    Filed: October 14, 1980
    Date of Patent: March 8, 1983
    Assignee: Exxon Research and Engineering Co.
    Inventors: Pawan K. Agarwal, Robert D. Lundberg
  • Patent number: 4374178
    Abstract: Calcium carbonate is rendered receptive to silanation by pretreatment with soluble sodium silicate.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: February 15, 1983
    Assignee: Union Carbide Corporation
    Inventors: Ravindra D. Kulkarni, Errol D. Goodard
  • Patent number: 4371652
    Abstract: This invention relates to unique and novel compositions based on chemically combining a sulfonated polymer and a tertiary amine terminated polylactone composition. The resulting amine neutralized sulfonated polymer compositions have a variety of uses including those as diverse as adhesive agents, thermoplastic elastomers, additive uses wherein these materials can be utilized to compatibilize two different polymers which are normally incompatible. These compositions can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.
    Type: Grant
    Filed: December 21, 1981
    Date of Patent: February 1, 1983
    Assignee: Exxon Research and Engineering Co.
    Inventor: Pawan K. Agarwal
  • Patent number: 4371635
    Abstract: In a thermosetting composition containing high vinyl alkadiene polymer, organic peroxide, calcium carbonate filler and optional ingredients comprising a vinyl arene liquid monomer, coupling agent, polymerizable plasticizer, and fiberglass reinforcing filler, the addition of an adduct of polybutadiene and a carboxylic acid anhydride improves properties of the molded compositions comprising flexural modulus, tensile strength and Barcol hardness.
    Type: Grant
    Filed: March 11, 1982
    Date of Patent: February 1, 1983
    Assignee: Phillips Petroleum Company
    Inventor: Guy Senatore
  • Patent number: 4370432
    Abstract: This invention relates to hot melt adhesive compositions which includes a neutralized sulfonated elastomeric polymer having about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated elastomeric polymer, about 25 to about 250 parts by weight of a polyisobutylene per 100 parts of the neutralized sulfonated elastomeric polymer, and about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, aliphatic dienes and mono and diolefins, cyclic olefins of 5 or 6 carbon atoms and hydrogenated poly cyclics per 100 parts by weight of the neutralized sulfonated EPDM terpolymer.
    Type: Grant
    Filed: September 4, 1981
    Date of Patent: January 25, 1983
    Assignee: Exxon Research and Engineering Co.
    Inventors: Pawan K. Agarwal, Robert D. Lundberg
  • Patent number: 4361659
    Abstract: This invention relates to an adhesive composition based upon an aqueous solution of alkali metal silicate with a content of powdered inorganic filler and optionally organic polymer, which comprises an aqueous alkali metal silicate solution containing:(a) from about 25 to 50 percent by weight of dispersed crystalline calcium carbonate;(b) from about 2 to 10 percent by weight of quartz powder with a particle size of up to about 15 .mu.m and a specific surface area of at least about 3.5 m.sup.2 /gm; and(c) from 0 to about 24 percent by weight of a 50 percent by weight stable, aqueous dispersion of an alkali-resistant organic polymer based upon acrylate, styrene/acrylate, styrene/butadiene, or a mixture thereofbased on the weight of the total composition.
    Type: Grant
    Filed: May 20, 1981
    Date of Patent: November 30, 1982
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Friedemann, Bernhard Laut
  • Patent number: 4352906
    Abstract: Fully cured calcium carbonate filled polyisocyanurate/polyurethane sheet molding compositions are improved in blister resistance at temperatures of 175.degree.-205.degree. C. by the incorporation therewith of from 0.05-2% based upon the weight of the carbonate of a polybutadiene telomers maleic anhydride addition products. Such compositions are most blister resistant when the polybutadiene telomer/maleic anhydride addition product is mixed with the resin ingredients prior to the addition of carbonate filler.
    Type: Grant
    Filed: August 6, 1981
    Date of Patent: October 5, 1982
    Assignee: ICI Americas Inc.
    Inventors: Weldon N. Reed, Thomas J. Galvin
  • Patent number: 4351912
    Abstract: The present invention is directed to a trowelable, lightweight, synthetic stucco composition containing a crushable, lightweight aggregate, and specifically to the protection of the lightweight aggregate from substantial particle size reduction during troweling application by providing in the composition a protective amount of a hard, non-crushable aggregate having a protective particle size. The hard aggregate is strong enough to resist the troweling step without crushing, and serves to keep the trowel a spaced distance away from the substrate upon which the stucco composition is applied, to thereby substantially prevent crushable, lightweight aggregates of similar or smaller particle size from crushing, and to limit the crushing of crushable, lightweight aggregates having a larger particle size.
    Type: Grant
    Filed: April 20, 1981
    Date of Patent: September 28, 1982
    Assignee: Northwood Mills Ltd.
    Inventor: F. Bon Jasperson
  • Patent number: 4341213
    Abstract: Nonwoven fabrics are bonded by a binding agent which comprises an aqueous dispersion of an organic polymer coupled to an inorganic filler by means of an organosilane or organotitanate coupling agent. Such fabrics possess properties which render them exceptionally suitable for use as top sheets for disposable diapers and the like.
    Type: Grant
    Filed: August 13, 1981
    Date of Patent: July 27, 1982
    Assignee: The Kendall Co.
    Inventor: Lawrence B. Cohen
  • Patent number: 4335034
    Abstract: Thermoplastic compositions are disclosed which are useful as backings for automotive carpets. The thermoplastic compositions contain a high filler content of at least 60 percent by weight, about 5 to 25 percent by weight of an ethylene homopolymer or copolymer, about 1 to 10 percent by weight of a non-vulcanized elastomeric resin and about 1 to 15 percent by weight of a plasticizer. Preferably a low viscosity precoat of polyethylene or ethylene/vinyl acetate copolymer is applied to the carpet prior to the application of the thermoplastic backing. The backed automotive carpet is moldable, withstands both high and low temperatures, possesses outstanding sound absorbing properties and can be produced economically.
    Type: Grant
    Filed: May 12, 1980
    Date of Patent: June 15, 1982
    Assignee: J. P. Stevens & Co., Inc.
    Inventors: Joseph L. Zuckerman, John W. Bzik
  • Patent number: 4330442
    Abstract: An asbestos-free gasket forming composition is disclosed. The composition is preferably produced by removing water from an aqueous furnish composition comprising phenolic fibers, aromatic polyamide fibers, an inorganic or cork filler, a synthetic rubber binder, and a water insoluble hydroxide produced from a soluble salt selected from the group consisting of aluminum salts, ferric salts and stannic salts, by reaction with a sufficient amount of an alkaline hydroxide to provide a furnish pH within the range of from about 6 to about 10, and preferably of from about 7 to 8.
    Type: Grant
    Filed: May 7, 1980
    Date of Patent: May 18, 1982
    Assignee: Armstrong World Industries, Inc.
    Inventors: Charles M. Lindeman, Ralph D. Andrew