With Water Nrm Patents (Class 524/446)
  • Patent number: 11499136
    Abstract: The present invention provides a cell culture substrate including a polymer having a lower critical solution temperature, the substrate including one or more inorganic materials selected from a water-swellable clay mineral and silica and further including an adhesive matrix in the substrate, in which the adhesive matrix is an extracellular matrix and/or an adhesive synthetic matrix. Furthermore, the invention is to provide a cell culture substrate in which the extracellular matrix is at least one selected from laminin, fibronectin, vitronectin, cadherin, and fragments thereof, and/or the adhesive synthetic matrix is poly[2-(methacryloyloxy)ethyl dimethyl-(3-sulfopropyl) ammonium hydroxide] or an oligopeptide-supporting polymer.
    Type: Grant
    Filed: December 12, 2017
    Date of Patent: November 15, 2022
    Assignee: DIC Corporation
    Inventors: Tetsuo Takada, Naoto Sakurai, Ayako Isshiki, Noriko Santou
  • Patent number: 10730963
    Abstract: A process for preparing aqueous dispersions of polymers containing oxazoline groups, by aqueous emulsion polymerization initiated by free radicals. The polymerization are carried out in two stages. In the first polymerization stage, an ?,?-monoethylenically unsaturated compound having at least one acid group, an monoethylenically unsaturated compound having at least one carboxylic acid amide group, a monoethylenically unsaturated compound having at least one carboxylic acid amide group are copolymerized. In the second polymerization stage, a monoethylenically unsaturated compound having at least one oxazoline group, a monoethylenically unsaturated compound having at least one carboxylic acid amide group and an ethylenically unsaturated compound are copolymerized with the final product from the first polymerization stage.
    Type: Grant
    Filed: July 26, 2016
    Date of Patent: August 4, 2020
    Assignee: BASF SE
    Inventors: Matthias Zorn, Kathrin Michl, Christian Brand
  • Patent number: 9382401
    Abstract: The problem to be solved is to provide a nondrying polymer hydrogel, which is not dried under atmospheric conditions and has excellent mechanical properties, and a method for producing the nondrying polymer hydrogel. A nondrying polymer hydrogel having both excellent nondrying properties and mechanical properties (e.g., excellent elongation properties, compression properties, and surface adhesiveness) can be produced by using a nondrying polymer hydrogel including a deliquescent substance in such a manner that the water vapor pressure shown by the polymer hydrogel is equal to or lower than the water vapor partial pressure in the atmosphere, in particular, by allowing a deliquescent substance to be contained at a high concentration in a polymer hydrogel having a network structure formed by a polymer of a water-soluble radically-polymerizable organic monomer having a specific chemical composition and a delaminated water-swellable clay mineral.
    Type: Grant
    Filed: June 19, 2013
    Date of Patent: July 5, 2016
    Assignees: DIC Corporation, Kawamura Institute of Chemical Research
    Inventors: Kazutoshi Haraguchi, Katsuhito Kuroki
  • Patent number: 9328216
    Abstract: The present invention relates to improved clayey barriers, such as compacted clay liners or geosynthetic clay liners, which can be used, among other uses, to isolate waste liquids from the environment. More in particular, the present invention relates to clay which is treated with an anionic polymer and is subsequently dehydrated before it is used as a barrier. The latter improved clays are surprisingly well, and for a long term, protected from chemical attack by aggressive electrolyte solutions present in, for example, sea water or waste liquids.
    Type: Grant
    Filed: August 24, 2011
    Date of Patent: May 3, 2016
    Assignee: Universiteit Gent
    Inventor: Gemmina Di Emidio
  • Patent number: 9296861
    Abstract: Methods of preparing a polyaniline homopolymer or copolymer comprising at least one carboxylic acid group, and homopolymers or copolymers arising therefrom, the methods comprising: preparing a solution of a polyaniline precursor having at least one aromatic amine group and at least one carboxylic acid group (eg. 2-aminobenzoic acid, 3-aminobenzoic acid or 4-aminobenzoic acid) in a solvent selected from aqueous methanesulfonic acid or aqueous ammonia and optionally one or more additional polyaniline precursors (such as aniline); and oxidatively polymerising the polyaniline precursor or precursors.
    Type: Grant
    Filed: March 27, 2012
    Date of Patent: March 29, 2016
    Assignee: AUCKLAND UNISERVICES LIMITED
    Inventors: Sudip Ray, Allan James Easteal, Ralph Cooney
  • Patent number: 8957135
    Abstract: The present invention relates to a composite powder, preparation and use thereof. The composite powder according to the present invention is prepared by intimately mixing an irradiated or non-irradiated rubber latex with a slurry of inorganic particles in a ratio corresponding to that of rubber particles to inorganic particles in the composite powder according to the present invention, and then drying the resultant mixture. The composite powder according to the present invention comprises agglomerates composed of powdery rubber particles and inorganic particles, with inorganic particles being uniformly distributed either inside the agglomerats or both inside the agglomerates and on the surfaces thereof. The composite powder according to the present invention can be easily dispersed in plastic matrixes and thus can be compounded with plastics to produce toughened plastics and thermoplastic elastomers.
    Type: Grant
    Filed: December 31, 2012
    Date of Patent: February 17, 2015
    Assignees: China Petroleum & Chemical Corporation, Sinopec Beijing Research Institute of Chemical Industry
    Inventors: Yiqun Liu, Jinliang Qiao, Xiaohong Zhang, Fan Huang, Jianming Gao, Banghui Tan, Genshuan Wei, Zhihai Song, Zhida Chen
  • Patent number: 8927640
    Abstract: A nitrile copolymer latex composition containing a latex of a nitrile copolymer rubber (A) having ?,?-ethylenically unsaturated nitrile monomer units in 10 to 75 wt %, conjugated diene monomer units in 5 to 89.9 wt %, and cationic monomer units and/or monomer units able to form cations in 0.1 to 20 wt %, an inorganic filler (B) having an aspect ratio of 30 to 2,000, and a plasticizer (C) having an SP value by the HOY method of 8 to 10.2 (cal/cm3)1/2, wherein a content of said plasticizer (C) is 0.1 to 200 parts by weight with respect to said nitrile copolymer rubber (A) as 100 parts by weight is provided.
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: January 6, 2015
    Assignee: Zeon Corporation
    Inventors: Akira Tsukada, Kazuhiro Ejiri, Chikara Katano
  • Patent number: 8912264
    Abstract: It is an object of the present invention to provide an aqueous ethylene-vinyl alcohol-based copolymer dispersion which is excellent in long-term storage stability and in film-forming properties even when subjected to low-temperature or short-time drying or applied to give thick coats and can give coatings showing high gas barrier performance. The prevent invention is an aqueous ethylene/vinyl alcohol-based copolymer dispersion, which comprises: (A) an ethylene/vinyl alcohol-based copolymer with an ethylene content of 15-65 mole percent and a degree of saponification of not lower than 80 mole percent, (B) a base-neutralized ethylene/?,?-unsaturated carboxylic acid-based copolymer and (C) a polyvinyl alcohol with a degree of saponification of 75-100 mole percent and a degree of polymerization of 100-3500, the content of the polyvinyl alcohol (C) being 0.5-100 parts by weight per 100 parts by weight of the ethylene/vinyl alcohol-based copolymer (A).
    Type: Grant
    Filed: November 25, 2005
    Date of Patent: December 16, 2014
    Assignees: Sumitomo Seika Chemicals Co., Ltd., Kuraray Co., Ltd.
    Inventors: Yuhei Funabiki, Norihiro Sugihara, Kazutoshi Terada, Yukio Ozeki, Michiyuki Nanba
  • Publication number: 20140364511
    Abstract: A stable, aqueous composition containing a crosslinked, nonionic, amphiphilic polymer capable of forming a yield stress fluid in the presence of a surfactant is disclosed. The yield stress fluid is capable of suspending insoluble materials in the form of particulates and/or droplets requiring suspension or stabilization.
    Type: Application
    Filed: September 13, 2012
    Publication date: December 11, 2014
    Applicant: LUBRIZOL ADVANCED MATERIALS, INC.
    Inventors: Krishnan Chari, Shui-Jen Raymond Hsu, Wei-Yeih Yang, Prachur Bhargava, Murat Kadir
  • Publication number: 20140316043
    Abstract: The present invention concerns aqueous polymer compositions comprising a water soluble hydrophilic polymer with poly(ethylene oxide) content higher than 50% by weight and a polyacrylic thickener containing sulfonic groups. The aqueous polymer compositions of the invention are useful as deflocculants, rheology modifiers and water retention agents for paper coating compositions.
    Type: Application
    Filed: November 7, 2012
    Publication date: October 23, 2014
    Inventors: Franco Federici, Vittorio Betti, Thierry Bossi, Christian Parisi, Riccardo Vago, Giovanni Floridi, Giuseppe Li Bassi
  • Patent number: 8846796
    Abstract: A method for producing a modified smectite or smectite-containing substance including treating a non-activated smectite or substance with a water soluble activating agent and polymer in a two stage process, the first stage including adding 0-3.0% of the activating agent and 0.05-1.0% of the polymer, by weight, and in a second stage adding 0-5.0% of the activating agent 0.3-5% of the polymer, by weight, to the mixture of the first stage, wherein at least a part of the polymer is added as a dry solid and the water in the first stage is at least 20% by weight and at most 50% by weight in the second stage.
    Type: Grant
    Filed: April 22, 2008
    Date of Patent: September 30, 2014
    Assignee: Trisoplast International B.V.
    Inventors: Oszkar Libor, Jacobus Cornelis Wammes
  • Publication number: 20140287206
    Abstract: The invention provides a white ink composition for inkjet recording, including: titanium dioxide having an average primary particle diameter of from 200 nm to 350 nm; a hydrophilic, layered clay mineral; a water-soluble resin; and water. The invention further provides: an ink set for multilayer formation including the white ink composition and an ink composition for inkjet recording, including a colorant having a hue other than white; an image forming method including applying the white ink composition to a recording medium and irradiating the white ink composition applied to the recording medium with an active energy ray; and a printed matter including an image formed on a recording medium by the image forming method.
    Type: Application
    Filed: February 27, 2014
    Publication date: September 25, 2014
    Applicant: FUJIFILM CORPORATION
    Inventors: Misato SASADA, Hiroshi YAMAMOTO
  • Publication number: 20140288208
    Abstract: An ink composition for an inkjet including titanium dioxide having an average primary particle diameter of 200 nm or more; a water-soluble resin; self-dispersing resin particles having an average particle diameter of 40 nm or less; and water.
    Type: Application
    Filed: February 17, 2014
    Publication date: September 25, 2014
    Applicant: FUJIFILM CORPORATION
    Inventors: Misato SASADA, Hiroshi YAMAMOTO
  • Patent number: 8722785
    Abstract: Provided is a composite of saponified product of an ethylene-vinyl ester-based copolymer from which films excellent in gas barrier properties and film rigidity and highly inhibited from having fish eyes are obtained. It is a process for producing a composite of saponified product of an ethylene-vinyl ester-based copolymer, which comprises: mixing a composition (a) containing a saponified product of ethylene-vinyl ester-based copolymer (A1) and having a moisture content of 50% by weight or higher with a water-swellable layered inorganic compound (B) to obtain a composition (C); and mixing the composition (C) in the state of having a moisture content of 10% by weight or higher and less than 60% by weight with a saponified product of ethylene-vinyl ester-based copolymer (A2).
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: May 13, 2014
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventor: Shouichi Kani
  • Publication number: 20140113144
    Abstract: The invention relates to a superhydrophobic coating composition containing a polyurethane; a fluoropolymer; a nanofiller; and an organic solvent. The polyurethane to fluoropolymer are present in a weight ratio from about 1:2 to about 15:1. Coated substrate having at least a portion of one surface coated with a hydrophobic coating using the superhydrophobic coating composition are disclosed as are methods for forming a superhydrophobic coating on a substrate. The invention also relates to a method of forming a superhydrophobic coating on a surface of a substrate by spray casting a superhydrophobic coating composition onto a surface of a substrate to form a coating using an ultrasonic nozzle or at an air pressure of about 20 to about 60 psi and from a height of about 3 to about 12 inches above the surface to form a coating, and curing the coating.
    Type: Application
    Filed: June 8, 2012
    Publication date: April 24, 2014
    Applicant: UNIVERSITY OF VIRGINIA PATENT FOUNDATION
    Inventors: Eric Loth, Adam Steele, Ilker Bayer
  • Publication number: 20140080956
    Abstract: A hydrogel having mechanical properties and capable of being produced simply by using and mixing an industrially obtainable polymer having high versatility and clay particles, and to provide a method of producing the hydrogel. A hydrogel-forming composition is characterized by containing a polyelectrolyte, clay particles, and a dispersant for the clay particles.
    Type: Application
    Filed: May 15, 2013
    Publication date: March 20, 2014
    Inventors: Hiroyuki TAKENO, Wataru NAKAMURA
  • Patent number: 8652430
    Abstract: The present invention provides an organic dispersion of inorganic platelets, which includes an organic solvent and H-form inorganic platelets dispersed therein. The H-form inorganic platelets have a particle size of between about 20 and 80 mm and the organic dispersion has a sold content of between about 1 and 20 wt %. A method for forming the organic dispersion is also provided.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: February 18, 2014
    Assignee: Industrial Technology Research Institute
    Inventors: Chih-Jen Yang, Chyi-Ming Leu, Chun-Wei Su
  • Patent number: 8648137
    Abstract: A nitrile copolymer latex composition containing a latex of a nitrile copolymer rubber (A) having ?,?-ethylenically unsaturated nitrile monomer units in 10 to 75 wt %, conjugated diene monomer units in 5 to 89.9 wt %, and cationic monomer units and/or monomer units able to form cations in 0.1 to 20 wt %, an inorganic filler (B) having an aspect ratio of 30 to 2,000, and a plasticizer (C) having an SP value by the HOY method of 8 to 10.2 (cal/cm3)1/2, wherein a content of said plasticizer (C) is 0.1 to 200 parts by weight with respect to said nitrile copolymer rubber (A) as 100 parts by weight is provided.
    Type: Grant
    Filed: January 29, 2009
    Date of Patent: February 11, 2014
    Assignee: Zeon Corporation
    Inventors: Akira Tsukada, Kazuhiro Ejiri, Chikara Katano
  • Patent number: 8598262
    Abstract: The present invention provides methods, admixture compositions for treating clay-bearing aggregates used for construction purposes, and aggregate compositions for construction purposes. The clay-bearing aggregates are treated with a cationic copolymer made from two and preferably three different monomer components. Cementitious compositions containing the treated aggregates are also described.
    Type: Grant
    Filed: May 13, 2013
    Date of Patent: December 3, 2013
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Lawrence L. Kuo, Ying Chen
  • Publication number: 20130303670
    Abstract: Multicolor thermal imaging members are described that comprise color-forming layers that are separated by thermally-insulating layers and can be addressed with a thermal printing head in contact with a surface to form an image. The thermally-insulating layers are designed to be as thin as possible consistent with at least partially independent addressing of the color-forming layers, and are formulated so as not to lead to instabilities either before or after printing or to give rise to dimensional changes of a thermal imaging member when it is subjected to changes in temperature or humidity. Coating compositions for manufacturing such thermally-insulating layers are also provided.
    Type: Application
    Filed: July 18, 2013
    Publication date: November 14, 2013
    Inventors: John C. Day, John Hardin, Yulin Hardin, Fariza B. Hasan, Stephen Telfer, William T. Vetterling
  • Patent number: 8580873
    Abstract: The present invention relates to an aqueous dispersion comprising (a) at least one (meth)acrylic polymer; (b) at least one vinyl acetate polymer selected from vinyl acetate homopolymer and vinyl acetate copolymers comprising in polymerized form vinyl acetate and ethylene; (c) water; and (d) optionally up to 50% by weight of an inorganic filler, based on the total weight of the aqueous dispersion, wherein the weight ratio of (meth)acrylic polymer(s) (a) to vinyl acetate polymer(s) (b) is from 70:30 to 30:70. The aqueous dispersion may be used as a joint compound or sealing compound.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: November 12, 2013
    Assignee: Dow Global Technologies LLC
    Inventors: Larry N. Hyman, Kim Struble
  • Patent number: 8563644
    Abstract: A nitrile copolymer rubber composition obtained by coagulation of a nitrile copolymer latex composition comprised of a latex of a nitrile copolymer rubber (A) having ?,?-ethylenically unsaturated nitrile monomer units in 55 to 80 wt % and cationic monomer units and/or monomer units able to form cations in which an inorganic filler (B) is dispersed is provided. Note that, preferably, the inorganic filler is a clay. According to the present invention, a nitrile copolymer rubber composition giving a nitrile copolymer rubber cross-linked product with an extremely low gasoline permeability and superior in sour gasoline resistance can be provided.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: October 22, 2013
    Assignee: Zeon Corporation
    Inventors: Akira Imada, Haruhiko Fujita, Yoshiyuki Nakamura
  • Patent number: 8557033
    Abstract: A film forming composition and a polymeric film or coating comprising hemicellulose and at least one component selected from the group consisting of plasticizers, cellulose, and an oligomer or polymer, is disclosed, said polymeric film or coating further comprising at least one additive/reactant increasing the liquid/moisture resistance and mixed with and/or reacting with the hemicellulose and said at least one component before or in conjunction with the forming of the film or coating. The use of said film or coating is also disclosed. Further, a method for the manufacture of said polymeric film or coating is disclosed, as well as a method for improving the liquid/moisture resistance of hemicellulose. Said at least one additive/reactant increasing the liquid/moisture resistance is either a cross-linking agent or a hydrophobizing agent. In another preferred embodiment the additive is a 2:1 layered phyllosilicate. The additive forms a nanocomposite with the hemicellulose as a matrix.
    Type: Grant
    Filed: February 19, 2008
    Date of Patent: October 15, 2013
    Assignee: Xylophane AB
    Inventors: Maria Gröndahl, Lisa Bindgard, Paul Gatenholm, Thomas Hjertberg
  • Patent number: 8530564
    Abstract: Disclosed are: an organic-inorganic complex dispersion improved in film formability and adhesion to a base material. The organic-inorganic complex dispersion comprises an aqueous medium and particles of a complex dispersed in the aqueous medium, wherein the complex has a three-dimensional network structure formed by a polymer of a monomer comprising a monomer represented by general formula (1) and at least one inorganic material selected from a water-swellable clay mineral and silica. Also disclosed is an antifogging material manufactured by using the organic-inorganic complex dispersion. Further disclosed is a cell culture substratum improved in the detachability of cells cultured on the substratum, which is manufactured by using the organic-inorganic complex dispersion. Still further disclosed are manufacturing methods for same.
    Type: Grant
    Filed: May 25, 2009
    Date of Patent: September 10, 2013
    Assignees: Kawamura Institute of Chemical Research, DIC Corporation
    Inventors: Tetsuo Takada, Kazutoshi Haraguchi
  • Publication number: 20130190431
    Abstract: The disclosure relates generally to the use of low molecular weight polymers to aggregate mineral components in aqueous mineral slurries to release and separate individual components of the slurry, which may then be recovered from the slurry.
    Type: Application
    Filed: January 23, 2013
    Publication date: July 25, 2013
    Applicant: SORTWELL & CO.
    Inventor: SORTWELL & CO.
  • Patent number: 8461245
    Abstract: The present invention provides methods, admixture compositions for treating clay-bearing aggregates used for construction purposes, and aggregate compositions for construction purposes. The clay-bearing aggregates are treated with a cationic copolymer made from two and preferably three different monomer components. Cementitious compositions containing the treated aggregates are also described.
    Type: Grant
    Filed: February 15, 2011
    Date of Patent: June 11, 2013
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Lawrence L. Kuo, Ying Chen
  • Patent number: 8431641
    Abstract: A composition comprises, based on the total weight of the composition, from 30 to 50 weight percent of an ionomeric telechelic polyalkylene ester comprising from 0.05 to 5 mole percent of sulfonate end groups; from 50 to 70 weight percent of a polycarbonate; from 0.1 to 10 weight percent of an organoclay; and from 2 to 12 weight percent of an impact modifier.
    Type: Grant
    Filed: December 28, 2007
    Date of Patent: April 30, 2013
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Sreepdaraj Karanam, Robert Lee Sherman, Jr., Ganesh Kannan, Steven James Montgomery, Daniel Joseph Brunelle, Enrico Binassi
  • Patent number: 8404040
    Abstract: Disclosed are wax emulsion compositions for curing or sealing concrete and cement formulations, methods for preparing and processes for using the same. The modifiers are applicable to curing or sealing membranes, used in roadways, highways, parking lots and other freshly placed or poured concrete surfaces to retain moisture and achieve high compressive strengths. This invention also relates to materials used to coat, spray, brush, roll etc. on conventional Portland cement concrete mix designs or other applied concrete mixes in formed structural shapes and transport road mix designs, providing an effective layer that controls and minimizes moisture loss from the mix to enable proper curing and achievement of desired compressive strengths. The compositions of the invention further provide for concrete and cement formulations having lower water soluble chloride content.
    Type: Grant
    Filed: July 7, 2009
    Date of Patent: March 26, 2013
    Assignee: Momentive Specialty Chemicals Inc.
    Inventor: Steven J. Wantling
  • Publication number: 20130053499
    Abstract: An aqueous including a particulate polymer having a particle diameter of from 0.5 microns to 150 microns, the polymer including, as copolymerized units, from 0.1% to 50%, by weight based on the polymer weight, monomer having a Hansch parameter of from 2.5 to 10, the polymer having been formed in the presence of a non-formaldehyde reductant such as, for example, from 0.01% to 0.5%, by weight based on the polymer weight, isoascorbic acid; and from 0.1% to 5%, by weight based on polymer weight, thickener is provided as is a method for forming a coated substrate and the coated substrate so formed.
    Type: Application
    Filed: August 20, 2012
    Publication date: February 28, 2013
    Inventors: Megan DONOVAN, Alvin M. MAURICE, Edwin H. NUNGESSER, Wei ZHANG
  • Patent number: 8383715
    Abstract: An aqueous primer dispersion which contains surfactant-stabilized polymer particles, an organic solvent and a mineral thicker, when coated onto a fluorocarbon substrate, significantly increase the bond strength between the fluorocarbon substrate and a subsequently applied water-derived protective coating, provided that the amount of surfactant-stabilized polymer particles in the aqueous primer dispersion, if any, is about 8 wt. % or less.
    Type: Grant
    Filed: May 15, 2008
    Date of Patent: February 26, 2013
    Assignee: Tremco Incorporated
    Inventors: Ge Wang, Dominic R. Cremona
  • Publication number: 20130045384
    Abstract: A fully calcined kaolin pigment extender is provided which has a product Mullite Index (M.I.) of 25.0 or higher. The calcined kaolin pigment extender can be advantageously used in paints to improve scrub and burnish resistance.
    Type: Application
    Filed: August 9, 2012
    Publication date: February 21, 2013
    Applicant: BASF CORPORATION
    Inventors: Ashok Khokhani, Kenneth W. Folmar
  • Patent number: 8367193
    Abstract: The invention relates in one aspect to a post-formulation concentrated nanocomposite dispersion containing an invisible marker dye. The dispersion typically includes a silicate filler and a matrix polymer dispersed in an aqueous medium as well. The dispersions form optically transparent barrier films wherein the dye is effective to indicate film thickness on a substrate. Specific embodiments of this invention include a nanocomposite coating formulation designed to provide transparent high barrier coatings at thicknesses from 1 to 10 microns that include a near infrared (NIR) or infrared (IR) dye that enables rapid measurement of coating thickness and uniformity. The preferred dye imparts no observable color or appearance change, and thus can also function as an identifier for the coating.
    Type: Grant
    Filed: March 19, 2009
    Date of Patent: February 5, 2013
    Assignee: INMAT Inc
    Inventors: Douglas P. Karim, Laxmi Samantara, Carrie A. Feeney, Michele Farrell, Harris A. Goldberg
  • Patent number: 8362132
    Abstract: Aqueous coating composition having a PVC from 78 to 85% and free of non-fugitive coalescing solvent, comprising, based on the total volume solids of the dry coating unless otherwise stated, a) opacifying pigment particles comprising from 3 to 10% titanium dioxide and from 0 to 20% of hollow polymeric particles; b) non-opacifying extender particles comprising calcium magnesium carbonate and/or calcium carbonate and/or nepheline syenite and/or kaolin; c) polymer binder particles of calculated Fox Tg of from 5 to 25° C. having an acid value of from 15 to 65 mg KOH/g of polymer; d) dispersant having weight average molecular weight of at least 3500 Daltons, and wherein the dispersant demand of a mixture of the opacifying pigment particles, other than the hollow polymeric particles, of a) and the extender particles of b) is greater than 0.35 wt %, calculated on the weight of the titanium dioxide and extender particles; e) fugitive coalescing solvent.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: January 29, 2013
    Assignee: Akzo Nobel Coatings International B.V.
    Inventors: Stephen Arthur Wheeler, Richard Barcock, Colin Pearce, Gary Jefferson, Anthony David Woods, Simon Nicholas Emmett, Javier Perez-Amoros
  • Patent number: 8354169
    Abstract: Films or other articles having a barrier coating derived from a concentrated nanocomposite dispersion which includes a silicate filler and a matrix polymer dispersed in an aqueous medium. The dispersions are condensed by selectively removing liquid therefrom to provide high solids coating formulations.
    Type: Grant
    Filed: April 23, 2012
    Date of Patent: January 15, 2013
    Assignee: Im Mat Inc.
    Inventors: Carrie A. Feeney, Harris A. Goldberg, Michele Farrell, Douglas P. Karim
  • Publication number: 20120329906
    Abstract: The present invention relates to the use of at least one inorganic particle having a layered structure and being modified by cation exchange, in particular as a functional additive, as an aldehyde scavenger, in particular as a formaldehyde scavenger, as a curing agent and for improving properties of WBPs, in particular particle boards. The invention relates further to a composition comprising said particles.
    Type: Application
    Filed: March 8, 2011
    Publication date: December 27, 2012
    Applicant: BOREALIS AGROLINZ MELAMINE GMBH
    Inventors: Rene Dicke, Katarina Rot
  • Patent number: 8338522
    Abstract: The instant invention generally provides a process of making a polymer nanocomposite by compounding an organoclay and a melt of a polymer in the presence of water. The instant invention also provides a polymer nanocomposite made by the process.
    Type: Grant
    Filed: July 16, 2009
    Date of Patent: December 25, 2012
    Inventor: Dmitry P. Dinega
  • Patent number: 8324303
    Abstract: A surge-resistant and abrasion resistant flexible insulating enamel has resin in an amount of 12 wt % to 76 wt % per 100 wt % by weight of the enamel, an organic solvent in an amount of 20 wt % to 80 wt % per 100 wt % by weight of the enamel, polyethylene oxide (PEO) intercalated clay in an amount of 0.005 wt % to 16 wt % per 100 wt % by weight of the enamel, and polysilicic acid in an amount of 0.995 wt % to 16 wt % per 100 wt % by weight of the enamel. The clay and polysilicic acid have high dielectric constant to absorb, evenly disperse and evacuate surges, preventing an insulating layer made by the insulating enamel from being damaged from the surge. PEO provides the insulating layer having good flexibility and adhesion.
    Type: Grant
    Filed: July 5, 2011
    Date of Patent: December 4, 2012
    Assignee: Fu Pao Chemical Co., Ltd.
    Inventors: Wei-Jung Yen, Wei-Chih Yang, Chun-Yu Huang
  • Patent number: 8278383
    Abstract: A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.
    Type: Grant
    Filed: March 27, 2012
    Date of Patent: October 2, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Kwok Pong Chan, Sarah Elizabeth Genovese, Erik C. Hagberg, David Bruce Hall, John Lester Maxam, Tara J. Mullen, Roy Ray Odle, Albert Santo Stella, James Mitchell White
  • Patent number: 8273817
    Abstract: A fiber, film or foam includes a plasticizer and a charged claylinked gel (A). The charged claylinked gel (A) includes clay nanoparticles (C) which are crosslinked by a charged polymer (A?) such that any particular clay nanoparticle is linked to at least one other clay nanoparticle by the charged polymer (A?). Methods for producing the fibers, film and foam are also provided.
    Type: Grant
    Filed: September 25, 2008
    Date of Patent: September 25, 2012
    Assignee: SCA Hygiene Products AB
    Inventors: Ingrid Gustafson, Anna Körner, Shabira Abbas, Maria Fanto, Rozalia Bitis, Charlotta Hanson
  • Patent number: 8273818
    Abstract: A non-halogenated elastomeric latex is disclosed, using as flame retardants, an aqueous dispersion of organoclay and a conventional non-halogenated flame retardant, of which less is needed than conventionally, because of the use of the organoclay. The latex can become a film, sheet, or other article.
    Type: Grant
    Filed: November 21, 2008
    Date of Patent: September 25, 2012
    Assignee: PolyOne Corporation
    Inventor: Stephen D. Horton
  • Publication number: 20120146297
    Abstract: The present invention refers to a textile formed by fiberglass impregnated with a water base elastomeric mixture, to substitute the aromatic base solvent elastomeric mixture and other types (acetates, ketones, alcohols, aliphatics, gas solvents, chlorates, glycoethers and mixtures such as Thinner Standard) used in the entire world and by doing so, offer a non-contaminating product to both the environment as well as to humans, given that it can cause brain, movement, cognitive, and learning problems through the inhalation of the solvent in the environment as it acts as a VOC contaminant given the high carbon content and the evaporation at room temperature which the solvent exhibits.
    Type: Application
    Filed: December 7, 2011
    Publication date: June 14, 2012
    Inventor: Juan Antonio MAYER GOYENECHEA CABALLERO
  • Publication number: 20120136105
    Abstract: A water-borne stain blocking primer comprises a) from about 10 to about 30 wt % of a water-dispersible, hydrophobic alkyd resin having an acid number of less, than 40 KOH/g, b) from about 5 to about 30 wt % of a pigment, the pigment having an average aspect ratio of at least 3:3:1; c) from about 0.05 to about 3 wt % of a tannin chelation agent; d) from about 0 to about 20 wt % of a water-dispersible, hydrophobic free-radically polymerized copolymer; e) a hydrophobically modified associative rheology modifier in an amount effective to provide a water-borne primer having an ICI viscosity of from about 0.5 to about 3.0 poise; and a KU viscosity range of from about 80 to about 120 Krebs units; and f) water. The water-borne primer has a VOC content of less than 5%. Methods of preparing and using such water-borne stain blocking primers also are described.
    Type: Application
    Filed: November 22, 2011
    Publication date: May 31, 2012
    Inventors: Matthew S. Gebhard, Cynthia Baricos
  • Patent number: 8182920
    Abstract: A concentrated nanocomposite dispersion which includes a silicate filler and a matrix polymer dispersed in an aqueous medium. The dispersions are condensed by selectively removing liquid therefrom, to provide high solids coating formulations. The concentrated formulations provide coatings which are good barriers to oxygen and other gases.
    Type: Grant
    Filed: September 14, 2007
    Date of Patent: May 22, 2012
    Assignee: Inmat Inc.
    Inventors: Carrie A. Feeney, Harris A. Goldberg, Michele Farrell, Douglas P. Karim
  • Patent number: 8168698
    Abstract: A method for producing random form of nanosilicate platelets comprises mixing and acidifying an exfoliating agent with an inorganic acid to form an acidified exfoliating agent; intercalating layered inorganic silicate clay with the acidified exfoliating agent to form a mixture; and dissolving the mixture in a solvent and reacting it with a hydroxide or chloride of alkali metal or alkaline-earth metal. The hyperbranched polyamines serving as the exfoliating agent are prepared by polymerizing poly(oxypropylene)-triamine and diglycidyl ether of bisphenol-A (DGEBA). Hydrophilic amine groups of the exfoliating agent are acidified and then reacted with the layered inorganic silicate clay through cation exchange reaction and physical clay exfoliation to give random form of nanosilicate platelets.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: May 1, 2012
    Assignee: National Taiwan University
    Inventors: Jiang-Jen Lin, Chih-Wei Chiu, Chien-Chia Chu
  • Publication number: 20120095128
    Abstract: A colorant composition for tinting or coloring surface coverings or paint is. provided that has a low volatile organic compound (VOC) concentration, alkylphenoi ethoxylate surfactants (APE) free and hazardous air pollutants (HAPS) free. Additionally, the colorant composition has performance properties substantially equal to or better than tinters possessing high VOC concentrations. The colorant composition includes a colorant component, a dispersant including a polyamide, a surface active agent, water, and optional additives, The polyamide is a high molecular weight polyamide. having at least two anchoring amines, and the surface active agent includes phosphoric acid, phosphate esters, or salts thereof.
    Type: Application
    Filed: October 1, 2009
    Publication date: April 19, 2012
    Applicant: BASF Corporation
    Inventors: Nilanjan Chakrabarti, Lee E. Young, Nancy Almasarweh, Shakera Thamanna, Christopher Flanders, William M. Wunch, Amrit P. Bindra
  • Patent number: 8158243
    Abstract: A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.
    Type: Grant
    Filed: March 10, 2011
    Date of Patent: April 17, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Kwok Pong Chan, Sarah Elizabeth Genovese, Erik C. Hagberg, David Bruce Hall, John Lester Maxam, Tara J. Mullen, Roy Ray Odle, Albert Santo Stella, James Mitchell White
  • Publication number: 20120082791
    Abstract: Waterborne, polymer based coating compositions for interior and exterior use on elastomeric substrates (such as tires) with one or more polymer latex resins (having one or more carboxylic acid groups) in an amount sufficient to provide polymer solids in an amount of from 5 to 50% by weight of the coating; optionally one or more coalescing agents in an amount effective to coalesce and fuse polymer particles of the polymer latex resin into a relatively stretchable film when cured; one or more defoaming agents in an amount effective to enhance foam dissipation prior to film formation; one or more coupling agents having a first reactive group which is capable of bonding with the one or more carboxylic acid groups and a second reactive group which is capable of bonding with an elastomers substrate. Also, a method for applying such compositions to elastomeric substrates, such as tires.
    Type: Application
    Filed: September 20, 2011
    Publication date: April 5, 2012
    Inventor: Robert Richard Liversage
  • Patent number: 8133933
    Abstract: Phenolic resin binder systems for sand molds, used in metal casting, which improve the quality of thermally reclaimed sand, are described. The substantial or complete elimination of calcium compounds (e.g., calcium stearate and calcium hydroxide, conventionally employed as a mold lubricant and a resin curing catalyst, respectively) allows the thermally reclaimed sand to be reused over multiple thermal reclamation cycles without the adverse effects previously encountered.
    Type: Grant
    Filed: August 11, 2006
    Date of Patent: March 13, 2012
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Richard Rediger, Edward Lucas
  • Patent number: 8115134
    Abstract: An arc extinguishing resin processed article having excellent flame retardancy is disclosed, in which the contribution to rise in inner pressure is small, a pyrolysis gas that can efficiently extinguish an arc generated upon the interruption of a circuit can be generated, and heat resistance withstanding the rise in temperature generated in such a case and pressure resistance withstanding the rise in inner pressure are provided, and a circuit breaker using the arc extinguishing resin processed article are disclosed. The arc extinguishing resin processed article comprises a resin composition comprising (A) a polyolefin resin containing a hydroxyl group in an amount of from 0.2 to 0.
    Type: Grant
    Filed: May 11, 2009
    Date of Patent: February 14, 2012
    Assignee: Fuji Electric Fa Components & Systems Co., Ltd.
    Inventors: Hironori Yanase, Toshiyuki Kanno, Shuichi Sugiyama
  • Patent number: 8063119
    Abstract: Barrier coating mixtures contain in a carrier liquid, (a) a non-elastomeric polymer; (b) an exfoliated layered platelet-like silicate filler which may or may not have been acid or base treated that has not been functionalized with organic cations having an aspect ratio greater than 25; and (c) at least one additive, wherein the total solids content is less than 30% and the amount of filler is between 5% to about 60% of the total solids content. Coated articles and containers, freestanding films and packaging films are produced using the barrier coating mixtures. Methods of manufacturing such coated products are also encompassed.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: November 22, 2011
    Assignee: InMat Inc.
    Inventors: Carrie A. Feeney, Harris A. Goldberg, Michele Farrell, Douglas P. Karim, Keisha R. Oree