Carboxyalkyl Or Alkali Metal Salt Thereof Patents (Class 524/45)
  • Patent number: 7037956
    Abstract: A water-soluble resin composition comprising a water-soluble resin and a colorant, which copolymer has a weight average molecular weight of at least 8,000 and is prepared by polymerizing an ethylenically unsaturated carboxylic acid monomer and a monomer copolymerizable therewith in the presence of an alcoholic hydroxyl group-containing water-soluble high polymer or a copolymerizable surface active agent to give a copolymer having an acid value in the range of 5 to 120 and then neutralizing the thus-obtained copolymer with a basic, exhibits a reduced viscosity change when it is stored for a long period, and is useful as an aqueous ink capable of giving an image having good dot reproducibility and good abrasion resistance.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: May 2, 2006
    Assignee: Zeon Corporation
    Inventors: Xiang Liu, Tomomi Onitake, Toshihiro Inoue
  • Patent number: 7034068
    Abstract: Aqueous dispersions of water-soluble polymers of N-vinylcarboxamides contain, based on 100 parts of water, (A) from 5 to 80 parts by weight of water-soluble polymer containing N-vinylformamide units and/or N-vinylacetamide units and having particle sizes of from 50 nm to 2 ?m and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the water-soluble polymers (A) in aqueous solution, which dispersions are prepared by polymerizing (A) from 5 to 80 parts by weight of N-vinylformamide and/or N-vinylacetamide, if desired together with other monoethylenically unsaturated monomers which form water-soluble polymers therewith, and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the polymers, formed from the monomers (A), in aqueous solution, in 100 parts by weight of water, at from 30 to 95° C. in the presence of from 0.001 to 5.
    Type: Grant
    Filed: October 30, 1999
    Date of Patent: April 25, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Anton Negele, Werner Gauweiler, Hubert Meixner, Norbert Mahr, Martin Rübenacker
  • Patent number: 6951895
    Abstract: Disclosed is an absorbent composition comprising each of an acidic and a basic material, wherein the absorbent composition exhibits desirable absorbent properties. Specifically, the present invention relates to an absorbent composition comprising either an acidic water-swellable, water-insoluble polymer having a pKa between about 2 to about 12 or a basic water-swellable, water-insoluble polymer having a pKb between about 2 to about 12 and either a basic or an acidic second material. The absorbent composition has the ability to slowly absorb a large quantity of liquid, particularly while under an external pressure. The absorbent composition is useful in disposable absorbent products, such as those disposable absorbent products that are used to absorb bodily liquids.
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: October 4, 2005
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Jian Qin, Palani Raj Ramaswami Wallajapet
  • Patent number: 6939441
    Abstract: A stock size intended to be added as a solution to the pulp stock in connection with the manufacture of paper or board in order to improve the characteristics of the paper or board, e.g.), to reduce the absorption of liquids, to increase the dry strength and wet strength. The stock size contains a polymer, which is based on styrene maleic acid and stabilised with a polysaccharide, such as cationic starch. The stock size is advantageously prepared in a steam jet cooker. The stock size is suitably used as a stock size in the manufacturing of liquid packaging board.
    Type: Grant
    Filed: April 17, 2001
    Date of Patent: September 6, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Markku Nurminen, Mari Niinikoski
  • Patent number: 6896725
    Abstract: The invention concerns the use of a water-soluble or water-dispersible polymer having a molecular weight of at least 800, containing at least 5 aldehyde groups per molecule and at least 1 carboxyl group per molecule, the ratio of aldehyde groups to carboxyl groups being higher than 0.75:1, as a wet strength additive. The invention also discloses novel cationic derivatives thereof.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: May 24, 2005
    Assignee: SCA Hygiene Products Zeist B.V.
    Inventors: Jeffrey Wilson Thornton, Dorine Lisa Van Brussel-Verraest, Arie Besemer, Sussan Sandberg
  • Patent number: 6800593
    Abstract: Disclosed is a hydrophilic, water soluble polymer concentrate for addition to aqueous liquids to enhance the properties thereof, particularly to increase the viscosity or decrease the fluid loss of well drilling and servicing fluids, the concentrate comprising a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, the water soluble polymer, and a stabilizing agent comprising one or more acids in an amount from about 0.001% to about 1.5%, one or more anionic surfactants in an amount from about 0.001% to about 1.0%, one or more nonionic surfactants in an amount from 0.001% to about 0.625% and, from about 0% to about 0.75% of one or more water soluble organic liquids, wherein the total concentration of the stabilizing agent is from about 0.1% to about 2.5%, these percentages being based on the weight of the concentrate.
    Type: Grant
    Filed: June 19, 2002
    Date of Patent: October 5, 2004
    Assignee: Texas United Chemical Company, LLC.
    Inventors: James W. Dobson, Jr., Shauna Leigh Hayden, Carolina Trejo Rangel
  • Patent number: 6777454
    Abstract: This invention relates to a process of preparing vesiculated granules of crosslinked carboxylated polyester resin utilising a particular class of non-alkylphenolethoxylate surfactant.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: August 17, 2004
    Assignee: Orica Australia Pty Ltd.
    Inventors: Philip J. A. Ritchie, Algirdas K. Serelis
  • Patent number: 6759473
    Abstract: By coating a dip-formed article with a coating agent comprising a polymer latex dispersion-stabilized with a water-soluble high-molecular-weight compound containing an alcoholic hydroxyl group, a coated article having excellent donning and putting off properties and anti-blocking property, and exhibiting greatly reduced fine particles-releasability is obtained.
    Type: Grant
    Filed: May 20, 2002
    Date of Patent: July 6, 2004
    Assignee: Zeon Corporation
    Inventors: Misao Nakamura, Toshihiro Inoue
  • Patent number: 6710100
    Abstract: A fluid-absorbing, composite material that is pressure sensitive adhesive and which is made of a mixture comprising a continuous phase formed from a pressure sensitive adhesive matrix, and a discontinuous phase substantially comprised of one or more natural or synthetically derived water soluble and/or water insoluble absorbents, characterised in that the continuous phase contains trans-polyoctenamer polymer, which material serves to elevate the shear strength of the composite. Because of its low melting point, compositions containing trans-polyoctenamer polymer are very easy to process. Formulations can be prepared that have only weakly adhesive properties, also formulations that are suitable as primary dressings for various hard-to-heal and chronic wounds. The pressure sensitive adhesive can also be combined with a non-adhesive, water impervious film, or other backing material, and can be used as the protective adhesive skin barrier component of ostomy pouches.
    Type: Grant
    Filed: August 22, 2002
    Date of Patent: March 23, 2004
    Assignee: Avery Dennison Corporation
    Inventor: Roger David Arnold Lipman
  • Patent number: 6667354
    Abstract: Stable and environmentally friendly suspensions of solid particulates are provided through the addition of such solid particulates to a suspension medium which is comprised of a liquid carrier, a liquid carrier soluble resin, an organophyllic clay, and an activator wherein said liquid carrier is a carboxylic acid ester, preferably 2-ethylhexyl oleate, said liquid carrier soluble resin is selected from the group consisting of styrene-isoprene copolymers, styrene ethylene-propylene block copolymers, styrene isobutylene copolymers, styrene butadiene copolymers, polybutylene, polystyrene, polyethylene-propylene copolymers, methyl methacrylate and mixtures thereof, said organophyllic clay is one of kaolinite, halloysite, vermiculite, chlorite, attapullgite, smectite, montmorillonite, bentonite, hectorite, and mixtures thereof and said activator is an alcohol of the formula ROH wherein R is an alkyl group of 1 to 10 carbon atoms.
    Type: Grant
    Filed: July 18, 2000
    Date of Patent: December 23, 2003
    Assignee: Phillips Petroleum Company
    Inventors: Kelly B. Fox, Alvin Evans, Jr.
  • Patent number: 6656983
    Abstract: The invention provides mixed aromatic vinyl-1,3-diene polymers stabilized by a protective colloid and present in the form of aqueous polymer dispersions or polymer powders redispersible in water as adhesives for porous substrates. The polymer dispersions and the polymer powders are obtained by emulsion polymerization of a mixture containing: a) 20 to 80 percent by weight of one or more vinylaromatics; b) 19.9 to 79.9 percent by weight of one or more 1,3-dienes; c) 0.1 to 15 percent by weight of one or more comonomers from the group consisting of N-methylolacrylamide, N-methylolmethacrylamide and the N-(alkoxymethyl)-acrylamides and N-(alkoxymethyl)-methacrylamides with a C1 to C6-alkyl radical. The sum of the above percentages adds up to 100% by weight. Emulsion polymerization is carried out in the presence of one or more protective colloids and without emulsifiers, optionally followed by drying of the resulting aqueous polymer dispersion.
    Type: Grant
    Filed: August 1, 2001
    Date of Patent: December 2, 2003
    Assignee: Wacker-Chemie GmbH
    Inventors: Theo Mayer, Thomas Kohler, Reinhard Harzschel, Hans-Peter Weitzel, Bernd Schilling
  • Patent number: 6599446
    Abstract: Inclusion of relatively small amounts of organic ionic species, such as calcium stearate, in the preparation of an electrically conductive polymer composite composition provides a composition having enhanced electrical properties relative to the composite composition lacking the added organic ionic species. As a result of this enhancement, normally insulating materials which rely upon a conductive filler to render them electrically conductive, can be made to achieve a given level of conductivity using less of the conductive filler than would otherwise be required. As a result, the adverse effects of the conductive filler on the polymer's physical properties can be minimized while maintaining a high level of electrical conductivity.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: July 29, 2003
    Assignee: General Electric Company
    Inventors: Michael Leslie Todt, David Ernest Rodrigues, Sai-Pei Ting
  • Patent number: 6506824
    Abstract: Biodegradable thermoplastic compositions comprising a starch component, a cellulose ester or ether, a plasticizer for the starchy phase and of the cellulose and derivatives, and a compatibilizer agent selected from polymers compatible with the cellulose and or starchy component, grafted with aliphatic or polyhydroxilated chains; copolymers obtained from hydroxy acids and/or diamines with 2-24C and aliphatic or aromatic diisocyanates; copolymers obtained from aliphatic polyesters, polyureas and polyalkylene glycols and aliphatic or aromatic diisocyanates; copolymers obtained from polymers compatible with cellulose ester or ethers and/or the starchy component by grafting starch soluble polyols; polymer capable of complexing starch; starch compatible polyols.
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: January 14, 2003
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Vittorio Bellotti, Roberto Lombi, Gabriele Perego
  • Patent number: 6482876
    Abstract: The invention relates to an agglomerate containing at least one of the following water-soluble or water-dispersible materials as a bonding base polymer: carboxylized and/or alkoxylized starch, cellulose ether and fully synthetic vinyl polymers and/or polyacrylates. The agglomerate is characterized in that it contains a blasting agent which produces a high swelling pressure, but, advantageously, does not gel. The agglomerate can have a regular geometric form or not. Its weight should be between 0.5 and 500 g. The agglomerate is used in particular in the production of lump-free paste.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: November 19, 2002
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Sandra Witt-Nuesslein, Werner Haller, Bernhard Schoettmer, Monika Boecker, Wolfgang Seiter, Ingo Hardacker, Heinz-Peter Hoffmann
  • Patent number: 6479573
    Abstract: Process for thickening aqueous systems by addition of aqueous suspensions of water-soluble hydrophobically modified polyurethanes, polyacrylates and poly(acetal- or ketal-polyethers) and carbon containing salts.
    Type: Grant
    Filed: September 12, 2001
    Date of Patent: November 12, 2002
    Assignee: Hercules Incorporated
    Inventors: Charles Lee Burdick, Arjun Chandra Sau
  • Patent number: 6368356
    Abstract: The invention provides a means of boosting the mechanical performance of shaped shaped medical devices comprising polymer hydrogels, such as stents, so that they may be more easily inserted into or removed from the body. In one aspect, the invention provides shaped medical devices having increased mechanical strength and comprising both ionic and covalent crosslinks. In another aspect, the invention provides a shaped medical device having a heterogeneous polymer composition and a variable dissolution or degradation rate along its length. The shaped medical devices according to the present invention retain their shape and stiffness during insertion into the body and can swell and soften inside the body to enhance patient comfort.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: April 9, 2002
    Assignee: SciMed Life Systems, Inc.
    Inventors: Sheng Ping Zhong, Arthur R. Madenjian, Douglas E. Godshall, John M. Ronan, Samuel A. Thompson
  • Patent number: 6359040
    Abstract: Aqueous compositions having advantageous Theological properties, preferably including any of enhanced yield stress, enhanced viscosity, and/or enhanced water retention, are disclosed. Included are low-viscosity compositions having high yield stress. The present invention also relates to processes for preparing and using the compositions. Compositions of the present invention comprise aqueous compositions of a polymer having a net ionic charge, and a viscosity promoter having an opposite net ionic charge. Compositions may also comprise a moderating agent to prevent precipitation and/or gelation.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: March 19, 2002
    Assignee: Hercules Incorporated
    Inventor: Charles L. Burdick
  • Patent number: 6326421
    Abstract: A pressure-sensitive adhesive material made of a weakly elastic mixture comprising a continuous phase formed essentially from a physically cross-linked solid rubber, which comprises a blend of A-B-A block copolymer, such as a styrene-isoprene-styrene block copolymer and a diblock copolymer such as styrene-butadiene, styrene-isoprene or a hydrogenated styrene-diene copolymer such as styrenel/etyhlene butylene, a compatible tackifying resin and a low-molecular weight polyisobutylene, optionally modified by butyl rubber, and a discontinuous phase comprising one or more hydrocolloids that are soluble and/or swellable in water.
    Type: Grant
    Filed: June 5, 2000
    Date of Patent: December 4, 2001
    Assignee: Avery Dennison Corporation
    Inventor: Roger D. A. Lipman
  • Patent number: 6284819
    Abstract: The present invention provides a recording medium comprising a substrate having a glossy coating thereon, wherein the glossy coating comprises a binder and first and second groups of particles, wherein: (a) the first group comprises metal oxide particles, wherein the metal oxide particles are aggregates of smaller, primary particles, (b) the mean diameter of the primary particles is less than about 100 nm, (c) the mean diameter of the aggregates is from about 100 nm to about 500 nm, (d) the mean diameter of the particles in the second group is less than about 50% of the mean diameter of the aggregates in the first group, and (e) the ratio of particles in the first group to particles in the second group is from about 0.1:1 to about 10:1 by weight. The glossy coating of the inventive recording medium has an excellent rate of liquid absorption, a relatively high liquid absorption capacity, excellent adhesiveness, and a non-brittle, crack-resistant, glossy surface.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: September 4, 2001
    Assignee: Cabot Corporation
    Inventors: Michael S. Darsillo, David J. Fluck, Rudiger Laufhutte
  • Patent number: 6201042
    Abstract: In a method of making repositionable pressure sensitive adhesive of tacky elastomeric microspheres wherein the microspheres are polymerized and formed in an aqueous suspension which includes a surfactant, a certain amount of the surfactant is removed from the aqueous suspension after completion of polymerization of the microspheres so that a predetermined reduced amount of surfactant remains, with the result that migration of the surfactant from the adhesive is at least substantially reduced.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: March 13, 2001
    Inventors: Howard B. Kaye, David K. Holbrook, Brian M. Vogler
  • Patent number: 6166119
    Abstract: A cement pumpability-enhancing additive which confers good pumpability on cementitious compositions such as concrete consists essentially of(a) polyethylene glycol;(b) diethylene glycol monobutyl ether and/or a derivative thereof;(c) polysaccharide; and(d) a thickening polymer selected from the group consisting of polyacrylic acid derivatives, polyacrylic amide derivatives, cellulose ethers, polyphenyl ethers and polyalkylene glycol fatty acid esters;the weight solids proportions of (a), (b), (c), and (d) in the additive being respectively 5-55%, 10-80%, 1-20% and 1-20%. The additive is preferably used with a cement dispersing agent.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: December 26, 2000
    Assignee: MBT Holding AG
    Inventors: Shigemi Matsuo, Hidenori Nagamine, Akira Ota
  • Patent number: 6143812
    Abstract: Asphalt release coatings are prepared by applying an aqueous emulsion containing an organopolysiloxane component, an effective amount of one or more emulsifying surfactants, and most minor amount of a multiple release additive. The compositions exhibit improved release, particularly multiple releases, even with polymer modified asphalt binders.
    Type: Grant
    Filed: August 25, 1998
    Date of Patent: November 7, 2000
    Assignee: Wacker Silicones Corporation
    Inventors: Eugene R. Martin, Michael L. Coffey
  • Patent number: 6121439
    Abstract: A coating composition is composed of a water-soluble polysaccharide composition comprising at least one hydrophobic group selected from aryl, alkyl, alkenyl, aralkyl and mixtures thereof and at least one quaternary ammonium salt group, both connected to a polysaccharide backbone by covalent bonds. This coating is used for improving the leveling of waterborne paints.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: September 19, 2000
    Assignee: Hercules Incorporated
    Inventor: Gijsbert Kroon
  • Patent number: 6071984
    Abstract: This invention relates to reinforced thermoplastic moulding compositions prepared from biodegradable polymers, for example aliphatic or polyester amides, aliphatic polyester urethanes, and to the use thereof for the production of mouldings and to the mouldings, wherein the reinforcing materials are selected from wood flour, fibres of natural origin, minerals of natural origin, cellulose and cellulose derivatives.
    Type: Grant
    Filed: June 25, 1998
    Date of Patent: June 6, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ernst Grigat, Hanns Peter Muller, Wolfgang Schulz-Schlitte, Aziz El Sayed, Ralf Timmermann
  • Patent number: 6054511
    Abstract: Hydroxyethylcellulose (HEC), hydrophobically modified hydroxyethylcellulose (HMHEC), hydroxypropylcellulose (HPC), methylhydroxypropylcellulose (MHPC), carboxymethylhydroxyethylcellulose (CMHEC), guar, starch, xanthan, hydroxypropylguar (HP Guar) or carboxymethylhydroxypropylguar (CMHP Guar) are stepwise or continuously reacted with hydrogen peroxide to produce aqueous compositions with a solids content greater than 5% by weight at a viscosity at 25.degree. C. below 9500 mPa.s. It is preferred to use 30-50% hydrogen peroxide to depolymerize the polysaccharide.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: April 25, 2000
    Assignee: Aqualon Company
    Inventors: J David Angerer, Jashawant Jamanadas Modi, Robert C Szafranski
  • Patent number: 5993530
    Abstract: A thermally-decomposable, biodegradable resin composition is dispersed and stabilized in water optionally along with additives to give an aqueous dispersion of the resin composition. In the dispersion, the base polymer consists substantially of a water-insoluble starch-type, biodegradable resin. The dispersion is usable in various fields of papermaking, non-woven fabric production, film and sheet production and woven fabric production, in those of dispersed adhesive production, and in those of metal processing, plastic processing, wood processing and stone processing.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: November 30, 1999
    Assignee: Japan Corn Starch Co., Ltd.
    Inventors: Hideyuki Tanaka, Nobuhiro Hosokawa, Nobuyuki Sugtura, Masato Takahara
  • Patent number: 5994530
    Abstract: The present invention provides certain carboxymethyl cellulose (CMC) esters of higher acids (e.g., CMC acetate propionate, CMC propionate, CMC acetate butyrate, and CMC butyrate)having specific use in aqueous dispersions useful in formulating waterborne coating compositions containing pigments, especially metallic pigments such as aluminum flakes and mica. The esters also have specific use as wetting agents and in high solids coatings.
    Type: Grant
    Filed: June 25, 1998
    Date of Patent: November 30, 1999
    Assignee: Eastman Chemical Corporation
    Inventors: Jessica Dee Posey-Dowty, Alan Kent Wilson, Larry Gerald Curtis, Paul Michael Swan, Kab Sik Seo
  • Patent number: 5989329
    Abstract: Water-borne paints containing reduced molecular weight polysaccharide derivatives that are resistant to enzyme hydrolysis. The water-borne paints are biostable, retaining at least about 80% of their initial viscosity 24 hours after they are inoculated with polysaccharide hydrolysis enzyme.
    Type: Grant
    Filed: November 10, 1998
    Date of Patent: November 23, 1999
    Assignee: Hercules Incorporated
    Inventor: Arjun Chandra Sau
  • Patent number: 5969012
    Abstract: A non-aqueous slurry comprising(a) one or more water soluble polymers;(b) polyalkylene glycol or thickened polyalkylene glycol; and a(c) a slurry stabilizer comprising an amine phosphate ester salt is provided. The slurry has a number of applications, including oil recovery, and in the paper and textile industries.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: October 19, 1999
    Assignee: Rhodia Inc.
    Inventor: William F. Harris, Jr.
  • Patent number: 5925182
    Abstract: A stable liquid suspension composition comprising a liquid carrier, a solid fatty acid or a salt thereof, and a solid particulate is disclosed wherein said liquid carrier is selected from the group consisting of oils, olefins, terpenes, glycols, esters, ethers, alcohols, and combinations of any two or more thereof and said liquid carrier, solid fatty acid or salt thereof, and solid particulate are each present in said composition in a stabilizing amount sufficient to produce a stable liquid suspension. Also disclosed is a stable liquid composition comprising a liquid carrier, an oil-soluble polymer, and a solid particulate wherein said liquid carrier is selected from the group consisting of olefins, terpenes, esters, and combinations of any two or more thereof and said liquid carrier, oil-soluble polymer, and solid particulate are each present in said composition in a stabilizing amount sufficient to effect the formation of a stable liquid suspension.
    Type: Grant
    Filed: July 16, 1998
    Date of Patent: July 20, 1999
    Assignee: Phillips Petroleum Company
    Inventors: Bharat B. Patel, Marshall D. Bishop
  • Patent number: 5922119
    Abstract: The invention is directed to the use of an aqueous protective coating composition containing a binder system and an associative thickener for industrial coatings. The associative thickener is not a polyurethane thickener and is selected so that its concentration required by the specific application method is below the critical concentration C*, defined as the thickener concentration at which the coils of the thickener polymer start to overlap of entangle calculated according to the Mark Houwink equation.
    Type: Grant
    Filed: March 27, 1998
    Date of Patent: July 13, 1999
    Assignee: Hercules Incorporated
    Inventor: Kroon Gijsbert
  • Patent number: 5883155
    Abstract: Elastomer films in which active chemical substances, such as corrosion inhibitors, lubricants or biocides for medical use are uniformly dispersed in the form of gel inclusions, processes for preparation and applications of these films.The elastomer film contains at least one active chemical substance in the form of a phase which is dispersed in the elastomer, wherein the disperse phase is in the form of a gel, reversible or irreversible, as a function of temperature, and filled with an active chemical substance.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: March 16, 1999
    Assignee: Hutchinson
    Inventors: Pierre Hoerner, Gerard Riess, Rene Guy Busnel, Andre Cheymol
  • Patent number: 5879440
    Abstract: Water-borne paints containing reduced molecular weight polysaccharide derivatives that are resistant to enzyme hydrolysis. The water-borne paints are biostable, retaining at least about 80% of their initial viscosity 24 hours after they are inoculated with polysaccharide hydrolysis enzyme. A process for making the biostable water-borne paints has the steps: a) treating precursor polysaccharide derivative with polysaccharide hydrolysis enzyme in aqueous medium for a time sufficient to obtain reduced molecular weight polysaccharide derivative; and b) mixing the reduced molecular weight polysaccharide derivative with an effective amount of at least one other water-borne paint ingredient to obtain a water-borne paint.
    Type: Grant
    Filed: July 28, 1997
    Date of Patent: March 9, 1999
    Assignee: Hercules Incorporated
    Inventor: Arjun Chandra Sau
  • Patent number: 5847031
    Abstract: A polymer composition, in particular an active substance-containing depot material composition or an absorbent composition are disclosed which substantially consist of a water-soluble and/or water-swellable polymer based on polysaccharides as the main component, and a water-swellable, synthetic polymer as further component, used as polymeric components, and of a matrix material for the prevention of separation and gel blocking, an ionic or covalent cross-linking agent, as well as of an anti-blocking agent. Additionally their production and use as well as (animal) hygiene items and chemico-technical products are disclosed which comprise these polymer compositions, these active-substance-containing depot material compositions, or the absorbent compositions.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: December 8, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Klimmek, Uwe Gunther, Helmut Bruggemann
  • Patent number: 5834538
    Abstract: A pressure sensitive adhesive(PSA) composition includes a latex system of an aqueous polymer dispersion derived from ethylenically-unsaturated monomers in the presence of a water soluble protective colloid. The PSA compositions are used in the manufacture of a variety of articles that are intended to be easily attachable to another substrate by the application of pressure alone.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: November 10, 1998
    Assignee: Hercules Incorporated
    Inventors: Jacobus G. deHullu, Dirk Kruythoff, Willemien G. Salomons, Adriana Veldhorst
  • Patent number: 5834533
    Abstract: A stable liquid suspension composition comprising a liquid carrier, a solid fatty acid or a salt thereof, and a solid particulate is disclosed wherein said liquid carrier is selected from the group consisting of oils, olefins, terpenes, glycols, esters, ethers, alcohols, and combinations of any two or more thereof and said liquid carrier, solid fatty acid or salt thereof, and solid particulate are each present in said composition in a stabilizing amount sufficient to produce a stable liquid suspension. Also disclosed is a stable liquid composition comprising a liquid carrier, an oil-soluble polymer, and a solid particulate wherein said liquid carrier is selected from the group consisting of liquid alkenes, terpenes, esters, and combinations of any two or more thereof and said liquid carrier, oil-soluble polymer, and solid particulate are each present in said composition in a stabilizing amount sufficient to effect the formation of a stable liquid suspension.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: November 10, 1998
    Assignee: Phillips Petroleum Company
    Inventors: Bharat B. Patel, Marshall D. Bishop
  • Patent number: 5830933
    Abstract: A denture adhesive composition contains a denture adhesive and a pharmacologically acceptable carrier in which the denture adhesive is a salt of a copolymer of maleic acid or anhydride and a 1 to 5 carbon atom alkyl vinyl ether having a specific viscosity of at least 4.0. The denture adhesive composition is used to adhere a denture to the oral mucosa.
    Type: Grant
    Filed: April 22, 1996
    Date of Patent: November 3, 1998
    Assignee: Block Drug Company, Inc.
    Inventors: Joseph Synodis, Alfred J. Smetana, Robert C. Gasman, Eddie Wong, Hal C. Clarke
  • Patent number: 5830934
    Abstract: An emulsion polymer is disclosed by the present invention. In particular, the emulsion polymer comprises a protective colloid and a functionalized silane component which is of the formula: ##STR1## wherein R" is C.sub.1 -C.sub.5 alkyl, R' is C.sub.1 -C.sub.5 alkyl, R is SH, CH.sub.2 .dbd.CH--, CH.sub.2 .dbd.C(CH.sub.3)--C(O)O--, CH.sub.2 .dbd.CH--C(O)O--, and ##STR2## n is 1-10, and m is 2 or 3.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: November 3, 1998
    Assignee: Reichhold Chemicals, Inc.
    Inventor: Venkataram Krishnan
  • Patent number: 5785747
    Abstract: The present invention provides compositions useful for viscosifying aqueous fluids, methods for making them and methods for using them. In one aspect of the invention, inventive compositions comprise a prehydrating alcohol having at least two hydroxyl groups and having a molecular weight of from about 60 to about 600; an inorganic salt; and a polymer. In a preferred aspect of the invention, the viscosifier composition additionally comprises a solvent having a molecular weight of from about 75 to about 1000. According to another aspect of the invention, inventive compositions comprise a prehydrating alcohol; an inorganic salt; and a polymer; and the composition is essentially free from water. Inventive compositions find advantageous use in viscosifying fluids utilized in subterranean drilling activities such as, for example, drilling, drill-in, completion, hydraulic fracturing, work-over, packer, well treating, testing, spacer, or hole abandonment fluids.
    Type: Grant
    Filed: January 17, 1997
    Date of Patent: July 28, 1998
    Assignee: Great Lakes Chemical Corporation
    Inventors: Daniel P. Vollmer, Paul H. Javora, Robert L. Horton
  • Patent number: 5780519
    Abstract: Lignocellulosic light weight molding products which are useful as heat insulator, shock absorber, sound absorber and so on and have open-celled foam-structure are mainly composed of lignocellulose that is able to use in not only fibrous shape but also other various shapes. They are at least composed of four components shown hereunder; (1) lignocellulose, (2) water soluble high polymer containing not less than two OH groups in a molecule and having the film properties of tensile strength 10 to 300 MPa and surface tension 30 to 65 mN/m in 0.4 wt % aqueous solution at 20.degree. C., (3) water soluble high polymer containing not less than two carboxyl groups in a molecule and/or anionic surfactant, and (4) high polymer having the film properties of tensile strength 0.1 to 10 MPa and ultimate elongation 200 to 2000%, 2nd transition point 30.degree. to 40.degree. C. and cohesion energy density 30 to 200 cal/cc.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: July 14, 1998
    Inventor: Saburo Imoto
  • Patent number: 5750591
    Abstract: A denture adhesive with significantly improved hold performance is comprised of the mixed partial salts of polymethyl vinyl ether maleic acid. At least one of said salts comprises zirconium while a second salt is selected from the group consisting of calcium, zinc, magnesium, iron, strontium and mixtures thereof. Optionally, a tripartite salt formulation may be prepared utilizing sodium, lithium or potassium. The adhesives are formulated in a standard pharmaceutically acceptable vehicle comprised of waxes, oils, colorants, viscosity modifiers and the like as is known in the art. The denture adhesive may be formulated as a paste, powder or liquid which has rapid absorption characteristics for faster swelling softening and superior coalescence.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: May 12, 1998
    Assignee: The Block Drug Company
    Inventors: Hal C. Clarke, Hyung-Kook Ahn, Eddie Wong, Robert C. Gasman, Alfred J. Smetana, Joseph Synodis, Tiang Shing Chang
  • Patent number: 5744520
    Abstract: A process for the preparation of polymer compositions which comprises mixing a conductive component with an anionic polymeric latex containing a polymer; adding a cationic surfactant, or flocculant whereby the aggregation of the latex particles and the conductive component particles results; subsequently adding colloidal stabilizer, followed by the addition of a base to obtain a pH of from about 7 to about 12; heating above about the polymer glass transition temperature thereby enabling the severage, or breakage of the formed aggregated particles; further heating above about the polymer glass transition temperature enabling the coalescence of the polymer and conductive component particles; and optionally washing and drying the resulting coalesced product.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: April 28, 1998
    Assignee: Xerox Corporation
    Inventors: Grazyna E. Kmiecik-Lawrynowicz, Richard P. N. Veregin, Raj D. Patel, Michael A. Hopper, Maria V. McDougall
  • Patent number: 5741836
    Abstract: This invention is a screen-printable ink receptive composition. It contains (a) a hydrophilic polymer and (b) a thickener and has (c) a viscosity of 10 to 1,000 poise at shear rates less than 10.degree. s.sup.-1 and exhibits (d) a shear thinning behavior defined by the following relationship:log(viscosity)=A ?log(shear rate)!wherein A represents (e) the slope of the line obtained by plotting log(viscosity) against log(shear rate) and has (f) a value of up to -0.1 when calculated over shear rates ranging from 10.degree. to 10.sup.-2 s.sup.-1.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: April 21, 1998
    Assignee: Eastman Kodak Company
    Inventors: Mary A. Krenceski, Kevin J. Swallow, Douglas Eugene Bugner, Alfred John Amell
  • Patent number: 5736595
    Abstract: A polymer composition, a process for the production of a polymer composition, in particular of an absorbent, are disclosed which substantially consist of a special component A based on renewable polysaccharide raw materials, a special component B consisting of a water-soluble polymer, a matrix material, an ionic and/or covalent cross-linking agent, or an anti-blocking agent, which is obtainable in that the water-swellable polymer is brought together with the polysaccharide polymer, that these are dried and ground then, the other components are added, and mixing up to homogeneity is effected followed by a heat treatment, and that during the addition of the cross-linking agent, after said heat treatment, the same is optionally fixed by the matrix by means of a final heat treatment.Additionally the use of this polymer composition and (animal) hygiene items and chemico-technical products are disclosed which comprise a previously manufactured polymer composition.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: April 7, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Uwe Gunther, Helmut Klimmek, Helmut Bruggemann
  • Patent number: 5725648
    Abstract: This invention relates to paper coating compositions comprising pigment, adhesive binder and rheology modifier wherein the rheology modifier comprises at least one of a) a mixture of guar and at least one other water-soluble polymer in sufficient amount to reduce the amount of guar adsorbed onto the pigment, or b) reduced molecular weight guar. The invention also relates to processes for making coated paper using the coating compositions, and to paper coated with the coating compositions.
    Type: Grant
    Filed: September 25, 1996
    Date of Patent: March 10, 1998
    Assignee: Hercules Incorporated
    Inventors: Michael J. Brown, Teng-Shau Young
  • Patent number: 5721295
    Abstract: A polymer composition, in particular an absorbent composition or an active substance-containing depot material are disclosed which substantially consist of a water-soluble and/or water-swellable polymer based on polysaccharides as the main component, and of a water-swellable polymer as further component, used as polymeric components, and of a matrix material for the prevention of separation and gel blocking, an ionic or covalent cross-linking agent, a reactive additive, as well as of an anti-blocking agent. Additionally, their production and use as well as (animal) hygiene items and chemico-technical products are disclosed which comprise these polymer compositions or absorbent compositions.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: February 24, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Bruggemann, Uwe Gunther, Helmut Klimmek
  • Patent number: 5705553
    Abstract: Copolymers containing carboxyl groups in aqueous dispersion form or redispersible powder form and their water-soluble salts, based on ethylenically unsaturated and copolymerizable monomers, the macro-molecules of which contain at least 24% by weight of monomer units carrying carboxyl groups prepared, by emulsion copolymerization initiated by free radicals in the presence of polyvinyl alcohol (PVA) or polyvinylpyrrolidone (PVP) dissolved in the aqueous phase and isolation of the copolymers in aqueous dispersion form, and optionally subsequent removal of water by spray drying to obtain redispersible copolymer powders and processes for their preparation and their use as thickeners in aqueous formulations which copolymers, by conversion into their water-soluble salt forms, are useful as thickening agents having a surprisingly advantageous rheology-modifying action in aqueous systems.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: January 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Rolf Kuropka
  • Patent number: 5698612
    Abstract: The present invention provides thermoplastically workable and completely biodegradable moulding compositions, a process for the preparation thereof and the use thereof as biodegradable materials for the production of, for example, injection-moulded parts, films, fibres or coatings.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: December 16, 1997
    Assignee: Bayer Akteingesellschaft
    Inventors: Joachim Simon, Hanns Peter Muller, Dirk Jacques Dijkstra, Jurgen Engelhardt, Volkhard Muller, Gunter Weber
  • Patent number: 5696181
    Abstract: An improved denture adhesive composition is comprised of a highly cross-linked lower alkyl ether/maleic acid or maleic anhydride copolymer in which up to about 85% of the initial free carboxyl groups are reacted with one or more cross-linking agents. The cross-linking agents are mixtures of inorganic divalent cations such as calcium, magnesium and zinc together with organic bifunctional compounds comprised of polyhydroxyl compounds such as propylene glycol, glycerin and the like. The copolymer has a specific viscosity of no less than 1.5. A hydrophilic polymer such as sodium alginate or carboxymethyl cellulose may also be added to the lower alkyl vinyl ether/maleic acid or maleic anhydride copolymer which is then formulated with other excipients in a paste, powder, liquid, gel or cream composition.
    Type: Grant
    Filed: September 22, 1995
    Date of Patent: December 9, 1997
    Assignee: The Block Drug Company, Inc.
    Inventors: Tiang-Shing Chang, Donna DiFerdinando
  • Patent number: RE36657
    Abstract: A denture adhesive composition contains a denture adhesive and a pharmacologically acceptable carrier in which the denture adhesive is a salt of a copolymer of maleic acid or anhydride and a 1 to 5 carbon atom alkyl vinyl ether having a specific viscosity of at least 4.0. The denture adhesive composition is used to adhere a denture to the oral mucosa.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: April 11, 2000
    Assignee: Block Drug Company, Inc.
    Inventors: Joseph Synodis, Alfred J. Smetana, Robert C. Gasman, Eddie Wong, Hal C. Clarke