Carboxyalkyl Or Alkali Metal Salt Thereof Patents (Class 524/45)
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Patent number: 7037956Abstract: A water-soluble resin composition comprising a water-soluble resin and a colorant, which copolymer has a weight average molecular weight of at least 8,000 and is prepared by polymerizing an ethylenically unsaturated carboxylic acid monomer and a monomer copolymerizable therewith in the presence of an alcoholic hydroxyl group-containing water-soluble high polymer or a copolymerizable surface active agent to give a copolymer having an acid value in the range of 5 to 120 and then neutralizing the thus-obtained copolymer with a basic, exhibits a reduced viscosity change when it is stored for a long period, and is useful as an aqueous ink capable of giving an image having good dot reproducibility and good abrasion resistance.Type: GrantFiled: October 19, 2001Date of Patent: May 2, 2006Assignee: Zeon CorporationInventors: Xiang Liu, Tomomi Onitake, Toshihiro Inoue
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Patent number: 7034068Abstract: Aqueous dispersions of water-soluble polymers of N-vinylcarboxamides contain, based on 100 parts of water, (A) from 5 to 80 parts by weight of water-soluble polymer containing N-vinylformamide units and/or N-vinylacetamide units and having particle sizes of from 50 nm to 2 ?m and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the water-soluble polymers (A) in aqueous solution, which dispersions are prepared by polymerizing (A) from 5 to 80 parts by weight of N-vinylformamide and/or N-vinylacetamide, if desired together with other monoethylenically unsaturated monomers which form water-soluble polymers therewith, and (B) from 1 to 50 parts by weight of at least one polymeric dispersant which is incompatible with the polymers, formed from the monomers (A), in aqueous solution, in 100 parts by weight of water, at from 30 to 95° C. in the presence of from 0.001 to 5.Type: GrantFiled: October 30, 1999Date of Patent: April 25, 2006Assignee: BASF AktiengesellschaftInventors: Anton Negele, Werner Gauweiler, Hubert Meixner, Norbert Mahr, Martin Rübenacker
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Patent number: 6951895Abstract: Disclosed is an absorbent composition comprising each of an acidic and a basic material, wherein the absorbent composition exhibits desirable absorbent properties. Specifically, the present invention relates to an absorbent composition comprising either an acidic water-swellable, water-insoluble polymer having a pKa between about 2 to about 12 or a basic water-swellable, water-insoluble polymer having a pKb between about 2 to about 12 and either a basic or an acidic second material. The absorbent composition has the ability to slowly absorb a large quantity of liquid, particularly while under an external pressure. The absorbent composition is useful in disposable absorbent products, such as those disposable absorbent products that are used to absorb bodily liquids.Type: GrantFiled: December 2, 1996Date of Patent: October 4, 2005Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Jian Qin, Palani Raj Ramaswami Wallajapet
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Patent number: 6939441Abstract: A stock size intended to be added as a solution to the pulp stock in connection with the manufacture of paper or board in order to improve the characteristics of the paper or board, e.g.), to reduce the absorption of liquids, to increase the dry strength and wet strength. The stock size contains a polymer, which is based on styrene maleic acid and stabilised with a polysaccharide, such as cationic starch. The stock size is advantageously prepared in a steam jet cooker. The stock size is suitably used as a stock size in the manufacturing of liquid packaging board.Type: GrantFiled: April 17, 2001Date of Patent: September 6, 2005Assignee: Ciba Specialty Chemicals CorporationInventors: Markku Nurminen, Mari Niinikoski
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Patent number: 6896725Abstract: The invention concerns the use of a water-soluble or water-dispersible polymer having a molecular weight of at least 800, containing at least 5 aldehyde groups per molecule and at least 1 carboxyl group per molecule, the ratio of aldehyde groups to carboxyl groups being higher than 0.75:1, as a wet strength additive. The invention also discloses novel cationic derivatives thereof.Type: GrantFiled: April 25, 2003Date of Patent: May 24, 2005Assignee: SCA Hygiene Products Zeist B.V.Inventors: Jeffrey Wilson Thornton, Dorine Lisa Van Brussel-Verraest, Arie Besemer, Sussan Sandberg
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Patent number: 6800593Abstract: Disclosed is a hydrophilic, water soluble polymer concentrate for addition to aqueous liquids to enhance the properties thereof, particularly to increase the viscosity or decrease the fluid loss of well drilling and servicing fluids, the concentrate comprising a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, the water soluble polymer, and a stabilizing agent comprising one or more acids in an amount from about 0.001% to about 1.5%, one or more anionic surfactants in an amount from about 0.001% to about 1.0%, one or more nonionic surfactants in an amount from 0.001% to about 0.625% and, from about 0% to about 0.75% of one or more water soluble organic liquids, wherein the total concentration of the stabilizing agent is from about 0.1% to about 2.5%, these percentages being based on the weight of the concentrate.Type: GrantFiled: June 19, 2002Date of Patent: October 5, 2004Assignee: Texas United Chemical Company, LLC.Inventors: James W. Dobson, Jr., Shauna Leigh Hayden, Carolina Trejo Rangel
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Patent number: 6777454Abstract: This invention relates to a process of preparing vesiculated granules of crosslinked carboxylated polyester resin utilising a particular class of non-alkylphenolethoxylate surfactant.Type: GrantFiled: June 28, 2002Date of Patent: August 17, 2004Assignee: Orica Australia Pty Ltd.Inventors: Philip J. A. Ritchie, Algirdas K. Serelis
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Patent number: 6759473Abstract: By coating a dip-formed article with a coating agent comprising a polymer latex dispersion-stabilized with a water-soluble high-molecular-weight compound containing an alcoholic hydroxyl group, a coated article having excellent donning and putting off properties and anti-blocking property, and exhibiting greatly reduced fine particles-releasability is obtained.Type: GrantFiled: May 20, 2002Date of Patent: July 6, 2004Assignee: Zeon CorporationInventors: Misao Nakamura, Toshihiro Inoue
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Patent number: 6710100Abstract: A fluid-absorbing, composite material that is pressure sensitive adhesive and which is made of a mixture comprising a continuous phase formed from a pressure sensitive adhesive matrix, and a discontinuous phase substantially comprised of one or more natural or synthetically derived water soluble and/or water insoluble absorbents, characterised in that the continuous phase contains trans-polyoctenamer polymer, which material serves to elevate the shear strength of the composite. Because of its low melting point, compositions containing trans-polyoctenamer polymer are very easy to process. Formulations can be prepared that have only weakly adhesive properties, also formulations that are suitable as primary dressings for various hard-to-heal and chronic wounds. The pressure sensitive adhesive can also be combined with a non-adhesive, water impervious film, or other backing material, and can be used as the protective adhesive skin barrier component of ostomy pouches.Type: GrantFiled: August 22, 2002Date of Patent: March 23, 2004Assignee: Avery Dennison CorporationInventor: Roger David Arnold Lipman
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Patent number: 6667354Abstract: Stable and environmentally friendly suspensions of solid particulates are provided through the addition of such solid particulates to a suspension medium which is comprised of a liquid carrier, a liquid carrier soluble resin, an organophyllic clay, and an activator wherein said liquid carrier is a carboxylic acid ester, preferably 2-ethylhexyl oleate, said liquid carrier soluble resin is selected from the group consisting of styrene-isoprene copolymers, styrene ethylene-propylene block copolymers, styrene isobutylene copolymers, styrene butadiene copolymers, polybutylene, polystyrene, polyethylene-propylene copolymers, methyl methacrylate and mixtures thereof, said organophyllic clay is one of kaolinite, halloysite, vermiculite, chlorite, attapullgite, smectite, montmorillonite, bentonite, hectorite, and mixtures thereof and said activator is an alcohol of the formula ROH wherein R is an alkyl group of 1 to 10 carbon atoms.Type: GrantFiled: July 18, 2000Date of Patent: December 23, 2003Assignee: Phillips Petroleum CompanyInventors: Kelly B. Fox, Alvin Evans, Jr.
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Patent number: 6656983Abstract: The invention provides mixed aromatic vinyl-1,3-diene polymers stabilized by a protective colloid and present in the form of aqueous polymer dispersions or polymer powders redispersible in water as adhesives for porous substrates. The polymer dispersions and the polymer powders are obtained by emulsion polymerization of a mixture containing: a) 20 to 80 percent by weight of one or more vinylaromatics; b) 19.9 to 79.9 percent by weight of one or more 1,3-dienes; c) 0.1 to 15 percent by weight of one or more comonomers from the group consisting of N-methylolacrylamide, N-methylolmethacrylamide and the N-(alkoxymethyl)-acrylamides and N-(alkoxymethyl)-methacrylamides with a C1 to C6-alkyl radical. The sum of the above percentages adds up to 100% by weight. Emulsion polymerization is carried out in the presence of one or more protective colloids and without emulsifiers, optionally followed by drying of the resulting aqueous polymer dispersion.Type: GrantFiled: August 1, 2001Date of Patent: December 2, 2003Assignee: Wacker-Chemie GmbHInventors: Theo Mayer, Thomas Kohler, Reinhard Harzschel, Hans-Peter Weitzel, Bernd Schilling
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Patent number: 6599446Abstract: Inclusion of relatively small amounts of organic ionic species, such as calcium stearate, in the preparation of an electrically conductive polymer composite composition provides a composition having enhanced electrical properties relative to the composite composition lacking the added organic ionic species. As a result of this enhancement, normally insulating materials which rely upon a conductive filler to render them electrically conductive, can be made to achieve a given level of conductivity using less of the conductive filler than would otherwise be required. As a result, the adverse effects of the conductive filler on the polymer's physical properties can be minimized while maintaining a high level of electrical conductivity.Type: GrantFiled: November 3, 2000Date of Patent: July 29, 2003Assignee: General Electric CompanyInventors: Michael Leslie Todt, David Ernest Rodrigues, Sai-Pei Ting
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Patent number: 6506824Abstract: Biodegradable thermoplastic compositions comprising a starch component, a cellulose ester or ether, a plasticizer for the starchy phase and of the cellulose and derivatives, and a compatibilizer agent selected from polymers compatible with the cellulose and or starchy component, grafted with aliphatic or polyhydroxilated chains; copolymers obtained from hydroxy acids and/or diamines with 2-24C and aliphatic or aromatic diisocyanates; copolymers obtained from aliphatic polyesters, polyureas and polyalkylene glycols and aliphatic or aromatic diisocyanates; copolymers obtained from polymers compatible with cellulose ester or ethers and/or the starchy component by grafting starch soluble polyols; polymer capable of complexing starch; starch compatible polyols.Type: GrantFiled: October 17, 1997Date of Patent: January 14, 2003Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Vittorio Bellotti, Roberto Lombi, Gabriele Perego
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Patent number: 6482876Abstract: The invention relates to an agglomerate containing at least one of the following water-soluble or water-dispersible materials as a bonding base polymer: carboxylized and/or alkoxylized starch, cellulose ether and fully synthetic vinyl polymers and/or polyacrylates. The agglomerate is characterized in that it contains a blasting agent which produces a high swelling pressure, but, advantageously, does not gel. The agglomerate can have a regular geometric form or not. Its weight should be between 0.5 and 500 g. The agglomerate is used in particular in the production of lump-free paste.Type: GrantFiled: March 15, 2000Date of Patent: November 19, 2002Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Sandra Witt-Nuesslein, Werner Haller, Bernhard Schoettmer, Monika Boecker, Wolfgang Seiter, Ingo Hardacker, Heinz-Peter Hoffmann
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Patent number: 6479573Abstract: Process for thickening aqueous systems by addition of aqueous suspensions of water-soluble hydrophobically modified polyurethanes, polyacrylates and poly(acetal- or ketal-polyethers) and carbon containing salts.Type: GrantFiled: September 12, 2001Date of Patent: November 12, 2002Assignee: Hercules IncorporatedInventors: Charles Lee Burdick, Arjun Chandra Sau
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Patent number: 6368356Abstract: The invention provides a means of boosting the mechanical performance of shaped shaped medical devices comprising polymer hydrogels, such as stents, so that they may be more easily inserted into or removed from the body. In one aspect, the invention provides shaped medical devices having increased mechanical strength and comprising both ionic and covalent crosslinks. In another aspect, the invention provides a shaped medical device having a heterogeneous polymer composition and a variable dissolution or degradation rate along its length. The shaped medical devices according to the present invention retain their shape and stiffness during insertion into the body and can swell and soften inside the body to enhance patient comfort.Type: GrantFiled: February 25, 2000Date of Patent: April 9, 2002Assignee: SciMed Life Systems, Inc.Inventors: Sheng Ping Zhong, Arthur R. Madenjian, Douglas E. Godshall, John M. Ronan, Samuel A. Thompson
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Patent number: 6359040Abstract: Aqueous compositions having advantageous Theological properties, preferably including any of enhanced yield stress, enhanced viscosity, and/or enhanced water retention, are disclosed. Included are low-viscosity compositions having high yield stress. The present invention also relates to processes for preparing and using the compositions. Compositions of the present invention comprise aqueous compositions of a polymer having a net ionic charge, and a viscosity promoter having an opposite net ionic charge. Compositions may also comprise a moderating agent to prevent precipitation and/or gelation.Type: GrantFiled: May 11, 1999Date of Patent: March 19, 2002Assignee: Hercules IncorporatedInventor: Charles L. Burdick
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Patent number: 6326421Abstract: A pressure-sensitive adhesive material made of a weakly elastic mixture comprising a continuous phase formed essentially from a physically cross-linked solid rubber, which comprises a blend of A-B-A block copolymer, such as a styrene-isoprene-styrene block copolymer and a diblock copolymer such as styrene-butadiene, styrene-isoprene or a hydrogenated styrene-diene copolymer such as styrenel/etyhlene butylene, a compatible tackifying resin and a low-molecular weight polyisobutylene, optionally modified by butyl rubber, and a discontinuous phase comprising one or more hydrocolloids that are soluble and/or swellable in water.Type: GrantFiled: June 5, 2000Date of Patent: December 4, 2001Assignee: Avery Dennison CorporationInventor: Roger D. A. Lipman
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Patent number: 6284819Abstract: The present invention provides a recording medium comprising a substrate having a glossy coating thereon, wherein the glossy coating comprises a binder and first and second groups of particles, wherein: (a) the first group comprises metal oxide particles, wherein the metal oxide particles are aggregates of smaller, primary particles, (b) the mean diameter of the primary particles is less than about 100 nm, (c) the mean diameter of the aggregates is from about 100 nm to about 500 nm, (d) the mean diameter of the particles in the second group is less than about 50% of the mean diameter of the aggregates in the first group, and (e) the ratio of particles in the first group to particles in the second group is from about 0.1:1 to about 10:1 by weight. The glossy coating of the inventive recording medium has an excellent rate of liquid absorption, a relatively high liquid absorption capacity, excellent adhesiveness, and a non-brittle, crack-resistant, glossy surface.Type: GrantFiled: July 1, 1999Date of Patent: September 4, 2001Assignee: Cabot CorporationInventors: Michael S. Darsillo, David J. Fluck, Rudiger Laufhutte
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Patent number: 6201042Abstract: In a method of making repositionable pressure sensitive adhesive of tacky elastomeric microspheres wherein the microspheres are polymerized and formed in an aqueous suspension which includes a surfactant, a certain amount of the surfactant is removed from the aqueous suspension after completion of polymerization of the microspheres so that a predetermined reduced amount of surfactant remains, with the result that migration of the surfactant from the adhesive is at least substantially reduced.Type: GrantFiled: April 27, 1999Date of Patent: March 13, 2001Inventors: Howard B. Kaye, David K. Holbrook, Brian M. Vogler
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Patent number: 6166119Abstract: A cement pumpability-enhancing additive which confers good pumpability on cementitious compositions such as concrete consists essentially of(a) polyethylene glycol;(b) diethylene glycol monobutyl ether and/or a derivative thereof;(c) polysaccharide; and(d) a thickening polymer selected from the group consisting of polyacrylic acid derivatives, polyacrylic amide derivatives, cellulose ethers, polyphenyl ethers and polyalkylene glycol fatty acid esters;the weight solids proportions of (a), (b), (c), and (d) in the additive being respectively 5-55%, 10-80%, 1-20% and 1-20%. The additive is preferably used with a cement dispersing agent.Type: GrantFiled: April 14, 1999Date of Patent: December 26, 2000Assignee: MBT Holding AGInventors: Shigemi Matsuo, Hidenori Nagamine, Akira Ota
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Patent number: 6143812Abstract: Asphalt release coatings are prepared by applying an aqueous emulsion containing an organopolysiloxane component, an effective amount of one or more emulsifying surfactants, and most minor amount of a multiple release additive. The compositions exhibit improved release, particularly multiple releases, even with polymer modified asphalt binders.Type: GrantFiled: August 25, 1998Date of Patent: November 7, 2000Assignee: Wacker Silicones CorporationInventors: Eugene R. Martin, Michael L. Coffey
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Patent number: 6121439Abstract: A coating composition is composed of a water-soluble polysaccharide composition comprising at least one hydrophobic group selected from aryl, alkyl, alkenyl, aralkyl and mixtures thereof and at least one quaternary ammonium salt group, both connected to a polysaccharide backbone by covalent bonds. This coating is used for improving the leveling of waterborne paints.Type: GrantFiled: July 27, 1998Date of Patent: September 19, 2000Assignee: Hercules IncorporatedInventor: Gijsbert Kroon
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Patent number: 6071984Abstract: This invention relates to reinforced thermoplastic moulding compositions prepared from biodegradable polymers, for example aliphatic or polyester amides, aliphatic polyester urethanes, and to the use thereof for the production of mouldings and to the mouldings, wherein the reinforcing materials are selected from wood flour, fibres of natural origin, minerals of natural origin, cellulose and cellulose derivatives.Type: GrantFiled: June 25, 1998Date of Patent: June 6, 2000Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Hanns Peter Muller, Wolfgang Schulz-Schlitte, Aziz El Sayed, Ralf Timmermann
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Patent number: 6054511Abstract: Hydroxyethylcellulose (HEC), hydrophobically modified hydroxyethylcellulose (HMHEC), hydroxypropylcellulose (HPC), methylhydroxypropylcellulose (MHPC), carboxymethylhydroxyethylcellulose (CMHEC), guar, starch, xanthan, hydroxypropylguar (HP Guar) or carboxymethylhydroxypropylguar (CMHP Guar) are stepwise or continuously reacted with hydrogen peroxide to produce aqueous compositions with a solids content greater than 5% by weight at a viscosity at 25.degree. C. below 9500 mPa.s. It is preferred to use 30-50% hydrogen peroxide to depolymerize the polysaccharide.Type: GrantFiled: January 15, 1993Date of Patent: April 25, 2000Assignee: Aqualon CompanyInventors: J David Angerer, Jashawant Jamanadas Modi, Robert C Szafranski
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Patent number: 5993530Abstract: A thermally-decomposable, biodegradable resin composition is dispersed and stabilized in water optionally along with additives to give an aqueous dispersion of the resin composition. In the dispersion, the base polymer consists substantially of a water-insoluble starch-type, biodegradable resin. The dispersion is usable in various fields of papermaking, non-woven fabric production, film and sheet production and woven fabric production, in those of dispersed adhesive production, and in those of metal processing, plastic processing, wood processing and stone processing.Type: GrantFiled: March 9, 1998Date of Patent: November 30, 1999Assignee: Japan Corn Starch Co., Ltd.Inventors: Hideyuki Tanaka, Nobuhiro Hosokawa, Nobuyuki Sugtura, Masato Takahara
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Patent number: 5994530Abstract: The present invention provides certain carboxymethyl cellulose (CMC) esters of higher acids (e.g., CMC acetate propionate, CMC propionate, CMC acetate butyrate, and CMC butyrate)having specific use in aqueous dispersions useful in formulating waterborne coating compositions containing pigments, especially metallic pigments such as aluminum flakes and mica. The esters also have specific use as wetting agents and in high solids coatings.Type: GrantFiled: June 25, 1998Date of Patent: November 30, 1999Assignee: Eastman Chemical CorporationInventors: Jessica Dee Posey-Dowty, Alan Kent Wilson, Larry Gerald Curtis, Paul Michael Swan, Kab Sik Seo
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Patent number: 5989329Abstract: Water-borne paints containing reduced molecular weight polysaccharide derivatives that are resistant to enzyme hydrolysis. The water-borne paints are biostable, retaining at least about 80% of their initial viscosity 24 hours after they are inoculated with polysaccharide hydrolysis enzyme.Type: GrantFiled: November 10, 1998Date of Patent: November 23, 1999Assignee: Hercules IncorporatedInventor: Arjun Chandra Sau
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Patent number: 5969012Abstract: A non-aqueous slurry comprising(a) one or more water soluble polymers;(b) polyalkylene glycol or thickened polyalkylene glycol; and a(c) a slurry stabilizer comprising an amine phosphate ester salt is provided. The slurry has a number of applications, including oil recovery, and in the paper and textile industries.Type: GrantFiled: May 29, 1997Date of Patent: October 19, 1999Assignee: Rhodia Inc.Inventor: William F. Harris, Jr.
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Patent number: 5925182Abstract: A stable liquid suspension composition comprising a liquid carrier, a solid fatty acid or a salt thereof, and a solid particulate is disclosed wherein said liquid carrier is selected from the group consisting of oils, olefins, terpenes, glycols, esters, ethers, alcohols, and combinations of any two or more thereof and said liquid carrier, solid fatty acid or salt thereof, and solid particulate are each present in said composition in a stabilizing amount sufficient to produce a stable liquid suspension. Also disclosed is a stable liquid composition comprising a liquid carrier, an oil-soluble polymer, and a solid particulate wherein said liquid carrier is selected from the group consisting of olefins, terpenes, esters, and combinations of any two or more thereof and said liquid carrier, oil-soluble polymer, and solid particulate are each present in said composition in a stabilizing amount sufficient to effect the formation of a stable liquid suspension.Type: GrantFiled: July 16, 1998Date of Patent: July 20, 1999Assignee: Phillips Petroleum CompanyInventors: Bharat B. Patel, Marshall D. Bishop
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Patent number: 5922119Abstract: The invention is directed to the use of an aqueous protective coating composition containing a binder system and an associative thickener for industrial coatings. The associative thickener is not a polyurethane thickener and is selected so that its concentration required by the specific application method is below the critical concentration C*, defined as the thickener concentration at which the coils of the thickener polymer start to overlap of entangle calculated according to the Mark Houwink equation.Type: GrantFiled: March 27, 1998Date of Patent: July 13, 1999Assignee: Hercules IncorporatedInventor: Kroon Gijsbert
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Patent number: 5883155Abstract: Elastomer films in which active chemical substances, such as corrosion inhibitors, lubricants or biocides for medical use are uniformly dispersed in the form of gel inclusions, processes for preparation and applications of these films.The elastomer film contains at least one active chemical substance in the form of a phase which is dispersed in the elastomer, wherein the disperse phase is in the form of a gel, reversible or irreversible, as a function of temperature, and filled with an active chemical substance.Type: GrantFiled: November 4, 1996Date of Patent: March 16, 1999Assignee: HutchinsonInventors: Pierre Hoerner, Gerard Riess, Rene Guy Busnel, Andre Cheymol
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Patent number: 5879440Abstract: Water-borne paints containing reduced molecular weight polysaccharide derivatives that are resistant to enzyme hydrolysis. The water-borne paints are biostable, retaining at least about 80% of their initial viscosity 24 hours after they are inoculated with polysaccharide hydrolysis enzyme. A process for making the biostable water-borne paints has the steps: a) treating precursor polysaccharide derivative with polysaccharide hydrolysis enzyme in aqueous medium for a time sufficient to obtain reduced molecular weight polysaccharide derivative; and b) mixing the reduced molecular weight polysaccharide derivative with an effective amount of at least one other water-borne paint ingredient to obtain a water-borne paint.Type: GrantFiled: July 28, 1997Date of Patent: March 9, 1999Assignee: Hercules IncorporatedInventor: Arjun Chandra Sau
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Patent number: 5847031Abstract: A polymer composition, in particular an active substance-containing depot material composition or an absorbent composition are disclosed which substantially consist of a water-soluble and/or water-swellable polymer based on polysaccharides as the main component, and a water-swellable, synthetic polymer as further component, used as polymeric components, and of a matrix material for the prevention of separation and gel blocking, an ionic or covalent cross-linking agent, as well as of an anti-blocking agent. Additionally their production and use as well as (animal) hygiene items and chemico-technical products are disclosed which comprise these polymer compositions, these active-substance-containing depot material compositions, or the absorbent compositions.Type: GrantFiled: January 16, 1996Date of Patent: December 8, 1998Assignee: Chemische Fabrik Stockhausen GmbHInventors: Helmut Klimmek, Uwe Gunther, Helmut Bruggemann
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Patent number: 5834538Abstract: A pressure sensitive adhesive(PSA) composition includes a latex system of an aqueous polymer dispersion derived from ethylenically-unsaturated monomers in the presence of a water soluble protective colloid. The PSA compositions are used in the manufacture of a variety of articles that are intended to be easily attachable to another substrate by the application of pressure alone.Type: GrantFiled: June 18, 1996Date of Patent: November 10, 1998Assignee: Hercules IncorporatedInventors: Jacobus G. deHullu, Dirk Kruythoff, Willemien G. Salomons, Adriana Veldhorst
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Patent number: 5834533Abstract: A stable liquid suspension composition comprising a liquid carrier, a solid fatty acid or a salt thereof, and a solid particulate is disclosed wherein said liquid carrier is selected from the group consisting of oils, olefins, terpenes, glycols, esters, ethers, alcohols, and combinations of any two or more thereof and said liquid carrier, solid fatty acid or salt thereof, and solid particulate are each present in said composition in a stabilizing amount sufficient to produce a stable liquid suspension. Also disclosed is a stable liquid composition comprising a liquid carrier, an oil-soluble polymer, and a solid particulate wherein said liquid carrier is selected from the group consisting of liquid alkenes, terpenes, esters, and combinations of any two or more thereof and said liquid carrier, oil-soluble polymer, and solid particulate are each present in said composition in a stabilizing amount sufficient to effect the formation of a stable liquid suspension.Type: GrantFiled: November 20, 1996Date of Patent: November 10, 1998Assignee: Phillips Petroleum CompanyInventors: Bharat B. Patel, Marshall D. Bishop
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Patent number: 5830933Abstract: A denture adhesive composition contains a denture adhesive and a pharmacologically acceptable carrier in which the denture adhesive is a salt of a copolymer of maleic acid or anhydride and a 1 to 5 carbon atom alkyl vinyl ether having a specific viscosity of at least 4.0. The denture adhesive composition is used to adhere a denture to the oral mucosa.Type: GrantFiled: April 22, 1996Date of Patent: November 3, 1998Assignee: Block Drug Company, Inc.Inventors: Joseph Synodis, Alfred J. Smetana, Robert C. Gasman, Eddie Wong, Hal C. Clarke
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Patent number: 5830934Abstract: An emulsion polymer is disclosed by the present invention. In particular, the emulsion polymer comprises a protective colloid and a functionalized silane component which is of the formula: ##STR1## wherein R" is C.sub.1 -C.sub.5 alkyl, R' is C.sub.1 -C.sub.5 alkyl, R is SH, CH.sub.2 .dbd.CH--, CH.sub.2 .dbd.C(CH.sub.3)--C(O)O--, CH.sub.2 .dbd.CH--C(O)O--, and ##STR2## n is 1-10, and m is 2 or 3.Type: GrantFiled: October 27, 1995Date of Patent: November 3, 1998Assignee: Reichhold Chemicals, Inc.Inventor: Venkataram Krishnan
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Patent number: 5785747Abstract: The present invention provides compositions useful for viscosifying aqueous fluids, methods for making them and methods for using them. In one aspect of the invention, inventive compositions comprise a prehydrating alcohol having at least two hydroxyl groups and having a molecular weight of from about 60 to about 600; an inorganic salt; and a polymer. In a preferred aspect of the invention, the viscosifier composition additionally comprises a solvent having a molecular weight of from about 75 to about 1000. According to another aspect of the invention, inventive compositions comprise a prehydrating alcohol; an inorganic salt; and a polymer; and the composition is essentially free from water. Inventive compositions find advantageous use in viscosifying fluids utilized in subterranean drilling activities such as, for example, drilling, drill-in, completion, hydraulic fracturing, work-over, packer, well treating, testing, spacer, or hole abandonment fluids.Type: GrantFiled: January 17, 1997Date of Patent: July 28, 1998Assignee: Great Lakes Chemical CorporationInventors: Daniel P. Vollmer, Paul H. Javora, Robert L. Horton
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Patent number: 5780519Abstract: Lignocellulosic light weight molding products which are useful as heat insulator, shock absorber, sound absorber and so on and have open-celled foam-structure are mainly composed of lignocellulose that is able to use in not only fibrous shape but also other various shapes. They are at least composed of four components shown hereunder; (1) lignocellulose, (2) water soluble high polymer containing not less than two OH groups in a molecule and having the film properties of tensile strength 10 to 300 MPa and surface tension 30 to 65 mN/m in 0.4 wt % aqueous solution at 20.degree. C., (3) water soluble high polymer containing not less than two carboxyl groups in a molecule and/or anionic surfactant, and (4) high polymer having the film properties of tensile strength 0.1 to 10 MPa and ultimate elongation 200 to 2000%, 2nd transition point 30.degree. to 40.degree. C. and cohesion energy density 30 to 200 cal/cc.Type: GrantFiled: March 28, 1997Date of Patent: July 14, 1998Inventor: Saburo Imoto
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Patent number: 5750591Abstract: A denture adhesive with significantly improved hold performance is comprised of the mixed partial salts of polymethyl vinyl ether maleic acid. At least one of said salts comprises zirconium while a second salt is selected from the group consisting of calcium, zinc, magnesium, iron, strontium and mixtures thereof. Optionally, a tripartite salt formulation may be prepared utilizing sodium, lithium or potassium. The adhesives are formulated in a standard pharmaceutically acceptable vehicle comprised of waxes, oils, colorants, viscosity modifiers and the like as is known in the art. The denture adhesive may be formulated as a paste, powder or liquid which has rapid absorption characteristics for faster swelling softening and superior coalescence.Type: GrantFiled: March 3, 1997Date of Patent: May 12, 1998Assignee: The Block Drug CompanyInventors: Hal C. Clarke, Hyung-Kook Ahn, Eddie Wong, Robert C. Gasman, Alfred J. Smetana, Joseph Synodis, Tiang Shing Chang
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Patent number: 5744520Abstract: A process for the preparation of polymer compositions which comprises mixing a conductive component with an anionic polymeric latex containing a polymer; adding a cationic surfactant, or flocculant whereby the aggregation of the latex particles and the conductive component particles results; subsequently adding colloidal stabilizer, followed by the addition of a base to obtain a pH of from about 7 to about 12; heating above about the polymer glass transition temperature thereby enabling the severage, or breakage of the formed aggregated particles; further heating above about the polymer glass transition temperature enabling the coalescence of the polymer and conductive component particles; and optionally washing and drying the resulting coalesced product.Type: GrantFiled: July 19, 1996Date of Patent: April 28, 1998Assignee: Xerox CorporationInventors: Grazyna E. Kmiecik-Lawrynowicz, Richard P. N. Veregin, Raj D. Patel, Michael A. Hopper, Maria V. McDougall
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Patent number: 5741836Abstract: This invention is a screen-printable ink receptive composition. It contains (a) a hydrophilic polymer and (b) a thickener and has (c) a viscosity of 10 to 1,000 poise at shear rates less than 10.degree. s.sup.-1 and exhibits (d) a shear thinning behavior defined by the following relationship:log(viscosity)=A ?log(shear rate)!wherein A represents (e) the slope of the line obtained by plotting log(viscosity) against log(shear rate) and has (f) a value of up to -0.1 when calculated over shear rates ranging from 10.degree. to 10.sup.-2 s.sup.-1.Type: GrantFiled: December 22, 1994Date of Patent: April 21, 1998Assignee: Eastman Kodak CompanyInventors: Mary A. Krenceski, Kevin J. Swallow, Douglas Eugene Bugner, Alfred John Amell
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Patent number: 5736595Abstract: A polymer composition, a process for the production of a polymer composition, in particular of an absorbent, are disclosed which substantially consist of a special component A based on renewable polysaccharide raw materials, a special component B consisting of a water-soluble polymer, a matrix material, an ionic and/or covalent cross-linking agent, or an anti-blocking agent, which is obtainable in that the water-swellable polymer is brought together with the polysaccharide polymer, that these are dried and ground then, the other components are added, and mixing up to homogeneity is effected followed by a heat treatment, and that during the addition of the cross-linking agent, after said heat treatment, the same is optionally fixed by the matrix by means of a final heat treatment.Additionally the use of this polymer composition and (animal) hygiene items and chemico-technical products are disclosed which comprise a previously manufactured polymer composition.Type: GrantFiled: November 3, 1995Date of Patent: April 7, 1998Assignee: Chemische Fabrik Stockhausen GmbHInventors: Uwe Gunther, Helmut Klimmek, Helmut Bruggemann
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Patent number: 5725648Abstract: This invention relates to paper coating compositions comprising pigment, adhesive binder and rheology modifier wherein the rheology modifier comprises at least one of a) a mixture of guar and at least one other water-soluble polymer in sufficient amount to reduce the amount of guar adsorbed onto the pigment, or b) reduced molecular weight guar. The invention also relates to processes for making coated paper using the coating compositions, and to paper coated with the coating compositions.Type: GrantFiled: September 25, 1996Date of Patent: March 10, 1998Assignee: Hercules IncorporatedInventors: Michael J. Brown, Teng-Shau Young
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Patent number: 5721295Abstract: A polymer composition, in particular an absorbent composition or an active substance-containing depot material are disclosed which substantially consist of a water-soluble and/or water-swellable polymer based on polysaccharides as the main component, and of a water-swellable polymer as further component, used as polymeric components, and of a matrix material for the prevention of separation and gel blocking, an ionic or covalent cross-linking agent, a reactive additive, as well as of an anti-blocking agent. Additionally, their production and use as well as (animal) hygiene items and chemico-technical products are disclosed which comprise these polymer compositions or absorbent compositions.Type: GrantFiled: January 26, 1996Date of Patent: February 24, 1998Assignee: Chemische Fabrik Stockhausen GmbHInventors: Helmut Bruggemann, Uwe Gunther, Helmut Klimmek
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Patent number: 5705553Abstract: Copolymers containing carboxyl groups in aqueous dispersion form or redispersible powder form and their water-soluble salts, based on ethylenically unsaturated and copolymerizable monomers, the macro-molecules of which contain at least 24% by weight of monomer units carrying carboxyl groups prepared, by emulsion copolymerization initiated by free radicals in the presence of polyvinyl alcohol (PVA) or polyvinylpyrrolidone (PVP) dissolved in the aqueous phase and isolation of the copolymers in aqueous dispersion form, and optionally subsequent removal of water by spray drying to obtain redispersible copolymer powders and processes for their preparation and their use as thickeners in aqueous formulations which copolymers, by conversion into their water-soluble salt forms, are useful as thickening agents having a surprisingly advantageous rheology-modifying action in aqueous systems.Type: GrantFiled: November 13, 1995Date of Patent: January 6, 1998Assignee: Hoechst AktiengesellschaftInventor: Rolf Kuropka
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Patent number: 5698612Abstract: The present invention provides thermoplastically workable and completely biodegradable moulding compositions, a process for the preparation thereof and the use thereof as biodegradable materials for the production of, for example, injection-moulded parts, films, fibres or coatings.Type: GrantFiled: December 11, 1996Date of Patent: December 16, 1997Assignee: Bayer AkteingesellschaftInventors: Joachim Simon, Hanns Peter Muller, Dirk Jacques Dijkstra, Jurgen Engelhardt, Volkhard Muller, Gunter Weber
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Patent number: 5696181Abstract: An improved denture adhesive composition is comprised of a highly cross-linked lower alkyl ether/maleic acid or maleic anhydride copolymer in which up to about 85% of the initial free carboxyl groups are reacted with one or more cross-linking agents. The cross-linking agents are mixtures of inorganic divalent cations such as calcium, magnesium and zinc together with organic bifunctional compounds comprised of polyhydroxyl compounds such as propylene glycol, glycerin and the like. The copolymer has a specific viscosity of no less than 1.5. A hydrophilic polymer such as sodium alginate or carboxymethyl cellulose may also be added to the lower alkyl vinyl ether/maleic acid or maleic anhydride copolymer which is then formulated with other excipients in a paste, powder, liquid, gel or cream composition.Type: GrantFiled: September 22, 1995Date of Patent: December 9, 1997Assignee: The Block Drug Company, Inc.Inventors: Tiang-Shing Chang, Donna DiFerdinando
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Patent number: RE36657Abstract: A denture adhesive composition contains a denture adhesive and a pharmacologically acceptable carrier in which the denture adhesive is a salt of a copolymer of maleic acid or anhydride and a 1 to 5 carbon atom alkyl vinyl ether having a specific viscosity of at least 4.0. The denture adhesive composition is used to adhere a denture to the oral mucosa.Type: GrantFiled: November 18, 1998Date of Patent: April 11, 2000Assignee: Block Drug Company, Inc.Inventors: Joseph Synodis, Alfred J. Smetana, Robert C. Gasman, Eddie Wong, Hal C. Clarke