Carboxyalkyl Or Alkali Metal Salt Thereof Patents (Class 524/45)
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Patent number: 5668273Abstract: This invention provides certain carboxymethyl cellulose (CMC) esters of higher acids (e.g., CMC acetate propionate, CMC propionate, CMC acetate butyrate, and CMC butyrate). These new ether derivatives of cellulose esters exhibit solubility in a wide range of organic solvents, compatibility with a variety of resins, and ease of dispersion in a water-borne formulation and are useful in coating compositions as binder resins and theology modifiers.Type: GrantFiled: January 29, 1996Date of Patent: September 16, 1997Assignee: Eastman Chemical CompanyInventors: John Michael Allen, Alan Kent Wilson, Paul Lee Lucas, Larry Gerald Curtis
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Patent number: 5631313Abstract: A new stable liquid suspension of a non soluble particulate material, and a method of preparation of same are provided. Such compositions comprise at least one oil, one oil soluble resin and a non oil soluble particulate material mixed together In the appropriate quantities and conditions.Type: GrantFiled: November 14, 1991Date of Patent: May 20, 1997Assignee: Phillips Petroleum CompanyInventors: Marshall D. Bishop, John E. Hostettler
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Patent number: 5616635Abstract: The present invention discloses a multicolor paint formulation which is comprised of:(1) from about 5 to about 30 weight percent of a neutralized latex made by a method which comprises (A) free radical aqueous emulsion polymerizing at a pH of less than about 3.5 a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 45 to about 85 weight percent vinyl aromatic monomers, (b) from about 15 to about 50 weight percent of at least one alkyl acrylate monomer, and (c) from about 1 to about 6 weight percent of at least one unsaturated carbonyl compound; in the presence of about 0.5 to 4.0 phm at least one phosphate ester surfactant and in the presence of about 0.5 to 4.0 phm of at least one water insoluble nonionic surface active agent to produce a latex, and (B) neutralizing the latex with ammonia to a pH which is within the range of about 7 to about 10.5 to produce the neutralized latex;(2) from about 0.5 to about 10 weight percent of hectorite clay;(3) from about 0.Type: GrantFiled: November 27, 1995Date of Patent: April 1, 1997Assignee: The Goodyear Tire & Rubber CompanyInventor: Kantilal D. Patel
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Patent number: 5612385Abstract: Novel aerated fibrous slurry comprising fibrous material, foaming agent, stabilizer, water and gas, which when dried to a water content of not more than 10% by weight, forms a dry, resilient fibrous foam composition. The dry, resilient fibrous foam composition is useful as an inexpensive cushioning filler, as a heat insulating material and as an absorbent of liquids.Type: GrantFiled: August 30, 1994Date of Patent: March 18, 1997Inventors: Anthony Ceaser, Mark A. Ceaser
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Patent number: 5596031Abstract: The present invention relates to absorbent materials comprising fibers cross-linked by a suitable heat activatable compound therefor, and wherein said heat activatable compound is associated with substantially the entire surface of each fiber, said materials being preparable by mixing of an aerated suspension of the charged fibers with the heat activated compound before heating and compressing, such fibers having a capacity for fluid absorption considerably greater than has been heretofore known for such materials.Type: GrantFiled: October 3, 1994Date of Patent: January 21, 1997Inventor: Peter M. Lock
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Patent number: 5591790Abstract: The present invention relates to absorptive dressings which are highly absorbent and which retain moisture, said dressings comprising cross-linked cellulosic fibers wherein the cross-linker has been blended with the fibers after electrostatically charging the fibers, the retentive membrane being a layer of thermoplastic which has been laminated onto the dressing at its glass transition temperature, thereby giving the membrane selective moisture permeability properties.Type: GrantFiled: June 7, 1995Date of Patent: January 7, 1997Inventor: Peter M. Lock
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Patent number: 5561177Abstract: An improved denture adhesive that exhibits superior tack, adhesion, cohesive strength and spreadability characteristics is made from a hydrocarbon-free base consisting of a mixture of medium length chain triglycerides which have been mixed with a small amount of fumed silica and other components so as to improve the viscosity, spreadability and taste. Preferred triglycerides include captic and caprylic acids and in particular, a mixture of the caprylic and captic acids which are combines with fumed silica and a water soluble cellosic polymer and a synthetic methyl vinyl ether/maleic anhydride copolymer that is formulated as a paste or gel.Type: GrantFiled: June 27, 1995Date of Patent: October 1, 1996Assignee: The Block Drug CompanyInventors: Nilofar Khaledi, Eddie Wong, Joseph Synodis, Hal C. Clarke, Robert C. Gasman, Alfred J. Smetana
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Patent number: 5543443Abstract: Disclosed are denture adhesive compositions possessing improved aesthetics and comprising a component which provides for easy removal of the adhesive from the denture and a hydrophilic powder.Type: GrantFiled: August 3, 1992Date of Patent: August 6, 1996Assignee: The Procter & Gamble CompanyInventors: Jayanth Rajaiah, Abel Saud, Bruce J. MacKay, Dennis R. Grubbs
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Patent number: 5541241Abstract: At least 20% of poly(vinyl alcohol) (PVA) is dispersed in an aqueous solution of at least one salt dissolved therein selected from the group of sodium or potassium formate, sodium, potassium, or magnesium sulfate, sodium or potassium citrate, sodium or potassium polyacrylate, or mixtures thereof. This aqueous suspension of PVA is useful in systems in which PVA is dissolved in order to reduce the time of dissolution.Type: GrantFiled: October 20, 1995Date of Patent: July 30, 1996Assignee: Hercules IncorporatedInventors: Charles L. Burdick, James L. Latta
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Patent number: 5534561Abstract: Ad adhesive composition suitable for wound dressing and other medical applications comprising a mixture of polyisobutylene and a rubber polymer selected from the group consisting of random styrene butadiene copolymer (SBR) and halobutyl rubber so as to form a rubbery elastomer base matrix, and at least one hydrocolloid. The addition of the SBR or halobutyl rubber to the elastomer base offsets the possible degradation of the polyisobutylene upon sterilization, and therefore, helps to maintain the integrity of the composition. Water soluble hydrocolloid gums and water swellable cohesive strengthening agents are dispersed within the base matrix and may carry a pharmaceutical agent to be dispensed directly to a wound site.Type: GrantFiled: July 18, 1994Date of Patent: July 9, 1996Inventor: Robert W. Volke
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Patent number: 5523331Abstract: A rubber composition or a rubber composite which is biodegradable in soil and is used to hold pot soil to the roots of plants to facilitate transplanting, said rubber composition containing a natural or synthetic rubber component and a water-soluble additive which does not bind to the rubber component and thus can elute into the soil.Type: GrantFiled: October 19, 1993Date of Patent: June 4, 1996Assignee: Asahi Co., Ltd.Inventor: Shoji Ezoe
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Patent number: 5504123Abstract: Cellulose ether derivatives comprising a hydrophobic substituent having an unsaturated alkyl portion are disclosed. The unsaturation in the alkyl portion of the hydrophobic substituent can promote crosslinking of the cellulose ether derivative. The cellulose ether derivatives are useful as ingredients in latex compositions. The cellulose ether derivatives can provide associative thickening and rheological properties to latex composition during storage and application. In addition, after the latex composition is applied to the surface to be coated, the cellulose ethers of the present invention can promote crosslinking of the latex film to provide a hard and durable coating. Latex paint compositions comprising the cellulose ether derivatives of the present invention are also disclosed.Type: GrantFiled: December 20, 1994Date of Patent: April 2, 1996Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Emmett M. Partan, III
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Patent number: 5492943Abstract: A pressure sensitive adhesive composition particularly suitable for use as a protective skin barrier material for sealing the faceplate of an ostomy appliance, such as the faceplate of a one-piece or two-piece urostomy or an ileostomy appliance, to skin surfaces surrounding a patient's stoma. The composition includes a blend of two viscoelastic adhesive elastomers, specifically, high molecular weight polyisobutylene and a styrene block copolymer, which, along with a plasticizer (preferably petrolatum) and a suitable tackifier and antioxidant, form a continuous phase in which hydrocolloids such as sodium carboxymethylcellulose and pectin are dispersed. The composition is exceptional for its durability, flexibility and strength, even when saturated, and for its controlled swelling upon hydration.Type: GrantFiled: June 20, 1994Date of Patent: February 20, 1996Assignee: Hollister IncorporatedInventor: Emil Stempel
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Patent number: 5489638Abstract: At least 20% of poly(vinyl alcohol) (PVA) is dispersed in an aqueous solution of at least one salt dissolved therein selected from the group of sodium or potassium formate, sodium, potassium, or magnesium sulfate, sodium or potassium citrate, sodium or potassium polyacrylate, or mixtures thereof. This aqueous suspension of PVA is useful in systems in which PVA is dissolved in order to reduce the time of dissolution.Type: GrantFiled: April 2, 1992Date of Patent: February 6, 1996Assignee: Aqualon CompanyInventor: Charles L. Burdick
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Patent number: 5478872Abstract: It is the object of the present invention to provide a hydrophilic surface treating aqueous solution, hydrophilic surface treating method, and hydrophilic surface treating film with lasting hydrophilicity and ensuring a film having a good processability. The hydrophilic treating aqueous solution contains as main components a hydrophilic polymer having a specific molecular weight and containing a polyoxyalkylene chain of 10 wt % or more in terms of solid content, and a specific aqueous resin. This enables the formation of film with good processability and good hydrophilicity and persistency of hydrophilicity on the surface of aluminum or aluminum alloy for use in aluminum fins of a heat exchanger, as well as suppressing the generation of unpleasant odor.Type: GrantFiled: May 6, 1994Date of Patent: December 26, 1995Assignee: Nippon Paint Co., Ltd.Inventors: Katsuyoshi Yamasoe, Fujio Mikami, Hidekimi Hirasawa, Masahiko Matsukawa, Kouji Mizohata
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Patent number: 5473005Abstract: A water based thixotropic adhesive gel is disclosed which contains: water; polyvinyl alcohol, or wherein a portion of the polyvinyl alcohol is replaced with polyvinylpyrrolidone; xanthan gum to impart thixotropic properties to the gel; and a plasticizer for the polyvinyl alcohol. The gel has a thixotropic index which permits the viscosity of the adhesive to break down when a flexible tube or squeeze bottle dispenser is finger-pressed while having a sufficiently low viscosity to allow for easy extrusion from an orifice having a diameter of about 0.06 to 0.15 inches. When pressure is released, after the desired amount of adhesive has flown out of the dispenser, the adhesive quickly reverts to very close to its original gel state so that it does not run on a vertical surface of porous or semiporous material such as paper. Preferred gels contain a water soluble dye and are clear.Type: GrantFiled: February 9, 1994Date of Patent: December 5, 1995Assignee: Borden, Inc.Inventors: Peter S. Columbus, John Anderson, Yogeshbhai B. Patel
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Patent number: 5466724Abstract: An adhesive composition suitable for wound dressing and other medical applications comprising a mixture of polyisobutylene and a rubber polymer selected from the group consisting of random styrene butadiene rubber (SBR) and halobutyl rubber so as to form a rubbery elastomer base matrix, and at least one hydrocolloid. The addition of the SBR or halobutyl rubber to the elastomer base offsets the possible degradation of the polyisobutylene upon sterilization, and therefore, helps to maintain the integrity of the composition. Water soluble hydrocolloid gums and water swellable cohesive strengthening agents are dispersed within the base matrix and may carry a pharmaceutical agent to be dispensed directly to a wound site.Type: GrantFiled: March 20, 1995Date of Patent: November 14, 1995Assignee: Variseal CorporationInventors: Robert W. Volke, Debashish Chakravarthy
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Patent number: 5432213Abstract: The present invention relates to a high strength water-permeable resinous road paving composition characterized by the use of 2-20 weight parts of thermosetting resin as a binder per 100 weight parts of granular aggregate and 1-20 weight parts of cellulose or 1-30 weight parts of lignocellulose as botanical fiber or their derivatives as additives per 100 weight parts of said thermosetting resin.Another feature of the present invention is to mix certain amount of inorganic substances in fine granular or fibrous form together with said granular aggregate, thermosetting resin, cellulose or lignocellulose, or their derivatives, wherein said inorganic substance is 5-200 weight parts per 100 weight parts of said resin. Furthermore, footpath blocks or pavement of footpaths, driveways, plazas, etc. by the use of the composition of the present invention is another feature of the present invention.Type: GrantFiled: September 20, 1993Date of Patent: July 11, 1995Assignee: Samsung General Chemicals Co., Ltd.Inventors: Hyun-Don Kim, Cheon-Seok Lee, Ju-Hyun Son, Seung-Ho Jeon
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Patent number: 5432215Abstract: Building material products, such as, for example, jointing compounds, adhesives, emulsion paints, synthetic plasters, fillers and the like, comprising a mixture ofa) at least 10% by weight, in particular 10 to 99% by weight, of a water-soluble natural polymer and derivatives thereof,b) 1 to 89% by weight of an alkali metal salt or ammonium salt of a crosslinked polyacrylate which, if desired, is grafted with a starch, andc) 0 to 60% by weight of a water-soluble alkali metal salt or alkaline earth metal salt of arylsulfonic acid/formaldehyde condensation products or of a sulfo-modified melamine/formaldehyde polycondensation product.Type: GrantFiled: March 18, 1992Date of Patent: July 11, 1995Assignee: Hoechst AGInventors: Friedrich Girg, Jozef Bohme-Kovac
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Patent number: 5430078Abstract: An electrodeposition coating composition is described comprising:(a) an aqueous dispersion of a water-dispersible, electrically-depositable resin, and(b) a water-soluble cellulose ether.Type: GrantFiled: August 31, 1993Date of Patent: July 4, 1995Assignee: BASF CorporationInventors: Monika Hoppe-Hoeffler, Linda K. Borton, Charles L. Tazzia
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Patent number: 5420180Abstract: A size for yarn which minimizes thread break is described. The size comprises an aqueous solution of (I) a polyvinyl alcohol resin, (II) a modified starch, and a water-soluble cellulose compound (III), wherein the components are related by the following equations:(I)/(II)+(III))=85/15 to 95/5, and(II)/(III)=20/80 to 80/20,while simultaneously satisfying the expressions0.27X-0.7.ltoreq.log.sub.10 Y.ltoreq.0.27X+0.6; and (1)20.ltoreq.Y.ltoreq.300; (2)(A)/(B).ltoreq.0.5 (3)where X is the solid concentration in % by weight, Y is viscosity in centipoise at 90.degree. C. and a shear rate of 10 sec.sup.-1, (A) is viscosity at 60.degree. C. and a shear rate of 10,000 sec.sup.-1 of an adjusted aqueous solution resulting from the adjustment of the viscosity to 100 centipoise at 60.degree. C. and a shear rate of 10 sec.sup.-1 with said compound ratio of each of the components kept constant, and (B) is viscosity of 100 centipoise at 60.degree. C. and a shear rate of 10 sec.sup.-1 of said adjusted aqueous solution.Type: GrantFiled: October 26, 1993Date of Patent: May 30, 1995Assignee: Kuraray Co., Ltd.Inventors: Tetsuya Katayama, Hirotoshi Miyazaki, Hitoshi Maruyama, Koji Onishi
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Patent number: 5382609Abstract: The present invention relates to absorbent materials comprising fibers cross-linked by a suitable cross-linker therefor, and wherein said cross-linker is associated with substantially the entire surface of each fiber, said materials being preparable by mixing of an aerated suspension of the charged fibers with the cross-linker before heating and compressing, such fibers having a capacity for fluid absorption considerably greater than has been heretofore known for such materials.Type: GrantFiled: June 25, 1992Date of Patent: January 17, 1995Inventor: Peter M. Lock
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Patent number: 5369145Abstract: A denture adhesive composition contains an adhesive mixture comprising carboxymethyl cellulose and partially neutralized sodium, a salt of an alkylvinyl ether maleic acid copolymer that forms crosslinked polymer complex compounds in situ with zinc cations.Type: GrantFiled: June 14, 1993Date of Patent: November 29, 1994Assignee: Block Drug CompanyInventors: Robert C. Gasman, Eddie Wong, Hal C. Clarke, Hyung-kook Ahn
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Patent number: 5360843Abstract: Water soluble cellulose acetoacetates prepared by contacting a cellulose material with diketene, an alkyl acetoacetate, 2,2,6-trimethyl-4H-1,3-dioxin-4-one or a mixture thereof in a solvent system comprising lithium chloride plus a carboxamide. Compositions containing the cellulose acetoacetates and, optionally, a crosslinking agent are useful for coatings applications.Type: GrantFiled: December 2, 1993Date of Patent: November 1, 1994Assignee: Eastman Chemical CompanyInventors: Kevin J. Edgar, William W. Blount, Jr.
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Patent number: 5340389Abstract: The invention provides aqueous multicolor compositions containing discrete hydrated colored globules dispersed in an aqueous dispersing medium containing a film forming material. To impart the enhanced properties of long term stability and resistance to application by means of brush and roller, the globules are obtained by reacting two or more pigment containing hydrophilic colloids selected from carboxylated cellulose colloids, polysaccaride gums and acrylic polymers with at least two metal cations selected from Fe.sup.3+, Al.sup.3+, Ca.sup.2+, and Mg.sup.2+. The thus obtained colored globules contain from 2.5 to 20.0% by weight of pigment and fillers and 10 to 40% by weight of a film forming resin. The globules constitute and are about 60 to 90% by weight of the final composition, while the dispersing medium is 40 to 10% by weight of the final composition.Type: GrantFiled: June 18, 1993Date of Patent: August 23, 1994Assignee: Brymore Enterprises S.A.Inventor: Germano Bollini
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Patent number: 5284897Abstract: A water based thixotropic adhesive gel is disclosed which consists essentially of: water; partially hydrolyzed polyvinyl alcohol, or wherein a portion of the polyvinyl alcohol is replaced with polyvinylpyrrolidone; a water-soluble high viscosity thickening agent polymer which is compatible with the polyvinyl alcohol and which imparts thixotropic properties to the gel; a water-soluble plasticizer for the polyvinyl alcohol; and a watersoluble defoamer in proportion of ingredients so that the viscosity of the adhesive will break down when a flexible tube or squeeze bottle dispenser is finger-pressed and have a sufficiently low viscosity to allow for easy extrusion from an orifice having a diameter of about 0.06 to 0.15 inches. When pressure is released, after the desired amount of adhesive has flown out of the dispenser, the adhesive quickly reverts to very close to its original gel state so that it will not run on a vertical surface on porous and semiporous surfaces such as paper.Type: GrantFiled: November 16, 1992Date of Patent: February 8, 1994Assignee: Borden, Inc.Inventors: Peter S. Columbus, John Anderson, Yogeshbhai B. Patel
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Patent number: 5278203Abstract: Water-soluble, polymer viscosifiers of aqueous solutions, also known as gelling agents, can be suspended in a hydrocarbon carrier fluid, such as, diesel to prepare a liquid gel concentrate. When a liquid gel concentrate is added to an aqueous solution the gelling agent disperses into it and viscosifies it. To make an improved performance admixture for preparation of liquid gel concentrates and render the gelling agent suspendable in the hydrocarbon carrier fluid, it is first coated with a mixture of an oil-compatible polymer suspending agent, such as a polymer suspension, comprising a branched chain alkyl acrylate monomer copolymerized with a minor amount of hydrophilic monomer such as acrylic acid with an appropriate amount of internal crosslinking agent to control polymer particle size, and a surfactant such as a nonylphenol reacted with several moles of ethylene oxide, styrenated phenol ethoxylate, or a phosphate ester of styrenated phenol ethoxylate.Type: GrantFiled: November 5, 1992Date of Patent: January 11, 1994Assignee: Halliburton CompanyInventor: Weldon M. Harms
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Patent number: 5272191Abstract: The rate of disintegration in cold water of water soluble packaging films is improved by incorporating into a film forming polymer composition, to form a dry blend or aqueous dispersion, a substantially water insoluble cellulose material prepared from alkali metal salts of carboxy(lower alkyl) cellulose or hydroxy(lower alkyl) cellulose. The increased disintegration is achieved without loss of film stability and, in some cases, the film stability is improved.Type: GrantFiled: August 21, 1991Date of Patent: December 21, 1993Assignee: FMC CorporationInventors: Nagui I. Ibrahim, Richard M. Herbert
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Patent number: 5258429Abstract: Cellulose ether compositions based on rapidly dissolving, pulverulent, water soluble cellulose ethers contain swellable and suction active superabsorbents to prevent the formation of lumps when dissolved. The cellulose ether composition can be converted into compression moulded pieces which retain the rapid solubility and dissolve without forming lumps.Type: GrantFiled: May 20, 1992Date of Patent: November 2, 1993Assignee: Wolff Walsrode AGInventors: Reinhard Kniewske, Eugen Reinhardt
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Patent number: 5217529Abstract: Insulating materials consisting of artificial mineral fibers are impregnated with water insoluble additives, e.g. dust binders and/or water repellant finishing agents in that they are wetted with an emulsion of the water insoluble additive in an aqueous solution of a cellulose ether. Impregnation takes place easily and is effective and resistant.Type: GrantFiled: May 25, 1990Date of Patent: June 8, 1993Assignee: Isover Saint-GobainInventors: Hartmut Tiesler, Joseph Schirmeisen
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Patent number: 5190997Abstract: An adhesive composition is prepared containing an aqueous copolymer emulsion which contains a first polymer network which is intertwined on a molecular scale with a second polymer network.Type: GrantFiled: February 2, 1989Date of Patent: March 2, 1993Assignee: Sequa Chemicals, Inc.Inventors: Martin K. Lindemann, Kim Deacon
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Patent number: 5183837Abstract: Process for binding cellulosic materials with a binding agent composed of aqueous emulsion of polyisocyanates and a cellulose ether. The cellulose wither is present in amounts of 0.1-10% b.w.Type: GrantFiled: January 16, 1992Date of Patent: February 2, 1993Assignee: Presidenza del Consiglio dei Ministri - Ufficio del Ministro per il coordinamento delle Iniziativae per la Ricerca Scientifica e TecnologicaInventors: Agostino Lepori, Domenico Camaioni
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Patent number: 5177141Abstract: The present invention is directed to coating compositions (pastes) containinga) about 20 to 90% of an aqueous polyurethane dispersion which has a solids content of about 20 to 60% and wherein the polyurethane is rendered hydrophilic by carboxylate groups, sulphonate groups, pendant polyether chains having oxyethylene units, terminal polyether chains having oxyethylene units or mixtures thereof,b) about 0.1 to 5% by weight of a water-soluble, polymeric thickening agent for aqueous polyurethane dispersions which is not a polyurethane and which is free from carboxyl groups,c) about 3 to 80% by weight of water-immiscible organic solvent which is not a solvent for polyurethanes dispersed in water and which has a boiling point up to 250 C.,d) about 0.1 to 5% by weight of a cross-linking agent for the polyurethane dispersed in water which does not contain free isocyanate groups ande) about 0.Type: GrantFiled: October 16, 1989Date of Patent: January 5, 1993Assignee: Bayer AktiengesellschaftInventors: Wilhelm Thoma, Rolf Langel, Walter Schroer
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Patent number: 5177128Abstract: A paper coating composition is prepared containing a polymer emulsion which comprises a first polymer network which is intertwined on a molecular scale with a second polymer network.Type: GrantFiled: February 6, 1989Date of Patent: January 5, 1993Assignee: Sequa Chemicals, Inc.Inventors: Martin K. Lindemann, Kim Deacon
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Patent number: 5173521Abstract: An absorbent fibrous structure comprising salts of fibrous carboxymethyl cellulose. In this structure, polyelectrolyte complexes are formed in at least a part of the salts of fibrous carboxymethyl cellulose by cationic water-soluble polymers. Each cationic water-soluble polymer comprises repeating units having at least one of primary, secondary, tertiary and quaternary nitrogen atoms and does not substantially have functional groups for forming cross-linking other than the nitrogen atoms. According to a preferred embodiment, polyamine resin was added to a suspension of Na-salts of fibrous CMC to prepare a stock, and from this stock, an absorbent fibrous sheet is produced by a paper-making method. Then, this sheet had a high water absorbency and had high wet tensile strength even after absorbing water. Further, slime was not generated at all and the sheet-surface was neutral.Type: GrantFiled: June 14, 1991Date of Patent: December 22, 1992Assignee: Mishima Paper Co., Ltd.Inventor: Yoshiaki Ishino
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Patent number: 5169884Abstract: A coating composition is prepared containing a polymer emulsion which comprises a first polymer network which is intertwined on a molecular scale with a second polymer network.Type: GrantFiled: February 6, 1989Date of Patent: December 8, 1992Assignee: Sequa Chemicals, Inc.Inventors: Martin K. Lindemann, Kim Deacon
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Patent number: 5104914Abstract: It is the object of this invention to provide a method for the preparation of an antiblocking agent which is effective in its antiblocking activity but is considerable less visible in photographic enlargements made from the film containing the antiblock of this invention.There is described a process for the preparation of monodispersed polymer particles between 5 and 10 microns in diameter which comprises preparing a dispersion of monosized seed polymer particles and then adding to this dispersion an ethylenically unsaturated monomer which is different from the monomer used to prepare the seed polymer particles, together with a polymerization initiator and completing the polymerization, the refractive index of one of the polymers produced being greater than 1.54 and the refractive index of the other polymer being less than 1.54.The refractive index of gelatin is 1.54. There is produced by the process of the present invention a particle which comprises two polymers.Type: GrantFiled: May 10, 1990Date of Patent: April 14, 1992Assignee: Ilford LimitedInventors: Peter J. Elton, John L. Cawse
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Patent number: 5093387Abstract: A denture adhesive base composition comprises a substantially anhydrous mixture of a cationic derivatives of guar gum, a mixed Na/Ca salt of methyl vinyl ether-maleic anhydride and sodium carboxymethylcellulose. A denture adhesive composition including this base composition is provided, as well as a method for formulating the novel adhesives of the invention. Upon hydration, the denture adhesives of the invention form denture adhesive compositions exhibiting improved denture holding and adhesive duration properties.Type: GrantFiled: December 21, 1989Date of Patent: March 3, 1992Assignee: Warner-Lambert CompanyInventors: Alexander M. Schobel, Lori D. Kumar
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Patent number: 5091448Abstract: A new stable liquid suspension of water soluble polymer, and a method of preparation are provided. Such compositions comprise of at least an iso-parrafinic oil medium, one styrene/isoprene copolymer, a water soluble polymer and preferably some hydrophobic fumed silica mixed together in the appropriate quantities and conditions.Type: GrantFiled: April 24, 1990Date of Patent: February 25, 1992Assignee: Phillips Petroleum CompanyInventors: John E. Hostettler, Marshall D. Bishop
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Patent number: 5077336Abstract: The present invention relates to a first low-temperature insulating material which comprises polyvinyl chloride, a plasticizer, a water-containing or absorbing gel or an aqueous solution of a water-soluble polymer and an emulsifier and a second low-temperature insulating material which comprises polyvinyl chloride gelled by mixing with a plasticizer and a surface-covered, water-containing hydrogel. The insulating materials are inexpensive and show excellent heat-insulating properties and excellent flexibility at low temperatures.Type: GrantFiled: November 16, 1988Date of Patent: December 31, 1991Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Takefumi Nakashita, Atsuko Mitsuba, Daijiro Touji, Ichiro Tominaga, Teruo Sasaki, Yukiyasu Nakashio, Tsuneyuki Nagase
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Patent number: 5070121Abstract: The invention concerns a solvent-free, polymerizing hotmelt substance free of, or low in monomers, for corrosion- and/or abrasion proofing and/or forming a protective film with barrier properties on a real substrates and molded bodies made of metal, plastic, cellulose materials and/or inorganic materials, in particular for wrapping purposes, and consisting of(a) one or more polymerizing polymers containing hydroxyls with an average molecular weight (M.sub.w) between 1,000 and 500,000 and with a glass transition temperature (T.sub.g).gtoreq.20.degree. C., and/or(b) one or more polymerizing, linear, unbranched and/or unbranched polyesters and/or their copolymers with an average molecular weight (M.sub.w) between 900 and 50,000 and with a glass transition temperature (T.sub.g).gtoreq.-50.degree. C.Type: GrantFiled: April 25, 1989Date of Patent: December 3, 1991Assignee: Schmalbach Lubeca AGInventors: Rudolf Hinterwaldner, Georg Bolte
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Patent number: 5011868Abstract: A denture adhesive base composition comprises a substantially anhydrous mixture of a cationic acrylamide polymer, sodium carboxymethylcellulose and ethylene oxide polymer. A denture adhesive composition including this base composition is provided. A method for formulating the novel denture adhesive base compositions and denture adhesive compositions of the invention is also disclosed.Type: GrantFiled: December 1, 1989Date of Patent: April 30, 1991Assignee: Warner-Lambert CompanyInventor: James J. Keegan
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Patent number: 5011875Abstract: A corrosion resistant, water expandable composition comprising:(A) 100 parts by weight of at least one material selected from the group consisting of rubbers, thermoplastic resins and mixtures thereof;(B) 10-200 parts by weight of a water-absorbable material; and(C) 5-30 parts by weight of a corrosion inhibitor is disclosed.Type: GrantFiled: March 26, 1990Date of Patent: April 30, 1991Assignees: Hiroshima Kasei Ltd., Mitsubishi Jidosha Kogyo Kabushiki KaishaInventors: Yuji Yamamoto, Hideyuki Shigematsu, Hiroshi Tanaka, Ryo Ashikawa, Tatsuo Ishida
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Patent number: 5006571Abstract: A denture adhesive base composition comprising a substantially anhydrous mixture of a mixed Na/Ca salt of methyl vinyl ether-maleic acid, sodium carboxymethylcellulose, and a trivalent cation. A denture adhesive composition including this base composition is provided, as well as a method for formulating the novel adhesives of the invention.Type: GrantFiled: December 21, 1989Date of Patent: April 9, 1991Assignee: Warner-Lambert CompanyInventors: Lori D. Kumar, Alexander M. Schobel
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Patent number: 4990551Abstract: Absorbing polymer consisting of a polymer A which is an optionally modified polyvinyl alcohol or an optionally modified polysaccharide or a mixture of these, and of a polymer B which is a maleic anhydride homo- or copolymer having a hydrolysis time of 5 to 120 minutes, the anhydride groups being open and 0.005 to 5 mol % of the acid functions being esterified with hydroxyl groups of polymer A, and the remaining acid functions being present as free acid groups, as salts or as acid amide groups, an absorbing product containing this polymer and a process for their preparation.Type: GrantFiled: October 13, 1989Date of Patent: February 5, 1991Assignee: Chemie Linz Gesellschaft m.b.H.Inventors: Georg Haubl, Willibald Scheuchenstuhl
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Patent number: 4980391Abstract: The present invention pertains to denture adhesive compositions comprising a substantially anhydrous mixture, in percentages by weight, of an adhesive component comprised of a mixture of (a) from about 29 to about 34% of a mixed, partial calcium/sodium salt of a methyl vinyl ether-maleic anhydride-type copolymer, and (b) from about 22 to about 26% sodium carboxymethylcellulose; a vehicle component comprises of a mixture of (c) from about 20 to about 26% petrolatum and from about 15 to about 24% mineral oil; and a hydration and tackifier component comprised of (d) from about 0.5 to about 2% silicon dioxide and (e) from about 1 to about 3% poly(ethylene oxide) homopolymer. The present invention also pertains to methods by which these denture adhesive compositions may be prepared.Type: GrantFiled: October 27, 1988Date of Patent: December 25, 1990Assignee: Warner-Lambert CompanyInventors: Lori D. Kumar, Alexander M. Schobel
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Patent number: 4957559Abstract: Insulating materials consisting of artifical mineral fibers are impregnated with water insoluble additives, e.g. dust binders and/or water repellant finishing agents in that they are wetted with an emulsion of the water insoluble additive in an aqueous solution of a cellulose ether. Impregnation takes place easily and is effective and resistant.Type: GrantFiled: May 14, 1987Date of Patent: September 18, 1990Assignee: Isover Saint-GobainInventors: Hartmut Tiesler, Joseph Schirmeisen
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Patent number: 4952618Abstract: Hydrocolloid adhesive compositions are disclosed comprising a rubbery elastomeric base having dispersed therein hydrocolloid particles, at least some of which are polycationic hydrocolloid particles. The compositions have enhanced resistance to breakdown by body fluids and are especially useful as wound dressings.Type: GrantFiled: May 3, 1988Date of Patent: August 28, 1990Assignee: Minnesota Mining and Manufacturing CompanyInventor: Roger A. Olsen
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Patent number: 4942192Abstract: A rubber composition for use in tire, particularly bead filler comprises 2.about.30 parts by weight of a particular modified novolak resin having a self-curability based on 100 parts by weight of rubber ingredient.Type: GrantFiled: August 26, 1988Date of Patent: July 17, 1990Assignees: Bridgestone Corporation, Ltd. UnitikaInventors: Takuo Yasuda, Hitoshi Kondo, Yoshiaki Echigo, Tsuneyuki Ohsawa, Yoshiaki Maekawa
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Patent number: 4931100Abstract: A process for producing boron-containing ceramics such as boron carbide and boron nitride comprises pyrolyzing a blend of a precarbonaceous polymer such as polyacrylonitrile and a boron-containing polymer such as that formed by the reaction of a borane with a Lewis base. Pyrolyzation in an inert atmosphere yields boron carbide while pyrolyzation in a reactive gas burns away the precarbonaceous polymer and yields a ceramic comprising the reaction product of boron and the pyrolyzation gas. Boron nitride ceramics are formed by pyrolyzing the preceramic blend in ammonia.Type: GrantFiled: January 5, 1989Date of Patent: June 5, 1990Assignee: Hoechst Celanese Corp.Inventor: Robert E. Johnson