Solid Polymer Utilized Is Derived From An Unsaturated Carboxylic Acid Or Salt Patents (Class 524/460)
  • Patent number: 7026369
    Abstract: To provide an aqueous emulsion composition which has high adhesion strength for a wide variety of materials including molded products and affords sufficient wettability even for the object to be adhesive bonded of low surface polarity so that it can develop sufficient adhesiveness and whose emulsion is stable so satisfactorily as to provide good mechanical stability and storage stability, and to provide an adherent composition comprising the aqueous emulsion composition, at least ethylene-vinyl acetate copolymer or modified resin thereof, photo polymerization initiator, and unsaturated ethylenic monomer are mixed and dissolved or dispersed, to prepare oil drop component, followed by emulsifying the oil drop component in water by using a surface-active agent, whereby an aqueous emulsion composition, in which micelles each encapsulating at least the ethylene-vinyl acetate copolymer or modified resin thereof, the photo polymerization initiator and unsaturated ethylenic monomer are dispersed in water, is prepared
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: April 11, 2006
    Assignee: Mitsui Takeda Chemicals, Inc.
    Inventors: Kenji Kuroda, Susumu Okatani, Hiroyuki Shiraki
  • Patent number: 7008312
    Abstract: The present invention relates to the use of an aqueous polymer dispersion comprising dispersed particles of at least one polymer A1 having a glass transition temperature, Tg, of from ?20° C. to +35° C. and obtainable through free-radical emulsion polymerization in the presence of a polymer A2 synthesized from from 50 to 99.5% by weight of at least one ethylenically unsaturated monocarboxylic and/or dicarboxylic acid whose carboxylic groups can form an anhydride group, or mixtures thereof, from 0.5 to 50% by weight of at least one ethylenically unsaturated compound selected from the esters of ethylenically unsaturated monocarboxylic acids and the monoesters and diesters of ethylenically unsaturated dicarboxylic acids with an amine containing at least one hydroxyl group, and up to 20% by weight of at least one further monomer as binder for producing abrasive material.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: March 7, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Laubender, Matthias Gerst, Bernd Reck, Manfred Weber
  • Patent number: 7001528
    Abstract: The use of an aqueous polymer dispersion comprising dispersed particles of at least one polymer A1 obtainable by free-radical emulsion polymerization in the presence of a polymer A2 synthesized from from 50 to 99.5% by weight of at least one ethylenically unsaturated monocarboxylic and/or dicarboxylic acid, from 0.5 to 50% by weight of at least one ethylenically unsaturated compound selected from the esters of ethylenically unsaturated monocarboxylic acids and the monoesters and diesters of ethylenically unsaturated dicarboxylic acids with an amine containing at least one hydroxyl group, up to 20% by weight of at least one further monomer as a binder for producing filter materials.
    Type: Grant
    Filed: February 10, 2004
    Date of Patent: February 21, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Laubender, Matthias Gerst
  • Patent number: 6987153
    Abstract: The invention relates to a latex that may be utilized as a binder for nonwoven applications to form a permeable sublayer of personal hygiene articles. The latex is prepared by a process including the steps of (1) polymerizing a monomer mixture comprising styrene, itaconic acid, surfactant and water soluble free radical initiator to form a seed; (2) sequentially adding equal increments of a monomer mixture of styrene, butadiene and acrylic acid to the seed under emulsion polymerization conditions to form a styrene-butadiene-acrylic acid copolymer; and then (3) neutralizing the styrene-butadiene-acrylic acid copolymer to a pH of about 4.5 to 7 to form the latex.
    Type: Grant
    Filed: May 26, 2004
    Date of Patent: January 17, 2006
    Assignee: Omrova Solutions Inc.
    Inventors: David F. Diehl, Carla B. Dittman McBain
  • Patent number: 6953822
    Abstract: Aqueous (meth)acrylate copolymer dispersions preparable by (I) subjecting at least one monomer (a) containing at least one hydrophilic functional group which brings about the water-solubility or water-dispersibility of the (meth)acrylate copolymer to (co)polymerization in aqueous/organic solution using at least one oil-soluble initiator which provides free radicals, (II) where appropriate, fully or partly neutralizing the resulting (co)polymer I, (III) dispersing the resultant solution of the (co)polymer I, (partly) neutralized where appropriate, in water, and (IV) copolymerizing and/or graft-copolymerizing at least one monomer (b) in the presence of the resultant dispersion III using oil-soluble initiators which provide free radicals, the monomer or monomers (b) containing at least one hydrophilic functional group which brings about no substantial water-solubility or water-dispersibility of the (meth)acrylate copolymer, or at least one hydrophobic group, and being selected in nature and amount such that th
    Type: Grant
    Filed: March 1, 2001
    Date of Patent: October 11, 2005
    Assignee: BASF Coatings AG
    Inventors: Wilma Löcken, Heinz-Peter Rink, Ursula Heimeier
  • Patent number: 6855761
    Abstract: Monodisperse particles having a particle diameter in the range of about from 1 to 1,000 ?m; a process for easily producing the particles; a column for liquid chromatography which is packed with the particles; and a method of liquid chromatography which comprises using the column. The monodisperse particles are obtained by adding an aqueous emulsion containing a polymerizable monomer to monodisperse polymer seed particles comprising a poly((meth)acrylic ester) containing at least one kind of groups selected from the group consisting of straight-chain alkyl groups having 6 or more carbon atoms, alicyclic alkyl groups having 6 or more carbon atoms, phenyl groups, benzyl groups and halogenated alkyl groups having 3 or more carbon atoms to thereby swell the seed particles and then polymerizing the polymerizable monomer.
    Type: Grant
    Filed: April 21, 2000
    Date of Patent: February 15, 2005
    Assignee: Tosoh Corporation
    Inventors: Kazuaki Muranaka, Teruhiko Tsuda
  • Patent number: 6852423
    Abstract: In paper coating slips containing, as a binder, a copolymer which is obtainable by free radical polymerization of ethylenically unsaturated compounds, at least one of the ethylenically unsaturated compounds is a polymer having at least one copolymerizable ethylenically unsaturated group, a number average molecular weight of from 500 to 50000 g/mol and at least one carboxyl group (referred to below as ethylenically unsaturated polymer for short).
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: February 8, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Schädler, David Christie, Roland Ettl
  • Patent number: 6849681
    Abstract: This invention relates to novel carboxylic acid-modified vinylic polymeric compositions and the process for preparing them. In particular, the invention relates to novel carboxylic acid-modified vinylic polymeric compositions which exhibit properties that make them useful as support resins for producing polymer latices which can be employed in the formulation of various water-based coatings and inks, particularly flexographic inks. More particularly, these carboxylic acid-modified vinylic polymeric compositions are produced by the addition polymerization reaction of vinylic monomers in the presence of dimer acids, trimer acids, dimerized rosins, or mixtures thereof.
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: February 1, 2005
    Assignee: MeadWestVaco Corporation
    Inventors: G. Frederick Hutter, Alexander John Conte
  • Patent number: 6841622
    Abstract: Acrylic polymer fine particles which comprise primary particles P of 250 nm or more in average particle diameter having a core shell structure and plastisols prepared using the same. In the fine particles, a core polymer C and a shell polymer S are copolymers of the following monomer mixtures Mc and Ms, respectively, and the weight ratio of Mc and Ms is 10/90-90/10: Mc: methyl methacrylate 20-85 mol % (meth)acrylic ester of C2-C8 aliphatic alcohol and/or aromatic alcohol 15-80 mol % other copolymerizable monomers not more than 30 mol %; , when the total amount of these monomers is 100 mol %; Ms: methyl methacrylate 20-79.5 mol % (meth)acrylic ester of C2-C8 aliphatic alcohol and/or aromatic alcohol 5-40 mol % a monomer containing carboxyl group or sulfonic acid group 0.5-10 mol % other copolymerizable monomers not more than 30 mol %.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: January 11, 2005
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventor: Toshihiro Kasai
  • Patent number: 6806315
    Abstract: A method for preparing a weatherable thermoplastic resin, having superior weatherability and colorability and a weatherable thermoplastic resin prepared by the method are provided. The method includes preparing a seed by adding a water-soluble initiator to either an aromatic vinyl compound or a (meth)acrylic acid alkyl ester to obtain a first compound and performing polymerization with respect to the first compound; preparing an alkyl acrylate rubber polymer by adding an alkyl acrylate monomer, a first emulsifier of pH about 3 to about 9, and an oil-soluble initiator to the seed to obtain a second compound and performing polymerization with respect to the second compound; and preparing graft copolymer by adding the aromatic vinyl compound, a vinyl cyanide compound, a second emulsifier of pH about 9 to about 13, and the oil-soluble initiator to the alkyl acrylate rubber polymer to obtain a third compound and performing graft copolymerization with respect to the third compound.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: October 19, 2004
    Assignee: LG Chem, Ltd.
    Inventors: Yang-Hyun Shin, Keun-Hoon Yoo, Tae-Bin Ahn, Chan-Hong Lee
  • Patent number: 6803400
    Abstract: Water-swellable hot-melt adhesives based on a tackifying resin, a water-dispersible EVA wax, an ethylene/acrylic ester copolymer, a water-soluble homo- or co-polymer and a super absorber polymer powder having an average particle size of less than 80 &mgr;m display a clearly improved swelling behavior in comparison with the prior art. Furthermore, the swelling agent is significantly more homogeneously distributed in the matrix. Such hot-melt adhesives are suitable for ensuring longitudinal water impermeability in modern cable structures, as water-swellable jointing compounds in the building industry in the area of building conservation and restoration. Such hot-melt adhesives are further suitable for the manufacture of absorbent textile fabrics in the personal hygiene sector.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: October 12, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ruediger Butterbach, Ulricke Maassen, Siegfried Kopannia
  • Patent number: 6794055
    Abstract: Stains comprising a polymer, an initiator, a colorant and a solvent are disclosed. The polymer comprises an alkyd portion and a free radical curable portion that is pendant from the alkyd portion; the alkyd portion includes one or more fatty acid moieties that can be derived from one or more drying, semi-drying or nondrying oils. When drying or semi-drying oils are used, the molecules of the present invention exhibit a dual cure, both oxidative and free radical. The compositions are particularly suitable for staining substrates comprising wood. Methods for using the present compositions are also disclosed.
    Type: Grant
    Filed: February 3, 2003
    Date of Patent: September 21, 2004
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Roy E. Dean, Truman F. Wilt, Shawn A. DeSaw, M. Lisa Perrine, Michael J. Ziegler
  • Patent number: 6790272
    Abstract: The invention relates to aqueous pigment preparations containing i) at least one copolymer P of ethylenically unsaturated monomers M in the form of an aqueous polymer dispersion which contains between 0.1 and 1.5 weight %, in relation to the total weight of the copolymer P, of polymerized itaconic acid as acid monomer M1, its salts and/or anhydride, where up to 50 weight % of the itaconic acid can be substituted by another monomer having at least one acid group or a neutralized acid group, and whose glass transition temperature TG lies between −10 and +50° C.; ii) at least one inorganic pigment; iii) possibly inorganic fillers; and iv) standard additives. The invention also relates to the use of the copolymers P containing itaconic acid for improving the wet-abrasion resistance of polymer-bound coatings containing pigments.
    Type: Grant
    Filed: September 15, 2000
    Date of Patent: September 14, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Cheng-Le Zhao, Joachim Roser, Rolf Dersch, Roland Baumstark
  • Patent number: 6790899
    Abstract: A combination of a potassium salt of a perfluoroalkane sulfonate and a sodium salt of toluene sulfonic acid, preferably in the presence of an antidrip agent to provide high melt strength, act synergistically to provide flame-retarded polycarbonate compositions at low levels. Thus, a flame-retarded polycarbonate resin can be made by adding to the polycarbonate resin an effective flame-retardant amount of a potassium salt of a perfluoroalkane sulfonate and a sodium salt of toluene sulfonic acid. The two salts may be formulated in advance into an additive composition.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: September 14, 2004
    Assignee: General Electric Company
    Inventors: Rajendra K. Singh, Ye-Gang Lin
  • Patent number: 6784262
    Abstract: Processes for chemically-modifying the surface of an emulsion polymer particle are provided which include providing an aqueous emulsion polymer, a monomer at a level of at least 0.5% by weight based on the weight of the emulsion polymer and a, surface-modifying chemical capable of bonding with the monomer, under conditions where there is no substantial polymerization of the monomer, and then reducing the level of the monomer by at least 50%.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: August 31, 2004
    Assignee: Rohm and Haas Company
    Inventor: Robert Mitchell Blankenship
  • Publication number: 20040167269
    Abstract: An aqueous polymerization method for preparing graft copolymers is disclosed. Copolymer compositions produced therefrom are also disclosed. The method of the present invention includes (a) forming a macromonomer aqueous emulsion containing water insoluble macromonomer particles; (b) forming a monomer composition containing at least one ethylenically unsaturated monomer; and (c) combining at least a portion of the macromonomer aqueous emulsion and at least a portion of the monomer composition and polymerizing the resulting polymerization reaction mixture in the presence of an initiator to form a copolymer composition. The copolymer composition produced contains water insoluble particles of graft copolymer.
    Type: Application
    Filed: January 23, 2004
    Publication date: August 26, 2004
    Inventors: Willie Lau, Karl Allen Bromm, Paul Ralph Van Rheenen
  • Patent number: 6780918
    Abstract: Process for the preparation of protective colloid-stabilized aqueous dispersions.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: August 24, 2004
    Assignee: PolymerLatex GmbH & Co.KG.
    Inventor: Davide Brizzolara
  • Patent number: 6780923
    Abstract: A molding compound contains a reinforcing fiber, a non-fibrous filler, and an unsaturated polyester resin. The unsaturated polyester resin contains an unsaturated monomer as well as a polyester polymer. The polymer is a unsaturated polyester made from a hydroxyl component and a carboxylic component. The hydroxyl component contains both a monomeric diol or triol, and a polymeric polyol. The polymeric polyol is a hydroxyl-terminated polymer such as polyether or polyester diols or triols. The carboxylic component can be provided by an unsaturated carboxylic diacid, an unsaturated carboxylic anhydride, an unsaturated carboxylic diester or mixtures thereof. Molded articles are provided by compression or extrusion molding of a molding compound as described above. The articles are characterized by improved crack resistance, toughness, and surface appearance.
    Type: Grant
    Filed: November 8, 2001
    Date of Patent: August 24, 2004
    Assignee: ThyssenKrupp Budd Company
    Inventors: Probir K. Guha, Michael J. Siwajek, Robert C. Yen
  • Patent number: 6777483
    Abstract: A method of preparing a diene rubber latex having large size particles, good stability and reduced coagulum during polymerization wherein the method comprises: (a) pretreating a seed diene rubber latex with an anionic emulsifier and a non-ionic emulsifier, (b) adjusting the pH of an unsaturated carboxylic acid-containing copolymer latex to about 5 to 11 and adjusting the solids content of the copolymer latex to about 1 to 10% by weight solids content to produce an agglomerating latex solution, and (c) adding the pretreated seed diene rubber latex of step (a) to the agglomerating latex solution of step (b). Step (c) must be carried out by adding the pretreated seed diene rubber latex to the agglomerating latex. If the agglomerating latex is added to the rubber latex, an undesirable level of coagulum is produced.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: August 17, 2004
    Assignee: Cheil Industries Inc.
    Inventors: Byeong-Do Lee, Ki-bo Chang, Kwang-Yeol Lim, Dong-Won Jun
  • Publication number: 20040138369
    Abstract: The present invention discloses a rubbery polymer having improved properties, which is comprised of repeat units which are comprised of (a) butyl acrylate, or optionally a mixture of butyl acrylate and 2-ethylhexyl acrylate containing up to about 40 percent 2-ethylhexyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) optionally, about 0% to about 40% of an alkoxy ethyl acrylate or an alkoxy ethyl methacrylate, (d) acrylonitrile, (e) styrene, and (f) a crosslinking agent; wherein about 1% to about 10% of a monomer containing reactive cure sites selected from the group consisting of hydroxyl groups, glycidyl groups, carboxylic acid groups, and unsaturated cure sites is incorporated into the rubbery polymer.
    Type: Application
    Filed: December 18, 2003
    Publication date: July 15, 2004
    Inventor: Hung Dang Ngoc
  • Patent number: 6762238
    Abstract: A coating composition which contains a polymeric complex between polyaniline and a polymeric ion. In addition to the said polymeric complex, the composition contains a water-dispersable binder. The composition is useful as a water-borne paint to be applied onto a metal substrate electrophoretically or non-electrophoretically.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: July 13, 2004
    Assignee: The Board of Governors for Higher Education, State of Rhode Island and Providence Plantations
    Inventors: Sze Cheng Yang, Richard Brown
  • Patent number: 6730729
    Abstract: The invention relates to a process for preparing an aqueous polymer dispersion comprising an emulsion polymer a polymer composed of at least 5% by weight of an ethylenically unsaturated monocarboxylic acid, dicarboxylic acid or dicarboxylic anhydride (acid polymer SP for short), and an alkoxysilane of the formula SiR1R2R3R4 in which the groups R1 to R4 independently of one another are each an organic radical with the proviso that at least one of the groups is an alkoxy group, which comprises preparing said emulsion polymer by emulsion polymerization in the presence of at least some of the alkoxysilane.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: May 4, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Gerst, Matthias Laubender, Bernd Reck
  • Publication number: 20040082709
    Abstract: The present invention relates to a dispersion of polymer particles, the particle containing, on average, more than 1 living radicals each, the radicals not being chemically protected. The invention is also directed to a free radical polymerization process resulting in a dispersion containing polymer particles having on average one or more living radicals. The process involves carefully regulating the polymerization conditions to produce small size particles under monomer-starved conditions containing, on average, more than one living radical in every particle. These living polymer radicals can be further reacted to form polymers with a controlled architecture.
    Type: Application
    Filed: August 1, 2003
    Publication date: April 29, 2004
    Inventors: Yadunandan Dar, Smita Shah
  • Patent number: 6723775
    Abstract: The present invention provides an aqueous polymerization method for preparing graft copolymers, and copolymer compositions produced therefrom. The method of the present invention includes (a) forming a macromonomer aqueous emulsion containing water insoluble macromonomer particles; (b) forming a monomer composition containing at least one ethylenically unsaturated monomer; and (c) combining at least a portion of the macromonomer aqueous emulsion and at least a portion of the monomer composition and polymerizing the resulting polymerization reaction mixture in the presence of an initiator to form a copolymer composition. The copolymer composition produced contains water insoluble particles of graft copolymer.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: April 20, 2004
    Assignee: Rohm and Haas Company
    Inventors: Willie Lau, Karl Allen Bromm, Paul Ralph Van Rheenen
  • Patent number: 6723114
    Abstract: The present invention is directed to bioabsorbable adhesive/hemostatic formulations of a 2-alkoxyalkylcyanoacrylate and liquid or solid polymeric modifiers and adjuvant. The present adhesive formulations are useful as tissue adhesive/sealants, hemostatic agents, and as a means for patching or anastomic coupling of damaged organs.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: April 20, 2004
    Assignee: Poly-Med, Inc.
    Inventor: Shalaby W. Shalaby
  • Patent number: 6709551
    Abstract: This invention is directed to high molecular weight water-soluble polymers comprised of zwitterionic, nonionic and cationic or anionic monomer units, and to the use of these polymers in papermaking processes.
    Type: Grant
    Filed: December 17, 2001
    Date of Patent: March 23, 2004
    Assignee: Ondeo Nalco Company
    Inventors: Martin J. Coffey, Steven T. Govoni, Arthur J. Begala, Ross T. Gray, Patrick G. Murray
  • Patent number: 6706356
    Abstract: Emulsion polymers useful in the preparation of coatings and adhesives, including PSA tapes, labels, and other constructions, are provided. The polymers are characterized by high solids content and low viscosity. A method of making the polymers is also provided. A plurality of acrylic monomers are copolymerized in the presence of a plurality of surfactants, using a split feed, and the resulting emulsion polymers have a bimodal or higher particle-size distribution.
    Type: Grant
    Filed: October 4, 2002
    Date of Patent: March 16, 2004
    Assignee: Avery Dennison Corporation
    Inventor: Ivan Lee
  • Publication number: 20040034147
    Abstract: An object of the present invention is to provide a hollow polymer particle having well-balanced properties such as gloss and coating strength, a process for producing the particle, a paper coating composition using the particle, and a coated paper.
    Type: Application
    Filed: August 13, 2002
    Publication date: February 19, 2004
    Applicant: JSR CORPORATION
    Inventor: Yoshiaki Zama
  • Patent number: 6689200
    Abstract: Aqueous water repellent coating compositions comprising admixtures of (i) water-based water repellent compositions and (ii) water-reducible film-forming polymers are disclosed.
    Type: Grant
    Filed: July 25, 2002
    Date of Patent: February 10, 2004
    Assignee: The Sherwin-Williams Company
    Inventors: Victoria D. Scarborough, Timothy G. Teague, Cedric M. Wilson, Heath G. Saunders
  • Patent number: 6656999
    Abstract: The present invention provides a method of preparing a synthetic rubber latex having a large particle size, showing good stability and reducing coagulum during polymerization, which comprises (a) pretreating a seed synthetic rubber latex by mixing the seed synthetic rubber latex with deionized water and a small amount of an emulsifier and stirring, (b) preparing an agglomerating latex with a pH value of about 5.0˜8.0 by mixing a copolymer latex containing unsaturated acid having from about 10 to about 50% by weight of solid content with deionized water and a pH controlling agent, and (c) adding the pretreated seed synthetic rubber latex of step (a) to the agglomerating latex of step (b). The step (c) may be carried out by adding the pretreated seed synthetic rubber latex dropwisely to the agglomerating latex containing unsaturated acid for about 30 minutes to about 1 hour.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: December 2, 2003
    Assignee: Cheil Industries Inc.
    Inventors: Byeong-Do Lee, Sang-Dong Park, Young-Sun Jun, Kwang-Yeol Lim, Sang-Kyu Park
  • Publication number: 20030212183
    Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion comprising: preparing a dispersant co-polymer of a monomer mixture (M) by polymerising the monomer mixture (M) in a reaction medium which is substantially free from organic solvents and/or substantially free from monomers which are not soluble in water, the monomer mixture (M) comprises at least one cationic vinyl monomer (m3) and at least one monomer (m4) which is tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, or a monomer of the general formula (I): 1
    Type: Application
    Filed: May 7, 2003
    Publication date: November 13, 2003
    Applicant: AKZO NOBEL N.V.
    Inventors: Oliver Struck, Christian Przybyla, Achim Sieger, Mathias Hahn, Dirk Ruppelt, Werner Jaeger
  • Patent number: 6639049
    Abstract: The invention relates to a process for the preparation of polymers stabilized with protective colloids in the form of water-redispersible powders or aqueous dispersions thereof having a reduced content of volatile components, by a) polymerizing by emulsion or suspension polymerization, one or more monomers from the group consisting of vinyl esters, (meth)acrylates, vinyl aromatics, olefins, 1,3-dienes and vinyl halides and optionally further monomers copolymerizable therewith, b) aftertreating the polymer dispersion thus obtained by means of postpolymerization, distillation, and/or introduction of steam or inert gas to obtain a residual content of volatile, nonaqueous components of <2000 ppm, and c) spray drying of aftertreated polymer dispersion to a residual content of volatile, nonaqueous components of <400 ppm, the dispersion being adjusted prior to spray drying to a solids content of <45% by weight before spraying, the spray drying performed with gas at an inlet temperature of >120° C.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: October 28, 2003
    Assignee: Wacker Polymer Systems & Co. KG
    Inventor: Hans-Peter Weitzel
  • Publication number: 20030166763
    Abstract: A hard capsule which is made mainly of a polymer or copolymer obtained by polymerizing or copolymerizing at least one polymerizable vinyl monomer in the presence of polyvinyl alcohol and/or a derivative thereof. Unlike conventional hard capsules, this hard capsule can be filled with a solvent (e.g., polyethylene glycol) for a sparingly soluble drug ingredient.
    Type: Application
    Filed: February 19, 2003
    Publication date: September 4, 2003
    Inventors: Noboru Hoshi, Toshio Shimamoto, Shigeru Sugiyama
  • Patent number: 6607788
    Abstract: The invention embraces basecoating compositions comprising as binder constituents (i) an acrylate dispersion having a content of from 30 to 60% by weight of C1-C8-alkyl (meth)acrylate-containing monomers, from 30 to 60% by weight of vinylaromatic monomers and from 0.5 to 10% by weight of (meth)acrylic acid in the polymer, and (ii) a dispersion of a polymer which is obtainable by subjecting an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monomers to free-radical polymerization in the presence of a water-insoluble initiator or of a mixture of water-insoluble initiators and in an aqueous dispersion of a polyurethane resin which has a number-average molecular weight Mn of from 1000 to 30,000 daltons and comprises on average from 0.05 to 1.
    Type: Grant
    Filed: April 18, 2000
    Date of Patent: August 19, 2003
    Assignee: BASF Coatings AG
    Inventors: Egon Wegner, Gudrun Wiemann, Ekkehard Sapper, Harald Angermüller
  • Patent number: 6590022
    Abstract: A method is provided for producing protective colloid-stabilized vinyl aromatic-1.3-diene-copolymers in the form of their aqueous polymer dispersions or in the form of a powder which can be re-dispersed in water, by emulsion-polymerizing a mixture containing at least one vinyl aromatic and at least one 1,3-diene in the presence of a protective colloid and optionally, drying the resulting polymer dispersions. In the method part of the protective colloid is provided straightaway and part is metered.
    Type: Grant
    Filed: May 21, 2000
    Date of Patent: July 8, 2003
    Assignee: Wacker-Chemie GmbH
    Inventors: Thomas Bastelberger, Reinhard Haerzschel, Theo Mayer, Peter Weitzel, Peter Ball
  • Patent number: 6590051
    Abstract: This invention is directed to high molecular weight water-soluble zwitterionic polymers derived from zwitterionic and nonionic monomer units, and to the use of the polymers in papermaking processes.
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: July 8, 2003
    Assignee: Ondeo Nalco Company
    Inventors: Phillip W. Carter, Patrick G. Murray, Larry E. Brammer, Jr., Andrew J. Dunham
  • Patent number: 6569939
    Abstract: The invention provides a polymer composition for flexibilizing building materials, in the form of their aqueous dispersion or of powder redispersible in water, containing a) at least one water-insoluble, film-forming polymer of one or more ethylenically unsaturated monomers capable of free radical polymerization, b) at least one compound from the group consisting of the water-soluble polymers of one or more ethylenically unsaturated monomers capable of free radical polymerization, and the ionic and nonionic emulsifiers, and c) a mixture of at least two organosilicon compounds, at least one of which is an amino-functional organosilicon compound present in salt form.
    Type: Grant
    Filed: March 5, 2001
    Date of Patent: May 27, 2003
    Assignee: Wacker-Chemie GmbH
    Inventors: Herbert Eck, Klaus Adler, Hermann Lutz, Heinrich Hopf
  • Patent number: 6569949
    Abstract: Inherently tacky, pressure-sensitive adhesive compositions useful in marking film applications are provided. The compositions comprise polymer particles prepared by emulsion polymerization of at least one monomer mixture. The monomer mixture comprises at least one alkyl acrylate, the alkyl group of which has from about 4 to 12 carbon atoms, preferably in an amount of from about 73% to 90% by weight, at least one unsaturated carboxylic acid containing from about 3 to 5 carbon atoms, preferably in an amount of from about 2% to 12% by weight, and at least one hard monomer, preferably present in an amount of from about 5% to 15% by weight. The particles have a mean diameter of about 300 nm or less, as determined by laser light scattering. Preferably the hard monomer comprises a styrenic monomer, more preferably both a styrenic monomer and an alkyl methacrylate. In some embodiments, the compositions are prepared by sequential polymerization of the first and second monomer charges.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: May 27, 2003
    Assignee: Avery Dennison Corporation
    Inventors: Ivan S. P Lee, Graham Yeadon, Paul Keller
  • Publication number: 20030088015
    Abstract: Preparing pigment preparations by mixing a dyestuff with a monomer and simultaneously polymerizing the monomers in an extruder at elevated temperatures, wherein the following steps are carried out:
    Type: Application
    Filed: August 9, 2002
    Publication date: May 8, 2003
    Inventors: Johannes Leugs, Harald Marinus Alexander Heere, Adrianus Hendrikus Van Rooijen
  • Patent number: 6559236
    Abstract: Process for the preparation of aqueous dispersions of (co)polymerizates using a polymer with cationic functionality, optionally accompanied by the use of conventional additives, the polymer with cationic functionality being obtained by (co)polymerization in an aqueous medium of olefinically unsaturated (co)monomers, in which at least one (co)monomer has a cationic functionality, further (co)monomers are added and polymerization takes place in the presence of suitable initiators, wherein the polymers and/or (co)monomers are so chosen and the process is so controlled that a (co)polymerizate particle with heterogeneous morphology is formed and the dispersed (co)polymerizate obtained has a glass transition temperature Tg of more than about 50° C. The invention also relates to a process in which the polymer with cationic functionality is formed in situ in the presence of a seed. Redispersible powders and the use thereof are also described.
    Type: Grant
    Filed: May 11, 2001
    Date of Patent: May 6, 2003
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Hongli Willimann, Robert Koelliker
  • Patent number: 6559259
    Abstract: A water-soluble, crosslinkable protective colloid is provided having a molecular weight of least than 500,000 comprising: a) 20 to 959 by weight of monomer units containing sulphonic acid or sulphonate groups, b) 4 to 800 by weight of monomer units containing N-methylol or N-alkoxymethyl groups, and c) 0.1 to 20% by weight of hydrophobic monomer units such as water insoluble ethylenically unsaturated compounds and the hydrophobic end groups of initiator radicals or regulator molecules. Optionally, up to 50% by weight of the monomer units containing sulphonic acid or sulphonate groups can be replaced by monomer units containing carboxyl groups or monomer units containing amide groups.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: May 6, 2003
    Assignee: Wacker-Chemie GmbH
    Inventors: Klaus Kohlhammer, Gerhard Koegler, Monika Rockinger, Walter Dobler
  • Patent number: 6559217
    Abstract: The invention provides a process for the preparation of polymer particles having a mode particle size of at least 50 &mgr;m which process comprises (a) obtaining a first particulate polymer seed material having a mode particle diameter of no more than 50 &mgr;m; (b) using said first seed material, performing a suspension polymerization involving the steps: (i) forming an aqueous dispersion comprising a polymer seed material, an organic compound (e.g. a polymerization initiator) which has a molecular weight of less than 5000 Daltons and a water solubility of less than 10−2 g/L at 25° C., a stabilizer and optionally an organic solvent (e.g. acetone or a portion of the monomer mentioned below); (ii) allowing said organic compound to diffuse into the seed material to produce an activated seed material; and (iii) contacting said activated seed material with a monomer (e.g.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: May 6, 2003
    Assignee: Polymer Systems AS
    Inventors: Rolf Nordal, Svein Tøgersen, Preben Cato Mørk
  • Patent number: 6555225
    Abstract: An ion complex which comprises a water-insoluble polyion (P) and a water-soluble polyion (A); and is insoluble in water and soluble in an aqueous organic solvent. Such an ion complex becomes a coating material which can preferably be used for coating of various ionic substances (e.g., substance having biological activity such as an anticoagulant property or an antibacterial property).
    Type: Grant
    Filed: March 27, 2000
    Date of Patent: April 29, 2003
    Assignees: M&M Laboratory Co., Ltd., Terumo Kabushiki Kaisha
    Inventors: Hiroshi Yoshioka, Yuichi Mori, Sunao Kubota
  • Patent number: 6552116
    Abstract: A multi-stage emulsion polymer containing at least one first domain having a glass transition temperature Tg of from −10 to +40° C. and at least one second domain having a Tg of from +50 to 120° C., the weight ratio of the first domain to the second domain being within the range from 90:10 to 50:50. The first and/or the second domain containing from 0.1 to 10% by weight of a nitrogen-coutaining adhesion monomer and the first domain containing at least 10% by weight of vinyl aromatic compounds and/or the second domain containing at least 15% by weight of vinyl aromatic compounds and/or C4 to C12 alkylmethacrylates.
    Type: Grant
    Filed: November 2, 2000
    Date of Patent: April 22, 2003
    Assignee: BASF Aktiengesellchaft
    Inventors: Joachim Pakusch, Uwe Dittrich, Harald Röckel, Alan Smith, Erich Gulbins, Li Zhuo
  • Patent number: 6538057
    Abstract: Adhesives comprising: a) from 5.0 to 95.0% by weight of an adhesive dispersion having a viscosity in the range from 2000 to 10,000 mpPa·s, which comprises (a1) an aqueous polymer dispersion which is obtainable by free-radical polymerization of a mixture M which comprises at least one ethylenically unsaturated monomer A to give a polymer P in the presence of at least one protective colloid-based on a water-soluble prepolymer which comprises at least one water-soluble monomer B, and further additives if desired, (a2) if desired, a base selected from the group consisting of alkali metal.hydroxides, ammonia and volatile organic amines, (a3) if desired, a completely water-miscible organic solvent, and, further additives; (b) from 0 to 90.0% by weight of a polysaccharide and/or a protein and/or a protein degradation product; (c) from 0 to 95.0% by weight of at least one filler; (d) from 0 to 10.0% by weight of at least one emulsifier; (e) from 0 to 30.
    Type: Grant
    Filed: May 21, 1998
    Date of Patent: March 25, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerald Wildburg, Dieter Urban, Georg Langhauser, Karl-Heinz Schumacher, Oliver Hartz, Eckehardt Wistuba
  • Patent number: 6531535
    Abstract: The present invention relates to a hydroxy-functional copolymer P, which is present as a dispersion and/or solution in water, and is obtained by successively carrying out process steps A-D: A) initially introducing a hydrophobic polymer containing hydroxyl groups into a reaction vessel, B) introducing an initiator component into that vessel, C) subsequently polymerizing a hydrophobic monomer mixture containing hydroxyl groups in that vessel and D) subsequently polymerizing a hydrophilic monomer mixture containing hydroxyl and acid groups in that vessel. The present invention also relates to a process for the preparation of copolymers P following the procedure previously set forth and to coating compositions containing these copolymers P and one or more crosslinking agents.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: March 11, 2003
    Assignee: Bayer Aktigensellschaft
    Inventors: Martin Melchiors, Rolf Bachmann, Wieland Hovestadt, Karl-Ludwig Noble, Harald Blum
  • Publication number: 20030027915
    Abstract: The invention relates to a process for preparing an aqueous polymer dispersion comprising
    Type: Application
    Filed: April 18, 2002
    Publication date: February 6, 2003
    Applicant: BASF Aktiengesellschaft
    Inventors: Matthias Gerst, Matthias Laubender, Bernd Reck
  • Patent number: 6515079
    Abstract: In a process for preparing thermoplastic molding compositions by a) polymerizing, in aqueous emulsion, dienes, C1-C12-alkyl acrylates or mixtures of these, where from 0 to 30% by weight of these monomers may have been replaced by other copolymerizable monomers, and where from 0 to 10 by weight of these monomers may have been replaced by crosslinking monomers, to give a rubber latex with a glass transition temperature below −10° C.
    Type: Grant
    Filed: December 12, 2000
    Date of Patent: February 4, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Graham Edmund McKee, Falko Ramsteiner, Peter Barghoorn, Michael Breulmann, Norbert Niessner
  • Publication number: 20020193548
    Abstract: An aqueous semi-continuous emulsion polymerization process for producing bimodal polymer particles in volumes large than a single batch size is provided. A bimodal polymer composition prepared by the process of carrying out an aqueous semi-continuous emulsion polymerization is also provided.
    Type: Application
    Filed: June 10, 2002
    Publication date: December 19, 2002
    Inventors: Thomas George Throne, Owen Clifford Hallerud
  • Patent number: 6475632
    Abstract: The present invention provides copolymer-based compositions which are used to produce point for roof tiles, in order to prevent algal vegetation, crack formation, increased water absorption, as well as chipping off of the paint, more particularly on concrete roof tiles.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: November 5, 2002
    Assignee: Clariant GmbH
    Inventors: Stephan Krieger, Klaus Zimmerschied, Erhard Lupprich