At Least Two Solid Hydrocarbons Patents (Class 524/477)
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Patent number: 10266731Abstract: A hot melt adhesive formulation includes 60 to 99 wt. % of an amorphous propylene-co-hexene-1 polymer component based on the total weight of the hot melt adhesive without the use of flammable solvents, 20 to 80 wt % of hexene-1 co-monomer based on the total weight of the amorphous propylene-co-hexene-1 copolymer component, 20 to 80 wt. % of a propylene co-monomer based on the total weight of the amorphous propylene-co-hexene-1 copolymer component, and from 1 to 40 wt. % of a co-adjuvant based on the total weight of the hot melt adhesive. The hot melt adhesive formulation has rolling ball tack from 2 to 50 centimeters at ambient temperature after conditioning at ambient temperatures for 24 hours. The hexene-1 monomer to propylene monomer ratios are from 4:1 to 1:4.Type: GrantFiled: August 24, 2018Date of Patent: April 23, 2019Inventors: Andres Sustic, Nick Fowler, John Passmore
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Patent number: 9765192Abstract: The present disclosure provides hydrosilylation curable compositions comprising resin linear organosiloxane block copolymers comprising, among other things, from about 0.5 to about 5 mole % C1 to C30 hydrocarbyl group comprising at least one aliphatic unsaturated bond. Such hydrosilylation curable resin-linear organosiloxane block copolymers have significantly faster cure speed, relative to their condensation curable counterparts. A faster cure speed can be important for encapsulating electronic devices, such as light-emitting diode (LED) chip devices, particularly devices having tall structures.Type: GrantFiled: September 18, 2014Date of Patent: September 19, 2017Assignee: Dow Corning CorporationInventors: John Bernard Horstman, Steven Swier, Yanhu Wei
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Patent number: 9315657Abstract: Disclosed are a propylene resin composition (A) composed of 0.5 to 10% by weight of a specific propylene homopolymer (a1), 40 to 98% by weight of a specific propylene polymer (a2), 1 to 25% by weight of a specific propylene-ethylene random copolymer (a3), and 0.5 to 25% by weight of a specific propylene-ethylene random copolymer (a4), where the total amount of (a1), (a2), (a3) and (a4) is taken as 100% by weight, and an olefin resin composition comprising 100 parts by weight of the propylene resin composition (A), 5 to 75 parts by weight of an ethylene-?-olefin copolymer (B), and 1 to 75 parts by weight of an inorganic filler (C). The propylene resin composition can afford a molded article excellent in scratch resistance and rigidity.Type: GrantFiled: July 8, 2014Date of Patent: April 19, 2016Assignee: Sumitomo Chemical Company, LimitedInventor: Hiroyoshi Nakajima
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Patent number: 9029456Abstract: The invention relates to a method for making cemented carbide or cermet parts, comprises mixing a binder system with cemented carbide powder or cermet powder to form a feedstock, and injection molding or extruding the feedstock to form the cemented carbide or cermet parts, wherein the binder system comprises 30-60 wt % olefinic polymers, 40-70 wt % waxes, and 2.5-10 wt % petroleum jelly CAS 8009-03-8, the feedstock has a solids loading of ?=0.54-0.56.Type: GrantFiled: February 16, 2010Date of Patent: May 12, 2015Assignee: SECO TOOLS ABInventors: Per Jonsson, Mattias Puide
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Patent number: 9029455Abstract: Soft polyolefin composition with improved processability comprising from 8 to 45% by weight of a polypropylene component (A), from 82 to 45% by weight of an elastomeric component (B), and from 10 to 25% by weight of a viscosity reducing agent (C) comprising polybutene-1 and paraffinic wax or grease. The composition is easily processable also by injection molding and has better tensile properties than compositions in which processability is improved by visbreaking.Type: GrantFiled: July 29, 2008Date of Patent: May 12, 2015Assignee: Basell Poliolefine Italia S.r.l.Inventors: Paolo Goberti, Johan De Clippeleir, Giampaolo Pellegatti, Friederike Morhard, Stefano Spataro
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Patent number: 8957147Abstract: Organosiloxane block copolymers, curable compositions, and solid compositions derived from these block copolymers are disclosed. The organosiloxane block copolymers comprise: 40 to 90 mole percent disiloxy units of the formula [R12—SiO2/2] 10 to 60 mole percent trisiloxy units of the formula [R2SiO3/2] 0.5 to 35 mole percent silanol groups [?SiOH] where R1 is independently a C1 to C30 hydrocarbyl, R2 is independently a C1 to C20 hydrocarbyl, wherein; the disiloxy units [R12SiO2/2] are arranged in linear blocks having an average of from 10 to 400 disiloxy units [R12SiO2/2] per linear block, the trisiloxy units [R2SiO3/2] are arranged in non-linear blocks having a molecular weight of at least 500 g/mol, and at least 30% of the non-linear blocks are crosslinked with each other, each linear block is linked to at least one non-linear block, and the organosiloxane block copolymer has a molecular weight (Mw) of at least 20,000 g/mole.Type: GrantFiled: September 21, 2011Date of Patent: February 17, 2015Assignee: Dow Corning CorporationInventors: Steven Swier, John Bernard Horstman
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Patent number: 8772812Abstract: A curable organopolysiloxane composition can be used as a sealant or a bonding agent for optical semiconductor elements. The composition comprises at least the following components: (A) a multi-constituent, alkenyl-containing organopolysiloxane; (B) an organopolysiloxane that contains silicon-bonded hydrogen atoms and comprises constituent (B-1) containing at least 0.5 wt. % of silicon-bonded hydrogen atoms and constituent (B-2) containing at least 0.5 wt. % of silicon-bonded hydrogen atoms, and, if necessary, constituent (B-3), an organopolysiloxane; and (C) a hydrosilylation-reaction catalyst. The composition can form a cured body that possesses long-lasting properties of light transmittance and bondability, and relatively high hardness.Type: GrantFiled: June 28, 2011Date of Patent: July 8, 2014Assignee: Dow Corning Toray Co., Ltd.Inventors: Makoto Yoshitake, Mieko Yamakawa
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Patent number: 8546477Abstract: The process for producing the coating composition according to the instant invention comprises the steps of: (1) providing an ethylene based copolymer composition; (2) providing a propylene polymer composition; (3) providing a chlorinated olefin polymer composition; (4) optionally providing a filler; (5) optionally providing an adhesion promoting agent; and (6) melt blending said ethylene based copolymer composition, said propylene polymer composition, said chlorinated olefin polymer composition, said optional filler and said optional adhesion promoting agent. The articles according to the instant invention comprise optionally a substrate; and a coating. The method for making the inventive articles comprises the steps of (1) providing a substrate; (2) providing a coating composition; and (3) coating said coating composition into onto at least one surface of said substrate.Type: GrantFiled: February 21, 2013Date of Patent: October 1, 2013Assignee: Dow Global Technologies LLCInventor: Daniel G. Moldovan
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Patent number: 8431642Abstract: Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 wt. % polypropylene and at least one wax. The polymer compositions have a Dot T-Peel of about 1 Newton or more, a branching index (g?) of 0.95 or less measured at the Mz of the polymer, a molecular weight of 100,000 or less, and the adhesive compositions has a fast set time. The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time.Type: GrantFiled: May 26, 2009Date of Patent: April 30, 2013Assignee: Exxonmobil Chemical Patents Inc.Inventors: Jean M. Tancrede, Christopher L. Curry, David R. Johnsrud, George Rodriguez, Fran A. Shipley
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Patent number: 8431643Abstract: The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and/or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time. Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 mol % polypropylene, at least one wax and at least one wax modifier.Type: GrantFiled: April 16, 2010Date of Patent: April 30, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: George Rodriguez, Fran A. Shipley, Peijun Jiang, Charles L. Sims, Kenneth Lewtas
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Patent number: 8404773Abstract: The instant invention is a coating composition, method of producing the same, articles made therefrom, and method of making such articles. The coating composition according to the instant invention comprises (a) 10 to 55 percent by weight of an ethylene based copolymer composition; (b) 5 to 25 percent by weight of a propylene polymer composition; (c) 15 to 60 percent by weight of a chlorinated olefin polymer composition; (d) optionally less than 40 percent by weight of a filler; and (e) optionally 1 to 20 weight percent by weight of an adhesion promoting agent.Type: GrantFiled: March 17, 2008Date of Patent: March 26, 2013Assignee: Dow Global Technologies LLCInventor: Daniel G. Moldovan
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Patent number: 8283400Abstract: An adhesive and method for hot melt adhesive application. The adhesive comprises polyolefin base polymer and from 1 to 15 wt % of a at least two wax components, based on the total weight of the polyolefin base polymer and the at least two wax components, wherein the at least two wax components comprise a first wax component having a relatively low weight average molecular weight at least 1000 g/mole less than a second wax component having a relatively high weight average molecular weight. The adhesive may have at least 50% fiber tear at 25° C., and a characteristic set time of less than 3 seconds. The adhesive may also include from 1 to 10 wt % of at least one functionalized polyolefin.Type: GrantFiled: December 9, 2009Date of Patent: October 9, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: George Rodriguez, Fran A. Shipley, Peijun Jiang
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Patent number: 8242198Abstract: An adhesive and method for hot melt application. The adhesive comprises polyolefin base polymer, from 1 to 10 wt % of at least one functionalized polyolefin, and from 1 to 15 wt % of a wax, based on the total weight of the polyolefin base polymer, functionalized polyolefin and wax, wherein the wax has a weight average molecular weight at least 8% of the weight average molecular weight of the polyolefin base polymer, viscosity at 190° C. of 60 mPa·s or more, and a crystallization temperature greater than the polyolefin base polymer and greater than 100° C., and wherein the adhesive has at least 5% fiber tear at 2° C., at least 50% fiber tear at 25° C., and a characteristic set time of less than 3 seconds.Type: GrantFiled: November 11, 2009Date of Patent: August 14, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Peijun Jiang, George Rodriguez, Fran A. Shipley, Aspy K. Mehta
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Publication number: 20120136107Abstract: The present invention disclosed a rubber-plastic alloy for a warm mix asphalt mixture and a method for manufacturing the same. The warm mix rubber-plastic alloy is consisted of 5%-30% plastic, 70%-95% crumb rubber, and cracked wax and rubber oil, the summed amount of which comprises 10%-50% of the summed amount of the plastic and the crumb rubber. The manufacturing method comprises extruding the plastic, the crumb rubber, the cracked wax, and the rubber oil at suitable ratio via a single screw extruder, and pelleting via a water-cooled die-face cutter. The use comprises mixing the rubber-plastic alloy with a hot mineral material in an asphalt mixture mixer, and then liquid asphalt matrix is pumped into the mixer via an asphalt pump to provide a warm mix rubber-plastic modified asphalt mixture having excellent performance.Type: ApplicationFiled: August 22, 2011Publication date: May 31, 2012Inventors: Yi Fu, Huaiyu Zheng, Songbin Tan
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Patent number: 8076422Abstract: A hot-melt adhesive for resealable packaging, containing 30 to 90 wt. % of at least one copolymer based on ethylene and/or propylene together with C4 to C12-?-olefins, which is obtainable by metallocene-catalyzed polymerization, with a melt index of 5 to 100 g/10 min (DIN ISO 1133), 5 to 50 wt. % of tackifier resins with a softening point of 80 to 140° C., 0 to 15 wt. % of waxes with a melting point of 120 to 170° C., 0.1 to 20 wt. % of additives and auxiliaries, the adhesive having a viscosity of 25,000 mPa·s to 250,000 mPa·s, measured at a temperature of 170 to 190° C.Type: GrantFiled: June 11, 2010Date of Patent: December 13, 2011Assignee: Henkel AG & Co. KGaAInventors: Marcus Heemann, Eckhard Pürkner, Volker Erb, Maja Schroeder, Dirk Vianden
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Patent number: 7999022Abstract: Polymer slurries of ultrahigh molecular weight polyalpha-olefins are made stable toward settling, separation and agglomeration by surface treatment with a combination of wax and optional relatively high-density particulates. The selection of the surface coating acts not only as an anti-blocking agent, or partitioning aid to keep the tacky polymer particles separated, but also provides the suspended polymer particle with a density that matches the carrier. This prevents separation of the slurry components over time. Such materials, ultimately used as pipeline additives to reduce the fluid drag and increase the volumetric throughput, can be stored and shipped for extended periods of time without degradation of the slurry quality. Upon injection into the pipeline, the polymer particle dissolves quickly, unhindered by the coating.Type: GrantFiled: December 2, 2010Date of Patent: August 16, 2011Assignee: Baker Hughes IncorporatedInventors: Thomas J. Martin, Lu Chien Chou
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Patent number: 7863362Abstract: Polymer slurries of ultrahigh molecular weight polyalpha-olefins are made stable toward settling, separation and agglomeration by surface treatment with a combination of wax and optional relatively high-density particulates. The selection of the surface coating acts not only as an anti-blocking agent, or partitioning aid to keep the tacky polymer particles separated, but also provides the suspended polymer particle with a density that matches the carrier. This prevents separation of the slurry components over time. Such materials, ultimately used as pipeline additives to reduce the fluid drag and increase the volumetric throughput, can be stored and shipped for extended periods of time without degradation of the slurry quality. Upon injection into the pipeline, the polymer particle dissolves quickly, unhindered by the coating.Type: GrantFiled: September 14, 2004Date of Patent: January 4, 2011Assignee: Baker Hughes IncorporatedInventors: Thomas J. Martin, Lu Chien Chou
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Patent number: 7833578Abstract: A composition and a method for fabricating microcapsules encapsulating phase-change material by interfacial condensation polymerization are provided. In this composition and method, a surfactant and an organic solvent are not needed.Type: GrantFiled: March 12, 2008Date of Patent: November 16, 2010Assignee: Taiwan Textile Research InstituteInventors: Yen-Hsi Lin, Chi-Shu Wei
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Patent number: 7765855Abstract: Adhesive compositions and a method for selecting adhesive compositions are disclosed herein. Preferred adhesives generally have small domains and/or a homogeneous domain distribution. The method of selecting adhesives is based on size and distribution of the domains.Type: GrantFiled: November 7, 2006Date of Patent: August 3, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kenneth Lewtas, Antonie Jan Bons, Johan Stuyver
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Publication number: 20100132886Abstract: An adhesive and method for hot melt adhesive application. The adhesive comprises polyolefin base polymer and from 1 to 15 wt % of a at least two wax components, based on the total weight of the polyolefin base polymer and the at least two wax components, wherein the at least two wax components comprise a first wax component having a relatively low weight average molecular weight at least 1000 g/mole less than a second wax component having a relatively high weight average molecular weight. The adhesive may have at least 50% fiber tear at 25° C., and a characteristic set time of less than 3 seconds. The adhesive may also include from 1 to 10 wt % of at least one functionalized polyolefin.Type: ApplicationFiled: December 9, 2009Publication date: June 3, 2010Inventors: George Rodriguez, Fran A. Shipley, Peijun Jiang
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Patent number: 7709571Abstract: Lubricant compositions and processes for producing such lubricant compositions. More specifically, low viscosity lubricant compositions for the working surface of an extrusion die during the processing of plastics that require lubricants to render them processable, such as polyvinyl chloride, chlorinated polyvinyl chloride, polyvinylidene chloride and copolymers thereof. The lubricant composition may include up to about 70% by weight of at least one metal salt while maintaining a melt viscosity low enough to process on conventional finishing equipment such as prill towers or pastillating equipment.Type: GrantFiled: October 30, 2006Date of Patent: May 4, 2010Assignee: Honeywell International IncInventor: Francis Sim
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Patent number: 7563398Abstract: A process for manufacturing extrudable/melt spinnable concentrate pellets which contain phase change materials (PCMs), whether the PCMs are micro-encapsulated absorbed into carrier polymers, or non-micro-encapsulated within the concentrate pellets. The polymer matrix within the concentrate pellets can be any thermoplastic polymer or combination of thermoplastic polymers, and the concentrate pellets can then be blended into similar thermoplastic polymers to form mono-filament melt spun fibers, extruded films, injection molded products, etc., or the concentrate pellets can be blended with other thermoplastic polymers to form bi-component or multi-component melt spun fibers, extruded films, injection molded products, etc.Type: GrantFiled: July 13, 2004Date of Patent: July 21, 2009Assignee: Outlast Technologies, Inc.Inventors: Mark Henry Hartmann, Monte Christopher Magill
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Patent number: 7501471Abstract: A waterborne hydrophobic barrier coating formulation comprising a blend of a vinyl acetate-ethylene (VAE) polymer emulsion and a paraffin wax emulsion, wherein a dried coating of the blend on a substrate, such as a nonwoven web, an absorbent pad, or a textile, and dried, has a hydrostatic head barrier sufficient to prevent passage of fluids but allow passage of water vapor through it. A multi-layer material comprising at least one layer of a nonwoven web, an absorbent pad, or a textile, and at least one layer of a blend of a VAE polymer emulsion and paraffin wax emulsion.Type: GrantFiled: January 24, 2006Date of Patent: March 10, 2009Assignee: Wacker ChemicalCorporationInventor: John Richard Boylan
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Patent number: 7381766Abstract: A low-VOC (volatile organic compound) and/or low-toxicity coating formulation, including at least one non-halogenated organic solvent including any terpene or terpenoid, and at least one conducting polymer, electroactive polymer and/or conjugated polymer. In another embodiment, the present invention includes a low-VOC (volatile organic compound) and/or low-toxicity coating formulation, including about 0.001% wt. to about 99.9% wt. of at least one non-halogenated organic solvent including a terpene or terpenoid, about 0.01% wt. to about 90% wt. of at least one conducting polymer, and about 0.001% wt to about 90% wt. of at least one surfactant.Type: GrantFiled: September 6, 2006Date of Patent: June 3, 2008Assignee: The United States of America as represented by the Secretary of the NavyInventor: Nicole Marie Anderson
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Patent number: 7166664Abstract: A low-VOC (volatile organic compound) and/or low-toxicity coating formulation, including at least one non-halogenated solvent including terpene(s) or terpenoid(s), and at least one polymer including conducting polymers, electroactive polymers and/or conjugated polymers, wherein the polymers and non-halogenated solvent(s) are in non-aqueous form. In other embodiments, coating formulations, includes about 0.01% wt. to about 99.9% wt. of at least one non-halogenated solvent including a terpene or terpenoid, about 0.01% wt. to about 90% wt. of at least one polymer including conducting polymers, conjugated polymers, and electroactive polymers, and about 0.001% wt to about 90% wt. of at least one surfactant, wherein the polymers, solvents, and surfactants are in non-aqueous form.Type: GrantFiled: April 2, 2004Date of Patent: January 23, 2007Assignee: The United States of America as represented by the Secretary of the NavyInventor: Nicole Marie Anderson
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Patent number: 7049361Abstract: The polyolefin [A] has a weight average molecular chain length of 2850 nm or longer and a density ?1 (g/cm3), the polyolefin wax [B] has a weight average molecular weight of 700–6000 and a density ?2 (g/cm3), the polyolefin and the polyolefin wax are incorporated at [A]/[B]=90/10–50/50 (ratio by weight), and the densities ?1 and ?2 satisfy the following conditions: 0.92??1?0.94, 0.91??2?0.93, ?0.03?(?1??2)?0.03.Type: GrantFiled: March 11, 2002Date of Patent: May 23, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Atsuhiro Takata, Ryuma Kuroda, Satoshi Hanada, Takeshi Yamada
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Patent number: 6884843Abstract: A method of preparing a cured laminate employing electron beam radiation is provided. The cured laminate is prepared from an uncured laminate including a prepolymer composition containing oligomer, tackifying resin, and optionally, monomer. Also provided are a prepolymer composition and an article including the cured laminate prepared by the method of this invention. The method is useful for preparing cured laminates such as flexible laminates for food packaging.Type: GrantFiled: April 30, 2002Date of Patent: April 26, 2005Assignee: Rohm and Haas CompanyInventors: Thomas Frederick Kauffman, David William Whitman
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Patent number: 6841212Abstract: Disclosed is an adhesive composition suitable for bonding to a polymeric material and steel. The composition comprises specified proportions of a maleic anhydride-modified propylene-ethylene copolymer resin, a maleic anhydride-modified polyethylene, a polyisobutylene, a terpolymer comprising ethylene, propylene and a non-conjugated diene, and a hydrocarbon resin tackifier. The composition is useful in preparing a heat-recoverable article that is used to provide a protective coating on the joints of a steel pipeline. Also provided is a single sleeve or two-sleeve system for application to the joints of a coated steel pipeline operating at temperatures up to 120° C.Type: GrantFiled: April 17, 2002Date of Patent: January 11, 2005Inventors: Sirarpi Bicakci-Jenkins, Abboud L. Mamish
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Patent number: 6822030Abstract: Continuous coatings including floor finishes can be prepared using novel two part compositions and methods. The two part compositions comprise a solid particulate polymer part and a liquid coalescing agent part. A novel method of the invention involves contacting the coalescing agent with the polymer in a variety of coating methods including applying the polymer to the coalescing agent, applying the coalescing agent to the polymer or applying the coalescing agent and polymer simultaneously. The polymer and coalescing agent interact to form a continuous coating layer or finish layer.Type: GrantFiled: May 13, 2003Date of Patent: November 23, 2004Assignee: Ecolab Inc.Inventors: Keith E. Olson, Bryan M. Anderson, Robert D. P. Hei
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Patent number: 6809142Abstract: The invention relates to a pressure sensitive sealant composition for sealing a clearance between a lamp unit housing and a vehicle body panel of an automotive vehicle. The pressure sensitive sealant composition includes (a) 10-40 wt % of a component A that is at least one copolymer selected from the group consisting of hydrogenated styrene-butadiene copolymers, hydrogenated styrene-isoprene copolymers, and modified copolymers thereof; (b) a component B that is at least one tackifier selected from the group consisting of petroleum resins, terpene resins, rosin resins, coumarone-indene resins, hydrogenated resins thereof, and modified resins thereof, and (c) a component C that is a hydrocarbonic plasticizer. The pressure sensitive sealant composition is prepared by maxing together 100 parts by weight of the component A, 20-60 parts by weight of said component B, and 150-400 parts by weight of said component C.Type: GrantFiled: October 19, 1999Date of Patent: October 26, 2004Assignees: Nissan Motor Co., Ltd., Yokohama Rubber Co., Ltd.Inventors: Hidekazu Takeyama, Tomohiro Kawasaki, Masahiko Ohnishi, Minoru Matano, Akira Ozaki, Katsuyuki Arima
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Patent number: 6777476Abstract: A polypropylene resin composition for automobile interior materials, more particularly to a polypropylene resin composition including a crystalline polypropylene and rubber mixture wherein inorganic filler, atactic polypropylene and process oil are added to offer good flexibility, heat-resistance, cold-resistance, extrusion coating property and calender processing property and to remove offensive odor, which is specially useful for back coat of automobile mats.Type: GrantFiled: December 30, 2002Date of Patent: August 17, 2004Assignee: Hyundai Motor CompanyInventors: Kieyoun Jeong, Seung-Wook Lee, Seung-Wook Hwang
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Patent number: 6774069Abstract: Hot-melt adhesive compositions of atactic polypropylene and isotactic polypropylene are particularly suitable for bonding non-woven elastic composites. A selected amount of isotactic polypropylene is blended with a selected amount of atactic polypropylene to prepare an adhesive composition having one or more performance properties (e.g., bond strength) that are superior to the performance properties of conventional hot-melt adhesives.Type: GrantFiled: August 31, 2001Date of Patent: August 10, 2004Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Peiguang Zhou, Lance J. Garrett, Jr.
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Patent number: 6767957Abstract: An emulsion consists essentially of clear binders and possibly colored pigments, and contains at least one clear synthetic binder with a softening point or ball-ring temperature (TBA), measured according to the NFT 66-008 standard, that ranges between 30 and 100° C.Type: GrantFiled: August 27, 2001Date of Patent: July 27, 2004Assignee: Total Raffinage Distribution S.A.Inventors: Guy Lemoine, Jean-Philippe Gillet, Yannick Jolivet
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Patent number: 6761764Abstract: The invention provides for the use of mixtures of waxes which comprise a) a homopolymer or copolymer of C2-C18 &agr;-olefins, prepared by means of metallocene catalysis, and, as auxiliaries, one or more other waxes selected from the group consisting of b) PE waxes, c) PTFE waxes, d) PP waxes, e) amide waxes, f) FT paraffins, g) montan waxes, h) natural waxes, i) macrocrystalline and microcrystalline paraffins, j) polar polyolefin waxes, or k) sorbitan esters for improving the properties of coating materials.Type: GrantFiled: November 1, 2002Date of Patent: July 13, 2004Assignee: Clariant GmbHInventors: Ernst Krendlinger, Franz-Leo Heinrichs, Dieter Nowicki
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Publication number: 20030204003Abstract: Continuous coatings including floor finishes can be prepared using novel two part compositions and methods. The two part compositions comprise a solid particulate polymer part and a liquid coalescing agent part. A novel method of the invention involves contacting the coalescing agent with the polymer in a variety of coating methods including applying the polymer to the coalescing agent, applying the coalescing agent to the polymer or applying the coalescing agent and polymer simultaneously. The polymer and coalescing agent interact to form a continuous coating layer or finish layer.Type: ApplicationFiled: May 13, 2003Publication date: October 30, 2003Inventors: Keith E. Olson, Bryan M. Anderson, Robert D.P. Hei
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Patent number: 6586516Abstract: The present invention relates to an aqueous coating composition having low volatile organic compounds (VOC) and producing a coating having excellent durability and resistance properties. The coating composition contains acetoacetate functional polymer and divalent metal ions. Coating compositions of the present invention are particularly useful in ink, polish and coating compositions where a tough, resistant coating is required. The coating composition can be used on various substrates such as floors, walls wood, metal, plastic, stone, paper, leather and concrete.Type: GrantFiled: October 4, 1996Date of Patent: July 1, 2003Assignee: Rohm and Haas CompanyInventors: Mark Alan Kesselmayer, Theodore Tysak, Matthew Stewart Gebhard, Min-Chi Tsai von Trentini
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Patent number: 6258882Abstract: Polish formulations are provided which comprise: a) an aliphatic hydrocarbon solvent comprising 0-10% aromatic hydrocarbons; b) an acrylic resin; and c) a wax product that is thermoplastic, transparent, a solid at room temperature and has a melting/softening point of about 60° to about 90° C.; wherein wt:wt ratio of said acrylic resin and wax is about 1:3 to about 1:8 and the wt:wt ratio of said resin and wax to said solvent is about 1:1 to about 1:9. The formulations function as surface polishes that can be used on any hard surface including wood, metal, stone, and other non-porous surfaces.Type: GrantFiled: December 23, 1998Date of Patent: July 10, 2001Assignee: The Smithsonian InstitutionInventor: Melvin Joseph Wachowiak, Jr.
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Patent number: 6218457Abstract: A polybutylene based hot melt adhesive composition having a variety of end uses, particularly in construction and elastic attachment applications for nonwoven articles such as disposable diapers. Unlike typical hot melt adhesives, the present composition can withstand high peel and shear loads at elevated temperatures for extended periods of time without experiencing catastrophic bond failure. The composition includes polybutylene polymer or a mixture of polybutylene and polyolefin polymers, and a stabilizer, with the remaining ingredients chosen from one or more of a polyolefin polymer, a tackifier resin, a plasticizer, or a wax. The hot melt adhesive composition can be applied using common application techniques such as extruding or spraying.Type: GrantFiled: March 3, 1999Date of Patent: April 17, 2001Assignee: Ato Findley, Inc.Inventors: Margaret M. Fralich, Mark Alper
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Patent number: 6184278Abstract: The present invention relates to organic polymer compositions, containing liquid ester compositions as plastisizers, said compositions comprising mixtures of esters derived from (a) diethylene glycol and triethylene glycol and (b) benzoic or toluic acid, wherein the freezing point of the ester mixture is below the freezing points of the constituent esters when the relative concentrations of the constituent esters are within specified limits.Type: GrantFiled: December 7, 1998Date of Patent: February 6, 2001Assignee: Velsicol Chemical CorporationInventors: William David Arendt, Thomas Joseph Bohnert, Mark Stephen Holt
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Patent number: 6183873Abstract: Submicron boron nitride is used as a catalyst for thermally activating polysiloxane resins when uniformly mixed with the resin either using anhydrous acetone for wet mixing or simply hot melt mixing. Boron nitride is also used to coat the fibers using a particulate sizing approach. The coated fibers are used to activate the polymer resin blend. Fabric may be impregnated with the resin to mold high temperature composite laminates from which high temperature, non-metallic gaskets may be cut.Type: GrantFiled: November 3, 1997Date of Patent: February 6, 2001Assignee: The Gasket KingInventor: William A. Clarke
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Patent number: 6172146Abstract: A hot melt composition comprising a specific ratio of: (a) an ethylene copolymer resin; (b) a modified aromatic petroleum resin having a specific weight-average molecular weight and produced by copolymerization using a Friedel-Crafts catalyst from a specific ratio of: (1) a polymerizable component of the thermal cracked oil fraction having boiling points in a specific range and obtained by the thermal cracking of petroleum hydrocarbons, and containing vinyltoluene and indene at specific contents, (2) a turpentine oil having a specific diene value, and (3) a phenol compound; and (c) a wax. It is possible to develop a hot melt composition having excellent heat stability and improved adhesion resistance to heat, which can be used as hot melt coating, printing ink, adhesive, and sealant, etc.Type: GrantFiled: January 27, 1998Date of Patent: January 9, 2001Assignee: Nippon Petrochemicals, Co. Ltd.Inventor: Hitoshi Yanagishita
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Patent number: 6022910Abstract: A hot-melt solid ink composition comprises at least one polyamide and at least one terpene resin. The terpene resin is present in an amount of from 0.5% by weight to 15% by weight based on the total weight of the ink composition. This hot-melt solid ink composition can be stable to heat upon recording using ink-jet recording apparatus where ink is heated to melt at a temperature higher than ordinary temperature to make a record, and has a superior transparency and a superior adhesion to printing mediums.Type: GrantFiled: November 21, 1997Date of Patent: February 8, 2000Assignee: Brother Kogyo Kabushiki KaishaInventors: Masahiro Nishizaki, Naomichi Kobayashi
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Patent number: 5767184Abstract: This invention provides a heat-sealable, peelable composition comprising ethylene vinyl acetate copolymer, polyethylene based wax and polypropylene. The composition can further comprise a dye or an ink. The composition can be heat-sealed onto a surface of a polymeric bag to provide a peelable seal.A closure arrangement for a polymeric bag with first and second opposing films comprises first and second opposing base strips, a first peelable strip of a first color, and a second peelable strip of a second color. An outer surface of the first base strip is attached to an inner surface of the first film. An outer surface of the second base strip is attached to an inner surface of the second film. The first peelable strip is attached to the inner surface of the first base strip, and the second peelable strip is attached to the inner surface of the second base strip. The first and second peelable strips are disposed between the first and second base strips.Type: GrantFiled: December 16, 1996Date of Patent: June 16, 1998Assignee: Reynolds Consumer Products Inc.Inventor: Timothy J. May
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Patent number: 5733636Abstract: A closure arrangement for a polymeric bag with first and second opposing films comprises first and second opposing base strips, a first peelable strip of a first color, and a second peelable strip of a second color. An outer surface of the first base strip is attached to an inner surface of the first film. An outer surface of the second base strip is attached to an inner surface of the second film. The first peelable strip is attached to the inner surface of the first base strip, and the second peelable strip is attached to the inner surface of the second base strip. The first and second peelable strips are disposed between the first and second base strips. The second peelable strip is generally parallel to and opposes the first peelable strip. The second color of the second peelable strip is lighter than the first color of the first peelable strip.Type: GrantFiled: April 11, 1997Date of Patent: March 31, 1998Assignee: Reynolds Metals CompanyInventor: Timothy J. May
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Patent number: 5677375Abstract: A gas phase process for the production of an in situ polyethylene blend comprising contacting ethylene and at least one alpha-olefin comonomer having 3 to 8 carbon atoms with a magnesium/titanium based catalyst system including an activator and a cocatalyst in each of two fluidized bed reactors corrected in series, under polymerization conditions, with the provisos that:(a) the mixture of ethylene copolymer matrix and active catalyst formed in the first reactor in the series is transferred to the second reactor in the series;(b) other than the active catalyst referred to in proviso (a) and the cocatalyst referred to in proviso (f), no additional catalyst is introduced into the second reactor;(c) in the first reactor in which a relatively high molecular weight copolymer is made:(1) the alpha-olefin is present in a ratio of about 0.01 to about 0.4 mole of alpha-olefin per mole of ethylene; and(2) optionally, hydrogen is present in a ratio of about 0.001 to about 0.Type: GrantFiled: March 29, 1996Date of Patent: October 14, 1997Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Mahmoud R. Rifi, Carlo F. Martino
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Patent number: 5591792Abstract: The invention relates to an adhesive resin composition comprising an ethylene polymer having a melting point of 70 to 132.degree. C., a density of 0.88 to 0.94% g/cm.sup.3 and a melt flow rate (MFR) of 0.05 to 50 g/10 min. and/or a modified product thereof with an unsaturated carboxylic acid or its derivative (component A); a tackifier (component B); and a block copolymer containing at least one polymer block mainly composed of a vinyl aromatic hydrocarbon and at least one polymer block mainly composed of a conjugated diene or a hydrogenated product thereof (component C). This composition is useful as an adhesives showing excellent adhesion over a wide temperature range as well as processability by film molding, sheet molding, blow molding, etc. It is available for laminates comprising various kinds of resins such as polyolefins, styrenic resins, polyesters, acrylic resins and polyamides.Type: GrantFiled: January 10, 1995Date of Patent: January 7, 1997Assignee: Mitsubishi Chemical CorporationInventors: Masafumi Hattori, Chikako Ikeda, Satoru Sugimoto, Tatsuoki Saito, Hitoshi Yamada, Etsushi Akashige
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Patent number: 5548014Abstract: Disclosed are hot melt adhesives comprising tackifier and a high M.sub.w, narrow MWD, narrow CD ethylene/alpha-olefin copolymer(s) and a low M.sub.w, narrow MWD, narrow MWD ethylene/alpha-olefin copolymer prepared with either supported or unsupported cyclopentadienyl derivatives of Group IV and catalysts for applications in hot melt adhesives, particularly in automotive product assembly, packaging and food packaging. These ethylene copolymers have a M.sub.w ranging from about 20,000 to about 100,000, an MWD of less than 6 and 3 to 17 mole percent comonomer, and composition distribution breadth index above 70 percent. These ethylene copolymer blends have a M.sub.w ranging from about 20,000 to about 100,000 and an MWD of less than 6. In addition, the copolymer blends have comonomer mole percent ranging from about 3 to about 17.Type: GrantFiled: March 20, 1995Date of Patent: August 20, 1996Assignee: Exxon Chemical Patents Inc.Inventors: Mun F. Tse, Virginia R. Cross, Barry C. Trudell
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Patent number: 5530054Abstract: Disclosed are hot melt adhesives comprising ethylene/alpha-olefin copolymers prepared with either supported or unsupported metallocene-alumoxane catalysts for applications in hot melt adhesives used in automotive product assembly, packaging and food packaging. These ethylene copolymers have weight average molecular weight ranging from about 20,000 to about 100,000 and comonomer weight percent ranging from about 6 to about 30. The hot melt adhesive composition includes the ethylene copolymer and a compatible tackifier at a ratio of tackifier to copolymer of from 70:30 to 30:70 and may also include up to 30 weight percent of a paraffinic and microcrystalline wax of the copolymer and tackifier.Type: GrantFiled: March 24, 1995Date of Patent: June 25, 1996Assignee: Exxon Chemical Patents Inc.Inventors: Mun F. Tse, Aspy K. Mehta, Vince L. Hughes
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Patent number: 5468829Abstract: A method for preparing in situ reinforced silicone elastomers and the compositions prepared by the method. The method comprises forming a mixture comprising an end-functional diorganopolysiloxane; a stoichiometric excess of a hydrolyzable siloxane having hydrolyzable functionality described by formula--R.sup.2 SiQ.sub.3-b R.sub.b, were each R is independently selected from a group consisting of alkyls comprising one to six carbon atoms, alkenyls comprising two to six carbon atoms, and aryls, R.sup.2 is a divalent hydrocarbon radical comprising one to 12 carbon atoms, each Q is independently selected from a group consisting of hydroxy, acyloxys comprising one to six carbon atoms, alkoxys comprising one to six carbon atoms, and substituted alkoxys comprising one to six carbon atoms, and b=0 to 2; and a tin salt catalyst and contacting the mixture with water to effect curing. The resulting silicone elastomers are in situ reinforced to provide high strength.Type: GrantFiled: October 11, 1994Date of Patent: November 21, 1995Assignee: Dow Corning CorporationInventors: Debora F. Bergstrom, Gary T. Burns, Patricia A. Giwa-Agbomeirele
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Patent number: 5416153Abstract: Polyolefin molding composition of high rigidity and hardnessA polyolefin molding composition essentially comprisinga) a polyolefin wax andb) a high-molecular-weight polyolefin or, instead of b),c) a high-molecular-weight olefin copolymer has high rigidity and hardness.In order to increase the impact strength, this molding composition may additionally be admixed with a rubber having a glass transition temperature of below -20.degree. C.Type: GrantFiled: June 22, 1994Date of Patent: May 16, 1995Assignee: Hoechst AktiengesellschaftInventors: Andreas Winter, Bernd Bachmann