Mixing Inorganic Silicon-containing Material Having Color Or Numerical Limitations Other Than Amount, E.g., Included Herein Are M.p., Chemical Composition, Particle Size, Surface Area, Etc., Or Composition Or Product Thereof, Dnrm Patents (Class 524/492)
  • Patent number: 9267901
    Abstract: The present invention provides a method for estimating breaking energy of a rubber material, in particular breaking energy of a surface of a rubber material. The present invention also provides to a rubber composition excellent in crack resistance. The present invention relates to a method for estimating breaking energy of a rubber material, including determining a carbon-carbon double bond content in the rubber material.
    Type: Grant
    Filed: January 13, 2014
    Date of Patent: February 23, 2016
    Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.
    Inventors: Fusae Kaneko, Takanobu Kawamura
  • Patent number: 9181447
    Abstract: A metal protective coating is provided, which is obtained by mixing homogeneously a raw mixture, which contains water soluble silicate, promoter, silane coupling agent, silicon oxide packing, water soluble film formation resin, and water; wherein, the promoter is at least one selected from the group consisting of methyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, carboxymethyl-hydroxyethyl cellulose, and their soluble salts; the silane coupling agent contains a first silane derivative shown in formula (1), wherein, R1, R2, and R3 are methoxyl or ethyoxyl respectively, and n is an integer with the range of 1-4. A hot-dip Zn metallic material and a hot-dip Al—Zn alloy metallic material are further provided. The protective film formed by the metal protective coating as provided has outstanding corrosion resistance, water resistance, thermal resistance, and fingerprint resistance properties.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: November 10, 2015
    Assignee: PANGANG GROUP PANZHIHUA IRON & STEEL RESEARCH INSTITUTE CO., LTD.
    Inventors: Zhefeng Xu, Dongsheng Mei, Yong Chen, Quan Xu, Yan Lou, Yilin Zhou
  • Patent number: 9181413
    Abstract: The invention provides a rubber composition that can enhance fuel economy, wet-grip performance, abrasion resistance, and handling stability in a balanced manner, and a pneumatic tire using this composition.
    Type: Grant
    Filed: April 17, 2012
    Date of Patent: November 10, 2015
    Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.
    Inventors: Takafumi Taguchi, Kenichi Uesaka, Yoji Imoto, Satomi Yamauchi, Yoshihiro Kagawa
  • Patent number: 9132686
    Abstract: An inkjet printable article includes an ink receptive layer bonded to a paper substrate. The ink receiving layer includes particles, polymeric binder and colorant durability enhancer. From about 60% to about 95% by total dry weight of the ink receiving layer is particles selected from the group consisting of clay, kaolin, and combinations thereof. The polymeric binder is selected from the group consisting of polyvinyl alcohol, styrene butadiene, acrylonithle-butadiene latex, and combinations thereof. The colorant durability enhancer is selected from the group consisting of boric acid, borax, phenyl boronic acid, butyl boronic acid, sodium tetraborate, and combinations thereof.
    Type: Grant
    Filed: May 27, 2008
    Date of Patent: September 15, 2015
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Yongzhong Wang, Xiaoqi Zhou, Kelly Ronk, Hai Quang Tran
  • Patent number: 9126839
    Abstract: Method of manufacturing the silica nanopowders with fungicidal properties, consists in that the silica gel is obtained by sol-gel method from the reaction mixture containing tetraalkoxysilane and aliphatic alcohol, in the presence of ammonium compound, and thereafter the thermodegradable copper(II) salt a compound from the group of carbofunctional alkoxysilanes, and then, after evaporation of solvents the dry residue is heated at the decomposition temperature of copper(II) salt.
    Type: Grant
    Filed: May 5, 2011
    Date of Patent: September 8, 2015
    Assignee: INSTYTUT CHEMI PRZEMYSLOWEJ IM. PROF. IGNACEGO MOSCICKIEGO
    Inventors: Maria Zielecka, Elżbieta Bujnowska, Regina Jeziórska, Krystyna Cyruchin, Blanka Kepska, Magdalena Wenda
  • Patent number: 9125328
    Abstract: A method of manufacturing a multichip package structure includes: providing a substrate body; placing a plurality of light-emitting chips on the substrate body, where the light-emitting chips are electrically connected to the substrate body; surroundingly forming surrounding liquid colloid on the substrate body to surround the light-emitting chips; naturally drying an outer layer of the surrounding liquid colloid at a predetermined room temperature to form a semidrying surrounding light-reflecting frame, where the semidrying surrounding light-reflecting frame has a non-drying surrounding colloid body disposed on the substrate body and a dried surrounding colloid body totally covering the non-drying surrounding colloid body; and then forming a package colloid body on the substrate body to cover the light-emitting chips, where the semidrying surrounding light-reflecting frame contacts and surrounds the package colloid body.
    Type: Grant
    Filed: March 21, 2012
    Date of Patent: September 1, 2015
    Assignee: PARAGON SEMICONDUCTOR LIGHTING TECHNOLOGY CO., LTD.
    Inventors: Chia-Tin Chung, Chao-Chin Wu, Fang-Kuei Wu
  • Patent number: 9120890
    Abstract: Provided are a rubber composition achieving balanced improvement in processability, fuel economy, rubber strength, abrasion resistance, and wet-grip performance, and a pneumatic tire thereof. The rubber composition includes a conjugated diene polymer and a silica having N2SA of 40-400 m2/g, the polymer being obtained by polymerizing a monomer component including a conjugated diene compound and a silicon-containing vinyl compound in the presence of a polymerization initiator of formula (I): to produce a copolymer, and reacting a compound containing nitrogen and/or silicon atoms with an active terminal of the copolymer, wherein the amount of the diene polymer is 1-60% by mass and the amount of polyisoprene-based rubber is 0-99% by mass, each per 100% by mass of the rubber component; the amount of the silica is 10-80 parts by mass per 100 parts by mass of the rubber component; and the composition has a carbon ratio of at least 50.
    Type: Grant
    Filed: June 26, 2012
    Date of Patent: September 1, 2015
    Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.
    Inventors: Soh Ishino, Kazuya Torita
  • Patent number: 9109076
    Abstract: The present invention provides two methods for synthesizing novel titania-polyurethane (nTiO2-PU) nanocomposites for self-cleaning coatings, one a polymer functionalization method (“grafting to”) and the other, a monomer functionalization method (“grafting from”). Here, 2,2 bis(hydroxymethyl) propionic acid (HMPA) was used as the coordination agent, which was reacted with n-TiO2 (50:50 anatase/rutile) to form nTiO2-HMPA, then polymerized in the monomer functionalization method. In the polymer functionalization method, HMPA was reacted with a pre-polymer to form the PU, and then subsequently reacted with n-TiO2 to form the polymer nanocomposite. The photocatalytic cleanability of the nanocomposites was investigated when exposed to ultraviolet radiation using additional unreacted HMPA or stearic acid as the model “dirt” compounds. Nanocomposites prepared using both strategies showed similar self-cleaning behavior, although the monomer technique gave less substrate degradation.
    Type: Grant
    Filed: January 8, 2010
    Date of Patent: August 18, 2015
    Assignee: THE UNIVERSITY OF WESTERN ONTARIO
    Inventors: Paul A. Charpentier, Kevin D. Burgess
  • Patent number: 9080078
    Abstract: Provided are hyper nanocomposite, hyper nanocomposite coatings, devices, and articles including s hyper nanocomposite coatings. An article can include a surface including at least one region and a hyper nanocomposite coating disposed over the one region, wherein the hyper nanocomposite coating can include a plurality of nanoparticles substantially uniformly dispersed in one or more cross-linked hyperbranched polymers selected from the group consisting of polycarbosilane, polycarbosilixane, and polycarbosilazene, polyfluorocarbon.
    Type: Grant
    Filed: October 22, 2009
    Date of Patent: July 14, 2015
    Assignee: XEROX CORPORATION
    Inventors: David J. Gervasi, Santokh Badesha, Alan R. Kuntz
  • Patent number: 9045622
    Abstract: Disclosed are a modified conjugated diene-based polymer capable of providing a polymer composition improved in tan ? balance, a polymer composition containing the modified conjugated diene-based polymer and silica, and a process for producing the modified conjugated diene-based polymer. The modified conjugated diene-based polymer is obtained by melt-kneading a conjugated diene-based polymer and 0.01 to 2 parts by weight of a Bunte salt per 100 parts by weight of the conjugated diene-based polymer, in the presence of water whose amount is from 0.1 to 1,000 parts by weight per one part by weight of the Bunte salt.
    Type: Grant
    Filed: July 17, 2014
    Date of Patent: June 2, 2015
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventor: Hisakatsu Hama
  • Patent number: 9040164
    Abstract: Self-assembled silica condensates are described as well as their use in coating compositions. The self-assembled silica condensates can be formed from the hydrolysis of medium to long chain trialkoxy silane compounds. Coating compositions containing the self-assembled silica condensates can provide coatings having improved scratch and mar resistance and can have excellent recoat adhesion.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: May 26, 2015
    Assignee: AXALTA COATING SYSTEMS IP CO., LLC
    Inventor: Jun Lin
  • Patent number: 9034969
    Abstract: A rubber composition for the manufacture of tires, based on a blend of at least one diene elastomer chosen from natural rubber and synthetic polyisoprene and of one or more diene elastomers chosen from the group consisting of polybutadienes, butadiene copolymers and isoprene copolymers, on one or more reinforcing fillers and on a vulcanization system, the said vulcanization system comprising one or more thiazoline compounds of formula:
    Type: Grant
    Filed: October 8, 2010
    Date of Patent: May 19, 2015
    Assignees: Michelin Recherche et Technique S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Anne Veyland, Nicolas Seeboth, José Carlos Araujo Da Silva
  • Patent number: 9029436
    Abstract: An artificial silica marble comprises a matrix and a line pattern portion. The line pattern portion comprises fine lines having a width of about 50 to about 500 ?m and forms a web- or net-like pattern. The line pattern portion divides or partitions the artificial silica marble into a plurality of irregularly shaped pattern portions to form an amorphous pattern in the cross section of the artificial silica marble.
    Type: Grant
    Filed: October 31, 2013
    Date of Patent: May 12, 2015
    Assignee: Cheil Industries Inc.
    Inventors: Cheol Yeon Hwang, Chang Ho Son, Su Sun Jeong, Hee Cheol Lee, Han Ju Kang, Sung Jin An
  • Patent number: 9022087
    Abstract: A rubber composition for tire treads is obtained by blending, per 100 parts by mass of a diene rubber, 5 to 150 parts by mass of silica and 0.5 to 20 parts by mass of a silicone oligomer represented by the following siloxane average formula (1): (X)a(Y)b(R1)c(R2)dSiO(4-a-b-c-d)/2 (wherein X is a mercapto group-containing organic group; Y is a hydrolyzable group, R1 is a monovalent hydrocarbon group having from 4 to 10 carbon atoms, R2 is a monovalent hydrocarbon group having from 1 to 3 carbon atoms, 0<a<1, 0<b<3, 0<c<2, 0?d<2, and 0<a+b+c+d<4). The diene rubber contains an aromatic vinyl-conjugated diene copolymer in an amount of at least 50 parts by mass per 100 parts by mass of the diene rubber, the aromatic vinyl-conjugated diene copolymer having an aromatic vinyl content of 20 to 45 mass % and a vinyl bond content in the conjugated diene of 10 to 50%.
    Type: Grant
    Filed: August 6, 2012
    Date of Patent: May 5, 2015
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventor: Naoki Kushida
  • Patent number: 9023961
    Abstract: The present invention provides an acrylic resin composition containing a polycrystal of colloidal particles of silicon oxide in an acrylic resin that is formed by curing an acrylic monomer liquid at room temperature and/or an acrylic oligomer liquid at room temperature, wherein a mean distance between the colloidal particles in the polycrystal is 140 to 330 nm. The size of the single crystal that constitutes the polycrystal can be controlled by adjusting the content of silicon oxide and/or the additive amount of impurities. An architectural material, a fashion accessory, and an optical material are provided that are formed by using the acrylic resin composition.
    Type: Grant
    Filed: August 19, 2010
    Date of Patent: May 5, 2015
    Assignee: Fuji Chemical Company, Limited
    Inventors: Junpei Yamanaka, Akiko Toyotama, Fumio Uchida, Satoshi Kawanaka
  • Patent number: 9023938
    Abstract: Method for the production of an initial rubber composition, in the course of which the following steps are carried out in succession: A—a rubber matrix, reinforcing fillers, and other components if required, with the exception of the cross-linking system, are introduced into a mixing means of the internal mixer type, comprising a mixing chamber in which there are mounted rotors which are driven in rotation and have radial projections forming a gap (e) between themselves and the vessel, B—said components are mixed in the chamber until a uniform mixture is obtained, care being taken to ensure that the temperature of the mixture remains at or below 170° C., after which C—the rotation speed of the rotors is adjusted so as to bring the rubber composition to a dropping temperature in the range from 180° C. to 240° C.
    Type: Grant
    Filed: July 25, 2012
    Date of Patent: May 5, 2015
    Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique, S.A.
    Inventors: Jean-Marc Loubaresse, Marie Eloy, Floriandre Voisin, Gérald Huguenot, Julien Loyau
  • Patent number: 9012540
    Abstract: A rubber composition for a tire tread includes a modified diene rubber comprising a styrene butadiene rubber and/or a polybutadiene rubber, having a functional group such as an amino group or a hydroxyl group, silica, a silane coupling agent, a lignin derivative, and a carbon masterbatch. The carbon masterbatch comprises a styrene butadiene rubber, and carbon black having iodine adsorption of from 60 to 130 g/kg, and a ratio of the amount (B) of a rubber in the carbon masterbatch to the amount (A) of the modified diene rubber is B/A=0.25 to 1. The total amount of the carbon black and the silica is from 40 to 100 parts by mass per 100 parts by mass of a rubber component, the proportion of the silica in fillers is from 25 to 80% by mass, and the amount of the lignin derivative is from 0.1 to 10 parts by mass.
    Type: Grant
    Filed: May 17, 2012
    Date of Patent: April 21, 2015
    Assignee: Toyo Tire & Rubber Co., Ltd.
    Inventor: Shinsaku Kamada
  • Patent number: 9010393
    Abstract: Tyre and rubber composition for tyre, based on at least one isoprene elastomer (for example natural rubber), an inorganic filler as reinforcing filler (for example silica) and a coupling system which provides the bonding between the said reinforcing inorganic filler and the isoprene elastomer, the said coupling system comprising, in combination: as first coupling agent, a silane sulphide compound; as second coupling agent, an at least bifunctional organosilicon compound (for example an organosilane or an organosiloxane) which can be grafted to the elastomer by means of an azodicarbonyl functional group (—CO—N?N—CO—).
    Type: Grant
    Filed: May 11, 2006
    Date of Patent: April 21, 2015
    Assignee: Michelin Recherche et Technique, S.A.
    Inventors: Jose Carlos Araujo Da Silva, Nathalie Binde, Pierre Robert, Sebastien Sterin, Anne Veyland
  • Patent number: 9006316
    Abstract: The present invention is directed to novel organometallic complexes as catalysts for the reaction of compounds with isocyanate and hydroxyl functional groups to form urethane and/or polyurethane and the process employing such catalysts. More particularly, the present invention is directed to novel complexes of zinc(II) with substituted amidines. These novel catalysts are useful for the production of urethanes and polyurethanes which are important in many industrial applications.
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: April 14, 2015
    Assignee: King Industries, Inc.
    Inventors: Bing Hsieh, Ramanathan Ravichandran, Farouk Abi-Karam
  • Patent number: 9006325
    Abstract: The invention relates to a polymeric composition, comprising: at least one thermoplastic resin having a glass transition temperature of at least about 220° C.; inorganic particulates having an average particle size in the range up to about 100 nanometers dispersed in the thermoplastic resin, the inorganic particulates having an index of refraction in the range from about 1.4 to about 3; and an effective amount of at least one dispersant to disperse the inorganic particulates in the thermoplastic resin. The polymer composition may be a high temperature thermoplastic suitable for forming, such as by molding, optical articles such as lenses.
    Type: Grant
    Filed: October 11, 2007
    Date of Patent: April 14, 2015
    Assignee: Suncolor Corporation
    Inventor: David A. Smetana
  • Patent number: 9006308
    Abstract: The present invention describes a reinforcing filler for rubber comprising the synergistic combination of precipitated silica with a pore structure defined by a maximum between 25 nm and 35 nm, a total pore volume between 1.3 cm3/g and 1.6 cm3/g, and a compression factor between 1.3 10?2 and 2.3 10?2 MPa?1, and at least one crystalline alkaline silicate corresponding to the general formula of the crystalline alkaline silicates, said crystalline alkaline silicate being swelled and/or layered in the presence of an organic cationic compound in the form of ammonium salt of the +NR4 type according to the formula [CnH2n+1N(CH3)3]+. The rubber formulation obtained by this reinforcing filler composition does present a great reduction of energy dissipated in the tread without compromising the abrasion resistance and elastic modulus properties.
    Type: Grant
    Filed: December 5, 2011
    Date of Patent: April 14, 2015
    Assignee: Industrias Quimicas del Ebro, S.A.
    Inventors: Daniel Javier Julve Sebastian, Maria Martinez Falcon, Jose Ramos Escribano, Jorge Perez Cacho, Miguel Menedez Sastre, Joaquin Coronas Ceresuela, Ma Pilar Bernal Paredes
  • Patent number: 9000112
    Abstract: The present invention relates to a resin mixture for melt processing, comprising a first resin; and a second resin comprising an acrylate-based copolymer including silica particles and having a polydispersity index (PDI) of 1 to 2.5, a method for preparing a resin-molded article using the same, and a resin-molded article. Surface characteristics of the molded article can be improved and excellent scratch resistance can be obtained by using the resin composition. In addition, processing time can be reduced, productivity is increased, and manufacturing costs are lowered by omitting the additional surface coating step.
    Type: Grant
    Filed: October 14, 2011
    Date of Patent: April 7, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Jin Young Ryu, Houng Sik Yoo, Hak Shin Kim, Eun Joo Choi, Young Jun Hong
  • Patent number: 8993664
    Abstract: The present invention provides a rubber composition for tires capable of improving handling stability, fuel economy, wet grip performance, elongation at break, and abrasion resistance together while maintaining the balance between them. The present invention also provides a pneumatic tire including the rubber composition. The present invention relates to a rubber composition for tires containing a diene rubber, silica having a BET specific surface area of 170 to 270 m2/g, sulfur, and a liquid resin having a softening point of ?20 to 45° C., wherein the amount of the liquid resin is 0.5 to 20 parts by mass, and the amount of the silica is 40 to 120 parts by mass, each per 100 parts by mass of the rubber component of the rubber composition.
    Type: Grant
    Filed: April 24, 2012
    Date of Patent: March 31, 2015
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Tatsuya Miyazaki
  • Patent number: 8993669
    Abstract: The present invention is directed to a functionalized elastomer comprising the reaction product of a living anionic elastomeric polymer and a polymerization terminator of formula I wherein R1, R2, R3, R4, and R5 are as defined. The invention is further directed to a rubber composition including the functionalized elastomer, and a pneumatic tire including the rubber composition.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: March 31, 2015
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Leena Nebhani, Michael Joseph Rachita
  • Patent number: 8987353
    Abstract: A rubber composition that can be used for the manufacture of tires, based on at least one diene elastomer; one sulphur-based crosslinking system; one inorganic filler as reinforcing filler; one coupling agent of general formula I below: (HO)3-nR1nSi—Z—Sm—R2 wherein in which: R1, which are identical or different, each represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; R2 represents a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 30 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms; n is an integer equal to 0, 1 or 2; and m is a number greater than or equal to 2.
    Type: Grant
    Filed: May 20, 2010
    Date of Patent: March 24, 2015
    Assignees: Michelin Recherche et Technique S.A., Compagnie Generale des Etablissements Michelin
    Inventors: Karine Longchambon, José Carlos Araujo Da Silva, Nicolas Seeboth
  • Patent number: 8980987
    Abstract: This invention relates to a method for producing a modified conjugated diene rubber wherein the method involves: (a) a step in which a conjugated diene polymer having an alkali metal or alkaline earth metal active end and obtained by polymerizing a conjugated diene compound or by polymerizing a conjugated diene compound with an aromatic vinyl compounds is reacted with a first alkoxysilane compound which has an alkoxysilyl group having two or more alkoxy groups and has a group protected by a protecting group wherein deprotection is possible to obtain a modified conjugated-diene polymer having an alkoxysilyl group; and (b) a step in which the modified conjugated-diene polymer is reacted with a second alkoxysilane compound which has an alkoxysilyl group.
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: March 17, 2015
    Assignee: JSR Corporation
    Inventors: Ryouji Tanaka, Naoya Nosaka
  • Patent number: 8980986
    Abstract: A reflector and a light-emitting device including the same. The reflector includes a wholly aromatic liquid crystalline polyester resin compound that includes a repeating unit derived from a hydroxybenzoic acid and a repeating unit derived from a hydroxynaphthoic acid, but does not include a repeating unit derived from an aromatic dicarboxylic acid, wherein the wholly aromatic liquid crystalline polyester resin compound further includes a white inorganic filler.
    Type: Grant
    Filed: September 29, 2011
    Date of Patent: March 17, 2015
    Assignee: Shenzhen Wote Advanced Materials Co., Ltd.
    Inventors: Youn Eung Lee, Jin Kyu Lee, Young Taek Oh
  • Patent number: 8980988
    Abstract: The present invention provides a rubber composition containing: (A) a rubber component containing from 90 to 100% by mass of at least one kind of diene rubber synthesized by solution polymerization and from 0 to 10% by mass of another kind of diene rubber; (B) a silica having a n-hexadecyltrimethylammonium bromide (CTAB) adsorption specific surface area of 180 m2/g or more measured according to a method described in ASTM D3765-92; (C) at least one silane coupling agent selected from a polysulfide compound and a thioester compound; and (D) a vulcanization accelerator, the rubber composition after vulcanization having an average aggregated aggregate area (nm2) of the silica of 1,700 or less, and thus provides a rubber composition that is improved in low-heat-generation property.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: March 17, 2015
    Assignee: Bridgestone Corporation
    Inventors: Satoshi Horie, Takaaki Igarashi
  • Patent number: 8980989
    Abstract: The present invention provides a rubber composition containing: (A) a rubber component containing 10% by mass or more of at least one kind of rubber selected from diene rubber synthesized by emulsion polymerization and natural rubber and 90% by mass or less of another kind of diene rubber; (B) silica having a n-hexadecyltrimethylammonium bromide (CTAB) adsorption specific surface area of less than 140 m2/g measured according to a method described in ASTM D3765-92; (C) at least one silane coupling agent selected from a polysulfide compound and a thioester compound; and (D) a vulcanization accelerator, the rubber composition after vulcanization having an average aggregated aggregate area (nm2) of the silica of 3,300 or less, and thus provides a rubber composition that is improved in low-heat-generation property.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: March 17, 2015
    Assignee: Bridgestone Corporation
    Inventors: Satoshi Horie, Takaaki Igarashi
  • Patent number: 8980990
    Abstract: The present invention provides a rubber composition containing: (A) a rubber component containing 10% by mass or more of at least one kind of rubber selected from diene rubber synthesized by emulsion polymerization and natural rubber and 90% by mass or less of another kind of diene rubber; (B) silica having a n-hexadecyltrimethylammonium bromide (CTAB) adsorption specific surface area of 140 m2/g or more and less than 180 m2/g measured according to a method described in ASTM D3765-92; (C) at least one silane coupling agent selected from a polysulfide compound and a thioester compound; and (D) a vulcanization accelerator, the rubber composition after vulcanization having an average aggregated aggregate area (nm2) of the silica of 2,300 or less, and thus provides a rubber composition that is improved in low-heat-generation property.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: March 17, 2015
    Assignee: Bridgestone Corporation
    Inventors: Satoshi Horie, Takaaki Igarashi
  • Patent number: 8975320
    Abstract: A flame retardant additive for polymers is disclosed which additive comprises a polyacrylate in combination with a) at least one zinc borate, b) at least one silicone resin, and c) alumina trihydrate or magnesium hydroxide or a mixture thereof, said additive being free of halogens, antimony oxide and phosphorus-containing substances. A flame retardant composition comprising a polymer and a flame retardant additive is also disclosed as well as a method of reducing the flammability of a polymer by mixing said polymer with said flame retardant additive.
    Type: Grant
    Filed: October 25, 2006
    Date of Patent: March 10, 2015
    Assignee: PP Polymer AB
    Inventor: Swaraj Paul
  • Patent number: 8975311
    Abstract: A protective coating that comprises a free radically polymerizable component with an atypically high content of tri- or higher functional ingredients is disclosed. Diluents such as oligomeric resins in combination with other resins and particulate materials may also be employed in the composition.
    Type: Grant
    Filed: December 6, 2011
    Date of Patent: March 10, 2015
    Assignee: Valspar Sourcing, Inc.
    Inventors: James V. Mirante, John F. Grunewalder
  • Patent number: 8969462
    Abstract: The present invention provides a rubber composition containing: (A) a rubber component containing from 90 to 100% by mass of at least one kind of diene rubber synthesized by solution polymerization and from 0 to 10% by mass of another kind of diene rubber; (B) silica having a n-hexadecyltrimethylammonium bromide (CTAB) adsorption specific surface area of 140 m2/g or more and less than 180 m2/g measured according to a method described in ASTM D3765-92; (C) at least one silane coupling agent selected from a polysulfide compound and a thioester compound; and (D) a vulcanization accelerator, the rubber composition after vulcanization having an average aggregated aggregate area (nm2) of the silica of 2,200 or less, and thus provides a rubber composition that is improved in low-heat-generation property.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: March 3, 2015
    Assignee: Bridgestone Corporation
    Inventors: Satoshi Horie, Takaaki Igarashi
  • Patent number: 8969461
    Abstract: The present invention provides a rubber composition containing: (A) a rubber component containing 10% by mass or more of at least one kind of rubber selected from diene rubber synthesized by emulsion polymerization and natural rubber and 90% by mass or less of another kind of diene rubber; (B) silica having a n-hexadecyltrimethylammonium bromide (CTAB) adsorption specific surface area of not less than 180 m2/g measured according to a method described in ASTM D3765-92; (C) at least one silane coupling agent selected from a polysulfide compound and a thioester compound; and (D) a vulcanization accelerator, the rubber composition after vulcanization having an average aggregated aggregate area (nm2) of the silica of 1,900 or less, and thus provides a rubber composition that is improved in low-heat-generation property.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: March 3, 2015
    Assignee: Bridgestone Corporation
    Inventors: Satoshi Horie, Takaaki Igarashi
  • Patent number: 8968459
    Abstract: A durable superhydrophobic coating, which coating has the ability to self-heal, similar to the regeneration function observed in biological systems. The coating composition comprises the reaction products of at least one fluorine-containing silane compound (A), at least one hydrolysable compound (B), at least one polysiloxane compound (C), at least one relatively large-sized ceramic particle (I), at least one nano-sized ceramic particle (II) and at least one solvent.
    Type: Grant
    Filed: December 11, 2013
    Date of Patent: March 3, 2015
    Assignee: NEI Corporation
    Inventor: Jiong Liu
  • Patent number: 8969463
    Abstract: The present invention provides a rubber composition containing: (A) a rubber component containing from 90 to 100% by mass of at least one kind of diene rubber synthesized by solution polymerization and from 0 to 10% by mass of another kind of diene rubber; (B) silica having a n-hexadecyltrimethylammonium bromide (CTAB) adsorption specific surface area of less than 140 m2/g or more measured according to a method described in ASTM D3765-92; (C) at least one silane coupling agent selected from a polysulfide compound and a thioester compound; and (D) a vulcanization accelerator, the rubber composition after vulcanization having an average aggregated aggregate area (nm2) of the silica of 3,100 or less, and thus provides a rubber composition that is improved in low-heat-generation property.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: March 3, 2015
    Assignee: Bridgestone Corporation
    Inventors: Satoshi Horie, Takaaki Igarashi
  • Patent number: 8969464
    Abstract: Synthetic aggregates and methods of producing the same are disclosed herein. The aggregates advantageously utilize styrene polymer particles coated with additional materials such as fly ash, silica fume, and/or “liquid glass” in order to provide an improved means for manufacturing lightweight concrete that is significantly stronger than conventional lightweight concretes.
    Type: Grant
    Filed: April 13, 2012
    Date of Patent: March 3, 2015
    Assignee: CityMix, Inc.
    Inventor: Michael W. LeBlanc
  • Patent number: 8957149
    Abstract: The invention relates to preparation and use of a silica reinforced rubber composition. Such rubber composition may be used, for example, for a truck tire tread expected to be exposed to heavy load duty.
    Type: Grant
    Filed: August 25, 2010
    Date of Patent: February 17, 2015
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Junling Zhao, Michael Joseph Rachita
  • Patent number: 8933150
    Abstract: This invention describes a composite molded material consisting of granular ceramic or ceramic coated material and liquid epoxy or urethane resin or vinyl ester resin or polyester resin or mixtures thereof in various ratios by weight and the processes by which the invention is produced. This invention results in a composite material of two or more dissimilar materials which improves the characteristic properties, such as wear, stain and abrasion resistance, oxidation resistance, corrosion resistance, heat resistance, electrical and thermal conductivity, and mechanical strength for which a monolithic material is not satisfactory.
    Type: Grant
    Filed: February 6, 2006
    Date of Patent: January 13, 2015
    Assignee: Grenite Sustainable Solutions, LLC
    Inventors: John G. Carpenter, Richard E. Johnson
  • Patent number: 8933160
    Abstract: A resin composition is provided, which comprises: 40 to 95% by mass of a resin component containing 10 to 100% by mass of a polyarylate resin and 90 to 0% by mass of a polycarbonate resin; and 60 to 5% by mass of spherical silica having an average particle diameter of not greater than 10 ?m. The resin composition is molded into a product.
    Type: Grant
    Filed: November 27, 2006
    Date of Patent: January 13, 2015
    Assignee: Unitika Ltd.
    Inventor: Hiroo Kamikawa
  • Patent number: 8933164
    Abstract: A dispersion, comprising 0.1 to 25% by weight hydrophobized silica, 8 to 90 wt % of at least one alcohol selected from the group consisting of ethanol, 1-propanol and 2-propanol, 7 to 89 wt % of water, 0 to 30% by weight solvent immiscible with water, and 0.04 to 5 wt % of at least one carboxyvinyl polymer present in neutralized form, can be applied to a surface using a non-drip application method and, by modifying the surface with hydrophobized silica, imparts water-repelling and self-cleaning properties to the surface.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: January 13, 2015
    Assignee: Evonik Degussa GmbH
    Inventors: Jörg Peggau, Harald Jakob, Wolfgang Lortz
  • Patent number: 8921475
    Abstract: The invention relates to a hardenable dental composition comprising component (A) comprising a cationically hardenable compound, component (B) comprising an initiator being able to initiate the hardening reaction of the cationically hardenable compound, and component (C) comprising a filler, wherein the filler comprises a filler body and a filler surface, the filler surface comprising side groups with polar moieties. The invention also relates to a process of producing the dental composition, to the use of the dental composition as dental impression material and to a method of taking an impression of dental tissue.
    Type: Grant
    Filed: July 19, 2010
    Date of Patent: December 30, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Joachim W. Zech, Thomas Klettke, Sebastian Zeller, Bernd Kuppermann, Hendrik Grupp
  • Patent number: 8916646
    Abstract: An addition curable self-adhesive silicone rubber composition comprising (A) an organopolysiloxane containing alkenyl at either end, (B) an organosilicon compound containing phenylene and SiH group, (C) an organohydrogenpolysiloxane containing two SiH groups, (D) an organohydrogenpolysiloxane containing at least three SiH groups, and (E) an addition reaction catalyst is integrally moldable with thermoplastic resins.
    Type: Grant
    Filed: August 6, 2013
    Date of Patent: December 23, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Nobu Kato
  • Patent number: 8907001
    Abstract: The invention relates to the use of a precipitated silica, pretreated by at least one organosilane hydrophobic compound or one hydrophobic silicone oil, as a reinforcing filler for silicone elastomer, the pretreated silica being incorporated in the silicone elastomer by cold mixing and having the following features: —a BET specific surface ranging from 50 to 450 m2/g, —a water wettability lower than 80, —a sulfur content lower than 0.1% by weight. The invention is directed to the curable silicone elastomer composition thus obtained.
    Type: Grant
    Filed: August 6, 2009
    Date of Patent: December 9, 2014
    Assignees: Rhodia Chimie, Shin-Etsu Chemical Co., Ltd
    Inventors: Agnès Pottier, Kyu-Min Hwang, Minoru Igarashi, Tsutomu Nakamura, Nahohiko Harada
  • Publication number: 20140345821
    Abstract: A roll covering is particularly suitable for a roll for the treatment of a paper web, paperboard web, or any other web of fibrous material in a machine for the production and/or finishing the same. The roll covering encompasses at least one layer. The at least one layer is formed of a rubber composition that includes at least one (meth)acrylate compound and a rubber component with at least one crosslinked hydrogenated nitrile rubber. Further, the at least one layer has a recovery rate of at least 12 mm per second and/or a maximal degree of plastic deformation of 0.9%, and a maximal tan ? value of 0.16 determined in accordance with DIN 53513 at 60° C. in tension at 10 Hz, 15% static elongation, and 1% dynamic elongation.
    Type: Application
    Filed: January 24, 2013
    Publication date: November 27, 2014
    Inventors: Peter Putschoegl, Stephan Ully
  • Patent number: 8889777
    Abstract: A composition for use as a sport or recreational surface includes about 88 to 90 percent by weight of a sand blend that is formed of at least three different sands mixed together, the sand blend including a first sand that is represents a majority by weight of the sand blend and has a clay/silt content of at least 1% by weight; about 5-7 percent by weight of a hydrocarbon wax; at least about 2 percent by weight of polymeric material; and at least about 3 percent by weight of rubber, the percentage by weight of each ingredient being based on the total weight of the composition.
    Type: Grant
    Filed: January 27, 2011
    Date of Patent: November 18, 2014
    Inventors: Lawton Adams, Karen Leeming
  • Patent number: 8883917
    Abstract: A method for the preparation of a polyamide-based composition provides for the substantially uniform dispersion of particulate silica and, optionally, mineral oil and any other lubricant additive, within a polyamide matrix. The method includes mixing particulate silica, and optionally, mineral oil and other lubricant additives, to one or more polyamide-producing monomers, and water, to form an emulsion or suspension wherein the particulate silica (and mineral oil and other lubricant additives, when added) are substantially uniformly dispersed therein, and then in situ polymerizing the monomer(s) to provide a polyamide matrix wherein the particulate silica, and optional mineral oil and other optional lubricant additives, remain substantially uniformly dispersed in the resulting polyamide matrix to form the polyamide-based composition.
    Type: Grant
    Filed: September 10, 2012
    Date of Patent: November 11, 2014
    Assignee: Nylon Corporation of America, Inc.
    Inventors: Jack D. Davies, Gregory J. Biederman, Christopher A. Coco
  • Patent number: 8877849
    Abstract: A thermosetting silicone resin composition for an LED reflector has: a thermosetting resin; at least one kind of white pigment selected from titanium oxide, zinc oxide, zirconium oxide, magnesium oxide, barium carbonate, magnesium silicate, zinc sulfate, and barium sulfate; and an inorganic filler other than the pigment, which contains at least one kind of inorganic filler that has an average particle diameter of 30 ?m to 100 ?m and a refraction index that is different from a refraction index of a cured material of the thermosetting resin by 0.05 or more, and at least one kind of inorganic filler that has an average particle diameter of less than 30 ?m. The thermosetting resin composition provides a cured material that has excellent heat and light resisting properties and hardly leaks light, a reflector for an LED obtained by molding using the composition, and an optical semiconductor apparatus using the reflector.
    Type: Grant
    Filed: March 29, 2013
    Date of Patent: November 4, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshio Shiobara, Tsutomu Kashiwagi, Takayuki Kusunoki, Yoshihiro Tsutsumi
  • Patent number: 8877846
    Abstract: The present teachings disclose a surface coating composition. The surface coating composition includes fluorine containing particles, aerogel particles and positive tribocharging particles. The surface coating is useful as the release layer for fuser members.
    Type: Grant
    Filed: April 17, 2012
    Date of Patent: November 4, 2014
    Assignee: Xerox Corporation
    Inventors: Carolyn P. Moorlag, Suxia Yang, Yu Qi, Qi Zhang, Brynn M. Dooley, Sandra J. Gardner
  • Patent number: 8877857
    Abstract: The present invention provides a polar group-containing copolymer which can provide a rubber composition and a winter tire achieving the abrasion resistance, performance on ice, and handling stability on dry roads in a balanced manner. The present invention relates to a polar group-containing copolymer obtainable by copolymerizing a conjugated diene compound and a polar group-containing vinyl compound, wherein the polar group-containing vinyl compound is a compound that has a polymerizable unsaturated bond and a polar group, wherein any one of carbon atoms forming the polymerizable unsaturated bond and a carbon atom linked to the polar group are connected to each other via at least one carbon atom, and wherein a cis content of the double bond portion of the conjugated diene compound in the polar group-containing copolymer is 80 mol % or more.
    Type: Grant
    Filed: April 6, 2010
    Date of Patent: November 4, 2014
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Ryuichi Tokimune, Kazuo Hochi, Katsumi Terakawa