Solid Polymer Or Specified Intermediate Condensation Product Derived From At Least One Oxygen-containing Reactant And Which Is Devoid Of A Fused Ring Or Bridged Ring System Patents (Class 524/4)
  • Patent number: 6166113
    Abstract: Flexible building compositions are provided which are based on mineral binders and vinylester-ethylene mixed polymers which are stabilized by protective colloids and prepared by radical aqueous emulsion polymerization.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: December 26, 2000
    Assignee: Wacker-Chemie GmbH
    Inventors: Reinhard Haerzschel, Christoph Hahner
  • Patent number: 6165262
    Abstract: A novel cement admixture is provided which fulfills the function as a thickener basically, possesses an ability to inhibit segregation of materials, excels in workability as well, and permits a decrease in the amount of addition while keeping these functions intact. The cement admixture is characterized by comprising a cement additive formed of a polymer resulting from polymerizing a monomer mixture having methyl acrylate as a main component thereof and a cement water reducing agent.
    Type: Grant
    Filed: January 20, 1999
    Date of Patent: December 26, 2000
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Kono, Tsutomu Yuasa, Tsuyoshi Hirata
  • Patent number: 6162839
    Abstract: A composition for producing light plaster contains as main constitutive elements particles of plaster in anhydride or hemihydrate form and at least one foaming agent. The composition is characterized in that the foaming agent generates gas after a delay of 1 minute to 24 hours and constitutes 0.1 to 50% by weight of the total dry mixture. Also disclosed is the use of said composition to produce in-situ cellular plastic and low density plaster moldings.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: December 19, 2000
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Klauck, Hermann Kluth, Wilfried Huebner, Felicitas Kolenda
  • Patent number: 6153673
    Abstract: The invention discloses a new phosphomagnesium cement that can be obtained by contacting at least one phosphorus compound and at least one magnesium compound based binder phase, with at least one polymer in water insoluble particle form, and water. The polymer can be selected among those derived from the polymerisation of at least one ethylenically unsaturated monomer and at least one monomer selected among monomers with carboxylic function and acrylamide or methacrylamide. The phosphomagnesium cement can also comprise an aminoalkylsilane, preferably an aminoalkyl(alkoxysilane).
    Type: Grant
    Filed: February 16, 1999
    Date of Patent: November 28, 2000
    Assignee: Rhodia Chimie
    Inventors: Dominique Lemos, Gilles Orange, Jean-Francois Colombet
  • Patent number: 6150437
    Abstract: Flow improving agents for binder suspensions containing cement are described, which consist of:a) Graft polymers which have been prepared by radical grafting of a polyalkylene oxide of the general formula (I) with an ethylenically unsaturated mono- or dicarboxylic acid or the anhydride thereof, and then by derivatizing with a primary or secondary amine and/or alcohol, and also ofb) Casein.These flow improving agents have the advantage that the ability to flow is considerably improved in comparison, for example, with casein alone, and the improved ability to flow is preserved over a longer period of time.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 21, 2000
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Konrad Wutz, Alfred Kern, Josef Weichmann
  • Patent number: 6133347
    Abstract: A cementitious formulation comprising a cement and an oligomeric dispersant is provided. The dispersant is a reaction product of two or three moieties. The first moiety (A) is a nonpolymeric, functional moiety that adsorbs onto a particle, and wherein one or more A moieties together contain at least two residues to provide attachment of the dispersant onto a particle to be dispersed. The second required moiety (C) is a linear or branched water soluble, nonionic polymer that provides the dispersing capability. A third moiety (B), if present, is a nonpolymeric moiety disposed between the first and second moiety, to connect the first and second moieties. A method is provided for dispersing a cementitious formulation comprising a cement in water, including providing in said cementitious formulation the above oligomeric dispersant.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: October 17, 2000
    Assignee: MBT Holding AG
    Inventors: Thomas M. Vickers, Jr., Rainer Packe-Wirth, Michael Porsch, Samy M. Shendy, Lynn E. Brower, John Pickett, Runhai Lu, Frank Danko
  • Patent number: 6124383
    Abstract: A composition comprising a polymer which comprises repeat units derived from a first unsaturated amide, a hydroxy acrylate, and at least two monomers selected from the group consisting of (1) a vinyl pyridine or derivative thereof and acrylic acid or salt thereof, (2) a vinyl morpholine and a second unsaturated amide; (3) acrylic acid or salt thereof and a second unsaturated amide; (4) acrylic acid or salt thereof, a vinyl pyridine, and a vinyl morpholine; and combination of two or more thereof wherein said first unsaturated amide is not the same as said second unsaturated amide.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: September 26, 2000
    Assignee: Phillips Petroleum Company
    Inventors: Michael L. Stephens, Howard F. Efner
  • Patent number: 6110270
    Abstract: The moisture content within, and moisture flow in and out of, porous building materials such as masonry, brick, concrete, and mortar, can be affected by coating the building material with polyvinyl alcohol, or by incorporating polyvinyl alcohol into the building material. The resultant control of moisture movement can influence the suction of the building material, leading to improved bonding with adjacent building material, and can also retard efflorescence.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: August 29, 2000
    Inventor: Thomas Beckenhauer
  • Patent number: 6106603
    Abstract: The present invention comprises a stable hydrocolloid composition in which preferably welan gum is uniformly dispersed in a superplasticizer solution such as sulfonated naphthalene, sulfonated melamine, modified lignosulfate, their derivatives and solution thereof. The mixture is wet milled to form an extremely fine particle size, from about 3 microns to about 500 microns distribution of the gum. The composition is rapidly hydratable and useful as a stabilizing additive in many cement and drilling fluid applications.
    Type: Grant
    Filed: April 16, 1998
    Date of Patent: August 22, 2000
    Assignee: Pharmacia Corporation
    Inventors: Bryan Skaggs, Harold Dial, Walter Rakitsky
  • Patent number: 6107368
    Abstract: A curable two-component composition with curable organic and curable inorganic constituents and with curing agents, the curing agents being separated from the respective curable constituent so as to inhibit reaction, but activatable for application or use, containing epoxide and the finely particulate cement as curable constituents and amine and alkali silicate as curing agent.
    Type: Grant
    Filed: July 20, 1999
    Date of Patent: August 22, 2000
    Assignee: Hilti Aktiengesellschaft
    Inventors: Gienau Roland, Pfell Armin
  • Patent number: 6087418
    Abstract: The present invention provides a cement admixture and a cement composition, both of which displays little dependence of the water-reducibility upon temperature in that these cement admixture and cement composition involve little slump loss at high temperature and little increase in the amount of addition at low temperature. The cement admixture comprises the following essential components: either or both of polymer (A) and polymer salt (AA), wherein polymer (A) includes constitutional unit (I) of general formula (1) below as an essential constitutional unit, and polymer salt (AA) is obtained by further neutralizing polymer (A) with an alkaline substance; and either or both of polymer (B) and polymer salt (BB), wherein polymer (B) includes constitutional unit (II) of general formula (2) below as an essential constitutional unit, and polymer salt (BB) is obtained by further neutralizing polymer (B) with an alkaline substance.
    Type: Grant
    Filed: January 1, 1999
    Date of Patent: July 11, 2000
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Akihiko Yamashita, Tsuyoshi Hirata, Tsutomu Yuasa, Hirokazu Niwa
  • Patent number: 6084011
    Abstract: A cementitious paste capable of setting after an interval of time comprises a mixture of a fines component selected from a group consisting of cement and a blend of cement and pozzolonic material, water and a water soluble polymer that is capable of taking up and releasing water when incorporated into the mixture. The polymer comprises a selected percent by weight of the mixture. A non-foamed cementitious composition is also provided to form a substantially homogeneous, pervious rigid mass that comprises a substantially surfactant-free mixture of the fines component, inert aggregate particles, water and a selected percentage by weight of the water-soluble polymer that is capable of adhesion to the aggregate particles.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: July 4, 2000
    Inventors: Richard F. Lucero, Bruce Davis
  • Patent number: 6063184
    Abstract: The invention relates to a random styrene-maleic anhydride (SMA) copolymer in free acid or salt form wherein the copolymer has the following types and numbers of monomer units ##STR1## in which M is selected from hydrogen, a cation and a residue of a hydrophobic polyalkylene glycol or polysiloxane, R is the residue of methylpoly(ethylene)glycol of molecular weight (weight-average) 900-2000, x=0.35-0.75 and y=0.25-0.65. These copolymers are particularly useful as superplasticizers in cementitious compositions such as concretes and mortars.
    Type: Grant
    Filed: May 22, 1998
    Date of Patent: May 16, 2000
    Assignee: MBT Holding AG
    Inventors: Bernhard Leikauf, Max Oppliger, Salvatore Valenti
  • Patent number: 6051634
    Abstract: Use of water-dispersible or water-soluble polyether-urethanes, which optionally contain isocyanate groups, as additives for inorganic binders in the preparation of a building material, particularly a high-density or high-strength mortar or concrete composition. The building material resulting from the use of the water-dispersible or water-soluble polyether-urethanes.
    Type: Grant
    Filed: September 11, 1998
    Date of Patent: April 18, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Josef Laas, Jan Mazanek, Dietbert Knofel, Karl-Georg Bottger, Anke Reinschmidt
  • Patent number: 6048916
    Abstract: A method for the dispersion of cement, which comprises incorporating in a cement composition consisting at least of cement and water a cement dispersing agent formed of a polymer obtained by polymerizing a monomer component containing an alkoxy polyalkylene glycol mono(meth)acrylic ester monomer produced by the interesterification of an alkoxy polyalkylene glycol and a (meth)acrylic ester. A cement composition comprising the cement dispersing agent, cement and water.
    Type: Grant
    Filed: April 2, 1997
    Date of Patent: April 11, 2000
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Tsuyoshi Hirata, Tsutomu Yuasa, Katsuhisa Shiote, Shogo Iwai, Koichiro Nagare, Hideyuki Tahara
  • Patent number: 6043329
    Abstract: Copolymers which are obtainable by reacting acrylic monomers with monomers of the following formula:R.sub.4 --O--R.sub.5 --CO--NH--R.sub.6wherein R.sub.4 represents H or a group of the following formulae: ##STR1## R.sub.5 represents an oxyalkenyl group of the following formulae:--(CHR.sub.1 --CH.sub.2 --O).sub.m -- or --(CHR.sub.1 --CH.sub.2 --O).sub.m1 --(CH.sub.2 --CH.sub.2 --O).sub.n --R.sub.6 represents a C.sub.1 - to C.sub.8 -alkyl group, a C.sub.5 - to C.sub.7 -cycloalkyl group, or a phenyl group. The copolymers are very useful as additives or admixtures for improving the properties of construction materials and of dispersions.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: March 28, 2000
    Assignee: Cement Intellectual Property Ltd. (CIP)
    Inventors: Agostino Lepori, Stefan Pieh, Manfred Akstinat, Fritz Burkhardt
  • Patent number: 6008275
    Abstract: A cementitious mixture comprises a hydraulic cement; greater than about 10% by weight of a pozzolanic cement replacement selected from fly ash, slag, natural pozzolans, and mixtures thereof, based on the weight of said hydraulic cement and cement replacement; and a compatabilizing admixture, wherein the compatabilizing admixture comprises a compatabilizing polycarboxylate polymer dispersant capable of acting as a water reducer, in combination with an accelerator.
    Type: Grant
    Filed: May 14, 1998
    Date of Patent: December 28, 1999
    Assignee: MBT Holding AG
    Inventors: John Moreau, Runhai Lu, Jeffrey R. Bury
  • Patent number: 5932334
    Abstract: The invention relates to a composition or pellet comprising a polyvinyl chloride homopolymer and wood fiber composite that can be used in the form of a linear extrudate or thermoplastic pellet to manufacture structural members. The fiber in the pellet or extrudate is of a particular dimension that lends enhanced modulus to the composition or pellet formed. The extruded pellet comprises a consistent proportion of polymer, wood fiber and water.
    Type: Grant
    Filed: November 13, 1997
    Date of Patent: August 3, 1999
    Assignee: Andersen Corporation
    Inventors: Michael J. Deaner, Giuseppe Puppin, Kurt E. Heikkila
  • Patent number: 5925695
    Abstract: Disclosed are a curable composition, a cured article therefrom having improved properties, an asphalt emulsion, an asphalt mixture for paving, and a cured article prepared therefrom having an excellent water permeability.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: July 20, 1999
    Assignee: Daicel Chemical Indstries Ltd.
    Inventors: Yoshihiro Ohtsuka, Yasuhiro Oshino
  • Patent number: 5922124
    Abstract: An additive for, a method of adding thereof to uncured mixes for and resulting cured cement-type concreations such as cured embodiments of concrete, marcadam, and roof-top shingles each exhibiting improved heat and freeze-thaw durability resulting from reduced efflorescence and stability against sun ultraviolet light exposure.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: July 13, 1999
    Inventor: William W. Supplee
  • Patent number: 5908885
    Abstract: Polysuccinimide and/or polyaspartate, copolymers of succinimide and aspartate and the polymers cross-linked with a diamine are demonstrated to be enhancement agents for the preparation of cementitious materials. The agents may be added to the dry cementitious mixture or the water which is added to form the cementitious material upon hardening. The enhancement agents improve the workability of the wet cementitious mixture, reduce slump loss during mixing, transport, and placement of the wet cementious mixture; and may provide extra strength upon hardening of the cementitious material.
    Type: Grant
    Filed: July 1, 1997
    Date of Patent: June 1, 1999
    Assignees: University of South Alabama, MBT Holding AG
    Inventors: C. Steven Sikes, Thomas M. Vickers, Jr., Stephen A. Farrington
  • Patent number: 5854318
    Abstract: A cement additive is added to increase flowability of a cement composition and to prevent a slump loss, but those characters are insufficient, or the cement additive becomes ununiform in the cement composition and causes a trouble of the hardening inferiority.Thus, to solve the subjects, the present invention provides a cement additive composed of a crosslinked polymer in which, between main chains having a water-soluble polymer structure of a molecular weight from 500 to 100,000, a bond having as a structural unit at least one group selected from divalent groups as shown in the following formula (I) is formed. ##STR1## ?In the formula (I), R.sup.1 and R.sup.2 independently denote any one of the following. ##STR2## However, R.sup.1 may not be required in a case of that R.sup.2 is the following. ##STR3## Moreover, R and R' independently denote an alkyl group of carbon number of 1 to 5.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: December 29, 1998
    Assignee: Nippon Shokubai Kagaku Kogyo Co, Ltd.
    Inventors: Hideyuki Tahara, Hiroshi Ito, Yasuhiro Mori, Makoto Mizushima
  • Patent number: 5814146
    Abstract: The invention concerns a MDF cement material showing better impact strength meant as an increase in the breaking total energy, by fibers addition.
    Type: Grant
    Filed: December 31, 1996
    Date of Patent: September 29, 1998
    Assignee: Italcementi S.P.A.
    Inventors: Rosa Di Maggio, Marcello Franchini, Gianluca Guerrini, Claudio Migliaresi, Stefano Poli
  • Patent number: 5807609
    Abstract: At least one compound ##STR1## is added to mineral building materials modified with polymers in order to increase their adhesive power on foams based on polystyrene.
    Type: Grant
    Filed: July 26, 1995
    Date of Patent: September 15, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Maximillian Angel, Andree Dragon, Wilhelm Friedrich Beckerle, Helmut Teichmann
  • Patent number: 5779788
    Abstract: A cement admixture composed of a mixture of lower alkyl ether oxyalkylene adducts with a sulfonated organocyclic material to provide cement compositions of mortar and concrete which inhibit drying shrinkage while attaining very high slump and/or increased compressive strength.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: July 14, 1998
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Neal Steven Berke, Michael Paul Dallaire, Awdhoot Vasant Kerkar
  • Patent number: 5753365
    Abstract: A rubber composition includes a rubber component and particulates of a crystalline syndiotactic-1,2-polybutadiene resin dispersed therein. The particulates have an average particle diameter of 1 to 500 .mu.m, and the melting point of the crystalline syndiotactic-1,2-polybutadiene resin is not less than 110.degree. C. The compounding ratio of the resin is 5 to 60 parts by weight relative to 100 parts by weight of the rubber component. The rubber composition is useful for tires, other rubber articles, etc. With respect to tires in particular, a pneumatic tire includes a rubber composition used for a tread, wherein the rubber composition includes a rubber component and particulates of crystalline syndiotactic-1,2-polybutadiene resin. The matrix portion of the tread rubber other than the above particulates is preferably a foamed rubber.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: May 19, 1998
    Assignees: Bridgestone Corporation, Ube Industries, Ltd.
    Inventors: Yoshiyuki Morimoto, Koji Yamauchi, Seiichiro Iwafune, Tatsuro Hamada, Masanori Aoyama, Eiji Yamanaka, Koichi Nagakura, Koji Ishiguchi
  • Patent number: 5753368
    Abstract: The bonding between concrete and fibers is enhanced by using a fiber coating material selected from certain glycol ethers, having at least three carbon atoms in an oxyalkylene group, and glycerol ethers. The present invention pertains to such coated fibers, a method for modifying a concrete using the coated fibers, and a cementitious composition containing the coated fibers.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: May 19, 1998
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Neal S. Berke, Kevin J. Folliard, Awdhoot Vasant Kerkar, Brian Scott Gilbert
  • Patent number: 5749963
    Abstract: The hardenable mortar composition consists of a bonding agent component including a hydraulic bonding agent, such as cement, gypsum or mortar, and a paste-forming agent consisting of a liquid solvent inert with respect to the hydraulic bonding agent, and an aqueous component kept separate from the bonding agent component until the two components are mixed to form a hardened mortar composition. The aqueous component includes water and a hydrophobic adsorbent or absorbent. The hydrophobic adsorbent or absorbent is included in the aqueous component to avoid the emergence of the paste-forming agent, which is at the very least unsightly, when the aqueous component is mixed with the bonding agent component. The hydrophobic adsorbent or absorbent binds the paste-forming agent which would otherwise escape during mixing and remains as an inert additive in the setting mortar composition, without reducing the hardness thereof.
    Type: Grant
    Filed: February 13, 1997
    Date of Patent: May 12, 1998
    Assignee: fischerwerke, Artur Fischer GmbH & Co. KG
    Inventors: Norbert Arnold, Willi Haug, Stefan Lind
  • Patent number: 5739179
    Abstract: Aqueous emulsions of grafted polymer compositions are provided. The grafted component of these compositions has two or more polymeric substituents. The aqueous emulsions of grafted polymer compositions are particularly useful as cement modifiers.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: April 14, 1998
    Assignee: Rohm and Haas Company
    Inventors: Shang Jaw Chiou, Miao-Hsun Li Sheng
  • Patent number: 5705553
    Abstract: Copolymers containing carboxyl groups in aqueous dispersion form or redispersible powder form and their water-soluble salts, based on ethylenically unsaturated and copolymerizable monomers, the macro-molecules of which contain at least 24% by weight of monomer units carrying carboxyl groups prepared, by emulsion copolymerization initiated by free radicals in the presence of polyvinyl alcohol (PVA) or polyvinylpyrrolidone (PVP) dissolved in the aqueous phase and isolation of the copolymers in aqueous dispersion form, and optionally subsequent removal of water by spray drying to obtain redispersible copolymer powders and processes for their preparation and their use as thickeners in aqueous formulations which copolymers, by conversion into their water-soluble salt forms, are useful as thickening agents having a surprisingly advantageous rheology-modifying action in aqueous systems.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: January 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Rolf Kuropka
  • Patent number: 5681385
    Abstract: Efflorescence of building material, such as portland cement based building products, masonry, brick, concrete, and mortar, can be retarded by contacting the building material with polyvinylalcohol (PVOH). The PVOH may be dissolved in solvent, preferably water, and either applied to a surface of the building material, or added to the components that form the building material. The PVOH has a hydrolysis percentage above about 90%.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: October 28, 1997
    Inventor: Thomas Beckenhauer
  • Patent number: 5679150
    Abstract: A cement admixture composition composed of an oxyalkylene compound and betaine. The betaine permits air entrainment in the presence of the oxyalkylene compound, which is used as a shrinkage reduction aid.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: October 21, 1997
    Inventors: Awdhoot Vasant Kerkar, Michael Paul Dallaire
  • Patent number: 5674929
    Abstract: The interlayer adhesion and final strength of cementitious compositions which are applied in consecutive layers are improved by the incorporation in the compositions of an admixture which is a combination of a waterproofing agent and a water retention agent. The invention is particularly applicable to sprayed concrete.
    Type: Grant
    Filed: September 6, 1994
    Date of Patent: October 7, 1997
    Assignee: MBT Holding AG
    Inventor: Tom Melbye
  • Patent number: 5651816
    Abstract: Cement comprising hydraulic cement and polymer precursor such as alcohol-soluble phenol resin precursor that is substantially anhydrous and generates water by polymerization.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: July 29, 1997
    Assignee: Maeta Concrete Industry Ltd.
    Inventors: Tadashi Kobayashi, Game Kankanamge Dinilprem Pushpalal, Masaki Hasegawa
  • Patent number: 5631312
    Abstract: A floor paint composition superior in resistance to oil and solvents, and in early strength. The composition is mainly composed of a synthetic resin emulsion based on an from anion copolymer obtained from the copolymerization of .alpha.-type hemihydrate gypsum, cement and ethylene unsaturated monomer. The ratio of weight of .alpha.-type hemihydrate gypsum to cement is between 80:20 and 95:5. The ratio of the solid content of the synthetic resin relative to 100 parts by weight of the mixture of .alpha.-type hemihydrate gypsum and cement is between 15 and 35 parts by weight. The anion copolymer contains at least one unit of a monomer selected from the group consisting of ethylene unsaturated carboxylic acid, ethylene unsaturated sulfonic acid and ethylene unsaturated phosphonic acid. The copolymer can include an ethylene unsaturated monomer having at least one organic silicon radical. The synthetic resin emulsion can include epoxy silane.
    Type: Grant
    Filed: May 21, 1996
    Date of Patent: May 20, 1997
    Assignees: Kikusui Chemical Industries Co., Ltd., Hoechst Industry Limited
    Inventors: Izumi Takada, Noriyuki Niwa, Ikuo Imaizumi
  • Patent number: 5609680
    Abstract: Cement comprising hydraulic cement and polymer precursor such as alcohol-soluble phenol resin precursor that is substantially anhydrous and generates water by polymerization.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: March 11, 1997
    Assignee: Maeta Concrete Industry Ltd.
    Inventors: Tadashi Kobayashi, Game K. D. Pushpalal, Masaki Hasegawa
  • Patent number: 5604273
    Abstract: The subject invention is directed to a cement admixture composition composed of certain alkylene glycols and copolymers of alkenyl ether and maleic anhydride. The present admixture provides a means to inhibit drying shrinkage of cement compositions while enhancing the compressive strength of the set composition.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: February 18, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Awdhoot V. Kerkar, Brian S. Gilbert
  • Patent number: 5599857
    Abstract: A polymer concrete pipe liner is formed from a fluidized, but substantially waterless cement containing mixture applied to the pipe interior. The mixture contains inorganic cement particles, a liquid styrene mixture and one or more poly-olefinically unsaturated co-monomers in a greater amount than the styrene. The mixture substantially excludes acrylonitrile and acrylamide. The co-monomers are preferably selected from a group including trimethylolpropane-trimethacrylate, trimethylolpropane-methacrylate, divinyl benzene, and hexadiene. Mixing liquid and solid aggregate components forms a slurry which is transferred to a pipe interior and centrifugally cast to form the liner. The composition avoids the need for high temperature curing the toxic reactive unsaturates to co-polymerize and cross-link polystyrene.
    Type: Grant
    Filed: January 3, 1994
    Date of Patent: February 4, 1997
    Assignee: Union Oil Company of California
    Inventor: William C. Allen
  • Patent number: 5580624
    Abstract: Containers use in the storing, dispensing, packaging, and/or portioning of food and beverage products are disclosed. The disposable and nondisposable food and beverage containers are manufactured from aggregates held together by organic binders in order to be lightweight, insulative, inexpensive, and more environmentally compatible than those currently used for storing, dispensing, packaging, or portioning such products. The food and beverage containers of the present invention are particularly useful for dispensing hot and cold food and beverages in the fast food restaurant environment. The structural matrices of the food and beverage containers include a hydrated organic binder paste (formed by mixing the binder with water) in combination with appropriate aggregate materials, such as fibers to add flexibility and strength, glass spheres to make the product more lightweight and insulative, or clay to make the product extremely inexpensive yet strong.
    Type: Grant
    Filed: March 17, 1995
    Date of Patent: December 3, 1996
    Assignee: E. Khashoggi Industries
    Inventors: Per J. Andersen, Simon K. Hodson
  • Patent number: 5567750
    Abstract: The invention provides a redispersibte dispersion powder composition comprisinga) a base polymer selected from the group consisting of vinyl ester polymers, styrene polymres, acrylate polymers and vinyl chloride polymers,b) from 2 to 15% by weight, based on the weight of the base polymer, of polyvinyl alcohol having a degree of hydrolysis of from 85 to 95 mol % and a Hoppler viscosity of from 2 to 25 mPa.s,c) from 3 to 30% by weight, based on the total weight of polymeric components, of fine antiblocking agent, andd) from 1 to 15% by weight, based on the weight of the base polymer, of an aminofunctional polyvinyl alcohol soluble in cold water and having a Hoppler viscosity of from 1 to 20 mPa.s and a saponification number of from 0 to 250, which comprises residues of aminofunctional vinyl units of the formula CH.sub.2 .dbd.CH--(CH.sub.2).sub.x --NH.sub.2, wherein x is a number of from 0 to 4.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: October 22, 1996
    Assignee: Wacker-Chemie GmbH
    Inventors: Joachim Schulze, Reinhard Haerzschel, Reiner Figge
  • Patent number: 5565027
    Abstract: The invention relates to a cement composition containing a water reducing amount of the product formed by reaction of polyvinyl alcohol and an hydroxyaldehyde such as 4-hydroxybutanal.
    Type: Grant
    Filed: April 2, 1996
    Date of Patent: October 15, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Edward T. Shawl, Jeffrey A. Klang
  • Patent number: 5508072
    Abstract: Compositions and methods for manufacturing sheets having a highly inorganically filled matrix. Suitable inorganically filled mixtures are prepared by mixing together an organic polymer binder, water, one or more inorganic aggregate materials, fibers, and optional admixtures in the correct proportions in order to form a sheet which has the desired performance criteria. The inorganically filled mixtures are formed into sheets by first extruding the mixtures and the passing the extruded materials between a set of rollers. The rolled sheets are dried in an accelerated manner to form a substantially hardened sheet, such as by heated rollers and/or a drying chamber. The inorganically filled sheets may have properties substantially similar to sheets presently made from traditional materials like paper, paperboard, polystyrene, plastic, or metal. Such sheets can be rolled, pressed, scored, perforated, folded, and glued.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: April 16, 1996
    Assignee: E. Khashoggi Industries
    Inventors: Per J. Andersen, Simon K. Hodson
  • Patent number: 5506046
    Abstract: Compositions, methods, and apparatus for manufacturing sheets having a highly inorganically filled matrix. Suitable inorganically filled mixtures are prepared by mixing together an organic polymer binder, water, one or more aggregate materials, fibers, and optional admixtures in the correct proportions in order to form a sheet which has the desired performance criteria. The inorganically filled mixtures are formed into sheets by first extruding the mixtures and then passing the extruded materials between a set of rollers. The rolled sheets are dried in an accelerated manner to form a substantially hardened sheet, such as by heated rollers and/or a drying chamber. The inorganically filled sheets may have properties substantially similar to sheets presently made from traditional materials like paper, paperboard, polystyrene, plastic, or metal. Such sheets can be cut, rolled, pressed, scored, perforated, folded, and glued to fashion articles from the sheets.
    Type: Grant
    Filed: November 24, 1993
    Date of Patent: April 9, 1996
    Assignee: E. Khashoggi Industries
    Inventors: Per J. Andersen, Simon K. Hodson
  • Patent number: 5476885
    Abstract: A cement additive composed of a crosslinked polymer in which, between main chains having a water-soluble polymer structure of a molecular weight from 500 to 100,000, there is a bond having as a structural unit at least one divalent group having the following formula (I): ##STR1## where R.sup.1 and R.sup.2 independently denote any one of the following: ##STR2## where R.sup.1 is not required, if R.sup.2 is the following: ##STR3## and where R and R' independently denote an alkyl group of carbon number of 1 to 5.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: December 19, 1995
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hideyuki Tahara, Hiroshi Ito, Yasuhiro Mori, Makoto Mizushima
  • Patent number: 5442002
    Abstract: A polymer scale deposition preventive agent for use in polymerization of a monomer having an ethylenically unsaturated double bond, comprising an alkaline solution containing a condensation product of (A) a diphenyl compound having at least two amino groups and (B) a quinone compound. When the aforementioned monomer is polymerized in a polymerization vessel having a coating formed by applying the aforementioned preventive agent to inner wall surfaces followed by drying, polymer scale can be effectively prevented from being deposited not only on the areas located in the liquid-phase region but also on the areas around the interface between the gas and liquid phases in the polymerization vessel. When an obtained polymer is formed into a sheet or the like, it is possible to obtain a formed product having few fish eyes and good initial coloration.
    Type: Grant
    Filed: July 21, 1994
    Date of Patent: August 15, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshihide Shimizu, Mikio Watanabe
  • Patent number: 5432212
    Abstract: A cement admixture which when added to a cement composition, such as cement mortar or concrete inhibits slump-loss of the cement composition and improve its workability and applicability. The admixture is composed of copolymers from an alkenyl ether, a polyalkenyl ether and maleic anhydride.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: July 11, 1995
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Susumu Honda, Tadashi Hara, Hideo Koyata
  • Patent number: 5401798
    Abstract: Materials based on gypsum and organic additives are improved if they contain polyethers and, if desired, polymers. They can be used in a wide range of areas, for example as slabs in the building sector and for improving plasters, mortars, insulating materials and other construction compositions, casts and/or moulds.
    Type: Grant
    Filed: August 2, 1993
    Date of Patent: March 28, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Rasp, Jan Mazanek, Ulrich von Gizycki
  • Patent number: 5360841
    Abstract: The addition of ethylene oxide/propylene oxide block copolymers containing 5 to 35 weight % of ethylene oxy groups and molar masses of the propylene glycol block between 1500 and 3000 to dry, hydraulic binder materials results in reduced dust formation, improved wettability, and enhanced flow properties of these materials when they are mixed with water.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: November 1, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernhard Knop, Horst Tamm, Gerhard Walter
  • Patent number: 5344490
    Abstract: A composition comprising gypsum plasticized by a polymer and containing gypsum in the range of about 40% to about 90% by weight. In a preferred embodiment the polymer is polyurethane. A wide variety of applications of the composition are described.
    Type: Grant
    Filed: August 24, 1993
    Date of Patent: September 6, 1994
    Assignee: Accuflex Products, Inc.
    Inventors: Peter P. Roosen, Gerard H. Koldyk, Frank Pap
  • Patent number: 5264470
    Abstract: The present invention provides set retarding additives, set retarded hydraulic cement compositions including such additives and methods of using the cement compositions for cementing zones in wells. The set retarding additives are graft polymers comprised of a backbone sugar having one or more pendant polymerized or copolymerized vinyl compounds grafted thereto.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: November 23, 1993
    Assignee: Halliburton Company
    Inventor: Larry Eoff