With Solid Polymer Derived From At Least One Reactant Wherein At Least One Of The Reactants Forming The Solid Polymer Is An Aldehyde Or Derivative; Or With Spfi Or Sicp Derived From An Aldehyde Or Derivative Wherein At Least One Of The Necessary Reactants Is Saturated Patents (Class 524/512)
  • Patent number: 11787968
    Abstract: The present invention relates to a coating composition, the coating composition comprising: a) a solution polymerised acrylic material; b) an emulsion polymerised acrylic latex material, wherein one or both of the solution polymerised acrylic material and the emulsion polymerised acrylic latex material have acid functionality; and c) a crosslinker material operable to crosslink the acid functionality on the solution polymerised acrylic material and/or emulsion polymerised acrylic latex material, the present invention also extends to a food and/or beverage package coated on at least a portion thereof with said coating composition.
    Type: Grant
    Filed: December 13, 2018
    Date of Patent: October 17, 2023
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Debra L. Singer, William H. Retsch, Jr., Dennis A. Simpson, Kam Lun Lock, Michael G. Olah, Hongying Zhou, Maria Magdalena Vladan
  • Patent number: 11739235
    Abstract: The present invention relates to a process for preparing liquid compositions of etherified melamine formaldehyde resins, namely melamine formaldehyde resins etherified with a primary C1-C6-alkanol, which have low formaldehyde contents. The invention also relates to such liquid compositions of etherified melamine formaldehyde resins having a content of free formaldehyde of less than 0.3% by weight. The liquid compositions of etherified melamine formaldehyde resins are useful as crosslinking agents in coating compositions.
    Type: Grant
    Filed: December 20, 2017
    Date of Patent: August 29, 2023
    Assignee: BASF SE
    Inventors: Stephan Weinkoetz, Dieter Weilacher, Guenter Scherr, Jens Steinbeck, Evelyn Fuchs, Ralf Strohmeier, Daniel Flojhar
  • Patent number: 11105027
    Abstract: Fabrics are provided that include mono-component staple fibers, a first group of split staple fibers comprising a first polymeric material, and a second group of split staple fibers comprising a second polymeric material that is different than the first polymeric material. The mono-component staple fibers, the first group of split staple fibers, and the second group of split staple fibers are physically entangled together to define a consolidated nonwoven. The fabrics may be physically entangled by hydroentanglement.
    Type: Grant
    Filed: October 5, 2018
    Date of Patent: August 31, 2021
    Assignee: Berry Global, Inc.
    Inventors: Herbert P. Hartgrove, Sayanti Basu, Jerry Snider
  • Patent number: 10428246
    Abstract: An adhesive composition is provided. The adhesive composition includes 3˜10 parts by weight of polyvinylidene fluoride (PVDF), wherein the polyvinylidene fluoride includes two polyvinylidene fluorides with different weight average molecular weights ranging from 20000 to 3000000, and at least one of the polyvinylidene fluorides has a carboxyl group; 0.1-0.5 parts by weight of polyvinyl butyral (PVB); and 0.1-3 parts by weight of a conductive powder.
    Type: Grant
    Filed: February 23, 2018
    Date of Patent: October 1, 2019
    Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Yi-Hsin Yuan, Wen-Bing Chu, Chang-Hsing Lu, Dar-Jen Liu
  • Patent number: 10407823
    Abstract: Composition, comprising a first component (I) comprising a polyacrylate (A1) and a wax (B), and a second component (II) comprising a polyacrylate (A2), wherein polyacrylate (A1) comprises moieties derived from (meth)acrylic acid ester monomers (M1) and (M2), and optionally (M3), CH2?CR3COO—R1??(M1) CH2?CR3COO—R2??(M2) CH2?CR3—X—R4;??(M3) wherein R1 is the alcohol moiety in monomer (M1) containing from 1 to 8 carbon atoms; R2 is the alcohol moiety in monomer (M2) containing from 9 to 40 carbon atoms; R3 is H, CH3, or C2H5; X is COO or CONH; R4 is glycidyl or CH2(CH2)n—OR5, wherein n is an integer in the range of from 1-10 and R5 is H or a residue containing from 1 to 6 carbon atoms; and polyacrylate (A2) is a fluorine-containing polyacrylate; wherein the composition is based on water and/or an organic solvent.
    Type: Grant
    Filed: July 3, 2015
    Date of Patent: September 10, 2019
    Assignee: ARCHROMA IP GMBH
    Inventors: Wolfgang Knaup, Regina Brunnmaier
  • Patent number: 10377844
    Abstract: A composition results from the mixture of at least one copolymer A resulting from the copolymerization of at least one monomer functionalized by diol functions and at least one compound A2 comprising at last two boronic ester functions. They have rheological properties which are very varied according to the proportion of the A1 and A2 compounds used. The field is that of associative and exchangeable polymers.
    Type: Grant
    Filed: January 26, 2015
    Date of Patent: August 13, 2019
    Assignees: Total Marketing Services, Ecole Superieure De Physique et de Chimie Industrielles De La Ville De Paris (ESPCI), Centre National De La Recherche Scientifique (CNRS)
    Inventors: Thi Hang Nga Nguyen, Renaud Nicolay, Lise Deves
  • Patent number: 10273366
    Abstract: An anticorrosive coating composition is provided which is excellent in adhesion to a substrate and in anticorrosiveness, and which provides a coating film whose surfaces hardly have bubbles remaining thereon even when the coating composition is applied by using a brush or a roller. The anticorrosive coating composition includes an epoxy resin (a), a curing agent (b) and a poly-?-olefin (c) that includes a structural unit derived from an ?-olefin having 6 or more carbon atoms.
    Type: Grant
    Filed: August 21, 2014
    Date of Patent: April 30, 2019
    Assignee: CHUGOKU MARINE PAINTS, LTD.
    Inventors: Takahiro Nishiguchi, Tomohisa Sumida, Shingo Wakisaka
  • Patent number: 10266707
    Abstract: A coating composition and method of making a scratch resistant UV blocking glass coating is described. The composition can include an aqueous colloidal silica. a bifunctional silanol coupling agent, tetraethylorthosilicate (TEOS), a UV absorber, and a water miscible solvent selected from glycol ethers, alkanols, keto alcohols, and combinations thereof. The molar ratio of the bi-functional silanol to TEOS is selected to provide scratch resistance coupled with water resistance.
    Type: Grant
    Filed: August 3, 2016
    Date of Patent: April 23, 2019
    Assignee: TRU VUE, INC.
    Inventors: Philip William Sherwood, Vinod Kanniah, Jean Dee Breshears
  • Patent number: 10190027
    Abstract: The object of the present invention is to provide a hot melt adhesive which is less likely to cause stringing and has excellent thermal stability, and further has excellent adhesion, in particular adhesion to a paper substrate. The present invention relates to a hot melt adhesive comprising: (A) a polar functional group-modified polymer, (B) a butyral resin, (C) an olefin-based polymer, and (D) a tackifier resin.
    Type: Grant
    Filed: August 21, 2018
    Date of Patent: January 29, 2019
    Assignee: HENKEL AG & CO. KGAA
    Inventor: Ai Takamori
  • Patent number: 10077383
    Abstract: The object of the present invention is to provide a hot melt adhesive which is less likely to cause stringing and has excellent thermal stability, and further has excellent adhesion, in particular adhesion to a paper substrate. The present invention relates to a hot melt adhesive comprising: (A) a polar functional group-modified polymer, (B) a butyral resin, (C) an olefin-based polymer, and (D) a tackifier resin.
    Type: Grant
    Filed: May 27, 2016
    Date of Patent: September 18, 2018
    Assignee: Henkel AG & Co. KGaA
    Inventor: Ai Takamori
  • Patent number: 9976050
    Abstract: The invention provides a cured product (for example, a film including the cured product) which has an excellent balance between hydrophilicity and abrasion resistance, can retain high hydrophilicity even when washed with water, and can remain hydrophilic and resistant to the attachment of (or can be easily cleaned of) contaminants even when subjected to long storage or heating, and a composition which can give such cured products. A cured product is obtained by curing a composition which includes a copolymer (i) including structural units represented by specific chemical formulae, and an amino resin (ii).
    Type: Grant
    Filed: July 28, 2015
    Date of Patent: May 22, 2018
    Assignee: MITSUI CHEMICALS, INC.
    Inventor: Koju Okazaki
  • Patent number: 9790397
    Abstract: The present invention relates to an anticorrosive coating composition comprising an epoxy resin (a), a curing agent (b), an amide wax (c), and a liquid acrylic polymer (d) including a structural unit derived from an acrylate having an alkyl group of 4 to 18 carbon atoms. The anticorrosive coating composition of the present invention can form an anticorrosive coating film that is excellent adhesion to a metal substrate, anticorrosive properties and so on.
    Type: Grant
    Filed: March 4, 2014
    Date of Patent: October 17, 2017
    Assignee: CHUGOKU MARINE PAINTS, LTD.
    Inventors: Shingo Wakisaka, Tomohisa Sumida, Naoya Nakamura
  • Patent number: 9527615
    Abstract: A packaging material for a retortable package provided with decorative artwork includes a paper layer and outer, heat-resistant plastic coatings. In order to improve the printability of the paper layer, the surface of the paper layer intended for printing is coated with a composition of pigment, adhesive or binder and a substance possessing the capability of modifying the rheological properties of the coating.
    Type: Grant
    Filed: August 5, 2011
    Date of Patent: December 27, 2016
    Assignee: TETRA LAVAL HOLDINGS & FINANCE S.A.
    Inventor: Åsa Olsson
  • Patent number: 9434844
    Abstract: Composition containing at least one poly acrylate (co)polymer binder and at least one of a condensation product formed by reaction of an effective 1-naphthol and formaldehyde, and a naphthalene molecule substituted in at least one of positions 1 to 8 with a sulfur-containing radical.
    Type: Grant
    Filed: October 12, 2012
    Date of Patent: September 6, 2016
    Assignee: INEOS EUROPE AG
    Inventors: Christopher Walls, Andrew John Bunney, Maurice Sydney Newton
  • Patent number: 9243171
    Abstract: Disclosed are pressure sensitive adhesive compositions having enhanced water resistance and adhesion properties, which compositions include 70-99 wt % of an acrylic polymer dispersion and 1-30 wt % of a polyolefin dispersion. The acrylic polymer dispersion includes (1) one or more acrylic acid ester or (meth)acrylate acid ester(s), (2) one or more hydrocarbon monomer(s), (3) one or more ethylenically unsaturated carboxylic acid(s), (4) one or more nitrile(s) or amide(s) of an ethylenically unsaturated carboxylic acid(s), (5) one or more vinyl ester(s) of a carboxylic acid(s), optionally (6) one or more nitrogen containing acetoacetoxy functional compound(s), and optionally (7) one or more mercaptan chain transfer agent(s), and the polyolefin dispersion includes one or more polyolefins, which may or may not contain acid functionality.
    Type: Grant
    Filed: November 18, 2013
    Date of Patent: January 26, 2016
    Assignee: HEXION INC.
    Inventor: Jong S. Guo
  • Patent number: 9074117
    Abstract: Disclosed are compositions that include: a) a thiol-terminated polymer; and b) a sulfur-containing ethylenically unsaturated silane. Related products, such as sealants, that include polymers derived from such compositions, are also disclosed.
    Type: Grant
    Filed: March 7, 2014
    Date of Patent: July 7, 2015
    Assignee: PRC-DeSoto International, Inc.
    Inventors: Raquel Keledjian, Renhe Lin, Chandra Rao, Bruce Virnelson
  • Patent number: 9068087
    Abstract: The present invention relates to an aqueous binder composition comprising (a) at least one emulsion polymer comprising as monomer units a C1-C8 alkyl (meth)acrylate, a vinylaromatic compound having up to 20 carbon atoms or mixtures thereof, (b) at least one water-soluble alkyd resin having a weight-average molecular weight of between 5000 and 40 000 Da, and (c) at least one alkyd resin having a weight-average molecular weight of more than 100 000 Da in the form of an aqueous emulsion, wherein the solids content of the mixture of (a), (b), and (c) is less than 60% by weight, and also to their use and preparation.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: June 30, 2015
    Assignee: BASF Aktiengesellschaft
    Inventors: Roelof Balk, Rolf Dersch, Uwe Dittrich
  • Patent number: 9056948
    Abstract: The invention relates to microcapsules, the capsule walls of which comprise a resin that can be obtained by reacting a) at least one compound selected from the group consisting of a1) amines and a2) aromatic or heteroaromatic compounds which are unsubstituted or substituted with one or more substituents from the group consisting of C1-C20-alkyl, OH, OR, COOH, SH, SR, NHCOR, OCOR, halogen, or an aromatic compound, where R is a C1-C10-alkyl group, with b) at least one aldehydic component that contains at least two carbons atoms per molecule, in the presence of c) at least one copolymer which contains units of 2-acrylamido-2-methylpropane sulphonic acid or salts (AMPS) thereof and/or 2-acrylamido-2-methylpropane phosphonic acid or salts (AMPP) thereof and units of one or more (meth)acrylates.
    Type: Grant
    Filed: March 14, 2011
    Date of Patent: June 16, 2015
    Assignee: FOLLMANN & CO. GESELLSCHAFT FUER CHEMIE-WERKSTOFFE UND VERFAHRENSTECHNIK MBH & CO. KG
    Inventors: Klaus Last, Daniel Mues
  • Publication number: 20150093952
    Abstract: The present invention provides methacrylic acid polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g. for roofing shingles, wherein the methacrylic acid polymer comprises the reaction product of at least 50 wt. %, based on the total weight of monomers used to make the methacrylic acid polymer, of methacrylic acid or its salts, or mixtures thereof, a water-soluble phosphorous or sulfur containing compound and the remainder of a carboxylic acid group containing monomer, such as acrylic acid. The methacrylic acid polymers have at least one of a phosphite group, hypophosphite group, phosphinate group, diphosphinate group, and/or sulfonate group and enable modified UF resins to have early strength development even when the binder compositions comprise from 0.1 to less than 5 wt. % of the polymer modifier, based on total solids of the UF resin and the polymer modifier.
    Type: Application
    Filed: September 30, 2014
    Publication date: April 2, 2015
    Inventors: William C. Finch, Michael D. Kelly, Sudhir M. Mulik, C. Damien Rodowski
  • Publication number: 20150093513
    Abstract: The present invention provides aqueous urea formaldehyde resin (UF resin) compositions having a pH or 7.0 or more, preferably, 8.5 or more, and comprising the UF resin modified with from 2.5 to 15 wt. %, of at least one ammonia or volatile amine neutralized carboxylic acid group containing solution polymer or alkali soluble emulsion polymer modifier, based on total UF resin and polymer solids, wherein the polymer modifier is the reaction product of 30 to 100 wt. % of methacrylic acid, acrylic acid, maleic anhydride, a salt thereof, or mixtures thereof, wherein the solution polymer has a weight average molecular weight of from 2,000 to 16,000 and the alkali soluble emulsion copolymer has a weight average molecular weight of from 1,500 to 20,000. The compositions enable the provision of untreated glass mats having improved wet web strength to prevent mat breakage in process.
    Type: Application
    Filed: September 30, 2014
    Publication date: April 2, 2015
    Inventors: Jean M. Brady, Maureen J. Finley, Drew E. Williams
  • Patent number: 8956723
    Abstract: A coating liquid for coating glass fiber cords, containing: a chlorophenol-formaldehyde condensate (A) obtained by condensing a chlorophenol (D) and formaldehyde (E) in water; an emulsion of a vinylpyridine-styrene-butadiene copolymer (B); and an emulsion of a chlorosulfonated polyethylene (C).
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: February 17, 2015
    Assignee: Central Glass Company, Limited
    Inventors: Katsuhiko Ogaki, Toshiya Monden, Takafumi Iwano
  • Publication number: 20140371362
    Abstract: Disclosed herein are self-healing materials, which are smart materials that are capable of repairing themselves without any external intervention when they are damaged. The self-healing materials may be microencapsulated, for example in a one-capsule system or a two-capsule system, and damage to a matrix containing the microcapsules may rupture the microcapsules and cause the healing materials to be released into the site of damage, where it may polymerize and restore the functional capabilities of the matrix. The self-healing materials may be based on unsaturated multi-functional resins capable of oxygen-initiated cross-linking, and may include alkyd resins, such as alkyd resins that include one or more telechelic end groups.
    Type: Application
    Filed: June 12, 2014
    Publication date: December 18, 2014
    Inventor: Gerald O. Wilson
  • Publication number: 20140272301
    Abstract: Durable, impact-resistant structural coatings with dewetting and anti-icing properties are disclosed. The coatings possess a self-similar structure with two feature sizes that are tuned to affect the wetting of water and freezing of water on the surface. Dewetting and anti-icing performance is simultaneously achieved in a structural coating comprising multiple layers, with each layer including (a) a continuous matrix; (b) porous voids, dispersed within the matrix, to inhibit wetting of water; and (c) nanoparticles, on pore surfaces, that inhibit heterogeneous nucleation of water. These structural coatings utilize low-cost and lightweight materials that can be rapidly sprayed over large areas. If the surface is damaged during use, fresh material will expose a coating surface that is identical to that which was removed, for extended lifetime.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Applicant: HRL Laboratories, LLC
    Inventors: Adam F. GROSS, Andrew P. NOWAK, William CARTER
  • Publication number: 20140243466
    Abstract: Disclosed herein are compositions comprising a polymer comprising polyetherimide, polyetheretherketone, polyamide, polyoxyalkylene, or polyalkylene terephthalate, or a mixture thereof, and ultra-high molecular weight polyethylene, wherein the ultra-high molecular weight polyethylene comprises a surface modifier. Also disclosed are articles comprising one or more of the described compositions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Application
    Filed: February 4, 2014
    Publication date: August 28, 2014
    Inventors: Reema Sinha, Susanta Mitra, Pramila Sharma, Domenico La Camera
  • Publication number: 20140220315
    Abstract: Provided are energy curable high-stretch inks and coatings for heat transfer labels. The inks and coatings include monofunctional monomers/oligomers, thermoplastic inert resins, and zero or a limited amount of multifunctional monomers/oligomers and exhibit good stretchability and surface resistance, such as scratch resistance and solvent (water, oil) resistance. Also provided are methods of using the high stretch inks in heat-transfer label (HTL) applications.
    Type: Application
    Filed: July 31, 2012
    Publication date: August 7, 2014
    Applicant: SUN CHEMICAL CORPORATION
    Inventors: Yuemei Zhang, Nicholas Tulling, Jitendra Modi, Leonard Davis, Stephen Anthony Hall
  • Publication number: 20140221554
    Abstract: The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.
    Type: Application
    Filed: April 14, 2014
    Publication date: August 7, 2014
    Applicants: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Eric Greyson, John N. Argyropoulos, Paul Foley, Andrew Swartz, Nahrain E. Kamber, Caroline Slone, Manesh N. Sekharan
  • Patent number: 8779052
    Abstract: This invention provides an effect pigment-containing, water-borne base coating composition comprising water-dispersible acrylic polymer particles (A) and effect pigment (B), the water-dispersible acrylic polymer particles (A) being obtained by emulsion polymerization of a radical-polymerizable unsaturated monomeric mixture including an amido-containing, radical-polymerizable unsaturated monomer having at least two radical-polymerizable unsaturated groups per molecule, and the effect pigment (B) being contained at a pigment weight concentration (PWC) within a range of 15-50%.
    Type: Grant
    Filed: October 6, 2006
    Date of Patent: July 15, 2014
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Hironori Tonomura, Yoshizumi Matsuno, Yasushi Nakao
  • Publication number: 20140166204
    Abstract: The invention concerns an adhesive system comprising (a) a resin component comprising a urea based amino resin having an F/NH2 ratio from 0.3 to 0.65; (b) a hardener component comprising at least one acid, acid generating salt or acidic salt; and, (c) an aqueous polymer dispersion; wherein the adhesive system comprises no or less than 0.9 wt % of urea, based on the weight of the entire adhesive system, in addition to any urea present in the urea based amino resin. The invention further concerns a method of producing a wood based product, wood based products obtainable thereby and use of the adhesive system.
    Type: Application
    Filed: July 13, 2012
    Publication date: June 19, 2014
    Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.
    Inventors: Jenny Adrian Meredith, Anna Kristina Furberb, Eugeniuez Abram, Benyahia Nasli-Bakir, Salme Pirhonen
  • Publication number: 20140018473
    Abstract: Disclosed are aqueous latex-based coating compositions which comprise a blend of an ethylene-vinyl acetate emulsion copolymer component and a selected type of acrylic emulsion copolymer component. The acrylic copolymer component comprises primarily acrylate ester co-monomers or acrylic ester co-monomers and vinyl aromatic, e.g., styrene, co-monomers. The blend of these two emulsion copolymer types also contains a specific type of hydrazine-based, water-soluble cross-linking agent which can eventually react with the acrylic emulsion copolymer component. The acrylic emulsion copolymer is one which contains minor amounts of both 1) carboxy functional co-monomers such as itaconic and/or (meth)acrylic acids, and 2) keto- or aldehyde-containing co-monomers such as diacetone acrylamide. Such latex-based coating compositions can be formulated in the form of water-based paint compositions.
    Type: Application
    Filed: December 17, 2010
    Publication date: January 16, 2014
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventors: Marc Theodorus Ratering, Rajeev Farwaha, Tara Joy Hansen
  • Publication number: 20140017006
    Abstract: A paving material for filling gaps between paving blocks or the like, the paving material comprising a powdered or granulated mixture of: inert particulate; a water-soluble resin formable from a polymerisation reaction between formaldehyde and an at least difunctional nucleophile; and a water-soluble acid. The paving material is filled into gaps between blocks and then liquid water is applied thereto, or the sand is exposed to ambient humidity (gaseous water). Upon contact with the water, the resin coats the sand and then sets hard, thereby stabilising the block paving.
    Type: Application
    Filed: March 21, 2012
    Publication date: January 16, 2014
    Inventors: John Thomas Liddy, Paul Andrew Darby
  • Publication number: 20140014267
    Abstract: The invention relates to an improved two component adhesive system, a kit comprising said two adhesive components, its use and a method for production of interior wood products, in particular form-pressed products, parquet floor elements and solid wood panels with very low formaldehyde emission and to the interior wood products obtainable having improved properties. The two-component adhesive system comprises adhesive component I comprising a 50-70 wt % melamine-formaldehyde (MF) type resin in 25-40 wt % water and adhesive component II comprising 25-40 wt % of a water based dispersion adhesive, 15-40 wt % of a formaldehyde scavenger and an acidic compound in an amount such that the pH of adhesive component II is 1.5-6.5, wherein adhesive component I and II are to be applied in a weight ratio I:II of 1:0.5 to 1:1.5 and the adhesive system has a molar ratio of formaldehyde (F) to total amino group (F/NH2) between 0.2 and 0.7.
    Type: Application
    Filed: February 4, 2013
    Publication date: January 16, 2014
    Applicant: DYNEA AS
    Inventors: Astrid PEDERSEN, Kristin GROSTAD, Per SANDBAKKEN
  • Publication number: 20130323451
    Abstract: The present invention relates to a molding composition, molded parts obtainable therefrom as well as the use of the molding composition for the manufacturing of molded parts used in the automotive industry, as well as for cables, pipes, tubes, corrugated pipes, fuel pipes, air pipes, fuel hoses, break hoses, air hoses, hydraulic hoses, pneumatic hoses, pressure hoses, and connection assemblies.
    Type: Application
    Filed: October 14, 2011
    Publication date: December 5, 2013
    Applicant: Ticona GmbH
    Inventors: Oliver Jünger, Kirsten Markgraf
  • Publication number: 20130302575
    Abstract: The present invention describes a method for building models in layers, wherein a first material and subsequent thereto selectively a second material are applied in layers in a build space, and these two application steps are repeated until a desired model is obtained. The two materials form a solid object in a suitable mixing ratio, the first material including a particulate material and the second material being applied with the aid of a print head. The first material, the second material and/or the particulate material include one or more diamines and/or one or more dicarbonyl compounds as the binder.
    Type: Application
    Filed: December 7, 2011
    Publication date: November 14, 2013
    Applicants: VOXELJET TECHNOLOGY GMBH, TECHNISCHE UNIVERSITAT MUNCHEN
    Inventors: Florian Mögele, Imke Nora Kellner
  • Publication number: 20130253100
    Abstract: Embodiments of the invention blend polyethylene (PE), polypropylene (PP), and polystyrene (PS) with calcium carbonate (CC) or other filler(s) to form a single or multi-layer plastic film. The result is an improved plastic film that retains the beneficial properties of conventional plastic films, but can also be easily fractured and creased. Embodiments of the invention also provide a method for manufacturing the single or multi-layer plastic film.
    Type: Application
    Filed: March 23, 2012
    Publication date: September 26, 2013
    Inventors: Robert D. Bailey, Benjamin C. Tran, Frank F. Su, Jack Randal Wilkerson
  • Patent number: 8524825
    Abstract: A composition for forming a peelable coating, the composition comprising an aqueous carrier, a water-dispersible polyvinyl butyral, and an acrylic latex compound.
    Type: Grant
    Filed: January 15, 2008
    Date of Patent: September 3, 2013
    Assignee: Valspar Sourcing, Inc.
    Inventors: James A. Register, Ted R. Best
  • Publication number: 20130217824
    Abstract: The invention relates to a coating composition comprising a reaction product UA of at least one multifunctional aldehyde A with at least one cyclic urea U, and a crosslinkable resin having at least one kind of functional groups selected from the group consisting of hydroxyl functional groups, acid functional groups, amide functional groups, amino functional groups, imino functional groups, mercaptan functional groups, phosphine functional groups, and carbamate functional groups, characterised in that the degree of etherification, measured as the ratio <<(-0-R)/<<(U) of the amount of substance n(-O-R) of alkoxy groups as substituents of the aldehyde carbon atoms of the multifunctional aldehyde chemically bound in the reaction product UA to the amount of substance <<(U) of cyclic urea U chemically bound in the reaction products, is less than 0.01 mol/mol, and to a process for the preparation of the reaction product UA.
    Type: Application
    Filed: September 23, 2011
    Publication date: August 22, 2013
    Inventors: Ram Gupta, Lawrence Flood, Urvee Treasurer, Barry Lawless, Colin Brogan
  • Publication number: 20130203929
    Abstract: The invention relates to a reaction product UA of at least one cyclic urea U and at least one multifunctional aldehyde A which reaction product has as substituents on the carbonyl carbon atoms of the aldehyde A at least one kind of functional groups selected from the group consisting of hydroxyl groups —OH and alkoxy groups —OR characterised in that the groups —OR comprise at least two kinds of alkoxy groups —OR1 and —OR2, where R1 and R2 are both selected from the group consisting of linear, branched or cyclic alkyl groups having from one to twelve carbon atoms, where R1 and R2 may be the same or may be different from each other, to a process of making these, and to a method of use as crosslinker in coating compositions.
    Type: Application
    Filed: September 23, 2011
    Publication date: August 8, 2013
    Inventors: Ram B. Gupta, Lawrence A. Flood, Urvee Y. Treasurer, Barry A. Lawless, Colin Brogan
  • Publication number: 20130189442
    Abstract: This invention relates to a process to make a reaction product UA of at least one multifunctional aldehyde A with at least one cyclic urea U, by mixing the at least one multifunctional aldehyde A with the at least one cyclic urea U in the presence of at least one alcohol R1—OH, and optionally, at least one solvent that has no reactive groups which may react with aldehyde groups, —CO—NH— groups, or hydroxyl groups, to effect an addition reaction to obtain a solution of a product UA, where R1 is selected from the group consisting of linear, branched or cyclic alkyl groups having from one to twelve carbon atoms, to the reaction product obtained by this process, and to a method of use thereof as crosslinker for coating compositions.
    Type: Application
    Filed: September 23, 2011
    Publication date: July 25, 2013
    Inventors: Ram B. Gupta, Lawrence A. Flood, Urvee Y. Treasurer, Barry A. Lawless, Colin Brogan
  • Publication number: 20130172472
    Abstract: The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.
    Type: Application
    Filed: December 27, 2012
    Publication date: July 4, 2013
    Applicants: Rohm and Haas Company, Dow Global Technologies LLC
    Inventors: Dow Global Technologies LLC, Rohm and Haas Company
  • Publication number: 20130137811
    Abstract: Described herein are compositions comprising (a) 92 to 99 weight percent, of polyoxymethylene with number average molecular weight from 65,000 to 250,000 g/mole; and (b) 1 to 8 weight percent of an imidized acrylic resin obtained by treating an acrylic polymer with a monoalkyl amine, wherein the weight percents of a and b are based on their combined weight, and monoalkyl group has from one to five carbon atoms, the degree of imidization is 20% to 100% and the acid level is from 0 to about 2 weight percent of the imidized acrylic resin. The composition has significantly higher heat deflection temperature than the neat polyoxymethylene. Processes of increasing heat deflection temperature of POM compositions described herein by blending (a) and (b), wherein the resultant melt-mixed composition has a 200% increase or greater in time to 5% creep strain relative to the same melt-mixed composition lacking (b).
    Type: Application
    Filed: November 29, 2011
    Publication date: May 30, 2013
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Xiyun Serene Fan, Ramabhadra Ratnagiri
  • Publication number: 20130018140
    Abstract: The invention relates to N-bridged polynitrons and their use for cross-linking of unsaturated polymers, as well as a curable composition comprising (a) a N-bridged polynitron, (b) an unsaturated polymer or a mixture of polymers, wherein at least one unsaturated polymer contains unsaturated functions or functional groups which can react with the polynitron, (c) optionally fillers, (d) optionally pigments, (e) optionally additives such as plasticizers, stabilizers, photoinitiators, and (f) optionally, other cross-linking agents such as polyisocyanates, bisdienes, polyoxaziridines, and their use as adhesives, rubber, filling, sprayable thick-layer filler, ink, paint, powder paint, waterborne paint or solvent based paint. Further, the invention relates to cross-linking products obtainable by curing the curable composition according to the present invention.
    Type: Application
    Filed: December 21, 2010
    Publication date: January 17, 2013
    Inventors: Marcus Dickmeis, Hakan Cinar, Helmut Ritter
  • Publication number: 20120201965
    Abstract: The present invention relates to multi-phase self-stratifying coating systems, and in particular, to multi-phase self-stratifying coating systems having a substantially homogeneous composition of polymeric binder components that upon application and cure generates a multi-phase stratified coating wherein each phase is rich in a different polymeric binder component and wherein individual phases are separated by a diffuse interface, such that the stratified coating exhibits a gradient behavior wherein a given interface exhibits the attributes of the polymeric binder component that is rich at that interface, and wherein at least one phase is rich in a polymeric binder having a telechelic resin with reactive internal groups, reactive end groups, and an alkoxide oligomer, and at least one other phase is rich in a polymeric binder having a fluorinated polymer derived from fluorinated vinyl-based monomers.
    Type: Application
    Filed: February 3, 2011
    Publication date: August 9, 2012
    Inventor: Mark D. Soucek
  • Publication number: 20120157588
    Abstract: The present invention relates to a molding composition, a process for the manufacturing of said molding composition, molded parts obtainable therefrom as well as the use of the molding composition for the manufacturing of molded parts used in the automotive industry, for housings, latches, window winding systems, wiper systems, sun roof systems, seat adjustments, levers, gears, claws, pivot housing or wiper arms.
    Type: Application
    Filed: October 14, 2011
    Publication date: June 21, 2012
    Applicant: TICONA GMBH
    Inventors: Kirsten Markgraf, Lowell Larson
  • Patent number: 8138247
    Abstract: Polyoxymethylene compositions comprising (a) 20 to 80 weight percent polyacetal homopolymer, copolymer, or mixtures of these; (b) 5 to 40 weight percent glass fiber; (c) 0.1 to 2 weight percent polymeric thermal stabilizer selected from the group consisting of polyacrylamide, polymethacrylamide, and mixtures of these; (d) 0.02 to 2 weight percent allantoin; and 0.1 to 5 weight percent of an ethylene copolymer of the formula E/X/Y; wherein Y includes a glycidyl group. Articles made from these compositions.
    Type: Grant
    Filed: August 27, 2009
    Date of Patent: March 20, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Kenichi Shinohara, Maiko Shibuya
  • Publication number: 20120064295
    Abstract: Cured non-woven fibrous mats, UF-based resinous binders, asphalt coated roofing material and processes for making cured non-woven fibrous mats are provided. A cured non-woven fibrous mat comprising randomly disposed fibers bound together with a resinous adhesive is provided. The mat has a caliper of less than 30 mil, an LOI of less than 18 wt. %, a hot tensile strength of at least about 60 lbs for a sample width of 2.5 inches, and an areal weight of equal to or less than about 1.8 lbs/100 ft2.
    Type: Application
    Filed: September 10, 2010
    Publication date: March 15, 2012
    Inventors: Michael W. Klett, Nancy E. Brown
  • Publication number: 20120064323
    Abstract: Fiberglass mats, binder compositions, and methods for making the same are provided. The fiberglass mat can include a plurality of glass fibers and an at least partially cured binder composition. The binder composition, prior to at least partial curing, can include a first copolymer modified by reaction with one or more base compounds. The first copolymer can include one or more unsaturated carboxylic acids, one or more unsaturated carboxylic anhydrides, or a combination thereof, and one or more vinyl aromatic derived units. The first copolymer can have a weight average molecular weight (Mw) of about 500 to about 200,000. The first copolymer can be present in an amount ranging from about 60 wt % to about 95 wt %, based on a combined weight of the first copolymer and the one or more base compounds.
    Type: Application
    Filed: September 9, 2011
    Publication date: March 15, 2012
    Applicant: GEORGIA-PACIFIC CHEMICALS LLC
    Inventors: Kelly A. Shoemake, Benjamin D. Gapud, Ramji Srinivasan, Arun Narayan, Ahmed A. Iman
  • Publication number: 20110198028
    Abstract: The invention relates to an improved two component adhesive system, a kit comprising said two adhesive components, its use and a method for production of interior wood products, in particular form-pressed products, parquet floor elements and solid wood panels with very low formaldehyde emission and to the interior wood products obtainable having improved properties. The two-component adhesive system comprises adhesive component I comprising a 50-70 wt % melamine-formaldehyde (MF) type resin in 25-40 wt % water and adhesive component II comprising 25-40 wt % of a water based dispersion adhesive, 15-40 wt % of a formaldehyde scavenger and an acidic compound in an amount such that the pH of adhesive component II is 1.5-6.5, wherein adhesive component I and II are to be applied in a weight ratio I:II of 1:0.5 to 1:1.5 and the adhesive system has a molar ratio of formaldehyde (F) to total amino group (F/NH2) between 0.2 and 0.7.
    Type: Application
    Filed: February 11, 2011
    Publication date: August 18, 2011
    Applicant: DYNEA OY
    Inventors: Astrid PEDERSEN, Kristin GRØSTAD, Per Olav SANDBAKKEN
  • Publication number: 20110123936
    Abstract: A resist pattern coating agent includes a hydroxyl group-containing resin, a solvent, and at least two compounds including at least two groups shown by a following formula (1), compounds including a group shown by a following formula (2), and compounds including a group shown by a following formula (4).
    Type: Application
    Filed: February 7, 2011
    Publication date: May 26, 2011
    Applicant: JSR Corporation
    Inventors: Masafumi HORI, Michihiro Mita, Kouichi Fujiwara, Katsuhiko Hieda, Yoshikazu Yamaguchi, Tomohiro Kakizawa
  • Publication number: 20110034618
    Abstract: A composition for forming a peelable coating, the composition comprising an aqueous carrier, a water-dispersible polyvinyl butyral, and an acrylic latex compound.
    Type: Application
    Filed: January 15, 2008
    Publication date: February 10, 2011
    Applicant: VALSPAR SOURCING, INC.
    Inventors: James A. Register, Ted R. Best
  • Publication number: 20110021669
    Abstract: The invention relates to a binder for producing materials based on wood chips and/or wood fibers. The aim of the invention is to design a binder which is used for producing and gluing materials based on wood chips and/or wood fibers, contains natural protein components, significantly reduces or even eliminates the drawbacks of the prior art, and can be economically produced and used. Said aim is achieved by a binder which is used for materials based on wood chips and/or wood fibers, comprises an aldehyde-based condensation resin and other additives, and is characterized in that the binder comprises a water-soluble reactive additive containing a peptide/amino acid mixture without moieties of water-insoluble and high-viscosity proteins. The invention also relates to a method for producing said binder as well as a molded article.
    Type: Application
    Filed: December 17, 2008
    Publication date: January 27, 2011
    Applicant: DYNEA OY
    Inventors: Hendrikus W. G. van Herwijnen, Wolfgang Heep, Andreas Weber, Axel Höhling, Maria Schultze