With Polycarboxylic Acid Or Derivative And A Polyamine, Or With Nitrogen Containing Carboxylic Acid Or Derivative Reactant At Least One Of Which Is Saturated Or With Solid Polymer Thereof Patents (Class 524/514)
  • Patent number: 6114430
    Abstract: The present invention discloses aqueous paint compositions having enhanced adhesion characteristics. The compositions contain at least one water-soluble and/or water-dispersible polyether amide comprising the reaction product of polyoxyalkylene diamines and polycarboxylic acids. The dried compositions have improved adhesion characteristics making them particularly useful protective and/or decorative coatings on substrates including wood, metal, concrete, and plastic.
    Type: Grant
    Filed: August 25, 1999
    Date of Patent: September 5, 2000
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Virginia A. Paulson, Keith W. Wiitala, Michael J. Dochniak
  • Patent number: 6096822
    Abstract: The invention provides low molecular weight polyesters and polyamides useful for flushing wet pigments and manufacturing color concentrates. More specifically, the compositions of the invention are effective for flushing wet pigments, producing pigment dispersions and then producing colored polymers with the pigment dispersions.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: August 1, 2000
    Assignee: AlliedSignal Inc.
    Inventors: Manfred K. Seven, Lawrence E. Coombs, Vincent Clarke, Joseph Wrozina, Levente L. Koller, Charles F. Lences
  • Patent number: 6096817
    Abstract: The invention relates to a polymeric blend having a major amount of an elastomeric material and a minor amount of at least one particulate polyimide. Additionally, the polymeric blend may further contain lubricants.
    Type: Grant
    Filed: June 26, 1997
    Date of Patent: August 1, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: James Francis Mc Namara
  • Patent number: 6087435
    Abstract: A polystyrene-based resin composition, comprising (A) a styrene-based resin with a mainly syndiotactic configuration, (B) a polyolefin, and (C) rubber polymer particles as main components, exhibits excellent heat resistance and impact resistance.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: July 11, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6077900
    Abstract: An aqueous dispersion containing a polyamide and non-polyamide polymer is prepared by dissolving the polyamide in an organic solvent with a surfactant to form a polyamide solution. Water is then added to the polyamide solution to form an aqueous dispersion. The non-polyamide polymer can be added before or after the addition of water. The polyamide/non-polyamide dispersion can be used to produce an ink with better adhesion to plastic substrates and reduced blocking problems.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: June 20, 2000
    Assignee: Cognis Corporation
    Inventors: Chase J. Boudreaux, Timothy Vogel, David I. Devore, Reimar Heucher, Stephen A. Fischer, Kartar S. Arora
  • Patent number: 6072024
    Abstract: A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced.
    Type: Grant
    Filed: March 17, 1998
    Date of Patent: June 6, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yoshihiro Irizato, Makoto Sukegawa, Toshio Katoh, Hiroaki Tamatani, Akinori Nagatomo, Masaru Wada
  • Patent number: 6051645
    Abstract: An ink jet recording ink comprising water, a coloring material, a water-soluble organic solvent and a plurality of dispersants each having a different HLB, and an ink jet recording method using this ink jet recording ink are disclosed. Preferably, given that respective HLBs of n (n.gtoreq.2) kinds of dispersants are such that HLB.sub.1 <HLB.sub.2 < . . . <HLB.sub.n, at least two dispersants satisfy the following formula:1.ltoreq.HLB.sub.x -HLB.sub.x-1 .ltoreq.30(wherein, X is an integer from 2 to n). The ink jet recording ink and ink jet recording method of the present invention do not clog a nozzle, have an excellent dispersion stability, discharge responsiveness and discharge stability, and provide uniform images having high resolution and high optical density stably.
    Type: Grant
    Filed: April 14, 1997
    Date of Patent: April 18, 2000
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Atsushi Suzuki, Toshitake Yui, Nobuyuki Ichizawa, Kunichi Yamashita, Ken Hashimoto
  • Patent number: 6051655
    Abstract: A composition amenable to injection molding and extrusion comprises a syndiotactic styrene resin, a thermoplastic resin such as a polyolefin and an inorganic filler optionally contains a rubber.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 18, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6037401
    Abstract: The invention relates to a flame retardant polyamide composition comprising at least one polyamide and a polymerized bromostyrene. In particular, the invention relates to polyamide compositions comprising a polymerized bromostyrene with a bromine content of more than 61% (wt).
    Type: Grant
    Filed: August 26, 1998
    Date of Patent: March 14, 2000
    Assignee: DSM N.V.
    Inventor: Johannes Tijssen
  • Patent number: 6025055
    Abstract: The invention relates to compositions comprising a matrix of an alloy of (a) polyamide and (b) polymer having polyamide blocks and polyether blocks, dispersed in which matrix is a crosslinked phase (c), the said compositions having a melt strength of more than 1.5 and a flexural modulus at 23.degree. C. (in accordance with ISO 178-93) of less than 700 MPa and preferably between 50 and 250 MPa.Such a composition is useful for manufacturing extrusion blow-moulded parts, especially for cars.It also relates to articles additionally comprising a part made of polyamide and polyolefin or of a mixture of polyamide and polyolefin.
    Type: Grant
    Filed: February 23, 1998
    Date of Patent: February 15, 2000
    Assignee: Elf Atochem,S.A.
    Inventors: Alain Bouilloux, Laurent Teze
  • Patent number: 6018000
    Abstract: Pigmented and unpigmented polymeric resin blends containing up to 45 weight percent polyvinylidene fluoride based polymer and either polyamide 11 or polyamide 12 having particular usefulness in powder coating of objects are disclosed.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: January 25, 2000
    Assignee: Elfatochem North America, Inc
    Inventors: Brian D. Keeny, Joseph L. Mitchell, David T. Wiggins
  • Patent number: 6013726
    Abstract: A polystyrene-based resin composition containing a styrene-based resin with mainly syndiotactic configuration, a polyamide, and a rubber polymer as main components.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 11, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6013719
    Abstract: Low melt viscosity polytetrafluorethylene (PTFE), i.e. having a melt viscosity of 50 to 1.times.10.sup.5 Pa.multidot.s at 372.degree. C., is combined with non-fluorinated thermally stable polymer such as polyarleneetherketone to provide melt-fabricability application for the low MV PTFE and provide improved properties for the thermally stable polymer.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: January 11, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Jacob Lahijani
  • Patent number: 6001922
    Abstract: This invention provides the preparation of water-dispersible polyester/acrylic hybrids via a two-stage emulsion polymerization process. For example, methacrylic acid and/or 2-hydroxyethyl methacrylate are copolymerized with styrene/acrylic monomers to yield a relatively hydrophilic and hydro-plasticized first stage. Subsequent additions of hydrophobic monomers to this first stage "seed" results in an inversion of the latex such that the more hydrophilic first stage is at the particle surface. This results not only in improved stability of the resulting latex without the use of additional surfactants, as evidenced by the production of reduced amounts of coagulum, while it also offers relatively low minimum filming temperatures due to the hydroplasticization of the shell of the particle. Furthermore, the use of the water-dispersible polyester results in extremely fine latex particle sizes which can significantly enhance coating properties such as film gloss and clarity.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: December 14, 1999
    Assignee: Eastman Chemical Company
    Inventors: Mark Dwight Clark, Hieu Duy Phan, James Russell Salisbury, Glen Dennis Shields
  • Patent number: 5998772
    Abstract: A system of interconnected heating conductors, suitable for preventing freezing of water lines in an aircraft for example, includes a plurality of heater units (1, 12, 14) electrically coupled together by respective extension cables (3) and electrical coupling elements (42). Each heater unit comprises one or more heating conductor bands, tapes or strips (2, 21, 22) connected to respective connection modules (5, 51, 52, 52', 53) at the ends thereof. The connection modules may connect together several heater bands within one heater unit, and may connect the terminal ends of the heater bands of one heater unit to the extension cables by which several respective heater units may be connected together. Each connection module includes a housing (6) enclosing an inner chamber (61) therein, and at least one electrical connector element (7) such as a crimpable connector fixed within the housing (6).
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: December 7, 1999
    Assignee: DaimlerChrysler Aerospace Airbus GmbH
    Inventors: Safa Kirma, Heinz Stoever, Joachim Pfeiff, Wolfgang Erdmann
  • Patent number: 5994449
    Abstract: Disclosed are resin compositions that are the reaction product of epihalohydrin with a mixture of polyaminoamide and vinyl amine polymer containing a minimum of about 1 mole % vinyl amine monomer units, wherein said polyaminoamide comprises the reaction product of dicarboxylic acid, or a derivative thereof, with polyamine selected from the group consisting of methyl bis(3-aminopropyl)amine and polyalkylenepolyamine containing from two to four alkylene groups having two to four carbons, two primary amine groups, and one to three secondary amine groups. Also disclosed are a process for creping fibrous webs utilizing the resin compositions, and creped paper prepared by the process. Also disclosed is wet and dry strength paper containing the resin compositions and processes for creping fibrous webs utilizing the resin compositions as creping adhesives.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: November 30, 1999
    Assignee: Hercules Incorporated
    Inventor: William Walter Maslanka
  • Patent number: 5965668
    Abstract: The invention relates to impact-resistant injection mouldings based on polyamide resin (A) and on a disperse phase whose particles have a number-average diameter greater than 0.4 .mu.m, a volume-average diameter greater than 1 .mu.m and such that more than 50% by volume of the particles are larger than 1 .mu.mThe disperse phase may consist of a mixture including at least one copolymer (B) of ethylene and of an unsaturated epoxide and of at least one polyolefin (C).
    Type: Grant
    Filed: April 16, 1997
    Date of Patent: October 12, 1999
    Assignee: Elf Atochem S.A.
    Inventors: Patrice Perret, Alain Bouilloux
  • Patent number: 5948880
    Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:forming a solution of a polyamide having an acid value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant, wherein at least a portion of the acid value of said polyamide is neutralized,adding sufficient water to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.
    Type: Grant
    Filed: May 8, 1997
    Date of Patent: September 7, 1999
    Assignee: Henkel Corporation
    Inventors: Stephen A. Fischer, Chase J. Boudreaux, Michael S. Wiggins
  • Patent number: 5939512
    Abstract: A composition comprising a polyamide, a polyolefinic modifier, and an ethylene/acrylic acid copolymer.
    Type: Grant
    Filed: February 28, 1998
    Date of Patent: August 17, 1999
    Assignee: AllliedSignal Inc.
    Inventors: Jay A. Gervasi, Harold W. Tuller, Wesley F. Smith, Charles W. Alpaugh
  • Patent number: 5928782
    Abstract: A hot melt useful for packaging, comprising from about 10% to about 30% by weight of at least one copolymer of ethylene and methyl acrylate (both acrylates and methacrylates); from about 10% to about 20% by weight of at least one copolymer of ethylene and n-butyl acrylate (both acrylates and methacrylates), wherein the total polymer content does not exceed 40% by weight, and the total ethylene n-butyl acrylate copolymer content does not exceed the total ethylene methyl acrylate copolymer content by percent weight in the adhesive; from about 20% to about 60% by weight of at least one tackifying resin selected from the group consisting of rosins and modified rosins and hydrogenated derivatives; aliphatic, cycloaliphatic and aromatic hydrocarbon resins and modified hydrocarbon resins and hydrogenated derivatives; terpenes and modified terpenes and hydrogenated derivatives; and mixtures thereof; from about 5% to about 30% by weight of at least one wax; and up to about 2% by weight of an antioxidant; wherein the r
    Type: Grant
    Filed: November 15, 1996
    Date of Patent: July 27, 1999
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventor: Steven W. Albrecht
  • Patent number: 5925712
    Abstract: A coating composition which encompasses an aqueous dispersion of from about 2 to about 40 percent by dry weight, based on the dry weight of the coating composition, of a cationic polymer; and from about 60 to about 98 percent by dry weight, based on the dry weight of the coating composition, of a nonionic or cationic binder. The coating composition is thermally fusible and adapted to be receptive to ink jet inks and to retain the ink jet inks after being thermally fused. Alternatively, the coating composition may encompass an aqueous dispersion of a powdered thermoplastic polymer and from about 10 to about 150 dry parts by weight of a binder, based on 100 dry parts by weight of the powdered thermoplastic polymer.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: July 20, 1999
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventor: Francis Joseph Kronzer
  • Patent number: 5922831
    Abstract: A polyamide resin comprising the reaction product obtained by the reaction of an acid component comprised of a major concentration of a dimer acid and minor concentration of a monobasic acid and an amine component comprised of a major concentration of a short-chain alkylenediamine, a first minor concentration of a medium-chain alkylenediamine and second minor concentration of a polyoxyalkylene diamine having a molecular weight greater than about 500 is provided. The polyamide resin is used to form a blend of containing the polyamide in a major amount by weight and a first minor amount by weight of a polar wax and a second minor amount by weight of a polyolefin elastomer. The composition is used to reinforce a footwear upper, e.g. as a print on box toe material.
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: July 13, 1999
    Inventors: Dwight D. Heinrich, Reimar Heucher, Sandra Drahos
  • Patent number: 5907010
    Abstract: Graft copolymers are obtainable by reactingA) polyarylene ethers,B) polyamides andC) copolymers which contain cyclic, .alpha.,.beta.-unsaturated dicarboxylic anhydridesand are used for the preparation of thermoplastic molding materials or as compatibilizers for polymer blends based on polyarylene ethers and polyamides.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: May 25, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Norbert Guntherberg
  • Patent number: 5900453
    Abstract: A heat-resistant, lubricative resin composition which can withstand temperatures of 250-270.degree. C., which is wear-resistant and low in friction, and which is less likely to attack a soft alloy such as aluminum alloy, and a high-performance, heat-resistant sliding bearing formed from the abovementioned heat-resistant, lubricative resin composition.
    Type: Grant
    Filed: July 9, 1996
    Date of Patent: May 4, 1999
    Assignee: NTN Corporation
    Inventors: Masaki Egami, Takumi Shimokusuzono, Hideyuki Tsutsui, Sadatoshi Inagaki
  • Patent number: 5886097
    Abstract: Thermoplastic resin compositions consisting of 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, further containing (C) 0.1-10% of a modified vinyl polymer containing carboxyl groups, are permanently antistatic, excellent in mechanical properties represented by impact resistance, heat resistance moldability and also in the appearance and gloss of the moldings, and suitable for housings of optical or magnetic recording media.
    Type: Grant
    Filed: September 17, 1997
    Date of Patent: March 23, 1999
    Assignee: Toray Industries, Inc.
    Inventors: Tadao Fukumoto, Masatoshi Iwamoto, Akihiko Kishimoto
  • Patent number: 5886094
    Abstract: There is provided a thermoplastic resin composition which has damping property, mechanical strength, impact resistance and heat stability resistance in well-balance proportion and has excellent workability, and the composition comprising the following components (A) to (E), in which the ratio by weight of (A)/(B) is from 1/99 to 80/20, the content of the component (C) is from 1 to 50 parts by weight based on 100 parts by weight of the total amount of the components (A) and (B), the content of the component (D) is sufficient amount to compatibilize the components (A) and (B), and the content of the component (E) is from 1 to 120 parts by weight based on 100 parts by weight of the total amount of the components (A) and (B):(A): polyphenylene ether,(B): polyamide,(C): conjugated diene-alkenyl aromatic compound copolymer in which not less than 50% of the conjugated diene compound is polymerized by 1,2-bond or 3,4-bond and the tan .delta. peak temperature thereof is not less than -20.degree. C.
    Type: Grant
    Filed: April 9, 1997
    Date of Patent: March 23, 1999
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Takashi Sanada, Mitsuyoshi Shimano
  • Patent number: 5886100
    Abstract: The thermosetting coating composition in a powdery form, includes (a) a binder resin prepared by the steps comprising preparing a starting material monomer mixture of two different polymerization reactions, each of the polymerization reaction being carried out in an independent reaction path, and then concurrently carrying out both of the two different polymerization reactions in one reaction vessel; (b) a colorant; and (c) a crosslinking agent. The coating film is prepared by curing the above thermosetting coating composition.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: March 23, 1999
    Assignee: KAO Corporation
    Inventors: Katsutoshi Aoki, Yukiya Sato, Masayuki Maruta, Yasunori Inagaki, Kuniyasu Kawabe
  • Patent number: 5883172
    Abstract: A composition of matter useful as a hotmelt adhesive is provided. The composition is comprised of a polyamide based on dimerized fatty acid and having an amine value higher by at least two units than the acid value of said polyamide and a filler comprised of a carbonate. The filler is preferably comprised of fine particles of calcium carbonate. The adhesive is particularly useful for bonding metals, e.g. to plastics and the bonding of cables with multilayer sheaths, e.g. in optical cables and power cables.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: March 16, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Reimar Heucher, Siegfried Kopannia, Ulrike Maassen
  • Patent number: 5877235
    Abstract: The aqueous ink of the present invention comprises a suspension of a polymer, preferably a polyester or a polyester polyamide, having adsorbed a dye or a pigment, wherein the surface tension (.gamma.) and the viscosity (.eta.) of the ink at 20.degree. C. and the average particle size (d) of the suspended particles satisfy the following inequality (1):0.1.ltoreq..gamma..multidot..eta..multidot.d.ltoreq.11 (1)wherein the units of the parameters .gamma., .eta. and d are dyne/cm, cps, and .mu.m, respectively.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: March 2, 1999
    Assignee: Kao Corporation
    Inventors: Tadashi Sakuma, Tetsuya Ueno, Kuniyasu Kawabe
  • Patent number: 5866658
    Abstract: Blends of highly-neutralized ionomers of copolymers of ethylene and high weight percentages of .alpha.,.beta.-ethylenically-unsaturated C.sub.3 -C.sub.8 carboxylic acids dispersed in a continuous or co-continuous polyamide phase are provided and a process for making such blends. The blends are particularly useful in applications such as molded parts where toughness, high gloss, abrasion/scratch (mar) resistance, UV resistance, high temperature properties and stiffness are desired.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: February 2, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Charles John Talkowski
  • Patent number: 5866648
    Abstract: A long fiber-reinforced polymer alloy resin composition (C) is provided which is obtained by blending a master batch (A) containing a long fiber reinforcement (a2) having a length of 3 to 30 mm in a resin matrix of a polyamide resin (a1), with a substantially polymer-alloyed resin diluent (B) obtained by melt kneading 45 to 20% by weight of a crystalline polyolefin resin (b1) and 55 to 80% by weight of a polyamide resin (b2), the crystalline polyolefin resin (b1) containing a modified olefin crystalline polymer (b11) having been substantially modified with unsaturated carboxylic acids. In this resin composition (C), the amount of the long fiber reinforcement (a2) is in the range of 10 to 60% by weight, and the amount of the crystalline polyolefin resin (b1) in resin components ((a1)+(b1)+(2)) other than the long finer reinforcement (a2) is in the range of 20 to 45% by weight. This resin composition (C) is excellent in tensile strength and particularly excellent in repeated impact resistance properties.
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: February 2, 1999
    Assignee: Chisso Corporation
    Inventors: Koichi Saito, Takashi Shimpuku, Rikio Yonaiyama
  • Patent number: 5849824
    Abstract: The invention provides for a thermoset or thermoplastic gel composition containing a polymer with anhydride groups along the polymer backbone at least at outset of the fabrication process and an extender fluid, optionally including thermally conductive fillers. The gel compositions are useful for sealing wires, vibration dampening, sporting goods, and toys.
    Type: Grant
    Filed: February 6, 1996
    Date of Patent: December 15, 1998
    Assignee: Raychem Corporation
    Inventors: Frank Mercer, Hendrik Graulus
  • Patent number: 5847042
    Abstract: A polyolefin resin composition of the present invention comprising 0.01 to 2.0 parts by weight of an anti-blocking agent per 100 parts by weight of a polyolefin resin, wherein said anti-blocking agent has substantially two or more maximum values in a weight-based particle size distribution and a difference between a particle diameter giving the largest maximum value and a particle diameter giving the smallest maximum value is not less than 3.0 .mu.m.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: December 8, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoru Hosoda, Satoru Koyama, Kenzo Chikanari
  • Patent number: 5837754
    Abstract: Ink for an ink-jet printer of the present invention includes polyester particles colored with a colorant which are dispersed in an aqueous medium.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: November 17, 1998
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Tetsuo Shimomura, Satoshi Maeda, Yozo Yamada
  • Patent number: 5830940
    Abstract: The present invention relates to a shaped article of a liquid crystalline polymer containing (A) 100 parts by weight of a liquid crystalline polyester and/or liquid crystal polyesteramide capable of forming an anisotropic melt and (B) 0.01 to 2 parts of an olefinic polymer and having a retention rate of a weld strength of 15% to 100%, which has excellent heat stability, mechanical properties, dimensional stability and mold releasability and is suitable for various application uses such as electrical and electronical related devices, accurate machine related devices, office related devices, automobile related parts.
    Type: Grant
    Filed: July 18, 1996
    Date of Patent: November 3, 1998
    Assignee: Toray Industries, Inc.
    Inventors: Kiyokazu Nakamura, Norio Kitajima, Toshihide Inoue
  • Patent number: 5821319
    Abstract: A sliding material and a heat resistant filament which primarily comprises a liquid crystal polyimide, a liquid crystal polyamide or a liquid crystal polyamide-imide copolymer having at least one recurring structural unit selected from the formula (1) and the formula (2) and is excellent in heat resistance, mechanical characteristics and other fundamental properties of polyimides, and relates to significant improvement of heat-resistance by heat-treating the sliding material, the filament and the molded items. The liquid crystal polyamide-imide copolymer which comprises in a polymer molecule 0.05.about.0.95 mole ratio of the recurring structural units of the formula (1) and 0.95.about.0.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: October 13, 1998
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Atsushi Shibuya, Yuichi Okawa, Shoji Tamai, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5807920
    Abstract: The present invention provides a retainer made of synthetic resin for a rolling-contact element such as a roller of a rolling-contact bearing or a one-way clutch, which is used in a lubricating oil. The retainer comprises an aliphatic polyamide resin as a matrix and a hydrocarbon polymer having no oil resistance and good compatibility with the matrix, which is dispersed in the matrix. Examples of the thermoplastic hydrocarbon polymer include olefin polymer and styrene polymer.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: September 15, 1998
    Assignee: Koyo Seiko Co., Ltd.
    Inventors: Hiroshi Ueno, Akira Yamamoto, Megumi Ohtani, Tadahiro Terada
  • Patent number: 5807968
    Abstract: A polyamide resin comprising the reaction product obtained by the reaction of an acid component comprised of a major concentration of a dimer acid and minor concentration of a monobasic acid and an amine component comprised of a major concentration of a short-chain alkylenediamine, a first minor concentration of a medium-chain alkylenediamine and second minor concentration of a polyoxyalkylene diamine having a molecular weight greater than about 500 is provided. The polyamide resin is used to form a blend of containing the polyamide in a major amount by weight and a first minor amount by weight of a polar wax and a second minor amount by weight of a polyolefin elastomer. The composition is used to reinforce a footwear upper, e.g. as a print on box toe material.
    Type: Grant
    Filed: April 4, 1996
    Date of Patent: September 15, 1998
    Assignee: Henkel Corporation
    Inventors: Dwight D. Heinrich, Reimar Heucher, Sandra Drahos
  • Patent number: 5804682
    Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:forming a solution of a polyamide having an acid value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant, wherein at least a portion of the acid value of said polyamide is neutralized,adding sufficient water to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: September 8, 1998
    Assignee: Henkel Corporation
    Inventors: Stephen A. Fischer, David I. Devore, Kartar S. Arora, Reimar Heucher, Michael S. Wiggins, Chase J. Boudreaux, Dwight D. Heinrich
  • Patent number: 5798407
    Abstract: A hydrophilic resin composition comprising a water-absorptive resin (component A), a thermoplastic modified ethylene polymer (component B), and, if desired, a thermoplastic polymer (component C) which is different from the component B, the water-absorptive resin (component A) being present in an amount of 0.1 to 70% by weight of the total amount of the components A to C, the component A being uniformly dispersed in the thermoplastic polymers (components B+C), in the form of particles having an average particle diameter of 5 .mu.m or less.A process for producing a hydrophilic resin composition, comprising kneading a water-absorptive resin containing water (component A) whose water content is 25 to 80% by weight to obtain a rubber-like resin, incorporating a modified ethylene polymer (component B), and, if desired, a thermoplastic polymer (component C) and an additive (component D) into the rubber-like resin, and melt kneading the mixture.
    Type: Grant
    Filed: October 22, 1996
    Date of Patent: August 25, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kazunori Yano, Hiroyoshi Kaito, Akeharu Wakayama, Shuhei Yada
  • Patent number: 5789529
    Abstract: A polyamide resin composition comprising: (A) 100 parts by weight of at least one member selected from a polyamide-11 resin and a polyamide-12 resin; optionally (B) from 3 to 30 parts by weight of a modified polyolefin resin; and (C) from 3 to 25 parts by weight of a plasticizer mixture comprising a plasticizer (C1) and a plasticizer (C2). The modified polyolefin resin (B) is either a modified polyolefin (B1) which is a copolymer of an olefin comprising at least one of ethylene and propylene, with an .alpha.,.beta.-unsaturated carboxylic acid or a derivative thereof, or a modified polyolefin (B2) which is a graft polymer obtained by grafting an .alpha.,.beta.-unsaturated carboxylic acid or a derivative thereof onto a copolymer of an olefin comprising at least one of ethylene and propylene. The plasticizer (C1) has a solidifying point of -40.degree. C.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: August 4, 1998
    Assignee: UBE Industries, Ltd.
    Inventors: Takenobu Matsumura, Noriyuki Isobe, Kanzou Tabata, Satoshi Kotera
  • Patent number: 5789083
    Abstract: An aqueous fluoropolymer primer useful for coating smooth substrates is provided. The primer contains two fluoropolymer resins of differing melt viscosities and a binder which is a polyamide imide and a polyphenylene sulfide at a weight ratio in the range of 3:1 to 1:3.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: August 4, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Philippe Andre Fernand Germain Thomas
  • Patent number: 5767186
    Abstract: Compositions for a tip seal for a scroll type compressor are proposed which are low in friction coefficient, high fluidity in a molten state and highly durable in a compressor using a substitute Freon. The composition comprises 2-10 wt % of fluororesin, 5-20 wt % of carbon fiber, and 75-93 wt % of polyphenylene sulfide resin containing 90 mol % or more of a repeating unit represented by the formula: ##STR1## The composition has a melt viscosity of 1200-3000 poise. Also, a method of manufacturing a plurality of such tip seals simultaneously is proposed.
    Type: Grant
    Filed: May 8, 1997
    Date of Patent: June 16, 1998
    Assignee: NTN Corporation
    Inventors: Takumi Shimokusuzono, Jiro Matsumoto
  • Patent number: 5750616
    Abstract: A fiber-reinforced thermoplastic resin composite material comprises a thermoplastic resin, 5 to 80% by weight of a fiber reinforcing material having an average diameter ranging from 3 to 21 .mu.m and an average length ranging from 0.3 to 30 mm, and 0.01 to 5% by weight of carbon black whose aggregate size upon primary cohesion is not more than 60 nm. The composite material permits effective prevention of any snapping of glass fibers for reinforcement in molded articles which are colored black or gray due to the contribution of the carbon black having a specific aggregate size incorporated into the resin along with the fiber reinforcing material. Therefore, the composite material can provide molded articles excellent in mechanical strength, for instance, all of tensile strength, flexural strength and Izod impact strength.
    Type: Grant
    Filed: March 27, 1996
    Date of Patent: May 12, 1998
    Assignee: Chisso Corporation
    Inventors: Takashi Shimpuku, Nobukazu Atsumi
  • Patent number: 5741845
    Abstract: The invention concerns a process for the production of block copolymers or aqueous dispersions and emulsions thereof, whereby azo macroinitiators are reacted with radical-polymerizable monomers or a mixture of several radical-polymerizable monomers. The azo macroinitiators are obtained by reacting simple reactive azo compounds with prepolymers with a molecular weight between 400 and 20000, which possess at least 2 functional groups, e.g. polyurethanes or polyesters.The aqueous block copolymer dispersions and emulsions produced according to the invention are suitable for use for the production of paints, adhesives etc.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 21, 1998
    Assignee: Dainippon Ink & Chemicals Inc.
    Inventors: Rainer B. Frings, Shigeru Komazaki, Gerwald F. Grahe
  • Patent number: 5741828
    Abstract: The present invention is directed to a coating composition which includes a component A and component B. Component A is either an emulsion or dispersion having a hydrophobic elastomer stabilized with at lease one emulsifier. Component B is a dispersion or solution of a hydrophilic polymer which is insoluble in water, swellable in water and soluble in one or more water-miscible solvents. The hydrophobic elastomers may be polymers or copolymers of butadiene, isoprene, chloroprene, styrene, acrylonitrile, ethylene, propylene, isobutylene, alkylacrylates and alkylmethacrylates; polyrethanes, polyureas, polysiloxanes, elastomeric polyamides and polyesters. The hydrophilic polymers may be segmented polyurethanes, segmented polyures, segmented polyesters, partially hydrolyzed poly(vinyl acetate), partially hydrolyzed polyacrylonitrile, partially aminolyzed polyacrylonitrile, and ethylene glycol monomethacrylate.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: April 21, 1998
    Assignee: S.K.Y. Polymers, Inc.
    Inventors: Vladimir A. Stoy, Gerald A. Gontarz, Jr.
  • Patent number: 5693698
    Abstract: A composition is provided which comprises an acrylamide-containing polymer comprising repeat units derived from at least two monomers, a polypropylene glycol, and optionally, a polysaccharide. Also provided is a water-based composition which can be used as drilling fluid wherein the composition comprises calcium chloride, an acrylamide-containing polymer which has repeat units derived from at least two monomers, a polypropylene glycol, and optionally, a polysaccharide.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: December 2, 1997
    Assignee: Phillips Petroleum Company
    Inventors: Bharat B. Patel, T. George Muller
  • Patent number: 5686507
    Abstract: High friction coatings, compositions for producing such coatings, and non-skid coatings for ships and decks are disclosed. Included are compositions comprising a curable resin, a filler, and aramid in the form of fibers or flakes.
    Type: Grant
    Filed: August 3, 1994
    Date of Patent: November 11, 1997
    Assignee: The Morgan Crucible Company p.l.c.
    Inventors: Jules J. Hermele, David P. Robinson
  • Patent number: 5684122
    Abstract: A transparent N-alkyl-substituted maleimide/olefin copolymer composite material is provided which comprises 100 parts by weight of an N-alkyl-substituted maleimide/olefin copolymer, and 0.1 to 100 parts by weight of phyllosilicate, the phyllosilicate being dispersed uniformly and finely in a matrix of the N-alkyl-substituted maleimide/olefin copolymer. A process for producing the N-alkyl-substituted maleimide/olefin copolymer composite material is also provided. The N-alkyl-substituted maleimide/olefin copolymer composite material is excellent in transparency, heat resistance, rigidity, and dimensional stability.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: November 4, 1997
    Assignee: Tosoh Corporation
    Inventors: Hiroshi Inoue, Toru Doi
  • Patent number: 5684075
    Abstract: A composition is provided which comprises an acrylamide-containing polymer comprising repeat units derived from at least two monomers, a polypropylene glycol, and optionally, a polysaccharide. Also provided is a water-based composition which can be used as drilling fluid wherein the composition comprises calcium chloride, an acrylamide-containing polymer which has repeat units derived from at least two monomers, a polypropylene glycol, and optionally, a polysaccharide.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: November 4, 1997
    Assignee: Phillips Petroleum Company
    Inventors: Bharat B. Patel, T. George Muller