Solid Polymer Derived From Nitrogen Heterocycle Monomer Patents (Class 524/516)
  • Patent number: 5356985
    Abstract: The present invention relates to aqueous emulsions of polymers which contain 80 to 100 weight % of acrylonitrile polymerized within them, to a method for their preparation, and to their use as raw materials for acrylic and modacrylic fibres and as dyeing additives for adjusting the dyestuff affinity of cationic dyestuffs for conventional acrylic and modacrylic polymers and fibre materials produced from them.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: October 18, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Sackmann, Siegfried Korte, Heinrich Alberts, Rolf-Volker Meyer
  • Patent number: 5338490
    Abstract: A two-phase composite of ionically-conductive pressure-sensitive adhesive, biomedical electrodes using the composite and methods of preparing the composite and the electrode are disclosed. The continuous phase is a hydrophilic, solid state pressure-sensitive adhesive composition ionically-conductive regardless of an amount of water present in the composition. The discontinuous phase are domains of a hydrophobic pressure-sensitive adhesive which enhances adhesion of the composite to mammalian skin while maintaining acceptable alternating current impedance of the composite.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: August 16, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Timothy M. Dietz, Robert A. Asmus, Rosa Uy
  • Patent number: 5331022
    Abstract: For the reduction of the radon load in enclosed spaces, an aqueous, solvent and softener-free dispersion of a vinylidene chloride-acrylate-copolymer is applied to the boundary surfaces of the room and left to dry. The dispersion contains also a nonionic surfactant on a base of alkylphenolethoxylate with a proportion of 10 mole ethylene oxide, a vinyl pyrrolidone-copolymer and a defrothing agent.
    Type: Grant
    Filed: October 1, 1992
    Date of Patent: July 19, 1994
    Assignee: Hesco AG, Industrieconsulting & Industrievertretungen
    Inventors: Ludwig Jochmann, Josef Hess
  • Patent number: 5324770
    Abstract: The present invention comprises block copolymers of alkylene oxides, such as ethylene oxide and propylene oxide, which are further formulated with additional polymers such as poly(N-vinylpyrrolidinone), poly (vinyl alcohol), and certain low foam additives. These polymers are useful for the coating of alumina powders for use in ceramics. In aqueous media, their lower viscosities enable facile spray drying of the coated alumina powders. The coated alumina powders may be compressed under relatively low pressure into high density forms with superior unfired compressive strengths (green strength), they are surprisingly insensitive to relative humidity, are readily ejected from the mold, and finally do not have a deleterious effect upon the ultimate high temperature sintering of the formed bodies.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: June 28, 1994
    Assignee: Nalco Chemical Company
    Inventor: David R. Cosper
  • Patent number: 5294662
    Abstract: Novel polymers are disclosed which can be used to prepare water-based compositions are disclosed having the capability of forming a uniform, low surface-energy, thin film on a substrate. Such compositions comprise a polymer having at least one fluoroaliphatic moiety and at least one anionic moiety, and a novel polymer having at least one fluoroaliphatic moiety and at least one oxazoline moiety.
    Type: Grant
    Filed: April 15, 1993
    Date of Patent: March 15, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: George G. I. Moore, Dong-Wei Zhu
  • Patent number: 5281638
    Abstract: An aqueous adhesive composition containing a chlorosulfonated polyethylene latex, a polymaleimide compound, a nitroso compound and a metal oxide. The adhesive composition can be effectively utilized without a primer component and exhibits an unusually high resistance to pre-bake conditions and adverse environments. The adhesive also possesses the ability to effectively bond a variety of substrates.
    Type: Grant
    Filed: April 23, 1993
    Date of Patent: January 25, 1994
    Assignee: Lord Corporation
    Inventor: Douglas H. Mowrey
  • Patent number: 5281674
    Abstract: A crosslinkable resin composition containing:(A) from 10% to 90% by weight of a thermoplastic resin component,(B) from 90% to 10% by weight of a curable resin component, comprising, expressed by reference to the curable resin (100%),(i) 50% to 95% of a (meth)acryloyl derivative, and(ii) 50% to 5% of a (meth)allyloxy derivative, and(C) from 0% to 30% by weight of a plasticiser for the thermoplastic resin component, is disclosed.Also a new crosslinked resin layer and a process for the manufacture of the new crosslinked resin layer on a substrate are described.The crosslinked resin layer herein exhibits a desirable balance between flexibility, resistance to stain and resistance to scuff properties, in combination with outstanding mechanical and chemical properties.The crosslinkable resin composition is particularly suitable for coating application of various substrates such as flooring materials, wall covering materials, coils, wires, and various shaped articles e.g. cars, containers and metallic profiles.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: January 25, 1994
    Assignee: Monsanto Company
    Inventors: Adolf A. Klaiber, Johannes F. H. Courtier, Daniel Gaeckle
  • Patent number: 5270358
    Abstract: A composite of a gel of swollen hydrocolloid dispersed in a pressure sensitive adhesive matrix is provided. The gel has a natural or synthetically derived hydrocolloid swollen with a non-volatile swelling agent, such that the gel may have a shear modulus of less than 6.2.times.10.sup.6 dynes/cm.sup.2. The gel-adhesive composite has continued skin adhesion whether applied to or existing in dry or moist skin conditions. The gel contributes a high moisture vapor transmission rate to attempt to maintain dry skin conditions while the adhesive maintains skin adhesion. The gel-adhesive composite may be used in a variety of tape, dressing, bandage, drape, or other skin contacting usage and may optionally include antimicrobial agents to treat the skin while adhesion continues.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: December 14, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Robert A. Asmus
  • Patent number: 5225483
    Abstract: A thermoplastic composition is provided which comprises a blend of a thermoplastic, such as a copolymer of styrene and maleic anhydride; polypropylene; a modified elastomeric component, such as EPM or EPDM, which has been modified with a specified functional monomer, such as a 2-substituted-5-norbornene, and an amine-modified maleic anhydride grafted polypropylene. The composition has improved properties.
    Type: Grant
    Filed: July 22, 1991
    Date of Patent: July 6, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Sudhin Datta, Narayanaswami R. Dharmarajan, Jean M. Dekoninck, Donald A. White
  • Patent number: 5219557
    Abstract: An aqueous covering agent containing a water-soluble base polymer and a further polymer for neutralizing the aqueous solution of the base polymer is provided for the sealing of microscopy specimens. The aqueous covering agent maintains the coloring of the specimens by staining techniques for prolonged periods of time.
    Type: Grant
    Filed: December 23, 1987
    Date of Patent: June 15, 1993
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Renate Kaschek, Erwin Rieke
  • Patent number: 5219916
    Abstract: A waterbased coating composition formed of an acrylic latex and an acrylic hydrosol dispersed in an aqueous carrier and has a pH of about 7-10; wherein the binder is a blend of an acrylic latex polymer having a particle size of about 0.06-0.20 microns and an acrylic hydrosol polymer having a particle size of less than 0.30 microns; wherein the blend containsa methylol (meth)acrylamide acrylic latex polymer of polymerized monomers of alkyl methacrylate, alkyl acrylate or mixtures thereof, 1-15% by weight of methylol methacrylamide, methylol acrylamide or mixtures thereof, 0.5-10% by weight of ethylenically unsaturated carboxylic acid having reactive carboxyl groups, 0.5-10% by weight of ethylenically unsaturated hydroxyl monomer and the carboxyl groups of the carboxylic acid component of the polymer are reacted with ammonia or an amine; and an acrylic hydrosol polymer of methylol (meth)acrylamide acrylic polymer containing about 0.5-10% by weight of an ethylenically unsaturated carboxylic acid, 0.
    Type: Grant
    Filed: December 5, 1990
    Date of Patent: June 15, 1993
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Herman C. Den Hartog, Eileen E. Konsza, James F. Matthews, Ervin R. Werner, Jr.
  • Patent number: 5219917
    Abstract: The ICI viscosity of a paint is improved by incorporating into the paint a binder that comprises a film former and polymeric composition. The polymeric composition comprises about 30 to about 50 weight percent of a substantially non-self-polymerizable monomer and about 50 to about 70 weight percent of a copolymerizable monomer having a water-soluble homopolymer. The polymeric composition and film former are substantially inseparable by chromatographic means.
    Type: Grant
    Filed: July 14, 1992
    Date of Patent: June 15, 1993
    Assignee: Rohm and Haas Company
    Inventors: David M. Ingle, Gaylen M. Knutson
  • Patent number: 5208285
    Abstract: Wet adhesion properties comparable or superior to all-acrylic latexes for vinyl acetate copolymers and other low cost polymers, such as EVA-vinyl chloride copolymers, is achieved by blending a minor proportion, usually about 5 to 15%, of a small particle size copolymer containing copolymerized wet adhesion monomer which is a cyclic ureido. Very low quantities of the wet adhesion monomer, less than 0.25 wt% of total monomers, only are required to achieve excellent results.
    Type: Grant
    Filed: August 16, 1991
    Date of Patent: May 4, 1993
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Clarke A. Boyce, Rajeev Farwaha, Brigitte H. Licht, Martin Menard
  • Patent number: 5162425
    Abstract: It is highly desirable to be able to cure rubbers quickly since the amount of energy required for the curing process is reduced and the number of articles that can be cured in a mold in a given time is increased. In other words, the cycle time needed to cure articles made from such a rubber is reduced and the throughput of a mold utilized in curing such a rubber is increased. Unfortunately, most attempts to accelerate the cure rate of rubber have resulted in the rubber having poor scorch safety. The present invention discloses a fast curing rubber blend having excellent scorch safety which comprises: (a) from 50 to 98 weight percent of at least one polydiene rubber, and (b) from 2 to 50 weight percent of at least one vinylpyridine copolymer comprised of repeat units which are derived from a diene monomer and vinylpyridine wherein from 1 to 75 weight percent of the repeat units in said copolymer are derived from vinylpyridine.
    Type: Grant
    Filed: September 28, 1990
    Date of Patent: November 10, 1992
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul H. Sandstrom, Emil M. Friedman, J. Dale Massie, II, Robert A. Smith
  • Patent number: 5157071
    Abstract: Wet adhesion, ICI viscosity, and scrub resistance of a paint are improved by incorporating into the paint a binder that comprises a film former and polymeric composition. The polymeric composition comprises either (a) about 15 to about 35 weight percent of substantially non-self-polymerizable monomer, about 30 to about 70 weight percent of a copolymerizable monomer whose homopolymer is water-soluble, and about 10 to about 35 weight percent of a wet adhesion promoting monomer, or (b) about 35 to about 65 weight percent of the substantially non-self-polymerizable monomer and about 35 to about 65 weight percent of the wet adhesion promoting monomer. The polymeric composition and film former are substantially inseparable by chromatographic means.
    Type: Grant
    Filed: October 9, 1991
    Date of Patent: October 20, 1992
    Assignee: Union Oil Company of California
    Inventor: David M. Ingle
  • Patent number: 5102945
    Abstract: Butadiene polymer rubber compositions containing a polymeric activator have particularly beneficial characteristics. The activator is an interpolymer of 2-vinylpyridine monomer and 1,3-butadiene monomer, optionally with styrene, which interpolymer contains from 20% to 65% by weight of vinylpyridine units, and is mostly insoluble in boiling tetrahydrofuran.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: April 7, 1992
    Assignee: Monsanto Company
    Inventors: Aubert Y. Coran, Leonard H. Davis
  • Patent number: 5082892
    Abstract: A glass fiber-reinforced synthetic resin composition is proposed which is particularly suitable as a molding material of chassis of electric and electronic instruments to satisfy the various requirements in this particular application. The resin composition comprises: (A) 100 parts by weight of a copolymeric resin of styrene and maleic anhydride or a derivative thereof, of which the molar fraction of the moiety of maleic anhydride or a derivative thereof is in the range from 3 to 20%; (B) from 1 to 30 parts by weight of a styrene-based thermoplastic elastomer, of which the weight fraction of the moiety of styrene is in the range from 5 to 50%; (C) from 5 to 80 parts by weight of glass fibers, (D) from 5 to 30 parts by weight of a bromine-containing organic compound as a flame retardant; and (E) from 2 to 15 parts by weight of antimony trioxide.
    Type: Grant
    Filed: February 26, 1990
    Date of Patent: January 21, 1992
    Assignee: Idemitsu Petrochemical Company, Ltd.
    Inventors: Yoshiaki Miura, Masami Mihara, Hidezo Hosomi
  • Patent number: 5079090
    Abstract: The present invention relates to pressure-sensitive adhesive compositions comprising tackified elastomeric copolymers or block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The invention also provides sheet materials coated with the adhesive compositions. The polymers of the present invention are made by a method which comprises the step of reacting under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic-substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: January 7, 1992
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Eugene G. Joseph, Spencer F. Silver, William R. Bronn
  • Patent number: 5066709
    Abstract: This invention relates to superior bioadhesive compositions having time extended adhesive properties comprising a non-toxic carrier and a polymer having between about 45 and about 70 weight % of units having the structure ##STR1## between about 50 and about 30 weight % of units having the structure ##STR2## and 2 to 7 weight % of an amine salt containing a lactam functionally derived from A and/or B, wherein R is hydrogen, alkoxy, phenyl, carboxy or --N lactam having from 3 to 6 carbon atoms; R.sub.1 is C.sub.1 to C.sub.6 alkylene and R.sub.2 is C.sub.2 to C.sub.4 alkylene; said copolymer having a number average molecular weight of about 40,000 to about 500,000 and a relatively small particle size. The invention also relates to the method of synthesizing and using the above composition.
    Type: Grant
    Filed: September 20, 1990
    Date of Patent: November 19, 1991
    Assignee: GAF Chemicals Corporation
    Inventors: Ratan K. Chaudhuri, Rama K. Haldar, Balgopal Gangadharan
  • Patent number: 5055046
    Abstract: This invention relates to superior bioadhesive compositions having time extended adhesive properties comprising a non-toxic carrier and a polymer having between about 45 and about 70 weight % of units having the structure ##STR1## between about 50 and about 30 weight % of units having the structure ##STR2## and 2 and 7 weight % of an amine salt containing a lactam functionality derived from A and/or B, wherein R is hydrogen, alkoxy, phenyl, carboxyl or --N lactam having from 3 to 6 carbon atoms; R.sub.1 is C.sub.1 to C.sub.6 alkylene and R.sub.2 is C.sub.2 to C.sub.4 alkylene; said copolymer having a number average molecular weight of about 40,000 to about 500,000 and a relatively small particle size. The invention also relates to the method of synthesizing and using the above composition.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: October 8, 1991
    Assignee: ISP Investments Inc.
    Inventors: Ratan K. Chaudhuri, Rama K. Haldar, Balgopal Gangadharan
  • Patent number: 5004777
    Abstract: Glutarimide polymers having an acid and anhydride content lower than the acid and/or anhydride content normally present in the glutarimide polymers. Blends of the reduced acid and anhydride glutarimide polymers with thermoplastic materials are disclosed. A process for altering the properties of imide polymers by reducing or substantially removing acid and anhydride levels normally present in the imide polymer is also disclosed.
    Type: Grant
    Filed: May 24, 1990
    Date of Patent: April 2, 1991
    Assignee: Rohm and Haas Company
    Inventors: Michael P. Hallden-Abberton, Newman M. Bortnick, Leslie A. Cohen, William T. Freed, Harry C. Fromuth
  • Patent number: 4970260
    Abstract: A polymeric solution comprising: water; about 0.005 to about 0.5 moles of an inorganic acid, an inorganic case or an inorganic salt per 100 ml of such water; and about 0.1 to about 5.
    Type: Grant
    Filed: May 25, 1988
    Date of Patent: November 13, 1990
    Assignee: Exxon Research and Engineering Company
    Inventors: Robert D. Lundberg, Robert R. Phillips, Dennis G. Peiffer
  • Patent number: 4966931
    Abstract: The present invention disclosed herein is connected with a polypropylene resin composition giving off no corrosive and poisonous gases, having excellent moldability, providing molded articles with excellent mechanical strength and high flame retardance. The composition of the present invention is composed of predetermined amounts of a polypropylene resin, a polyethylene resin, polyammonium phosphate or polyammonium phosphate modified by melamine resin and a 1,3,5-triazine derivative. This composition may additionally contain a predetermined amount of one or more of specific thiophosphites and may further contain a predetermined amount of an olefinic synthetic rubber or elastomer and a crosslinking agent.
    Type: Grant
    Filed: January 19, 1989
    Date of Patent: October 30, 1990
    Assignee: Chisso Corporation
    Inventors: Shinichi Akitaya, Toru Fukazawa, Yutaka Nozokido, Nobuchika Tabata
  • Patent number: 4960819
    Abstract: It is highly desirable to be able to cure rubbers quickly since the amount of energy required for the curing process is reduced and the number of articles that can be cured in a mold in a given time is increased. In other words, the cycle time needed to cure articles made from such a rubber is reduced and the throughput of a mold utilized in curing such a rubber is increased. Unfortunately, most attempts to accelerate the cure rate of rubber have resulted in the rubber having poor scorch safety. The present invention discloses a fast curing rubber blend having excellent scorch safety which comprises: (a) from 50 to 98 weight percent of at least one polydiene rubber, and (b) from 2 to 50 weight percent of at least one vinylpyridine copolymer comprised of repeat units which are derived from a diene monomer and vinylpyridine wherein from 1 to 75 weight percent of the repeat units in said copolymer are derived from vinylpyridine.
    Type: Grant
    Filed: July 14, 1989
    Date of Patent: October 2, 1990
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul H. Sandstrom, Emil M. Friedman
  • Patent number: 4942189
    Abstract: The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 1,000 cps; forming an interpolymer complex of neutralized sulfonated polymer (water insoluble) and copolymer of styrene/vinylpyridine in the solvent system to form a solution, a concentration of the water insoluble interpolymer complex polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; the admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and interpolymer complex transferring from the organic liquid to the water phase, thereby causing the water phase to gel (i.e., thicken).
    Type: Grant
    Filed: July 31, 1989
    Date of Patent: July 17, 1990
    Assignee: Exxon Research and Engineering Company
    Inventors: Dennis G. Peiffer, Robert D. Lundberg, Ilan Duvdevani
  • Patent number: 4935307
    Abstract: A hydrophilic, polymeric blend which provides improved durability and reduced curl when used as an image-receptive layer on graphic arts films. The blend comprises at least one water-absorbing, hydrophilic polymeric material, at least one hydrophobic polymeric material having acid functionality, and at least one polyethylene glycol. The layer formed from the blend provides high sorption capacity combined with good physical integrity even when wet, along with dimensional stability.The invention also provides sheets suitable for preparing visual transparencies having a backing bearing on at least one major surface thereof an image-receptive layer formed from the aforementioned blend.
    Type: Grant
    Filed: October 21, 1988
    Date of Patent: June 19, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mohammad Iqbal, Armin J. Paff
  • Patent number: 4929666
    Abstract: Water-soluble or water-dispersible, crosslinkable polymeric surfactants having fluorocarbon and ionic moieties are disclosed. Such surfactants can be cured into tough, solvent resistant, low critical surface tension coatings useful for protective finishes on metal, plastics and fabrics.
    Type: Grant
    Filed: September 1, 1989
    Date of Patent: May 29, 1990
    Assignee: The Dow Chemical Company
    Inventors: Donald L. Schmidt, Perry J. McCrackin, Charles E. Coburn
  • Patent number: 4925887
    Abstract: Moulding compositions comprising(a) a melamine/formaldehyde resin, a melamine/phenol/formaldehyde resin or a mixture of said resins,(b) organic and/or inorganic fillters,(c) a lubricant, and(d) 0.1 to 2% by weight, based on on the total composition, of 3-chloro-1,2-propanediol as latent hardener,are suitable for the production of mouldings by injection moulding. The latent hardener employed permits extremely short cycle times coupled with long residence times at the cylinder temperature of the injection moulding machine. The moulding compositions are distinguished at the same time by very good flow properties.
    Type: Grant
    Filed: April 7, 1989
    Date of Patent: May 15, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Gunther, Hermann O. Wirth, Wilhelm Endlich
  • Patent number: 4904722
    Abstract: A method for controlling the viscosity of organic liquids, said organic liquid having a solubility parameter of less than 9.5, a viscosity, as measured at 25.degree. C., of less than 200 centipoises and said organic liquid is selected from the group consisting of mineral oils, synthetic oils, naphthanes, alkanes, cycloalkanes and aromatics and mixtures thereof, which comprises incorporating in said organic liquid about 0.01 to 20 grams of polymer complex per 100 ml. of said organic liquid, said polymer complex being formed "in situ" in said organic liquid or dissolved in said organic liquid, said complex being comprised of polymer A, containing about 4 meq. to 500 meq. of neutralized sulfonate groups, and polymer B, containing basic nitrogen groups, both functional groups being present at a level of from about 4 to 500 meq. per 100 g. of polymer, wherein polymer B has the formula: ##STR1## wherein x is about 50.0 to 99.8 weight percent and y is about 0.2 to about 50.
    Type: Grant
    Filed: October 18, 1985
    Date of Patent: February 27, 1990
    Assignee: Exxon Research and Engineering Company
    Inventors: Robert D. Lundberg, Robert R. Phillips, Dennis G. Peiffer, Ilan Duvdevani
  • Patent number: 4874811
    Abstract: An alkaline aqueous adhesive of a poly(meth-)acrylate base which contains poly(meth-)acrylate and polyvinylpyrollidone in a total amount of 5 to 40% by weight in the adhesive and in a weight ratio of 10:1 to 1:5. The poly(meth-)acrylate contains free carboxyl groups and has a degree of esterification of 0.55 to 0.9. The adhesive has a wide range of applications and can be transparent.
    Type: Grant
    Filed: April 21, 1989
    Date of Patent: October 17, 1989
    Assignee: Pelikan Aktiengesellschaft
    Inventors: Jurgen Borchers, Petra Bubolz
  • Patent number: 4871812
    Abstract: A moldable, putty-like adhesive mass is disclosed comprising a blend of (1) an acrylate terpolymer adhesive containing a hydrophilic macromolecular moiety and (2) a reinforcing material which is a carbonylamido group containing polymer. The adhesive blends are moisture vapor permeable and non-water swellable. They are useful in many medical applications.
    Type: Grant
    Filed: October 15, 1987
    Date of Patent: October 3, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Donald H. Lucast, Donald R. Battles, Steven S. Kantner
  • Patent number: 4868227
    Abstract: Webs composed of inorganic or organic fiber material are bonded with a cured resin mixture consisting essentially of(A) from 5 to 80% by weight of a water-soluble condensation product of carbonyl number 0-200 which has been prepared by alkaline condensation from 0.1 to 0.4 mole of an aliphatic or cycloaliphatic condensable ketone and 1 mole of formaldehyde, and(B) from 20 to 95% by weight of a water-soluble amino and/or phenolic resin.
    Type: Grant
    Filed: February 22, 1988
    Date of Patent: September 19, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Fritz E. Kempter, Franz Matejcek, Werner Neubach, Gerd Busse
  • Patent number: 4847318
    Abstract: An effective method for gelling certain organic liquids. The invention, in one embodiment, comprises forming a solution of the organic liquids and an amount of a triblock copolymer of relatively moderate molecular weight, having poly(4-vinylpyridene) end blocks and a small amount of a salt of a transition metal. In another embodiment, the invention comprises forming a solution of the organic liquids and an amount of a triblock copolymer of relatively moderate molecular weight, having poly(4-vinylpyridene) end blocks and a small amount of an acid. Such gelled liquids are useful as pipe line pigs, in automobile lacquers and in charcoal lighter fluids.
    Type: Grant
    Filed: January 22, 1988
    Date of Patent: July 11, 1989
    Assignee: The Dow Chemical Company
    Inventor: Kent S. Dennis
  • Patent number: 4810745
    Abstract: Comestibles are packaged in wrappers formed of plastic film or equivalent sheet material sealed with cold-seal adhesives containing a minor percentage of vinyl-pyrrolidone/styrene copolymer as a bond enhancement agent.
    Type: Grant
    Filed: July 16, 1987
    Date of Patent: March 7, 1989
    Assignee: Century Adhesives Corp.
    Inventors: Charles O. Pike, Tamela A. Viers
  • Patent number: 4791165
    Abstract: An ink composition is provided for an ink-jet printer, preferably a thermal ink-jet printer. The composition comprises about 5 to 40 wt % glycol, about 60 to 90 wt % water, about 0.001 to 10 wt % polymer blend and about 1 to 7 wt % dye. The polymer blend includes both uncharged and charged monomeric units.The glycol and polymer blend act to form a soft plug that forms in the orifice of the ink-jet pen. The soft plug prevents further evaporaion of water, but unlike a hard plug, is readily blown out upon firing. The charged units in the polymer blend contribute to water fastness and light fastness of the dye on paper. Further, by employing appropriate functional groups in the polymer blend, chemical degradation of the ink dye can be retarded on acid or alkaline papers.
    Type: Grant
    Filed: March 16, 1987
    Date of Patent: December 13, 1988
    Assignee: Hewlett-Packard Company
    Inventors: James G. Bearss, Kenneth A. Norton
  • Patent number: 4778833
    Abstract: Composition for the preservation of wood containing a wood preservative, such as a boron compound or a fluorine compound, in a polymer or polymer composition, which upon contact with water releases the wood preservative. Said composition is introduced into a hole in the wood or in a wood construction, whereafter the hole is sealed.
    Type: Grant
    Filed: December 11, 1986
    Date of Patent: October 18, 1988
    Assignee: Nederlandse Centrale Organisatie voor Toegepast- Natuurweten- Schappelijk Onderzoek
    Inventors: Jan W. P. T. Van der Drift, Jan La Brijn
  • Patent number: 4769443
    Abstract: Novel light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers have been synthesized; these are of the formula: ##STR1## in which R.sub.3 and R.sub.4 can be identical or different and are radicals of formula (III), (IV), (V), (VI) ##STR2## and R.sub.5 additionally can be a radical of formula VII ##STR3## and R.sub.4 is C.sub.2 -C.sub.
    Type: Grant
    Filed: August 3, 1987
    Date of Patent: September 6, 1988
    Assignee: Ciba-Geigy Corporation
    Inventor: Giuseppe Cantatore
  • Patent number: 4748074
    Abstract: Non linear optical compositions contain a vinylidene fluoride copolymer and an additive having molecular optoelelectronic activity, e.g. methyl-N-(2,4-dinitrophenyl)-alaninate. Poled films derived from the composite display optoelectronic activity. There is a marked contrast with known techniques in which single crystals are utilized. The compositions are used to make laminates which display good waveguide properties.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: May 31, 1988
    Assignee: British Telecommunications Public Limited Company
    Inventors: Philippos Pantelis, Graham J. Davies
  • Patent number: 4746577
    Abstract: Non linear optical compositions contain a vinylidene fluoride copolymer and an additive having molecular optoelectronic activity, e.g. methyl-N-(2,4-dinitrophenyl)-alaninate. Poled films derived from the composite display optoelectronic activity. There is a marked contrast with known techniques in which single crystals are utilized. The compositions are used to make laminates which display good waveguide properties.
    Type: Grant
    Filed: February 24, 1987
    Date of Patent: May 24, 1988
    Assignee: British Telecommunications Public Limited Company
    Inventors: Philippos Pantelis, Graham J. Davies
  • Patent number: 4745140
    Abstract: Aqueous-based adhesive compositions having good adhesion to a non-polar polymeric surface and to cellulosic materials comprise a dispersion of an adhesive comprising an N-vinyl lactam polymeric resin, a tackifier for such adhesive, and an effective amount of an ethylene/vinyl acetate copolymer emulsion stabilizer for the resin and tackifier. Preferred N-vinyl lactam polymeric resins are vinyl pyrrolidone/vinyl acetate copolymers and a preferred class of tackifier are the rosin ester tackifiers.
    Type: Grant
    Filed: March 13, 1987
    Date of Patent: May 17, 1988
    Assignee: Chesebrough-Pond's Inc.
    Inventor: Jagadish C. Goswami
  • Patent number: 4743637
    Abstract: Novel flame retardant agents comprise polyalkylene oxides or a derivative thereof end-capped with brominated phthalimide groups, and have the general formulaeR--R.sup.1 --O--R.sup.1).sub.n R (I)(R--R.sup.1 --O--R.sup.1).sub.n' NH).sub.2 C.dbd.O (II)orR--R.sup.1 --OR.sup.1).sub.n" CH.sub.2).sub.3 C--R.sup.2 (III)wherein R is ##STR1## R.sup.1 is alkylene of from about 2 to about 6 carbon atoms; R.sup.1 is alkyl of from about 1 to about 6 carbon atoms; n is from about 4 to about 40; n' is from about 3 to about 15; and n" is from about 1 to about 10. Thermoplastic compositions, for example, polyphenylene ether compositions, rendered flame retardant with the novel compounds have a high resistance to additive vaporization and surface liquid exudation as well as desirable high flow characteristics.
    Type: Grant
    Filed: August 1, 1986
    Date of Patent: May 10, 1988
    Assignee: General Electric Company
    Inventors: Robert J. Axelrod, Donald B. G. Jaquiss, John A. Tyrell
  • Patent number: 4743647
    Abstract: Described herein are novel bismaleimides and prepregable resin compositions comprising these bismaleimides and one or more liquid coreactants and optionally, one or more other additives. The novel bismaleimides, such as alpha, alpha-bis-(4-maleimidophenyl)-meta-diisopropylbenzene, are characterized by the presence of three aromatic rings in the molecular structure and in some respects optimize the desirable characteristics of the one or two and four atomatic ring-containing bismaleimides in resins prepared therefrom.
    Type: Grant
    Filed: December 18, 1986
    Date of Patent: May 10, 1988
    Assignee: Amoco Corporation
    Inventor: Linda A. Domeier
  • Patent number: 4737410
    Abstract: Pressure-sensitive adhesives comprise blends of acrylate copolymer copositions with polyalkyloxazolines. The blends exhibit enhanced cohesive strength with balanced adhesive properties and are useful as coatings for sheet materials.
    Type: Grant
    Filed: November 28, 1986
    Date of Patent: April 12, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Steven S. Kantner
  • Patent number: 4737534
    Abstract: The instant invention relates to a process for controlling the viscosity of organic liquids by incorporating in said liquid a minor amount of polymer complex, and optionally a cosolvent for the ionic groups of said polymer. The polymer complex comprises the reaction product of a metal neutralized sulfonated polymer and a basic nitrogen-containing polymer, wherein the polymer complex is substantially soluble in said organic liquid, and pendant sulfonate groups which are substantially insoluble in said organic liquid. The optional cosolvent is selected which will solubilize the pendant sulfonate groups and provide a reasonably homogeneous mixture of solvent, cosolvent and polymer complex. The preferred compositions prepared by the method of the instant invention comprise an organic liquid having a solubility parameter of from 6 to 10.5 in combination with a polymer complex containing from 0.2 up to 10.
    Type: Grant
    Filed: April 8, 1985
    Date of Patent: April 12, 1988
    Assignee: Exxon Research and Engineering Company
    Inventors: Robert D. Lundberg, Robert R. Phillips, Dennis G. Peiffer, Ilan Duvdevani
  • Patent number: 4734446
    Abstract: Polymeric compositions comprised of particularly disclosed oil-soluble polymers and specific oil-soluble acrylate polymerization products are disclosed. The oil-soluble polymer (A) is a polymer selected from the group consisting of a non-aromatic mono-olefin having at least three carbon atoms, and a copolymer of the non-aromatic mono-olefin with an aromatic monoolefin, the polymer having a number average molecular weight of about 500 to about 100,000. The oil-soluble acrylate polymerization product (B) is at least one ester of the formula CH.sub.2 .dbd.C(X)--COOR wherein X is hydrogen or an alkyl or aryl group, and R is a monovalent hydrocarbyl group containing at least four carbon atoms, or an ether derivative of said hydrocarbyl group. The components (A) and (B) are preferably present in a weight ratio of (A):(B) of about 20:1 to about 1:10.
    Type: Grant
    Filed: October 27, 1986
    Date of Patent: March 29, 1988
    Assignee: The Lubrizol Corporation
    Inventor: Craig D. Tipton
  • Patent number: 4731408
    Abstract: Processable conductive polymers prepared by an oxidative polymerization are disclosed. A monomer which is oxidatively polymerizable into an electrically conductive polymer is polymerized with the aid of a chemical oxidizing agent in a reaction medium containing a dispersed phase of a polymeric counterion having anionic surface character. The polymeric counterion, which is in affiliation with the oxidatively polymerized polymer, confers processability to the conductive polymer material.
    Type: Grant
    Filed: December 20, 1985
    Date of Patent: March 15, 1988
    Assignee: Polaroid Corporation
    Inventor: Stanley J. Jasne
  • Patent number: 4727102
    Abstract: Polyolefins which are made self-extinguishing by means of flame-retarding compositions comprising ammonium polyphosphate, melamine cyanurate and a hydroxyalkyl-derivative of isocyanuric acid at least partially in the form of a homopolymer.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: February 23, 1988
    Assignee: V.A.M.P. S.r.l.
    Inventor: Luciano Scarso
  • Patent number: 4701493
    Abstract: An acrylic modified styrenic/N-arylmaleimide copolymer containing composition which exhibits excellent melt flow properties, impact strength and gloss upon molding is disclosed.
    Type: Grant
    Filed: July 14, 1986
    Date of Patent: October 20, 1987
    Assignee: Atlantic Richfield Company
    Inventor: Barry D. Dean
  • Patent number: 4696961
    Abstract: Novel light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers have been synthesized; these are of the formula: ##STR1## in which R.sub.3 and R.sub.5 can be identical or different and are radicals of formula (III), (IV), (V), (VI) ##STR2## and R.sub.5 additionally can be a radical of formula VII ##STR3## and R.sub.4 is C.sub.2 -C.sub.
    Type: Grant
    Filed: September 20, 1984
    Date of Patent: September 29, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Giuseppe Cantatore
  • Patent number: 4684692
    Abstract: A moldable composition which comprises a novel random bromostyrene-containing copolymer and a flame-retardant synergist is disclosed. The molded composition exhibits at least a 94V-1 classification when tested in accordance with Underwriters' Laboratories Inc. Test Method UL94.
    Type: Grant
    Filed: December 16, 1986
    Date of Patent: August 4, 1987
    Assignee: Atlantic Richfield Company
    Inventor: Usama E. Younes