Solid Polymer Derived From Nitrogen Heterocycle Monomer Patents (Class 524/516)
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Patent number: 5356985Abstract: The present invention relates to aqueous emulsions of polymers which contain 80 to 100 weight % of acrylonitrile polymerized within them, to a method for their preparation, and to their use as raw materials for acrylic and modacrylic fibres and as dyeing additives for adjusting the dyestuff affinity of cationic dyestuffs for conventional acrylic and modacrylic polymers and fibre materials produced from them.Type: GrantFiled: September 20, 1993Date of Patent: October 18, 1994Assignee: Bayer AktiengesellschaftInventors: Gunter Sackmann, Siegfried Korte, Heinrich Alberts, Rolf-Volker Meyer
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Patent number: 5338490Abstract: A two-phase composite of ionically-conductive pressure-sensitive adhesive, biomedical electrodes using the composite and methods of preparing the composite and the electrode are disclosed. The continuous phase is a hydrophilic, solid state pressure-sensitive adhesive composition ionically-conductive regardless of an amount of water present in the composition. The discontinuous phase are domains of a hydrophobic pressure-sensitive adhesive which enhances adhesion of the composite to mammalian skin while maintaining acceptable alternating current impedance of the composite.Type: GrantFiled: August 31, 1993Date of Patent: August 16, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Timothy M. Dietz, Robert A. Asmus, Rosa Uy
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Patent number: 5331022Abstract: For the reduction of the radon load in enclosed spaces, an aqueous, solvent and softener-free dispersion of a vinylidene chloride-acrylate-copolymer is applied to the boundary surfaces of the room and left to dry. The dispersion contains also a nonionic surfactant on a base of alkylphenolethoxylate with a proportion of 10 mole ethylene oxide, a vinyl pyrrolidone-copolymer and a defrothing agent.Type: GrantFiled: October 1, 1992Date of Patent: July 19, 1994Assignee: Hesco AG, Industrieconsulting & IndustrievertretungenInventors: Ludwig Jochmann, Josef Hess
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Patent number: 5324770Abstract: The present invention comprises block copolymers of alkylene oxides, such as ethylene oxide and propylene oxide, which are further formulated with additional polymers such as poly(N-vinylpyrrolidinone), poly (vinyl alcohol), and certain low foam additives. These polymers are useful for the coating of alumina powders for use in ceramics. In aqueous media, their lower viscosities enable facile spray drying of the coated alumina powders. The coated alumina powders may be compressed under relatively low pressure into high density forms with superior unfired compressive strengths (green strength), they are surprisingly insensitive to relative humidity, are readily ejected from the mold, and finally do not have a deleterious effect upon the ultimate high temperature sintering of the formed bodies.Type: GrantFiled: June 17, 1992Date of Patent: June 28, 1994Assignee: Nalco Chemical CompanyInventor: David R. Cosper
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Patent number: 5294662Abstract: Novel polymers are disclosed which can be used to prepare water-based compositions are disclosed having the capability of forming a uniform, low surface-energy, thin film on a substrate. Such compositions comprise a polymer having at least one fluoroaliphatic moiety and at least one anionic moiety, and a novel polymer having at least one fluoroaliphatic moiety and at least one oxazoline moiety.Type: GrantFiled: April 15, 1993Date of Patent: March 15, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: George G. I. Moore, Dong-Wei Zhu
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Patent number: 5281638Abstract: An aqueous adhesive composition containing a chlorosulfonated polyethylene latex, a polymaleimide compound, a nitroso compound and a metal oxide. The adhesive composition can be effectively utilized without a primer component and exhibits an unusually high resistance to pre-bake conditions and adverse environments. The adhesive also possesses the ability to effectively bond a variety of substrates.Type: GrantFiled: April 23, 1993Date of Patent: January 25, 1994Assignee: Lord CorporationInventor: Douglas H. Mowrey
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Patent number: 5281674Abstract: A crosslinkable resin composition containing:(A) from 10% to 90% by weight of a thermoplastic resin component,(B) from 90% to 10% by weight of a curable resin component, comprising, expressed by reference to the curable resin (100%),(i) 50% to 95% of a (meth)acryloyl derivative, and(ii) 50% to 5% of a (meth)allyloxy derivative, and(C) from 0% to 30% by weight of a plasticiser for the thermoplastic resin component, is disclosed.Also a new crosslinked resin layer and a process for the manufacture of the new crosslinked resin layer on a substrate are described.The crosslinked resin layer herein exhibits a desirable balance between flexibility, resistance to stain and resistance to scuff properties, in combination with outstanding mechanical and chemical properties.The crosslinkable resin composition is particularly suitable for coating application of various substrates such as flooring materials, wall covering materials, coils, wires, and various shaped articles e.g. cars, containers and metallic profiles.Type: GrantFiled: June 16, 1992Date of Patent: January 25, 1994Assignee: Monsanto CompanyInventors: Adolf A. Klaiber, Johannes F. H. Courtier, Daniel Gaeckle
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Patent number: 5270358Abstract: A composite of a gel of swollen hydrocolloid dispersed in a pressure sensitive adhesive matrix is provided. The gel has a natural or synthetically derived hydrocolloid swollen with a non-volatile swelling agent, such that the gel may have a shear modulus of less than 6.2.times.10.sup.6 dynes/cm.sup.2. The gel-adhesive composite has continued skin adhesion whether applied to or existing in dry or moist skin conditions. The gel contributes a high moisture vapor transmission rate to attempt to maintain dry skin conditions while the adhesive maintains skin adhesion. The gel-adhesive composite may be used in a variety of tape, dressing, bandage, drape, or other skin contacting usage and may optionally include antimicrobial agents to treat the skin while adhesion continues.Type: GrantFiled: June 25, 1992Date of Patent: December 14, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventor: Robert A. Asmus
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Patent number: 5225483Abstract: A thermoplastic composition is provided which comprises a blend of a thermoplastic, such as a copolymer of styrene and maleic anhydride; polypropylene; a modified elastomeric component, such as EPM or EPDM, which has been modified with a specified functional monomer, such as a 2-substituted-5-norbornene, and an amine-modified maleic anhydride grafted polypropylene. The composition has improved properties.Type: GrantFiled: July 22, 1991Date of Patent: July 6, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Sudhin Datta, Narayanaswami R. Dharmarajan, Jean M. Dekoninck, Donald A. White
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Patent number: 5219557Abstract: An aqueous covering agent containing a water-soluble base polymer and a further polymer for neutralizing the aqueous solution of the base polymer is provided for the sealing of microscopy specimens. The aqueous covering agent maintains the coloring of the specimens by staining techniques for prolonged periods of time.Type: GrantFiled: December 23, 1987Date of Patent: June 15, 1993Assignee: Merck Patent Gesellschaft Mit Beschrankter HaftungInventors: Renate Kaschek, Erwin Rieke
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Patent number: 5219916Abstract: A waterbased coating composition formed of an acrylic latex and an acrylic hydrosol dispersed in an aqueous carrier and has a pH of about 7-10; wherein the binder is a blend of an acrylic latex polymer having a particle size of about 0.06-0.20 microns and an acrylic hydrosol polymer having a particle size of less than 0.30 microns; wherein the blend containsa methylol (meth)acrylamide acrylic latex polymer of polymerized monomers of alkyl methacrylate, alkyl acrylate or mixtures thereof, 1-15% by weight of methylol methacrylamide, methylol acrylamide or mixtures thereof, 0.5-10% by weight of ethylenically unsaturated carboxylic acid having reactive carboxyl groups, 0.5-10% by weight of ethylenically unsaturated hydroxyl monomer and the carboxyl groups of the carboxylic acid component of the polymer are reacted with ammonia or an amine; and an acrylic hydrosol polymer of methylol (meth)acrylamide acrylic polymer containing about 0.5-10% by weight of an ethylenically unsaturated carboxylic acid, 0.Type: GrantFiled: December 5, 1990Date of Patent: June 15, 1993Assignee: E. I. du Pont de Nemours and CompanyInventors: Herman C. Den Hartog, Eileen E. Konsza, James F. Matthews, Ervin R. Werner, Jr.
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Patent number: 5219917Abstract: The ICI viscosity of a paint is improved by incorporating into the paint a binder that comprises a film former and polymeric composition. The polymeric composition comprises about 30 to about 50 weight percent of a substantially non-self-polymerizable monomer and about 50 to about 70 weight percent of a copolymerizable monomer having a water-soluble homopolymer. The polymeric composition and film former are substantially inseparable by chromatographic means.Type: GrantFiled: July 14, 1992Date of Patent: June 15, 1993Assignee: Rohm and Haas CompanyInventors: David M. Ingle, Gaylen M. Knutson
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Patent number: 5208285Abstract: Wet adhesion properties comparable or superior to all-acrylic latexes for vinyl acetate copolymers and other low cost polymers, such as EVA-vinyl chloride copolymers, is achieved by blending a minor proportion, usually about 5 to 15%, of a small particle size copolymer containing copolymerized wet adhesion monomer which is a cyclic ureido. Very low quantities of the wet adhesion monomer, less than 0.25 wt% of total monomers, only are required to achieve excellent results.Type: GrantFiled: August 16, 1991Date of Patent: May 4, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Clarke A. Boyce, Rajeev Farwaha, Brigitte H. Licht, Martin Menard
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Patent number: 5162425Abstract: It is highly desirable to be able to cure rubbers quickly since the amount of energy required for the curing process is reduced and the number of articles that can be cured in a mold in a given time is increased. In other words, the cycle time needed to cure articles made from such a rubber is reduced and the throughput of a mold utilized in curing such a rubber is increased. Unfortunately, most attempts to accelerate the cure rate of rubber have resulted in the rubber having poor scorch safety. The present invention discloses a fast curing rubber blend having excellent scorch safety which comprises: (a) from 50 to 98 weight percent of at least one polydiene rubber, and (b) from 2 to 50 weight percent of at least one vinylpyridine copolymer comprised of repeat units which are derived from a diene monomer and vinylpyridine wherein from 1 to 75 weight percent of the repeat units in said copolymer are derived from vinylpyridine.Type: GrantFiled: September 28, 1990Date of Patent: November 10, 1992Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul H. Sandstrom, Emil M. Friedman, J. Dale Massie, II, Robert A. Smith
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Patent number: 5157071Abstract: Wet adhesion, ICI viscosity, and scrub resistance of a paint are improved by incorporating into the paint a binder that comprises a film former and polymeric composition. The polymeric composition comprises either (a) about 15 to about 35 weight percent of substantially non-self-polymerizable monomer, about 30 to about 70 weight percent of a copolymerizable monomer whose homopolymer is water-soluble, and about 10 to about 35 weight percent of a wet adhesion promoting monomer, or (b) about 35 to about 65 weight percent of the substantially non-self-polymerizable monomer and about 35 to about 65 weight percent of the wet adhesion promoting monomer. The polymeric composition and film former are substantially inseparable by chromatographic means.Type: GrantFiled: October 9, 1991Date of Patent: October 20, 1992Assignee: Union Oil Company of CaliforniaInventor: David M. Ingle
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Patent number: 5102945Abstract: Butadiene polymer rubber compositions containing a polymeric activator have particularly beneficial characteristics. The activator is an interpolymer of 2-vinylpyridine monomer and 1,3-butadiene monomer, optionally with styrene, which interpolymer contains from 20% to 65% by weight of vinylpyridine units, and is mostly insoluble in boiling tetrahydrofuran.Type: GrantFiled: November 14, 1990Date of Patent: April 7, 1992Assignee: Monsanto CompanyInventors: Aubert Y. Coran, Leonard H. Davis
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Patent number: 5082892Abstract: A glass fiber-reinforced synthetic resin composition is proposed which is particularly suitable as a molding material of chassis of electric and electronic instruments to satisfy the various requirements in this particular application. The resin composition comprises: (A) 100 parts by weight of a copolymeric resin of styrene and maleic anhydride or a derivative thereof, of which the molar fraction of the moiety of maleic anhydride or a derivative thereof is in the range from 3 to 20%; (B) from 1 to 30 parts by weight of a styrene-based thermoplastic elastomer, of which the weight fraction of the moiety of styrene is in the range from 5 to 50%; (C) from 5 to 80 parts by weight of glass fibers, (D) from 5 to 30 parts by weight of a bromine-containing organic compound as a flame retardant; and (E) from 2 to 15 parts by weight of antimony trioxide.Type: GrantFiled: February 26, 1990Date of Patent: January 21, 1992Assignee: Idemitsu Petrochemical Company, Ltd.Inventors: Yoshiaki Miura, Masami Mihara, Hidezo Hosomi
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Patent number: 5079090Abstract: The present invention relates to pressure-sensitive adhesive compositions comprising tackified elastomeric copolymers or block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The invention also provides sheet materials coated with the adhesive compositions. The polymers of the present invention are made by a method which comprises the step of reacting under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic-substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone.Type: GrantFiled: October 20, 1989Date of Patent: January 7, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Eugene G. Joseph, Spencer F. Silver, William R. Bronn
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Patent number: 5066709Abstract: This invention relates to superior bioadhesive compositions having time extended adhesive properties comprising a non-toxic carrier and a polymer having between about 45 and about 70 weight % of units having the structure ##STR1## between about 50 and about 30 weight % of units having the structure ##STR2## and 2 to 7 weight % of an amine salt containing a lactam functionally derived from A and/or B, wherein R is hydrogen, alkoxy, phenyl, carboxy or --N lactam having from 3 to 6 carbon atoms; R.sub.1 is C.sub.1 to C.sub.6 alkylene and R.sub.2 is C.sub.2 to C.sub.4 alkylene; said copolymer having a number average molecular weight of about 40,000 to about 500,000 and a relatively small particle size. The invention also relates to the method of synthesizing and using the above composition.Type: GrantFiled: September 20, 1990Date of Patent: November 19, 1991Assignee: GAF Chemicals CorporationInventors: Ratan K. Chaudhuri, Rama K. Haldar, Balgopal Gangadharan
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Patent number: 5055046Abstract: This invention relates to superior bioadhesive compositions having time extended adhesive properties comprising a non-toxic carrier and a polymer having between about 45 and about 70 weight % of units having the structure ##STR1## between about 50 and about 30 weight % of units having the structure ##STR2## and 2 and 7 weight % of an amine salt containing a lactam functionality derived from A and/or B, wherein R is hydrogen, alkoxy, phenyl, carboxyl or --N lactam having from 3 to 6 carbon atoms; R.sub.1 is C.sub.1 to C.sub.6 alkylene and R.sub.2 is C.sub.2 to C.sub.4 alkylene; said copolymer having a number average molecular weight of about 40,000 to about 500,000 and a relatively small particle size. The invention also relates to the method of synthesizing and using the above composition.Type: GrantFiled: April 8, 1991Date of Patent: October 8, 1991Assignee: ISP Investments Inc.Inventors: Ratan K. Chaudhuri, Rama K. Haldar, Balgopal Gangadharan
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Patent number: 5004777Abstract: Glutarimide polymers having an acid and anhydride content lower than the acid and/or anhydride content normally present in the glutarimide polymers. Blends of the reduced acid and anhydride glutarimide polymers with thermoplastic materials are disclosed. A process for altering the properties of imide polymers by reducing or substantially removing acid and anhydride levels normally present in the imide polymer is also disclosed.Type: GrantFiled: May 24, 1990Date of Patent: April 2, 1991Assignee: Rohm and Haas CompanyInventors: Michael P. Hallden-Abberton, Newman M. Bortnick, Leslie A. Cohen, William T. Freed, Harry C. Fromuth
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Patent number: 4970260Abstract: A polymeric solution comprising: water; about 0.005 to about 0.5 moles of an inorganic acid, an inorganic case or an inorganic salt per 100 ml of such water; and about 0.1 to about 5.Type: GrantFiled: May 25, 1988Date of Patent: November 13, 1990Assignee: Exxon Research and Engineering CompanyInventors: Robert D. Lundberg, Robert R. Phillips, Dennis G. Peiffer
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Patent number: 4966931Abstract: The present invention disclosed herein is connected with a polypropylene resin composition giving off no corrosive and poisonous gases, having excellent moldability, providing molded articles with excellent mechanical strength and high flame retardance. The composition of the present invention is composed of predetermined amounts of a polypropylene resin, a polyethylene resin, polyammonium phosphate or polyammonium phosphate modified by melamine resin and a 1,3,5-triazine derivative. This composition may additionally contain a predetermined amount of one or more of specific thiophosphites and may further contain a predetermined amount of an olefinic synthetic rubber or elastomer and a crosslinking agent.Type: GrantFiled: January 19, 1989Date of Patent: October 30, 1990Assignee: Chisso CorporationInventors: Shinichi Akitaya, Toru Fukazawa, Yutaka Nozokido, Nobuchika Tabata
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Patent number: 4960819Abstract: It is highly desirable to be able to cure rubbers quickly since the amount of energy required for the curing process is reduced and the number of articles that can be cured in a mold in a given time is increased. In other words, the cycle time needed to cure articles made from such a rubber is reduced and the throughput of a mold utilized in curing such a rubber is increased. Unfortunately, most attempts to accelerate the cure rate of rubber have resulted in the rubber having poor scorch safety. The present invention discloses a fast curing rubber blend having excellent scorch safety which comprises: (a) from 50 to 98 weight percent of at least one polydiene rubber, and (b) from 2 to 50 weight percent of at least one vinylpyridine copolymer comprised of repeat units which are derived from a diene monomer and vinylpyridine wherein from 1 to 75 weight percent of the repeat units in said copolymer are derived from vinylpyridine.Type: GrantFiled: July 14, 1989Date of Patent: October 2, 1990Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul H. Sandstrom, Emil M. Friedman
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Patent number: 4942189Abstract: The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 1,000 cps; forming an interpolymer complex of neutralized sulfonated polymer (water insoluble) and copolymer of styrene/vinylpyridine in the solvent system to form a solution, a concentration of the water insoluble interpolymer complex polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; the admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and interpolymer complex transferring from the organic liquid to the water phase, thereby causing the water phase to gel (i.e., thicken).Type: GrantFiled: July 31, 1989Date of Patent: July 17, 1990Assignee: Exxon Research and Engineering CompanyInventors: Dennis G. Peiffer, Robert D. Lundberg, Ilan Duvdevani
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Patent number: 4935307Abstract: A hydrophilic, polymeric blend which provides improved durability and reduced curl when used as an image-receptive layer on graphic arts films. The blend comprises at least one water-absorbing, hydrophilic polymeric material, at least one hydrophobic polymeric material having acid functionality, and at least one polyethylene glycol. The layer formed from the blend provides high sorption capacity combined with good physical integrity even when wet, along with dimensional stability.The invention also provides sheets suitable for preparing visual transparencies having a backing bearing on at least one major surface thereof an image-receptive layer formed from the aforementioned blend.Type: GrantFiled: October 21, 1988Date of Patent: June 19, 1990Assignee: Minnesota Mining and Manufacturing CompanyInventors: Mohammad Iqbal, Armin J. Paff
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Patent number: 4929666Abstract: Water-soluble or water-dispersible, crosslinkable polymeric surfactants having fluorocarbon and ionic moieties are disclosed. Such surfactants can be cured into tough, solvent resistant, low critical surface tension coatings useful for protective finishes on metal, plastics and fabrics.Type: GrantFiled: September 1, 1989Date of Patent: May 29, 1990Assignee: The Dow Chemical CompanyInventors: Donald L. Schmidt, Perry J. McCrackin, Charles E. Coburn
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Patent number: 4925887Abstract: Moulding compositions comprising(a) a melamine/formaldehyde resin, a melamine/phenol/formaldehyde resin or a mixture of said resins,(b) organic and/or inorganic fillters,(c) a lubricant, and(d) 0.1 to 2% by weight, based on on the total composition, of 3-chloro-1,2-propanediol as latent hardener,are suitable for the production of mouldings by injection moulding. The latent hardener employed permits extremely short cycle times coupled with long residence times at the cylinder temperature of the injection moulding machine. The moulding compositions are distinguished at the same time by very good flow properties.Type: GrantFiled: April 7, 1989Date of Patent: May 15, 1990Assignee: Ciba-Geigy CorporationInventors: Peter Gunther, Hermann O. Wirth, Wilhelm Endlich
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Patent number: 4904722Abstract: A method for controlling the viscosity of organic liquids, said organic liquid having a solubility parameter of less than 9.5, a viscosity, as measured at 25.degree. C., of less than 200 centipoises and said organic liquid is selected from the group consisting of mineral oils, synthetic oils, naphthanes, alkanes, cycloalkanes and aromatics and mixtures thereof, which comprises incorporating in said organic liquid about 0.01 to 20 grams of polymer complex per 100 ml. of said organic liquid, said polymer complex being formed "in situ" in said organic liquid or dissolved in said organic liquid, said complex being comprised of polymer A, containing about 4 meq. to 500 meq. of neutralized sulfonate groups, and polymer B, containing basic nitrogen groups, both functional groups being present at a level of from about 4 to 500 meq. per 100 g. of polymer, wherein polymer B has the formula: ##STR1## wherein x is about 50.0 to 99.8 weight percent and y is about 0.2 to about 50.Type: GrantFiled: October 18, 1985Date of Patent: February 27, 1990Assignee: Exxon Research and Engineering CompanyInventors: Robert D. Lundberg, Robert R. Phillips, Dennis G. Peiffer, Ilan Duvdevani
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Patent number: 4874811Abstract: An alkaline aqueous adhesive of a poly(meth-)acrylate base which contains poly(meth-)acrylate and polyvinylpyrollidone in a total amount of 5 to 40% by weight in the adhesive and in a weight ratio of 10:1 to 1:5. The poly(meth-)acrylate contains free carboxyl groups and has a degree of esterification of 0.55 to 0.9. The adhesive has a wide range of applications and can be transparent.Type: GrantFiled: April 21, 1989Date of Patent: October 17, 1989Assignee: Pelikan AktiengesellschaftInventors: Jurgen Borchers, Petra Bubolz
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Patent number: 4871812Abstract: A moldable, putty-like adhesive mass is disclosed comprising a blend of (1) an acrylate terpolymer adhesive containing a hydrophilic macromolecular moiety and (2) a reinforcing material which is a carbonylamido group containing polymer. The adhesive blends are moisture vapor permeable and non-water swellable. They are useful in many medical applications.Type: GrantFiled: October 15, 1987Date of Patent: October 3, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Donald H. Lucast, Donald R. Battles, Steven S. Kantner
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Patent number: 4868227Abstract: Webs composed of inorganic or organic fiber material are bonded with a cured resin mixture consisting essentially of(A) from 5 to 80% by weight of a water-soluble condensation product of carbonyl number 0-200 which has been prepared by alkaline condensation from 0.1 to 0.4 mole of an aliphatic or cycloaliphatic condensable ketone and 1 mole of formaldehyde, and(B) from 20 to 95% by weight of a water-soluble amino and/or phenolic resin.Type: GrantFiled: February 22, 1988Date of Patent: September 19, 1989Assignee: BASF AktiengesellschaftInventors: Fritz E. Kempter, Franz Matejcek, Werner Neubach, Gerd Busse
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Patent number: 4847318Abstract: An effective method for gelling certain organic liquids. The invention, in one embodiment, comprises forming a solution of the organic liquids and an amount of a triblock copolymer of relatively moderate molecular weight, having poly(4-vinylpyridene) end blocks and a small amount of a salt of a transition metal. In another embodiment, the invention comprises forming a solution of the organic liquids and an amount of a triblock copolymer of relatively moderate molecular weight, having poly(4-vinylpyridene) end blocks and a small amount of an acid. Such gelled liquids are useful as pipe line pigs, in automobile lacquers and in charcoal lighter fluids.Type: GrantFiled: January 22, 1988Date of Patent: July 11, 1989Assignee: The Dow Chemical CompanyInventor: Kent S. Dennis
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Patent number: 4810745Abstract: Comestibles are packaged in wrappers formed of plastic film or equivalent sheet material sealed with cold-seal adhesives containing a minor percentage of vinyl-pyrrolidone/styrene copolymer as a bond enhancement agent.Type: GrantFiled: July 16, 1987Date of Patent: March 7, 1989Assignee: Century Adhesives Corp.Inventors: Charles O. Pike, Tamela A. Viers
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Patent number: 4791165Abstract: An ink composition is provided for an ink-jet printer, preferably a thermal ink-jet printer. The composition comprises about 5 to 40 wt % glycol, about 60 to 90 wt % water, about 0.001 to 10 wt % polymer blend and about 1 to 7 wt % dye. The polymer blend includes both uncharged and charged monomeric units.The glycol and polymer blend act to form a soft plug that forms in the orifice of the ink-jet pen. The soft plug prevents further evaporaion of water, but unlike a hard plug, is readily blown out upon firing. The charged units in the polymer blend contribute to water fastness and light fastness of the dye on paper. Further, by employing appropriate functional groups in the polymer blend, chemical degradation of the ink dye can be retarded on acid or alkaline papers.Type: GrantFiled: March 16, 1987Date of Patent: December 13, 1988Assignee: Hewlett-Packard CompanyInventors: James G. Bearss, Kenneth A. Norton
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Patent number: 4778833Abstract: Composition for the preservation of wood containing a wood preservative, such as a boron compound or a fluorine compound, in a polymer or polymer composition, which upon contact with water releases the wood preservative. Said composition is introduced into a hole in the wood or in a wood construction, whereafter the hole is sealed.Type: GrantFiled: December 11, 1986Date of Patent: October 18, 1988Assignee: Nederlandse Centrale Organisatie voor Toegepast- Natuurweten- Schappelijk OnderzoekInventors: Jan W. P. T. Van der Drift, Jan La Brijn
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Patent number: 4769443Abstract: Novel light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers have been synthesized; these are of the formula: ##STR1## in which R.sub.3 and R.sub.4 can be identical or different and are radicals of formula (III), (IV), (V), (VI) ##STR2## and R.sub.5 additionally can be a radical of formula VII ##STR3## and R.sub.4 is C.sub.2 -C.sub.Type: GrantFiled: August 3, 1987Date of Patent: September 6, 1988Assignee: Ciba-Geigy CorporationInventor: Giuseppe Cantatore
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Patent number: 4748074Abstract: Non linear optical compositions contain a vinylidene fluoride copolymer and an additive having molecular optoelelectronic activity, e.g. methyl-N-(2,4-dinitrophenyl)-alaninate. Poled films derived from the composite display optoelectronic activity. There is a marked contrast with known techniques in which single crystals are utilized. The compositions are used to make laminates which display good waveguide properties.Type: GrantFiled: December 16, 1985Date of Patent: May 31, 1988Assignee: British Telecommunications Public Limited CompanyInventors: Philippos Pantelis, Graham J. Davies
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Patent number: 4746577Abstract: Non linear optical compositions contain a vinylidene fluoride copolymer and an additive having molecular optoelectronic activity, e.g. methyl-N-(2,4-dinitrophenyl)-alaninate. Poled films derived from the composite display optoelectronic activity. There is a marked contrast with known techniques in which single crystals are utilized. The compositions are used to make laminates which display good waveguide properties.Type: GrantFiled: February 24, 1987Date of Patent: May 24, 1988Assignee: British Telecommunications Public Limited CompanyInventors: Philippos Pantelis, Graham J. Davies
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Patent number: 4745140Abstract: Aqueous-based adhesive compositions having good adhesion to a non-polar polymeric surface and to cellulosic materials comprise a dispersion of an adhesive comprising an N-vinyl lactam polymeric resin, a tackifier for such adhesive, and an effective amount of an ethylene/vinyl acetate copolymer emulsion stabilizer for the resin and tackifier. Preferred N-vinyl lactam polymeric resins are vinyl pyrrolidone/vinyl acetate copolymers and a preferred class of tackifier are the rosin ester tackifiers.Type: GrantFiled: March 13, 1987Date of Patent: May 17, 1988Assignee: Chesebrough-Pond's Inc.Inventor: Jagadish C. Goswami
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Patent number: 4743637Abstract: Novel flame retardant agents comprise polyalkylene oxides or a derivative thereof end-capped with brominated phthalimide groups, and have the general formulaeR--R.sup.1 --O--R.sup.1).sub.n R (I)(R--R.sup.1 --O--R.sup.1).sub.n' NH).sub.2 C.dbd.O (II)orR--R.sup.1 --OR.sup.1).sub.n" CH.sub.2).sub.3 C--R.sup.2 (III)wherein R is ##STR1## R.sup.1 is alkylene of from about 2 to about 6 carbon atoms; R.sup.1 is alkyl of from about 1 to about 6 carbon atoms; n is from about 4 to about 40; n' is from about 3 to about 15; and n" is from about 1 to about 10. Thermoplastic compositions, for example, polyphenylene ether compositions, rendered flame retardant with the novel compounds have a high resistance to additive vaporization and surface liquid exudation as well as desirable high flow characteristics.Type: GrantFiled: August 1, 1986Date of Patent: May 10, 1988Assignee: General Electric CompanyInventors: Robert J. Axelrod, Donald B. G. Jaquiss, John A. Tyrell
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Patent number: 4743647Abstract: Described herein are novel bismaleimides and prepregable resin compositions comprising these bismaleimides and one or more liquid coreactants and optionally, one or more other additives. The novel bismaleimides, such as alpha, alpha-bis-(4-maleimidophenyl)-meta-diisopropylbenzene, are characterized by the presence of three aromatic rings in the molecular structure and in some respects optimize the desirable characteristics of the one or two and four atomatic ring-containing bismaleimides in resins prepared therefrom.Type: GrantFiled: December 18, 1986Date of Patent: May 10, 1988Assignee: Amoco CorporationInventor: Linda A. Domeier
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Patent number: 4737410Abstract: Pressure-sensitive adhesives comprise blends of acrylate copolymer copositions with polyalkyloxazolines. The blends exhibit enhanced cohesive strength with balanced adhesive properties and are useful as coatings for sheet materials.Type: GrantFiled: November 28, 1986Date of Patent: April 12, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventor: Steven S. Kantner
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Patent number: 4737534Abstract: The instant invention relates to a process for controlling the viscosity of organic liquids by incorporating in said liquid a minor amount of polymer complex, and optionally a cosolvent for the ionic groups of said polymer. The polymer complex comprises the reaction product of a metal neutralized sulfonated polymer and a basic nitrogen-containing polymer, wherein the polymer complex is substantially soluble in said organic liquid, and pendant sulfonate groups which are substantially insoluble in said organic liquid. The optional cosolvent is selected which will solubilize the pendant sulfonate groups and provide a reasonably homogeneous mixture of solvent, cosolvent and polymer complex. The preferred compositions prepared by the method of the instant invention comprise an organic liquid having a solubility parameter of from 6 to 10.5 in combination with a polymer complex containing from 0.2 up to 10.Type: GrantFiled: April 8, 1985Date of Patent: April 12, 1988Assignee: Exxon Research and Engineering CompanyInventors: Robert D. Lundberg, Robert R. Phillips, Dennis G. Peiffer, Ilan Duvdevani
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Patent number: 4734446Abstract: Polymeric compositions comprised of particularly disclosed oil-soluble polymers and specific oil-soluble acrylate polymerization products are disclosed. The oil-soluble polymer (A) is a polymer selected from the group consisting of a non-aromatic mono-olefin having at least three carbon atoms, and a copolymer of the non-aromatic mono-olefin with an aromatic monoolefin, the polymer having a number average molecular weight of about 500 to about 100,000. The oil-soluble acrylate polymerization product (B) is at least one ester of the formula CH.sub.2 .dbd.C(X)--COOR wherein X is hydrogen or an alkyl or aryl group, and R is a monovalent hydrocarbyl group containing at least four carbon atoms, or an ether derivative of said hydrocarbyl group. The components (A) and (B) are preferably present in a weight ratio of (A):(B) of about 20:1 to about 1:10.Type: GrantFiled: October 27, 1986Date of Patent: March 29, 1988Assignee: The Lubrizol CorporationInventor: Craig D. Tipton
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Patent number: 4731408Abstract: Processable conductive polymers prepared by an oxidative polymerization are disclosed. A monomer which is oxidatively polymerizable into an electrically conductive polymer is polymerized with the aid of a chemical oxidizing agent in a reaction medium containing a dispersed phase of a polymeric counterion having anionic surface character. The polymeric counterion, which is in affiliation with the oxidatively polymerized polymer, confers processability to the conductive polymer material.Type: GrantFiled: December 20, 1985Date of Patent: March 15, 1988Assignee: Polaroid CorporationInventor: Stanley J. Jasne
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Patent number: 4727102Abstract: Polyolefins which are made self-extinguishing by means of flame-retarding compositions comprising ammonium polyphosphate, melamine cyanurate and a hydroxyalkyl-derivative of isocyanuric acid at least partially in the form of a homopolymer.Type: GrantFiled: July 15, 1985Date of Patent: February 23, 1988Assignee: V.A.M.P. S.r.l.Inventor: Luciano Scarso
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Patent number: 4701493Abstract: An acrylic modified styrenic/N-arylmaleimide copolymer containing composition which exhibits excellent melt flow properties, impact strength and gloss upon molding is disclosed.Type: GrantFiled: July 14, 1986Date of Patent: October 20, 1987Assignee: Atlantic Richfield CompanyInventor: Barry D. Dean
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Patent number: 4696961Abstract: Novel light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers have been synthesized; these are of the formula: ##STR1## in which R.sub.3 and R.sub.5 can be identical or different and are radicals of formula (III), (IV), (V), (VI) ##STR2## and R.sub.5 additionally can be a radical of formula VII ##STR3## and R.sub.4 is C.sub.2 -C.sub.Type: GrantFiled: September 20, 1984Date of Patent: September 29, 1987Assignee: Ciba-Geigy CorporationInventor: Giuseppe Cantatore
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Patent number: 4684692Abstract: A moldable composition which comprises a novel random bromostyrene-containing copolymer and a flame-retardant synergist is disclosed. The molded composition exhibits at least a 94V-1 classification when tested in accordance with Underwriters' Laboratories Inc. Test Method UL94.Type: GrantFiled: December 16, 1986Date of Patent: August 4, 1987Assignee: Atlantic Richfield CompanyInventor: Usama E. Younes