Solid Polymer From Oxygen Heterocycle Monomer Patents (Class 524/517)
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Patent number: 4868226Abstract: A process for producing a filler-containing polypropylene resin composition is disclosed. The composition comprises (a) from 27 to 87% by weight of a polypropylene resin, (b) from 3 to 15% by weight of a modified polypropylene resin containing from 0.1 to 3 mol% of an unsaturated dicarboxylic acid anhydride repeating unit, (c) from 5 to 30% by weight of an ethylene copolymer composed of from 82 to 98.7 mol% of an ethylene repeating unit, from 1 to 15 mol% of an ester repeating unit selected from alkyl acrylates and alkyl methacrylates having from 1 to 8 carbon atoms in the alkyl moiety thereof, and from 0.3 to 3 mol% of an unsaturated dicarboxylic acid anhydride repeating unit, and (d) from 5 to 40% by weight of a filler. The process comprises melt-mixing the components (a), (b), and (d) and then melt-mixing the resulting mixture with the component (c).Type: GrantFiled: April 13, 1988Date of Patent: September 19, 1989Assignee: Sumitomo Chemical CompanyInventors: Tatsuyuki Mitsuno, Hideo Shinonaga, Akio Daimon
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Patent number: 4863990Abstract: Modified solution polymer compositions useful for films, coatings, caulks, adhesives, and mastics having advantitious properties such as low surface tack, short drying time, high tensile strength, and hardness, uses of such compositions, and processes for preparing them are disclosed.Type: GrantFiled: December 16, 1987Date of Patent: September 5, 1989Assignee: Rohm and Haas CompanyInventors: Shang-Jaw Chiou, Donald A. Winey
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Patent number: 4822654Abstract: A vulcanizable rubber composition comprising (1) 100 parts by weight of a polymer composition comprising(I) a vinylidene fluoride resin,(II) at least one rubber selected from the group consisting of acrylic rubbers, .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers and hydrides of .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers, said acrylic rubber consisting of (A) 30 to 99.9% by weight of an alkyl acrylate and/or an alkoxy-substituted alkyl acrylate, (B) 0.1 to 10% by weight of a crosslinkable monomer and (C) 0 to 70% by weight of another ethylenically unsaturated compound copolymerizable with (A) and (B) (the sum of (A), (B) and (C) is 100% by weight) and said .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubber consisting of (D) 10 to 60% by weight of an .alpha.,.beta.Type: GrantFiled: March 10, 1988Date of Patent: April 18, 1989Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Yasuhiko Takemura, Shinichiro Zen, Yoshiaki Zama, Hiroji Enyo
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Patent number: 4820753Abstract: A sonic window suitable for use in sonar applications wherein an elastomer such as natural or synthetic natural rubbers, a low air entrapping fiber or fibril used for reinforcement, fillers, and thermosetting resins are formed into desired window configuration. The low air entrapment associated with the fiber or fibrils produces a remarkably sonicly transparent window.Type: GrantFiled: March 15, 1988Date of Patent: April 11, 1989Assignee: The B. F. Goodrich CompanyInventors: Samuel J. Caprette, Jr., Wilson N. Smith, Jr.
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Patent number: 4820774Abstract: A vulcanizable elastomer composition comprising an .alpha.-olefin copolymer comprising ethylene and an .alpha.-olefin(s) and an ethylene copolymer comprising ethylene and at least one member selected from the group consisting of acrylic and methacrylic esters, which has an excellent roll-processability and gives by vulcanization an elastomeric material having well-balanced properties in respect of resistance to heat and oil, low-temperature property and the like.Type: GrantFiled: October 14, 1987Date of Patent: April 11, 1989Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroyoshi Takao, Yoshio Tanimoto, Kiyosi Ikeda, Masahiro Fukuyama
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Patent number: 4818790Abstract: A room temperature-curable resin composition consisting essentially of (A) a vinyl polymer containing a basic nitrogen atom and (B) a compound containing both an epoxy group and a hydrolyzable silyl group in each molecule. The composition is especially useful as a paint, an adhesive, or a sealing agent.Type: GrantFiled: August 28, 1985Date of Patent: April 4, 1989Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Masataka Ooka, Shinichi Kuwamura, Hiroshi Ozawa, Hiroshi Ozawa
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Patent number: 4778833Abstract: Composition for the preservation of wood containing a wood preservative, such as a boron compound or a fluorine compound, in a polymer or polymer composition, which upon contact with water releases the wood preservative. Said composition is introduced into a hole in the wood or in a wood construction, whereafter the hole is sealed.Type: GrantFiled: December 11, 1986Date of Patent: October 18, 1988Assignee: Nederlandse Centrale Organisatie voor Toegepast- Natuurweten- Schappelijk OnderzoekInventors: Jan W. P. T. Van der Drift, Jan La Brijn
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Patent number: 4775713Abstract: When a hydrophobic thermoplastic resin such as an olefin resin and a water-insoluble or non-water-swelling polymer containing a carboxylic acid salt group are melt-kneaded in the presence of water, phase inversion of forming a dispersion comprising water as the dispersion medium phase and resin particles as the dispersed phase is caused even if the amount of water is very small. If an anionic surfactant, optionally together with a solvent or oil, is made present in the composition to be melt-kneaded, the size of dispersed particles can be greatly reduced in the formed aqueous dispersion even if a resin having a very high molecular weight or a high melt viscosity is used.Type: GrantFiled: December 16, 1987Date of Patent: October 4, 1988Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Shiro Homma, Masatoshi Kashiwagi, Mutsuhiro Tanaka
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Patent number: 4764546Abstract: A filler-containing polypropylene resin composition and a process for producing the same are disclosed. The composition comprises (a) from 27 to 87% by weight of a polypropylene resin, (b) from 3 to 15% by weight of a modified polypropylene resin containing from 0.1 to 3 mol % of an unsaturated dicarboxylic acid anhydride repeating unit, (c) from 5 to 30% by weight of an ethylene copolymer composed of from 82 to 98.7 mol % of an ethylene repeating unit, from 1 to 15 mol % of an ester repeating unit selected from alkyl acrylates and alkyl methacrylates having from 1 to 8 carbon atoms in the alkyl moiety thereof, and from 0.3 to 3 mol % of an unsaturated dicarboxylic acid anhydride repeating unit, and (d) from 5 to 40% by weight of a filler. The process comprises melt-mixing the components (a), (b) and (d) and then melt-mixing the resulting mixture with the component (c).Type: GrantFiled: April 23, 1987Date of Patent: August 16, 1988Assignee: Sumitomo Chemical Co., Ltd.Inventors: Tatsuyuki Mitsuno, Hideo Shinonaga, Akio Daimon
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Polyolefinic elastomer compositions, production process and articles obtained from said compositions
Patent number: 4762877Abstract: The compositions according to the invention comprise at least one unsaturated polyolefin elastomer, at least one vulcanizing agent and at least one vulcanization activator for the said elastomer, and in addition at least one terpolymer (A) comprising repeat units derived from ethylene, repeat units derived from maleic anhydride and repeat units derived from at least one ester of acrylic or methacrylic acid.For their manufacture, the unsaturated polyolefin elastomer, the vulcanizing agent, the vulcanization activator and the terpolymer are mixed at a temperature of between 70.degree. C. and 150.degree. C. for a sufficient time to produce homogenization of the mixture.Application to the production of articles such as seals, flexible connection pipings, belts, and the like.Type: GrantFiled: August 13, 1986Date of Patent: August 9, 1988Assignee: Societe Chimique Des Charbonnages S.A.Inventor: Alain Heilbrunn -
Patent number: 4758617Abstract: This invention provides a process for preparing a water-absorbing resin which comprises the steps of mixing powder of an inorganic inactive substance with a water-absorbing resin having carboxylate-containing monomer units, and adding water and a high molecular-weight cross-linking agent to the mixture to perform cross-linking reaction and evaporation of water, the cross-linking agent being selected from a specified copolymer (1) and a specified mixture of copolymers (2), and also provides a water-absorbing resin prepared by the process.The process of the invention gives water-absorbing resins improved not only in water-absorbing ability, rate of water absorption, gel strength after water absorption and unlikelihood of affording a wetty feeling after water absorption but also in capability of retaining water under pressure.Type: GrantFiled: June 16, 1986Date of Patent: July 19, 1988Assignee: Arakawa Kagaku Kogyo Kabushiki KaishaInventors: Shozo Tanioku, Nobuyuki Oshima, Jun-ichi Maeno, Kiyoshi Sato
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Patent number: 4758629Abstract: A melt processible multi-phase thermoplastic composition comprising a blend of:(A) 5-95 parts by weight of a crystalline polyolefin resin of a substantially saturated homopolymer or copolymer of polymerized monomer units of C.sub.2 -C.sub.8 alpha monoolefins forming one phase of the composition,(B) 5-95 parts by weight of a crosslinked ethylene-containing copolymer forming a second phase of the composition comprising units derived from (1) ethylene, (2) alkyl acrylates or alkyl methacrylates wherein the alkyl group contains 1-6 carbon atoms or vinyl esters of monocarboxylic acids having 2-6 carbon atoms, and (3) glycidyl acrylate or glycidyl methacrylate.Type: GrantFiled: May 28, 1986Date of Patent: July 19, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Edward J. Deyrup, Coretta C. Tam
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Patent number: 4748196Abstract: A water repellent composition comprising an emulsion prepared by emulsifying in water (A) a wax having a melting point of from 40.degree. to 90.degree. C. and (B) an olefin-maleic anhydride derivative in the presence of (C) a water-soluble alkaline compound and/or a nonionic emulsifier.Type: GrantFiled: September 18, 1986Date of Patent: May 31, 1988Assignees: Mitsubishi Chemical Industries, Ltd., Yoshino Gpysum Company, Ltd.Inventors: Katsuhiko Kuroda, Toru Tagawa, Kiyoharu Yoshimi, Yasoji Ozawa
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Patent number: 4692483Abstract: A water-based paint composition comprising:(A) a reaction product prepared by reacting a butadiene-based polymer and/or a drying oil with an .alpha.,.beta.-unsaturated dicarboxylic acid anhydride followed by reacting with water, a primary monoalcohol or a dialkylamine; and(B) a modified epoxy resin with acrylic acid, methacrylic acid or unsaturated fatty acid, or a modified phenol resin with glycidyl acrylate or methacrylate, components (A) and(B) being dispersed in an aqueous medium containing a base.Type: GrantFiled: April 25, 1986Date of Patent: September 8, 1987
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Patent number: 4686257Abstract: A filler-containing polypropylene resin composition is disclosed, comprising (a) from 30 to 90% by weight of a polypropylene resin, (b) from 2.5 to 38% by weight of an ethylene copolymer composed of from 82 to 98.7 mol % of ethylene, from 1 to 15 mol % of an ester selected from alkyl acrylate and alkyl methacrylates having from 1 to 8 carbon atoms in the alkyl moiety thereof and from 0.3 to 3 mol % of an unsaturated dicarboxylic acid anhydride, and (c) from 5 to 50% by weight of a filler. Molded products obtained from the composition have improved finishing properties, such as adhesion, coating properties, printability, and the like.Type: GrantFiled: July 25, 1986Date of Patent: August 11, 1987Assignee: Sumitomo Chemical Company, LimitedInventors: Tatsuyuki Mitsuno, Teruhisa Koyama, Hideo Shinonaga, Akio Daimon
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Patent number: 4661536Abstract: An in situ polymerization process is disclosed whereby an .alpha.-amino acid N-carboxyanhydride is blended intimately and efficiently with one or more calcium phosphate biomaterials. The polymerization proceeds at ambient temperature and pressure without the need for initiators or surface modification of the calcium phosphate biomaterials. The resulting composite material may subsequently be ground and blended with a compatible water soluble pore-forming agent and then molded to form dense, shaped objects which may be made porous by leaching out said water soluble pore-forming agent. The resulting shaped objects may then be used as hard tissue prosthetics either alone or in conjunction with conventional prostheses.Type: GrantFiled: October 2, 1986Date of Patent: April 28, 1987Assignee: The Dow Chemical CompanyInventors: Linneaus C. Dorman, Paul A. Meyers
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Patent number: 4636437Abstract: A coating composition substantially prevents fraying of glass fiber yarn packages. The composition is composed of an aqueous solution of a resin formed of the hydrolysis product of a copolymer of vinyl aromatic monomer and maleic anhydride, an organo silane glass fiber anchoring agent and an effective amount of a water-soluble pyrrolidone-containing polymer sufficient to form a protective film over the glass fiber.Type: GrantFiled: November 5, 1984Date of Patent: January 13, 1987Assignee: Owens-Corning Fiberglas CorporationInventors: Donald J. Algrim, Donn R. Vermilion, Donald J. Hammond, Richard M. Haines
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Patent number: 4634731Abstract: A moldable composition which comprises a novel random bromostyrene-containing copolymer, thermoplastic resin, preferably polycarbonate and a flame retardant synergist is disclosed. The molded composition exhibits at least a 94 V-1 classification when tested in accordance with Underwriters Laboratories Inc. Test Method UL94.Type: GrantFiled: December 24, 1984Date of Patent: January 6, 1987Assignee: Atlantic Richfield CompanyInventor: Usama E. Younes
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Patent number: 4619951Abstract: The present invention relates to a method of manufacturing sealing compositions for electric wires, wherein one mixes together a filler (comprised chiefly of an alkaline earth carbonate), a binder component, and possibly additives of the type common in the art.The binder component is a combination of two binders: binder I is a homopolymer of 1,3-butadiene or a copolymer which is essentially obtained from 1,3-butadiene; and binder II is a polymer based on 1,3-butadiene and having laterally extending succinic anhydride groups.The sealing compositions are distinguished by good processibility and high dielectric strength.Type: GrantFiled: September 20, 1985Date of Patent: October 28, 1986Assignee: Chemische Werke Huls AktiengesellschaftInventors: Klaus Gorke, Josef Schoppen
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Patent number: 4613646Abstract: A surface-treating water-in-oil emulsion composition, which is essentially wax-free, comprising water, hydrocarbon solvent, film-former, nonionic emulsifier and an alpha-olefin/maleic anhydride polymer.Type: GrantFiled: April 15, 1985Date of Patent: September 23, 1986Assignee: S. C. Johnson & Son, Inc.Inventor: Paul E. Sandvick
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Patent number: 4611015Abstract: Polymer concrete compositions comprising an unsaturated thermosettable resin(s) and/or ethylenically unsaturated monomer(s), an aggregate component and a water absorbent polymer are cured to provide polymer concrete with enhanced adhesion to substrates, especially wet concrete. A primer or coating composition for concrete comprising a water absorbent polymer and an unsaturated thermosettable composition is also disclosed.Type: GrantFiled: December 13, 1984Date of Patent: September 9, 1986Assignee: The Dow Chemical CompanyInventors: Robert E. Hefner, Jr., Deborah I. Haynes
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Patent number: 4609701Abstract: Blends of (a) a vinyl chloride polymer having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25.degree. C. falling within the range of about 1.50 to about 1.85; (b) a copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride in which the relative proportions of said compound and said anhydride fall within the range of about 91 to about 70 weight percent of said compound and about 9 to about 30 weight percent of said anhydride; and (c) a tin-containing stabilizer and an impact modifier for vinyl chloride polymers. These blends contain 60 to 40 weight percent of (a) and 40 to 60 weight percent of (b) and have an Izod impact strength (ASTM D 256, Method A) of at least 0.5 foot pound per inch; a heat deflection temperature (ASTM D 648) at 66 psi of at least 75.degree. C.; and a dynamic thermal stability of at least 10 minutes.Type: GrantFiled: February 4, 1985Date of Patent: September 2, 1986Assignee: Ethyl CorporationInventors: Jesse D. Jones, Edwin D. Hornbaker
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Patent number: 4609591Abstract: A non-aqueous coating for glass fibers consisting of 100 percent solids formulation of organosilane, an ethylene-ethyl acrylate copolymer, a hydrogenated heterocyclic hydrocarbon thermoplastic resin, a microcrystalline wax, a viscosity-reducing agent, an antioxidizing agent, and a whitening agent. When employing glass fibers coated with the size composition of the present invention in a non-acid modified polypropylene resin, the size formulation also includes a maleic anhydride-modified polyolefin. Glass fibers coated with the size composition of this invention are suitable for use in reinforcing resinous products, particularly polypropylene, to achieve a white or translucent molded glass fiber-reinforced product.Type: GrantFiled: May 10, 1985Date of Patent: September 2, 1986Assignee: Owens-Corning Fiberglas CorporationInventors: Jean-Claude Pollet, Gordon P. Armstrong, Martin C. Flautt
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Patent number: 4598118Abstract: A coating composition which produces glossy, clear coatings comprises a terpolymer of an anhydride, a higher alphaolefin and either a lower alphaolefin or a mono-alkenyl aromatic compound; an acrylic emulsion polymer and the balance of the composition being an aqueous vehicle.Type: GrantFiled: June 28, 1983Date of Patent: July 1, 1986Assignee: S. C. Johnson & Son, Inc.Inventors: Frederick C. Hansen, Richard A. Kiehlbauch
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Patent number: 4596841Abstract: A composition for bonding metal powders which is used in an amount of at most about 7 parts by weight as the solids content per 100 parts by weight of a metal powder for obtaining a flexible metal powder molding which is capable of tolerating deformation at a radius of curvature of up to 15 mm, the composition comprising as a main monomer an acrylic polymer having a weight average molecular weight of about 50,000 to 1,500,000 which comprises alkyl (meth)acrylate having an average carbon atom number of 3 to 12 in the alkyl moiety, or a mixture of the acrylic polymer and a resin which gives adhesive property, as a main component, the main component having a glass transition temperature in a range of about -70.degree. to -10.degree. C. and an elastic modulus in a range of about 0.05 to 50 kg/cm.sup.2 at 25.degree. C.Type: GrantFiled: February 25, 1985Date of Patent: June 24, 1986Assignee: Nitto Electric IndustrialInventors: Toshiharu Konishi, Yoshiki Kobayashi, Takefumi Shimomura, Yukio Shimizu
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Patent number: 4585824Abstract: A glass fiber-reinforced heat resistant resin composition which comprises:from 5 to 90% by weight of a pelletized polymer (A) obtained by suspension-polymerizing a vinyl aromatic monomer optionally together with an unsaturated nitrile monomer and a vinyl monomer copolymerizable therewith, in the presence of chopped glass fiber strands, and comprising from 50 to 90% by weight of the chopped glass fiber strands and from 50 to 10% by weight of a resin component consisting essentially of from 40 to 100% of residues of the vinyl aromatic monomer, from 0 to 60% of residues of the unsaturated nitrile monomer and from 0 to 30% of residues of the copolymerizable vinyl monomer;from 95 to 10% by weight of a polymer (B) comprising from 10 to 50% of residues of a maleimide monomer, from 90 to 50% of residues of a vinyl aromatic monomer, from 0 to 10% of residues of maleic anhydride and from 0 to 30% of residues of a vinyl monomer copolymerizable therewith.Type: GrantFiled: October 5, 1984Date of Patent: April 29, 1986Assignee: Mitsubishi Monsanto Chemical CompanyInventors: Minoru Uchida, Sadao Ikuma
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Patent number: 4558095Abstract: A coating composition comprising:(a) A graft copolymer, having surfactant properties, comprising the reaction product of (i) a vinyl copolymer comprising vinyl chloride, a vinyl carboxylate ester, and a source of hydroxyl groups, such that the hydroxyl content prior to reaction is about 0.5 to about 8% by weight of the vinyl copolymer and of which about 1 to about 75% of said hydroxyl groups have been reacted with (ii) an anhydride copolymer comprising the reaction product of an aromatic monomer and a dicarboxylic acid anhydride, such that the graft copolymer has a molecular weight of about 2,000 to about 30,000, and a vinyl copolymer/anhydride copolymer weight ratio of about 20 to about 2, of which a sufficient number of carboxyl groups have been hydrolyzed to produce surfactant properties;(b) a dispersible powder,(c) optionally, other hard resins,(d) optionally, a rubbery polymer,(e) optionally, a supplemental surfactant,all mixed in an organic solvent.Type: GrantFiled: April 1, 1985Date of Patent: December 10, 1985Assignee: Union Carbide CorporationInventors: Bruce P. Barth, Charles B. Mallon
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Patent number: 4556686Abstract: Improved stable crosslinked dispersion which is further stabilized with butylated melamine formaldehyde resin. The dispersion to which the improvement of the invention applies is formed by addition polymerization of selected monomers in the presence of an organic liquid which is a solvent for the monomers, but a non-solvent for the polymer and a polymeric dispersion stabilizer having solvated and non-solvated segments.Type: GrantFiled: June 20, 1985Date of Patent: December 3, 1985Assignee: Ford Motor CompanyInventor: Stanley K. Horvath
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Patent number: 4546149Abstract: A vinylidene fluoride resin composition which comprises 100 parts by weight of vinylidene fluoride resin and 0.1 to 10 parts by weight of glycidyl (meth)acrylate resin, said glycidyl (meth)acrylate resin being a polymer composed of at least one of glycidyl acrylate and glycidyl methacrylate, or a copolymer composed of a monomer selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate and ethyl methacrylate and at least one of glycidyl acrylate and glycidyl methacrylate.The resin composition has improved thermal stability and electrical properties, and is immune to deleterious discoloration.Type: GrantFiled: April 30, 1984Date of Patent: October 8, 1985Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Kunizoh Kidoh, Mitsuru Ohta
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Patent number: 4537926Abstract: Described is an aqueous chip resistant coating composition exhibiting a viscosity of at least 5,000 centipoise, preferably containing binders with a high molecular weight, preferably at least 20,000. Although these coatings may be applied to a variety of substrates, for coating electrocoated substrates the following eight binders are particularly preferred: ethylene vinyl acetate copolymer, carboxylated ethylene vinyl acetate, epoxy functional acrylic resin, carboxylated styrene-butadiene resin, carboxylated acrylic, hydroxy functional acrylic, self-crosslinking acrylic; and carboxylated PVC acrylic. Generally, it is preferred to apply the chip resistant coating via an airless spray and the heat curing the coating.Type: GrantFiled: April 6, 1984Date of Patent: August 27, 1985Assignee: Grow Group, Inc.Inventors: Daniel M. Kivel, Gerhard M. Weber
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Patent number: 4537601Abstract: This invention relates to compositions comprising (1) acrylic-type ester-acrylonitrile copolymers and (2) polymeric polyamines; and to such compositions in combination with organic liquids such as hydrocarbon fluids in which such compositions are effective as antistatic agents.Type: GrantFiled: October 29, 1984Date of Patent: August 27, 1985Assignee: Petrolite CorporationInventor: Michael I. Naiman
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Patent number: 4529765Abstract: A coating composition which cures at ambient temperatures of 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, the binder contains:A. an acrylic amino ester polymer of polymerized monomers of methyl methacrylate and monomers from the group of alkyl methacrylate and alkyl acrylate each having 2-12 carbon atoms in the alkyl group and the polymer has pendent amino ester or hydroxy amino ester groups wherein the amine group is a primary; andB.Type: GrantFiled: April 9, 1984Date of Patent: July 16, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventors: Herman C. DenHartog, Aloysius N. Walus
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Patent number: 4525521Abstract: A coating composition which cures at ambient temperatures of 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, the binder contains about:A. 60-80% by weight, based on the weight of the binder, of an acrylic polymer of polymerized monomers of methyl methacrylate and an alkyl methacrylate, an alkyl acrylate or mixtures thereof, each having 2-12 carbon atoms in the alkyl group and the polymer has pendent amino ester or hydroxy amino ester groups;B. 20-40% by weight, based on the weight of the binder, of a glycidyl acrylic crosslinking polymer of polymerized monomers of glycidyl methacrylate or glycidyl acrylate and an alkyl methacrylate, alkyl acrylate or mixtures thereof, each having 2-12 carbon atoms in the alkyl group.The composition is useful as an exterior finish for automobiles and trucks and for repairing finishes of automobiles and trucks.Type: GrantFiled: July 27, 1984Date of Patent: June 25, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventors: Herman C. DenHartog, Aloysius N. Walus
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Patent number: 4523922Abstract: The viscosity of aqueous printing inks for gravure printing is adjusted by means of partially organophilic gels which contain plastics mixtures of at least one polymer swelling in water and at least one polymer not swelling in water or to an insignificant extent only, in a solvent mixture of at least two hydrophilic organic hydroxy compounds and one hydrophobic organic hydroxy compound. The printing inks prepared with the aid of the thickener mixtures of the invention contain up to 90% of water, and can be handled as textile printing pastes.Gravure printing inks on the basis of such plastics gels containing disperse dyestuffs are suitable for the manufacture of transfer printing paper sheets. Since the thickening system adjusting the viscosity contains aqueous alcohols, if any, and no solvents as usual in transfer printing inks, no special measures have to be taken with respect to flammability and explosion risks.Type: GrantFiled: April 2, 1984Date of Patent: June 18, 1985Assignee: Hoechst AktiengesellschaftInventors: Sienling Ong, Ulrich Karsunky, Helmut Schmidt
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Patent number: 4495325Abstract: Coating compositions containing large amounts of polymer-bound ultraviolet radiation absorbing stabilizers and cross linkers give highly ultraviolet absorbent properties.Type: GrantFiled: February 25, 1983Date of Patent: January 22, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventors: Michael DeBergalis, Robert P. O'Fee
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Patent number: 4491646Abstract: Disclosed is an improved aqueous latex adhesive composition of the type having an aqueous latex in admixture with an organic solvent-dispersed multi-isocyanate cross-linking agent and a thickener. The improvement for a room temperature curable adhesive composition having improved water resistance comprises the curable ingredients consisting essentially of an aqueous hydroxyl functional acrylic latex which contains hydroxyl groups as its only isocyanate reactive functionality and the multi-isocyanate cross-linking agent. Desirably, fillers incorporated into the adhesive composition are formed into a filler grind prior to incorporation into the adhesive composition. The adhesive composition is especially useful as a structural adhesive in structural lamination manufacture.Type: GrantFiled: September 29, 1983Date of Patent: January 1, 1985Assignee: Ashland Oil, Inc.Inventors: Norma J. Gruber, Clois E. Powell
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Patent number: 4478962Abstract: Acid-curable furfuryl alcohol prepolymer binders have improved properties when admixed with a dibasic acid di-ester of the compositionR.sup.1 O.sub.2 C(CH.sub.2).sub.n CO.sub.2 R.sup.2when n is from 1 to 8, R.sup.1 is furfuryl, and R.sup.2 is furfuryl or methyl. The diesters are preferably added in the amount of 5-35% by weight of total composition. These compositions are particularly useful in the preparation of sand cores and molds for foundry use which have improved strength and hardness. These furfuryl esters are also acid-curable and can be used alone as resin binders.Type: GrantFiled: July 5, 1983Date of Patent: October 23, 1984Assignee: CL Industries, Inc.Inventor: Wayne D. Woodson
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Patent number: 4476273Abstract: Moldings having enhanced physical properties are made from compositions of a conjugated diene polymer, calcium carbonate and certain .alpha.,.beta.-unsaturated carboxylic modifiers.Type: GrantFiled: November 8, 1982Date of Patent: October 9, 1984Assignee: Phillips Petroleum CompanyInventor: Guy Senatore
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Patent number: 4468493Abstract: A high solid coating composition comprising(A) a film-forming polymer having functional group(s) capable of reacting with the crosslinking agent (D) hereinafter referred to,(B) a volatile organic liquid diluent in which the polymer (A) is carried,(C) polymer microparticles having an average diameter of from 0.02 to 40 microns, which are insoluble in the combination of the film-forming polymer (A) and the diluent (B) and are maintained in a stabilized state of dispersion therein, and(D) a crosslinking agent dissolved in the diluent (B), which is characterized by the fact that the microparticles (C) are composed of crosslinked copolymer obtained by copolymerizing at least one of the polymerizable amino acid compounds of the formula: ##STR1## with other polymerizable .alpha.,.beta.-ethylenically unsaturated monomers, at least part of which is crosslinking monomer.Type: GrantFiled: January 25, 1983Date of Patent: August 28, 1984Assignee: Nippon Paint Co., Ltd.Inventors: Shinichi Ishikura, Kazunori Kanda, Katsuaki Kida, Ryuzo Mizuguchi
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Patent number: 4463120Abstract: A process for preparing an aqueous adhesive composition which comprises preparing a solvent dispersion by mixing rubber, carbon black, vulcanizing agent, tackifying resin and accelerator with sufficient organic solvent to form a solvent dispersion and thereafter emulsifying the solvent dispersion in the presence of water to form an aqueous emulsion. The aqueous emulsion may be used to bond unvulcanized rubber compounds, such as a tread stock to the carcass portion during the formation of a tire.Type: GrantFiled: January 24, 1983Date of Patent: July 31, 1984Assignee: SWS Silicones CorporationInventors: Wendell Collins, Howard L. Brooks
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Patent number: 4454279Abstract: The viscosity of aqueous printing inks for gravure printing is adjusted by means of partially organophilic gels which contain plastics mixtures of at least one polymer swelling in water and at least one polymer not swelling in water or to an insignificant extent only, in a solvent mixture of at least two hydrophilic organic hydroxy compounds and one hydrophobic organic hydroxy compound. The printing inks prepared with the aid of the thickener mixtures of the invention contain up to 90% of water, and can be handled as textile printing pastes.Gravure printing inks on the basis of such plastics gels containing disperse dyestuffs are suitable for the manufacture of transfer printing paper sheets. Since the thickening system adjusting the viscosity contains aqueous alcohols, if any, and no solvents as usual in transfer printing inks, no special measures have to be taken with respect to flammability and explosion risks.Type: GrantFiled: August 15, 1983Date of Patent: June 12, 1984Assignee: Hoechst AktiengesellschaftInventors: Sienling Ong, Ulrich Karsunky, Helmut Schmidt
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Patent number: 4447580Abstract: A resin composition comprising (A) a polymer having, in the molecule, at least two groups represented by the following structural formula (I): ##STR1## wherein R.sub.1 is isopropyl, sec-butyl, tert-butyl, a C.sub.5-20 alkyl group, a C.sub.3-20 cycloalkyl group, a C.sub.5-20 alkenyl group, a C.sub.3-20 hydroxyalkyl group, a C.sub.5-20 alkoxyalkyl group, a C.sub.3-20 aminoalkyl group, a C.sub.6-20 aryl group or a C.sub.6-20 arylalkyl group, and n is 0, 1 or 2, and (B) a polymer having an electron attractive group and an .alpha.,.beta.-ethylenic double bond adjacent thereto. Though said composition is stable at room temperature, it is crosslinked and cured at high temperatures because the amino group of the polymer (A) adds to the double bond of the polymer (B). Accordingly, said resin composition is suitable for use as a cathodic electrocoating material.Type: GrantFiled: November 12, 1981Date of Patent: May 8, 1984Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hideo Ai, Naohiro Tsuruta
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Patent number: 4429070Abstract: Composition useful as an emulsion for coating compositions, binders for non-wovens, adhesives, and the like comprising a blend of an emulsion acid copolymer and an emulsion halohydroxypropyl ammonium liposalt copolymer, at least one of which being film forming. Also, a process for producing tough, solvent resistant films, and the reacted films.Type: GrantFiled: November 12, 1981Date of Patent: January 31, 1984Assignee: Rohm and Haas CompanyInventors: Mary L. Gioeni, Richard F. Merritt
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Patent number: 4423172Abstract: A self-curable coating composition for cathode-precipitating electrodeposition is disclosed which essentially comprises a water-dispersible resin having a carbon-carbon double bond and a tertiary amino group and an epoxy resin having a teritary amino group and an unsaturated group of the formula ##STR1## The two resins are neutralized by an acid to render the composition water-soluble or water-dispersible.Type: GrantFiled: March 30, 1982Date of Patent: December 27, 1983Assignee: Nippon Oil Co., Ltd.Inventors: Yutaka Otsuki, Yoshihiko Araki, Hiroyoshi Omika, Hajime Hara, Kazuho Aoyama
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Acid containing emulsion copolymer crosslinked by a halohydroxypropyl ammonium salt solution polymer
Patent number: 4420583Abstract: A composition useful in coatings, binders, adhesives, and the like comprises a stable blend of a carboxylic acid copolymer emulsion and a halohydroxy propyl ammonium copolymer solution. The blend is curable, after activation by base, to a crosslinked insoluble alloy polymer.Type: GrantFiled: June 24, 1982Date of Patent: December 13, 1983Assignee: Rohm and Haas CompanyInventor: Thomas W. Hutton -
Patent number: 4417019Abstract: An improved molding compound comprising a polyolefin modified with an unsaturated carboxylic acid, and has dispersed therein a filler material comprising a mixture of glass fiber and calcium silicate. In one embodiment the molding compound also includes an ethylene-.alpha.-olefin copolymer rubber.Type: GrantFiled: August 5, 1982Date of Patent: November 22, 1983Assignee: TOA Nenryo Kogyo Kabushiki KaishaInventors: Noboru Yamamoto, Keiichi Morikubo, Masato Komatsu, Kazuo Sei
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Patent number: 4415697Abstract: Coating compositions comprising hydroxy functional film formers and a novel flow control additive comprising a stable crosslinked dispersion prepared by addition polymerization of (a) first and second ethylenically unsaturated monomers each bearing functionality capable of crosslinking with the other and (b) at least one other monoethylenically unsaturated monomer, in the presence of (I) organic liquid which is a solvent for the polymerizable monomers, but a non-solvent for the resultant polymer and (II) a novel polymeric dispersion stabilizer.Type: GrantFiled: August 14, 1981Date of Patent: November 15, 1983Assignee: Ford Motor CompanyInventors: Stephen C. Peng, John D. Nordstrom
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Patent number: 4414342Abstract: Glass fiber reinforced thermoplastic resins composing glass fiber, a thermoplastic resin and a copolymer of an ethylenically-unsaturated monomer and from about 1 to about 20 wt. % of copolymerizable functional monomer exhibit a marked improvement in impact properties, heat distortion values and ductility, and improved adhesion between matrix resin and fiber.Type: GrantFiled: December 7, 1981Date of Patent: November 8, 1983Assignee: Borg-Warner CorporationInventors: John C. Falk, Klementina F. Khait
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Patent number: 4414355Abstract: An insulative coating composition for providing water-repellancy to and protecting communication wire comprises an admixture of an anhydride copolymer, a flexibilizing copolymer, a suitable solvent system, a hydrophobic, soluble, compatible fluoroaliphatic radical-containing composition and optionally, a mercaptan, and optionally, an antioxidant. Articles coated with the insulative composition are disclosed.Type: GrantFiled: July 14, 1981Date of Patent: November 8, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventor: Richard J. Pokorny
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Patent number: H582Abstract: New blends of ethylene/carboxylic acid copolymers with high density polyethylene and inorganic fillers such as calcium carbonate are disclosed and are useful for making films for skin packaging applications.Type: GrantFiled: March 17, 1987Date of Patent: February 7, 1989Inventor: John H. Tucker