Solid Polymer Derived From Carboxylic Acid-containing Monomer Patents (Class 524/522)
  • Patent number: 5278217
    Abstract: A water absorptive composition comprising a thermoplastic elastomer as a first component, a water-absorptive resin as a second component, and a third component selected from the group which consists of: a water-soluble resin; a hydrophilic compound selected from the group consisting of metal salt of carboxylic acid, polyhydric alcohol, amino alcohol, linear polyether, saccharide, and sugar alcohol; and a surface treating agent selected from the group consisting of sorbitan fatty acid ester, glycidyl ether of polyhydric alcohol, and silane coupling agent. The composition is suitably used for producing a water absorptive member for protecting optical fiber elements of an optical fiber cable.
    Type: Grant
    Filed: October 7, 1992
    Date of Patent: January 11, 1994
    Assignees: Tokai Rubber Industries, Ltd., Summitomo Electric Industries, Ltd., Nippon Telegraph and Telephone Corp.
    Inventors: Masanari Umeda, Yukio Sakuraba, Fumihiro Ashiya, Toshinobu Matsuo
  • Patent number: 5270358
    Abstract: A composite of a gel of swollen hydrocolloid dispersed in a pressure sensitive adhesive matrix is provided. The gel has a natural or synthetically derived hydrocolloid swollen with a non-volatile swelling agent, such that the gel may have a shear modulus of less than 6.2.times.10.sup.6 dynes/cm.sup.2. The gel-adhesive composite has continued skin adhesion whether applied to or existing in dry or moist skin conditions. The gel contributes a high moisture vapor transmission rate to attempt to maintain dry skin conditions while the adhesive maintains skin adhesion. The gel-adhesive composite may be used in a variety of tape, dressing, bandage, drape, or other skin contacting usage and may optionally include antimicrobial agents to treat the skin while adhesion continues.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: December 14, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Robert A. Asmus
  • Patent number: 5252667
    Abstract: Poly(vinyl chloride) exhibits a useful combination of acceptable flow for injection molding, improved processability, and acceptable heat distortion resistance and toughness when modified with a multi-stage polymer having as one stage an alkyl (meth)acrylate polymer or copolymer containing a low level of a copolymerized unsaturated acid partly to completely in the form of its alkali metal salt. In preferred compositions, the melt viscosity under injection molding conditions of the blend will be equal to or less than that of the PVC alone.
    Type: Grant
    Filed: December 7, 1992
    Date of Patent: October 12, 1993
    Assignee: Rohm and Haas Company
    Inventor: Hsing-Yeh Parker
  • Patent number: 5252393
    Abstract: The present invention is concerned with a thermal delayed tack composition which is non-adhesive at ordinary temperatures but can be activated and tackified when heated and can maintain its tackiness for a long period of time even after separated from a heat source, and thermal delayed tack sheets prepared by coating basic sheets with this thermal delayed tack composition and then drying the same. The thermal delayed tack sheets have the features that even when they are wound into a roll or superimposed upon each other, no blocking or sticking occurs, and that the tackiness thereof can be maintained for a long period of time even upon a plastic material such as for example polyethylene having low polarity.
    Type: Grant
    Filed: May 5, 1992
    Date of Patent: October 12, 1993
    Assignee: Mitsubishi Paper Mills Ltd.
    Inventors: Nobuhiro Kagota, Hirokazu Tsukahara
  • Patent number: 5248719
    Abstract: A solid coating composition based on a polyolefin containing a filler is disclosed. The polyolefin is partly or completely reacted with either an unsaturated organic acid or an unsaturated organic acid anhydride.
    Type: Grant
    Filed: June 21, 1991
    Date of Patent: September 28, 1993
    Assignee: Huels Aktiengesellschaft
    Inventors: Helmut Kehr, Adolf Kuehnle, Heinrich Leppek, Matthias Schleinzer
  • Patent number: 5225483
    Abstract: A thermoplastic composition is provided which comprises a blend of a thermoplastic, such as a copolymer of styrene and maleic anhydride; polypropylene; a modified elastomeric component, such as EPM or EPDM, which has been modified with a specified functional monomer, such as a 2-substituted-5-norbornene, and an amine-modified maleic anhydride grafted polypropylene. The composition has improved properties.
    Type: Grant
    Filed: July 22, 1991
    Date of Patent: July 6, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Sudhin Datta, Narayanaswami R. Dharmarajan, Jean M. Dekoninck, Donald A. White
  • Patent number: 5219900
    Abstract: The invention provides a base coat composition comprising a dispersion in an aqueous carrier for the composition of polymer microparticles, the polymer microparticles being a mixture of:(a) 5 to 95% by weight of addition polymer micro-particles having a crosslinked core and a stabilising mantle containing salt forming groups and(b) 95 to 5% by weight of addition polymer micro-particles having polyoxyalkylene stabiliser units derived from C.sub.1-4 alkoxypolyoxyalkylene containing monomers.
    Type: Grant
    Filed: October 2, 1991
    Date of Patent: June 15, 1993
    Assignee: Imperial Chemical Industries PLC
    Inventors: Stephen P. Davies, Graham S. Kay
  • Patent number: 5219916
    Abstract: A waterbased coating composition formed of an acrylic latex and an acrylic hydrosol dispersed in an aqueous carrier and has a pH of about 7-10; wherein the binder is a blend of an acrylic latex polymer having a particle size of about 0.06-0.20 microns and an acrylic hydrosol polymer having a particle size of less than 0.30 microns; wherein the blend containsa methylol (meth)acrylamide acrylic latex polymer of polymerized monomers of alkyl methacrylate, alkyl acrylate or mixtures thereof, 1-15% by weight of methylol methacrylamide, methylol acrylamide or mixtures thereof, 0.5-10% by weight of ethylenically unsaturated carboxylic acid having reactive carboxyl groups, 0.5-10% by weight of ethylenically unsaturated hydroxyl monomer and the carboxyl groups of the carboxylic acid component of the polymer are reacted with ammonia or an amine; and an acrylic hydrosol polymer of methylol (meth)acrylamide acrylic polymer containing about 0.5-10% by weight of an ethylenically unsaturated carboxylic acid, 0.
    Type: Grant
    Filed: December 5, 1990
    Date of Patent: June 15, 1993
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Herman C. Den Hartog, Eileen E. Konsza, James F. Matthews, Ervin R. Werner, Jr.
  • Patent number: 5218011
    Abstract: A gel composition including a gel matrix with a thickener having a water absorbent polymer with pendent anionic groups dispersed therein. Preferred thickeners are organophilic clays such as bentonite and mixtures of such clays with waxes, silica and/or ethylene or polyethylene microspheres.The gel composition is activated with moisture so that the water absorbent polymer migrates to engage and absorb the water. The composition can be used to protect enclosed components or contents from water damage. Also, the gel composition protects wires which carry a small dc current such as the wires of telecommunication cables and splices. The composition eliminates shorts caused by water contact with such wires.
    Type: Grant
    Filed: May 20, 1991
    Date of Patent: June 8, 1993
    Assignee: WaterGuard Industries, Inc.
    Inventor: Clarence S. Freeman
  • Patent number: 5211827
    Abstract: An electrochemical cell employs an ionic semiconductor material as a separator between an anolyte and a catholyte. Ionic semiconductor material includes 10 to approximately 50 percent by weight of a hydrogel which is dispersed within an inert nonporous matrix material to form a composite wherein the quantity of water that can be absorbed by the composite does not substantially exceed the weight of the composite.
    Type: Grant
    Filed: August 5, 1991
    Date of Patent: May 18, 1993
    Assignee: T and G Corporation
    Inventor: Robert L. Peck
  • Patent number: 5208285
    Abstract: Wet adhesion properties comparable or superior to all-acrylic latexes for vinyl acetate copolymers and other low cost polymers, such as EVA-vinyl chloride copolymers, is achieved by blending a minor proportion, usually about 5 to 15%, of a small particle size copolymer containing copolymerized wet adhesion monomer which is a cyclic ureido. Very low quantities of the wet adhesion monomer, less than 0.25 wt% of total monomers, only are required to achieve excellent results.
    Type: Grant
    Filed: August 16, 1991
    Date of Patent: May 4, 1993
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Clarke A. Boyce, Rajeev Farwaha, Brigitte H. Licht, Martin Menard
  • Patent number: 5206279
    Abstract: Aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers (e.g., random ethylene/acrylic acid interpolymers) are formed using a mixture of bases at a concentration of at least about 0.2 equivalents of base per mole of .alpha.,.beta.-unsaturated carboxylic acid. The dispersions have at least about 10 weight percent dispersed solids and not more than about 1 weight percent of the initial polymer in non-dispersed form. Preferred bases for use in forming the dispersions are ammonium hydroxide and/or alkali metal hydroxides. A mixture of ammonium hydroxide and potassium hydroxide is especially preferred for forming the dispersions with ethylene/acrylic acid interpolymers at an ammonium hydroxide:acrylic acid molar ratio of about 1:1 and a potassium hydroxide:acrylic acid molar ratio in the range of about 0.6-0.8:1. The dispersions are particularly useful in forming thin coatings of adhesive on substrates, such as paper and metal foil, using conventional techniques.
    Type: Grant
    Filed: January 25, 1991
    Date of Patent: April 27, 1993
    Assignee: The Dow Chemical Company
    Inventors: Michael E. Rowland, Kenneth E. Springs
  • Patent number: 5204401
    Abstract: There is disclosed a metallic and nonmetallic water borne base coat compositions exhibiting excellent appearance. A method for long term stability and the introduction of aluminum flake pigments into a water borne coating is also disclosed. The method is based on storing the aluminum flake in a solvent environment with introduction of the aluminum flake in to the aqueous environment just before appling the base coat coating. A water reducible acrylic resin with nonionic and acid functionality derived from vinyl monomers having nonionic and urethane functionality has been disclosed that allows for direct introduction of aluminum flake in to an aqueous environment. The coating vehicle is based on acrylic latex vehicle which exhibits excellent drying and film properties. The rheology control agent employed allows for a wetter application of the coating to the substrate. The coating compositions disclosed are also in compliance with current and proposed volatile organic compound regulations.
    Type: Grant
    Filed: July 13, 1990
    Date of Patent: April 20, 1993
    Assignee: BASF Corporation
    Inventors: James L. Anderson, Jr., Horst J. Finkenauer, David L. Newton, Jeff P. Jones
  • Patent number: 5202381
    Abstract: This invention relates to improved poly(vinyl chloride) compositions which contain ionomeric additive polymers, and to a process for preparing such compositions.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: April 13, 1993
    Assignee: Rohm and Haas Company
    Inventor: Hsing-Yeh Parker
  • Patent number: 5198301
    Abstract: Films are provided made from ionomeric polymer resins with 2-40% by weight of a filler material, where the film has a thickness between 0.050 and 0.127 mm. These films are highly flexible and conformable. Adhesive composites comprising these films are also provided.
    Type: Grant
    Filed: May 17, 1991
    Date of Patent: March 30, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Patrick J. Hager, Del A. Kauss, Janet T. Keller
  • Patent number: 5196469
    Abstract: A semi-aqueous ethylene-vinyl alcohol coating composition that is a stable, homogeneous solution which is capable of being easily applied to a substrate to form a multi-layer structure at room temperature, by spray, rod, gravure, or other mechanical means. Upon evaporation of the volatile components, this coating solution leaves a clear, homogeneous film comprising EVOH. The film resists degradation and discoloration during the lifetime of the structure, and upon incineration or recycling does not evolve harmful acids into the environment.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: March 23, 1993
    Assignee: Mica Corporation
    Inventors: Virginia P. Cushing, Daniel Siegel
  • Patent number: 5194184
    Abstract: A flame-retardant resin composition comprising (i) a mixture comprising (A) 50 to 90% by weight of a polyolefin resin, (B) 10 to 50% by weight of a polyamide resin, (C) 1 to 5% by weight of a polyolefin resin modified by an unsaturated carboxylic acid or a derivative thereof, (D) 25 to 55% by weight of a hydrated metal oxide and (E) 0 to 10% by weight of antimony trioxide; the total of the polyolefin resin (A) and the polyamide resin (B) being from 30 to 74% by weight of the mixture (i); and (ii) glass fibers (F) in an amount of 18 to 70 parts by weight to 100 parts by weight of the mixture (i). The resin composition is not toxic and has an excellent flame-retardant property and a high mechanical strength.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: March 16, 1993
    Assignee: Idemitsu N.S.G. Co., Ltd.
    Inventors: Yoshiharu Takeyama, Shuichi Yamagami
  • Patent number: 5194483
    Abstract: Disclosed herein are water-based protective composition for coating films. The compositions contain (a) a water-based dispersion of copolymer particles having a number average molecular weight of from 2,000 to 20,000 and a glass transition point of from -10.degree. C. to +40.degree. C. and obtained by emulsion-polymerizing 100 parts by weight of a monomer mixture consisting substantially of (X) 7-12 parts by weight of an .alpha.,.beta.-monoethylenically-unsaturated carboxylic acid and (Y) 88-93 parts by weight of at least one ester selected from the group consisting of C.sub.1-4 -alkyl acrylates and C.sub.1-4 -alkyl methacrylates; as well as specific amounts of (b) an ultraviolet absorber, (c) an antioxidant, (d) a thickening agent and (e) a surface active agent. They can form barrier coats having excellent removability, weatherability, water-proofness, heat resistance and coating-film-protecting property. Their preparation processes are also disclosed.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: March 16, 1993
    Assignee: Nippon Oil Co., Ltd.
    Inventor: Nobuaki Kawabata
  • Patent number: 5180774
    Abstract: A binder for use in gravure printing ink formulations comprising a modified rosin ester resinate prepared by forming a rosin-dienophile adduct, reacting the adduct with a polyfunctional hydroxy compound to form an ester and reacting with an acrylic-containing polymer to form a hard rosin ester. The polymer-modified rosin ester resinate is formed by reacting the prepared hard rosin ester with a rosin-dienophile adduct and an acrylic-containing polymer, reacting the product thereof with reactive zinc, followed by a reaction with lime, dehydrating the resinate product by refluxing, and adjusting its viscosity with a hydrocarbon solvent.
    Type: Grant
    Filed: November 4, 1991
    Date of Patent: January 19, 1993
    Assignee: Westvaco Corporation
    Inventor: Joseph W. LeVine
  • Patent number: 5179165
    Abstract: A composition suitable for encapsulating articles such as small electronic devices and having improved tensile strength and other mechanical properties. The composition comprises a poly(phenylene sulfide) base resin, a non-reinforcing mineral filler and an ethylene/methacrylic acid copolymer. Also provided are a method of forming the composition and articles such as electronic components encapsulated with the composition.
    Type: Grant
    Filed: June 12, 1991
    Date of Patent: January 12, 1993
    Assignee: International Flavors & Fragrances Inc.
    Inventor: Nathaniel Harry, Sr.
  • Patent number: 5171777
    Abstract: Blends of polymers of vinyl acetate and polymers derived from acrylic acid have been discovered which exhibit thermodynamic miscibility. These polymer blends exhibit excellent mechanical compatibility, provide enhanced toughness and strength superior to the sum of the weight averaged properties of the constituent polymers and are useful in molding structures such as films and in compounded formulations such as coatings, emulsions and adhesives.
    Type: Grant
    Filed: December 26, 1990
    Date of Patent: December 15, 1992
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Jeffrey A. Kuphal, Lloyd M. Robeson, Dennis Sagl
  • Patent number: 5168105
    Abstract: There is disclosed a metallic and nonmetallic water borne base coat compositions exhibiting excellent appearance. A method for long term stability and the introduction of aluminum flake pigments into a water borne coating is also disclosed. The method is based on storing the aluminum flake in a solvent environment with introduction of the aluminum flake in to the aqueous environment just before appling the base coat coating. A water reducible acrylic resin with nonionic and acid functionality has been disclosed that allows for direct introduction of aluminum flake in to an aqueous environment. The coating vehicle is based on acrylic latex vehicle which exhibits excellent drying and film properties. The rheology control agent employed allows for a wetter application of the coating to the substrate. The coating compositions disclosed are also in compliance with current and proposed volatile organic compound regulations.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: December 1, 1992
    Assignee: BASF Corporation
    Inventors: James L. Anderson, Jr., Horst J. Finkenauer, David L. Newton, Jeff P. Jones
  • Patent number: 5166255
    Abstract: There is disclosed a metallic and nonmettalic water borne base coat compositions exhibiting excellent appearance. A method for long term stability and the introduction of aluminum flake pigments into a water borne coating is also disclosed. The method is based on storing the aluminum flake in a solvent environment with introduction of the aluminum flake in to the aqueous environment just before applying the base coat coating. A water reducible acrylic resin with nonionic and acid functionality has been disclosed that allows for direct introduction of aluminum flake in to an aqueous environment. The coating vehicle is based on acrylic latex vehicle which exhibits excellent drying and film properties. The rheology control agent employed allows for a drier application of the coating to the substrate. The coating compositions disclosed are also in compliance with current and proposed volatile organic compound regulations.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: November 24, 1992
    Assignee: BASF Corporation
    Inventors: James L. Anderson, Jr., Horst J. Finkenauer, David L. Newton, Jeff P. Jones, Craig J. McClanahan
  • Patent number: 5162422
    Abstract: Novel polypropylene-polyamide molding compositions which comprise, based on 100 parts by weight of the molding compositions,A) 10 to 89.9 parts by weight of one or more polypropylene homopolymer and/or copolymer,B) 10 to 89.9 parts by weight of one or more polyamide,C) 0.1 to 5.0 parts by weight of one or more olefinically unsaturated carboxylic acid and/or one or more olefinically unsaturated carboxylic acid derivate,D) 0 to 3.0 parts by weight of an impact modifier, andE) 0 to 60.0 parts by weight of a reinforcing agent and/or additive,are prepared by melting together components (A), (C) and, if desired (D) at from 200.degree. to 300.degree. C. in a first reaction step and then, in a second reaction step, introducing component (B) and, if appropriate, components (D) and/or (E) into the modified melt obtained, and melting together the components.The molding compositions obtained are used for the production of moldings.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: November 10, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietrich Lausberg, Wolfgang F. Mueller, Erhard Seiler
  • Patent number: 5162392
    Abstract: An injection moldable biodegradable plastic formed of corn starch and low-density polyethylene. Ethylene acrylic acid co-polymer can be included in proportions ranging from 0-10%, by weight, and sodium hydroxide can be utilized to neutralize the acidic portions of the ethylene acrylic acid co-polymer. When no ethylene acrylic acid co-polymer is utilized, glycerol is added. To improve injection molding characteristics, the ethylene acrylic acid co-polymer and polyethylene are premixed before the addition of corn starch.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: November 10, 1992
    Assignee: Agri-Tech Industries, Inc.
    Inventors: Richard P. Wool, David C. Schiltz, Dale Steiner
  • Patent number: 5147757
    Abstract: A novel optically transparent polymer alloy comprisesA) at least one elastomer which contains ethylene and propylene as copolymerized units andB) at least one elastomer which contains ethylene and (meth)acrylic acid as copolymerized units,and is used as a molding material or for the production of molding materials, moldings, films, coatings, adhesives and photosensitive recording elements.
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: September 15, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Rudolf Kurtz, Horst Koch, Thomas Telser
  • Patent number: 5137963
    Abstract: Non-formaldehyde emitting binders for nonwoven cellulosic materials comprise a solution copolymer of an olefinically unsaturated organic compound having at least one carboxylate group conjugated with the olefinic linkage, which is reacted with a hydroxyalkyl ester of an olefinically unsaturated carboxylic acid. The product of said reaction is admixed with a non-formaldehyde containing latex carrier to produce a binder composition which will reach substantially fully cured wet strength in 8 seconds or less.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: August 11, 1992
    Assignee: Union Oil Company of California
    Inventor: Dennis P. Stack
  • Patent number: 5116899
    Abstract: The present invention is directed to a resin composition for electric insulation materials for vehicles such as distributor caps which is prepared by blending a crystalline propylene-ethylene copolymer resin with 3 to 10 wt. % of a glass fiber, 10 to 20 wt. % of talc or mica, 5 to 20 wt. % of silica, 4 to 20 wt. % of modified polyolefin resins, 10 to 30 wt. % of halogen-containing flame retardants and 3 to 15 wt. % of flame retardant auxiliaries. In the resin composition of the present invention, balance is kept in all points of mechanical characteristics, mechanical characteristics at high temperature, electrical characteristics, nitric acid resistance, weld characteristics, blooming resistance, corona resistance and flame retardance.
    Type: Grant
    Filed: August 8, 1991
    Date of Patent: May 26, 1992
    Assignees: Chisso Corporation, Nippondenso Co., Ltd.
    Inventors: Kazuhiko Aratake, Masayoshi Horikoshi, Fumio Kato, Yasuhiko Suzuki, Yuki Morimoto
  • Patent number: 5106881
    Abstract: A water base pigment ink composition for use in marking pens which contain an absorbent ink reservoir and a pen tip connected thereto, the ink composition comprising:(a) water in amounts of not less than 50% by weight;(b) an aqueous emulsion of hollow resin particles in amounts of 0.5-40% by weight as solids;(c) a white pigement in amounts of 1-40% by weight; and(d) a water-solubilized .alpha.-methylstyrene/styrene/acrylic acid copolymer which has a weight average molecular weight of 1000-10000 and a distribution of molecular weight of 0.5-3.3, but which contains substantially no components having a weight average molecular weight of not more than 500, in amounts of 0.1-30% by weight, based on the ink compositions, respectively.The ink composition may contain chromatic or achromatic (other than white) pigments in amounts of 0.1-30% by weight based on the ink composition.
    Type: Grant
    Filed: March 11, 1991
    Date of Patent: April 21, 1992
    Assignee: Sakura Color Products Corp.
    Inventors: Hiroshi Inoue, Wataru Yokono, Yasuji Okuda
  • Patent number: 5102946
    Abstract: A stabilized chlorinated resin latex comprising a mixture in water of A) 50-95 wt. %, based on the weight of A and B, of a chlorinated resin, substantially free of acid moieties, having a chlorine content of 15-70 wt. %, and B) 5-50 wt. %, based on the weight of A and B, of a salt of a water-insoluble C.sub.2 -C.sub.12 alpha, beta- unsaturated olefin copolymer which contains at least 2 mole % acid moieties and is compatible with the chlorinated resin.
    Type: Grant
    Filed: June 27, 1991
    Date of Patent: April 7, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: John C. Chen, Royce E. Ennis
  • Patent number: 5098948
    Abstract: Disclosed herein are water-based protective composition for coating films. The compositions contain (a) a water-based dispersion of copolymer particles having a number average molecular weight of from 2,000 to 20,000 and a glass transition point of from -10.degree. C. to +40.degree. C. and obtained by emulsion-polymerizing 100 parts by weight of a monomer mixture consisting substantially of (X) 7-12 parts by weight of an .alpha.,.beta.-monoethylenically-unsaturated carboxylic acid and (Y) 88-93 parts by weight of at least one ester selected from the group consisting of C.sub.1-4 -alkyl acrylates and C.sub.1-4 -alkyl methacrylates; as well as specific amounts of (b) an ultraviolet absorber, (c) an antioxidant, (d) a thickening agent and (e) a surface active agent. They can form barrier coats having excellent removability, weatherability, waterproofness, heat resistance and coating-film-protecting property. Their preparation processes are also disclosed.
    Type: Grant
    Filed: June 5, 1990
    Date of Patent: March 24, 1992
    Assignee: Nippon Oil Co.
    Inventor: Nobuaki Kawabata
  • Patent number: 5093449
    Abstract: A styrene-butadiene composition containing about 0.1 to 10 weight % of a monoester of maleic acid or fumaric acid provides improved bonding strength. In addition, small amounts of a functional monomer can also be included.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: March 3, 1992
    Assignee: Reichhold Chemicals, Inc.
    Inventors: Rebecca L. Durney Cronin, W. Scott Rutherford, James F. Campbell
  • Patent number: 5079281
    Abstract: A fiber-reinforced polypropylene resin composition is disclosed, comprising (1) a mixed polymer of polypropylene and carboxyl group containing polypropylene, (2) a silane treated reinforcing fiber, and (3) a coloring component of zinc sulfide and carbon black with a dispersing agent compounded thereto, said dispersing agent is polyethylene wax and the amount of said dispersing agent added to 20 to 50 parts by weight per 100 parts by weight of the zinc sulfide and carbon black.
    Type: Grant
    Filed: November 28, 1989
    Date of Patent: January 7, 1992
    Assignee: Toyoda Gosei Co., Ltd.
    Inventors: Junji Takeuchi, Masahiro Takimoto
  • Patent number: 5078994
    Abstract: A copolymer microparticle is presented which is derived from at least about 5 weight percent of free carboxylic acid group-containing vinyl monomers, monomers which have a poly(alkylene oxide) appended thereto, oleophilic monomers and other nonionic hydrophilic monomers. Microgels containing these copolymers having a median water swollen diameter of about 0.01 to about 1.0 micrometer are disclosed. Pharmaceutical and diagnostic compositions are disclosed comprising a therapeutic or diagnostic agent and microgels comprising a copolymer derived from at least about 5 weight percent of non-esterified carboxylic acid group-containing vinyl monomers, oleophilic monomers and other nonionic hydrophilic monomers, with the proviso that when the median water swollen diameter of the microgels is 0.1 micrometer or greater, at least 5 weight percent of the monomers have a poly(alkylene oxide) appended thereto.
    Type: Grant
    Filed: April 12, 1990
    Date of Patent: January 7, 1992
    Assignee: Eastman Kodak Company
    Inventors: Mridula Nair, Julia S. Tan
  • Patent number: 5059456
    Abstract: A method for improving the quality of a mastic coating system by using a latex barrier tiecoat which is composed of a water-insoluble latex polymer and a multivalent metal ion. The tiecoat is applied to a substrate and then a mastic coating is applied to the tiecoat to yield a mastic coating system having excellent resistance to blistering when the mastic coating system is exposed to long-term ponded water.
    Type: Grant
    Filed: May 4, 1990
    Date of Patent: October 22, 1991
    Assignee: Rohm and Haas Company
    Inventors: Gary R. Larson, George A. Papsin, Jr., Donald A. Winey
  • Patent number: 5047482
    Abstract: Cable insulation having high resistance to the formation or growth of water trees and high aging resistance consists of an ethylene polymer (I) and from 0.5 to 20% by weight of an ethylene polymer (II), which is an ethylene/C.sub.1 -C.sub.8 -alkyl-C.sub.3 -C.sub.6 -alkene carboxylate/C.sub.3 -C.sub.6 -alkenecarboxylic acid terpolymer.
    Type: Grant
    Filed: March 5, 1987
    Date of Patent: September 10, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Johannes Schlag, Ernst Koehnlein, Peter Bauer, Ludwig Koessler
  • Patent number: 5043377
    Abstract: Disclosed herein is granite-like artificial stone which comprises a matrix and chips dispersed therein, said matrix being a cured product of specific radical-polymerizable monomers and an inorganic filler powder, and said chips being a cured product of a mixture (II) which contains the components identical or similar to those in the mixture (I) but giving a different clarity and/or color tone from the cured product of the mixture (I). The artificial stone gives the appearance of granite and is superior in fabricability, heat resistance, hot water resistance, weather resistance, yellowing resistance, and stain resistance.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: August 27, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Company, Ltd.
    Inventors: Kozo Nogi, Chihiro Tani, Nobuhiko Yukawa, Terukuni Hashimoto
  • Patent number: 5032462
    Abstract: Coating compositions comprise a thixotropic resin dispersion in which the resin particles are a vinyl polymer, a cross-linked unsaturated carboxylic acid polymer which is neutralized with a salt of a low valence metal, and an adhesion promoter.
    Type: Grant
    Filed: July 18, 1989
    Date of Patent: July 16, 1991
    Assignee: The B. F. Goodrich Company
    Inventor: Jongshun S. Kim
  • Patent number: 5030662
    Abstract: Construction materials prepared from recycled polymeric material containing primarily polyolefins such as high density polyethylene, ultra high molecular weight polyethylene, low density polyethylene, linear low density polyethylene, and polypropylene homopolymers and copolymers are useful for profiled extruded forms such as fence posts, door frames, rails, railway sleepers, and other applications where lumber is conventionally employed. The compositions of the invention contain, in addition to the mixed plastic matrix, reactive compatibilizers, impact modifiers, and reinforcing agents. When desired, foaming agents may also be employed. The recycled mixed plastic materials have been subject to at least one high temperature processing step when used in their original application. Such plastics differ in physical and chemical composition from virgin material.
    Type: Grant
    Filed: August 11, 1988
    Date of Patent: July 9, 1991
    Assignee: Polymerix, Inc.
    Inventor: Asis K. Banerjie
  • Patent number: 5030682
    Abstract: Disclosed is a glass fiber reinforced polyolefin resin composition comprising 15-80% by weight of polypropylene, 20-60% by weight of polybutene-1 and 5-60% by weight of glass fiber. This resin composition is excellent in the balance of impact strength, stiffness, heat distortion temperature, surface hardness and processability. When this composition is molded, the molded products have no surface roughness and no color shade and have good appearance. The properties are further improved when a modified polyolefin alone or together with a crystal nucleating agent are added.
    Type: Grant
    Filed: July 31, 1989
    Date of Patent: July 9, 1991
    Assignee: Idemitsu Petrochemical Company Limited
    Inventors: Manabu Nomura, Hirohide Mizuno, Kaoru Wada
  • Patent number: 5028655
    Abstract: Non-formaldehyde emitting binders for nonwoven cellulosic materials comprise a solution copolymer of an olefinically unsaturated organic compound having at least one carboxylate group conjugated with the olefinic linkage, which is reacted with a hydroxyalkyl ester of an olefinically unsaturated carboxylic acid. The product of said reaction is admixed with a non-formaldehyde containing latex carrier to produce a binder composition which will reach substantially fully cured wet strength in 8 seconds or less.
    Type: Grant
    Filed: December 15, 1987
    Date of Patent: July 2, 1991
    Assignee: Union Oil Company of California
    Inventor: Dennis P. Stack
  • Patent number: 5019621
    Abstract: Acrylate copolymers containing hydroxyl groups as additives for aqueous anionic paint systems for the purpose of preventing surface defects are described. The acrylate copolymers contain selected amounts of hydroxyl groups originating from hydroxyethyl (meth)acrylates or hydroxypropyl (meth)acrylates, in addition to carboxyl groups neutralizable with bases. The additives are used in amounts of from 0.1 to 2.0% by weight, calculated on solids content and based on the total solids content of the binder in the paint.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: May 28, 1991
    Assignee: Vianova Kunstharz, A.G.
    Inventors: Harald Rauch-Puntigam, Werner Staritzbichler, Peter Morre
  • Patent number: 5010120
    Abstract: The invention provides a solid adhesive composition useful for temporary and repeated fixation of an article on a surface which comprises about 5.0 to about 45 weight percent of an acrylic resin having a glass transition point of -10.degree. C. or below about 0.1 to about 2.0 weight percent of a polyacrylic acid-based thickening agent, about 5.0 to about 30 weight percent of a fatty acid soap, about 0.1 to about 2.0 weight percent of an alkali hydroxide, about 0.1 to about 10 weight percent of microspheres with an average grain size of about 10 to about 200 .mu.m and about 2.0 to about 60 weight percent of water.
    Type: Grant
    Filed: July 5, 1990
    Date of Patent: April 23, 1991
    Assignee: Sakura Color Products Corporation
    Inventor: Koji Sugiura
  • Patent number: 5009536
    Abstract: A water base pigment ink composition for use in marking pens which contain an absorbent ink reservoir and a pen tip connected thereto, the ink composition comprising:(a) water in amounts of not less than 50% by weight;(b) an aqueous emulsion of hollow resin particles in amounts of 0.5-40% by weight as solids;(c) a white pigment in amounts of 1-40% by weight; and(d) a water-solubilized .alpha.-methylstyrene/styrene/acrylic acid copolymer which has a weight average molecular weight of 1000-10,000 and a distribution of molecular weight of 0.5-3.3, but which contains substantially no components having a weight average molecular weight of not more than 500, in amounts of 0.1-30% by weight, based on the ink compositions, respectively.The ink composition may contain chromatic or achromatic (other than white) pigments in amounts of 0.1-30% by weight based on the ink composition.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: April 23, 1991
    Assignee: Sakura Color Products Corp.
    Inventors: Hiroshi Inoue, Wataru Yokono, Yasuji Okuda
  • Patent number: 5008326
    Abstract: Non-formaldehyde emitting binders for nonwoven cellulosic materials comprise a solution copolymer of an olefinically unsaturated organic compound having at least one carboxylate group conjugated with the olefinic linkage, which is reacted with a hydroxyalkyl ester of an olefinically unsaturated carboxylic acid. The product of said reaction is admixed with a non-formaldehyde containing latex carrier to produce a binder composition which will reach substantially fully cured wet strength in 8 seconds or less.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: April 16, 1991
    Assignee: Union Oil Company of California
    Inventor: Dennis P. Stack
  • Patent number: 5004501
    Abstract: The invention relates to a two phase cement mixture which is particularly suitable for orthopaedic use, in which the solid phase comprises a polymer, polymetyl methacrylate, and a catalyst, benzoyl peroxide, while the liquid phase comprises a monomer, monomethyl methacrylate, an accelerator, N-N-dimethyl-p-toluidine and hydroquinone. The said polymetyl methacrylate is in powder form with particles of a spherical shape which are of a suitable particle size. Fluoride in form of salt can be added to the said solid phase, realizing fluoride ions, making them available to the part of the bone with which the said mixture is in contact when is used to attach a prothesis to a bone.
    Type: Grant
    Filed: May 16, 1989
    Date of Patent: April 2, 1991
    Assignee: Tecres Spa
    Inventors: Giovanni Faccioli, Basilio M. De Bastiani, Bruno Magnan, Renzo Soffiatti
  • Patent number: 4997720
    Abstract: Thermoplastic compositions and articles made therefrom which have a high receptivity toward automotive paints comprises the following components:2%-25% of a copolymer of an ethylenically unsaturated carboxylic acid and ethylene,3%-50% of an elastomer comprising an ethylene-alpha-olefin copolymer,1%-50% of a crystalline homopolymer or copolymer of propylene,5%-40% of polyethylene or a copolymer of ethylene and an alpha-olefin,2%-20% of an epoxy or phenoxy resin; andoptionally, up to 50% of an inorganic filler. Such articles, when injection molded, exhibit flexural moduli in the range of 100,000 to 200,000 psi and have excellent paintability, a broad range of stiffness values and high impact and tensile strengths suitable for automotive applications such as bumpers, facias and wheel covers.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: March 5, 1991
    Assignee: Dexter Corporation
    Inventors: Edward Bourbonais, Davei Yu, Khemchand Nangrani
  • Patent number: 4992486
    Abstract: A composition stabilized against thermal crosslinking and consequent reduction of its melt index, consisting essentially of a uniform dispersion of alumina-coated titanium dioxide pigment in a blend of a matrix polymer which is a dipolymer of ethylene with an ethylenically unsaturated carboxylic acid or a terpolymer of ethylene with an ethylenically unsaturated carboxylic acid and with another ethylenically unsaturated comonomer, or with carbon dioxide or sulfur dioxide, with a stabilizing polymer which is a high melt index copolymer of ethylene with acrylic or methacrylic acid. Such compositions are useful in melt-fabricating white-pigmented articles such as, e.g., toothpaste tubes and condiment pouches.
    Type: Grant
    Filed: November 14, 1989
    Date of Patent: February 12, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Stewart C. Feinberg
  • Patent number: 4985486
    Abstract: The invention relates to thermoplastic molding compounds of reinforced (for example with glass fibers) and/or filled (for example with kaolin) polyamides, interpolymers having a certain chemical composition (of polyamides and thermoplastic copolymers) and, optionally, a rubber modifier which increases the toughness of the molding compounds, and to a process for their production.
    Type: Grant
    Filed: August 3, 1989
    Date of Patent: January 15, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Westeppe, Christian Lindner, Karl-Erwin Piejko, Hans-Joachim Laue
  • Patent number: 4983426
    Abstract: A method for improving the quality of a mastic coating system by using a selected tiecoat composition. The tiecoat is applied to a substrate in order to correct substrate problems which would cause premature failure of a mastic coating applied directly to the substrate. The mastic coating is then applied to the tiecoat to yield a superior mastic coating system.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: January 8, 1991
    Assignee: Rohm and Haas Company
    Inventor: Arthur D. Jordan, Jr.