Ester Derived From An Unsaturated Alcohol And A Saturated Acid, E.g., Vinyl Acetate, Etc. Patents (Class 524/524)
  • Patent number: 5420185
    Abstract: A bow-tie tree resistant electrical insulating composition comprises 100 parts by weight of at least one polymer selected from polyolefins and ethylene copolymers, 0.005-1.0 part by weight of a metal salt of a fatty acid containing a hydroxyl group in the molecule, and 0.005-1.0 part by weight of a fatty acid or a derivative thereof.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: May 30, 1995
    Assignee: Hitachi Cable Ltd.
    Inventors: Kiyoshi Watanabe, Takanori Yamazaki, Hideki Yagyu, Mamoru Kanaoka, Katsutoshi Hanawa, Chuki Ikeda
  • Patent number: 5403884
    Abstract: A process for flocking cured or uncured elastomeric substrates comprising the steps of applying to the substrate an aqueous adhesive comprising 10 to 100% (dry weight) of an alkaline dispersion of an ethylene carboxylic acid copolymer and 0 to 90% of an aqueous elastomeric dispersion; electrostatically applying flocking fibers thereto; and drying the thus flocked substrate.
    Type: Grant
    Filed: January 13, 1993
    Date of Patent: April 4, 1995
    Assignee: National Starch And Chemical Investment Holding Corporation
    Inventor: Witold Perlinski
  • Patent number: 5393804
    Abstract: There is provided a biodegradable composition as obtained from a melt comprising converted starch, a plasticizer and at least one member selected from alkenol homopolymers and/or alkenol copolymers which are combined under conditions sufficient to ensure uniform melt formation, in which the at least one member is present in the composition at a concentration of from 10 to 200 parts per 100 parts of dry converted starch.The invention further relates to methods of making the composition, and to articles made from said composition.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: February 28, 1995
    Assignee: Parke, Davis & Company
    Inventors: Eric George, Eddie Park, Paul A. Altieri, Charles W. Paul
  • Patent number: 5391625
    Abstract: The present invention provides for compatibilized elastomer blend compositions based on a preferred mixture of a copolymer of a C.sub.4 to C.sub.7 isoolefin, such as isobutylene, copolymerized with a para-alkyl styrene comonomer, such as para-methyl styrene wherein at least some of the alkyl substituent groups present in the styrene monomer units contain halogen, and at least one dissimilar elastomer, said blend composition further containing, as a compatibilizer, minor amounts of a copolymer of ethylene and vinyl acetate or a copolymer of ethylene, a lower alkyl acrylate or methacrylate and, optionally, a third comonomer based on acrylic or methacrylic acid.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: February 21, 1995
    Inventor: Palanisamy Arjunan
  • Patent number: 5367003
    Abstract: Environmentally friendly, disposable, degradable and/or recyclable plastic articles are made from water soluble, miscible, high molecular weight, thermoplastic, polymeric resin blends that are comprised by weight of about 65% to 95% high molecular weight water soluble thermoplastic resin having an inverse solubility characteristic and about 35% to 5% of at least one of certain high molecular weight thermoplastic polymers that are functionally compatible (miscible) with the inversely soluble resin. The articles are insoluble when used for their intended purposes, but become soluble when exposed to tepid or cool water and degradable when buried in a land fill or compost. The inversely soluble resin comprises high molecular weight poly(ethylene oxide). The compatible polymer is selected from the group consisting of Nylon 11, Nylon 12, polycaprolactone, polycaprolactone, polyethylene-co-acrylic acid, polyethylene-co-methacrylic acid, polyethylene-co-vinylacetate and polyethylene-co-vinylalcohol.
    Type: Grant
    Filed: June 18, 1993
    Date of Patent: November 22, 1994
    Inventor: Robert J. Petcavich
  • Patent number: 5362790
    Abstract: Impact-resistant compositions based on vinyl chloride polymers and their use in the extrusion of sections, comprising, as vinyl chloride polymers:(a) from 3 to 40 parts of vinyl chloride graft copolymer on weakly crosslinked polybutyl acrylate,(b) from 5 to 85 parts of vinyl chloride graft copolymer on a copolymer of ethylene and vinyl acetate, and(c) from 10 to 85 parts of unmodified vinyl chloride polymer per 100 parts by weight in all of the combination of the vinyl chloride polymers of the composition and, by way of reinforcing filler,(d) from 3 to 10 parts of coated calcium carbonate whose elementary particles have a mean diameter smaller than 1 .mu.m per 100 parts by weight of the combination of the vinyl chloride polymers of the composition.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: November 8, 1994
    Assignee: Solvay (Societe Anonyme)
    Inventor: Daniel Gloesener
  • Patent number: 5349009
    Abstract: A water-based construction adhesive composition containing an aqueous emulsion polymer binder which comprises a blend, based on 100 weight parts of polymer solids, of 25 to 75 parts aqueous emulsion vinyl acetate/-ethylene copolymer and 75 to 25 parts aqueous emulsion vinyl acetate homopolymer.
    Type: Grant
    Filed: December 8, 1992
    Date of Patent: September 20, 1994
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Wayne R. Furlan
  • Patent number: 5340869
    Abstract: A binder composition comprising a petroleum resin, an aromatic heavy mineral oil, a thermoplastic elastomer, an ethylene copolymer and a waxy substance has a high viscosity at 60.degree. C. and a low viscosity at high temperatures, and can provide a mixture together with aggregate having remarkably high compressive strength.
    Type: Grant
    Filed: April 23, 1993
    Date of Patent: August 23, 1994
    Assignee: Nippon Oil Company, Ltd.
    Inventors: Masao Isobe, Yoshio Aizawa, Kenichi Kogo, Chuzo Yoshida
  • Patent number: 5334643
    Abstract: Heat-sealable thermoplastic elastomeric films comprise from approximately 35% to about 65% of an A-B-A block copolymer wherein "A" blocks are derived from polystrene or a polystrene homolog and said "B" blocks being derived from lower alkenes and from about 25% to about 55% of an ethylene vinyl acetate copolymer, the ethylene vinyl acetate copolymer comprising approximately 28% vinyl acetate. The films are heat-sealable to various substrates including polyvinyl chloride. Once sealed to the substrate, the film may be readily peeled from the substrate by the application of a low and relatively constant peel force. A method for measuring the peel strengths of the film is disclosed. The films are especially adapted to being heat-sealed to a substrate which forms, together with the substrate a package, or multiple serially connected packages.
    Type: Grant
    Filed: July 1, 1991
    Date of Patent: August 2, 1994
    Assignee: Rexene Products Company
    Inventor: Paul D. Gage
  • Patent number: 5326602
    Abstract: A pre-formed composition having essentially no yield point comprising a blend of:(a) at least about 50 percent by weight of a copolymer of ethylene and a 4 to 8 carbon atom alpha-olefin having a density in the range of 0.880 to 0.915 gram per cubic centimeter; a melt index of no greater than about one gram per 10 minutes; long chain branching in an amount of about 0.5 to about 1.5 long chains per 1000 carbon atoms; and a molecular weight of at least about 200,000; and(b) at least about 5 percent by weight of a copolymer of ethylene and vinyl acetate or a copolymer of ethylene and ethyl acrylate, the percent by weight being based on the combined weight of components (a) and (b).
    Type: Grant
    Filed: December 1, 1992
    Date of Patent: July 5, 1994
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Mahmoud Rifi
  • Patent number: 5324760
    Abstract: The present invention provides a copolymer comprising polybutadiene and other olefinic saturated or unsaturated thermoplastics. The mixing ratio between the polybutadiene and the thermoplastics is 30:70 to 95:5 weight percent. Surface improving additives, such as polysiloxane, may be added in quantities from 0.5 to 6 weight percent. The copolymer may be used to produce medical and food compatible semi-finished or finished products.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: June 28, 1994
    Assignee: Rehau AG & Co.
    Inventor: Siegfried Hopperdietzel
  • Patent number: 5317051
    Abstract: A flame-retardant olefin polymer composition superior in surface whitening preventing property is obtained by blending 100 parts by weight of a resin component consisting principally of:a) 99-60% by weight of a polyolefin resin andb) 1-40% by weight of an olefin polymer modified with an unsaturated carboxylic acid or a derivative thereof: withc) 5-200 parts by weight of a flame retardant: andd) at least one component selected from the group consisting of:1 a mineral oil, a wax, or a paraffin.2 a higher fatty acid or an ester, amide or metallic salt thereof,3 a silicone4 a partial fatty ester of a polyhydric alcohol or aliphatic alcohol-, fatty acid-, aliphatic amino-, fatty acid amide-, alkylphenol- or alkylnaphthol-ethylene oxide adduct, and5 a fluoric elastomer.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: May 31, 1994
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Masahiro Harashige, Tsutomu Kawamura, Satoru Kaneko, Takashi Inoue, Atsuo Tokutake, Toshitsune Yoshikawa
  • Patent number: 5314943
    Abstract: A low viscosity, fast-curing binder for textile substrates is produced by admixing an aqueous emulsion copolymer latex with an aqueous solution copolymer formed by the copolymerization of an olefinically unsaturated polycarboxylic acid and an olefinically unsaturated monocarboxylic acid. Viscosities in the range of about 2 cps at 25% total solids to about 1000 cps at 35% total solids are realized by using solution copolymers containing about 40%-75% by weight of polycarboxylic acid.
    Type: Grant
    Filed: November 30, 1990
    Date of Patent: May 24, 1994
  • Patent number: 5298552
    Abstract: Predominantly water based adhesive compositions and primers comprising:A) 2 to 50 parts by weight of a solution in a non-ionic surface active agent of one or more chlorinated polyolefins;B) 50 to 98 parts by weight of a component selected from:1) an aqueous dispersion comprising from 35 to 65 part per hundred by weight of vinylacetate-ethylene copolymer and2) an aqueous solution comprising from 0.1 to 5% by weight of an anionic surface-active agent.
    Type: Grant
    Filed: March 24, 1992
    Date of Patent: March 29, 1994
    Assignee: Himont Incorporated
    Inventors: Angelo Borghi, Vincenzo Giannella
  • Patent number: 5288780
    Abstract: An adhesion promoting composition for use on polyolefin substrates which is formulated with a chlorinated polyolefin in a water-based emulsion.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: February 22, 1994
    Assignee: Tioga International, Inc.
    Inventors: Richard E. Jarzombek, William J. Yapp, David W. Helms
  • Patent number: 5264467
    Abstract: An aqueous contact adhesive composition consisting essentially ofa) an aqueous emulsion containing an adhesive polymer,b) 0-50 wt % plasticizer, based on polymer solids,c) 0.5-10 wt % thermoplastic hollow microspheres, based on polymer solids, andd) 0-4.5 wt % polyethylenimine, based on polymer solids,the adhesive composition demonstrating less than one pound per linear inch adhesion to stainless steel by PSTC-1 method.
    Type: Grant
    Filed: September 24, 1991
    Date of Patent: November 23, 1993
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Frank V. DiStefano
  • Patent number: 5260382
    Abstract: The ethylene/pentene-1 copolymer composition comprises an ethylene/pentene-1 copolymer satisfying specific request and an ethylene/vinyl acetate copolymer. This composition has excellent balance between impact resistance and tear properties, excellent transparency and good hot tack properties, and are particularly useful for packing films.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: November 9, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masaki Kohyama, Masaya Yamada
  • Patent number: 5260381
    Abstract: A cross-linkable polyethylene-based composition useful for rotational molding and, when cured, characterized by exceptional percent elongation after long term exposure to degradation conditions, is provided. The cured composition has a high degree of crosslinking which may be a more random type of crosslinking.
    Type: Grant
    Filed: October 8, 1991
    Date of Patent: November 9, 1993
    Assignee: Neeco, Inc.
    Inventor: Donald G. Needham
  • Patent number: 5250598
    Abstract: A quick drying liquid electrical tape formulation having good shelf life. The formulation forms a durable vinyl coating or film on wires, junctions and objects. The formulation is comprised of at least about 10% of a vinyl material effective to achieve the durable vinyl coating. The formulation further includes a thixotropic agent to add body, and a plasticizer to impart flexibility to the vinyl coating. The vinyl material, thixotropic agent and plasticizer are admixed with solvents comprising at least one drying agent. The formulation further including a stabilizing agent and at least one solvent, such that the thixotropic agent and plasticizer enable the application of a satisfactory coating using the formulation.
    Type: Grant
    Filed: April 10, 1991
    Date of Patent: October 5, 1993
    Inventors: Peter Dornau, Robert R. Russo, Jeffrey Tieger
  • Patent number: 5244942
    Abstract: The invention concerns a homogenous, in particular multicolored plastic sheet or panel, based on ethylene vinyl acetate copolymer (EVA) as binder with a filler content of 30 to 80 wt. % and a process for producing it. In other embodiments the binder contains, in addition to the 70 to 85 wt. % of EVA, polypropylenes to improve the processability (tendency to adhere), EPDM to improve the flexibility, and polyethylenes to reduce the tendency to soiling. In the process described, several additives, each consisting of a binder containing at least some ethylene vinyl acetate copolymer, up to 80 wt. % of fillers and up to 5 wt. % of pigments, are mixed, plasticized and granulated or comminuted to form granules or chips of assorted colours which are mixed and, possibly after other processing operations, pressed to form the plastic web or plates.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: September 14, 1993
    Assignee: Huels Troisdorf AG
    Inventors: Alexander Hover, Manfred Simon, Herbert Schulte, Josef Becker, Richard Weiss, Hans-Joachim Kaseler
  • Patent number: 5234986
    Abstract: Copolymers of ethylene with such monomers as an alkyl acrylate and carbon monoxide or with vinyl acetate alone are blended with a thermoplastic block-polyester elastomer and a tackifier to produce thermally stable, hot-melt adhesive compositions which adhere well to polyvinyl chloride and which retain adhesivity at elevated temperatures. Fillers, plasticizers and compatible waxes may also be present in the composition.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: August 10, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Edward McBride
  • Patent number: 5234988
    Abstract: The invention provides a water based mixture of a rubber latex and a resin emulsion containing ground rubber which provides a high adhesion coating having excellent air bleed when coated on an uncured rubber article which is thereafter cured or vulcanized.
    Type: Grant
    Filed: August 12, 1992
    Date of Patent: August 10, 1993
    Assignee: Wacker Silicones Corporation
    Inventors: Howard L. Brooks, George M. Hart, Jaimini R. Vora
  • Patent number: 5218036
    Abstract: Shrinkable film and articles prepared therefrom which shrink more than 5% when heated to a temperature of 50.degree. C. are disclosed. The shrinkable film is prepared by stretching a polymer film of EPDM or EPM and EVA and talc more than 1.5 times in at least one direction at specified temperatures.
    Type: Grant
    Filed: December 24, 1990
    Date of Patent: June 8, 1993
    Assignee: Tonen Sekiyukagaku K.K.
    Inventors: Seiji Kagawa, Hideaki Toda, Yoshinaga Murakami
  • Patent number: 5218030
    Abstract: A novel curable polyphenylene ether resin composition is disclosed, which comprises (a) a curable polyphenylene ether resin having at least one group selected from the group consisting of an allyl group and a propargyl group and (b) at least one cyanurate. The resin composition has excellent storage stability, film-forming properties and melt moldability. If desired, a fire retardant, optionally together with an antimony-containing auxiliary fire retardant, and/or a reinforcement is incorporated into the resin composition in order to improve the fire retardance and mechanical properties of the resin composition, respectively. By curing the resin composition, a cured polyphenylene ether resin composition comprising a chloroform nonextractable polyphenylene ether resin component and a chloroform extractable, polyphenylene ether-containing component is obtained, which has excellent chemical resistance, electrical properties, dimensional stability and heat resistance.
    Type: Grant
    Filed: February 7, 1990
    Date of Patent: June 8, 1993
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Teruo Katayose, Hiroji Oda, Haruhisa Sasaki
  • Patent number: 5208285
    Abstract: Wet adhesion properties comparable or superior to all-acrylic latexes for vinyl acetate copolymers and other low cost polymers, such as EVA-vinyl chloride copolymers, is achieved by blending a minor proportion, usually about 5 to 15%, of a small particle size copolymer containing copolymerized wet adhesion monomer which is a cyclic ureido. Very low quantities of the wet adhesion monomer, less than 0.25 wt% of total monomers, only are required to achieve excellent results.
    Type: Grant
    Filed: August 16, 1991
    Date of Patent: May 4, 1993
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Clarke A. Boyce, Rajeev Farwaha, Brigitte H. Licht, Martin Menard
  • Patent number: 5137963
    Abstract: Non-formaldehyde emitting binders for nonwoven cellulosic materials comprise a solution copolymer of an olefinically unsaturated organic compound having at least one carboxylate group conjugated with the olefinic linkage, which is reacted with a hydroxyalkyl ester of an olefinically unsaturated carboxylic acid. The product of said reaction is admixed with a non-formaldehyde containing latex carrier to produce a binder composition which will reach substantially fully cured wet strength in 8 seconds or less.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: August 11, 1992
    Assignee: Union Oil Company of California
    Inventor: Dennis P. Stack
  • Patent number: 5122557
    Abstract: The present invention relates to light polarizing films containing water-soluble, transparent organic polymers and dichroic dyes capable of fluorescence and to new dichroic dyes.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: June 16, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Claussen, Friedrich W. Krock
  • Patent number: 5120787
    Abstract: Ethylene vinyl acetate copolymer films having about 25%-33% by weight vinyl acetate and melting points of about 160.degree.-170.degree. F. are provided for packaging, lining or wrapping purposes. Low melt bags for rubber compounds and additives are made from the films.
    Type: Grant
    Filed: July 5, 1991
    Date of Patent: June 9, 1992
    Assignee: J. Drasner & Co., Inc.
    Inventor: Joseph Drasner
  • Patent number: 5091458
    Abstract: An improved wood glue containing polyvinyl acetate also contains a cross-linking catalyst comprised of aluminum chloride and a dicarboxylic acid, such as oxalic acid. The catalyst also may contain a polyvinyl alcohol and an alkaline metal chloride, such as calcium chloride, to increase the amount of dicarboxylic acid that can be absorbed.
    Type: Grant
    Filed: February 15, 1990
    Date of Patent: February 25, 1992
    Assignee: Findley Adhesives, Inc.
    Inventor: John Santoemma
  • Patent number: 5082875
    Abstract: A sanitary rubber composition or article comprising a synthetic rubber prepared by solution polymerization and a fine powder of polyethylene having a molecular weight of 1.times.10.sup.6 to 1.times.10.sup.9 and having excellent chemical and physical properties is described.
    Type: Grant
    Filed: April 17, 1989
    Date of Patent: January 21, 1992
    Assignee: Kabushiki Kaisha Toritsu Industry
    Inventor: Masao Tajima
  • Patent number: 5070121
    Abstract: The invention concerns a solvent-free, polymerizing hotmelt substance free of, or low in monomers, for corrosion- and/or abrasion proofing and/or forming a protective film with barrier properties on a real substrates and molded bodies made of metal, plastic, cellulose materials and/or inorganic materials, in particular for wrapping purposes, and consisting of(a) one or more polymerizing polymers containing hydroxyls with an average molecular weight (M.sub.w) between 1,000 and 500,000 and with a glass transition temperature (T.sub.g).gtoreq.20.degree. C., and/or(b) one or more polymerizing, linear, unbranched and/or unbranched polyesters and/or their copolymers with an average molecular weight (M.sub.w) between 900 and 50,000 and with a glass transition temperature (T.sub.g).gtoreq.-50.degree. C.
    Type: Grant
    Filed: April 25, 1989
    Date of Patent: December 3, 1991
    Assignee: Schmalbach Lubeca AG
    Inventors: Rudolf Hinterwaldner, Georg Bolte
  • Patent number: 5051462
    Abstract: A halogen-containing thermoplastic resin composition comprising a halogen-containing thermoplastic resin (A), a metallic soap (B) and an ash- and alkali metal-lean ethylene-vinyl acetate copolymer hydrolysate (C) having an ethylene content of 20 to 75 mole percent, a degree of saponification not less than 50 mole percent, an ash content not exceeding 300 ppm and an alkali metal content not exceeding 200 ppm, the proportions of (B) and (C) based on 100 parts of weight by (A) being 0.1 to 5 parts by weight and 0.1 to 5 parts by weight, respectively. The composition may further include, in addition to (A), (B) and (C) mentioned above, at least one compound (D) selected from the group consisting of .beta.-diketone compounds, organic phosphorous esters and aminocarboxylic acid compounds, the proportion of (D) based on 100 parts by weight of (A) being 0.
    Type: Grant
    Filed: August 11, 1988
    Date of Patent: September 24, 1991
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Takida, Takamasa Moriyama, Yoshimi Akamatu, Makoto Kunieda
  • Patent number: 5051478
    Abstract: A dynamically vulcanized composition is provided which comprises a polyolefin resin, an elastomer, and an ethylene copolymer resin such as a copolymer of ethylene and vinyl acetate or an alkyl acrylate. A process for producing the dynamically vulcanized composition is also provided, which process includes the addition of the ethylene copolymer resin after the dynamic vulcanization step. The resulting composition comprises the ethylene copolymer resin predominantly in the polyolefin resin phase. The compositions have improved surface appearance and softness.
    Type: Grant
    Filed: July 26, 1990
    Date of Patent: September 24, 1991
    Assignee: Advanced Elastomer Systems, L. P.
    Inventors: Robert C. Puydak, Donald R. Hazelton
  • Patent number: 5028655
    Abstract: Non-formaldehyde emitting binders for nonwoven cellulosic materials comprise a solution copolymer of an olefinically unsaturated organic compound having at least one carboxylate group conjugated with the olefinic linkage, which is reacted with a hydroxyalkyl ester of an olefinically unsaturated carboxylic acid. The product of said reaction is admixed with a non-formaldehyde containing latex carrier to produce a binder composition which will reach substantially fully cured wet strength in 8 seconds or less.
    Type: Grant
    Filed: December 15, 1987
    Date of Patent: July 2, 1991
    Assignee: Union Oil Company of California
    Inventor: Dennis P. Stack
  • Patent number: 5021499
    Abstract: Hot melt adhesives containing petroleum resin tackifiers which are prepared by a process wherein (1) a C.sub.8 -- and/or C.sub.9 aromatic unsaturated hydrocarbon-containing feed (optionally containing up to 18 wt. % of C.sub.4 or C.sub.5 unsaturated aliphatic hydrocarbons) is first polymerized completely and thereafter a C.sub.5 -aliphatic unsaturated hydrocarbon-containing feed is added, polymerization continued and the reactor effluent stripped to obtain the resin. The order of polymerization may be reversed.
    Type: Grant
    Filed: July 9, 1990
    Date of Patent: June 4, 1991
    Assignee: Exxon Research and Engineering Company
    Inventors: Chiaki Tochinai, Tadanao Kohara, Sadayoshi Budo, Hiroaki Masuda, Takayoshi Yoshida
  • Patent number: 5017659
    Abstract: This invention relates to a polymer composition comprising per 100 parts by weight of the composition(a) 30-60 parts by weight of copolymer of ethylene and 1-olefin having at least 6 C atoms,(b) 35-65 parts by weight of copolymer of ethylene and vinyl acetate,(c) 1-10 parts by weight of ethylene-propylene-diene rubber,said polymer composition being obtained by reaction at elevated temperature of the components.
    Type: Grant
    Filed: November 3, 1988
    Date of Patent: May 21, 1991
    Inventor: L. A. van der Groep
  • Patent number: 5013771
    Abstract: A glass fiber-reinforced composite material is produced by treating glass fibers with a silane composition comprising silane molecules having amine functional groups and silane molecules having ethylenically-unsaturated functional groups; admixing the treated glass fibers with a polyolefin resin, and a fiber bonding agent comprising a polymerizable unsaturated organic compound having at least two polymerizable unsaturation groups, a vinyl-polymerizable unsaturated, hydrolyzable silane, and a free radical generator, and exposing the resultant mixture to conditions of temperature and pressure sufficient to cause the formation of a glass fiber-reinforced composite material. The use of the silane composition promotes improved impact strength of the composite.
    Type: Grant
    Filed: December 21, 1989
    Date of Patent: May 7, 1991
    Assignee: Union Carbide Chemicals and Plastics Technology Corporation
    Inventors: Antoine Guillet, Fred D. Osterholtz
  • Patent number: 5010131
    Abstract: An aqueous solution is provided for forming a thermally releasable coating on paint spray booth surfaces and equipment located in paint spray booths such that the coating is easily removable with heated water. The solution comprises water, filler, film former, an alkaline source and a blowing agent. In one embodiment of the invention the solution also comprises buffer, corrosion inhibitor, dispersant, detackifier, thickener, and flow modifier. In another embodiment of the invention the solution also comprises corrosion inhibitor and detackifier. There is also disclosed a method for removing paint from a surface using the barrier coating of this invention.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: April 23, 1991
    Assignee: Texo Corporation
    Inventor: Steven D. Wagner
  • Patent number: 5008326
    Abstract: Non-formaldehyde emitting binders for nonwoven cellulosic materials comprise a solution copolymer of an olefinically unsaturated organic compound having at least one carboxylate group conjugated with the olefinic linkage, which is reacted with a hydroxyalkyl ester of an olefinically unsaturated carboxylic acid. The product of said reaction is admixed with a non-formaldehyde containing latex carrier to produce a binder composition which will reach substantially fully cured wet strength in 8 seconds or less.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: April 16, 1991
    Assignee: Union Oil Company of California
    Inventor: Dennis P. Stack
  • Patent number: 5004799
    Abstract: An improved modified sulfur concrete product is provided in the form of discrete, self-sustaining pellets of modified sulfur concrete which can be shipped and stored for indefinite periods and remelted to yield useable concrete. The pellets are preferably formed by first preparing a quantity of hot modified sulfur concrete (74), followed by passing such concrete (74) into a pelletizing chamber (12) equipped with an elongated auger-type, axially rotatable mixing element (14) and apparatus (16) for the introduction of pressurized air and water into the chamber (12) in the form of a spray. Supplementary pressurized air may advantageously be added at spaced points along the length of the chamber (12).
    Type: Grant
    Filed: September 20, 1989
    Date of Patent: April 2, 1991
    Assignee: Reece Construction Company, Inc.
    Inventors: Dennis E. Kohls, Francis M. Moser
  • Patent number: 4997880
    Abstract: This invention relates to a polymer composition comprising(a) 30-70 parts by weight of one or more ethylene-propylenediene rubbers,(b) 30-70 parts by weight of one or more ethylene-vinyl acetate copolymers with a vinyl acetate content of 18-40% by weight, and(c) 1-25 parts by weight of one or more other polymers.The composition can be used with advantage, among other purposes for improving the miscibility of synthetic resins.
    Type: Grant
    Filed: May 17, 1990
    Date of Patent: March 5, 1991
    Inventor: Lambertus A. Van Der Groep
  • Patent number: 4980411
    Abstract: Binders for non-tacky, non-soiling, flexible coatings based on aqueous copolymer dispersions which contain zinc-amine complexes essentially consist of(A) from 99 to 90% by weight of a (meth)acrylate copolymer dispersion whose polymer has a glass transition temperature of from -40.degree. to -1.degree. C. and(B) from 1 to 10% by weight of a water-soluble zinc-amine complex salt of a polymeric carboxylic acid,the percentages by weight being based on the total amount of polymer.
    Type: Grant
    Filed: December 30, 1988
    Date of Patent: December 25, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Wilhelm F. Beckerle, Andree Dragon, Gernot Franzmann, Lothar Matthaei, Eckehardt Wistuba, Helmut Teichmann
  • Patent number: 4977208
    Abstract: (A) Water-absorbent coating compositions comprising (1) a nonaqueous dispersion of a resin, or a solution of a resin, and (2) a water-in-oil type emulsion of a water-swellable polymer with an average particle size not greater than 10 .mu.m; and a process for coating the same which uses a proper primer. (B) Water-absorbent coating compositions which comprise 100 parts by weight (on dry basis) of a resinous solution and 10 to 150 parts by weight (on solid basis) of a dehydrated water-in-oil type emulsion of a water-swellable polymer with an average particle size not greater than 10 .mu.m and which gives coated film with an elongation not lower than 30%.
    Type: Grant
    Filed: May 16, 1989
    Date of Patent: December 11, 1990
    Assignee: Mitsui-Cyanamid, Ltd.
    Inventors: Yoshio Hosoya, Naotaka Watanabe, Isao Takagi, Atsuo Miyoshi
  • Patent number: 4975481
    Abstract: An aqueous contact adhesive containing an aqueous dispersion of a water-immiscible solvent. The aqueous contact adhesive can contain additives such as preservatives, anti-oxidants, thickeners and thixotropicizing agents, emulsifiers and protective colloids. The contact adhesive has outstanding properties, particularly in regard to the absence of surface tackiness of substrate surfaces coated with the contact adhesive and a high initial tack of the substrate surfaces fitted together under pressure.
    Type: Grant
    Filed: November 2, 1988
    Date of Patent: December 4, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst Tamm, Franz-Bernhard Knop, Claus Kirchner
  • Patent number: 4945127
    Abstract: A heat-resistant formed product produced from a polymer composition comprising 40-70 weight % of a thermoplastic elastomer containing a repeating unit derived from ethylene and a repeating unit derived from propylene and 60-30 weight % of an ethylene-vinyl acetate copolymer containing 7.5 weight % or more of a vinyl acetate repeating unit, by blending the polymer composition at a temperature of 160.degree. C. or less, molding it at a temperature of 180.degree. C. or less, and then cross-linking the resulting molded product by irradiating electron beam or heating. The formed product also has good shape memory characteristics.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: July 31, 1990
    Assignee: Tonen Sekiyukagaku Kabushiki Kaisha
    Inventors: Seiji Kagawa, Hideaki Toda, Shinichiro Nomura
  • Patent number: 4940747
    Abstract: Thermoplastic moulding materials, of vinyl chloride polymers, which contain a polymer, prepared in the presence of mercaptans, from styrene, .alpha.-methylstyrene, vinyltoluene, acrylonitrile, methyl methacrylate or mixtures thereof and which possess improved processing properties.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: July 10, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Christian Lindner, Karl-Heinz Ott, Hans-Eberhard Braese
  • Patent number: 4906682
    Abstract: Concentrated emulsions, adaptable to use as pour point improvers, of (1) copolymers of ethylene and a vinyl ester of a C.sub.1 -C.sub.24 -carboxylic acid and/or (2) polyalkyl(meth)acrylic acid ester polymers in a liquid carrier medium which does not dissolve said polymers, said emulsions additionally containing, as an emulsifier, a graft- or block-copolymer of the formulaA--Y,wherein A is a segment of a copolymer of ethylene and a vinyl ester of a C.sub.1 -C.sub.24 -carboxylic acid (corresponding to polymer P1) or of a polymer of esters of acrylic acid and/or methacrylic acid with a C.sub.1 -C.sub.20 -alkanol, wherein Y is at least one segment obtained by the polymerization of vinyl monomers which are predominantly esters of acrylic acid or methacrylic acid with a C.sub.1 -C.sub.40 -alkanol, and wherein the carrier medium is capable of dissolving segments Y; oils containing such emulsions as pour point improvers.
    Type: Grant
    Filed: September 7, 1988
    Date of Patent: March 6, 1990
    Assignee: Rohm GmbH
    Inventors: Michael Mueller, Horst Pennewiss, Juergen Gebhardt
  • Patent number: 4900771
    Abstract: Thermally stable hot applied plastisol compositions are especially useful in the assembly of metal parts. The compositions have adhesive and sealant qualities which allow them to be used in automotive assembly plants. Compositions of the invention comprise as major ingredients finely divided polyvinyl chloride resin, plasticizer, thermoplastic polymeric resin which is solid at room temperature but softens to a flowable state at application temperature, and an adhesion promotion system. Optionally a filler, wax, heat stabilizer, pigment, wetting agent, or mixtures thereof may be added. The individual components work synergistically to get good application properties, metal adhesion, wash-out resistance, and paintability.
    Type: Grant
    Filed: January 26, 1989
    Date of Patent: February 13, 1990
    Assignee: Aster, Inc.
    Inventors: Michael J. Gerace, Janet M. Gerace
  • Patent number: 4894408
    Abstract: Heat shrinkable thermoplastic compositions are prepared by blending an ethylene copolymer resin with an EPDM rubber and dynamically vulcanizing the rubber. The ethylene copolymer resin is a copolymer of ethylene with an alkyl ester of an alpha, beta monoethylenically unsaturated monocarboxylic acid as well as copolymers of ethylene with the acid per se. The preferred copolymer is ethylene-vinylacetate copolymer. Uncured rubber can be included in the composition.
    Type: Grant
    Filed: August 23, 1988
    Date of Patent: January 16, 1990
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Donald R. Hazelton, Robert C. Puydak
  • Patent number: 4889884
    Abstract: This invention presents a series of synthetic based cold seal adhesives which are capable of forming a strong bonds at room temperature, yet which may be reeled up without blocking and stored for extended periods of time. Such adhesives can be used in place of the natural rubber based cold seal adhesives currently used, and thus, can be employed in any packaging application where cold seal properties are desirable.
    Type: Grant
    Filed: April 18, 1988
    Date of Patent: December 26, 1989
    Assignee: National Starch and Chemical Corporation
    Inventors: Richard A. Dust, Peter Causton