Ethylenic Monomer Contains A Chalcogen Heterocycle Patents (Class 524/531)
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Patent number: 11441095Abstract: The present invention is concerned with the use of polymeric additives for paraffin-containing fluids as pour point depressants and low temperature flow improvers, wherein the polymers comprise styrene and maleic acid dialkyl ester building blocks.Type: GrantFiled: July 22, 2016Date of Patent: September 13, 2022Assignee: Sasol Chemicals GmbHInventors: Oliver Herzog, Sabine Scherf, Michael Ruffmann, Wolfgang Breuer
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Patent number: 10640656Abstract: There are provided primer compositions comprising a primer component comprising: a rubber; an amine-functional (meth)acrylic resin; and a plasticizer. There are also provided articles made using these primer compositions.Type: GrantFiled: December 6, 2016Date of Patent: May 5, 2020Assignee: 3M Innovative Properties CompanyInventors: Dean M. Moren, David T. Amos
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Patent number: 10208192Abstract: Copolymers comprising ethylene, vinyl esters, in particular vinyl acetate and esters of (meth)acrylic acid, selected from esters comprising branched alkyl, cyclic alkyl or optionally alkyl substituted aryl moieties and having a weight average molecular weight of 35,000 g/mol to 150,000 g/mol, formulations of such copolymers in organic solvents and their use as pour point depressant, wax inhibitor and flow enhancer for crude oils.Type: GrantFiled: February 16, 2015Date of Patent: February 19, 2019Assignee: BASF SEInventors: Ivette Garcia Castro, Stefan Frenzel, Maria Heuken, Jennifer Jackson
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Patent number: 9556299Abstract: The invention relates to a copolymer whose overall structure as such and/or an optionally present segment A having at least 10 bivalent structural units in the overall structure contains surface-active bivalent structural units present in the form of long hydrocarbon chains among other forms. The copolymer is effective as a universal surface-active additive, especially also in conjunction with nonpolar media.Type: GrantFiled: May 4, 2012Date of Patent: January 31, 2017Assignee: BYK-Chemie GmbHInventors: Renë Nagelsdiek, Bernd Göbelt, Dorothée Greefrath, Bärbel Gertzen, Jürgen Omeis
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Patent number: 9469785Abstract: The invention includes an aqueous coating composition having a substituted succinimide compound, wherein the substituted succinimide compound has an acid value of at least about 30 mg KOH/g of the substituted succinimide compound. The substituted succinimide compound may be the reaction product of an unsaturated oil comprising at least one non-aromatic unsaturated carbon-carbon bond, a polymer derived from the unsaturated oil, or a combination thereof with maleic anhydride and a primary amine.Type: GrantFiled: September 19, 2013Date of Patent: October 18, 2016Assignee: AKZO NOBEL COATINGS INTERNATIONAL B.V.Inventors: Gary Pierce Craun, Jude Rademacher, Patricia Geelen
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Publication number: 20150031800Abstract: The present invention relates to polymeric materials including a glycosaminoglycan networked with a polyolefin-containing polymer. The present invention also relates to hydrogels containing the polymeric materials. The present invention further relates to methods of synthesizing the polymeric materials and hydrogels of the present invention.Type: ApplicationFiled: October 6, 2014Publication date: January 29, 2015Applicant: COLORADO STATE UNIVERSITY RESEARCH FOUNDATIONInventors: Susan P. JAMES, Susan S. YONEMURA, Ariane VARTANIAN
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Patent number: 8916642Abstract: The invention relates to the use in a photovoltaic module of a film of a composition as a backsheet or as an encapsulant, this composition comprising, with respect to the total weight of the composition: from 1 to 99% of a polyethylene having an ethylene whose level by weight is greater than or equal to 80% chosen from the homopolymers of ethylene and the copolymers of ethylene and another alpha-olefin; from 99 to 1% of a polyolefin B, other than A, carrying a reactive functional group X chosen from the anhydride carboxylic acids and epoxides. The invention further relates to a photovoltaic module comprising the film of the composition according to the invention and also a process for the manufacture of this module.Type: GrantFiled: December 14, 2009Date of Patent: December 23, 2014Assignee: Arkema FranceInventors: Catherine Corfias-Zuccalli, Laurent B. Cartier, Samuel Devisme, Stephane Bizet
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Patent number: 8835533Abstract: The present invention relates to anaerobically curable compositions demonstrating resistance to elevated temperature conditions.Type: GrantFiled: October 14, 2009Date of Patent: September 16, 2014Assignee: Henkel US IP LLCInventors: Qinyan Zhu, Shabbir Attarwala
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Publication number: 20130312904Abstract: A sealant article useful for sealing a substrate surface having a first surface and a second surface is provided. The first surface comprises a deformable composition that is capable of conforming to a substrate surface when subjected to heat and/or pressure. The second surface of the sealant article has been at least partially cured by exposing said surface to an amount of radiation effective to induce at least partial curing of the second surface of the sealant article. Prior to such curing, the second surface also is comprised of the deformable composition. Such at least partial curing is effective to render the second surface less deformable than the first surface.Type: ApplicationFiled: August 14, 2012Publication date: November 28, 2013Applicant: Henkel AG & Co. KGaAInventors: Jeffrey T. PACHL, Don K. HOWARD, Grady C. RORIE, Gregory A. FERGUSON
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Patent number: 8592040Abstract: Polymer emulsion formulations suitable for use as binders or in coating systems generally are provided. The formulations comprise a copolymer derived from one or more vinyl ester monomers of the formula I, one or more copolymerizable surfactants of formula II, and optionally one or more additional co-monomers. Gypsum boards, methods of making gypsum boards, and methods of making the copolymer are also disclosed.Type: GrantFiled: September 5, 2008Date of Patent: November 26, 2013Assignee: BASF SEInventors: Peter C. Hayes, Ronald Horwitz
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Publication number: 20130237660Abstract: Provided is a (meth)acrylate composition containing: (A) at least one (meth)acrylate compound selected from the group consisting of a (meth)acrylate-modified silicone oil, a (meth)acrylate having a long-chain aliphatic hydrocarbon group, and a polyalkylene glycol (meth)acrylate having number-average molecular weight of not less than 400; (B) a (meth)acrylate compound to which an alicyclic hydrocarbon group having 6 or more carbon atoms is ester-linked; (C) (meth)acrylic acid or a (meth)acrylate compound having a polar group; (D) a radical polymerization initiator; and (E) a white pigment.Type: ApplicationFiled: October 19, 2011Publication date: September 12, 2013Applicant: Idemitsu Kosan Co. LtdInventors: Takeshi Iwasaki, Daichi Ogawa, Yutaka Obata, Tomoaki Takebe
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Publication number: 20130164679Abstract: A curable resin composition comprises: (I) 100 parts by weight of a curable resin; (II) 10 to 1200 parts by weight of an inorganic filler; and (III) 1 to 100 parts by weight of an organic filler having an elastic modulus of 1 to 2000 (MPa) and an average particle diameter of 0.01 to 10 v, wherein a content weight ratio of the components (II) and (III) is 1 to 41.Type: ApplicationFiled: February 15, 2013Publication date: June 27, 2013Applicant: SAN-EI KAGAKU CO., LTD.Inventor: SAN-EI KAGAKU CO., LTD.
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Patent number: 8378017Abstract: The invention is based on the discovery that adhesive compositions containing certain low-viscosity, mono-ethylenically unsaturated monomers have surprisingly good cure parameters, resulting in very little weight loss upon cure. Many of these monofunctional monomers used alone or in combination with other monofunctional monomers described herein have high glass transition temperatures when cured. Moreover, since these monomers are monofunctional the crosslink density of the adhesive composition does not increase (relative to multi-functional monomers), which in turns results in lower stress, lower modulus adhesive compositions. As such, these monomers are useful in a variety of thermoset adhesive compositions, such as for example, die attach adhesive compositions.Type: GrantFiled: December 14, 2006Date of Patent: February 19, 2013Assignee: Designer Molecules, Inc.Inventors: Stephen M. Dershem, Gina Hoang, Melin Lu
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Patent number: 8360625Abstract: A vehicle headlamp is provided with: a frame; a lamp unit, which includes a first and a second connection sections and, which is rotatable with respect to the frame; a slider connected to first connection section and which is supported on the frame so as to be movable in a front-rear direction; a rotor connected to the second connection section and which is supported on the frame so as to be turnable in a horizontal direction; a drive operation section for moving the slider in the front-rear direction; and a rotation operation section for turning the rotor in the horizontal direction. The first connection section and the second connection section are positioned so as to be separated from each other substantially in the up-down direction.Type: GrantFiled: September 13, 2010Date of Patent: January 29, 2013Assignee: Koito Manufacturing Co., Ltd.Inventors: Hiroki Shibata, Kazutami Oishi, Masahiro Kusagaya, Tatsuhiro Terada, Kouji Magoori
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Publication number: 20120244369Abstract: The invention provides novel compositions comprising one or more polymers, including a functional triblock copolymer and optionally a structural triblock copolymer and compositions that include such polymers. The functional triblock contains quaternized nitrogen anti-fouling functionality. The compositions can be used to prepare antimicrobial, antifouling coatings, for example, for medical, health, marine fouling, corrosion and general protein fouling resistance applications.Type: ApplicationFiled: February 23, 2012Publication date: September 27, 2012Applicant: Cornell UniversityInventors: Christopher K. Ober, Craig Jonathan Weinman, Daewon Park, Dale L. Handlin
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Publication number: 20120196957Abstract: A compatibilizer blend having at least one compatibilizer and at least one desiccant to address the presence of certain interfering components, such as water, in a polymeric matrix.Type: ApplicationFiled: September 28, 2010Publication date: August 2, 2012Inventors: Jeffrey Jacob Cernohous, Neil R. Granlund
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Publication number: 20120022205Abstract: An object of the present invention is to provide a graft copolymer that is usable as various functional materials, that is stimulus responsive, and that is soluble in water at ordinary temperatures; and to provide an aqueous coating composition that comprises the graft copolymer as a thickener. The present invention also provides a rheology modifier for an aqueous coating composition comprising a graft copolymer consisting of (A) a main chain comprising an N-substituted (meth)acrylamide compound in a monomer component and having a lower critical solution temperature in water of 40° C. or higher, and (B) a hydrophobic side chain.Type: ApplicationFiled: March 3, 2010Publication date: January 26, 2012Inventor: Takeshi Fujii
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Publication number: 20110319551Abstract: It is an object to provide a film having both high transparency and high heat resistance, and particularly a coating solution for forming a coating film from which an optical film can be produced. A triaroylbenzene-skeleton polymer in which a terminal of a polymer produced by polymerizing a compound of Formula [1] below is modified by a compound of Formula [2] below. A coating solution for forming a coating film, comprising the polymer. A film obtained from the coating solution for forming a coating film. In the formulae below, X1 is a divalent group of Formula [1a], Formula [1b], or Formula [1c] below (where Y1 and Y2 are independently a C1-2 alkylene group; n is an integer of 1 to 6; and m is an integer of 1 to 6), X2 is divalent benzene, thiophene, furan, or fluorine, and X3 is a hydrogen atom, a halogen atom, CF3, a C1-6 alkoxy group, or a C1-6 alkyl group.Type: ApplicationFiled: October 2, 2009Publication date: December 29, 2011Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.Inventor: Takuro Oda
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Publication number: 20110318499Abstract: A laser fusible composition comprises a marking component, e.g. plastic dyes and pigments, coated with hot melt adhesive composition which can absorb laser irradiation at 780-10600 nm, and thereby causes through laser fusing, the composition to adhere firmly to metals, ceramics, glass, porcelain, marble, natural stone, paper and cardboards when heated.Type: ApplicationFiled: June 23, 2011Publication date: December 29, 2011Inventor: Jagdip Thaker
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Patent number: 7955655Abstract: The present invention provides a thermosetting and photocurable coating composition comprising: (A) at least one compound selected from the group consisting of radical-polymerizable unsaturated monomers, resins containing radical-polymerizable unsaturated groups, and resins containing radical-polymerizable unsaturated groups and thermosetting functional groups; (B) a hydroxyl-containing polyester resin produced by esterifying a polybasic acid (a) and a polyhydric alcohol (b), wherein an alicyclic polybasic acid (a1) and/or an alicyclic polyhydric alcohol (b1) are included in a ratio of 20% or more based on the total weight of polybasic acid (a) and polyhydric alcohol (b); (C) a crosslinking agent; and (D) a photopolymerization initiator; and a method of forming a coating film using the coating composition.Type: GrantFiled: February 18, 2003Date of Patent: June 7, 2011Assignee: Kansai Paint Co., Ltd.Inventors: Kazutoshi Sugiura, Kazuhiro Masuda, Hiromi Katoh, Kenichi Nagai, Yoshizumi Matsuno
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Publication number: 20100167615Abstract: The present invention describes a process for the surface finishing of materials via application of specific polymethacrylate layers. The polymethacrylate layers are composed of blends of at least two (co)polymers of polymethacrylates, and specific “reactive monomers” are present here in a polymerized mixture which forms the polymethacrylate layer. At the application temperature established, these form a chemical and, where appropriate, also a physical bond to the substrate, and therefore have adhesion-promoting action.Type: ApplicationFiled: December 23, 2009Publication date: July 1, 2010Applicant: Evonik Roehm GmbHInventors: Uwe Numrich, Michael Wicker, Achim Neuhaeuser, Christoph Krohmer, Guenther Dickhaut-Bayer
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Publication number: 20100062264Abstract: Polymer emulsion formulations suitable for use as binders or in coating systems generally are provided. The formulations comprise a copolymer derived from one or more vinyl ester monomers of the formula I, one or more copolymerizable surfactants of formula II, and optionally one or more additional co-monomers. Gypsum boards, methods of making gypsum boards, and methods of making the copolymer are also disclosed.Type: ApplicationFiled: September 5, 2008Publication date: March 11, 2010Applicant: BASF SEInventors: Peter C. Hayes, Ronald Horwitz
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Publication number: 20100044257Abstract: The present invention relates to a package for mailing CDs, DVDs or other optical computer readable mediums made of materials that include polycarbonate. The package includes a panel, preferably made of paperboard material, against which a surface of the optical computer readable medium can be located to protect against damage during mailing. The panel has a coating applied thereto that has a hardness that is less than the hardness of the polycarbonate material from which the optical computer medium is made in order to prevent the panel from scratching the surface of the optical computer readable medium. Although the coating may be in any form, it is preferred that the coating include an acrylic polymeric material.Type: ApplicationFiled: December 23, 2004Publication date: February 25, 2010Applicant: MEDIA TECHNOLOGY PTY LTD.Inventor: Allan Morton
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Publication number: 20090085240Abstract: Use of an aqueous polymer composition as a binder for fibrous and granular substratesType: ApplicationFiled: April 5, 2007Publication date: April 2, 2009Inventors: Oihana Elizalde, Matthias Gerst
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Patent number: 7495053Abstract: Aqueous, hydroxy-functional binder dispersions with a low solvent content and based on hydroxy-functional copolymers. The binders are prepared by subjecting one or more vinyl monomer mixtures containing OH-free (meth)acrylic esters and/or vinylaromatics, hydroxy-functional vinyl monomers and/or hydroxy-functional (meth)acrylic esters, and ionic and/or potentially ionic monomers capable of free-radical copolymerization, to free-radical polymerization in the presence of at least one compound containing lactone groups and subsequently dispersing the resultant copolymer before or after addition of a neutralizing agent in water. The binder combinations can be used in coating materials.Type: GrantFiled: December 15, 2004Date of Patent: February 24, 2009Assignee: Bayer MaterialScience AGInventors: Martin Melchiors, Thomas Münzmay, Thomas Stingl, Hartmut Ottensmann
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Patent number: 7235603Abstract: An ambient curable aqueous dispersion of polymer particles containing pendant ethylenically unsaturated side chains; a method of applying to a substrate a coating composition containing the aqueous dispersion of polymer particles; and a method of making the aqueous dispersion of polymer particles are provided.Type: GrantFiled: March 17, 2004Date of Patent: June 26, 2007Assignee: Rohm and Haas CompanyInventors: Thomas Glenn Madle, Matthew Stewart Gebhard, Chao-Jen Chung, Gary David Greenblatt
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Publication number: 20040254287Abstract: Aqueous coating compositions are described where the binder includes an anionically stabilised addition polymerised polymeric dispersion. The monomers used to prepare the dispersion are acrylic acid and methacrylic acid as a carboxylic monomer and styrene, alpha methyl styrene or vinyl toluene as a hydrophobic high Tg aromatic monomer and an alkyl acrylate ester as a low Tg monomer. The relative weight proportions of the monomers are required to satisfy a formula. Blends of high and low Tg dispersions are also described. Paints formulated with the binders exhibit an excellent balance of stain resistance, tint strength and viscosity stability.Type: ApplicationFiled: August 27, 2001Publication date: December 16, 2004Applicant: Orica Australia Pty Ltd.Inventors: Michelle Carey, Karen Elsbury, Patrick Houlihan, Bruce Leary, Lisa Madigan, Thamala Weerasinghe, Chantel Marise, Susan George
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Publication number: 20030105211Abstract: The present invention provides an adhesive composition comprising: an amorphous polyalphaolefin 50-90; a tackifier 10-40%; a functional polypropylene trace −20%; and optional further ingredients selected from stablisers, fillers and waxes; wherein the proportions of the amorphous polylphaolefin, tackifier and functionalised polypropylene are selected to total 100%. The invention also provides a method of forming polypropylene packaging by use of the adhesive.Type: ApplicationFiled: December 23, 2002Publication date: June 5, 2003Inventors: Sum-Wing Tsui, Anthony Francis Johnson
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Patent number: 6525118Abstract: A silica-filled, vulcanized elastomeric compound comprises 100 parts by weight of an elastomer; from about 5 to about 100 parts by weight of a reinforcing filler per 100 parts of elastomer, wherein the reinforcing fillers are selected from the group consisting of carbon black and silica filler; from 0 to about 20 percent by weight of a silane, based upon the weight of the silica filler; a cure agent; from about 0 to about 20 parts by weight of a processing aid selected from the group consisting of fatty acid esters of hydrogenated and non-hydrogenated C5 and C6 sugars; from about 0 to about 20 parts by weight of a processing aid selected from the group consisting of polyoxyethylene derivatives of fatty acid esters of hydrogenated and non-hydrogenated C5 and C6 sugars; from about 0 to about 40 parts by weight of an additional filler other than silica or carbon black, with the provisos that at least one of the processing aids or additional fillers are present; that if the processing aid is sorbitan monooleate,Type: GrantFiled: December 5, 1997Date of Patent: February 25, 2003Assignee: Bridgestone CorporationInventors: William L. Hergenrother, William M. Cole, James Oziomek
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Patent number: 6420474Abstract: Aqueous coating composition are described wherein the binder includes an anionically stabilized addition polymerized dispersion of a polymer. The monomers used to prepare the dispersion are acrylic cid and methyacrylic acid, as carboxylic monomers and styrene, alpha-methyl styrene or vinyl toluene as a hydrophobic high Tg aromatic monomer. Acrylate ester is used as a low Tg monomer. The relative weight proportions of the monomers are required to satisfy the designated formula. Blends of high and low Tg dispersions are also provided. Pains formulated with the binders of present invention exhibit excellent balance of stain resistance, tint strength and viscosity stability.Type: GrantFiled: May 27, 1999Date of Patent: July 16, 2002Assignee: Orica Australia Pty LtdInventors: Michelle Carey, Karen Elsbury, Patrick Houlihan, Bruce Leary, Lisa Madigan, Thamala Weerasinghe, Chantel Marise, Susan George
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Patent number: 6413306Abstract: A pigment dispersion useful for forming coating compositions containing dispersed pigment, a non-aqueous carrier liquid and an ABC-block polymer dispersant (binder); wherein the ABC block polymer has a number average molecular weight of about 5,000-20,000 and contains a polymeric A segment, a polymeric B segment and a polymeric C segment; wherein the polymeric A segment of the block polymer is of polymerized monomers selected from the following group: alkyl (meth)acrylate monomers having 1-12 carbon atoms in the alkyl group, aryl (meth)acrylate monomers, cyclo alkyl (meth)acrylate monomers or mixtures of any of the above; the polymeric B segment of the block polymer is of polymerized alkyl amino alkyl (meth)acrylate monomers having 1-4 carbon atoms in the alkyl group quaternized with an alkylating agent; and the polymeric C segment of the block polymer is of polymerized monomers of hydroxy alkyl (meth)acrylate having 1-4 carbon atoms in the alkyl group and monomers selected from the following group: alkylType: GrantFiled: October 7, 1999Date of Patent: July 2, 2002Assignee: E. I. du Pont de Nemours and CompanyInventors: Daniel C. Kraiter, Beatriz E. Rodriguez-Douglas
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Patent number: 6365656Abstract: Liquid dispersion polymer compositions which comprise microparticles of a hydrophilic, water soluble or swellable polymer, preferably an acrylic-based polymer, dispersed in a di- or triglyceride oil such as soybean oil and an oil-in-water surfactant, are useful to prepare microparticulate thickening systems to thicken aqueous or aqueous/organic compositions, particularly for use in personal care and pharmaceutical formulations. The preparation and the use of these liquid dispersion polymer compositions is described.Type: GrantFiled: April 5, 2000Date of Patent: April 2, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Michael Green, Eleanor Bernice Ridley, Dwayne Erick Gavin
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Publication number: 20020010257Abstract: The invention relates to solvent-based primer compositions containing 0.5 to 40 weight percent of a modified polyolefin and a solvent selected from the group consisting of ester solvents, ketone solvents, aliphatic solvents, aromatic solvents and mixtures thereof. The modified polyolefin is formed from an amorphous polyolefin selected from polypropylene and a propylene copolymer or a propylene terpolymer or an ethylene copolymer or terpolymer. Preferably the polyolefin is a polypropylene copolymer or terpolymer containing about 1 to about 99 mole percent ethylene, 1-butene, 1-pentene, and 1-hexene. The amorphous polyolefin has a number average molecular weight ranging from about 1,000 to 15,000 and is chemically modified with one or more unsaturated carboxylic acids selected from the group consisting of acids, esters and anhydrides. These primers are useful for significantly improving the adhesion of paints to polyolefin surfaces.Type: ApplicationFiled: October 5, 2001Publication date: January 24, 2002Applicant: Eastman Chemical CompanyInventors: Lisa Kay Templeton, Kevin Alan Williams, Richard Leon McConnell, Michael Alan Callahan
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Patent number: 6310134Abstract: The invention relates to solvent-based primer compositions containing 0.5 to 40 weight percent of a modified polyolefin and a solvent selected from the group consisting of ester solvents, ketone solvents, aliphatic solvents, aromatic solvents and mixtures thereof. The modified polyolefin is formed from an amorphous polyolefin selected from polypropylene and a propylene copolymer or a propylene terpolymer or an ethylene copolymer or terpolymer. Preferably the polyolefin is a polypropylene copolymer or terpolymer containing about 1 to about 99 mole percent ethylene, 1-butene, 1-pentene, and 1-hexene. The amorphous polyolefin has a number average molecular weight ranging from about 1,000 to 15,000 and is chemically modified with one or more unsaturated carboxylic acids selected from the group consisting of acids, esters and anhydrides. These primers are useful for significantly improving the adhesion of paints to polyolefin surfaces.Type: GrantFiled: June 29, 1999Date of Patent: October 30, 2001Assignee: Eastman Chemical CompanyInventors: Lisa Kay Templeton, Kevin Alan Williams, Richard Leon McConnell, Michael Alan Callahan
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Patent number: 6258889Abstract: An object of the present invention is to provide an emulsion and its production process, which is used for coating of plastic materials such as polyolefin and has enough coating and adhesion to polyolefin materials and is excellent in compatibility with an acrylic resin and other resins and has high storage stability. An emulsion includes: A styrene-acryl-acid grafted polyolefin chloride, which includes a polyolefin chloride structure moiety (1), an acid anhydride and/or carboxylic acid structure moiety (2) bonded to the moiety (1) and a styrene-acryl based polymerization chain moiety (3) bonded to the moiety (2) excluding some of the acid anhydride groups and/or carboxylic acid groups, wherein a ratio of the moiety (2) to a sum of the moiety (1) and the moiety (2) is 1-10 weight %; an emulsifier; a basic substance made of at least one of amine compound and ammonia; and water.Type: GrantFiled: March 9, 1999Date of Patent: July 10, 2001Assignee: Nippon Bee Chemical Co., Ltd.Inventors: Katsumi Mizuguchi, Yukiko Iida, Takeshi Nakasuka, Yoshihiko Saito
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Patent number: 6177488Abstract: The present invention provides an aqueous colored base coating composition (A) comprising a hydroxyl- and carboxyl-containing acrylic resin (A-1), a melamine resin (A-2), an alicyclic epoxy-containing compound (A-3), a neutralizing agent (A-4) and a coloring pigment (A-5). The present invention further provides a method for forming a topcoat which comprises applying the aqueous colored base coating composition (A) to a substrate and applying to the base coat an organic solvent type clear coating composition (B) to be cured by the crosslinking reaction between a carboxyl group and an epoxy group.Type: GrantFiled: August 13, 1996Date of Patent: January 23, 2001Assignee: Kansai Paint Company, LimitedInventors: Akira Kasari, Hiroaki Oda, Junichi Kajima, Mikio Shimakawa
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Patent number: 6107391Abstract: The present invention relates to a one-component system based on coreactive latexes which is able to lead to coatings which are crosslinkable at room temperature and post-crosslinkable by heat treatment, the said system consisting of a mixture of two particle dispersions, (A) and (B), each obtained by aqueous emulsion polymerization of a monomer composition A and B, respectively, (a) at least one free-radically polymerizable ethylenically unsaturated monomer comprising a functional group ##STR1## where X represents O or S, which enters into the monomer composition A; and (b) at least one free-radically polymerizable ethylenically unsaturated monomer comprising a masked aldehyde functional group selected from acetal, mercaptal, mercaptol, dioxolane and dithiolane, which enters into the monomer composition B.Type: GrantFiled: April 24, 1998Date of Patent: August 22, 2000Assignee: Elf Atochem S.A.Inventors: Christophe Verge, Isabelle Betremieux
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Patent number: 6103788Abstract: The present invention relates to a curable resin composition for use in water-based coating materials which includes as essential components an emulsion polymer (A) containing tertiary amino groups obtained by carrying out emulsion polymerization of a vinyl monomer containing a tertiary amino group with another copolymerizable vinyl monomer in a water-based medium, and a compound (B) containing, at least, an epoxy group and a hydrolyzable silyl group, with this composition preferably also including a water-based compound (C) obtained by adding a neutralizing agent to a vinyl polymer (I) containing acidic groups and/or tertiary amino groups so as to neutralize at least 10% of the acidic groups and/or the tertiary amino groups, and then dispersing or dissolving in water, and/or a compound (D), which is not included in compound (B), and contains hydrolyzable silyl group and/or a silanol group.Type: GrantFiled: July 22, 1997Date of Patent: August 15, 2000Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Nobuo Harui, Akifumi Yamamoto, Hidehisa Nakamura
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Patent number: 5994442Abstract: A thermoplastic resin composition containing(A) 100 parts by weight of:(1) a polycarbonate resin, and(2) a copolymer containing:(a) a rubber polymer(b) an aromatic vinyl monomer component, and(c) a vinyl cyanide monomer component,or a polystyrene resin;(B) 1-30 parts by weight of an addition polymer containing units derived from glycidyl (meth)acrylate; and(C) 0.001-1 part by weight of a compound such as an organic acid, phosphoric acid, phosphorous acid, hypophosphoric acid and/or a compound other than an organic acid that has one or more functional groups selected from among carboxyl, amino, hydroxyl, acid anhydride and thiol groups.Type: GrantFiled: September 18, 1992Date of Patent: November 30, 1999Assignee: General Electric CompanyInventors: Tomohide Fujiguchi, Hideyuki Itoi, Akihiro Saito
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Patent number: 5922119Abstract: The invention is directed to the use of an aqueous protective coating composition containing a binder system and an associative thickener for industrial coatings. The associative thickener is not a polyurethane thickener and is selected so that its concentration required by the specific application method is below the critical concentration C*, defined as the thickener concentration at which the coils of the thickener polymer start to overlap of entangle calculated according to the Mark Houwink equation.Type: GrantFiled: March 27, 1998Date of Patent: July 13, 1999Assignee: Hercules IncorporatedInventor: Kroon Gijsbert
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Patent number: 5907010Abstract: Graft copolymers are obtainable by reactingA) polyarylene ethers,B) polyamides andC) copolymers which contain cyclic, .alpha.,.beta.-unsaturated dicarboxylic anhydridesand are used for the preparation of thermoplastic molding materials or as compatibilizers for polymer blends based on polyarylene ethers and polyamides.Type: GrantFiled: March 18, 1997Date of Patent: May 25, 1999Assignee: BASF AktiengesellschaftInventors: Martin Weber, Norbert Guntherberg
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Patent number: 5900454Abstract: Aqueous dispersions comprising emulsified polyolefins and metal salts of phosphoric acid esters which are useful for sizing glass fibers.Type: GrantFiled: June 21, 1996Date of Patent: May 4, 1999Assignees: Bayer Aktiengesellschaft, Bayer Antwerpen N.V.Inventors: Stephan Kirchmeyer, Alexander Karbach, Raymond Audenaert
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Patent number: 5849824Abstract: The invention provides for a thermoset or thermoplastic gel composition containing a polymer with anhydride groups along the polymer backbone at least at outset of the fabrication process and an extender fluid, optionally including thermally conductive fillers. The gel compositions are useful for sealing wires, vibration dampening, sporting goods, and toys.Type: GrantFiled: February 6, 1996Date of Patent: December 15, 1998Assignee: Raychem CorporationInventors: Frank Mercer, Hendrik Graulus
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Patent number: 5847036Abstract: The present invention provides a (meth)acrylic molding material comprising (A) a (meth)acrylic polymer obtained by polymerization of monomer components essentially containing a monomer having (a) carboxyl group(s) and an alkyl (meth)acrylate monomer, and (B) one or more kinds of monomers containing a vinyl group, wherein 30-600 parts by weight of aluminum hydroxide and 0.01-10 parts by weight of a succinic acid derivative are added for 100 parts by weight of the total of said polymer (A) and monomer (B). The (meth)acrylic molding material is thickened by aluminum hydroxide and the thickening behavior is controlled by the succinic acid derivative to prevent the viscosity from increasing with time, accordingly, the (meth)acrylic molding material shows good workability.Type: GrantFiled: June 21, 1996Date of Patent: December 8, 1998Assignee: Nippon Shokubai Co., Ltd.Inventors: Kouji Takabatake, Yuichi Kawata, Shigeo Otome
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Patent number: 5811484Abstract: A process is disclosed for preparing water-dilutable, acrylate copolymer-based lacquer binders. A polycarboxylic component is reacted with an epoxide group-containing polyhydroxylic component, and the carboxylic groups are then at least partially neutralized. As epoxide group-containing monomers for the polyhydroxylic components, glycidyl(meth)acrylate and/or glycidylallylether are used in proportions from 0.1 to 3% by weight. Associated with cross-linking components and if required with other lacquer binders, these lacquer binders are suitable for producing water-dilutable baking enamels with a low auxiliary organic solvent content.Type: GrantFiled: June 24, 1996Date of Patent: September 22, 1998Assignee: Vianova Resins AktiengesellschaftInventors: Werner Wilfinger, Ingo Kriessmann, Kurt Gossak
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Patent number: 5770638Abstract: An adhesive for dental resin composite materials is disclosed, which comprises (a) from 10 to 40 parts by weight of tetrahydrofurfuryl methacrylate; (b) from 90 to 60 parts by weight of one or more methacrylates having at least one unsaturated double bond in one molecule thereof; and (c) from 0.04 to 0.12 part by weight, based on 100 parts by weight of the monomer mixture consisting of (a) and (b), of a photopolymerization initiator, the adhesive for dental resin composite materials of the present invention having a proper viscosity, not causing the color remaining, is superior in the operability and esthetics, having further a satisfactory adhesive strength, and is of safe even when used in the mouth.Type: GrantFiled: March 27, 1996Date of Patent: June 23, 1998Assignee: GC CorporationInventors: Takayuki Ueno, Tomohiro Kumagai
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Patent number: 5753728Abstract: Polymeric compositions well suited for conversion into electroconductive shaped articles, e.g., films, comprise at least one convertible polymer (Pm) and at least one amphiphilic organic compound (B) which comprises a charge transfer complex or a radical ion salt having the formula (I): D.sub.d A.sub.a Z.sub.z, in which D is an electron donor; A is an electron acceptor; Z is a doping agent which itself can be a non-amphiphilic electron donor or electron acceptor, with the proviso that at least one of D and A is amphiphilic and contains at least one saturated or unsaturated hydrocarbon substituent having at least 10 carbon atoms; d is a number equal to or greater than 0; a is a number equal to or greater than 0; and z is a number equal to or greater than 0, with the further proviso that at least one of the symbols d and a is a number greater than 0.Type: GrantFiled: June 5, 1995Date of Patent: May 19, 1998Assignee: Rhone-Poulenc ChimieInventors: Bernard Chauvel, Joel Richard
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Patent number: 5728767Abstract: The invention relates to an aqueous resin composition characterized by comprising 80 to 10 parts by weight of modified polyolefin with weight average molecular weight of 1000 to 100000, modified by copolymerizing polypropylene, polyethylene, copolymer of propylene or ethylene with .alpha.-olefin or degradation products of these under heat or with oxidizing agent, radical-generating agent or the like, with 0.1 to 20% by weight of one kind or not less than two kinds of acid anhydride, carboxylic acid or alcohol with radically polymerizable double bond, and 20 to 90 parts by weight of one kind or a mixture of two or more kinds of acrylic or methacrylic monomers, mixed or dissolved and polymerized in water in the presence of surfactant and polymerization initiator. And, the aqueous resin composition of the invention not only shows excellent adhesion to polyolefin, but also has adherence to other organic substrates and inorganic substrates.Type: GrantFiled: December 20, 1996Date of Patent: March 17, 1998Assignee: Nippon Paper Industries Co., Ltd.Inventors: Noriyuki Kanetou, Kenichi Fujino, Hiroaki Namba, Taro Abe
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Patent number: 5714096Abstract: The present invention is directed to a positive temperature coefficient composition comprising by weight based on total composition, 10-30% carbon black possessing a DBP absorption of about 125 cc/100 g carbon black or less; 10-40% chlorinated, maleic anhydride grafted, polypropylene resin; and organic medium capable of solubilizing the resin.Type: GrantFiled: September 3, 1996Date of Patent: February 3, 1998Assignee: E. I. Du Pont de Nemours and CompanyInventor: Jay Robert Dorfman
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Patent number: 5712362Abstract: The invention relates to a process for the production of UV-stable polycarbonates, to the polycarbonates obtainable in accordance with the invention and to their use for the production of sheets, more particularly plastic panels.Type: GrantFiled: August 10, 1995Date of Patent: January 27, 1998Assignee: Bayer AGInventors: Thomas Scholl, Peter Bier