From Fluorine-containing Monomer Patents (Class 524/544)
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Patent number: 7202324Abstract: Disclosed is a fluorine compound having perfluorostyrene introduced at a terminal thereof, as represented in the following Formula 1, and a coating solution and an optical waveguide device using the same, characterized in that the introduction of perfluorostyrene results in a facile fabrication of thin films by a UV curing or a thermal curing, high thermal stability and chemical resistance, and low optical propagation loss and birefringence: Wherein Z is O or S; RF is an aliphatic or aromatic group; y is a natural number of 1–10; y? is an integer of 0–1; x is an integer of 0–200; and Wherein B is a single bond or selected from the group consisting of —CO—, —SO2—, —S— and —O—, and Hal is selected from the group consisting of F, Cl, Br and I.Type: GrantFiled: January 13, 2005Date of Patent: April 10, 2007Assignee: Chemoptics Inc.Inventors: Ji-Hyang Kim, Jae-II Kim, Tae-Kyun Kim, Hyung Jong Lee, Seon Gyu Han
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Patent number: 7202299Abstract: A fluoroelastomer composition, which comprises 100 parts by weight of vinylidene fluoride-perfluoro(methyl vinyl ether)-tetrafluoroethylene terpolymer or vinylidene fluoride-hexafluoropropene copolymer, and 10–50 parts by weight of liquid fluoroelastomer having a viscosity of 500 to 3,000 cps at 100° C., can be made cross-linkable or vulcanizable fluoroelastomer composition upon further addition of 0.5 to 5 parts by weight of an organic peroxide and 0.5 to 10 parts by weight of a polyfunctional unsaturated compound or further addition of 0.5 to 10 parts by weight of a polyol-based vulcanizing agent thereto. The fluoroelastomer composition can give a cross-linked or vulcanized product having a hardness (Durometer A) of not more than 50 and distinguished processability and compression set resistance characteristics.Type: GrantFiled: January 7, 2004Date of Patent: April 10, 2007Assignee: NOK CorporationInventors: Yoshifumi Kojima, Atsushi Koga, Kenichi Fujimoto
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Patent number: 7198863Abstract: A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.Type: GrantFiled: November 10, 2004Date of Patent: April 3, 2007Assignee: Sony CorporationInventors: Berthold Nuber, Bjoern Pietzak
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Patent number: 7199197Abstract: Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.Type: GrantFiled: December 28, 2004Date of Patent: April 3, 2007Assignee: 3M Innovative Properties CompanyInventors: Gregg A. Caldwell, John C. Clark, David J. Kinning, Alan R. Kirk, Thomas P. Klun, Ramesh C. Kumar, Roger A. Mader, George G. I. Moore, Zai-Ming Qiu, Richard B. Ross
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Patent number: 7192997Abstract: A composition for use in making an encapsulant usable in the encapsulation of a semiconductor chip assembled to a substrate with C4 solder interconnections therebetween, which in turn may form part of an electronic package. The composition comprises a resin, a flexibilizing agent and a filler material.Type: GrantFiled: February 7, 2001Date of Patent: March 20, 2007Assignee: International Business Machines CorporationInventor: Konstantinos I. Papathomas
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Patent number: 7189780Abstract: A process to produce an acid-treated aqueous dispersion is provided. The process comprises contacting a polymer, a water dispersible polyester, water, and at least one acid-generating compound; wherein said polymer comprises repeating units from at least one fluoroalkyl monomer and optionally, at least one ethylenically unsaturated monomer; wherein the acid-generating compound is at least one acid or acid salt.Type: GrantFiled: August 12, 2003Date of Patent: March 13, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: James Foster Von Schmittou, Darrell Scott Nasser
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Patent number: 7186769Abstract: In this invention, an aqueous dispersion is provided to improve the oil and water repellency of materials. The aqueous dispersion comprises a polymer, at least one water dispersible polyester, and water; wherein the polymer comprises the repeating units from at least one fluoroalkyl monomer and optionally, at least one ethylenically unsaturated monomer. This invention also provides an article coated with the aqueous dispersion.Type: GrantFiled: August 12, 2003Date of Patent: March 6, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: James Foster Von Schmittou, Darrell Scott Nasser
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Patent number: 7173081Abstract: A process is provided to produce an aqueous dispersion wherein the aqueous dispersion enhances the water and oil repellency of materials. The process comprises: 1) contacting at least one fluoroalkyl monomer, at least one water-dispersible polyester, water, and optionally an ethylenically unsaturated monomer to form a pre-emulsion; and 2) polymerizing the pre-emulsion in a polymerization zone in the presence of an initiator to produce the aqueous dispersion. In another embodiment, a process to produce an aqueous dispersion is provided. The process comprises: 1) contacting at least one fluoroalkyl monomer, at least one water-dispersible polyester, water, and optionally an ethylenically unsaturated monomer to form a pre-emulsion; 2) shearing the pre-emulsion to produce a mini-emulsion; and 3) polymerizing the miniemulsion in a polymerization zone to produce the aqueous dispersion.Type: GrantFiled: August 12, 2003Date of Patent: February 6, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: James Foster Von Schmittou, Darrell Scott Nasser
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Patent number: 7173084Abstract: Use of a polymer as a levelling agent or anti-cratering agent, said polymer comprising at least one fluorinated unit represented by formula 1, (Formula 1) wherein R?1 is a moiety represented by Cn?F2n+1?-(CH2?)m?-, ?Cn?F2n?-(CH2?)m?-, Cn?F2n+1?-(CII2?)m?-(OCII2?CIIR?5)p?-, ?Cn?F2n?-(CH2?m?-(OCH2?CHR?5)p?? Cn?F2n+1?-(CII2?)m?-X-, ACn?F2n?-(CII2?)m?-X-?Cn?F2n?-(CH2?)m?-(OCH2?CHR?5)p?-X or Cn?F2n+1?-(CII2?)m?-(OCII2?CIIR?5)p?-X-; wherein A=H, Cl, Br, I, a C1–12? alkyl or a OC1–12 ?alkyl, wherein 4?n?20,0?m˜?4 and 0?p?20, wherein X is a spacer moiety selected from the group consisting of esters, amides, sulphoamides, mercapto groups, poltyurethane groups and alkyl groups, wherein R?2, is H, a metal moiety, an (alkyl)ammonium moiety or an alkyl group, Cn?F2n+1?-(CII2?)m?-, ACn?F2n?-(CII2?)m?-, Cn?F2n+1?-(CII2?)m?-(OCII2?CIIR?5)p?-, ?Cn?F2n?-(CH2?)m?-(OCH2?CHR?5)p?? Cn?F2n+1?-(CH2?)m?-X-, ?Cn?F2n?-(CH2?)m?-X-, ACn?F2n?-(CH2?)m?-(OCH2?CHR?5)p?-X or Cn?F2n+1?-(CH2?)m?-(OCH2?CHR?5)p?-X-; wherein A=H, Cl, Br, I, C1–12?Type: GrantFiled: October 8, 2002Date of Patent: February 6, 2007Assignee: EFKA Additives B.V.Inventors: Frank Oliver Heinrich Pirrung, Elizabeth Maaike Loen, Lothar Alexander Engelbrecht, Arend Noordam
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Patent number: 7169854Abstract: The present invention provides a fluororesin composition, which is excellent in moldability and crack resistance, a process for preparing the composition and a cable evenly coated with the composition. Specifically, the present invention provides a fluororesin composition wherein polytetrafluoroethylene is compounded to a terpolymer comprising tetrafluoroethylene, hexafluoropropylene and perfluoroalkyl vinylether. Also, the present invention provides a process for preparing the composition which comprises kneading with a multi-screw kneader. Furthermore, the present invention provides a cable which is coated with the resin.Type: GrantFiled: September 10, 2002Date of Patent: January 30, 2007Assignee: Daikin Industries, Ltd.Inventors: Masayuki Namimatsu, Yoshiyuki Hiraga, Yoshiyuki Takase, Tadahiro Yabu
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Patent number: 7166329Abstract: A fluorochemical composition comprising of organic solvent and fluorochemical oligomer represented by the general formula: X-MfnMhmMar-G wherein X represents the residue of an initiator or hydrogen; Mf represents units derived from fluorinated monomers; Mh represents units derived from a non-fluorinated monomers; Ma represents units having a silyl group represented by the formula: wherein each of Y4, Y5 and Y6 independently represents an alkyl group, an aryl group or a hydrolyzable group; G is a monovalent organic group comprising the residue of a chain transfer agent; n represents a value of 1 to 100; m represents a value of 0 to 100; r represents a value of 0 to 100; and n+m+r is at least 2.Type: GrantFiled: January 17, 2002Date of Patent: January 23, 2007Assignee: 3M Innovative Properties CompanyInventor: Rudolf J. Dams
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Patent number: 7160622Abstract: An oil repelling agent to coat a dynamic pressure device, such as a fluid dynamic pressure bearing device, includes a UV coloring agent, a fluorine-based polymer and a solvent. In an exemplary embodiment of the invention, the concentration of the UV coloring agent component is about 100 PPM to about 400 PPM, and the concentration of the fluorine polymer is about 0.1% by weight to about 0.6% by weight.Type: GrantFiled: September 4, 2003Date of Patent: January 9, 2007Assignee: Minebea Co., Ltd.Inventors: Akio Okamiya, Takahiko Ito
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Patent number: 7157550Abstract: A purification process of thermoprocessable tetrafluoroethylene (TFE) copolymers comprising the following steps: A) the polymer latex is transformed into gel form, under mechanical stirring, by addition of an acid electrolyte having pH values?2; B) washing of the polymer gel with aqueous solutions having pH from 1 to 7.Type: GrantFiled: March 3, 2004Date of Patent: January 2, 2007Assignee: Ausimont S.p.A.Inventors: Hua Wu, Vincenzo Arcella
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Patent number: 7144948Abstract: It is to provide a production process by which gelation can be prevented, in a case where a solvent is removed from a curable fluororesin to obtain a chief material resin, and then coating additives such as a curing agent are mixed to produce a powder coating composition, or in a case where a curable fluororesin, a curing agent and various additives are dissolved or dispersed in a solvent to prepare a raw material solution, and the solvent is removed from the raw material solution to directly produce a powder coating material. To a solution or dispersion of a curable fluorinated copolymer (A), a gelation inhibitor (B) is added, followed by mixing, or a gelation inhibitor (B), a curing agent (C) and as the case requires, various additives (D) are added, followed by mixing, and the solution or dispersion is supplied to a thin-film vacuum evaporator to remove the solvent.Type: GrantFiled: June 9, 2004Date of Patent: December 5, 2006Assignee: Asahi Glass Company, LimitedInventors: Masaru Yamauchi, Toru Ishida
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Patent number: 7135527Abstract: Processable rubber compositions contain a vulcanized fluorocarbon elastomer dispersed in a thermoplastic matrix comprising a fully fluorinated polymer and a partially fluorinated polymer. The processing temperature is below the melting point of the fully fluorinated polymer. The compositions are made by combining a curative, uncured fluorocarbon elastomer, a fully fluorinated thermoplastic, and a partially fluorinated thermoplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles such as seals, gaskets, O-rings, and hoses may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.Type: GrantFiled: March 30, 2004Date of Patent: November 14, 2006Assignee: Freudenberg-NOK General PartnershipInventor: Edward Hosung Park
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Patent number: 7129014Abstract: The present invention provides a positive resist composition comprising a resin which itself is insoluble or poorly soluble in an alkali aqueous solution but becomes soluble in an alkali aqueous solution by the action of an acid, an acid generator, and multifunctional epoxy compound, wherein the content of halogen atoms in the resin is 40% by weight or more, at least one of structural units constituting the resin is a structural unit having an alicyclic hydrocarbon skeleton, and the structural unit having an alicyclic hydrocarbon skeleton contains therein at least one group rendering the resin soluble in an alkali aqueous solution by the action of an acid, and at least one halogen atom.Type: GrantFiled: April 2, 2003Date of Patent: October 31, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Kouji Toishi, Yoshiko Miya, Yasunori Uetani
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Patent number: 7125598Abstract: There is provided a fluorine-containing elastomer molded article which is obtained by irradiating the fluorine-containing elastomer molded article with a plasma and has a center line average roughness of not less than 0.65 ?m or a fluorine-containing elastomer molded article which is obtained by applying a resin coating layer on a fluorine-containing elastomer substrate, has a small peeling strength and a small etching rate at the irradiation of plasma and is excellent in detachability and whiteness. There is provided particularly a molded article suitable as various sealing materials for semiconductor production apparatuses.Type: GrantFiled: April 19, 2001Date of Patent: October 24, 2006Assignee: Daikin Industries, Ltd.Inventors: Takafumi Yamato, Katsuhiko Higashino, Hiroyuki Tanaka, Tsuyoshi Noguchi, Mitsuru Kishine
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Patent number: 7105597Abstract: The present invention provides a resin aqueous dispersion composition comprising water and at least one kind of resin particle, wherein when a primary average particle of each resin particle is taken as a sphere of the same volume, a nonionic surfactant is present in the composition in an amount which occupies 75 to 95% of a theoretical void among resin particles of 26% when each resin particle is arranged in a close packed structure. The nonionic surfactant is a solvent which is substantially nonvolatile in a temperature range of up to 100° C. and evaporates or thermally decomposes at a temperature lower than the thermal decomposition temperature of the resin particles. The resin aqueous dispersion composition can be coated thickly and can prevent development of mud crack.Type: GrantFiled: July 16, 2002Date of Patent: September 12, 2006Assignee: Daikin Industries, Ltd.Inventors: Yoshihiro Soda, Nobuyuki Tomihashi, Hiromichi Momose, Koichiro Ogita
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Patent number: 7101924Abstract: In this invention, an acid treated, aqueous dispersion is provided that improves the oil and water-repellency of materials. The acid-treated, aqueous dispersion comprises at least one polymer, at least one water-dispersible polyester, water, and at least one acid-generating compound; wherein the polymer comprises repeating units from at least one fluoroalkyl monomer and optionally, at least one ethylenically unsaturated monomer. Articles coated with the acid-treated, aqueous dispersion are also provided.Type: GrantFiled: August 12, 2003Date of Patent: September 5, 2006Assignee: Hexion Specialty Materials, Inc.Inventors: James Foster Von Schmittou, Darrell Scott Nasser
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Patent number: 7101925Abstract: A process to substantially remove the fluorinated anionic surfactants comprising the following steps: a) addition to a fluoropolymer dispersion of a nonionic surfactant, in an amount in the range 1.5%–25% by weight, referred to the fluoropolymer weight; b) addition to the dispersion of a salt, soluble in water and not giving precipitates in the dispersion under the use conditions; c) contact of the dispersion with a basic anionic exchanger; d) separation of the dispersion from the basic anionic exchanger; before step d) the dispersion being filterable on a 180 micrometer net and successively on a 10 micrometer net.Type: GrantFiled: January 12, 2005Date of Patent: September 5, 2006Assignee: Solvay Solexis, S.p.A.Inventors: Marco Malvasi, Valeri Kapeliouchko
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Patent number: 7094839Abstract: Aqueous microemulsions obtained from a perfluorinated alkane sulphonic or carboxylic acid or salt thereof, a liquid fluorinated monomer comprising a cure-site and optionally an inert liquid and highly fluorinated hydrocarbon compound. The aqueous microemulsion may be formed by mixing together water, a perfluorinated alkane sulphonic or carboxylic acid or salt thereof, optionally an inert liquid and highly fluorinated hydrocarbon compound and a liquid fluorinated monomer having a cure-site.Type: GrantFiled: July 25, 2003Date of Patent: August 22, 2006Assignee: 3M Innovative Properties CompanyInventors: Werner M. A. Grootaert, Klaus Hintzer, Bernhard Hirsch, Harald Kaspar, Robert E. Kolb, Gernot Löhr, Werner Schwertfeger
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Patent number: 7094829Abstract: A fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain repellent and comprising a fluorinated polymer dispersed in water or dissolved or dispersed in an organic solvent, the fluorinated polymer comprising units derived from (i) a mixture of two or more fluorinated polyether monomers that differ in at least their molecular weight, the fluorinated polyether monomers having an ethylenically unsaturated group and a perfluorinated polyether group and wherein at least 90% by weight of the mixture consists of fluorinated polyether monomers that have a perfluorinated polyether group having a molecular weight of at least 750 g/mol and (ii) one or more units derived from one or more co-monomers other than a fluorinated polyether monomer and wherein the co-monomers comprise at least one non-fluorinated monomer. Also, method for treating fibrous substrate with such composition, fluorinated polyether monomers, and fluorinated polymers derived from such monomers.Type: GrantFiled: May 23, 2003Date of Patent: August 22, 2006Assignee: 3M Innovative Properties CompanyInventors: Frans A. Audenaert, Rudolf J. Dams, Richard S. Buckanin
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Patent number: 7090909Abstract: The present invention provides a hard coat agent composition that is useful for forming a hard coat layer with excellent anti-staining properties and lubricity, as well as superior scratch resistance and abrasion resistance, on the surfaces of various articles. The present invention also provides an optical information medium using the above hard coat agent composition. A hard coat agent composition comprising a fluorine-containing block copolymer (A1), a fluorine-containing polyether compound (A2) comprising an active energy ray-reactive group, and an active energy ray-curable compound (B). An optical information medium comprising a film element composed of one or more layers including at least a recording layer (4) or a reflective layer, on a supporting substrate (20), wherein at least one of the supporting substrate (20)-side surface and the film element-side surface is formed of a hard coat layer (8) comprising a cured product of the hard coat agent composition.Type: GrantFiled: December 22, 2004Date of Patent: August 15, 2006Assignee: TDK CorporationInventors: Hidetake Itoh, Kenji Yoneyama, Kazushi Tanaka
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Patent number: 7087673Abstract: A crosslinkable fluororubber composition comprising (A) a polymer of the formula: Z-(Rf-Q)n—Rf-Z wherein n is an integer of at least 1, Rf is a divalent perfluoroalkylene or perfluorooxyalkylene radical, Q is a divalent organic radical, and Z is a monovalent organic radical, having a viscosity of at least 1,000 Pa·s at 25° C., (B) a reinforcing filler, and (C) a peroxide crosslinking agent is effectively roll milled and experiences minimal changes of viscosity after milling. Molded parts can be produced on a mass scale.Type: GrantFiled: January 7, 2003Date of Patent: August 8, 2006Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takashi Matsuda, Yasuhisa Osawa, Noriyuki Koike, Yasunori Sakano
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Patent number: 7078456Abstract: A method of treating fibrous substrates by contacting the substrate with a fluorochemical composition comprising: a fluorochemical oligomeric component and an antisoiling component is described. The compositions provide desirable antisoiling properties, as well as oil, water and stain repellency to fibrous substrates.Type: GrantFiled: November 26, 2003Date of Patent: July 18, 2006Assignee: 3M Innovative Properties CompanyInventors: Chetan P. Jariwala, Dirk M. Coppens, Frank A. H. M. Godefroidt
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Patent number: 7074848Abstract: The invention pertains to a resin composition comprising a polymer and a solvent, characterized in that the polymer is obtained by polymerizing the following monomers: (a) an acrylate monomer; (b) a tertiary carboxylic ester; and (c) a monomer selected from the group consisting of a fluoro acrylate monomer, a silicone monomer, and a mixture thereof. The resin composition of the invention can be formulated into a coating for a substrate to impart stain resistance to the coated surface.Type: GrantFiled: January 29, 2004Date of Patent: July 11, 2006Assignee: Eternal Chemical Co., Ltd.Inventors: Mao-Jung Yeh, Chun-Hsiung Chang
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Patent number: 7067580Abstract: A flexible thermal control composite comprising a natural or synthetic polymer and an endotherm dispersed, distributed and suspended within said natural or synthetic polymer i.e. “P”olymer “C”ontaining an “E”ndothermic “A”gent (PCEA). The PCEA can be formed into thin and thick films. It can be drawn, molded, extruded and spun into fibers or all dimensions. It can be formed and chopped into PCEA mulch. Irrespective its final form, the PCEA can be used in insulating, thermoprotecting, heat absorbing applications on the one hand, and heat maintenance applications of all types on the other.Type: GrantFiled: April 26, 2004Date of Patent: June 27, 2006Inventor: Claude Q. C. Hayes
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Patent number: 7060748Abstract: A catalyst paste composition for making electrodes has a uniform dispersion condition of a carbon black supporting a hydrogen reduction catalyst and is excellent in storage stability. The catalyst paste composition comprises a carbon black supporting a hydrogen reduction catalyst, an electrolyte, a water-soluble sulfonated polymer and a solvent.Type: GrantFiled: May 20, 2003Date of Patent: June 13, 2006Assignees: JSR Corporation, Honda Motor Co.,Ltd.Inventors: Makoto Higami, Keiichi Bessho
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Patent number: 7056974Abstract: A method of use of copolymers containing fluoro groups and hydroxyl groups as additives in powder coating materials, comprising mixing these component with powder coatings resins, the copolymers comprising units of the following monomers: olefinically unsaturated monomers having from 5 to 40 carbon atoms, at least one hydroxyl group, and at least one free-radically polymerizable C?C double bond, alkyl esters of monoolefinically unsaturated monocarboxylic acids or dialkyl esters of olefinically unsaturated dicarboxylic acids or mixtures thereof, and (per)fluoroalkyl esters of said carboxylic acids, and powder coating materials which comprise these additives for the purpose of improving the flow properties and the surface.Type: GrantFiled: October 19, 2004Date of Patent: June 6, 2006Assignee: Solutia Austria GmbHInventors: Gerald Hobisch, Peter Morre, Roberto Cavalieri, Sergio Gazzea, Robertino Chinellato
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Patent number: 7049365Abstract: A heat sealable tape of a copolymer of tetrafluoroethylene and at least about 15% by weight of a highly fluorinated monomer. The copolymer has a melt viscosity of no greater than about 1000 Pa·S at 372° C. and an application temperature of no greater than about 250° C. The invention further provides for a seam formed from two sections of sheet material, especially fabric, wherein each sheet has at least one fluoropolymer surface. The sections are sealed one to the other by application of heat sealable composition over one fluoropolymer surface of each section. The heat sealable composition comprises a copolymer of tetrafluoroethylene and at least about 15% by weight of a highly fluorinated monomer, the copolymer having a melt viscosity of no greater than about 1000 Pa·S at 372° C. and an application temperature of no greater than about 250° C.Type: GrantFiled: December 5, 2003Date of Patent: May 23, 2006Assignee: E. I. du Pont de Nemours and CompanyInventors: Ronald Earl Uschold, Sina Ebnesajjad
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Patent number: 7041728Abstract: The present invention provides a method of making an aqueous dispersion of non-melt processible polytetrafluoroethylene, the method comprising: (a) an aqueous emulsion polymerization of an amount of tetrafluoroethylene to produce a final amount of polytetrafluoroethylene solids and optionally up to 1% by weight based on the amount of tetrafluoroethylene of a perfluorinated comonomer, wherein said aqueous emulsion polymerization is initiated with a free radical initiator and the polymerization is carried out in the presence of a fluorinated surfactant, and wherein before completing the feeding of said amount of tetrafluoroethylene but after feeding at least 80% by weight of said amount of tetrafluoroethylene, free radicals capable of introducing ionic end groups or precursors thereof in the polytetrafluoroethylene polymer are caused to be formed at a rate that without counter measures would cause an increase in the polymerization rate of at least 20%; (b) reducing the amount of fluorinated surfactant in the thType: GrantFiled: October 12, 2004Date of Patent: May 9, 2006Assignee: 3M Innovative Properties CompanyInventors: Tilman Zipplies, Klaus Hintzer, Michael C. Dadalas, Gernot Loehr
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Patent number: 7037966Abstract: The invention relates to a fluoropolymer resin-based composition useful as a stain resistant coating. The coating composition contains organosilicates and at least one water-scavenger, and has an extended pot life. Articles coated with the composition show superior weatherability, dirt shedding, and stain resistance, without a negative effect on gloss. The coating is especially useful on roofing materials, wall materials and other outdoor building materials.Type: GrantFiled: June 23, 2004Date of Patent: May 2, 2006Assignee: Arkema Inc.Inventors: Min Zheng, Kurt Wood, Lonnie Bryant
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Patent number: 7015275Abstract: An aqueous water- and oil-repellent dispersion containing: (A) a homopolymer or copolymer containing at least one polymerizable compound having a perfluoroalkyl or perfluoroalkenyl group and an acrylate or methacrylate group, or a copolymer containing said polymerizable compound and another compound copolymerizable therewith, (B) a surfactant comprising a cationic surfactant and a nonionic surfactant comprising an alkylene oxide adduct of a higher aliphatic secondary alcohol, and (C) a high flash-point organic solvent, has durable water- and oil-repellency and excellent storage stability.Type: GrantFiled: April 4, 2000Date of Patent: March 21, 2006Assignee: Daikin Industries, Ltd.Inventors: Tsukasa Aga, Masahiro Miyahara, Masaki Fukumori, Ryosuke Hara
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Patent number: 6984697Abstract: The invention provides a fluorothermoplastic composition comprising interpolymerized units derived from about 94 to about 97.5 mole percent (mol %) tetrafluoroethylene (TFE), about 2 to about 3 mol % perfluoro (propyl vinyl ether) (PPVE), and about 0.5 to about 3 mol % hexafluoropropylene (HFP). The invention also provides a fluorothermoplastic composition comprising interpolymerized units derived from about 94 to about 97 mol % TFE, about 0.75 to about 3 mol % PPVE, and about 1.5 to about 3.5 mol % HFP. These fluorothermoplastic compositions have a flex life that fits the equation: log(flex life cycles)?0.71+4.0*(MFI(?0.294)), a method of making fluorothermoplastic compositions, a method of improving stress crack resistance, and fluorothermoplastic articles.Type: GrantFiled: October 7, 2003Date of Patent: January 10, 2006Assignee: 3M Innovative Properties CompanyInventors: Thomas J. Blong, Lisa P. Chen, Ralph Kaulbach, Friedrich Kloos, Georg Burkard
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Patent number: 6953830Abstract: The present invention is a fluorine containing ethylene copolymer obtained by the copolymerization of ethylene with suitable fluorine-containing comonomer compounds, wherein the fluorine-containing comonomer compound is present at a concentration of up to 40% by weight, based on the total weight of the ethylene copolymer.Type: GrantFiled: March 7, 2002Date of Patent: October 11, 2005Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard T. Chou
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Patent number: 6946511Abstract: Elastomeric parts having a magnetic flux density of at least 10 gauss on their surface deflect a portion of reactive plasmas from contact with the surface of the parts. Thus, such parts may be exposed to reactive plasmas for longer periods, with less degradation, than may similar elastomer parts that do not have such a magnetic flux density on their surface.Type: GrantFiled: October 20, 2003Date of Patent: September 20, 2005Assignee: DuPont Dow Elastomers, LLCInventors: Kaori Iwamoto, Bunichi Rai, Shinichi Sogo
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Patent number: 6946513Abstract: There is provided an elastomer composition which is prepared by using a very clean filler reduced in both of an amount of moisture generation and an amount of organic outgas generation and is suitable as a molding material for semiconductor production apparatuses and there is provided a molded article. The composition is a crosslinkable composition comprising a high molecular weight polymer, particularly a crosslinkable fluorine-containing elastomer and a filler which has a weight reduction ratio per unit surface area of not more than 2.5×10?5% by weight/m2 when heating at 200° C. for two hours and a total amount of organic gas generated of not more than 2.5 ppm when heating at 200° C. for 15 minutes. The molded article is produced from the crosslinkable composition.Type: GrantFiled: April 27, 2001Date of Patent: September 20, 2005Assignee: Daikin Industries, Ltd.Inventors: Katsuhiko Higashino, Hiroyuki Tanaka, Takafumi Yamato, Tsuyoshi Noguchi
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Patent number: 6933338Abstract: To provide a water- and oil-repellent composition excellent in durability and excellent in safety and preservation of the environment. A water- and oil-repellent composition which comprises (A) a polymer, (B) an aqueous medium and (C) a surfactant in a mass ratio of (A)/(B)/(C)=100/100-500/1-10, the polymer (A) containing a polymerization unit based on a (meth)acrylate having a polyfluoroalkyl group, a polymerization unit based on an alkyl(meth)acrylate having a C1-C12 alkyl group, a polymerization unit based on an alkyl(meth)acrylate having a C16-C22 alkyl group and a polymerization unit based on a specific compound having a blocked isocyanate group.Type: GrantFiled: October 27, 2003Date of Patent: August 23, 2005Assignee: Asahi Glass Company, LimitedInventors: Shuichiro Sugimoto, Takashige Maekawa
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Patent number: 6930142Abstract: A seal ring with a sliding surface, which is obtained by molding a molding powder or granulated powder of non-melt-moldable modified polytetrafluoroethylene containing 0.01 to 1% by weight of a perfluorovinylether unit represented by the formula (I): —CF2—CF(—O—X)—??(I) wherein X represents a perfluoroalkyl group having 1 to 6 carbon atoms or a perfluoroalkoxyalkyl group having 2 to 9 carbon atoms, the modified polytetrafluoroethylene having a heat of crystallization of 18 to 25J/g measured by a differential scanning calorimeter.Type: GrantFiled: March 21, 2001Date of Patent: August 16, 2005Assignee: Daikin Industries, Ltd.Inventors: Tomihiko Yanagiguchi, Masamichi Sukegawa, Michio Asano
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Patent number: 6927265Abstract: The present invention provides a fluoropolymer that is melt-processible and thermoplastic and that has a melting point between 100° C. and 320° C. The fluoropolymer is derived from (a) one or more gaseous fluorinated monomers, (b) one or more modifiers selected from (i) olefins having a bromine or iodine atom bonded to a carbon of the double bond of the olefin, (ii) olefins corresponding to formula (I): Xa2C?CXa—Rf—Br??(I) wherein each Xa independently represents hydrogen, fluorine, bromine, chlorine or iodine, Rf is a perfluoroalkylene group, typically having 1 to 8 carbon atoms, a perfluorooxyalkylene group or a perfluoropolyether group and (iii) mixtures thereof; and (c) optionally one or more comonomers selected from non-gaseous fluorinated monomers and non-fluorinated monomers. The resulting fluoropolymer has long chain branches. The invention further provides a method for making these polymers.Type: GrantFiled: February 6, 2004Date of Patent: August 9, 2005Assignee: 3M Innovative Properties CompanyInventors: Harald Kaspar, Klaus Hintzer, Tilman Zipplies, Ralph Kaulbach
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Patent number: 6921787Abstract: Non-stick coatings for use on a flexible substrate include a fluoropolymer, an acrylic polymer, and a polyol and/or diol. The ratio of acrylic polymer to polyol and/or diol is between about 90:10 and about 10:90 by weight, preferably about 50:50. The ratio of acrylic polymer and polyol or diol to fluoropolymer is preferably about 100:60 by weight.Type: GrantFiled: December 3, 2003Date of Patent: July 26, 2005Assignee: Akzo Nobel Non-Stick CoatingsInventor: Thomas J. Bate
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Patent number: 6916871Abstract: A composition and method for making a fluoroelastomer is disclosed. The composition comprises a fluoroelastomer containing chlorine and an organic compound containing at least an hydride function. The hydride function has the formula MH where M is Si, Ge, Sn or Pb.Type: GrantFiled: October 28, 2002Date of Patent: July 12, 2005Assignee: 3M Innovative Properties CompanyInventors: Erik D. Hare, William D. Coggio, Klaus Hintzer, Robert E. Kolb, Peter J. Scott, Alain Verschuere, Harald Kaspar
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Patent number: 6916875Abstract: A crosslinkable fluororubber composition comprising (A) a liquid perfluoro compound having alkenyl groups and a divalent perfluorolakylene or perfluoropolyether structure, (B) a reinforcing filler, (C) a surface treating agent having a fluoroalkyl or fluoropolyalkyl ether group and a silanol group, (D) an addition reactive compound having hydrosilyl groups, and (E) a hydrosilyl or peroxide crosslinker is prepared by mixing components (A) to (C) to form a liquid or paste composition, adding component (D) thereto to form a millable composition, and mixing component (E) therewith. The composition is effectively roll workable and cures into products having excellent physical properties.Type: GrantFiled: March 21, 2003Date of Patent: July 12, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yasuhisa Osawa, Shinichi Sato, Masatoshi Arai
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Patent number: 6914093Abstract: Polyamideimide coating compositions for magnet wire which exhibit solvent or varnish-induced craze resistance. The polyamideimide compositions include a compound selected from the group consisting of diacid compounds, trimellitic anhydrides, benzophenonetetracarcoxylic anhydrides and mixtures thereof, a diisocyanate compound, dihydroxyl compound, a trihydroxyl compound, a fluoropolymer, and a mineral filler.Type: GrantFiled: October 16, 2001Date of Patent: July 5, 2005Assignee: Phelps Dodge Industries, Inc.Inventor: James J. Xu
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Patent number: 6911482Abstract: An ion exchange fluorocarbon resin precursor composition obtained by removing liquid components from a mixed solution of a dispersion of an ion exchange fluorocarbon resin precursor and a dispersion of tetrafluoroethylene polymer (PTFE).Type: GrantFiled: February 13, 2002Date of Patent: June 28, 2005Assignee: Asahi Kasei Kabushiki KaishaInventors: Takuya Hasegawa, Yoshimichi Nakayama
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Patent number: 6894106Abstract: Provided is an aqueous water- and oil-repellent dispersion free of an organic solvent and having durable water- and oil-repellency and excellent storage stability. The aqueous water- and oil-repellent dispersion is produced by emulsifying a perfluoroalkyl group-containing (meth)acrylate copolymer with the use of an ionic surfactant and/or a nonionic surfactant having less than 8 mol of added ethylene oxide per one hydrophobic group so that an average particle diameter is at most 100 nm and an integrating sphere turbidity is at most 20 (kaolin); adding, before the polymerization, a surfactant having at least 8 mol of added ethylene oxide per one hydrophobic group and a protective colloid; and conducting the polymerization.Type: GrantFiled: September 13, 2001Date of Patent: May 17, 2005Assignee: Daikin Industries, Ltd.Inventors: Tsukasa Aga, Masaki Fukumori
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Patent number: 6894105Abstract: Dyed fluoropolymers that are useful, for example, as conformal coatings comprise the reaction product of one or more fluorochemical (meth)acrylate monomers and one or more (meth)acrylate functional dyes. Coating compositions comprise the dyed fluoropolymer and articles are coated with the coating composition.Type: GrantFiled: July 26, 2002Date of Patent: May 17, 2005Assignee: 3M Innovatives Properties CompanyInventors: Michael J. Parent, Patricia M. Savu, Harry E. Johnson, David B. Olson
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Patent number: 6890657Abstract: A surface contacting member for toner fusing systems and processes. This surface contacting member has a fluoroelastomer surface layer containing amorphous silica that has been surface treated with at least one organoaminosilane.Type: GrantFiled: June 12, 2001Date of Patent: May 10, 2005Assignee: Eastman Kodak CompanyInventors: Jerry A. Pickering, Stephen V. Davis, Theodora Miller
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Patent number: 6884827Abstract: A seal ring seals operating oil hermetically and is attached to an annular seal ring groove provided on an outer circumference of a shaft member. The seal ring comprises fluororesin, metal powder having a hardness equal to or more than that of any of a side surface of the seal ring groove serving as a sliding partner and an inner circumferential surface of a housing engaged relatively rotatable with the outer circumference of the shaft member, and modified fluororesin formed by irradiating an ionizing radiation in a range from 1 kGy to 10 MGy inclusive in a state of being heated up to a melting point thereof or higher under an inert gas atmosphere with an oxygen partial pressure of 1.33 kPa or less.Type: GrantFiled: April 1, 2003Date of Patent: April 26, 2005Assignees: Nissan Motor Co., Ltd., Hitachi Cable Ltd.Inventors: Tomohito Ota, Tomihito Hashimoto, Yasuaki Yamamoto, Hiroo Kusano
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Patent number: 6869997Abstract: Fluoropolymers are prepared by a process comprising polymerizing at least one fluoromonomer in an aqueous reaction medium containing monomer, a radical initiator and a 3-allyloxy-2-hydroxy-1-propanesulfonic acid salt as surfactant. The medium may optionally contain one or more of an antifoulant, a buffering agent and a chain-transfer agent.Type: GrantFiled: May 6, 2003Date of Patent: March 22, 2005Assignee: Arkema, Inc.Inventors: Roice Andrus Wille, Lotfi Hedhli, Mehdi Durali, Sayed Youssef Antoun