Abstract: A method for treating an outdoor article, wherein a surface treating agent comprising a medium (B) containing a tetraalkoxysilane or a silane compound having a silanol group obtained by hydrolyzing an oligomer of such a tetraalkoxy silane (A), wherein the content of (A) is from 0.01 to 100 parts by weight per 100 parts by weight of (B), is used, and a thin film is formed by treating a hydrophobic synthetic resin coating film surface of the outdoor article with such a surface treating agent. It is thereby possible to prevent formation of a streak soils which are likely to form at a portion where rain water collects and runs down, such as below a window frame of a building.

Abstract: A low dielectric constant material is provided for use as an insulation element in an electronic device, such as but not limited to an integrated circuit structure for example. Such a low dielectric constant material may be formed from an aqueous fluoropolymer microemulsion or microdispersion. The low dielectric constant material may be made porous, further lowering its dielectric constant. The low dielectric constant material may be deposited by a spin-coating process and patterned using reactive ion etching or other suitable techniques.

Abstract: A water repellent for automobile window glass includes dimethyl polyorganosiloxane, an inorganic acid, a water-type solvent, and at least one member selected from the group consisting of alkyl group-containing polyorganosiloxanes each having a specific structure, fluorine resins each having a specific structure, and paraffin waxes.

Abstract: Fluorine-containing resin molded article comprising a molded article of a fluorine-containing resin composition containing 0.1 to 30% by weight of a carbon material, a surface of said molded article being fluorinated. The fluorine-containing resin molded article can be obtained by, after preparing molded article of a fluorine-containing resin composition containing 0.1 to 30% by weight of a carbon material, fluorinating the surface of the article with a reaction gas which comprises a compound containing fluorine atom. This fluorine-containing resin molded article has an antistatic property and non-tackiness.

Abstract: An aqueous dispersion composition comprising a fluorine-containing melt-processable resin powder having an average particle size of 10 to 1000 .mu.m, a water-soluble solvent, a surfactant and water, and said fluorine-containing melt-processable resin powder being contained in an amount of 15 to 80 % by weight. Without generating cracks and pin holes, a thickness of coating film per one application can be increased more than 1 mm, and a total thickness can further be made thicker.

Abstract: The invention provides a first water-based fluorine-containing paint including a water-based emulsion containing a fluorine-containing copolymer dispersed therein, and 1-50 parts by weight of a hardener per 100 parts by weight of the copolymer. The copolymer is prepared by copolymerizing 30-65 mol % of a fluoroolefin, 14-69 mol % of a copolymerizable vinyl-containing compound, and 1-30 mol % of a hydroxyl-containing compound and/or a polymerizable carboxyl-containing compound. The hardener is prepared by mixing 1 part by weight of a self-emulsifiable polyisocyanate with 0.01-1 part by weight of a compound containing in the molecule an oxyethylene unit and an alkoxysilyl group. When mixed with the emulsion, the hardener becomes well dispersed therein.

Abstract: This invention provides a fluoropolymer dispersion useful for coating applications. The dispersion is a homogeneous and non-ozone depleting dispersion comprising a lubricious fluoropolymer, an inert perfluorinated liquid, a polar solvent, and an effective amount of a surface active agent selected from the group consisting ofa. perfluoroaliphatic amidoalkanols;b. polymerized products formed from the reaction of a mixture comprising a hydrophilic monomer and a monomer of the general formula: ##STR1## wherein p and q are integers between 1 and 4 inclusive, x and y are integers between 0 and 4 inclusive, m is 1 or 2, n is an integer between 3 and 10 inclusive, X' is either a methyl group or a single hydrogen atom, g is 0 or 1, and Q is a sulfonamido constituent group according to the formula: ##STR2## wherein R.sup.

Abstract: Enhanced fidelity of pattern transfer of aqueous developable photoresist compositions is achieved with top antirefective coatings which are fluorine-containing and have a refractive index approximately equal to the square root of the underlying photoresist and which are removable in the developer for the photoresist.

Abstract: A water-absorptive soft contact lens comprising a polymer prepared by polymerizing a monomer mixture comprising (A) a fluorine-containing styrene derivative represented by the general formula (I): ##STR1## wherein R.sup.1 is hydrogen atom or methyl group, m is an integer of 1 to 3 and n is 0 or an integer of 1 to 7, and (B) N, N-dimethyl(meth)acrylamide. The water-absorptive soft contact lens has excellent oxygen permeability, high mechanical strength and excellent flexibility independent of water content.

Abstract: A vinylidene fluoride copolymer having a relatively high molecular weight is formed by copolymerizing (a) vinylidene fluoride as a principal component, (b) a small amount of epoxy group-containing monomer, and (c) an optional component, such as an unsaturated dibasic acid monoester functioning as a curing agent for the epoxy group. When cured with an optional epoxy curing agent, the vinylidene fluoride copolymer provides a cured product having an adhesion with a metal substrate, etc., and also showing excellent solvent resistance and chemical resistance. The vinylidene fluoride copolymer is particularly suitable for constituting a binder for producing an electrode for a non-aqueous solvent-type secondary battery.

Abstract: A method of dehydrofluorinating a fluoropolymer comprising the steps of: providing an fluoropolymer emulsion comprising water, a fluoropolymer, and substantially no organic solvent; adding to the fluoropolymer emulsion a basic compound, the base compound being added at a concentration and in an mount that does not result in coagulation of the fluoropolymer; and exposing the mixture of fluoropolymer emulsion and basic compound to reaction conditions sufficient to cause dehydrofluorination of the fluoropolymer.

Abstract: A reactive and processable fluoropolymer, obtainable by mechanical shearing ofa fluoropolymer A) comprising polymerized monomer units of at least one fluorinated, optionally substituted, alkene with 2 to 8 carbon atoms andoptionally at least one member selected from the group consisting of a perfluorinated vinyl ether, non-fluorinated olefin and non-fluorinated vinyl ester, and0.3 to 7% of a compound B) which possessesa double bond (I) capable of adding to polymeric radical fragments anda II-electron system which is either conjugated with double bond (I) or has readily transferrable hydrogen atoms in the allyl or benzyl position andoptionally further double bonds or reactive groups andoptionally further auxiliary agents (C).The fluoropolymer is especially useful in radical addition or nucleophilic or electrophilic substitution or addition, e.g. cross-linking or grafting.

Abstract: Aqueous dispersion of a fluorine-containing copolymer which is prepared by, in an aqueous dispersion containing fluorine-containing copolymer particles which comprise 70 to 95% by mole of vinylidene fluoride and 5 to 30% by mole of chlorotrifluoroethylene, seed-polymerizing 20 to 100 parts by weight of an acrylic acid ester and/or a methacrylic acid ester in the presence of 100 parts by weight of the fluorine-containing copolymer particles. The aqueous dispersion assures excellent film forming property, and can provide a highly glossy coating excellent in mechanical properties, transparency at clear coating and weatherability.

Abstract: The present invention relates to a gelled fluoride resin fine particle dispersion for use as a coating, to a method of production thereof, and to a method using this gelled fluoride resin fine dispersion to protect an alkaline inorganic hardened body.The objective of the present invention is to provide an aqueous resin for use as a coating, this aqueous resin being able to form a high performance coating film that is superior in its ability to inhibit the leaching out of the alkaline substance from the alkaline inorganic hardened body, which has excellent weatherability, water resistance, alkaline resistance, and dirt picking resistance.The present invention accomplishes the stated objective through the utilization of gelled fine particles of a fluorine containing resin.The present invention may be used in the coating field.

Abstract: A fluororubber coating composition containing a fluororubber, a liquid medium, a coupling agent, a crosslinking agent and a carboxylic acid, which has a long pot life and provides a coating film having a uniform thickness.

Abstract: Vinylidene fluoride copolymers having a melting temperature below about 160.degree. C. are used to prepare pigmented powder coatings for galvanized steel. The coatings are corrosion-resistant and generally show a high gloss.

Abstract: Aqueous dispersions of fluoropolymers which are obtained by emulsion polymerization, are not processsable from the melt and form a film on sintering, which comprise a fluoropolymer A) having an average particle size (number average) of from 180 to 400 nm and a fluoropolymer B) having an average particle size which is lower by a factor of from about 0.3 to about 0.7, so that the total dispersion has a non-monomadal number distribution of the particle diameter, are suitable for soaking, impregnating or coating surfaces, for example of fibers or planiform articles of fibers or porous materials, in particular for coating fiberglass fabrics, and also for the formulation of metal coating systems.

Abstract: Resin compositions comprising inorganic species selected from the group consisting of siloxanes and phosphazenes in combination with and capable to being bonded to thermoset and/or thermoplastic resin system derivable from cyanate functional monomers and/or oligomers. Reacted resin compositions are found to have enriched areas of the inorganic species. The resin compositions have a variety of improved properties including toughness and improved resistance to oxidation.

Abstract: The present invention relates to a polyolefin composition, having good extrusion characteristics. The composition comprises a fluoropolymer; one or more of a low molecular weight C.sub.1-4 alkyl ethers of a poly C.sub.2-4 alkylene oxide; and a metal oxide the weight ratio of the ether to fluoropolymer being less than 1:1. The blend is suitable for making blown film.

Abstract: A sealant composition comprises a dispersion of a fluorocarbon polymer with particles no larger than 25 micrometers in a low volatility liquid and up to 50 percent of a higher volatility liquid. Also covered is an applicator for applying the sealant to the gasket of an electrochemical cell.

Abstract: This invention provides a fluoropolymer dispersion useful for coating applications. The dispersion is a homogeneous and non-ozone depleting dispersion comprising a lubricious fluoropolymer, an inert perfluorinated liquid, a polar solvent, and an effective amount of a surface active agent selected from the group consisting of:a. perfluoroaliphatic amidoalkanols;b. polymerized products formed from the reaction of a mixture comprising a hydrophilic monomer and a monomer of the general formula: ##STR1## wherein p and q are integers between 1 and 4 inclusive, x and y are integers between 0 and 4 inclusive, m is 1 or 2, n is an integer between 3 and 10 inclusive, X' is either a methyl group or a single hydrogen atom, g is 0 or 1, and Q is a sulfonamido constituent group according to the formula: ##STR2## wherein R.sup.

Abstract: A mold release agent composition which contains A) 10 to 95% by weight of a copolymer of a polyfluoroalkyl acrylate or methacrylate ester having a polyfluoroalkyl group having 1 to 20 carbon atoms and a vinyl compound having an alkyl group having 8 to 30 carbon atoms, and B) 90 to 5% by weight of a silicone, has sufficient releasability, has an only slightly amount of the migration to a shaped article and gives no adverse effect on fabricability of a shaped article surface.

Abstract: A fluoropolymer composition for coating, which comprises a polymer having a fluorine-containing cycloaliphatic structure and at least one coupling group in its molecule and a solvent for dissolving said polymer.

Abstract: An improved process for preparing free flowing tetrafluoroethylene (TFE) polymer powders is disclosed in which a TFE polymer powder is (1) wetted with an aqueous solution containing a wetting agent selected from the group consisting of (a) ethylene glycol ethers, (b) propylene glycol ethers and (c) diols or triols, (2) agglomerated and (3) dried.

Abstract: The invention concerns a polyethylene-based ski coating containing up to 5%-wt of a fluorinated additive. This ski coating is especially suitable for making downhill and cross-country skis.

Abstract: An elastomeric composition having improved resistance to chemical attack is provided, the elastomeric composition including a perfluoroelastomer and a non-fibrillating particulate fluorographite. Also, a process for improving the processibility and resistance to chemical attack of a perfluoroelastomer is provided, in which the perfluoroelastomer is mixed with a non-fibrillating fluorocarbon particulate polymer to form a elastomeric composition which is processed at a temperature less than the melting temperature of the non-fibrillating fluorocarbon particulate polymer to disperse the fluorocarbon polymer throughout the perfluoroelastomer while maintaining the fluorocarbon polymer in particulate form. A method of making a seal which is resistant to chemical attack for preventing the leakage of a fluid between a first member and a second member is also provided.

Abstract: An elastomeric composition having improved resistance to chemical attack is provided, the elastomeric composition including a perfluoroelastomer and a non-fibrillating particulate fluorographite. Also, a process for improving the processibility and resistance to chemical attack of a perfluoroelastomer is provided, in which the perfluoroelastomer is mixed with a non-fibrillating fluorocarbon particulate polymer to form a elastomeric composition which is processed at a temperature less than the melting temperature of the non-fibrillating fluorocarbon particulate polymer to disperse the fluorocarbon polymer throughout the perfluoroelastomer while maintaining the fluorocarbon polymer in particulate form.

Abstract: A thermosetting powdery coating composition which comprises, in admixture: (A) from 40 to 98 parts by weight of a fluorine-containing copolymer, which is a copolymer of a fluoroolefin and a comonomer having a crosslinkable reactive group, e.g., hydroxy, carboxyl, amino and glycidyl groups, containing at least 10% by weight of fluorine and having an intrinsic viscosity of 0.05-2 dl/g (30.degree. C., tetrahydrofuran), a glass transition temperature of 30.degree.-120.degree. C. and a weight loss by heating which does not exceed 2% and (B) from 60 to 2 parts by weight of a curing agent capable of forming crosslinks by reacting with the crosslinkable reactive groups in (A), except for the composition wherein (A) is a hydroxyl group and a weight loss by heating which does not exceed 2% and (B) is a blocked isocyanate compound.

Abstract: An oil-repellent fluororubber composition obtained by compounding a low-molecular weight tetrafluoroethylene resin with a peroxide crosslinked fluororubber having a Mooney viscosity of 90 or more ML.sub.1+10 (100.degree. C.) or compounding a low-molecular weight tetrafluoroethylene resin and an inorganic filler selected from powders of solid substances, such as iron, nickel, cobalt, iron-cobalt alloy, molybdenum, tungsten, tantalum and tungsten-carbide, having surface energy higher than that of copper with a peroxide crosslinked fluororubber. An oil-repellent fluororubber elastomer having excellent oil repellency and at the same time maintaining original mechanical and physical characteristics sufficiently can be obtained, using easily available materials on the market without any special means of processing and treatment.

Abstract: There are disclosed a graft copolymer formed by grafting a styrenic monomer onto a high polymer having double bonds in the side chain to constitute highly syndiotactic polystyrenic chain as the graft component, the graft copolymer having a content of graft component of 0.005 to 99% by weight and a reduced viscosity of 0.01 to 30 dl/g as measured at a concentration of 0.05 g/dl in 1,2,4-trichlorobenzene at 135.degree. C. or a melt index of 0.001 to 500 g/10 minutes as measured at 300.degree. C. under a load of 2.16 kg; a process for efficiently producing the above graft copolymer using a catalyst comprising specific components; and a resin composition comprising the above graft copolymer, a highly syndiotactic styrenic polymer or other thermoplastic resin and, when necessary, an inorganic or organic filler. The above graft copolymer and resin composition are excellent in resistance to heat and chemicals, electrical properties, moldability, compatibility, impact resistance, etc.

Abstract: An aqueous fluorine-containing polymer dispersion having particle diameters of 0.05-3 .mu.m, which is obtainable by emulsion-polymerizing 5-95 parts by weight of a monomer mixture consisting of at least one monomer selected from the group consisting of alkyl acrylates whose alkyl groups have 1-18 carbon atoms and alkyl methacrylates whose alkyl groups have 1-18 carbon atoms and optionally an ethylenically unsaturated compound copolymerizable with the alkyl acrylates and the alkyl methacrylates, in an aqueous medium in the presence of 100 parts by weight of particles of a vinylidene fluoride polymer; and an aqueous dispersion containing a fluorine-containing polymer which consists essentially of 95-30 parts by weight (in terms of solids content) of said aqueous fluorine-containing polymer dispersion and 5-70 parts by weight (in terms of solids content) of an aqueous dispersion of a water-soluble resin and/or a water-dispersible resin.

Abstract: A fluororubber-containing powder coating composition comprising a fluororubber, an adhesion-preventing material and optionally a cross-linking agent, which composition has an particle size of 10 to 2,000 .mu.m and an apparent density of at least 0.2 g/cc, which provides a homogeneous smooth coated film having no or only a small amount of bubbles.

Abstract: A wholly aromatic polyester resin composition contains:(1) a wholly aromatic polyester resin,(2) at least one member selected from a glass fiber and a silica-alumina fiber,(3) glass beads,(4) titanium oxide, and(5) a fluorocarbon polymerThe wholly aromatic polyester resin composition has high heat resistance and mechanical strengths, low anisotropy and excellent appearance, and shows low dissolution of components, excellent releasability and non-tackiness. It can be molded into an ovenware.

Abstract: A fluorine-containing polymer composition comprising a solvent containing a block compound composed of a polyfluorinated segment and a hydrocarbon segment and a fluorine-containing polymer having a fluorine-containing aliphatic cyclic structure dissolved in the solvent.

Abstract: Preparation of poly(vinyl fluoride) films with minimal defects is aided by the incorporation of toluene in the casting dispersion.

Abstract: Disclosed are a matte fluorine based aqueous dispersion containing, as the resin component, a reaction product of a fluorine based polycarboxylic acid resin with an epoxysilane compound; a process for preparing the fluorine based aqueous dispersion, which process comprises dissolving or dispersing the fluorine based polycarboxylic acid resin and an alicyclic epoxysilane compound in an organic solvent to form an organic solution or organic dispersion, followed by heating and reacting until an acid value of the fluorine based polycarboxylic acid resin is reduced by one or more, incorporating a neutralizing agent and by dispersing in water, or which process comprises dissolving or dispersing the fluorine based polycarboxylic acid resin in an organic solvent to form an organic solution or organic dispersion, followed by adding an aliphatic epoxysilane compound after or before neutralization, dispersing in water, provided after neutralization when the aliphatic epoxysilane compound is added before neutralization,

Abstract: Aqueous fluoropolymer formulations containing in finely divided form from 15 to 75% by weight of a fluoropolymer which preferably has at least 40% by weight of tetrafluoroethylene units, from 0.5 to 10% by weight of an organic compound which has at least two, preferably 2-4, isocyanate groups and, optionally, up to 20% by weight of auxiliary or additive substances are prepared and used for coating yarn, in particular sewing yarn, and textile sheet materials.

Abstract: A process for purifying fluoropolymers by contacting them at temperatures above 140.degree. C. with a liquid perfluorinated cycloalkane. The resulting polymers are particularly useful where polymers with reduced impurities are desirable, such as in medical devices and in parts for the semiconductor manufacturing industry. The liquid perfluorinated cycloalkanes improve the adhesion of fluoropolymer to themselves and other materials.

Abstract: A process for preconsolidating a planar porous fiber-thermoplastic resin layer which is unconstrained in the inplane directions by heating the layer to above the melting point of the resin, then applying pressure to the plane of the layer causing resin flow, thus orienting the fibers in the plane of the layer.

Abstract: Concentrated, aqueous, colloidal dispersions of tetrafluoroethylene polymers having a polymer solids content of 25 to 70% by weight, which comprise, as the dispersion stabilizer, an amine oxide of the formula ##STR1## in which R.sup.1 is an alkyl radical having 6 to 22 carbon atoms or a mixture of such alkyl radicals and R.sup.2 is an alkyl radical having 1 to 22 carbon atoms or a mixture of such alkyl radicals, and in which R.sup.1 and R.sup.2 are identical or different and 50 to 0% by weight of the alkyl radicals R.sup.1 and R.sup.2 can be replaced by alkenyl radicals having 6 to 22 carbon atoms and having 1 to 3 C.dbd.C double bonds, are obtained by concentration with addition of these dispersion stabilizers. The dispersions are used for impregnating yarns and textile sheet-like structures.

Abstract: A cross-linkable, fluorine-containing elastomer composition comprising a fluorine-containing elastomer containing at least one of iodine and bromine in the molecule, an organic peroxide having a peroxy group --O--O--C(CH.sub.3).sub.2 R, where R is a lower alkyl group, in the molecule and an activation energy of not more than 34.0 Kcal/mole and another organic peroxide having the same peroxy group as defined above in the molecule and an activation energy of less than 34.0 Kcal/mole as cross-linking agents for the elastomer has less generation of CH.sub.3 I or CH.sub.3 Br at the decomposition of the organic peroxides without any substantial decrease in the compression set of the vulcanization products.

Abstract: A vinylidene fluoride-hexafluoroisobutylene copolymer powder is employed to thicken a conventional fluorine-containing liquid lubricant to provide a grease composition which has improved lubrication character in metal bearing subjected to the simultaneous conditions of high load, high speed and elevated temperature.

Abstract: A process is described for the preparation of a crosslinkable paint binder by working up a solution of a fluorine-containing copolymer composed of copolymerized units of a perfluoroolefin, a vinyl ester of a short-chain, saponifiable carboxylic acid and a vinyl ester of a strongly branched carboxylic acid which resists saponification. In this process, the bulk of the solvent and the residual monomers are first removed by distillation, the residual highly viscous copolymer is then dissolved in a mixture of alkanol and another solvent which is also capable of dissolving the saponified copolymer to form a homogeneous solution, and the alkaline saponification is subsequently carried out. If desired, the solvent is removed and exchanged for a paint solvent and this solution is finally filtered. A mild saponification is achieved in this manner.

Abstract: A tetrafluoroethylene base polymer-containing coating composition comprising a dispersion of a tetrafluoroethylene base polymer having a molecular weight of at least 5,000,000 in a liquid medium containing a surfactant, which is particularly useful for coating a fixing heater roller and a cooking utensil.

Abstract: A process for producing PTC (positive temperature coefficient) self-resetting overcurrent protection elements using two different crystalline polymers with an organic peroxide and carbon black. The mixture is kneaded at an elevated temperature. The two crystalline polymers include different proportions of tertiary hydrogen atoms to carbon atoms, so that the desired PTC characteristics of a highly crystallized polymer can obtain the benefit of greater proportions of tertiary hydrogen in a less highly crystallized polymer. A high degree of grafting to carbon black that increases the number of polymer having unpaired electrons in the crystalline polymer mixture through the decomposition of organic peroxide. The resulting mixture tends to disperse the carbon black uniformly throughout the resulting mixture, and to position the carbon black in a three-dimensional matrix in which it is fixed by cross-linking.

Abstract: Polyimide compositions containing both graphite and fluoropolymer exhibit superior wear performance against aluminum.

Abstract: A contrast medium-containing tube is provided which is a thermoplastic resin tube incorporated with a white bismuth compound composed mainly of bismuth oxide containing 70-85 wt % bismuth and having a particle diameter substantially smaller than 20 .mu.m. This contrast medium-containing tube looks white and remains white in appearance over a long period of time. It is easy to carry out extrusion molding for producing this contrast medium-containing tube.

Abstract: This invention relates to thermoplastic molding compositions, particularly thermoplastic polyesters, having incorporated therein a fluorinated polyolefin to improve wear resistance. More particularly, disclosed are polyester compositions having improved wear resistant good properties comprising a polyester resin, most preferably a poly(butylene terephalate) resin; a fluorinated polyolefin compound and a hindered phenolic compound and an ester compound, the last two components serving as a migrator package that serves to push a disproportionate amount of the fluorinated polyolefin within the subsurface of the resulting composition to thereby augment the wear resistant effect of the fluorinated polyolefin.

Abstract: A printing ink composition having a high degree of rub-off resistance comprising (a) a dispersion of a pigment in a vehicle containing a C.sub.7 -C.sub.40 oil and (b) a polymer latex emulsified in said dispersion. When employed for printing at high speeds, an anti-misting compound such as tridecyl acid phosphate, phosphoric acid, glycerol, or propylene carbonate is preferentially added to the ink composition. Where cost is not of paramount concern, a polytetrafluoroethylene wax is preferentially added to the ink composition.

Abstract: Ultra-violet screening compounds have been combined with hydrophobic fluid and solid-repellent compounds to provide a spray, and ultimately a thin solid adherent layering, deposit or coating for fabrics and the like that simultaneously imparts both fade or photodegradiation-resisting properties, and fluid and soil repellent properties.